NEETPrep Crash Course

Revision Class # 11
Contact Number of NEETPrep: 8527521718

SOLID STATE
1. Triclinic crystal has the following unit 6. The atomic radius of strontium (Sr) is
cell parameters: 215 pm and it crystallizes with a cubic
1. a = b = c; 𝛼 = 𝛽 = 𝛾 = 90° closest packing. Edge length of the cube
2. a = b ≠ c; 𝛼 = 𝛽 = 𝛾 = 90° is :
3. a ≠ b ≠ c; 𝛼 ≠ 𝛽 ≠ 𝛾 ≠ 90° 1. 430 pm
4. a = b ≠ c; 𝛼 = 𝛽 = 90°, 𝛾 = 120° 2. 608.2 pm
2. Which of the crystal contains the 3. 496.53 pm
maximum number of Bravais lattices ? 4. None of these
1. Cubic 7. In the spinel structure, oxide ions are
2. Hexagonal cubical-closest packed whereas 1/8th of
3. Triclinic tetrahedral voids are occupied by A2+
4. Orthorhombic cation and ½ of octahedral voids are
3. The crystal system of a compound with occupied by B3+ cations. The general
unit cell parameters, formula of the compound having spinel
a = 0.328 nm, b = 0.328 nm, c = 0.527 structure is:
nm and 𝛼 = 𝛽 = 𝛾 = 90° is : 1. A2B2O4
1. Cubic 2. AB2O4
2. Tetragonal 3. A2B4O2
3. Monoclinic 4. A4B2O2
4. Rhombohedral 8. An alloy of copper, silver and gold is
4. An element X ( At. Wt = 80 g/mol) found to have copper constituting the
having fcc structure, calculate no. of ccp lattice. If silver atoms occupy the
unit cells in 8 gm of X : edge centres and gold is present at
1. 0.4 × NA body centre, the alloy will have the
2. 0.1× NA formula :
3. 4 × NA 1. Cu4Ag2Au
4. None of these 2. Cu4Ag4Au
5. Molybdenum ( At. Wt. = 96 g mol-1) 3. Cu4Ag3Au
crystallizes as bcc crystal. If density of 4. CuAgAu
crystal is 10.3 g/cm3, then radius of Mo 9. A binary solid (AB) has a rock salt
atom is ( use NA = 6× 1023) : structure. If the edge length is 400 pm,
1. 111 pm and radius of cation is 80 pm the radius
2. 314 pm of anion is :
3. 135.96 pm 1. 100 pm
4. None of these 2. 120 pm
3. 250 pm
4. 325 pm

SOLID STATE
10. An ionic compound AB has fluorite type
structures. If the radius B- is 200 pm,
then the ideal radius of A+ would be :
1. 82.8 pm
2. 146.4 pm
3. 40 pm
4. 45 pm
11. Which of the following statements for
crystals having Schottky defect is not
correct?
1. Schottky defect arises due to the
absence of a cation and anion from
the position which it is expected to
occupy
2. Schottky defect are more common
in ionic compounds with high co-
ordination numbers
3. The density of the crystals having
Schottky defect is larger than that
of the perfect crystal
4. The crystal having Schottky defect is
electrical defect is electrical neutral
as a whole
12. Which of the following defects does KBr
show?
1. Frenkel
2. Schottky
3. Metal excess
4. Metal deficiency
13. Doping of AgCl crystals with CdCl2
results in:
1. Schottky defect
2. Frenkel defect
3. Substitutional cation vacancy
4. Formation of F-centres
NEETPrep Crash Course
Revision Class # 11
Contact Number of NEETPrep: 8527521718
14. Select the incorrect statement:
1. Stoichiometry of crystal remains
unaffected due to Schottky defect
2. Frenkel defect is usually shown by
ionic compounds having low
coordination number
3. F-centres generation is responsible
factor for imparting the colour to
the crystal
4. Density of crystal always increases
due to substitutional impurity
defect
15. When NaCl is doped with 10-5 mole % of
SrCl2, what is the no. of cationic
vacancies ?
1. 10-5 × NA
2. 10-7 × NA
3. 2×10-7 NA
4. None of these
16. The composition of a sample of
Wusitite is Fe0.93O. What is the
percentage of iron present as Fe3+ in
total iron ?
1. 15.05 %
2. 25 %
3. 35 %
4. 45 %
17. A crystal lead (II) sulphide has NaCl
structure. In this crystal the shortest
distance between a Pb2+ ion and S2- ion
is 297 pm. What is the volume of unit
cell in lead sulphide ?
1. 209.6 ×10-24 cm3
2. 207.8× 10-23 cm3
3. 22.3× 10-23 cm3
4. 209.8× 10-23 cm3
 NEETPrep Crash Course
Revision Class # 11
Contact Number of NEETPrep: 8527521718

SOLID STATE
18. KCl crystallizes in the same type of
lattice as does NaCl. Given that rNa+/rCl- =
0.50 and rNa+/rK+ = 0.70, calculate the
ratio of the side of the unit cell for KCl
to that for NaCl:
1. 1.143
2. 1.224
3. 1.414
4. 0.875
19. An element X (atomic weight = 24
gm/mol) forms a face centered cubic
lattice. If the edge length of the lattice
is 4 × 10-8 cm and the observed density
is 2.40 × 103 kg/m3, then the
percentage occupancy of lattice points
by element X is : ( Use NA = 6 × 1023) :
1. 96
2. 98
3. 99.9
4. None of these