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Journal ofFood Protection, Vol. 43, No. 8, Pa~es 618-624 (Au~ust, 1980)
Copyright© 1980, International Association of Milk, Food, and Environmental Sanitarians
ABSTRACT
changing electric field generating a magnetic field, the
Microwaves, such as those used in cooking and processing food, are change of which gives rise in turn to an electric field,
part of the broad spectrum of electromagnetic radiation which includes
allows the propagation of an electromagnetic field in free
radio waves. microwaves. infrared radiation, visible light. ultra-violet
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radiation. x-rays and Gamma rays. Electromagnetic radiation has a space. In 1864, James Clerk Maxwell set down the
dual nature, it is both wave-like and particle-like. An understanding of equations governing the electric and magnetic fields and
this dual nature of electromagnetic radiation is necessary for an their interactions. He noted that one of the solutions to
understanding of the processes of emission. transmission and his equations was a wave of oscillating electric and
absorption of microwaves. which is in turn necessary for understanding
magnetic fields propagating at a fixed velocity in empty
the processes and phenomena which are important in the use of
microwave radiation as a source of energy for heating and food space.
processing. The properties of electromagnetic waves and the processes Some time later, in 1886, Hendrich Hertz, for whom
of emission. transmission and absorption are described and some the frequency unit is named, developed oscillating
Journal of Food Protection 1980.43:618-624.
effects in microwave-heating applications are discussed. electric circuits and generated electromagnetic waves. He
measured the velocity of these waves and confirmed their
Establishment of electric and magnetic fields in empty transverse nature. The fact that light waves exhibited the
space requires the expenditure of energy, much the same same properties and traveled at the same velocity helped
as stretching a spring requires an expenditure of energy. with their identification as electromagnetic waves of very
When the spring is stretched we say that the work done short wavelength.
in stretching it is stored as elastic energy in the stretched For periodic electromagnetic waves, there is a definite
spring. We can get the energy back by letting the spring relationship between the wave velocity (v), the frequency
relax to its original condition. Similarly, we say that the of oscillation (D and the wavelength (A) of the wave. The
energy expended in establishing electric and magnetic wavelength of the wave is equal to the wave velocity
fields is stored in those fields and we can get the energy divided by the frequency, A = v/f. The wave velocity of
back by letting the fields relax to nothing. Of course, if electromagnetic waves in empty space is 2.997 x 10 8
we want to use the stored energy for some purpose we meters/second. The waves we will be interested in have
may have to be quite ingenious as to how we couple the wavelengths of 0.5 to 50 em, which means that the
electric and magnetic fields to the material on which we frequencies of these microwaves lie between 3 x 10 10 Hz
want to do work. In a long spring, if we stretch some local and 6 x 10 8 Hz. To generate electromagnetic waves of a
region and release it, the strained region of the spring given frequency, electric charges must be oscillated at
will travel in both directions from its original position. that frequency. One can identify the kind of oscillating
We can think of the energy stored in the stretched part of charged system which can give rise to a given wavelength
the spring as traveling along the spring. When the electromagnetic wave because of the limits imposed by
stretched region reaches the end of the spring, it can the frequency of oscillation. In Table 1, the relationship
deposite its energy in the mounting at the end, if the between frequency. wavelength and the kind of
mounting is what we call a "lossy" one. Similarly, energy oscillating source necessary to generate the electromag-
deposited by a pebble striking the surface of a pond netic wave is shown for a large range of wavelengths.
