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PRODUCT

SPECIFICATIONS

47 - 01 - 000 / - - E

PROTECTION
AGAINST AMBIENT CORROSIVE ATTACK
OF METAL PARTS AND ASSEMBLIES
FITTED TOGETHER ON THE VEHICLE
ON ASSEMBLY

Renault Automobile standardisation


DQSC - S / Department 00621
Section Normes et Cahiers des Charges
RENAULT 47 - 01 - 000 / - - E
This document is to be considered as a whole, the parts of which shall not be separated.

"Seul le texte français fait foi, les traductions n'étant faites que pour en faciliter l'emploi".
"The French text alone is valid. The translations are provided to assist the reader in understanding the standards".

© RENAULT 2016.
No duplication permitted without the consent of the issuing department.
No circulation permitted without the consent of RENAULT.

FIRST ISSUE

February 2002 --- This document supersedes Product Specifications 47-04-000


and 47-03-006.
This issue originates from draft NC 1998 0548 / - - E.

REVISIONS

November 2005 --A Document fully revised for update.


This issue originates from the project NC 2005 0627 / - - A.
July 2006 --B Updated.
This issue originates from the project NC 2006 0326 / - - -.
June 2007 --C Addition of As0 coding and update.
This issue originates from the project NC 2007 0460 / - - -.
February 2014 --D Completely redone.
October 2015 --E Updating § 6.8.6 and table simplifications § 7.
This issue originates from the project NC 2015 0515 / - - -.

DOCUMENTS CITED

Standards : 00-10-050 ; 00-10-415 ; 01-00-510 ; 01-70-003 ; 01-70-006 ; 01-70-007 ;


01-72-001 ; 01-72-010 ; 02-00-005 ; 03-50-004 ; 03-70-330 ; 03-70-550 ;
34-00-160 ; 01-71-002 ; 01-71-001

Specifications : 36-00-802 ; 36-05-019 ; 36-05-211 ; 36-05-218

Test Methods : D17-1058 ; D17-1974 ; D17-2028 ; D23-1001 ; D23-3083 ; D24-1702 ;


D34-2027 ;

Standards : NF EN ISO 1456 ; NF EN ISO 1461 ; EN ISO 2409 ; ISO 4925 : 2005;
ISO 60068-2-74

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CONTENTS

Page

1 PURPOSE 5

2 GENERAL CONDITIONS 6

2.1 APPROVAL 6

2.2 TOXICITY AND REGULATION AND GUIDELINE 6

3 ANTI-CORROSION CODING 7

4 DOCUMENTATION BY THE SUPPLIER 8

4.1 INDICATIONS TO BE INCLUDED ON THE DRAWING 8

4.2 CORROSION VALIDATION FILE OF STEEL AND ALUMINIUM PARTS COATED WITH ONE
OR MORE LAYERS OF ANTI-CORROSION PROTECTION (STANDARD 01.70.003) 8

5 DEFINITIONS OF THE PROTECTION SYSTEMS 9

5.1 METALLIC COATING WITH OR WITHOUT FINISHING 9

5.2 METALLIC COATING + THIN ORGANIC LAYER (≤ 5 MICRONS) 9

5.3 METALLIC COATING + THICK ORGANIC LAYER (> 5 MICRONS) 10

5.4 METALLIC SUBSTRATE + THICK ORGANIC LAYER ( > 5 MICRONS) 10

6 CORROSION TESTS TO BE PERFORMED ACCORDING TO THE TYPE OF PROTECTION AND


ANTI-CORROSION CODING 11

6.1 SUPPLIER PROCEDURE BY COMPARISON WITH THIS DOCUMENT 11

6.2 CORROSION TEST TO BE PERFORMED ON A SINGLE PART 11

6.3 CORROSION TEST TO BE PERFORMED ON AN ASSEMBLY (MULTI-PARTS) 11

6.4 SCRATCHES ON PAINTED PART SAMPLE OF PART 11

6.5 ACTIONS TO BE TAKEN BEFORE CONDUCTING THE CORROSION TEST FOR


ADDITIONAL CODING (G, T, L ET Z) 13

6.6 AGGRESSION BY GRITTING OF PARTS PROTECTED WITH AN ORGANIC LAYER OF


THICKNESS GREATER THAN 50 MICRONS 13

6.7 PARTS EXPOSED TO TEMPERATURE  80 °C CODING TΘ 14

6.8 ADDITIONAL CHARACTERISTICS 14

6.8.1 Conductivity (Z1) 14

6.8.2 Contact with another part (Z2) 14

6.8.3 Parts machined after painting (Z3) 14

6.8.4 Part getting an additional protection (Z4) 15

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6.8.5 Part subjected to mechanical aggressions by friction (Z5) 15

