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SAFETY DATA SHEET

Product Name: SWANCOR 1306

1、IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY


PRODUCT NAME:SWANCOR 1306

PRODUCT NO:UN1866

SUPPLIER: SWANCOR IND. CO., LTD.


NO. 9 INDUSTRY SOUTH 6 ROAD,
NAN-KANG INDUSTRIAL PARK,
NAN-TOU CITY, TAIWAN 54066 R.O.C.
TEL: 886-49-2255420
FAX: 886-49-2251534
E-MAIL: nantou@swancor.com

EMERGENCY TELEPHONE:886-49-2255420

2、HAZARDS IDENTIFIACTION
HAZARDS TO CLASSIFY:Flammable liquids to 3 class、Acute toxicity (Oral) to 5 class corrosion/irritation to SECOND class、
Serious eye damage/eye irritation to 2A class、Specific target organ toxicity - Repeated exposure to 2 class 、Aute toxicity to the
aquatic environment to 2 class。

LABELLING:

WARN:DANGER
WARN INFORMATION:
Flammable liquid and vapor
May be harmful if swallowed
Causes skin irritation
Causes serious eye irritation
May damage fertility or the unborn child
Causes damage to respiratory, liver, central nervous system, kidney May cause drowsiness or dizziness
Causes damage to respiratory, nervous system through prolonged or repeated exposure
May be harmful if swallowed and enters airways
Toxic to aquatic life
Toxic to aquatic life with long lasting effects
EMERGENCY OVERVIEW:
Straw-yellow viscous liquid. Pungent XYLENE odor. Flammable. Reactive. Causes eye irritation. Highly toxic to fish and/or other
aquatic organisms
POTENTIAL HEALTH EFFECTS:
Refer to Section XI for toxicological data, Effects of Overexposure: for Xylene
EYE CONTACT:
May cause moderate eye irritation. May cause slight corneal injury. Vapors may irritate eyes. Vapors may cause lacrimation (tears).
SKIN CONTACT:
Prolonged or repeated exposure may cause skin irritation. Material may stick to skin causing irritation upon removal. A single
prolonged exposure is not likely to result in the material being absorbed through skin in harmful amounts.
INGESTION:
Single dose oral toxicity is considered to be low. If aspirated (liquid enters the lung), may be rapidly absorbed through the lungs and
result in injury to other body systems.
INHALATION:
Excessive vapor concentrations are attainable and could be hazardous on single exposure. Signs and symptoms of excessive
exposure may be anesthetic or narcotic effects and result in injury to other body systems.

SYSTEMIC (OTHER TARGET ORGAN) EFFECTS:


Contains XYLENE, which, in animals, has been reported to cause effects on the following organs; central nervous system, kidney,
liver and reparatory tract. Lung effects have been observed in mice following repeated exposure to XYLENE. however, the relevance
of this to humans is unknown. Some studies in humans allege that repeated exposure to XYLENE may result in minor subclinical
decreases in the ability to discriminate between colors.

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Product Name: SWANCOR 1306

CANCER INFORMATION:
This mixture contains a component (s) which are listed as potential carcinogens for hazard communication purposes under OSHA
Standard 29 CFR 1910.1200. Component(s) listed by IARC; XYLENE. An increased incidence of lung tumors was observed in mice
from a recent inhalation study on XYLENE. The relevance of this finding to humans is uncertain since data from other long-term
animal studies and from epidemiology studies of workers exposed to XYLENE do not provide a basis to conclude that XYLENE is
carcinogenic.
TERATOLOGY:
In laboratory animals, XYLENE did not produce birth defects or any other effects on the fetus even at exposure concentrations having
an adverse effect on the mother.
REPRODUCTIVE EFFECTS:
Contains component(s) which did not interfere with reproduction in animal studies. The component(s) is/are: XYLENE.

