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SAFETY DATA SHEET according to Regulation (EC) No.

1907/2006

RESIN SP 1045 H / BAG 25 KG


Version 5.2 Print Date 19.01.2018

Revision date / valid from 18.01.2018

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product identifier

Trade name : RESIN SP 1045 H / BAG 25 KG

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the : Chemical intermediate


Substance/Mixture

Uses advised against : At this moment we have not identified any uses advised
against

1.3. Details of the supplier of the safety data sheet

Company : Brenntag Nordic AB


Koksgatan 18
SE 20211 Malmoe
Telephone : +46 (0)40-28 73 00
Telefax : +46 (0)40-93 7015
E-mail address : SDS.SE@brenntag-nordic.com
Responsible/issuing : Environment & Quality
person

1.4. Emergency telephone number

Emergency telephone : In case of personal injury call:


number Denmark: 82 12 12 12 Giftlinien, Bispebjerg Hospital
Finland: Poison Information Centre: (09) 471 977 (direct) or
(09) 47 11 (exchange), open 24h/day
Norway: 22 59 13 00 Giftinformasjonen (døgnåpent)
Sweden: +46-8-331231 Giftinformationscentralen (24 hour
service)
Outside these countries: Please call your local
emergency services

SECTION 2: Hazards identification


2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008

REGULATION (EC) No 1272/2008

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RESIN SP 1045 H / BAG 25 KG

Hazard
Hazard class Hazard category Target Organs
statements
Skin sensitisation Category 1 --- H317

For the full text of the H-Statements mentioned in this Section, see Section 16.

Most important adverse effects

Human Health : May cause an allergic skin reaction.


Mechanical irritation of the eyes is possible.
Ingestion may cause gastrointestinal irritation, nausea,
vomiting and diarrhoea.

Physical and chemical : Risk of dust explosion., In case of fire hazardous


hazards decomposition products may be produced such as:,
Formaldehyde, Carbon oxides

Potential environmental : According to available data, this product is not harmful to the
effects environment.

2.2. Label elements

Labelling according to Regulation (EC) No 1272/2008

Hazard symbols :

Signal word : Warning

Hazard statements : H317 May cause an allergic skin reaction.

Precautionary
statements

Prevention : P261 Avoid breathing dust/ fume/ gas/ mist/


vapours/ spray.
P280 Wear protective gloves/ protective clothing/
eye protection/ face protection.

Response : P302 + P352 IF ON SKIN: Wash with plenty of water.


P305 + P351 + P338 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact
lenses, if present and easy to do. Continue
rinsing.
P308 + P313 IF exposed or concerned: Get medical
advice/ attention.

Disposal : P501 Dispose of contents/ container to an


approved waste disposal plant.

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RESIN SP 1045 H / BAG 25 KG

Hazardous components which must be listed on the label:

• Methylols

2.3. Other hazards

For Results of PBT and vPvB assessment see section 12.5.

SECTION 3: Composition/information on ingredients


3.2. Mixtures

Classification
(REGULATION (EC) No 1272/2008)

Hazard class / Hazard


Hazardous components Amount [%] Hazard statements
category
Methylols
>= 1 Skin Sens.1 H317

4-(1,1,3,3-tetramethylbutyl)phenol
Index-No. : 604-075-00-6 <4 Skin Irrit.2 H315
CAS-No. : 140-66-9 Eye Dam.1 H318
EC-No. : 205-426-2 Aquatic Acute1 H400
Aquatic Chronic1 H410

xylene
Index-No. : 601-022-00-9 <3 Flam. Liq.3 H226
CAS-No. : 1330-20-7 Acute Tox.4 H332
EC-No. : 215-535-7 Acute Tox.4 H312
Skin Irrit.2 H315

ethylbenzene
Index-No. : 601-023-00-4 < 0,5 Flam. Liq.2 H225
CAS-No. : 100-41-4 Acute Tox.4 H332
EC-No. : 202-849-4 STOT RE2 H373
Asp. Tox.1 H304

formaldehyde
Index-No. : 605-001-00-5 < 0,01 Acute Tox.3 H301
CAS-No. : 50-00-0 Acute Tox.3 H331
EC-No. : 200-001-8 Acute Tox.3 H311
Skin Sens.1 H317
Muta.2 H341
Carc.1B H350
Skin Corr.1B H314

Remarks : This product contains a substance included in Annex XIV of Regulation


EC No. 1907/2006 ('REACH') in a concentration >= 0.1% w/w.

