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CHAPTER 2
LITERATURE REVIEW
2.1 INTRODUCTION
vapour pressure is similar to that of R22 and hence it is expected that R407C
may be used in existing equipment without having major changes. At present
it seems that R410A can be adopted in new systems while R407C are used in
the existing systems. HFC407C is a close match to HCFC22 in existing
equipment with respect to energy efficiency and other performance
parameters such as compressor discharge temperature and pressure. Studies
by Aprea et al (2004) show that the performance of HFC407C is superior to
blends like HFC507 and HFC417A. Heat transfer behavior of R407C has
been described by Bivens et al (1994).
3.5
3.0
2.5
2.0
COP
1.5 R410
R407C
1.0 HCFC22
0.5 HFC134a
0.0
-5 0 5 10 15
o
Evaporating Temperature C
% Relative to HCFC-22
Refrigerant Cooling Pressure Compressor Discharge
COP
Capacity ratio power Pressure
R407-C - 1.76 1.72 6.60 1.75 7.67
R-410A -8.90 41.21 -2.29 9.81 55.60
HFC-134a 4.40 -33.00 13.75 -4.27 -31.45
HC-290 1.00 -14.13 -6.87 -1.00 -12.42
HFC-32/HFC-34a 1.00 -1.00 8.80 -1.00 1.30
(30/70 by wt%)
HFC-32/HFC-125 -8.32 45.40 2.00 8.30 57.72
(60/40 by wt%)
HFC-32/HFC-125/HFC- 0.34 2.93 7.44 0.35 6.71
134a (30/10/60 by wt%)
11
3.0
R407C
2.5
R22
2.0
1.5
1.0
0.5
0.0
DT ETA ETB
Operating conditions
140
HCFC-22 Evaporator
120
Pressure drop (kPa)
R407C Evaporator
100 HCFC 22 Condenser
80 R407C Condenser
60
40
20
0
DT ETA ETB
Operating conditions
zeotropic mixtures of R290 / R600a and R290 / R600 are used, the cooling
and heating capacities increase almost linearly with respect to mass fraction
of R290. COPs of the mixtures are found to be higher than linearly
interpolated values based on those of pure components. COP of hydro carbon
mixtures for the cooling condition is higher than that of R22 for a wide range
of composition of mixtures. Propane and mixtures as alternate refrigerant has
also been reported by various investigators like Treadwell (1994), Halozen et
al (1994), Richardson and Butterworth (1995), Kim et al (1994) and
Richardson and Ritter (1996). Lee et al 2002, Alok and Agarwal (1998),
Ritter (1996), Lee and Su (2002) and Horst and Florian (1997) also have
reported studies on HC.
The major set back reported with HCs is the flammability. James
and Missenden (1992) claimed that in case of the household refrigerators, the
possibility of explosion by flammability can be negligible because half the
amount of HCs can be charged compared to general CFC. Also, some simple
safety devices such as a ventilation system and a leak detector can be installed
to overcome the flammability problem in large sized air conditioning systems.
Extensive studies on flammability of hydrocarbons have been conducted by
Richard and Shanland (1992). Studies on the use of hydrocarbon in
refrigeration system have also been done by various investigators including
Chen et al (1994), Colbourne (2000) and Jung (1996).
portion of the evaporator provides only little contribution to the total cooling
capability. This practice also results in excessive evaporator volume.
A two TR(EER 10) off the shelf window air conditioner was
modified and tested by Mei et al,1996, with and without liquid overfeeding
(LOF) feature. A recuperative accumulator heat exchanger has been added
and the system charged with an additional 15% of R22 for additional piping.
Original components have not been replaced. LOF operation is reported to
improve the system cooling capacity and COP. At 28oF, LOF improves the
cooling capacity by 14% and COP by 10%. As ambient temperature
increases, the improvement decreases. At 43oF, the COP of the LOF becomes
equal to, or less than, that of the baseline unit. LOF has a lower compressor
pressure ratio, lower compressor discharge temperature, higher refrigerant
17
mass flow rate, slightly higher power consumption and slightly higher suction
pressure.
Bivens et al 1997 has tested heat pumps and water chillers with
accumulators (IHE). Commercial split type heat pump of capacity 8.8 kW
with scroll compressor, fin and tube heat exchangers, suction line accumulator
and thermostatic expansion valve have been used and the capacity of R407C
is found to be increased by 0.98% - 1.09% and COP by 0.94% - 0.97%,
compared to R22. Further, a water chiller of capacity 528 kW with screw
compressor, water inside tube shell and tube condenser and evaporator was
tested. The weight percentages of components (R23/R125/R134a) have been
fixed as 30/10/60. During this test, the capacity with the mixture (R407C) is
found to be reduced by 36% compared to operation with R22 due to a reduced
mixture heat transfer coefficient in the evaporator. Power required was
increased by 14% due to reduced mixture heat transfer coefficient in both the
evaporator and condenser (causing lower refrigerant evaporator temperature
and pressure and higher condenser pressure). The combined effect was a
reduction in COP of 44%.
Ref. Temperature
Refrigerants
Number glide (oC)
1 R22 0.00
2 23% R23/ 25% R125/ 52% R134a 6.64
(R407C, Du Pont’s AC9000)
3 26% R32/ 14% R125/ 60% R134a 6.87
4 26% R32/ 20% R125/ 54% R134a 6.74
5 50% R125/ 30% R134a/ 20% R152a 4.64
6 70% R125/ 10% R134a/ 20% R152a 4.85
7 75% R125/ 5% R134a/ 20% R152a 4.77
8 25% R32/ 71.5% R134a/ 3.5% R152a 10.91
9 26%R32/ 60% R134a/ 14% R152a 6.19
10 30% R125/ 60% R134a/ 10% R1270 6.08
11 33% R125/ 55% R134a/ 12% R1270 5.82
12 43.6% R125/ 45.9% R134a/ 10.5% R1270 5.40
13 30% R32/ 70% R134a 6.93
14 26% R32/ 74% R134a 6.77
15 45% R290/ 55% R134a 0.00
10
8
Change in COP (%)
6
4
2
0
-2 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
-4
-6
Refrigerants
5
4
4
Percentage
0
Pc Pe Pc/Pe ηi m P Qe Qc COP
-2
-4
5.0
4.5
Relative capacity variation
4.0
3.5
3.0
2.5
2.0
1.5
R134a
1.0
R22
0.5 R407C
0.0
3.5 4.0 4.5 5.0 5.5 6.0 6.5
Compression ratio with IHE
3.5
Relative variation of COP
3.0
2.5
2.0
1.5
1.0
0.5 R134a
0.0 R22
-0.5 R407C
-1.0
3.5 4 4.5 5 5.5 6 6.5
Compression ratio with IHE
From the literature review presented so far, the following are the
major conclusions.