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Task:
Calculate the density of propylene at T=300K and P=10bar using the Peng-Robinson equation
of state. (The vapor pressure of propylene is Ps (300K)=12,12bar)
Given specifications:
Source:
http://encyclopedia.airliquide.com/images_encyclopedie/VaporPressureGraph/Propylene_Vap
or_Pressure.GIF
Gas Properties:
http://encyclopedia.airliquide.com/Encyclopedia.asp?GasID=54#GeneralData
Notes:
Solution
z^3+(((bP)/(R*T))-1)*z^2+((aP)/(R^2*T^2)-3*((bP)/(RT))^2 – 2
*((bP)/(RT)))*z+[((bp)/(RT))^3+((bp)/(RT))^2- ((aP*bP)/(R^2*T^2*RT))]
The advantage of this formulation is that all coefficients and z itself remain dimensionless.
Caution! In Order to minimize consequential errors, you are required to use the now given
values for the upcoming Caluclations!
• \(a(T)\)={NewAT}\(\frac{Jm^3}{mol^2}\)
• \(b\)={NewB}*\(10^{-5}\frac{m^3}{mol}\)
To solve the given cubic equation for z you can apply Cardano’s formula in this form:
• z^3+L*z^2+M*z+N=0
• P= (3*M-L^2)/3
• Q= (2*L^3)/27 – (LM/3)+N
D=(P/3)^3+(Q/2)^2=…(Value)
For D< 0, there are 3 real solutions obtained. With the abbreviations:
Calculate all 3 real solutions and give the values from high (z_1) to low (z_3)!
z_1=2*Thetha^(1/3)*cos(phi/3)-(L/3)= (value)
z_2=2*Thetha^(1/3)*cos(phi/3+(2*pi)/3)-(L/3) (value)
z_3=2*Thetha^(1/3)*cos(phi/3+(4*pi)/3)-(L/3) (value)
Aufgabe:
Calculate the density of propylene at T=300K and P=10bar using the Peng-Robinson equation
of state. (The vapor pressure of propylene is Ps (300K)=12,12bar)
Given specifications:
Source:
http://encyclopedia.airliquide.com/images_encyclopedie/VaporPressureGraph/Propylene_Vap
or_Pressure.GIF
Gas Properties:
http://encyclopedia.airliquide.com/Encyclopedia.asp?GasID=54#GeneralData
Notes:
Solution
z^3+(((bP)/(R*T))-1)*z^2+((aP)/(R^2*T^2)-3*((bP)/(RT))^2 – 2
*((bP)/(RT)))*z+[((bp)/(RT))^3+((bp)/(RT))^2- ((aP*bP)/(R^2*T^2*RT))]
The advantage of this formulation is that all coefficients and z itself remain dimensionless.
Caution! In Order to minimize consequential errors, you are required to use the now given
values for the upcoming Caluclations!
• \(a(T)\)={NewAT}\(\frac{Jm^3}{mol^2}\)
• \(b\)={NewB}*\(10^{-5}\frac{m^3}{mol}\)
To solve the given cubic equation for z you can apply Cardano’s formula in this form:
• z^3+L*z^2+M*z+N=0
• P= (3*M-L^2)/3
• Q= (2*L^3)/27 – (LM/3)+N
D=(P/3)^3+(Q/2)^2=…(Value)
For D< 0, there are 3 real solutions obtained. With the abbreviations:
Calculate all 3 real solutions and give the values from high (z_1) to low (z_3)!
z_1=2*Thetha^(1/3)*cos(phi/3)-(L/3)= (value)
z_2=2*Thetha^(1/3)*cos(phi/3+(2*pi)/3)-(L/3) (value)
z_3=2*Thetha^(1/3)*cos(phi/3+(4*pi)/3)-(L/3) (value)