Calculos para diagramas T-x-y, X-y, H-x,y para etanol (1)-agua(2) @

Pman (bar) 0.23335 Patm (bar) 0.7799 PTOT (bar) 1.01325

(g/mol) (cal/g) (cal/mol) (cal/g) VanLaar (cal/mol) A B C (°C) (cal °C/mol)

Compuesto PM Cp Az A12_21 l Ctes de Antoine p.e. hli Hvi
etanol (1) 46.069 0.582 26.8122 0.894 1.7966 9216 5.33675 1648.22 230.918 78.257 2098.228 11314.23
agua (2) 18.015 0.999 17.9970 0.956 0.9238 9718 5.11564 1687.537 230.17 100.077 1801.085 11519.08

Ec. Antoine Ec. Van Laar Raoult m

(°C) (bar) (-) (-) (-) (bar) (-) (cal °C/mol) volatilidad
Ti P1 i
0
P2 i
0
x1_supuesta g1 g2 P y1 hl Hv K1 K2 a 1/(y-x
78.257 1.01325 0.4408 1.00 1.0000 2.5188 1.0133 1.0000 2098 11314 #REF! #REF! 0.91267 #DIV/0!
102
78.234 1.012339 0.4404 0.99 1.0000 2.4950 1.0132 0.9892 2091 11312 #REF! #REF! 0.92147 -1186.3 100
78.171 1.009821 0.4392 0.95 1.0012 2.4007 1.0132 0.9480 2061 11302 #REF! #REF! 0.958876 -491.9 98
78.152 1.009065 0.4389 0.9 1.0053 2.2856 1.0132 0.9010 2027 11293 #REF! #REF! 1.011203 1001.8 96
94

Temperatura, T (°C)
78.293 1.014707 0.4414 0.8 1.0236 2.0654 1.0132 0.8200 1961 11281 #REF! #REF! 1.139232 49.9
92
78.638 1.028683 0.4477 0.7 1.0603 1.8595 1.0132 0.7535 1900 11277 #REF! #REF! 1.310324 18.7 90
79.150 1.049715 0.4571 0.6 1.1242 1.6692 1.0132 0.6988 1843 11279 #REF! #REF! 1.546734 10.1 88
79.794 1.07668 0.4692 0.5 1.2302 1.4962 1.0132 0.6536 1788 11286 #REF! #REF! 1.88689 6.5 86
84
80.549 1.109056 0.4837 0.4 1.4059 1.3424 1.0132 0.6155 1734 11296 #REF! #REF! 2.401334 4.6
82
81.457 1.149029 0.5016 0.3 1.7065 1.2103 1.0132 0.5806 1681 11309 #REF! #REF! 3.22951 3.6
80
82.797 1.210229 0.5291 0.2 2.2555 1.1039 1.0132 0.5388 1636 11331 #REF! #REF! 4.673114 3.0 78
83.939 1.264545 0.5536 0.15 2.7069 1.0622 1.0132 0.5067 1622 11349 #REF! #REF! 5.821334 2.8 76
85.906 1.362787 0.5979 0.1 3.3698 1.0296 1.0132 0.4532 1622 11380 #REF! #REF! 7.46012 2.8 0
87.136 1.427396 0.6271 0.08 3.7226 1.0195 1.0132 0.4195 1630 11398 #REF! #REF! 8.311741 2.9
88.803 1.51906 0.6685 0.06 4.1442 1.0113 1.0132 0.3728 1645 11421 #REF! #REF! 9.311348 3.197
91.147 1.656108 0.7306 0.04 4.6523 1.0052 1.0132 0.3042 1673 11450 #REF! #REF! 10.49047 3.786
94.602 1.876767 0.8310 0.02 5.2701 1.0013 1.0132 0.1952 1719 11485 #REF! #REF! 11.88683 1
5.707
96.996 2.043479 0.9070 0.01 5.6296 1.0003 1.0132 0.1135 1754 11504 #REF! #REF! 12.67961 9.659 0
99.902 2.262183 1.0070 0.001 6.0081 1.0000 1.0132 0.0067 1798 11518 #REF! #REF! 13.49752 161.112 0