OTHER:

3、COMPOSITION ON INGREDIENTS
NAME:SWANCOR 1306 Vinyl Ester Resin Accelerator

INGREDIENTS (%) :
2-Butoxyethanol :0~5%(111-76-2 25)
Cobalt 2-Ethylhexanoate :15~30% (136-52-7)
Mineral Spirits: 10~30%
Di-methyl aniline:15~20% (121-69-7)
Xylene:35~45% (1330-20-7)

4、FIRST AIDS MEASURES


SKIN CONTACT:
Thoroughly wash exposed area with soap and water immediately. Remove contaminated clothing. Launder contaminated clothing
before re-use.
EYE CONTACT:
Flush with large amount of water immediately and continuously for 20 minutes, lifting upper and lower lids occasionally. Get medical
attention.
INGESTION:
Do not induce vomiting. Keep person warm, quiet and get medical attention. Aspiration of material into the lungs can cause chemical
pneumonitis which can be fatal.
INHALATION:
If affected, remove individual to fresh air. If breathing is difficult, administer oxygen. If breathing has stopped, give artificial respiration.
Keep person warm, quiet, and get medical attention
NOTE TO PHYSICIAN:
Because rapid absorption may occur through lungs if aspirated and cause systemic effects, the decision of whether to induce vomiting
or not should be made by an attending physician. If lavage is performed, suggest endotracheal and/or exophageal control. Danger
from lung aspiration must be weighed against toxicity when considering emptying the stomach. No Specific antidote. Supportive care.
Treatment based on judgment of the physician in response to reactions of the patient.

5、FIRE FIGHTING MEASURES


HAZARDOUS DECOMPOSITION PRODUCT:
May form toxic materials: carbon dioxide and carbon monoxide, various hydrocarbons.
OTHER FLAMMABILITY INFORMATION:
Dense smoke is produced when product burns. Violent steam generation or eruption may occur upon application of direct water
stream. Vapors are heavier than air and may travel a long distance and accumulate in low areas. Ignition and/or flash back may
occur. Flammable mixtures may exist within the vapor space of containers at room temperature. Flammable concentrations of vapor
can accumulate at temperatures above 74oF. Spills of these organic liquids on hot fibrous insulations may lead to lowering of the auto-
ignition temperatures possibly resulting in spontaneous combustion.
EXTINUISHING MEDIA:
Water fog or fine spray, carbon dioxide, dry chemical, foam. Water fog, applied gently may be used as a blanket for fire
extinguishments. General purpose synthetic foams (including AFFF type) or protein foams are preferred if available. Alcohol resistant
foams (ATC type) may function. Do not use direct water stream, straight or direct water. Stream may not be effective to extinguish
fire.
MEDIA TO BE AVOIDED:

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Product Name: SWANCOR 1306

Do not use direct water stream.


FIRE FIGHTING INSTRUCTIONS:
Keep people away. Isolate fire area and deny unnecessary entry. Burning liquids may be moved by flushing with water to protect
personnel and minimize property damage. Water fog, applied gently may be used as a blanket for fire extinguishments. Eliminate
ignition sources. Stay upwind. Keep out of low areas where gases (fumes) can accumulate. Do not use direct water stream. May
spread fire. Water may not be effective in extinguishing fire. Move container from fire area if this is possible without hazard.
PROTECTIVE EQUIPMENT FOR FIRE FIGHTERS:
Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet,
coat, pants, boots, and gloves). If protective equipment is not available or not used, fight fire from a protected location or safe
distance.

6、ACCIDENTAL RELEASE MEASURES


PROTECT PEOPLE:
Do not breathe vapors. Vapor explosion hazard, keep out of sewers. Eliminate all sources of ignition in vicinity of spill or released
vapor to avoid fire or explosion. For large spills, warn public of downwind explosion hazard. Check area with explosion meter before
reentering area. Ground and bond all containers and handling equipment
PROTECT THE ENVIRONMENT:
For large spills, evacuate upwind of spills and contain with dike.
CLEANUP:
Pump with explosion-proof equipment. If available use foam to smother and suppress. Remove residual with hot soapy water.
Residual can be removed with solvent. Solvents are not recommended for cleanup unless the recommended exposure guide-lines
and safe handling practices for the specific solvent are followed. Consult appropriate solvent MSDS for handling information and
exposure guidelines.