6.8.6 Parts subjected to specific chemical aggression by vehicle fluids (L) 15

6.8.7 Part subjected to dimensional constraints (Z7) 17

6.8.8 Unprotected zone (Z8) 18

6.8.9 Part that must be subjected to degassing after the electrolysis processing (Z9) 18

6.8.10 “Engine engraving" regulatory part based on specifications 34-00-160 (Z12) 18

6.9 RATING OF THE AREAS OF THE PART 19

7 CORROSION TESTS AND THEIR COSMETIC CRITERIA 23

7.1 FERROUS-BASED SUBSTRATES 23

7.1.1 FERROUS-BASED substrates with METALLIC coating (zinc, aluminium, tin, etc.) 23

7.1.2 STEEL SHEET METAL with or without metallic precoating protected with an ORGANIC
coating 24

7.1.3 Massive parts made up of FORGED STEEL AND CAST IRON protected with an
ORGANIC coating 25

7.2 ALUMINUM ALLOY BASED SUBSTRATES 26

7.2.1 ALUMINIUM ALLOY based substrate protected by an ANODIC OXIDATION 26

7.2.2 ALUMINIUM ALLOY based substrate protected by an ORGANIC coating 27

7.3 PARTS MADE UP OF STAINLESS STEEL EXPOSED TO A TEMPERATURE LESS THAN


300°C 28

7.3.1 STAINLESS STEEL parts protected or not by an ORGANIC coating less than or equal
to 5 µm 28

7.3.2 STAINLESS STEEL parts exposed to a temperature less than 300°C protected with an
ORGANIC coating greater than 5 µm of thickness 29

7.4 METALLIC PARTS PROTECTED BY DECORATIVE CHROMIUM COATING ≤ 2 MICRONS 30

7.5 FERROUS-BASED SUBSTRATE PROTECTED WITH AN ANTI-WEAR COATING 31

7.6 ZAMAC OR MAGNESIUM SUBSTRATES: SHEET METAL OR CASTING 32

7.6.1 Rough parts or with a protective layer 32

7.6.2 ZAMAC or MAGNESIUM substrates: protected SHEET metal OR CASTING METAL of


an ORGANIC coating > 5µm 33

7.7 PARTS ASSEMBLED WITH DIFFERENT SUBSTRATES: CORROSION AT THE JOINT


PERIPHERY 34

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1 PURPOSE

The purpose of this document is to define the anti-corrosion requirements to protect the metallic parts and
assemblies against ambient aggression with an anti-corrosion coding defined in the functional drawing of the
part or in the RFQ specifications.

The required tests in the specifications are performed on complete parts, or on assemblies. During
the corrosion test, the sampling and the positioning of the part or the assembly must enable protection
against corrosion. It may be necessary to test several parts in order to validate different zones of the part.

These specifications only pertain to cosmetic corrosion. They do not pertain to functionality problems
linked to corrosion. They must be processed by part specifications that include all the thermal, mechanical
requirements, etc.

Summary:
- To ensure the durability of a part, the design rules must be respected : orientation of the edges not visible
by the customer, no water retention, limitation of galvanic couplings, etc.

- The compliance of the materials (chemical composition, processing method, final appearance,
mechanical resistance, etc.) is managed by the part specifications.
- Painting appearance criteria are managed by the part specifications.

Limitations:
This document must not be used:
- For parts assembled on the body before phosphate coating/cataphoresis stage (e.g. the hinges).

- For the engine sub-frame, the brake rotors (brake disks, drum), the exhaust parts. Refer to the part
specifications.

- For parts that can be replaced for vehicle maintenance: oil filter, petrol or diesel filter, front and rear
windshield wiper blade, plates. Refer to the part specifications.