travels outward and is carried in waves to the shore where The quantized nature of electromagnetic waves was
it is deposited. When energy is put into a region by established by Max Planck and was used by Einstein to
establishment of an electric field, the field will start to explain the photoelectric effect and by Bohr in his theory
decrease at the original location if the cause of the field is of the hydrogen atom spectrum. One can describe the
removed. This will cause a magnetic field to be formed, quantized nature of electromagnetic waves by saying that
the change of which gives rise to generation of new electromagnetic waves can only be absorbed or emitted
electric fields in the surrounding space and a wave of the in definite energy units. called photons; the energy
electric field will travel outward and carry energy with it. content of a photon depends on the frequency or
It is most common to consider periodic electromag- wavelength of the radiation. The energy of the photon is
netic waves. Periodic electromagnetic waves arc gener- given as:
ated by oscillating electric charges which cause Ephoton = hf. where h = 6.625 X w- 34 Joule - seconds
oscillating electric fields. The changing electric fields (is called Planck's constant) and f is the frequency of the
also cause oscillating magnetic fields. The interplay of a radiation. The wavelength values of Table I are for
TABLE L Electromagnetic spectrum. unit area of beam, will decrease continuously away from
Frequency Vacuum wave~
the source as the beam spreads. If one directs the beam
(Hz) 8 length (m) Desc:ription Typical oscillating source perpendicularly towards a metallic sheet, then the beam
3X 1()2 1 10"" Gamma rays Nuclear charges will be reflected and in the region near the sheet, there
3X 1()2° 10"11 are two waves of the same wavelength traveling in
3X !O'Q 10"" X-rays Atomic inner shell electrons
3X 10' 8 10"10 opposite directions, the direct wave from the source and
3X 1()" 10-• Ultraviolet Atomic outer shell electrons the reflected wave from the sheet. The field of the
3x 10' 6 w-• reflected wave at the metal sheet is just opposite that of
3x 1()15 10-, Light Atomic outer shell electron the incident wave and these two fields cancel at the metal
Jx l()l4 w·• sheet and each point an integral number of half
Jx 10' 1 10"5 Infrared Molecular vibrations
3 X 1Ql2 w·• wavelengths from this metal sheet. In between these
J X lQll 10"1 Molecular vibrations and positions, the electrical field oscillates with twice the
rotations
J X 10' 0 10"2 Microwaves
amplitude it would have if only one or the other wave was
Jx 109 10"1 Klystrons and magnetrons present separately. Such a combination of two oppositely
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Jx10' 1,0 Radio waves Electronic circuits traveling waves is called a standing wave.
aThe frequency unit one Hertz (Hz) is one cycle per second. The wavelength of a wave can be determined by
measuring the distance between nodes, the points at
empty space only. When electromagnetic radiation which no oscillating electric field exists because of
travels through any material, it travels at a different cancellation between the oppositely traveling waves. The
velocity, and as a consequence the frequency remains the wavelength is twice the distance between nodes. We
same but the wavelength of the wave changes. In general, encounter examples of wave interference frequently;
the wavelength shortens since the velocity of an acoustically dead spots in rooms for certain frequencies,
Journal of Food Protection 1980.43:618-624.
electromagnetic wave is less in a material than it is in interpenetrating water waves and the fading in and out of
empty space. the television program as a plane flies by. In this latter
The intensity of electromagnetic radiation is common- case, the direct and reflected waves cancel when path
ly expressed in one of two ways. The maximum value of from the source to the receiver by reflection from the
the oscillating electric field strength, Emax• in volts per plane is some odd number of half wave lengths different
meter is given, or the energy flux, I, in watts per square from the direct path. Interference phenomena are also
meter Goules per square meter per second) is given. observed for light, which is also electromagnetic
When dealing with microwave applications, the unit used radiation. In fact, light exhibits reflection, refraction and
is most often milliwatts per square centimeter. The polarization effects, and these same effects can be
intensity of radiation is proportional to the square of the observed for microwave radiation.
maximum electric field intensity, which is called the
amplitude to the wave. An easily remembered equality REFLECTION, REFRACTION AND POLARIZATION
between these two ways of expressing the intensity of A good conductor, such as a sheet of metal, is a
radiation is: reflector of microwaves because the electrons in the
I = '/zc£0 E 2max• where c is the velocity of electromag- metal, in the presence of the electric field of the wave,
netic waves in vacuum (2.997 x 10 8 meters/sec.), Eo is the move in such a way as to reduce the electric field in the
permittivity of vacuum (8.854 x to· 12 Farads/meter) and metal to zero. The response of the electric charges in the
Emax is the maximum electric field strength, or metal causes a reflected wave to come back from the
amplitude, of the wave in volts per meter. A typical surface of the metal, which cancels the field of the
comparison is that a microwave with a electric field incident wave at the surface. At any place where there is
amplitude of 1 volt/centimeter has an intensity of 1.328 an interface between materials with different electrical
milliwatts/square centimeter. properties, a partial reflection will occur. For example,
light is partially reflected at a glass to air interface, and
INTERFERENCE EFFECTS similarly microwaves will be partially reflected at an air
Microwaves, as all electromagnetic waves, are capable to roast or fat to muscle interface in a microwave oven.
of interference effects. This occurs because the electric The law of reflection holds for reflection"of microwaves
field intensity at a given point in space at one instant of from a plane interface, that is the angle of the reflected
time is the sum of the electric fields from each wave beam to the normal to the surface is equal to the angle of
passing that point at that instant of time. Since electric the incident beam to the normal and the incident beam,
fields can be in one direction or another, it is possible for reflected beam and surface normal are the same plane.
