Aits 1819 Ot Jeea Paper 1 Sol

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ALL INDIA TEST SERIES

OPEN TEST
JEE (Advanced)-2019
PAPER – 1
TEST DATE: 03-02-2019
ANSWERS, HINTS & SOLUTIONS

Physics PART – I
SECTION – A
1. A, B, C, D
n
Sol. C2  3, n  3
So initially atoms was in n = 2.
E3  E2  68 eV
Hence Z = 6
12400
min   28.49 Å
E 3  E1
2. A, B, C, D
Sol. Let potential of point A is x and potential of point B is zero. Consider charge flown through 3V
battery is q0.
2  3  x   q0   0  x  2  0 …(1)
q0   x  3   1   2  x  3  2  0 …(2)
3. A, B, C
Sol. In figure-1
1 1 1
 
v u f
1 1 1
 
v 60 30
V = – 60
v
Hence m    1
v
In figure-2, images will not separated.
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AITS-OT-(Paper-1)-PCM(Sol.)-JEE(Advanced)/19 2
4. A, B
   
Sol. If v  a  0 , then there must be a component of a along v
   
If r  v  0 , then there must be a component of v along r
5. B, C, D
Sol. Phase difference between two particles in standing wave is either zero or  at any instant of time.
Potential energy depends upon strain. Particle near to nodes will experience more strain.
6. A, B, C

Sol. a0  (2giˆ  gj) ˆ
  
FB  V(a0  g)  2Vg(iˆ  ˆj)
  
Fnet  FB  mg  2Vg(iˆ  ˆj)  0 Vgjˆ
 2 ˆ ˆ
anet  g(i  j)  gjˆ
0
  
arelative  anet  a0
7. C
8. C
Sol. (for Q. 7 to Q. 8)
ft = mg = 8N …(i)
f f = I
11
 rad/s2 …(ii)
7
v 22
  ad/sec …(iii)
R 7
2  02  2
 =  rad …(iv)
 = 0 + t
t = 2 sec …(v)
1
y   2  1m …(vi)
2
1
x   R  m …(vii)
2
9. C
10. B
P1(V1) = P2(V2)
 4/3
V   50 
P2 = P1  1   21 
 V2   400 
1
 21
16
= 1.3125 atm
Work done =
P1V1  P2 V2
=
 21 50  1.3125  400 105  10 6 = 157.5 Joule
 1 4
1
3
3 AITS-OT-(Paper-1)-PCM(Sol.)-JEE(Advanced)/19
SECTION – D
11. 00000.88
dp P m
Sol. F   u.  
dt t  t 
200
  2  2.2  
1000
= 0.88 Newton
12. 00031.63
1 2 GmM GmM
Sol. mv – = 
2 r 2a
 2 1 
v 2  GM   
 r a
 2 1
= 6.67  10–11  2  1030     1011 =10.005  108
 2 4
v = 31.63 km/sec
13. 00007.10
Sol. 1 MSD = 1 mm
1 VSD = 0.9 mm
L.C. = 0.1 mm
ve error = 4  0.1 mm = 0.4 mm
Reading = 6 mm + 7  0.1 mm = 6.7 mm
Diameter = 6.7 + 0.4 = 7.1 mm
14. 00003.00
R
Sol. q0   dv   0 r n 4 r 2 dr
0
R/2
n
q   dv   0 r .4r 2 dr
0
kq0 kq
 16.
R2 R 
2
 
2
So n=3
15. 01800.00
Sol. x 2  16y Q
16dy
2x 
dx 20 3 30 m
dy x 60°
  3 P
dx 8
10 3
  60 
12 m
W  K
WF  Wff  Wg  WN  0
WF   Wff  Wg 8 3

