Professional Documents
Culture Documents
Definition
Many definitions
– Mechanical compaction
– Chemical compaction
• Thus:
– Coarse clastics: rapid porosity loss early in
burial slowing down rapidly
– Fine clastics rapid porosity loss at depth.
Authigenic cementation
• Allogenic: during deposition
• Authigenic grown in situ during diagenesis
•Also clays
•Chlorite, smectite
Timing of reprecipitation is
important:
• First mineral to form = limonite (yellow)
which matures to become crystalline
haematite Fe2O3
• Once formed, red colour may be leached
by later fluids unless protected from
further diagenesis: best is quartz
overgrowths.
Aeolian Red Beds
• Infiltration of wind-blown dust (mainly
siliceous but contains iron oxides)
• A lot of fine silica abrasion dust is
generated in deserts:
– Good source of silica for precipitation of
protective quartz overgrowths.
Subsurface sandstone diagenesis
Subsurface sandstone diagenesis
• Sand horizons: fluid pathways especially for
fluids from compacting mudstones
• Fluids carry dissolved ions (cements)
• The compacting sands can be a long distance
from shales (10’s of km)
As sand compacts…
• VLF’s Æ smectite
Result
• Thus:
– Any sand rich in feldspars and VLF’s generates
a lot of clay generated in diagenesis.
– Clays flatten to form a matrix: reduces
permeability of the sedimentary rock.
– Micas and mudstone clasts also flatten and
deform to reduce permeability (bend around
grains)
Brief review of cements
• Silica
• Clays
• Carbonates
Silica
• Dissolution of quartz
• Dissolution of feldspars
• Clay transformation (Smectite Æ Illite)
• Illite
– Forms hair-like
threads
– Low overall
volume: porosity
not reduced much
– Form matted webs:
permeability
reduced
Authigenic illite cement in Lower
Permian Rotliegendes sandstone,
North Sea: c. 1.9km
Poroperm
• Smectite
(montmorillonite)
– Forms honeycombe
structures
– Some reduction of
both porosity and
permeability
Material Composition
← Increasing micritization
Corraline algae High Mg calcite
Halimeda Aragonite
Corals Aragonite
• Shallow Marine
• Supertidal
– Phreatic environment
– Vadose environment
Shallow Marine cementation
• Forms ISOPACHOUS/ SYNTAXIAL CEMENT
– Crystals have same orientation as fossil on which they
grow
droplets of cement
Concretions
• Carbonate concretions common in shales
• Form before compaction (bedding visible within
them)
• Oriented parallel to bedding
• Uncertain origin:
– Organic material common in concretions
– Disintegration produces alkaline conditions locally
(NH3) decreasing CaCO3 solubility
– No depletion of CaCO3 ever demonstrated around
concretions: dubious theory
(b) Subaerial carbonate
diagenesis
• Second largest area of carbonate diagenesis
• Most important process is cementation
• Occurs when calcareous muds elevate
above water and meteoric waters attack it
METEORIC WATER
HUMIC ACID
SOIL
CALCAREOUS
MUD
13
C
(c) Subsurface cementation and
diagenesis
• Absolute mechanisms not fully understood
• Cementation occurs continuously: new term
applied – Lithification: production of a solid
limestone with no porosity
• However:
– Modern lst muds have 40 – 70% φ whilst lsts
never have >5%
– Cannot be blamed on compaction (delicate
fossils preserved)
– Where does the CaCO3 come from to close the
space?
Pressure Solution and
Stylolitization
• P.S. is a popular choice for pore closure
– Any strained part of a crystal becomes highly soluble:
– CaCO3 migrates to areas of lower energy
• Stylolites: impurities in the lsts along a layer
become stress razors (pressure points)
– Interpenetration occurs (see graphic next)
– Definitely a solution phenomenon since stylolites can
cut fossils
– Material dissolved is a calcite source
Measurements in the local U.W.L. show 30%
thickness reduction due to stylolitization
a and c terminate
(b)
(a)
Triple Junctions
• Boundary of 3 crystal faces.