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Galvanic Cells allow us to control the electron flow in a redox reaction to perform useful
work. Such cells find common use as batteries, pH meters, and as fuel cells. The setup of the
cell requires that the oxidation and reduction half-reactions are connected by a wire and by a
salt bridge. Electrons will flow through that wire creating an electrical current. The salt bridge
or porous disk allows the passage of ions in solution to maintain charge neutrality in each half-
cell.
The direction of the current in a cell is determined by the standard reduction potential
of each half-cell. For a reaction to be spontaneous, the overall cell potential must be positive.
Therefore, the half-reaction with the greater reduction potential will be a reduction and the
other half-reaction will be an oxidation. The electrode in the oxidation half-reaction is called
the anode. The electrode in the reduction half-reaction is called the cathode
The objective of this experiment is to measure the relative reduction potentials for several
half cell (redox) couples in galvanic cells, to develop an understanding of the movement of
electrons, anions and cations, to study factors affecting cell potentials and to estimate the
concentration of ions in solution using Nernst Equation.
Copper, zinc and iron metal strip, 0.1M Cu(NO3)2 solution, 0.1M Fe(NO3)2, 0.1M FeSO4,
1M CuSO4, 0.001M CuSO4, ammonia solution, voltmeter, wire, filter paper and beakers.
PROCEDURE
2) Cu – Fe :
E°cell = ECu - EFe
= 0.34- (-0.44)
=0.78 V
0.0592 0.1𝑀
Ecell = 0.78 - 2
log 0.1𝑀
= 0.78 V
3) Zn – Fe :
E°cell = ECu - EFe
= -0.44- (-0.79)
=0.35 V
0.0592 0.1𝑀
Ecell = 0.35 - 2
log 0.1𝑀
= 0.35 V
B. Effect of concentration changes on cell potential
1. Cell potential of “concentration cell” : 0.0083V
Anode reaction : Cu Cu2+ + 2e-
Cathode reaction : Cu2+ + 2e- Cu
A potential is recorded because the solution used has difference
concentration.
Dilution of Cu(NO3)2 :
Solution 1 Solution 2
E°cell = ECu – EZn E°cell = ECu – EZn
= 0.34- (-0.76) = 0.34- (-0.76)
= 1.10 V = 1.10 V
0.0592 0.1𝑀 0.0592 0.1𝑀
Ecell = 1.10 - log Ecell = 1.10 - log
2 0.1𝑀 2 0.001𝑀
= 1.10 V = 1.041 V
Solution 3 Solution 4
E°cell = ECu – EZn E°cell = ECu – EZn
= 0.34- (-0.76) = 0.34- (-0.76)
= 1.10 V = 1.10 V
0.0592 0.1𝑀 0.0592 0.1𝑀
Ecell = 1.10 - log Ecell = 1.10 - log
2 0.00001𝑀 2 0.0000001𝑀
= 0.982 V = 0.922 V
2. E cell versus log [Cu2+]
1.5
0.5
ECELL (V)
0
-60 -50 -40 -30 -20 -10 0
-0.5
-1
-1.5
LOG [CU2+]
4. The concentrations of Cu2+ and Zn2+ for the Cu-Zn cell to maximize the cell potential can
be adjusted by increase the concentration one of the solution.
DISCUSSIONS
In electrochemistry, redox reactions are a common term that used for oxidation and
reduction process that happen in a same time. Oxidation is when electron is lost and take
places in anode electron while reduction is when electron is gain at cathode electrode.
In this experiment, the interest of redox reaction was carried out for galvanic cell which consist
of voltmeter to measure it reduction potential with the presence of salt bridge as medium to
transfer electron from one solution to another solution.
From part A of this experiment, three metal strips were used as electrode with three different
solution with 0.1M respectively. The Ecell that measured by the voltmeter were compared with
the calculated Ecell by using formula,
The arrangement of the redox couples in decreasing order based on the results are:
For part B, the concentration used for the galvanic cell are different where CuSO4 solution with
0.1M and 0.001M are used as electrolyte. The electron will move from anode to cathode as
solution containing 0.001M Cu2+ will transfer electron to the one containing 0.1M Cu2+. Thus,
the electron transfer will produce more Cu2+ in the less concentrated solution and consume
Cu2+ in the more concentrated solution. Electron will continue to transfer until it reaches the
equilibrium concentration. On the other hand, the addition of NH3 to the solution makes Cu2+
ions flow from cathode to anode and the concentration of Cu2+ ions tend to decrease.
Nernst equation can be used to find the cell potential at any moment during a reaction or at
condition other than standard state.
0.0592 [𝑝𝑟𝑜𝑑𝑢𝑐𝑡]
Ecell = E°cell - log
𝑛 [𝑟𝑒𝑎𝑐𝑡𝑎𝑛𝑡]
In part A, this equation was applied, however the differences can be seen clearly in part C
since the molar concentration of electrolyte used were different. From Nernst equation, the
unknown concentration can be determined by plotting graph of Ecell versus log [Cu2+].
However, the expected Ecell from the experiment cannot be seen from the graph because the
intercept between line of Ecell measured and Ecell calculated is larger than expected
(0.018V).
This may due to some errors during the experiment. First, the solution used may be
contaminated with other solutions which affect its molarity. This can be overcome by use a
clear and dry beaker to transfer the solution from sample bottle. Next, the crocodile clippers
use may not be stable as it loses its sensitivity to the electric voltage and can be avoid by use
the clippers that in a good condition. Last but not least, the dilution of the electrolyte could
wrongly dilute from standard solution.
CONCLUSIONS
REFERENCES