the field at a point to be greater than that of any of the Refraction occurs for microwaves as well as for other
separate waves arriving at a point, or to cancel and cause electromagnetic radiation. If a beam of microwaves
a vanishing electric field at the point. Let us talk about a strikes an interface between two regions of different
specific example. If a microwave source is set up and a electrical properties at other than normal incidence, the
beam of microwaves directed out into a large region, the direction of travel of the wave will change. This is the
measured intensity of this beam, that is the power per same effect as the bending of a light beam when it passes
from air to water. The same law governs the direction of The only frequencies which are approved by the
the incident and refracted beams in the case of Federal Communication Commission for industrial,
microwaves as in the case of visible light. Lenses and medical and scientific uses in the United States and the
optical instruments are designed on the basis of the laws wavelength of these microwaves are given in Table 2.
of reflection and refraction, thus it is obvious that
TABLE 2. Frequency and wavelength of microwaves approved for
microwave lenses and focussing mirrors can be industrial, medical use.
constructed. You see these devices in use on the top of
microwave communication towers. Frequency band (MHz) Central wavelength (em)
polarized horizontally. Only transverse waves, that is consists of a capacitor and inductor. The capacitor
waves for which the wave motion is perpendicular to the consists of two conducting plates with an insulator
direction of wave travel. can exhibit polarization. Sound between them. If electric charge is moved from one plate
waves, for example, cannot be polarized. They are to the other an electric field is set up between the plates,
longitudinal waves, waves in which the wave motion is a voltage will exist between the plates and work will have
back and forth along the direction of propagation of the been done in the process. We can consider the energy to
wave. be stored in the capacitor. If we connect the two plates
Electromagnetic waves can show polarization, thus with a wire a current will flow, the charge will be
Journal of Food Protection 1980.43:618-624.
they are transverse waves. The wave is a wave of electric neutralized and the electrical potential difference
and magnetic fields which are directed perpendicular to (voltage) and the stored energy will go to zero. An
the direction of propagation of the wave. There are two inductor consists of a wire coil with or without a core. If
directions perpendicular to the direction of travel of the current is passed through such an inductor, a magnetic
wave, thus there are two directions for plane polariza- field is set up. Work is done in establishing the current in
tion. An actual wave may have both plane polarizations the coil, and if the driving source of the current and power
present at the same time, and, depending on the relative is removed the magnetic field starts to collapse. This
phase between them, the resultant electromagnetic wave collapsing magnetic field induces an electrical potential
may be plane-polarized or elliptically-polarized. Inter- (voltage) in the coil which tends to keep the current
fering waves of different polarizations can never totally flowing in the same direction as before. A combination of
cancel so they will not show complete destructive an inductor and a capacitor forms an electrical circuit
interference. which is capable of oscillating charges back and forth
Polarization of electromagnetic waves is determined by over a large range of frequencies, from zero up to about
the direction of motion of the oscillating charges which 1 MHz, depending on the values of the capacitance and
serve as a source of the waves. Microwaves are usually inductance.
generated by moving electrons back and forth at high In Fig. 1, the oscillation of a capacitor-inductor circuit
frequency in a wire antenna or on the inner surface of a is shown. In sketch (a) we start with the capacitor
wave guide. There is a direction associated with the charged and no current. There is an electric field (E) in the
motion of the electrons and the radiated waves are
usually plane-polarized.
capacitor and consequently a voltage across it. This microwaves. The radiation is coupled into the oven
situation cannot exist unchanged so a current begins to through a very short piece of wave guide.
flow through the coil, reducing the charge on the
capacitor. The current through the coil sets up a PROCESS OF HEATING
magnetic field (B) through the coil as shown in sketch (b).
We are all familiar with the usual processes by which
This continues until the charge on the capacitor is zero
food is heated in ovens for cooking or other processing.
and the magnetic field in the coil is at a maximum. Under
The outside of the food is heated by convection of heated
this condition the current cannot simply stop because the
oven air. The hot walls, heating elements, resistance rods
magnetic field will start to decrease and will cause a
or burners radiate infrared waves which are absorbed
voltage to be induced in the coil which will keep the
and heat a very thin layer at the surface of the food. The
current flowing in the same direction as we see in sketch
interior of the food is then heated by conduction from the
(c). The capacitor starts charging up in the opposite
heated surface. The thermal conductivity of foods is not
direction as a result of the current flow, as in sketch (d).
high; thus it takes quite long for the interior of food
This continues until the magnetic field is reduced to zero,
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energy. This mechanism is conduction. In materials with interior and is less sensitive to some door misalignment
conduction electrons, such as metals, the electrons will than the electrical contacts described previously.
