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Term Squats (tis, py s6~63, Dekock & Gray) Wei, to/aa/2006
Sonne Wsthowic tmafparahnn may fue wit to several odote en tebes
£3. Gvbew Is* 2s? 29? €4.,'D.7P, “s -
sre Ke follwing, orbital’ arrangpmants paling ae ns septal syste)
Aniasley hove different energitr ~ dagen erate — seeks
was
Ae Seat elechor
Fe HH emfogevadinn Ist 25% 2p™
a tr eo
&
Goal: ¥ determine Henny Dates Gov cach & GP in an ato fion.
+ aatiqn teen Kywbol to gach enargry Sinte
feat ope_clede Heel alathent,
2 angular momerhun Quanhea no, LL + total orbital andpatenr yal
of an election in individual evovtad (Leb eT vc. dum ortr sla)
(was 0, =, 22)
Ss Spm AnGulor mtn Quantin no ~
Fan eheden (= + Lewien!) So etal opin angular ihr
Come ea) (Se Brae. sam over elechas)
3 D: trtel angular mtn
(5-2 +3)
Addition of angular momenta
LeGak + pessite lnc, Le bitte, o, IG-b) te iakeysr Caesemerts
elechons) 7 .
lela AMEN Play 2b
Sais ax posse values: S=Sitsa, —-, [oisa) oe beger acnenerh
@ eres ) La Ms = 5-0) -S ae RL bast
2 -tomponcantnels
Ser
+3 pessbla volues F=bL+S,..., b-Sl Q Cader Gerennents,
My- 5, Jo. 3
Teen Sapnbol S41 Leo,1, 2.4
Zo bs S.P.D, F,
muthiplicihy rT
(spin degpreroog)
One - electron alow fon
LL 3 teem septocl S. PDF Conrerpeds oracthy to S$, p. dif orbital asigeodin
S39 sek w& Sek
ASA =Q doublet (mest or -h ove degnerte)
Bai Grind Sate Hydeogin bows :
<=
Clechar tmfigarahinn Ie!
S#4, T=
Gyr culled sabe Hydeyn abn clack tofQirohon 2° =
nel: two anergy states anse
E
fom ave tachon efneele(deynenis) apy, |
Energy difftrene ov splih iat ee
results lm spin-orbit Pha ap (seit) |
cmspg CE-8), Ows Ye
Splitting B Seal yon!
ie oA re else cluepee
co athens wie non-equivalent elechens
elechons with Aifentct A oe L quarhann Auamaess
Tn tnis @e, Pauli eeelucion Principle (a e7 eank hove Sama cet ef 7
quanti namues fa, Li my, S. meh) B cbeyd automakealle,
xd tender clacton orfguration 2p'3P* Qua term sgetaly for
atouie energy States
2 L=a,1,0
Sh, S-% 3 S- Lo
Herms Mak anse
Egy conser shechon Corfgarahm 2p! 3p'4E' (3 elachens)
he Gates) Le 5 43,2, 1 we nena
t {
hy+hth { zo
( E
SSE ye S = hh | Sze
. i fi
Sitsasy | SttSa— Sy
Con write dam terms with differant J vatucs fr each tmbbmabin
el Lh and S