- For parts consisting of electrical or electronic (Battery, Machine, ECU, etc.) components that are managed
by 36-00-802, 36-05-019, 36-05-211, 36-05-218 specifications and that involve any functional aspect. In
case of doubt of a part with electrical purpose, contact the concerned department.

- For fasteners “repetitive multi-users parts” (RMU). Refer to the standard 01-71-002 which will details the
technical requirement linked to the assembly and the coefficients of friction. For the fasteners with phosphate
coating, refer to the standard 01-72-001.

- For the hot-galvanised parts (thickness> 40µm), refer to the standard NF EN ISO 1461.

- For permanent contacts with the automotive liquids, for example: cooling liquid present inside the
radiators, etc.. Contact the fluids team of DEA-TC-PT Renault.

- For parts made of polymeric substrate covered with a single or multiple layer of metal plating, contact DEA-
TC-P

- For the bonnet joints and hinges. Refer to the standard 01-70-007.

- For parts made up of stainless steel subjected to temperature greater than or equal to 300°C. Refer to the
part specifications.

Note: In case of doubt on any of these limitations mentioned above or in other cases (parts made up of
magnesium, parts assembled before cataphoresis, etc.), contatc the Renault Coating team DEA-TC-MC.

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2 GENERAL CONDITIONS

Refer to the Standard 00-10-415 and the specifications that define the part.

2.1 APPROVAL

The concerned parts are approved based on the standard 01-70-003: “validation file for cosmetic corrosion
of metallic parts assembled on the vehicle in the assembly stage”.

2.2 TOXICITY AND REGULATION AND GUIDELINE

In a dry state and irrespective of the use conditions of the part, the protective coating must neither contain
nor release toxic products or be liable to any inconvenience to the users. The initial samples must be
provided along with toxicological information sheet filled in compliance with the recommendations duly
completed. Protection applied must comply with the standard 00-10-050.

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3 ANTI-CORROSION CODING

The anticorrosion objectives are defined by the product direction and by the technical politic committee of
anticorrosion (CPTA).

The anticorrosion coding of standard 01-70-002 are only available for consultation by persons of core competences
(Métiers) from Nissan and Renault (not available for external diffusion).

To define the anti-corrosion coding according to the aggression level, the criteria given below must be documented.
Each criterion corresponds to a code which has led to the creation of corrosion coding to be specified in the
functional drawing and RFQ specifications.

CODES CRITERIA REQUIREMENTS

ANTI-CORROSION OBJECTIVES
 As0 Short term
 As1 Average term
 As2 Long term

PARTS VISIBILITY
 NV Part that is not visible or hidden by a fairing, a style cache, skid, etc. An invisible part must not
cause the running of red oxidation that would become visible to the customer. Refer to
 VC Part visible while the “vehicle is on the lift”. §7
 VB Part visible during a customer intervention “fuel, wheel change, engine compartment”.
 VA Part visible “vehicle on wheels, opening systems opened except the engine hood”.
CORROSIVE AGGRESSION
I Interior part slightly damaged (off monsoon area).
M Middle part moderately damaged (including the parts in monsoon area).

E Exterior part heavily damaged.

DAMAGE CAUSED BY GRITTING


Refer to
 NG Part that is not subjected to gritting
§ 6.6
G Part subjected to gritting.

EXPOSURE TO TEMPERATURE
Refer to
 NT Part that is not exposed to a peak temperature equal to or greater than 80°C.
§ 6.7
 T Part that is exposed to a peak temperature 
SPECIFIC CHEMICAL AGGRESSION BY VEHICLE LIQUIDS
Refer to
 NL Part not subjected to chemical damage by fluids.
§ 6.8.6
L Part that could be subjected to splashing (refer to the list § 6.8.6.3).

ADDITIONAL CHARACTERISTICS
Refer to
 Z… When one or more additional characteristics are requested, the designation is completed with
the letters Z1, Z2, etc. A note defining this or these additional characteristics is specified in the § 6.8
drawing or in the parts specifications.