respond to electromagnetic fields with frequencies in the
microwave range. If the material has little or no ATOMIC BASIS FOR HEATING
resistivity, the energy put into the motions of the One needs to understand the existence of allowed
electrons will be reradiated. However, in a material with energy states of material systems and the quantization of
resistivity, the electrons will collide with nuclei and the electromagnetic field to discuss the absorption and
electrons which are bound to other atoms and will set thermalization of microwave energy on an atomic scale;
them into vibration which will become thermal energy, however, for many purposes the classical viewpoint of
and the electron will not reradiate all of the energy it has Maxwell is quite adequate. In this classical approach, the
received from the electromagnetic field. This means very properties of the atoms and their interactions are
good conductors of electricity are poor absorbers of expressed in terms of measured constants for a given
electromagnetic radiation, they are instead good material under its physical conditions of pressure and
reflectors of electromagnetic radiation. This phenome- temperature. These empirical constants express the
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non is used in constraining the electromagnetic waves in strength of the interaction between the radiation field
waveguides and in microwave ovens. The door of a and the matter as well as the ability of the material to
microwave oven is a good conductor, usually aluminum, thermalize the absorbed energy, or its "lossiness". For
with a regular pattern of small holes in it so that one can visible radiation, the constants usually given are the
see into the oven. One might wonder if the microwaves index of refraction (n) and the absorption coefficient (a),
could not escape from the oven through these holes. The both of which genera11y depend on the frequency of the
results of both calculations and measurements is that if radiation. For microwaves, it is more common to give
the holes are much smaller than the wavelength of the either the real (K ') and imaginary (K") parts of the
Journal of Food Protection 1980.43:618-624.
radiation then the electromagnetic fields extend through dielectric constant or the real part of dielectric constant
the holes only a distance comparable to that of the hole (K ')and the resistivity (p) of the material. These constants
diameter and that no waves are passed through. This have been determined experimentally for a wide variety
effect is rather striking in the case of a good conductor of materials over a large frequency range (1,3,4).
with slits cut in it which are narrow compared to the There is a defmite relationship between these
wavelength of some particular microwave radiation. I fthe constants. For materials in which magnetic effects are
microwave is polarized, say its electric field oscillates in negligible, the imaginary part of the relative dielectric
the vertical direction, and if the conductor is placed with constant, K", is related to the restivity, p, of the material,
the slits perpendicular to the electric field, or horizontal, the frequency of the radiation, f, and the dielectric
the wave will travel through because the charges in the constant of a vacuum, £ 0 as follows:
conductor are not free to travel perpendicular to the slits
and the slitted conductor acts on a non-conductor. If the 1
slits are vertical, the electrons in the conductor are free to K"
2nfp£Q
respond to the electromagnetic field and the slitted
conductor will behave as a solid conductor and reflect the The absorption constant, a, is related to the frequency of
waves. Such a slitted conductor can be used to analyze the radiation, f, and the real and imaginary parts of the
the polarization of microwaves. dielectric constant by the expression.
a= 2rrf /i[""[{l + (K~'hl/2 -l]l/2,
CONTROLLING LEAKAGE c y2 K'
As we have noted, the reflection of microwaves from a where c is the velocity of electromagnetic radiation in
good conductor is used to confine microwaves in an oven empty space. This expression relates the absorption and
cavity. The door closure provides a possibility for some the imaginary part of the dielectric constant, the loss
microwave leakage since the length of the opening is part, which is in turn related to the resistivity of the
longer than the wavelength. There are two ways by which material. This is another way of describing the loss or
this leakage is minimized generally. One way is by absorption of energy within the material. If one is
electrically connecting the door to the oven interior, interested in the relative absorbing properties of different
using a conducting strip with fingers that contact both the materials, it is the absorption constants fop the materials
door and the interior of the oven. This technique works which should be compared. If only the real and
quite well as long as the mechanical alignment of the imaginary parts of the dielectric constant are known, one
door is maintined so that the contacts have very low can readily compute the absorption coefficient from the
electrical resistance. If the door becomes bent or preceding equations.
misadjusted, some microwave leakage may occur. A The velocity of travel of electromagnetic waves in
second method is to use a lossy flexible gasket at the biological material such as we have been describing is
distance from the interior of the oven where the current given by the real part of the index of refraction, nr- This
flow in the gasket due to leakage is maximized. This constant is related to the frequency of the radiation, f,
maximizes the absorption of the leakage from the oven ·,d the real and imaginary parts of the dielectric