Fracción molar del vapor, y

100.08 2.275928 1.0133 0.000 6.0291 1.0000 1.0133 0.0000 1801 11519 #REF! #REF! 13.54239 #DIV/0! 0
0
0
0
0
0
0
0

Tabla de Xw y 1/(Y-X) para 2 etapas, Yd=0.84, Rcte

refujo 2 et yd xw 1/y-x Aparcial
2.25 0.2584615 0.84 0.8131 37.238547 0.54630
2.25 0.2553846 0.83 0.7970 30.267117 3.33403
2.25 0.2307692 0.75 0.6218 7.8000035 2.12052
2.25 0.2215385 0.72 0.54 5.5555556 1.72009
2.25 0.2092308 0.68 0.4 3.5714286 0.98687
2.25 0.2 0.65 0.1983 2.21372 0.24463
2.25 0.1846154 0.6 0.08 1.9230769 0.0696
2.25 0.1692308 0.55 0.0443 1.977457 0.0491
2.25 0.1384615 0.45 0.0215 2.3337223 0.0217
2.25 0.1076923 0.35 0.013311 2.9701012 0.0180
2.25 0.0769231 0.25 0.008259 4.1366513 0.0449
2.25 0.0307692 0.1 0.002 10.204082 0.0153
2.25 0.0153846 0.05 0.001 20.408163 #REF!
2.25 0 0 0 #DIV/0! #REF!
agua(2) @ 1.013 bar = 1 atm = 760 mm Hg

NOMENCLATURA DE COLOR

Celdas dato (llenar)

y Constantes de los componentes de la mz
y Titulos generales del proceso de cálculo
y Variables calculadas
Información obtenida por iteración usando el comando
Solver

Referencia
1.00
Diagrama T vs x-y (mz etanol-agua) @ 1 atm=1.01325 bar
102
0.99 100
0.95 98 l i qui do Vapor
0.9 96
94
Temperatura, T (°C)

0.8
92
0.7 90
0.6 88
0.5 86
84
0.4
82
0.3
80
0.2 78
0.15 76
0.1 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
Fracción molar x, y
0.08
0.06
0.04 Diagrama x vs y (mz etanol-agua) @ 1atm = 1.01325 bar
0.02 1.00

0.01 0.90
0.001 0.80
Fracción molar del vapor, y

0.000 0.70
0.60
0.50
0.40
0.30
0.20
0.10
0.00
00 05 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 00
0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1.
Fracción molar del líquido, x
RECTIFICACION POR LOTES .
Azeotropo PM
ro W %w 46.069 x 1.0000
0.798 95.6 18.015 0.894 0.894

R= 4.813 reflujo=D/(V-D)
dato dato dato dato destilado dato de ro
Dtot 1 465
min ro W t°C vol W masa xw de ro w et ro dato t D vol Di gr D gr T W g xD pesodi gr d et totf et-d et xw calc
sin re 1 450
No 0.946 30 28380 0.3259 9249 0 0 0 28380 9223 0.325
1 10 0.945 25 0.331 0 0.833 25 800 666.4 666.4 27714 0.8254 550 550 8673 0.3129
10 0.945 25 0.337 0 0.812 25 800 649.6 1316 27064 0.906 589 1139 8084.42 0.2987
10 0.948 22 0.33 0 0.807 25 800 645.6 1962 26418 0.924 597 1735 7487.88 0.2834
29.63 0.812 25 2370 1924 3886 24494 0.906 1744 3479 5744.34 0.235
obs sin sec menor a w
W gmol xWmol Fet gmol xd mol
1045 0.19212 200.765
0.649
0.7903
0.8262
0.7903
x ro W %w 46.069
az 0.894 0.798 95.6 18.015
R= 2.25 4.641
dato dato dato dato destilado dato de ro
refl1 465 W xW
min ro W t vol W masa xw de ro w et ro dato t D vol Di gr D gr T W g xD pesodi gr d et totf et-d et xw calc con xW con 30 lt
1 30000 0.833 450 375 0.825 309 309.3
No F 0.946 38000 35948 0.3259 11715 0 0 0 35948 11715 0.3259 0.326
1 10 0.945 25 0.331 0 0.833 25 800 666.4 666.4 35282 0.8254 550 550 11165 0.3165 x 0.314
10 0.944 25 0.337 0 0.812 25 800 649.6 1316 34632 0.906 589 1139 10577 0.3054 x 0.3
10 0.948 22 0.3296 0 0.807 25 800 645.6 1962 33986 0.924 597 1735 9980.33 0.2937 x 0.284
0 32711 0
obs xd mol
W gmol xWmol Fet gmol 6.7128
1323.7 0.19212 254.302 0.649 11.94 242.363 0.1533
0.7903 24.715 229.588 0.1467
0.8262 37.663 216.639 0.1398
| 3mzo14

ro F t vol F masa xw de ro F et ro dato t D vol Di gr D gr T W g xD pesodi gr d et totf et-d et xw calc

Pvapor = 1.1
0.975 35 30000 29250 0.1376 4024.8 0.811 22 3450 2798 26452 0.9500 2658 2658 1366.75 0.0517
kg/cm2 gasto
0.985
1337.1 87.3646 155 592.21 0.8814 57.7 57.7 29.6674 0.0209 G :=
n
kmol /h
0.96 30000 28800 0.28 8064 0.819 25 3500 2867 25934 0.92 2637 2637 5426.82 0.2093 agua