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4 DOCUMENTATION BY THE SUPPLIER

4.1 INDICATIONS TO BE INCLUDED ON THE DRAWING

The following data, comply with the standard 01-00-510 “Technical drawing and supplier drawing approval",
must be indicated in the supplier drawing:

- Anti-corrosion coding,

- Name of the coating proposed by referring to a normative document explaining the coating
characteristics,

- Compounder,

- Applicator and the mode of application,

- Coating thickness (+tolerance interval).

Unless otherwise agreed, the measures indicated on the drawing must be the measures of the
protected part.

4.2 CORROSION VALIDATION FILE OF STEEL AND ALUMINIUM PARTS COATED WITH ONE OR MORE
LAYERS OF ANTI-CORROSION PROTECTION (STANDARD 01.70.003)

The file is completed by the supplier to be sent to the part pilot (PFE, LI, etc.).

If the supplier's competence for "measurements and testing" is recognized by Renault and sanctioned by a
self-validation according to NF EN ISO/CEI 17025, it will deliver to Renault DVC consists of: on the
"Identification sheet product / process "and pages of results of measurements or tests for which it is self-
validated.

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5 DEFINITIONS OF THE PROTECTION SYSTEMS

Note: For the parts that are treated hanged, the contact areas must be minimal. These areas are not to
consider in the corrosion rating.

5.1 METALLIC COATING WITH OR WITHOUT FINISHING

Definition: this coating consists of metallic elements deposited on a substrate and possibly covered with a
finishing of mineral or organic nature, of a thickness less than or equal to 1 µm.
Passivation and/or finishing
(conversion layer, organo-mineral film,
etc.)
Metallic coating e.g. pure zinc,
lamellar zinc, zinc-nickel, zinc-iron,
etc.

Substrate e.g. steel, cast iron,


aluminium, etc.

5.2 METALLIC COATING + THIN ORGANIC LAYER (≤ 5 MICRONS)

Definition: this coating consists of metallic elements deposited on a substrate coated with an organic
layer of a thickness less than or equal to 5 µm.

The anti-corrosion requirements for this type of coating are the same as for metallic coating.

Organic finish layer

Metallic coating (possibly with passivation):


Pure zinc, lamellar zinc , zinc-nickel, zinc-iron,
etc.

Substrate e.g. steel, cast iron, aluminium, etc.

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5.3 METALLIC COATING + THICK ORGANIC LAYER (> 5 MICRONS)

Definition: this coating consists of metallic elements deposited on a substrate coated with an organic
layer of a thickness greater than 5 µm.

The anti-corrosion requirements for this type of coating are the same as for organic coating.

Organic layer e.g. painting cataphoresis, polyester,


epoxy etc.

Surface processing e.g. phosphatation, Ni-free,


passivation etc.
Metallic coating (with possible passivation): pure
zinc, lamellar zinc, zinc-nickel, zinc-iron, etc.

Substrate e.g. steel, cast iron, aluminium, etc.

Note 1: In this case, the organic layer must be scratched on the full-panel before the corrosion test
(except for the cast iron and the cast aluminium). The test method D34-2027 describes how to scratch the
full-panel, and the standard 02-00-005 describes how to perform the rating of the delamination at the end of
the corrosion test ECC1.

Note 2: Adhesive test on a dedicated painted part:


Conduct the comb test on a new part, based on the standard EN ISO 2409.
The requirements are as follows: Rating ≤ 1.
If the result is compliant, you can conduct the corrosion test on other parts from the same lot.

5.4 METALLIC SUBSTRATE + THICK ORGANIC LAYER ( > 5 MICRONS)

Definition: It is a metallic substrate coated with an organic layer of thickness greater than 5 µm.

Organic layer: e.g. painting, cataphoresis, polyester,


epoxy etc.
Surface processing: e.g. phosphatation, Ni-free,
passivation etc.

Substrate e.g. steel, cast iron, aluminium, etc.

Note 1: In this case, the organic layer must be scratched on the full-panel before the corrosion test
(except for stainless steel, the cast iron and the cast aluminium). The test method D34-2027 describes how
to scratch the full-panel, and the standard 02-00-005 describes how to perform the rating of the delamination
at the end of the corrosion test ECC1.

