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RADIOACTIVITY
One of the early workers with this phenomenon was Marie Curie. She experimented
with uranium compounds and discovered new elements such as polonium and radium.
These substances emitted invisible radiation that eventually killed her in 1934 from
overexposure.
Alpha particles (α) are helium nuclei. They have 2 protons and 2 neutrons existing
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together. [ 2 He ]
Cloud Chamber
Radioactivity can be detected by using by using a device called the diffusion cloud
chamber. The device consists of a cylinder chamber under which dry ice is placed.
Inside the chamber is filled with alcohol vapour, which is cooled about –65 oC by
using dry ice.
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When the radioactive source is placed close to the base, the inside is illuminated with
white vapour trails, which can be seen shooting from the source. The vapour trails
formed, shows the paths taken by the radiation and can be used to distinguish the type
of radiation present.
Some radioactive emissions are deflected by both electric and magnetic fields; the
diagram below shows the effects of magnetic fields on α particles, β particles and
γ rays.
Gamma (γ) rays are not affected by magnetic fields since they have no charge, hence
they do not deflect.
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Alpha (α) particles show a slight deviation to the left as shown in the diagram above.
By using Fleming Left Hand Rule we can determine that the alpha particles are
positively charged.
Beta (β) particles deviate to the right, which shows that they have a negative charge.
Note that alpha particles deviate less than beta particles because they are massive
compared to beta particles.
Nuclear Reactions
There are several types of nuclear reactions. These are
(i) Radioactivity decay,
(ii) Fusion and
(iii) Fission.
Radioactive Decay
If an isotope is radioactive it has an unstable arrangement in its nuclei. The emission
of alpha or beta particles can make the isotope more stable. This type of reaction
however alters the number of protons or neutrons in the nucleus making the nucleus
of a different element. The original nucleus is called the parent nucleus and the new
nucleus is called the daughter nucleus. (N.B. Further decay can also produce a
granddaughter nucleus.) The daughter nucleus and the emitting products are called
decay products.
When a nucleus decays by emitting alpha (α) particles, its atomic mass number (Z)
decreases by two and its mass number (A) decreases by four.
General Equation:
A A–4 4
Z X Z–2 Y + 2 He + ENERGY
parent daughter alpha
nuclide nuclide particle
Examples
α
4 4 4
2 Ra 2 Rn + 2 + energy
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4
2
U 4
2
Th + 4
2
α + energy
Beta Particle Decay
Beta emission causes the proton number (Z) to increase by 1, but the nucleon number
(A) does not change.
General Equation:
A 0
- 1β
A
Z X Z +1
Y + + ENERGY
parent daughter beta
nuclide nuclide particle
Examples
14 14 0
6 C 7 N + -1 β + energy
131
53
I 131
54
Xe + 0
-1
β + energy
With some isotopes the emission of alpha particles and/ or beta particles leaves the
neutrons and protons in an excited arrangement. As the protons and neutrons arrange
themselves into a more stable arrangement they lose energy. This energy is emitted as
a burst of gamma radiation. Gamma radiation does not cause changes in the mass
number (A) or the atomic number (Z) of the isotope.
Half-Life
The half-life of a radioactive substance is the time taken for half of the unstable atoms
to decay (decrease by half of its original mass).
N.B.
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ISOTOPE HALF-LIFE
Radon-220 52 seconds
Iodine-128 25 minutes
Examples
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much of the isotope will remain in her body after 24 days assuming none is
expelled form the body?
Decay Curve
If a radioactive source has a short half-life, apparatus can be used to obtain data to
plot a decay curve. It is not easy to measure the number of nuclei in a sample of
radioactive material but the rate of decay can be used to indicate how much of the
nuclei is present.
To plot a radioactive decay curve we need to find the value for the background count,
this would be subtracted from each reading obtained. Readings are then taken at
regular intervals and the corrected count rate is plotted against the time. We can then
use the graph to find the half-life of the substance.
Fusion
This occur when two small nuclei join together to form a larger one. Energy is
released in the process and Einstein’s formula can be used to calculate the energy
released.
In fusion:
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Fission
This occurs when a large nucleus splits into two roughly equal smaller ones with the
release of energy. This energy is the result of matter converting into energy. We can
therefore use Einstein’s equation to calculate the amount of energy to the quantity of
matter converted. (E = mc2)
In fission:
1 light particle + 1 heavy particle 2 less heavy particles about the same mass +
energy
235 1 144 90 1
92
U + 0
n 56
Ba + 36
Kr + 2 0
n
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