1113.3 175.042 69.9 1043 0.8181 57.24 57.2 117.798 0.0938

18 de dic 2014
x ro W %w 46.069
az 0.894 0.798 95.6 18.015
R= 2.25 R= 2.009
dato dato dato dato destilado dato de ro
refl 1 W 465 W xW
min ro W t vol W masa xw de ro w et ro dato t D vol Di gr D gr T W g xD pesodi gr d et totf et-d et xw calc con xW con 30 lt
Rt 1 0.967 25 44000 360 0.8265 24 400 330.6 0.825 273 272.7
No F 0.96 25 44000 42240 0.3259 13766 0 0 0 42240 13766 0.3259 0.326
1 10 0.973 20 630 0.331 208.53 0.818 20 1660 1358 1358 34590 0.8254 1121 1121 10595 0.3063 x 0.314
2 10 0.976 20 300 0.337 101.1 0.816 20 1100 897.6 2255 33693 0.906 813 1934 9781.43 0.2903 x 0.3
10 0 0 2255 33693 0 1934 9781.43 0.2903 x 0.284
0 32711 0
obs xd mol
W gmol xWmol Fet gmol 5.9204
1555.4 0.19212 298.813 0.649 24.329 229.974 0.1472
0.7903 41.981 212.321 0.1379
0 41.981 212.321 0.1379

ADRIAN
x ro W %w 46.069
az 0.894 0.798 95.6 18.015
R= 1.7 R= 0
dato dato dato dato destilado dato de ro
refl 1 W 465 F-D W xW
min ro t vol masa x con ro w et ro dato t D vol D gr D gr T W g xD pesodi gr d et totf et-d et xw calc con xW con 30 lt
F 0.941 25 37000 34817 0.352 12256 25 0 34817 0.7 0 0 0
Rt 1 0.9517 25 0.292 0 0 0 0 0 0 0.326
D1 10 0.8292 20 2150 1782.8 0.675 1203.38 0.8292 20 2150 1783 1783 33034 0.675 1203 1203 10512 0.3182 x 0.314
0 0 0 0 1783 33034 0 1203 10512 0.3182 x 0.3
W 0.96 32000 30720 0.24 7372.8 0 1783 33034 0 1203 10512 0.3182 x 0.284
0 0
obs calculo de w y xw de oper xd mol
W gmol xWmol Wet gmol 0
1241.3 0.12893 160.038 0.4482 26.121 228.181 0.1543
0 26.121 228.181 0.1543
0 26.121 228.181 0.1543
tabla de peso en el hervidor a diferentes %w y densidades según vol 0 Hervidor carga de 20 a 35 litros
46.069 18.015 V 4000 con x%w de 5 a 30 corresponde;
vol tot> peso de 20 a 34 kg
20000 25000 30000 35000 20 25 30 35 peso alcohol de 0.99 a 9.41 kg etanol
%W x ro peso total en el hervidor peso alcohol Z V Kg et xD sup R
0 0.000 0.9971 19942 24927 29912.4 34897.8 0 0 0 0 0.85
5 0.020 0.9882 19763 24704 29645.1 34586 988 1235 1482 1729 5 20 988.2 1162.55
10 0.042 0.9804 19609 24511 29412.9 34315 1961 2451 2941 3432 10 20 1961 1
15 0.065 0.9733 19467 24334 29200.2 34066.9 2920 3650 4380 5110
20 0.089 0.9664 19328 24160 28991.7 33824 3866 4832 5798 6765 20 25 4832 2
25 0.115 0.9590 19179 23974 28768.5 33563 4795 5993 7192 8391
30 0.144 0.9507 19013 23767 28520.1 33273 5704 7130 8556 9982 30 35 9982 3
35 0.174 0.9415 18829 23537 28243.8 32951.1 6590 8238 9885 11533
1000 2000 D lt/10 min
20 25 35 20 25 30 Recup 20 25 30
10 1.96 2.45 3431.51 10 1.764 2.205 3088 0.9 544 681 953
20 3.87 4.83 6764.73 20 1.935 2.415 3382 0.5 597 745 1044
30 5.7 7.13 9982 30 2.28 2.852 3993 0.4 704 880 1232
 W xW ro 25
dar calc calc
0.28 0.9541
30000 0.284
32000 0.287 28 0.9541
34000 0.29
36000 0.292 0.952
38000 0.294

= 1.1
gasto volumetrico 100%
8.02 - ρ
n
G := Ga 
n n 7.02  ρ
n
kmol /h etanol y
agua

vol nivel
W xW ro 25
dar calc calc
0.28 0.9541
30000 0.284
32000 0.287
34000 0.29
36000 0.292 0.952
38000 0.294