Note 2: Adhesive test on a dedicated painted part:


Conduct the comb test on a new part based on the standard EN ISO 2409.
The requirements are as follows: Rating ≤ 1.
If the result is compliant, you can conduct the corrosion test on other parts from the same lot.

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6 CORROSION TESTS TO BE PERFORMED ACCORDING TO THE TYPE OF PROTECTION AND ANTI-


CORROSION CODING

6.1 SUPPLIER PROCEDURE BY COMPARISON WITH THIS DOCUMENT

To determine the corrosion test(s) and requirements associated:

- It is required to ensure the presence of anti-corrosion coding of the part.

- Is it a single part with a single coding, or a set of parts and/or coding?

- For a single part, what is the substrate? (Iron, Aluminium)

- For a single part, is there any or no coating? If yes, then what type? (painting, metallic coating, etc.) and
what is the thickness?

6.2 CORROSION TEST TO BE PERFORMED ON A SINGLE PART

Organic layer > 5µm Decorative


applied on a ferrous, aluminium, metallic coating
Metallic coatings anodised aluminium, ZAMAC, of Cr/Ni/Cu and
magnesium, or stainless steel anodised
substrate aluminium.

Perform a Salt Spray Test, Perform an ECC1 test, Perform a CASS-Test,


based on D17-1058 based on D17-2028 based on D23-1001

Note: The tests are performed on single parts (e.g. a screw) or on the assemblies (e.g. door lock). Refer to the
Corrosion validation file 01-70-003 for the number of parts or assemblies to be tested simultaneously.

The durations of the test and the requirements are stated in § 7.

6.3 CORROSION TEST TO BE PERFORMED ON AN ASSEMBLY (MULTI-PARTS)


In addition to the tests performed on each of the part considered separately (refer to chapter 6.2), an ECC1 test
must be carried out on the assembly to evaluate the resistance of the interfaces to corrosion (runnings, joint
periphery, bimetallic and galvanic coupling).

Note: The codded parts Z2 face the risk of galvanic corrosion, it is mandatory to test them assembled to evaluate
the risk:
- Bimetallic corrosion (2 metals electrically connected to different electrical potentials).
- Galvanic corrosion, e.g. for the joints in contact with a metallic material or another paint.

The duration of the test and the requirements are stated in § 7.7.

6.4 SCRATCHES ON PAINTED PART SAMPLE OF PART


The organic layer (greater than 5 microns) must be scratched on full-panel before the corrosion test (except for the
cast iron).

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Remark: To evaluate the performance of a surface treatment on painted parts, in addition to the assemblies, it is
necessary to use a sample on another part to scratch it and position it at 20° in the corrosion chamber.

The test method D34-2027 describes how to scratch the full-panel, and the standard 02-00-005 describes how to
perform the rating of the delamination at the end of the corrosion test ECC1.

Note 1: The parts with high curvature too high can’t be scratched using the tool described in the method D34-2027.
In this case and only in this case, use a tool "scratch needle made up of hard steel" or “Handcutter 428 Erichsen
with a 0.5 mm blade”. The rating method remains the same.

Scratch needle made up Handcutter 428 Erichsen


of hard steel with a 0.5 mm blade

Note 2: A part or specimen exposed to temperature must be scratched after thermal shock then tested through
corrosion test. Refer to the summary diagram in § 5.6.

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6.5 ACTIONS TO BE TAKEN BEFORE CONDUCTING THE CORROSION TEST FOR ADDITIONAL CODING
(G, T, L ET Z)

L Zx
G T Parts exposed to
Part exposed to Part exposed to Part that must comply
chemical aggresion with the additional
gritting temperature by the fluids
characteristics
of the vehicle

Part gritting, in the case of Conduct appropriate Conduct a Conduct the To be done, based on
an organic layer greater thermal shock, based on pre-pollution test without the case.
than or equal to 50µm. the type of protection. test with the pre-pollution, Refer § 6.8
Refer to the method Refer to the method in appropriate the part will be
specified in § 6.6. § 6.7. automobile used as the
fluids based reference.
on the type of
protection.
Perform full panel scratch for Refer to the
Impact requirements are the organic layer. method in
defined in § 6.6. § 6.8.6.

