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2.1.3.1 Radioisotopes
The basic fact is that x-rays are produced when electrons decelerate.
When the speeding electrons pass near the nucleus (which has a net positive charge)
they experience a force of attraction and are slowed down.
In this process of slowing down or deceleration, they lose a part of their initial kinetic
energy which is converted into X-rays.
So we can say that X-rays are emitted as a consequence of the deflection of cathode
electrons by the strong fields surrounding the nucleus of the target atoms.
Sometime the electrons are stopped instantaneously, then all their energy is
transformed into the maximum radiation energy with minimum wave length.
But there actually is a whole spectrum of longer wave lengths or low frequencies
emitted by electrons which lose only a part of their energy in a single encounter with
a nucleus and experience many collisions with target atoms before being brought to
rest.
The X-ray spectrum is therefore continuous with a definite minimum wavelength min.
We have E = hf, where h = Plank's Constant, and f = frequency.
The energy of an electron of charge (e) in falling through a potential difference V is
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eV and on complete absorption (or being completely stopped) this energy appears as
a quantum of X-rays of energy hf= hc/= eV which gives min = hc/eV = 12.
Where, c is the velocity of light and V is the voltage applied to the X-ray tube.
Characteristic X-rays are produced in quite a different way.
Sometimes the impinging electrons can make a direct impact upon one of the inner
electrons in an atom of the target, and, if the energy is great enough, can knock it
right out of the atom.
The atom is then unstable, and another electron in the same atom will drop into the
space vacated. In so doing it loses energy and a quantum of radiation is emitted. If E
is the energy lost then
E = hf = hc/
which gives =hc/E
E is a definite quantity associated with the particular energy change in the atom and
so the wave lengths concerned are specific.
Several wave lengths are possible and they constitute the characteristic spectrum (Fig.
2.1) .
The process is similar to the production of light, but for light the outer electrons only
are involved.
For X-rays the tightly bound inner shells K, L, M are concerned. If a K electron is
dislodged and an electron falls from the L shell to the K shell the K X-ray line is
produced, if an M shell electron falls to the K shell then the weaker K line is
produced.
The letter K shows the shell into which the electron falls.
The characteristic X-ray spectrum for copper will look like the continuous line in
Figure 2.2.
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where r1 and r2 are respectively the distances of C1 and C2 from the source.
Since I1 x I/E1 and I2 x I /E2
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E 2 (r2 ) 2
therefore E 1 (r1 ) 2
Here D1 & D2 are radiation dose rates at distances r1 and r2 from the source.
D1 and D2 have the same units and r1 and r2 also are in the same units.
This means that the radiation hazard (dose rate) decreases rapidly as we move away
from the radiation source.
As an example, the dose rate due to a radiation source at a distance of 10 meter from
the source would be only one hundredth (1/100 = 1/10 2) of the dose rate due to the
same source at 1 meter.
This is the simplest practical way in which a person working with external radiation
sources can keep his radiation dose down.
2.2 Radioactivity
It has already been stated in Section 2.1.3.1 that some of the isotopes of an element
are stable while others may be unstable.
The unstable atoms may become stable by emitting radiation.
The process which is followed by the emission of radiation is commonly known as
disintegration and this phenomenon of disintegration of atoms of (naturally occurring
or artificially produced) elements is called radioactivity.
Materials exhibiting this phenomenon are termed radioactive materials, or
radioisotopes.
Curie (Ci) is the unit of radioactivity and is equal to the disintegration rate of 3.7 x
1010 d.p.s.
Smaller units of radioactivity are millicurie and microcurie which are one thousandth
and one millionth part of a curie respectively.
The internationally agreed system of coherent unit for radioactivity that is now in use
for all scientific and technological purposes in many countries is the Bacquerel (Bq).
The Bacquerel is defined as one disintegration per second.
The relationship between Curie and Bacquerel is 1 Curie = 3.7 x 1010 Bacquerel.
If the incident beam intensity is Io, and I is the transmitted beam intensity then I = I o
exp (-x) where is called the linear absorption coefficient which depends on the
incident radiation energy and the specimen material/density.
The attenuation takes place through three principal effects photoelectric absorption,
Compton absorption and compton scattering.
A fourth mechanism, pair production, is operative above 1.02 MeV and is of
relatively lesser importance.
Taking into account all these effects the value for can be written as = (+ +k) where is
the total or linear attenuation coefficient, is the attenuation coefficient due to
photoelectric absorption, is the scattering coefficient.
has two components a Compton absorption coefficient and r Compton scattering
coefficient and k is called the pair production coefficient.
Figure 2.11 : Variation of attenuation coefficients of Al, Pb and Fe with radiation energy.
The equations and curves given relate only to monochromatic radiation.
If a radiation spectrum is composed of more than one spectral line radioisotopes or is
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a continuous (spectrum Bremsstrahlung) then for each radiation energy, a different
attenuation coefficient applies.
Sometimes it is convenient to use (m = /) instead of , where is the density of the shield
material.
m is called mass attenuation coefficient and is expressed in cm2/gm.
In most of the literature, the values quoted are in mm, while using these values from
the literature in the equation I = Io e-x should be calculated by multiplying m with the
respective of the material.
2.4 IONIZATION
Atoms and molecules are generally electrically neutral.
If by any process the electrons are removed from these neutral bodies then a net
positive charge remains on them.
Atoms, molecules and various subatomic particles which carry either a positive or
negative electrical charge are called ions.
Free electrons, not attached to any parent atom, are negative ions and free particles
carrying positive charges are positive ions.
Any action which disturbs the electrical balance of the atoms which make up matter
is referred to as ionization.
Radiation, either particle or electromagnetic, has the ability to ionize.
A high speed particle or a photon of energy which passes through matter will disrupt
the atomic arrangement of the matter.
For example, an alpha particle may strike an orbital electron in an atom and cause the
electron to leave its orbit.
The electron may attach itself to an atom.
The first atom then has a positive charge and the latter atom a negative charge, and
these are referred to as positive and negative ions or an ion pair.
By the process of ionization, the number of orbital electrons may be changed but not
the nucleus.
The nucleus remains as an atom of the same element as it was originally.
Gamma and X-rays have no mass and no weight.
They travel at the speed of light and do not produce ionization directly by collision.
In passing through mater, gamma and X-rays lose their energy to atoms by the three
ionization processes described in 2.3, namely photoelectric absorption, Compton
scattering and pair production.
Figure 2.12 shows an ion-chamber which forms an important part of a radiation
detector utilizing the phenomenon of ionization.
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2.5.2 Fluorescence
Several substances such as cadmium sulphate, barium platinocyanid or calcium
sulphate emit visible and ultraviolet light when irradiated with X-or gamma-rays.
If the emission of light takes place only during the period of irradiation, this is called
fluorescence.
Fluorescence is used both in fluoroscopy (fluorescent screens on which a picture of
the examined object can be observed) and in radiography, where fluorescent
intensifying screens are used to increase the photochemical effect of radiation.
The fluoro-metallic radiographic screens also employ this effect for image
intensification.
Using fluorescent screens either in fluoroscopy or radiography has some advantages
that help to reduce the time of inspection thereby making radiographic inspection
more economical.
The fluorescent or salt screens as they are generally called are especially suited to
medical radiography where there is a requirement to get a proper radiograph with a
minimum possible exposure to the patient.
However, in fluoroscopy the technique is not quantitative and often cannot show
serious defects.
The quality of the image is generally poor, The screens tend to saturate with small
amounts of radiation after which the glow remains constant, and the image contrast
cannot be improved further.