911

APÉNDICE 1

TABLA A-2
Calores específicos de gas ideal de varios gases comunes (conclusión)
c) Como una función de la temperatura
_
cp  a  bT  cT 2  dT 3
(T en K, cp en kJ/kmol · K)

% de error
Rango de
Sustancia Fórmula a b c d temp., K Máx. Prom.
Acetileno C2H2 21.8 9.2143  102 6.527  105 18.21  109 273–1500 1.46 0.59
Aire — 28.11 0.1967  102 0.4802  105 1.966  109 273–1800 0.72 0.33
Amoniaco NH3 27.568 2.5630  102 0.99072  105 6.6909  109 273–1500 0.91 0.36
Azufre S2 27.21 2.218  102 1.628  105 3.986  109 273–1800 0.99 0.38
Benceno C6H6 36.22 48.475  102 31.57  105 77.62  109 273–1500 0.34 0.20
i-Butano C4H10 7.913 41.60  102 23.01  105 49.91  109 273–1500 0.25 0.13
n-Butano C4H10 3.96 37.15  102 18.34  105 35.00  109 273–1500 0.54 0.24
Cloruro de
hidrógeno HCl 30.33 0.7620  102 1.327  105 4.338  109 273–1500 0.22 0.08
Dióxido de
azufre SO2 25.78 5.795  102 3.812  105 8.612  109 273–1800 0.45 0.24
Dióxido de
carbono CO2 22.26 5.981  102 3.501  105 7.469  109 273–1800 0.67 0.22
Dióxido de
nitrógeno NO2 22.9 5.715  102 3.52  105 7.87  109 273–1500 0.46 0.18
Etano C2H6 6.900 17.27  102 6.406  105 7.285  109 273–1500 0.83 0.28
Etanol C2H6O 19.9 20.96  102 10.38  105 20.05  109 273–1500 0.40 0.22
Etileno C2H4 3.95 15.64  102 8.344  105 17.67  109 273–1500 0.54 0.13
n-Hexano C6H14 6.938 55.22  102 28.65  105 57.69  109 273–1500 0.72 0.20
Hidrógeno H2 29.11 0.1916  102 0.4003  105 0.8704  109 273–1800 1.01 0.26
Metano CH4 19.89 5.024  102 1.269  105 11.01  109 273–1500 1.33 0.57
Metanol CH4O 19.0 9.152  102 1.22  105 8.039  109 273–1000 0.18 0.08
Monóxido de
carbono CO 28.16 0.1675  102 0.5372  105 2.222  109 273–1800 0.89 0.37
Nitrógeno N2 28.90 0.1571  102 0.8081  105 2.873  109 273–1800 0.59 0.34
Óxido nítrico NO 29.34 0.09395  102 0.9747  105 4.187  109 273–1500 0.97 0.36
Óxido nitroso N2O 24.11 5.8632  102 3.562  105 10.58  109 273–1500 0.59 0.26
Oxígeno O2 25.48 1.520  102 0.7155  105 1.312  109 273–1800 1.19 0.28
n-Pentano C5H12 6.774 45.43  102 22.46  105 42.29  109 273–1500 0.56 0.21
Propano C3H8 4.04 30.48  102 15.72  105 31.74  109 273–1500 0.40 0.12
Propileno C3H6 3.15 23.83  102 12.18  105 24.62  109 273–1500 0.73 0.17
Trióxido de
azufre SO3 16.40 14.58  102 11.20  105 32.42  109 273–1300 0.29 0.13
Agua (vapor) H2O 32.24 0.1923  102 1.055  105 3.595  109 273–1800 0.53 0.24

Fuente: B. G. Kyle, Chemical and Process Thermodynamics, Englewood Cliffs, Nueva Jersey, Prentice Hall, 1984. Usada con permiso.

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18Appendix_01 ITALICAS.qxd 911 7/12/11 14:25:58