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PART : CHEMISTRY
1. Excessive release of CO2 into the atmosphere results in :
(1) global warming (2) polar vortex (3) formation of smog (4) depletion of ozone
i;kZoj.k esa CO2 dk vR;f/kd fuLltZu dk ifj.kke gS %
(1) HkweaMyh; rkiu (2) /kqzoh; Hkzfey (vortex) (3) /kwezdqgk dk cukuk (4) vkstksu dk vo{k;
Ans. (1)
Ans. (4)
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Ans. (2)
In sucrose two monosaccharides are joined together by an oxide linkage formed by loss of water
molecule. Such linkage through oxygen atom is called glycosidic linkage. In sucrose linkage in between
C1 of -glucose and C2 of -fructose. Since the reducing group of glucose & fructose are involved in
glycosidic bond formation, sucrose is non reducing sugar.
C1 –D-glucose + C2 –D-fructose
-D-Glucose -D-Fructose.
lqØksl vipk;d 'kdZjk ugha gksrh gSA mnkgj.k ds fy, ;g Qsgfyax foy;u ;k VkWysu vfHkdeZd dks vipf;r ugha djrs gSA ;g vkWfDle ;k
vkslktksu ugha cukrs gS] rFkk E;wVkjksVs'ku ugha n'kkZrs gSA ;g n'kkZrk gS fd oy; esa gsfe,flVsy leqg mifLFkr ugha gksrk gSA
-Xywdksl + -ÝDVksl
H3 O
lqØksl (b{kq 'kdZjk )
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6. The number of water molecule(s) not coordinated to copper ion directly in CuSO4.5H2O, is :
CuSO4.5H2O esa] dkWij vk;u ds lkFk lh/ks :i ls milgla ;ksftr ugha gksus okyk@okys ty ds v.kq¼vksa½ dh la[;k
gS %
(1) 2 (2) 4 (3) 3 (4) 1
Ans. (4)
Sol. In CuSO4.5H2O, Four water molecules form coordinate bond with Cu2+ ion while one water molecule is
associated with H-bond.
CuSO4.5H2O esa ty ds pkj v.kq Cu2+ vk;u ls milgla ;kstd ca/k }kjk cfU/kr gks rs gS tcfd ,d ty dk v.kq
H-ca/k }kjk cfU/kr gks rk gSA
A B C D
(1) D < A < C < B (2) A < B < C < D (3) D < B < A < C (4) B < C < A < D
Ans. (1)
10. The osmotic pressure of a dilute solution of an ionic compound XY in water is four times that of a
solution of 0.01 M BaCl 2 in water. Assuming complete dissociation of the given ionic compounds in
water, the concentration of XY (in mol L–1) in solution is :
ty esa ,d vk;fud ;kSfxd XY ds ruq foy;u dk ijklj.kh; nkc] 0.01 M BaCl2 ds ty esa foy;u ds ijklj.kh;
nkc dk pkj xquk gSA fn, x;s vk;fud ;kSfxdksa dk ty esa fo;kstu iw.kZ ekurs gq,] foy;u esa XY dh lkUnzrk
(mol L–1 esa ) gksxh %
(1) 6 × 10–2 (2) 4 × 10–2 (3) 16 × 10–4 (4) 4 × 10–4
Ans. (1)
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Sol. xy = 4BaCl2
i[XY] = 4 × i × [BaCl2]
2 × [XY] = 4 × 3 × 0.01
[XY] = 0.06M
11. The correct order of the oxidation states of nitrogen in NO, N2O, NO2 and N2O3 is
NO, N2O, NO2 rFkk N2O3 esa ukbVªkstu dh vkWDlhdj.k voLFkkvksa dk lgh Øe gS %
(1) NO2 < N2O3 < NO < N2O (2) N2O < N2O3 < NO < NO2
(3) N2O < NO < N2O3 < NO2 (4) NO2 < NO < N2O3 < N2O
Ans. (3)
Sol.