W xW ro 25
dar calc calc
0.28 0.9541
30000 0.284
32000 0.287
34000 0.29
36000 0.292 0.952
38000 0.294
 3.-84 DENSITIES OF AQUEOUS ORGANIC SOLUTIONS
(g/mol) (cal/g) (cal/mol) (cal/g)
Compuesto PM Cp Az
etanol (1) 46.069 0.582 26.8122 0.894
agua (2) 18.015 0.999 17.9970 0.956

Table 3-112. Ethyl Alcohol -(1)-water (2) 1atm 25°C

%w frac mol v %w 20° . 25C. 30° . 35°C. 40°C. PM V %vol delta xw ro
0 0 1.00293 0 0.99823 0.99708 0.99568 0.99406 0.99225 18.015 18.06776 0
1 0.39344 1.00482 1 0.99636 0.9952 0.99379 0.99217 0.99034 18.1254 18.2128 1.2677
2 0.79173 1.00668 2 0.99453 0.99336 0.99194 0.99031 0.98846 18.2371 18.35902 2.5307
3 1.19496 1.0085 3 0.99275 0.99157 0.99014 0.98849 0.98663 18.3502 18.50624 3.7891
4 1.60323 1.01026 4 0.99103 0.98984 0.98839 0.98672 0.98485 18.4648 18.6543 5.0434
5 2.01662 1.01197 5 0.98938 0.98817 0.9867 0.98501 0.98311 18.5807 18.80318 6.2936
6 2.43524 1.01362 6 0.9878 0.98656 0.98507 0.98335 0.98142 18.6982 18.95291 7.54
7 2.85919 1.01523 7 0.98627 0.985 0.98347 0.98172 0.97975 18.8171 19.10367 8.7828
8 3.28856 1.01682 8 0.98478 0.98346 0.98189 0.98009 0.97808 18.9376 19.25607 10.022
9 3.72346 1.0184 9 0.98331 0.98193 0.98031 0.97846 0.97641 19.0596 19.41032 11.257
10 4.16401 1.01996 10 0.98187 0.98043 0.97875 0.97685 0.97475 19.1832 19.56608 12.489
11 4.6103 1.02148 11 0.98047 0.97897 0.97723 0.97527 0.97312 19.3084 19.72315 13.717
12 5.06246 1.02299 12 0.9791 0.97753 0.97573 0.97371 0.9715 19.4352 19.88197 14.942 -2.7569 13.76 0.97500
13 5.52061 1.02447 13 0.97775 0.97611 0.97424 0.97216 0.96989 19.5638 20.04257 16.164 -0.7254 12.73 0.97650
14 5.98485 1.02594 14 0.97643 0.97472 0.97278 0.97063 0.96829 19.694 20.20476 17.382 -0.0791 13.08 0.97600
15 6.45531 1.02739 15 0.97514 0.97334 0.97133 0.96911 0.9667 19.826 20.36901 18.597 0.225004 6.230 0.97400
16 6.93212 1.02882 16 0.97387 0.97199 0.9699 0.9676 0.96512 19.9597 20.53492 19.81 0.356725 6.575 0.97300
17 7.41541 1.03027 17 0.97259 0.97062 0.96844 0.96607 0.96352 20.0953 20.70359 21.018 0.486816 6.929 0.97200
18 7.90531 1.03175 18 0.97129 0.96923 0.96697 0.96452 0.96189 20.2328 20.87508 22.223 0.623829 7.281 0.97100
19 8.40195 1.03325 19 0.96997 0.96782 0.96547 0.96294 0.96023 20.3721 21.04946 23.423 0.767865 7.634 0.97000
20 8.90549 1.03478 20 0.96864 0.96639 0.96395 0.96134 0.95856 20.5133 21.22678 24.62 0.214794 8.691 0.96700
21 9.41605 1.03634 21 0.96729 0.96493 0.96242 0.95973 0.95687 20.6566 21.40733 25.811 0.024479 9.392 0.96500
22 9.9338 1.0379 22 0.96592 0.96348 0.96087 0.95809 0.95516 20.8018 21.59031 27 0.185674 9.748 0.96400
23 10.4589 1.03951 23 0.96453 0.96199 0.95929 0.95643 0.95343 20.9491 21.77687 28.184 0.003524 10.455 0.96200
24 10.9914 1.04115 24 0.96312 0.96048 0.95769 0.95476 0.95168 21.0985 21.96666 29.363 0.191447 10.800 0.96102
25 11.5317 1.04281 25 0.96168 0.95895 0.95607 0.95306 0.94991 21.2501 22.15975 30.537 0.017654 11.514 0.95900 -0.431
