aueepre 15, 16 17. 18, 19. 20. 21 22. 2B 24, 25. EXERCISE I (A) (Mole & Equivalent Concept) Fill in the blanks with appropriate items : ‘The number of water molecules in 0.5 mol of barium chloride dihydrate is 20ml of 0.1 M H,C,0, 2H,0 (oxalic acid) sotution contains oxalic acid equal to moles. The volume of 1,204 x 10% molecules of water at 4°C is 0.2 mol of ozone (O,) at NTP. will occupy volume The balancing of chemical equation is based upon 2.gm of hydrogen will have same number of H atoms as are there in ghydrazine (NH,-NH,) x The mass of x atoms of element = la x The moles of x atoms of atriatomic gas= 35 ~ * The amount of Na,SO, which gives9.6 gmof SO} is ‘The 44 mg of certain substance contain 6,02 * 10” molecules. The molecular mass of the substance is The mass of | «10%? molecules of CuSO, SH,Ois. The atomic mass of iron is 56, The equivalent mass of the metal in FeCl is. ___ and that in FeCl, is ‘The sulphate ofa metal M contains 9.87% of M. The sulphate is isomorphous with ZnSO, 7H,0. The atomic mass of Mis ‘Abinary compound contains 50% of A (at. mass = 16) & 50% B (at. mass = 32). The empirical formula ofthe compound is 10.6 g of Na,CO, react with 9.8 g of H,SO, to form 16 g of Na,SO, & 4.4 g CO,, This is in accordance with the law of. 3 g ofa salt (m. wt, 30) are dissolved in250 ml of water. The molarity of solution is, 0.5 mole of BaCl, are mixed with 0.2 mole of Na,PO, the maximum number of mole of Ba,(PO,), formed are The Eq, weight of NaHPO, whenit reacts with excess of HClis ‘The mole fraction of solutein 20% (by weight) aqueous H,O, solution’ A metallic oxide contains 60% of the metal, The Eq, weight of the metal is ‘The number of gm of anhydrous Na,CO, present in 250 ml of 0.25 N solutionis, ml of0.1 MH,SQ, is required to neutralize 50 ml of 0.2M.NaOH solution The number of mole of water present in 90 g HO are The concentration of K* ionin 0,2M K,Cr,0, solution would be. 280 ml of sulphur vapour at NTP weight 3.2.¢. TheMol. formula of the sulphur vapouris___. W Bansal Classes Redox & Equivalent Concepts (Stochiometry-1) “iyQ2 UL 12. 13 14 Is 16. 17. 18 19. 20. 22. 2B. 4 25. True or False Statements : Equal volumes of helium and nitrogen under similar conditions have equal number of atoms. ‘The smallest particle is a substance which is capable in independent existence is called an atom. ‘The number of formula units in 0:5 mole of KClis 6.02 « 10°. 22.4 ofethane gas at S..P. contains H atoms as are present in 3 gram molecules of dihydrogen. Molarity of pure water is 55.5. A.20% solution of KOH (density = 1.02 g/ml) has molarity =3.64 Ina mixture of 1 g C,H, & 1 g C,H, the mole fraction ofboth are same. 1 mole of C,,H,,0, contains 22 hydrogen atoms. KCIO, & KMnO, are isomorphous in nature Mass of 3.01 x 10 molecules of of methane is 8 gm. Abhydrocarbon contains 86% C. 448 ml of the hydrocarbon weighs 1.68 gat STP. Then the hydrocarbon isanalkene. 6.023 * 10° e-* weigh one kg ‘An oxide of metal M has 40% by mass of oxygen. Metal M has relative atomic mass of 24. The ‘empirical formula of the oxideis MO. S gofa crystalline salt when rendered anhydrous lost 1.8 g of water. The formula weight ofthe anhydrous salts 160, The number of molecules of water of crystallisation in the salt is 5 Number of valence ein 4.2 g of N>is24N,. The equivalent mass of KMnO, in alkaline medium is molar mass divided by five. ‘The equivalent mass of Na,S,0; inits reaction with I, is molar mass divided by two. Ina reaction, HjMoO, is changed to MoO," In this case, H,MoO, acts as an oxidising agent KBrO, acts asa strong oxidising agent, I accepts 6 electrons to give KBr. 0.1 Msulphuric acid has normality of 0.05 N. Thereaction, 2H,0, > 2H, +0, isnot an example ofa redox reaction. The disproportionation reaction, 2Mn** +2H,0—> MnO, + Mn'? + 4H* isanexample ofa redox reaction ‘The oxidation number of hydrogen is always taken as+ 1 inits all compounds. ‘The increase in oxidation number of an element implies thatthe element has undergone reduction. The oxidation state of oxygen atom in potassium super oxide is -} E Bansal Classes Redox & Equivalent Concepts (Stochiometry-T)) 12]