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RESIN SP 1045 H / BAG 25 KG

For the full text of the H-Statements mentioned in this Section, see Section 16.

Non-hazardous component

Chemical name Identification Number Amount [%]

Alkylphenol formaldehyd resin : >= 92

SECTION 4: First aid measures


4.1. Description of first aid measures

If inhaled : Move to fresh air. If symptoms persist, call a physician.

In case of skin contact : Take off contaminated clothing and shoes immediately. Wash
off with soap and water. If symptoms persist, call a physician.

In case of eye contact : Rinse thoroughly with plenty of water, also under the eyelids. If
symptoms persist, call a physician.

If swallowed : Clean mouth with water and drink afterwards plenty of water.
Never give anything by mouth to an unconscious person. Do
NOT induce vomiting. If symptoms persist, call a physician.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms : See Section 11 for more detailed information on health effects


and symptoms.

Effects : See Section 11 for more detailed information on health effects


and symptoms.

4.3. Indication of any immediate medical attention and special treatment needed

Treatment : Treat symptomatically.

SECTION 5: Firefighting measures


5.1. Extinguishing media

Suitable extinguishing : Water spray, foam, dry powder or CO2.


media
Unsuitable extinguishing : Water jet.
media

5.2. Special hazards arising from the substance or mixture

Specific hazards during : Risk of dust explosion.


firefighting
: In case of fire hazardous decomposition products may be
produced such as: Formaldehyde

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RESIN SP 1045 H / BAG 25 KG

5.3. Advice for firefighters

Special protective : Wear self-contained breathing apparatus and protective suit.


equipment for firefighters
Further advice : Cool closed containers exposed to fire with water spray.

SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions : For personal protection see section 8.

6.2. Environmental precautions

Environmental : The product should not be allowed to enter drains, water


precautions courses or the soil.
6.3. Methods and materials for containment and cleaning up

Methods and materials for : Do not allow to enter drainage system, surface or ground
containment and cleaning water. Scoop or vacuum into a receptable for disposal. Avoid
up dust.

6.4. Reference to other sections

See Section 1 for emergency contact information.


See Section 8 for information on personal protective equipment.
See Section 13 for waste treatment information.

SECTION 7: Handling and storage


7.1. Precautions for safe handling

Advice on safe handling : Handle in accordance with good industrial hygiene and safety
practice. Avoid contact with skin and eyes. Provide for good
ventilation. Avoid dusting. Use mechanical ventilation at
dusting. Do not smoke.

Hygiene measures : When using, do not eat, drink or smoke. Wash hands before
breaks and immediately after handling the product. Keep away
from food, drink and animal feedingstuffs.

7.2. Conditions for safe storage, including any incompatibilities

Requirements for storage : Keep containers tightly closed in a dry, cool and well-ventilated
areas and containers place. Keep away from sources of ignition - No smoking.

Advice on protection : Take precautionary measures against static discharges. Risk of


against fire and explosion dust explosion.

7.3. Specific end use(s)

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RESIN SP 1045 H / BAG 25 KG

Specific use(s) : No information available.

SECTION 8: Exposure controls/personal protection


8.1. Control parameters

Component: formaldehyde CAS-No. 50-00-0


Other Occupational Exposure Limit Values

Sweden. OEL
Medical control is required when handling the substance.

Sweden. OEL, Time Weighted Average (TWA):


0,3 ppm, 0,37 mg/m3

Sweden. OEL, Short Term Exposure Limit


0,6 ppm, 0,74 mg/m3

Sweden. OEL, Skin designation:


Can be absorbed through the skin.

Component: xylene CAS-No. 1330-20-7


Other Occupational Exposure Limit Values

EU. Indicative Exposure Limit Values in Directives 91/322/EEC, 2000/39/EC, 2006/15/EC,


2009/161/EU, 2017/164/EU, Short Term Exposure Limit (STEL):
100 ppm, 442 mg/m3
Indicative

EU. Indicative Exposure Limit Values in Directives 91/322/EEC, 2000/39/EC, 2006/15/EC,


2009/161/EU, 2017/164/EU, Time Weighted Average (TWA):
50 ppm, 221 mg/m3
Indicative

Sweden. OEL, Skin designation:


Can be absorbed through the skin.