26 12.0797 1.04452 26 0.9602 0.95738 0.95442 0.95133 0.9481 21.4038 22.35668 31.707 0.216422 11.863 0.95800
27 12.6357 1.04629 27 0.95867 0.95576 0.95272 0.94955 0.94625 21.5598 22.55778 32.871 0.082374 12.553 0.95600
28 13.1999 1.04811 28 0.9571 0.9541 0.95098 0.94774 0.94438 21.7181 22.76292 34.029 0.749916 12.450 0.95631
29 13.7724 1.04997 29 0.95548 0.95241 0.94922 0.9459 0.94248 21.8787 22.97196 35.182 -0.11451 13.887 0.95207
30 14.3535 1.05189 30 0.95382 0.95067 0.94741 0.94403 0.94055 22.0417 23.18547 36.329 0.544331 13.809 0.95230
31 14.9433 1.05385 31 0.95212 0.9489 0.94557 0.94214 0.9386 22.2072 23.40309 37.47 0.366535 14.577 0.95000
32 15.542 1.05587 32 0.95038 0.94709 0.9437 0.94021 0.93662 22.3752 23.62516 38.605 0.301009 15.241 0.94800
33 16.1498 1.05792 33 0.9486 0.94525 0.9418 0.93825 0.93461 22.5457 23.85155 39.734 0.247759 15.902 0.94600 0.348
34 16.767 1.06003 34 0.94679 0.94337 0.93986 0.93626 0.93257 22.7188 24.08262 40.856 0.206818 16.560 0.94400 -0.331
35 17.3937 1.06218 35 0.94494 0.94146 0.9379 0.93425 0.93051 22.8946 24.31823 41.973 0.833445 16.560 0.94400 -0.427
36 18.0302 1.06437 36 0.94306 0.93952 0.93591 0.93221 0.92843 23.0732 24.5585 43.083 1.469857 16.560 0.94400 1.564
37 18.6768 1.0666 37 0.94114 0.93756 0.93391 0.93016 0.92634 23.2546 24.80329 44.187 0.474985 18.202 0.93900 2.531
38 19.3335 1.06888 38 0.93919 0.93556 0.93186 0.92808 0.92422 23.4388 25.05325 45.285 2.771492 16.562 0.94400 3.492
39 20.0007 1.0712 39 0.9372 0.93353 0.92979 0.92597 0.92208 23.626 25.30825 46.376 0.154484 19.846 0.93400 4.422
40 20.6787 1.07356 40 0.93518 0.93148 0.9277 0.92385 .91992.23.8162 25.56814 47.46 4.140668 16.538 0.94400 5.356
41 21.3677 1.07596 41 0.93314 0.9294 0.92558 0.9217 0.91774 24.0095 25.83333 48.538 0 21.368 0.92940 6.304
42 22.068 1.07841 42 0.93107 0.92729 0.92344 0.91952 0.91554 24.206 26.10397 49.609 5.545698 16.522 0.94400 7.213
43 22.7798 1.08089 43 0.92897 0.92516 0.92128 0.91733 0.91332 24.4056 26.37992 50.674 6.296087 16.484 0.94400 8.110
44 23.5035 1.08341 44 0.92685 0.92301 0.9191 0.91513 0.91108 24.6087 26.66132 51.732 0.123465 23.380 0.92338 9.033
45 24.2393 1.08595 45 0.92472 0.92085 0.91692 0.91291 0.90884 24.8151 26.94802 52.784 0.391746 23.848 0.92200 -2.216
46 24.9875 1.08861 46 0.92257 0.9186 25.025 27.24254 53.825 1.130689 23.857 0.92200 -1.195
0.91472 0.91069 0.9066
47 25.7485 1.09112 47 0.92041 0.91649 0.9125 0.90845 0.90434 25.2385 27.53821 54.868 1.987301 23.761 0.92200 -0.190
48 26.5226 1.09374 48 0.91823 0.91429 0.91028 0.90621 0.90207 25.4557 27.842 55.901 2.712917 23.810 0.92200 0.812
49 27.3102 1.0964 49 0.91604 0.91208 0.90805 0.90396 0.89979 25.6766 28.1517 56.928 3.535073 23.775 0.92200 1.808
50 28.1115 1.09908 50 0.91384 0.90985 0.9058 0.91168 0.8975 25.9014 28.46778 57.948 0.053902 28.058 0.91000 2.800
51 28.927 1.10181 51 0.9116 0.9076 0.90353 0.8994 0.89519 26.1302 28.79043 58.961 5.219188 23.708 0.92200 3.750