Nirtrogen Oxide Ox.state of Nitrogen
N2O +1
NO +2
N2O3 +3
NO2 +4
12. Consider the van der Waals constants, a and b, for the following gases.
Gas Ar Ne Kr Xe
a/(atm dm6 mol –2) 1.3 0.2 5.1 4.1
b/(10–2 dm3 mol–1) 3.2 1.7 1.0 5.0
Which gas is expected to have the highest critical temperature ?
fuEufyf[kr xSlksa ds okUMjokYl fLFkjkad a rFkk b ij fopkj dhft, %
xSl Ar Ne Kr Xe
a/(atm dm6 mol –2) 1.3 0.2 5.1 4.1
b/(10–2 dm3 mol–1) 3.2 1.7 1.0 5.0
fuEufyf[kr esa ls fdlds fy, Økafrd rki ds lokZf/kd gksus dh laHkkouk gksxh \
(1) Kr (2) Xe (3) Ne (4) Ar
Ans. (1)
a
Sol. TC
b
13. The given plots represent the variation of the concentration of a reactant R with time for two different
reactions (i) and (ii). The respective orders of the reactions are :
(i) (ii)
In [R] [R]
time time
uhps fn;s x;s IykV] nks vfHkfØ;kvksa (i) rFkk (ii) ds fy,] vfHkdeZd R dh lkUnzrk dk le; ds lkFk gksus okys ifjorZu
dks fu:fir djrs gSaA vfHkfØ;kvksa ds Øfed dksfV gSa %
(i) (ii)
In [R] [R]
le; le;
(1) 0, 2 (2) 1, 0 (3) 0, 1 (4) 1, 1
Ans. (2)
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Sol. For zero order
C A C A 0 – kt
for first order
C A C A 0 e kt
CA
or, ln = – kt
C A0
or, ln CA – ln C A 0 = – kt
or, ln CA = ln C A 0 – kt
Sol. 'kwU; dksfV ds fy,
C A C A 0 – kt
izFke dksfV ds fy,
C A C A 0 e kt
CA
or, ln = – kt
C A0
or, ln CA – ln C A 0 = – kt
or, ln CA = ln C A 0 – kt
14. The standard Gibbs energy for the given cell reaction in kJ mol–1 at 298 K is :
Zn(s) + Cu2+(aq) Zn2+(aq) + Cu(s).
Eº = 2 V at 298 K
(Faraday's constant, F = 96000 C mol –1)
fn;s x;s lsy vfHkfØ;k ds fy, 298 K ij ekud fxCl ÅtkZ (kJ mol–1 esa) gS %
Zn(s) + Cu2+(aq) Zn2+(aq) + Cu(s).
298 K ij Eº = 2 V
(QSjkMs fLFkjkad] F = 96000 C mol –1)
(1) 384 (2) –384 (3) –192 (4) 192
Ans. (2)
Sol. Gº = – nF ECellº
= – 2 × 96000 × 2.0 × 10–3 = –384 kJ/mol
15. Liquid 'M' and liquid 'N' form an ideal solution. The vapour pressures of pure liquids 'M' and 'N' are 450
and 700 mmhg, respectively, at the same temperature. Then correct statement is :
(xM = Mole fraction of 'M' in solurtion;
xN = Mole fraction of 'N' in solution;
yM = Mole fraction of 'M' in vapour phase;
yN = Mole fraction of 'N' in vapour phase;)
nzo 'M' rFkk nzo 'N' ,d vkn'kZ foy;u cukrs gSaA 'kq) nzo 'M' rFkk 'N' ds ok"i nkc mlh rki ij Øe'k% 450 rFkk
700 mmhg gSa rks lgh dFku gS %
tgk¡ xM = foy;u esa 'M' dk eksyj va'k (
xN = foy;u esa 'N' dk eksyj va'k (
yM = ok"i voLFkk esa 'M' dk eksyj va'k (
yN = ok"i voLFkk esa 'N' dk eksyj va'k (
x y
(1) M M (2) (xM – yM) < (xN – yN)
x N yN
xM yM xM yM
(3) (4)
xN yN xN yN
Ans. (3)
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Sol. Mole fraction of more volatile component increase in vapour phase. PNº PMº
Sol. ok"i izkoLFkk esa vf/kd ok"i'khy ?kVd dk eksy izHkkt vf/kd gksrk gSA
PNº PMº
16. The ore that contains the metal in the form of fluoride is :
(1) Magnetite (2) Sphalerite (3) Malachite (4) Cryolite
v;Ld ftlesa /kkrq ¶yksjkbM ds :i esa gS] og gS %
(1) eSXusVkbV (2) LQSysjkbV (3) eSysdkbV (4) Økb;ksykbV
Ans. (4)
Sol. Sphalerite ¼LQsysjkbV½ – ZnS
Magnetite (eSXusVkbV) – Fe3O4
Malachite ¼esysdkbV½ – CuCO3 Cu(OH)2
Cryolite ¼Økb;ksykbV½ Na3 AlF6 .