Sweden. OEL, Time Weighted Average (TWA):


50 ppm, 221 mg/m3

Sweden. OEL, Short Term Exposure Limit


100 ppm, 442 mg/m3

8.2. Exposure controls

Appropriate engineering controls

Provide for good ventilation. Avoid dusting. Use mechanical ventilation at dusting.

Personal protective equipment

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RESIN SP 1045 H / BAG 25 KG

Respiratory protection

Advice : In case of insufficient ventilation, wear suitable respiratory


equipment.

Hand protection

Advice : Choose right chemical protection as:


Nitrile rubber
PVC

Eye protection

Advice : Safety glasses

Skin and body protection

Advice : Wear suitable protective clothing.

Environmental exposure controls

General advice : The product should not be allowed to enter drains, water courses
or the soil.

SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties

Form : solid

Colour : no data available

Odour : characteristic

Odour Threshold : no data available

pH : no data available

Melting point/range : 60 - 70 °C

Boiling point : no data available

Flash point : > 100 °C

Evaporation rate : no data available

Flammability (solid, gas) : no data available

Upper explosion limit : no data available

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RESIN SP 1045 H / BAG 25 KG

Lower explosion limit : no data available

Vapour pressure : no data available

Relative vapour density : no data available

Density : 0,95 - 1,05 g/cm3

Water solubility : insoluble

Partition coefficient: n-octanol/water : no data available

Auto-ignition temperature : no data available

Thermal decomposition : no data available

Viscosity, dynamic : no data available

Explosivity : no data available

Oxidizing properties : no data available

9.2. Other information

No further information available.

SECTION 10: Stability and reactivity


10.1. Reactivity

Advice : No information available.


10.2. Chemical stability

Advice : Stable under normal conditions.

10.3. Possibility of hazardous reactions

Hazardous reactions : Hazardous polymerisation does not occur.

10.4. Conditions to avoid

Conditions to avoid : Keep away from heat and sources of ignition.Avoid dust
formation.

10.5. Incompatible materials

Materials to avoid : Oxidizing agents, Strong acids and strong bases

10.6. Hazardous decomposition products

Hazardous decomposition : Hazardous decomposition products, Formaldehyde


products

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SECTION 11: Toxicological information


11.1. Information on toxicological effects

Data for the product


Acute toxicity
Oral

Acute toxicity : > 2000 mg/kg ) (Calculation method)


estimate
This material may be a slight health hazard if ingested in large
quantities.
Inhalation

Acute toxicity : > 5 mg/l (dust/mist) (Calculation method)


estimate
Inhalation of high concentration may cause mechanical
overstraining of mucous membranes.
Dermal

Acute toxicity : > 2000 mg/kg ) (Calculation method)


estimate
Irritation
Skin

Result : Prolonged skin contact may cause skin irritation.


Eyes

Result : Dust in the eyes may cause mechanical irritation.


Sensitisation

Result : May cause an allergic skin reaction.


CMR effects
CMR Properties

Carcinogenicity : no data available

Mutagenicity : no data available

Reproductive toxicity : no data available

Specific Target Organ Toxicity


Single exposure

no data available

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RESIN SP 1045 H / BAG 25 KG

Repeated exposure

no data available

Other toxic properties


Repeated dose toxicity

no data available

Aspiration hazard

no data available

SECTION 12: Ecological information


12.1. Toxicity

Data for the product


Acute toxicity
Fish

: This product is based on the reaction between formaldehyde and


para-tertiary-octylphenol [PTOP]. Although the chemical reactions
have been completed, some reaction residues remain in the
product's chemical structure and the product may contain up to the
amount PTOP shown in Section 3. In the EU PTOP is classified as
Category 1 for both acute and chronic hazard and has a required
concentration range used for product classification and labeling.
However, test is performed by the manufacturer according to the
test procedures referred in Appendix I, Regulation (EC) 1272/2008.
These tests on the product showed that there is no risk to the
aquatic environment. The product must not be considered to be
environmentally hazardous, and not classified or labeled.

12.2. Persistence and degradability

Data for the product


Persistence and degradability
Biodegradability

Result : Not inherently biodegradable.