52 29.7571 1.10456 52 0.90936 0.90534 0.90125 0.8971 0.89288 26.363 29.1195 59.967 6.118736 23.638 0.92200 4.750
53 30.602 1.10733 53 0.90711 0.90307 0.89896 0.89479 0.89056 26.6001 29.45518 60.967 2.579545 28.022 0.91000 5.729
54 31.4623 1.11014 54 0.90485 0.90079 0.89667 0.89248 0.88823 26.8414 29.79767 61.96 8.00298 23.459 0.92200 6.704
55 32.3384 1.11297 55 0.90258 0.8985 0.89437 0.89016 0.88589 27.0872 30.14714 62.947 8.989993 23.348 0.92200 7.674
56 33.2306 1.11581 56 0.90031 0.89621 0.89206 0.88784 0.88356 27.3375 30.50347 63.929 -0.47144 33.702 0.89500 8.674
57 34.1395 1.11867 57 0.89803 0.89392 0.88975 0.88552 0.88122 27.5925 30.86685 64.904 0.428642 33.711 0.89500 9.636
58 35.0655 1.12155 58 0.89574 0.89162 0.88744 0.88319 0.87888 27.8523 31.23783 65.873 1.36081 33.705 0.89500 10.594
59 36.0091 1.12447 59 0.89344 0.88931 0.88512 0.88085 0.87653 28.117 31.61663 66.835 2.32427 33.685 0.89500 11.548
60 36.9708 1.12741 60 0.89113 0.88699 0.88278 0.87851 0.87417 28.3868 32.0035 67.79 3.32037 33.650 0.89500 12.498
61 37.9511 1.13063 61 0.88882 0.88446 0.88044 0.87615 0.8718 28.6618 32.406 68.723 4.084104 33.867 0.89500 -3.818
62 38.9506 1.13336 62 0.8865 0.88233 0.87809 0.87379 0.86943 28.9422 32.80203 69.682 5.945512 33.005 0.89500 -2.802
63 39.9699 1.13639 63 0.88417 0.87998 0.87574 0.87142 0.86705 29.2282 33.21457 70.617 6.514667 33.455 0.89500 -1.790
64 41.0095 1.13943 64 0.88183 0.87763 0.87337 0.86905 0.86466 29.5198 33.63583 71.547 1.933239 39.076 0.88200 -0.782
65 42.0701 1.1425 65 0.87948 0.87527 0.871 0.86667 0.86227 29.8173 34.06646 72.469 3.024424 39.046 0.88200 0.221
66 43.1523 1.14559 66 0.87713 0.87291 0.86863 0.86429 0.85987 30.1209 34.50635 73.386 4.168178 38.984 0.88200 1.221
67 44.2567 1.14871 67 0.87477 0.87054 0.86625 0.8619 0.85747 30.4308 34.9562 74.295 5.340411 38.916 0.88200 2.216
68 45.3841 1.15185 68 0.87241 0.86817 0.86387 0.8595 0.85407 30.7471 35.41593 75.199 6.578809 38.805 0.88200 3.216
69 46.5352 1.15501 69 0.87004 0.86579 0.86148 0.8571 0.85266 31.07 35.88627 76.095 7.839843 38.695 0.88200 4.203
70 47.7107 1.15821 70 0.86766 0.8634 0.85908 0.85047 0.85025 31.3997 36.36756 76.985 0.295106 47.416 0.86400 5.185
71 48.9114 1.16144 71 0.86527 0.861 0.85667 0.85228 0.84783 31.7366 36.86016 77.868 10.50634 38.405 0.88200 6.163
72 50.1382 1.1647 72 0.86287 0.85859 0.85426 0.84986 0.8454 32.0808 37.36447 78.744 11.91643 38.222 0.88200 7.138
73 51.3918 1.16798 73 0.86047 0.85618 0.85184 0.84743 0.84297 32.4325 37.88042 79.613 13.43138 37.960 0.88200 8.137
74 52.6733 1.17129 74 0.85806 0.85376 0.84941 0.845 0.84053 32.792 38.40887 80.476 14.95387 37.719 0.88200 9.104
75 53.9835 1.17462 75 0.85564 0.85134 0.84698 0.84257 0.83809 33.1595 38.9498 81.332 16.59928 37.384 0.88200 -0.264
 76 55.3233 1.17798 76 0.85322 0.84891 0.84455 0.84013 0.83564 33.5354 39.50408 82.181 -2.15595 57.479 0.84500 0.736