7、HANDLING AND STORAGE


HANDLING INFORMATION:
Avoid inhalation and contact with eyes, skin, and clothing. Wash hands thoroughly after handling and before eating or drinking.
Remove and wash contaminated clothing before reuse. Use with adequate ventilation. Ground and bond containers when
transferring the material to prevent static electricity sparks which could ignite the vapor. Use spark-proof tools and explosion-proof
equipment. Consult your supplier or promoters and catalysts for additional instructions on proper mixing and usage.

Empty containers may retain product residue (liquid and/or vapor). Do not pressurize, cut, weld, braze, solder, drill, grind, or expose
these containers to heat, flame, sparks, static electricity, or other sources of ignition as the container may explode and may cause
injury or death. Empty drums should be completely drained and properly bunged. Empty drums should be promptly returned to a drum
re-conditioner or properly disposed.

STORAGE INFORMATION:
Keep away from ignition sources; flames, pilot lights, electrical sparks, and sparking tools. NO SMOKING. Do not store in direct
sunlight. Store separate from oxidizing materials, peroxides, and metal salts. Keep container closed when not in use. To ensure
maximum stability and maintain optimum resin properties, resins should be stored in closed containers at temperatures below 75
degrees F (25 degrees C). Copper or copper containing alloys should be avoided as containers.

8、EXPOSURE CONTROLS/PERSONAL PROTECTION


EXPOSURE GUIDELINE(S):Control parameters, eg, occupational exposure limit values or biological limit values ACGIH2005, TLV-
TWA 100ppm A3 (o, m & p isomers) TLV-STEL 150ppm A4 (o, m & p isomers) Appropriate engineering controls (Please refer to
engineering controls described in "7.1 Precautions for safe handling".) Individual protection measures, such as personal protective
equipment (Please refer to Individual protection measures described in "7.1 Precautions for safe handling".)

PEOPLE P:
PROTECTIVE GLOVES:
Wear resistant gloves such as: neoprene, nitrite rubber.
EYE PROTECTION:
Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA regulations also permit other type safety
glasses (consult your safety equipment supplier).
OTHER PROTECTIVE EQUIPMENT:
Normal work clothing covering arms and legs.

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Product Name: SWANCOR 1306

9、PHYSICAL AND CHEMICAL PROPERTIES


APPEARANCE: Purple liquid. ODOR:

ODOR THRESHOLD: MELTING POINT:-13℉/-25℃

pH : BOILING POINT:279℉~/137℃

FLAMMABILITY: FLASH POINT:77℉/ 25℃

DECOMPOSITION TEMPERATURE:

AUTOIGNITION TEMPERATURE:981℉/527℃ EXPLOSIVE LIMITS:1.0%~7.0%

VAPOR PRESSURE:6.25mmHg @20℃ VAPOR DENSITY:3.66 g/l

SPECIFIC GRAVITY:0.93 ± 0.02 / 25℃ SOLUBILITY :

PARTITION COEFFICIENT N-OCTANOL/WATER:3.12~3.20 EVAPORATION RATE :0.7

10、STABILITY AND REACTIVITY


HAZARDOUS POLYMERIZATION:
May occur.
STABILITY:
Stable at room temperature.
INCOMPATIBILITY:
Strong alkalis, strong mineral acids and oxidizing agents.
CONDITIONS TO AVOID:
o o
Exposure to excessive heat or direct sunshine or open flame; storage in open containers; storage above 38 C (100 F). Contamination
with oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon Monoxide, Carbon Dioxide, Low Molecular Weight Hydrocarbon, Organic Acids.

11、TOXICOLOGICAL INFORMATION
Acute toxicity (Oral)

Based on the rat LD50 (oral route) value of 3,500 mg/kg representing the lower of the two testing data, 3,500mg/kg
(CaPSAR, 1993) and 4,300mg/kg (MOE Risk Assessment Vol. 1, 2002).

May be harmful if swallowed (Acute toxicity (Oral) Category 5 )

Acute toxicity (Dermal)

No definitive value available, although the substance can be classified as Category 5 or not classified based on the
rabbit LD 50 (dermal route) value of >4,350 mg/kg, (IUCLID 2000).

Acute toxicity (Inhalation: Gases)

Due to the fact that the substance is "liquid" according to the GHS definition and inhalation of its gas is not expected.