Corrosion Corrosion
test test

6.6 AGGRESSION BY GRITTING OF PARTS PROTECTED WITH AN ORGANIC LAYER OF THICKNESS


GREATER THAN 50 MICRONS

THERMAL SHOCK
(see § 6.7)

Must be performed before gritting, in the case where the baking temperature of the organic
coating is less than the maximum functioning temperature ( indicated in the coding).

GRITTING ON SPECIMEN OR FLAT PART


(based on the test method D24-1702)

REQUIREMENTS

The scaling of painting must reach a maximum of 3 (refer to the type photo).
No impact must be seen on the ferrous substrate (no red colouring after the test with copper
sulphate).

Note: For non-flat parts, the quotation will be done case by case.

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6.7 PARTS EXPOSED TO TEMPERATURE  80 °C CODING TΘ

After being constantly maintained to a warm temperature for 2 hours, the parts must comply with the
requirements of resistance to corrosion.

Anticorrosion coding: the temperature T is indicated in the anti-corrosion coding of the part.

Organic or organo-minerals coatings: If the baking temperature of the organic coating is greater than , it
is not required to conduct the thermal shock test.

Operating mode:

The part is stored outside the oven at ambient temperature of the lab while the oven is warmed-up.

The operator must beforehand place a thermocouple inside the oven at a 10 cm distance from the edges
(effective volume). The thermocouple reading must be ± 2°C between the temperature range of 80 to °C).

Close the door of the oven without the part and wait for its stabilisation at a temperature of T°C ± 2°C.

Open the door of the oven and place the part(s) to be tested in the centre of the oven such that the parts do
not come in contact with the thermocouple or with each other and then close the door.

Wait for the oven to get stabilised at a temperature of °C ± 2°C, then leave the part(s) in the oven at °C ±
2°C for 2 hours.

Remove the part and wait for it to cool down to ambient temperature before putting it through the corrosion
test.

6.8 ADDITIONAL CHARACTERISTICS

In certain cases, the additional requirements are indicated in the functional coding as a Z and a note that
goes along with it.

6.8.1 Conductivity (Z1)

RENAULT may require a part conducting electricity (e.g. part on which the ground wire is fixed); in this case,
the part must allow ensuring the requested functioning.

6.8.2 Contact with another part (Z2)

In the case where a part of the part or the assembly is in contact with another metallic part or a metallic
coating, refer to the requirements stated in 7.7 for the additional risks of coupling.

6.8.3 Parts machined after painting (Z3)

The parts must be tested after machining to check the efficiency of the cutting and washing fluids. The
machined zones must be covered using an adhesive tape or a painting applied manually, to avoid running of
oxidation.

The resistance of the anti-corrosion protection coating to machining and washing liquids is estimated
according to the test method described in paragraph 6.8.6.

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6.8.4 Part getting an additional protection (Z4)

A part can get the following additional protections:

- Anti-gritting product (protection P1) in compliance with the standard 03-70-330,

- Additional under-body protection (Protection P2) based on the standard 03-70-550,

- Cavity wax (Protection P3) based on the standard 03-70-550.

Compatibility of protections:

The coating or the painting must not be altered by the additional protection(s) and must allow the adhesion of
the additional products defined in the drawing.

Note: The DIPV department is responsible of specifications for these products. The corrosion department
must be involved in the case of study of a new additional protection.

6.8.5 Part subjected to mechanical aggressions by friction (Z5)

Certain parts are subjected to mechanical aggressions by friction during use, e.g. seat runner.

The GFE must define the areas that are subjected to such aggression on the drawing.

The parts subjected to friction must meet corrosion requirements after being subjected to mechanical
aggression. Conditions must be defined with the GFE who is in charge of the part.

6.8.6 Parts subjected to specific chemical aggression by vehicle fluids (L)

The parts might be subjected to occasional and intermittent contamination with certain vehicle fluids. The
parts are pre-contaminated before the corrosion test and must comply with the requirements defined in these
specifications. Simultaneously, some parts must be tested without pre-contamination through a corrosion
test and must meet the same requirements.
Note 1: For permanent contacts with the vehicle liquids (e.g. cooling liquid inside the radiator),
contact the fluids team of UET DE-TC-PT.