 mg 8 3  10 3  mg  42  
= 1800 J
16. 00256.00
1
Sol. a 4
n
where, a is acceleration of electron and ‘n’ is no. orbits.
17. 00033.33
100  v
Sol. Acceleration of container a 
200  t
v 100
dv dt
 100  v   200  t
0 0
100
v m/ s.
3
18. 00001.33
I1 mL2
Sol. T1  2 , I1   mL2
mgd 3
2
I2 mL2  m L / 2  
T2  2 , I2    mL2 
mgd 3  6 
T1 I 4 6
 1  ,
T2 I2 3 11
Chemistry PART – II
SECTION – A
19. A, B
Sol. In first molecule, lone pair of electrons lie in equatorial position, hence decreases 2 more rapidly
the 2 . In second molecule, -electron cloud lie closer to axial bonds and pushes them more, so
1  1 .
20. A, B, D
Sol. Since AB is an isobaric process, so
VB TB T
  2  B  TB  600K
VA TA 300
WABCDA  WAB  WBC  WCD  WDA
WAB  nRT  1200 cal
VC V
WBC  2.303nRTB log  2.303nRTB log B  as VC  VD 
VB VD
VB VA
WBC  2.303  2  2  600  log 
VA VD
= 2.303 × 2 × 2 × 600 × log 2/4
= - 1663.68 cal.
WCD  0
VD
WD A  2.303nRTA  log
VA
= 2.303 × 2 × 2 × 300 × log4
= 1663.68 cal.
WA BCD A  1200  1663.68  0  1663.68
= - 1200 cal
21. A, B, C, D
Sol. A → Curtius degradation type reaction
B → Hydration + deprotonation + tautomerisation
C → Friedel-Crafts reaction followed by benzylic acid rearrangement
D → Baeyer-Villiger + Perkin condensation reaction.
22. A, B, C, D
Sol. All substrates give the same major product which is given below
OH
23. A, B, C, D
Sol. Coordination number of Al in AlCl3(s) is 6.
Anhydrous AlCl3 is covalent but becomes ionic when dissolved in water.
BI3 is the strongest Lewis acid among all boron halides.
All BX3 are covalent in nature.
24. A, C, D
Sol.
 
CuCl2 O  C  NH2 
2    Dichloridodicarbamidocopper II
2
25. C
Sol.
2
1 1s2
1s1
3 4 5 6 7 8
[ ] 2s1 [ ] 2s2 2s22p1 2s22p2 2s22p3 2s22p4
9
[ ] 3s1 10 11 12 13 14
[ ] 3s 2 3s23p1 3s23p2 3s23p3 3s23p4
15 16 17 22 23 24
18 19 20 21
[ ] 4s1 [ ] 4s2 4s 3d1
2 2 4 1 2 4 2 4s23d44p3 2 4 4
4s2, 3d2 4s , 3d3
2 2 4
4s , 3d 4s 3d 4p 4s 3d 4p 4s 3d 4p
26. C
Sol. Lewis structures 3 – 1; 1 – 4 – 1;
1
5 ; 6 ; 7 1
1 1 1
1
27. D
28. C
(i) The solid must contain Na and I. The yellow colouration of the flame indicates the presence of
Na+ ion; a yellow silver salt that is dissolved only by strong complexing agent such as CN  or
S2 O 32  must be AgI.
(ii) Reaction (i) to (iv) indicates a sodium salt of an oxygen containing acid containing iodine.
Both SO2 and I– are oxidized, while in the first case I  is formed with an intermediate of I2 or
I 3 (brown solution) and in the second I2 or ( I 3 ) is formed. As the solution is neutral NaIO3 or
NaIO4 come into consideration.
(iii) Conditions given in observation(v) proves that solid (x) is NaIO4.
2
1 mole of NaIO4 = 213.90 g NaIO4 = 8 moles of S2 O3 .
0.1000  8
 0.1000 g NaIO4   3.740  10 3 mol of S 2O32
213.90
   
IO4  7I  8H 
 4I2  4H2O 
SECTION – D
29. 00006.11
30. 00002.20
Sol. O O O
OH O
N OH O O
C C
C OH
P  Q R  S 
31. 00003.50
Sol. PV = RT (for 1 mole of ideal gas)
PV = R(K + V2)
RK
P  RV
V
For minimum pressure
dP d2P
 0 and 2   ve
dV dV
So, Pmin  2R  K
32. 00000.61
Sol. H2O
s
cos104.5o   s  0.20
s 1
So, fraction of s-character of lone pair in H2O = 0.30
Similarly, fraction of s-character of lone pair in NH3 = 0.31
33. 00001.25
Sol. x = 5 and y = 4
Only a, b, d, e and h will form buffer.
34. 00002.50
Sol. O S O O O O
O S S ; S ; S S O ; O S S O;
O O O
O O
O O O O O O
O S S O ; O S O S O; O S ;O O S O
O O O O O O
x = 5, y = z = 1
35. 00001.80
Sol. NH2
O
CH CH C CH3
N CH3
(A) (B)
36. 00007.50
Sol. Let, x ml of 2.0 M NaOH solution be added, then
H3PO 4  NaOH  NaH2PO 4  H2O
millimoles 10 2x 0 0
0  2x  10 
NaH2PO 4  NaOH  Na2HPO 4  H2O
10  2x  10  0
10   2x  10  0 2x  10
= 20 – 2x
2x  10
So, 7.2  7.2  log , on solving x = 7.5
20  2x
Mathematics PART – III