Acute toxicity (Inhalation: Vapours)

Based on the rat LC50 (4 hour inhalation exposure) value of 29.08 mg/L (MOE Risk Assessment Vol.1, 2002)
(equivalent to 6,700ppm) was lower than 90% of the saturated vapor concentration (8,000ppm) under a saturated
vapour pressure of 0.8 kPa (20degree C), the substance was considered as "vapour containing substantially no mist"
and was classified based on standard values expressed in ppm.

Acute toxicity (Inhalation: Dusts / Mist)

No data available

Skin corrosion / irritation

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Product Name: SWANCOR 1306

Based on the description in the report on the rabbit skin irritation test (CERI-NITE Hazard Assessment No.62, 2004):
"moderate irritant".

Causes skin irritation (Skin corrosion/irritation Category 2 )

Serious eye damage / eye irritation

Based on the description in the report on the rabbit eye irritation test (CERI-NITE Hazard Assessment No.62, 2004):
"moderate irritant".

Causes serious eye irritation (Serious eye damage/eye irritation Category 2A )

Respiratory sensitization / Skin sensitization

Respiratory sensitizer: No data available Skin sensitizer: No data available

Germ cell mutagenicity

Based on the negative data on human multi-generation epidemiological studies and somatic cell mutagenicity tests in
vivo (micronucleus/chromosome tests) and the absence of data on heritable mutagenicity tests, germ cell mutagenicity
tests in vivo and germ cell genotoxicity tests in vivo, described in CERI-NITE Hazard Assessment No.62 (2004),
CaPSAR (1993), IARC (1999) and NTP DB (Access on December 2005).

Carcinogenicity

Due to the fact that the substance is classified as Category A4 by ACGIH (2001) and Group 3 by IARC (1999).

Reproductive toxicity

Based on the evidence of weight reduction and hydrocephalus in foetuses at dosing levels not toxic to parent animals
in mouse developmental toxicity tests, described in CERI-NITE Hazard Assessment (No. 62, 2004), EHC 190 (1997)
and IRIS (2003).

May damage fertility or the unborn child (Reproductive toxicity Category 1B )

Specific target organ toxicity - Single exposure

Based on the human evidence including "throat irritation, severe pulmonary congestion, alveolar hemorrhage,
pulmonary edema, congestion accompanying hepatomegaly, centrilobular vacuolation of hepatocytes, nerve cell
damage associated with dot hemorrhage, swelling and disappearance of Nissl bodies, limb cyanosis, a transient
increase in serum transaminase activity, an increase in the blood level of urea, a decrease in endogenous creatinine
clearance in the urine, liver damage, severe kidney damage, amnesia, coma" (CERI-NITE Hazard Assessment No.62,
2004) and "pulmonary congestion, pulmonary edema, focal alveolar hemorrhage" (MOE Risk Assessment Vol.1, 2002)
and the evidence from animal studies including "strong narcotic effect (EHC 190, 1997). The basis for the classification
includes data on xylene with unknown composition or containing other substances (ethyl benzene, toluene, etc.).

Causes damage to respiratory, liver, central nervous system, kidney May cause drowsiness or dizziness (Specific
target organ toxicity - Single exposure Category 1(respiratory, liver, central nervous system, kidney), 3(drowsiness and
dizziness) )

Specific target organ toxicity - Repeated exposure

Based on the human evidence including "eye/nose irritation, thirst" (DFGOT Vol. 15, 2001) and "chronic headache,
chest pain, abnormal electroencephalogram, dyspnea, cyanosis of the hands, fever, a decrease in WBC count,
discomfort, impairment of pulmonary function, a decrease in working capacity, physical/mental disorders" (CERI-NITE
Hazard Assessment No.62, 2004). The basis for the classification includes data on xylene with unknown composition
or containing other substances (ethyl benzene, toluene, etc.).

Causes damage to respiratory, nervous system through prolonged or repeated exposure (Specific target organ toxicity
- Repeated exposure Category 1(respiratory, nervous system) )

Aspiration hazard

Based on the description in ICSC(J) (2002) regarding o-xylene, m-xylene and p-xylene: "May cause aspiration and
chemical pneumonia if swallowed".