12.3. Bioaccumulative potential

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RESIN SP 1045 H / BAG 25 KG

Data for the product


Bioaccumulation

Result : No information available.

12.4. Mobility in soil

Data for the product


Mobility

Result : The product is insoluble in water.

12.5. Results of PBT and vPvB assessment

Data for the product


Results of PBT and vPvB assessment

Result : This mixture contains no substance considered to be persistent,


bioaccumulating and toxic (PBT)., This mixture contains no
substance considered to be very persistent and very
bioaccumulating (vPvB).

12.6. Other adverse effects

Data for the product


Additional ecological information

Result : Do not flush into surface water or sanitary sewer system.

SECTION 13: Disposal considerations


13.1. Waste treatment methods

Product : Eliminate waste in conditions authorized by the regulations.


Store waste in containers provided for this purpose. Do not
dump in drains, water sheets or the ground.

Contaminated packaging : Dispose of contaminated packaging in the same way as the


product.

European Waste : No waste code according to the European Waste Catalogue


Catalogue Number can be assigned for this product, as the intended use dictates
the assignment. The waste code is established in consultation
with the regional waste disposer.

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SECTION 14: Transport information

Not dangerous goods for ADR, RID, IMDG and IATA.

14.1. UN number

Not applicable.

14.2. UN proper shipping name

Not applicable.

14.3. Transport hazard class(es)

Not applicable.

14.4. Packaging group

Not applicable.

14.5. Environmental hazards

Not applicable.

14.6. Special precautions for user

Not applicable.

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

IMDG : Not applicable.

SECTION 15: Regulatory information


15.1. Safety, health and environmental regulations/legislation specific for the substance or
mixture

Data for the product

Other regulations : Exposure limits in accordance to local regulations


See national regulation according to specific requirements for
allergenic products.

15.2. Chemical safety assessment

no data available

SECTION 16: Other information

Full text of H-Statements referred to under sections 2 and 3.

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RESIN SP 1045 H / BAG 25 KG

H225 Highly flammable liquid and vapour.


H226 Flammable liquid and vapour.
H301 Toxic if swallowed.
H304 May be fatal if swallowed and enters airways.
H311 Toxic in contact with skin.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H331 Toxic if inhaled.
H332 Harmful if inhaled.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
May cause damage to organs through prolonged or repeated
H373
exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

Abbreviations and Acronyms

BCF bioconcentration factor


BOD biochemical oxygen demand
CAS Chemical Abstracts Service
CLP Classification, Labelling and Packaging
CMR carcinogenic, mutagenic or toxic to reproduction
COD chemical oxygen demand
DNEL derived no-effect level
EINECS European Inventory of Existing Commercial Chemical Substances
ELINCS European List of Notified Chemical Substances
GHS Globally Harmonized System of Classification and Labelling of
Chemicals
LC50 median lethal concentration
LOAEC lowest observed adverse effect concentration
LOAEL lowest observed adverse effect level
LOEL lowest observed effect level
NLP no-longer polymer
NOAEC no observed adverse effect concentration
NOAEL no observed adverse effect level
NOEC no observed effect concentration
NOEL no observed effect level
OECD Organisation for Economic Cooperation and Development
OEL occupational exposure limit
PBT persistent, bioaccumulative and toxic
PNEC predicted no-effect concentration
STOT specific target organ toxicity
SVHC substance of very high concern
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UVCB substance of unknown or variable composition, complex reaction


products or biological materials
vPvB very persistent and very bioaccumulative

Key literature references : Supplier information and data from the "Database of registered
and sources for data substances" of the European Chemicals Agency (ECHA) were
used to create this safety data sheet.
Methods used for : The classification for human health, physical and chemical
product classification hazards and environmental hazards were derived from a
combination of calculation methods and if available test data.
Hints for trainings : The workers have to be trained regularly on the safe handling
of the products based on the information provided in the Safety
Data Sheet and the local conditions of the workplace. National
regulations for the training of workers in the handling of
hazardous materials must be adhered to.

|| Indicates updated section.

The information provided in this Safety Data Sheet is correct to our knowledge at the date of its
revision. The information given only describes the products with regard to safety arrangements
and is not to be considered as a warranty or quality specification and does not constitute a legal
relationship.
The information contained in this Safety Data Sheet relates only to the specific material designated and
may not be valid for such material used in combination with any other material or in any process, unless
specified in the text.

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