SECTION – A
37. A, B
Sol. x = 4k + 1, y = 2m (k1m  N)
yx = (2m)4n + 1 (it is divisible by 8)
y 2m
x = (4n + 1) (it leave remainder 1)
38. A, C, D
Sol. As f(x)f(x) > 0  x  R
For y = f(x)f(x); y = (f(x))2 + f(x)f(x) > 0
If f(x)0 < 0 then f(x0) < 0
39. B, D
Sol. If it is parallelogram z1 + z3 = z2 + z4 = 0 (in some order)
d
 If it is rhombus then area is 2|z1||z2| where |z1|2|z2|2 =
a
40. A, C, D
Sol. y = fk(x) is periodic with period 10 and fk(f4k + 1(x) – x) = 0
41. B, C, D
Sol. R.H.D. at x = –1 is (p – m2) where n = 2m or 2m – 1
L.H.D. at x = –1 is (m2 – p) for differentiability m2 = p
42. A, C
Sol. x3 – 3x + 2 = 2; x = 0,  3
3(f 2(t) – 1)f(t) = 1
43. B
Sol. x2 + y2 = r2 and (x – 1)2 + (y – 5)2 = 4 must be orthogonal
44. C
Sol. OP·OP = r2
Using P(r1 cos , r1 sin )
Locus of P is
mr 2 r2
x 2  y2  x y 0
c c
45. D
46. A
3 2
ax + bx = 8a + 2b  (x – 2)(ax + 2ax + 4a + b) = 0
3
D = 0  3a + b = 0 as a = 1  f(x) = x – 3x
Similarly for g(x) = 4x + ax + bx + c, f(x) = (4x3 – 3x) and f(1) = 1
3 2
SECTION – D
47. 00010.00
Sol. Minimum will occur at z = 0
4 2019
1
  1010  10
k 0 r 0
48. 00009.00
Sol. Let ABCD have coordinates P
O, (i + j), (j + k), (i + k) respectively
d1  d1
 cosec   3
d d
Where  is angle between AB and normal of BCD

B Q
49. 00002.25
3 3
Sol. 4f (x) = f (2x + 1) + c
1 3 5
By taking x   , , and 6, we get
8 4 2
3 5 3 5
f 3    c  4 , f 3    c  4f 3   , 4f 3    f 3  6   c
4 2 4 2
8 8
So, we c  i.e., 4f 3(x) = f 3(2x + 1) +
3 3
50. 00002.00
Sol. The given equation reduces to 4f2(x) + x2 = 9, an ellipse.
As in the figure it has two solutions
51. 00035.32
4 k
C1 4 C2  2! 6 C2k 2 2k  2! 10  2k! 8
Sol. P x    and P(d) = 0.4
k 1 10! 21
52. 00480.00
1  eto  e to  e to  e to  to P0(to)
Sol.      ydx
2 2  2  0
2
1 2to
e  e 2to
to e t  e  t

  dt 
to
 240 O
8 0
4 2
to = 480
53. 00003.00
Sol. I = cos  cos  + sin2  sin  – cos2  sin   cos  cos  + sin  sin  = cos( – )
  –  = 0 & cos  = 0, sin  = 1

===
2
54. 57060.00
Sol. For point of intersection we take say two points A and B, from each we can draw 9C2 lines cut of
which 8C2 are parallel. So total number of intersection points are
10
 2
C2  36   28  57060

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FIITJEE

ALL INDIA TEST SERIES

TEST DATE: 03-02-2019

ANSWERS, HINTS & SOLUTIONS

Mathematics PART – III

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