77 56.694 1.18138 77 0.85079 0.84647 0.84211 0.83768 0.83319 33.9199 40.07221 83.023 19.95818 36.736 0.88200 1.733
78 58.0964 1.18479 78 0.84835 0.84403 0.83966 0.83523 0.83074 34.3134 40.65419 83.859 0.557515 57.539 0.84500 2.725
79 59.5317 1.18824 79 0.8459 0.84158 0.8372 0.83277 0.82827 34.716 41.25101 84.688 0.831902 58.700 0.84300 3.714
80 61.0011 1.19174 80 0.84344 0.83911 0.83473 0.83029 0.82578 35.1283 41.8637 85.508 25.51541 35.486 0.88200 4.699
81 62.5058 1.19526 81 0.84096 0.83664 0.83224 0.8278 0.82329 35.5504 42.49186 86.322 8.13893 54.367 0.85000 5.661
82 64.0472 1.19883 82 0.83848 0.83415 0.82974 0.8253 0.82079 35.9828 43.13708 87.127 0.526157 63.521 0.83500 6.661
83 65.6265 1.20244 83 0.83599 0.83164 0.82724 0.82279 0.81828 36.4258 43.80002 87.925 0.85571 64.771 0.83300 7.635
84 67.2451 1.20608 84 0.83348 0.82913 0.82473 0.82027 0.81576 36.8799 44.48029 88.715 2.49571 64.749 0.83300 8.574
85 68.9047 1.20977 85 0.83095 0.8266 0.82220.81774 0.81322 37.3455 45.17967 89.498 4.198026 64.707 0.83300 -1.561
86 70.6066 1.21352 86 0.8284 0.82405 0.81965 0.81519 0.81067 37.823 45.89889 90.271 5.97357 64.633 0.83300 10.431
87 72.3527 1.21732 87 0.82583 0.82148 0.81708 0.81262 0.80811 38.3128 46.63877 91.036 3.410573 68.942 0.82650 -1.101
88 74.1445 1.22118 88 0.82323 0.81888 0.81448 0.81003 0.80552 38.8155 47.40073 91.791 5.251555 68.893 0.82650 12.219
89 75.9841 1.2251 89 0.82062 0.81626 0.81186 0.80742 0.80291 39.3316 48.1851 92.537 3.327979 72.656 0.82100 0.337
90 77.8731 1.22907 90 0.81797 0.81362 0.80922 0.80478 0.80028 39.8615 48.99281 93.274 0.987478 76.886 0.81500 1.332
91 79.8138 1.23314 91 0.81529 0.81094 0.80655 0.80211 0.79761 40.406 49.82609 94 0.767587 79.046 0.81200 2.317
92 81.8083 1.23727 92 0.81257 0.80823 0.80384 0.79941 0.79491 40.9655 50.68544 94.715 2.774551 79.034 0.81200 3.283
93 83.8587 1.24148 93 0.80983 0.80549 0.80111 0.79669 0.7922 41.5407 51.572 95.42 1.129993 82.729 0.80700 4.259
94 85.9676 1.24576 94 0.80705 0.80272 0.79835 0.79393 0.78947 42.1323 52.48697 96.115 3.258447 82.709 0.80700 5.198
95 88.1374 1.25014 95 0.80424 0.79991 0.79555 0.79114 0.786742.7411 53.43233 96.797 5.474668 82.663 0.80700 -2.221
96 90.3708 1.25461 96 0.80138 0.79706 0.79271 0.78831 0.78388 43.3676 54.40948 97.467 0.893363 89.477 0.79820 -1.182
97 92.6706 1.25921 97 0.79846 0.79415 0.78981 0.78542 0.781 44.0128 55.42129 98.123 3.200838 89.470 0.79820 -0.158
98 95.04 1.26395 98 0.79547 0.79117 0.78684 0.78247 0.77806 44.6775 56.47018 98.763 5.589387 89.451 0.79820 0.846
99 97.482 1.26881 99 0.79243 0.78814 0.78382 0.77946 0.77507 45.3626 57.55651 99.388 8.107727 89.374 0.79820 9.563
100 100 1.27379 100 0.78934 0.78506 0.78075 0.77641 0.77205 46.069 58.68214 100 10.74257 89.257 0.79820 10.408
20°C 30°C
nivel vol
0 0 0
4.5 2 2.0185
6 4 4.037
7.5 6 6.0555
9 8 8.074 44
0.967 25 10.5 10 10.092 42
0.960 25 11.5 12 12.111 40
0.973 20 12.5 14 14.129
38
0.976 20 13.8 16 16.148
36
15 18 18.166
16 20 20.185 34