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Product Name: SWANCOR 1306

May be harmful if swallowed and enters airways (Aspiration hazard Category 2 )

12、ECOLOGICAL INFORMATION
ENVIRONMENTAL FATE:
LC50:3.3mg/L /96H
EC50:----
BCF:------

DEGRADATION & PERSISTENCE:


Based on information for XYLENE. Material is readily biodegradable. Passes OECD test(s) for ready biodegradability. Material is
ultimately biodegradable. Reaches more than 70% mineralization in OECD test(s) for inherent biodegradability.

13、DISPOSAL CONSIDERATIONS
Description of waste residues and information on their safe handling and methods of disposal
If you would like to dispose of this chemical, you should properly dispose of this by yourself or ask qualified specific agents dispose of
this according to related legislations and local regulations. If you would like to ask the agents dispose of this chemical, you should
provide sufficient information on dangerousness and hazard of this chemical.
the disposal of any contaminated packaging
Container should be recycled after cleaning or if you would like to dispose of container of this chemical, you should properly dispose
of this by yourself or ask qualified specific agents dispose of this according to related legislations and local regulations. If you would
like to ask the agents dispose of this container, you should provide sufficient information on dangerousness and hazard of this
chemical in this container and information on ingredient and notice of container.

14、TRANSPORT INFORMATION
UN NO:1866

UN TRANSPORT NAME: RESIN SOLUTION

Hazard Class: 3
PG:III

SEA POLLUTANTS:(YES / NO):NO

15、REGULATORY INFORMATION
OSHA STATUS:
This material is classified as a hazardous chemical under the criteria of the US Occupational Safety and Health Administration
(OSHA) Hazard Communication Standard, 29 CFR 1910.1200.
TSCA EXPORT NOTIFICATION:
This material does not contain any components that are subject to the US Toxic Substances Control Act (TSCA) Section 12(b) Export
Notification requirements.
TSCA INVENTORY STATUS:
All components of this material are listed on the US the Toxic Substances Control Act (TSCA) inventory.
EUROPEAN/INTERNATIONAL REGULATIONS:
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 10: Flammable
R 36/38: Irritating to eyes and skin.
R 20: Harmful by inhalation.
Safety Phrases:
S 23: Do not inhale gas/fumes/vapor/spray.
CALIFORNIA PROPOSITION 65:
WARNING: This product contains a chemical(s) known to the State of California to cause cancer. XYLENE Oxide.
CAA:
XYLENE (1330-20-7) is listed as a Hazardous Air Pollutant (HAP) under Section 112 of the Clean Air Act.
CWA:
XYLENE (1330-20-7) is listed under Section 311 as a Hazardous Substance.
CANADA WHMIS:

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Product Name: SWANCOR 1306

This material is classified by the Canadian Workplace Hazardous Material Information System as: B2 (flammable liquid) D2A
(materials causing other toxic effects, very toxic material) D2B (materials causing other toxic effects, toxic material)
CANADA CEPA:
All components of this material are listed on the Canadian Domestic Substances List (DSL).
ADDITIONAL CANADIAN REGULATORY INFORMATION:
Under the Transportation of Dangerous Goods regulations, the following Chemicals have been assigned Regulated Limits (RL):
XYLENE (CAS # 1330-20-7): RL=50 KG.

The following chemicals are listed on the WHMIS Ingredient Disclosure List:
XYLENE (CAS # 1330-20-7)

The following chemical (s) are listed on the Canadian National Pollutant Release Inventory (NPRI):
XYLENE (CAS # 1330-20-7)

16、OTHER INFORMATION
REVISION:R&D NAME:SWANCOR 1306

ADD/TEL:SWANCOR IND. CO., LTD.


NO. 9 INDUSTRY SOUTH 6 ROAD,
NAN-KANG INDUSTRIAL PARK,
NAN-TOU CITY, TAIWAN 54066 R.O.C.
/886-49-2255420
PREPARED BY: MONICA HSIES SDS NO. :NT27-021-E

DATE:2014.03.28 HAZARD RATING: Health 2 / Flammability 3 / Reactivity 0

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