17. Among the following, the molecule expected to be stabilized by anion formation is :
C2, O2, NO, F2
fuEufyf[kr esa ls] v.kq ftldh _.kk;u cudj LFkk;hÛÑr gksu dh laHkkouk gS] og gS %
C2, O2, NO, F2
(1) C2 (2) O2 (3) NO (4) F2
Ans. (1)
Sol. C 2– : (1s)2 (*1s)2 (2s)2 (*2s)2 (2p2x = 2p2y) or KK (2s)2 (*2s)2 (2p2x = 2p2 y) 2P1z
1
Bond order : (9 – 4) = 2.5
2
O 2– : (1s)2 (*1s)2 (2s)2 (*2s)2 (2pz)2 (2p2x = 2p2y) (*2px2 = *2p1y)
1
Bond order : (10 – 7) = 1.5
2
F2– : (1s)2 (*1s)2 (2s)2 (*2s)2 (2pz)2 (2p2x = 2p2y ) (*2px2 = *2p2y) 2P1z
1
Bond order : (10 – 9) = 0.5
2
NO– : (1s)2 (*1s)2 (2s)2 (*2s)2 (2pz)2 (2p2x = 2p2y) (*2px1 = *2p1y)
1
Bond order : (10 – 6) = 2.0
2
Bond order Stability
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19. Aniline dissolved in dilute HCl is reacted with sodium nitrite at 0ºC. This solution was added dropwise to
a solution containing equimolar mixture of aniline and phenol in dil. HCl. The structure of the major
product is :
ruq HCl esa ?kqyh gqbZ ,sfuyhu dks lkfM;e ukbVªkbV ds lkFk 0ºC ij vfHkfØf;r fd;k tkrk gSA bl foy;u dks
,sfuyhu rFkk fQukWy ds leeksyh; feJ.k ds ruq HCl foy;u esa cwan&cwan djds feyk;k tkrk gSA eq[; mRikn dh
lajpuk gS %
Ans. (2)
OH NH2
NH2 N2
+ , H+
NaNO HCl
Sol.
2
N=N NH2
0C
20. Among the following, the set of parameters that represents path function, is :
(A) q + w (B) q (C) w (D) H – TS
(1) (A) and (D) (2) (A), (B) and (C) (3) (B) and (C) (4) (B), (C) and (D)
fuEufyf[kr eas ls] izkpyks dk og leqPp; tks iFk Qyuksa dks n'kkZrk gS] og gS %
(A) q + w (B) q (C) w (D) H – TS
(1) (A) rFkk (D) (2) (A), (B) rFkk (C) (3) (B) rFkk (C) (4) (B), (C) rFkk (D)
Ans. (3)
Sol. w, q are path functions; q + w = E, H – TS = G are state function.
Sol. w, q iFk Qyu gS; q + w = E, H – TS = G voLFkk Qyu gS A
Cl
CH3
(1) 3–chloro–4–methyl–1–nitrobenzene (2) 5–chloro–4–methyl–1–nitrobenzene
(3) 2–methyl–5–nitro–1–chlorobenzene (4) 2–chloro–1–methyl–4–nitrobenzene
fuEufyf[kr ;kSfxd dk lgh IUPAC uke gS %
NO2
Cl
CH3
(1) 3–Dyksjks–4–esfFky–1–ukbVªkscsUthu (2) 5–Dyksjks–4–esfFky–1–ukbVªkscsUthu
(3) 2–esfFky–5–ukbVªks–1–DyksjkscsUthu (4) 2–Dyksjks–1–esfFky–4–ukbVªkscsUthu
Ans. (4)
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NO2
4
5 3
6
2
1 Cl
Sol. CH3 2–chloro–1–methyl–4–nitrobenzene
22. The major product of the following reaction is :
fuEufyf[kr vfHkfØ;k dk eq[; mRikn gS %
1. PBr3
OH
2. KOH(alc.)
O
OH
(1) (2) (3) (4)
HO O O O
Ans. (3)
1. PBr E2reaction
Sol. OH
3
Br
SN 2reaction 2. KOH(alc.)