17 22 22.203 32
18 24 24.222 30
19.5 26 26.24 28
20.5 28 28.259
26
21.5 30 30.277
24
23 32 32.296
24.5 34 34.314 22
25.8 36 36.333 20
27 38 38.351 18
28.3 40 40.37
16
29.5 42 42.388
14
31.1 44 44.407
12
10
24.431 0.9625 8
6
4
2

-0.326 29.67 0.948 %w para la densidad 0

0 1 2 3 4 5 6 7 8 9 10 11
de 0.948g/cm3, a T=
25.0 20, 22 y 25°C
31.652 0.951 22.0 29.71 20°C 25°C 30°C
33.33 0.948 20.0 33.3 31.50 29.67
34.427 0.946
35.054 0.946
36.054 0.946
37.054 0.946
38.054 0.946
39.054 0.946
40.054 0.946
41.054 0.946
42.054 0.946
22.557 0.946
44.080 0.920
45.080 0.920
46.080 0.920
47.080 0.920
48.080 0.920 0.8 24 400
49.080 0.920 0
50.080 0.920 0.8 20 1660
51.080 0.920 0.8 20 1100
52.080 0.920
53.080 0.920
54.080 0.920
55.080 0.920
56.080 0.920
57.080 0.920
58.080 0.920
59.080 0.920
60.120 0.880
61.120 0.880
62.120 0.880
63.120 0.880
64.120 0.880
65.120 0.880
66.120 0.880
67.120 0.880
68.120 0.880
69.120 0.880
70.120 0.880
71.120 0.880
72.120 0.880
73.120 0.880
74.145 0.855
75.145 0.855
76.145 0.855
77.145 0.855
78.145 0.855
79.145 0.855
80.145 0.855
81.145 0.855
82.145 0.855 ro dato t D vol
83.145 0.855 0.8265 24.0 400
84.173 0.827 0
85.145 0.855 0.8180 20 1660
86.177 0.823 0.8160 20 1100
87.145 0.855
88.179 0.822
89.179 0.822
90.179 0.822
91.179 0.822
92.179 0.822
93.179 0.822
94.202 0.798
95.202 0.798
96.202 0.798
97.202 0.798
98.179 0.822
99.179 0.822
 vol

4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33
 3/18/2016 Hernandez Gaspar Emanuel e E Ramirez Orozco Agustin E 1 1 II
Gpo 3IM72 Jimenez Sanchez Israel 1 1 E Reyes Lopez Jorge Daniel E 1 1
Eq 3 y 4 Perez Monroy Yael 1 1 E Rosette Mendoza Jose Antonio E 1 1
MATUT 1a Portillo Olivera Silvestre Axe 1 1 E Santos Fernandez Floriana E 1 1
1 2 3 4 5 6 7 8.0 9 10 11 12 13 14 15 16 17 18
F Rt l/mD1 t°C D2 t°C D t°C D purgW purgWdato Wcalc W-purgas F calcul RELACION DE REFLUJO
ro 0.948 0.814 0 0.814 0.961 0.939 0.961 0.9563 0.9234 Rot en l/m R TOTAL DESTILADO REFLUJO
%w 0.303858 0.89857 0 0.899 0.3039 0.38775 0.2364 0.2667 0.43831 Rot agua 0.15
x 0.1458 0.776 0 0.776 0.1458 0.1985 0.108 0.1245 0.2338 Rot et-agua
nivel 23 ó volumen 1.83
% r ó vol/t } tempo 27
volumen 32000 3800 800 800 27400 vol/tempo 0.067778
hora-total
masa 30336 3093.2 0 3744.4 651.2 768.8 25728.6 26592 25823 29473.0 ro 0.814 0.814 29473
masa et 9217.831 2779.46 0 2779.5 585 233.61 9976.38 6438 5620 12755.8 %w 0.8985706 0.89857
masa w 21118.17 313.742 0 313.7 66.05 535.19 15752 20804 20203 16066.0 fraccion mol 0.776 0.776
mole et 200.0875 60.3 0.0 60.3 12.7 5.1 216.6 139.8 122 276.9 mol/min
moles w 1172.255 17.4 0.0 17.4 3.7 29.7 874.4 1155 1121 891.8
moles 1372.342 77.7 0.0 77.7 16.4 34.8 1090.9 1294.6 1243 1168.7 Rel. de R= 2.21311
frac mol 0.1458 0.776 0.8 0.776 0.1458 0.1985 0.1080 0.0981 0.2369
vol seg l/m
vol 1000 28 2143 W/F D/F
ro purga 310 300 62 D,z, xd,xb. Ajus F o W (12/2) x x
%mol 320 300 64 D xd,F,z. Calc W,xw. (13/2) 0.9433 0.0567
moles purga 350 300 70 D,xd,W,xw. Calc F,z. (12/14) 0.9335 0.0665
etanol purga 850 720 70.8
holdup 1.6 1830 1620 67.8
T hervidor t1 77
T2 73
T3 72
T4 71
T5 22
T6 27
T7 69
T8 44
T9 62
T10 28
T11 23