O O
O
23. For a reaction.
N2(g) + 3H2(g) 2NH3(g) ; identify dihydrogen (H2) as a limiting reagent in the following reaction
mixtures.
(1) 14g of N2 + 4g of H2 (2) 35g of N2 + 8g of H2 (3) 28 g of N2 + 6g of H2 (4) 56g of N2 + 10g of H2
vfHkfØ;k
N2(g) + 3H2(g) 2NH3(g) ds fy, fuEufyf[kr vfHkfØ;kRed feJ.kksa esa MkbgkMªkstu (H2) dks lheka r vfHkdeZd ds
:i esa igpkfu;s %
(1) N2 dk 14g + H2 dk 4g (2) N2 dk 35g + H2 dk 8g
(3) N2 dk 28 g + H2 dk 6g (4) N2 dk 56g + H2 dk 10g
Ans. (4)
Sol. In the mixture of 56g of N2 + 10g of H2, dihydrogen (H2) acts as a limiting reagent.
24. For any given series of spectral lines of atomic hydrogen, let v v max – v min be the differenece in
maximum and minimum frequencies in cm–1. The ratio v Lyman / v Balmer is :
ijek.kq gkbMªkstu ds LisDVªy js[kkvksa dh nh xbZ Ük`a[kykvksa ds fy, ;fn mPpre rFkk fuEure vko`fÙk;ksa esa vUrj
v v max – v min ( cm–1 esa) gS rks vuqikr v Lyman / v Balmer gksxk %
(1) 9 :4 (2) 5 : 4 (3) 27 : 5 (4) 4 : 1
Ans. (1)
1 1
1 1
( )Lyman 4 4 9
Sol. = =
( )Balmer 1 1 1 1 4
4 4 9 4
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25. The organic compound that gives following qualitative analysis is :
Test Inference
(a) Dil. HCl Insoluble
(b) NaOH solution Soluble
(c) Br2/water Decolourization
dkcZfud ;kSfxd tks fuEufyf[kr xq.kkRed fo'ys"k.k nsrk gS] og gS %
ijh{k.k vuqeku
(a) ruq HCl v?kqyu'khy
(b) NaOH foy;u ?kqyu'khy
(c) Br2/ty jax dk yqIr gksuk ¼foo.kZu½
NH2 OH NH2 OH
(1) (2) (3) (4)
Ans. (2)
n
(1) KOH (alc.)
Sol. (2) Free radical (2) Free radical
Cl polymerisation Cl polymerisation
Cl
Cl
27. The aerosol is a kind of colloid in which :
(1) Liquid is dispersed in water (2) Solid is dispersed in gas
(3) Gas is dispersed in liquid (4) Gas is dispersed in solid
,jkslkWy ,d ,slk dksyk;M gS] ftlesa %
(1) ty esa nzo ifjf{kIr gSA (2) Bksl esa xSl ifjf{kIr gS A
(3) nzo esa xSl ifjf{kIr gS A (4) xSl esa Bkasl ifjf{kIr gSA
Ans. (2)
Sol. Aerosol is solid is dispersed in gas.
,jkslkWy Bksl esa xSl ifjf{kIr gSA
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30. The element having greatest difference between its first and second ionization energies, is :
izFke rFkk f}rh; vk;uu ÅtkZvksa ds chp lokZf/kd vUrj ftl rÙo esa gS] og gS %
(1) Ba (2) K (3) Ca (4) Sc
Ans. (2)
Sol.
Element IE1 (KJ/mol) IE2(KJ/mol) Difference(KJ/mol)
Ba 503 965 462
K 419 3052 2633
Ca 590 1145 555
Sc 633 1235 602
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