Note 2: When you consider the contacts with the fluids, downgraded modes like battery leakage, brake fluid
leakage, etc. are not considered.

There are 2 levels of contaminations:

6.8.6.1 Occasional contamination (Class A)

Definition : In case of repair, maintenance, an upgrade of liquids, use of windshield washer fluid, filling the
fuel etc.

Note: It is imperative to test a minimum of 5 samples or parts.

Step 1: At room temperature immerse the specimen in question within the specified fluid or spray it with this fluid
and ensure that the specimen is wet over its entire surface.
Step 2: Let the sample drain naturally at room temperature for 5 to 10 min; it is not allowed to shake or wipe.
Step 3: Place the specimen in a test room at 70 ° C ± 2 ° C during 93 hours ± 3 hours. At the end of this period,
cooling the sample to room temperature.
Step 4: Perform the corrosion test as defined in paragraph 6.2. The corrosion resistance should respect the criteria
defined in the tables in paragraph 7.

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Synoptic of the occasional contamination method to automotive fluids

Note : The choice between spray or immersion method will depend on the size of the part (feasibility) and available
test means.

Step 1
Choice of mode of pollution: Spray or Immersion.
At room temperature immerse the specimen in question within the specified fluid or spray it with this fluid
and ensure that the specimen is wet over its entire surface.

Spray during 30 ± 2 seconds of the Immersion during 30 ± 2 secondes


entire surface of the test part. The then remove the sample
wetting must be uniform.

Step 2
Let the sample drain naturally at room temperature for 5 to 10 min; it is not allowed to
shake or wipe.

Step 3
Place the specimen in a test room at 70 ° C ± 2 ° C during 93 hours ± 3 hours. At the
end of this period, cooling the sample to room temperature.

Step 4
Perform the corrosion test as defined in paragraph 6.2. The corrosion resistance should
respect the criteria defined in the tables in paragraph 7.

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6.8.6.2 Definition of the liquids

The standards 03-50-004 and 03-50-000 define the liquids to use.

Codding
Type of product Replacement product
marking

Brake liquids and


L1 Brake liquid class 6 based on the standard ISO4925 :2005.
hydraulic clutch

Type D in a 50/50 mix (Antigel ELF XT 4030 or TEXACO ETX


L2 Cooling liquid
6280 I with distilled water)

Washing liquid with ethanol and/or isopropanol, used with


L3 “Standard” window-washing fluid
“extreme cold” concentration
According to geographic plates :
- Gasoline with 10% of ethanol + corrosive water
(Europe) : C(E10)A
- Gasoline with 30% of ethanol + corrosive water
Gasoline fuel with biofuel (Brazil) : C(E30)A
L4
fraction (1) And hydrated ethanol + corrosive water (Brazil)
= 92%m/m ethanol + 7,5%m/m corrosive water +
0,5% m/m fluid C
- Gasoline with 15% of ethanol + corrosive water
(Europe) : C(M15)A
Diesel fuel with biofuel fraction
L5 Diesel B30 soja
(2)

Electric vehicle battery mounting


L6 TRANSNET SCM (foaming/degreasing agent)
washing fluid

“Multi material” aqueous liquid without chlorine used in


Z3 Machining liquid industrial settings.
Suppliers: Fuchs, Henkel, Chemetall, Quaker Chemical.

(1) Corrosive water is defined according to SAR J1681 (for more details, see appendix E of SAR J1681).

For C(E10)A, C(E30)A, hydrated ethanol and C(M15)A, the composition of the final fluid will have the target
for aggressive compounds :

- 1ppm of chloride (in the form of sodium chloride)

The "essence" fraction may be replaced by a substitution fluid. The fluid used here is the "Fluid C" as
described in ASTM D471 / ISO1817, composed of 50% isooctane and 50% toluene. We can also refer to
appendix A of SAE J1681 specifications for these components.

(1) and (2) : Special fuel suppliers are :


- Total ACS
- Haltermann
- Shell
- Coryton

6.8.7 Part subjected to dimensional constraints (Z7)

In the case of parts with dimensional constraints or threaded parts, this indication must be specified in the
functional drawing. The thickness of the coating must be taken into account in measures. Be careful with the
anodic oxidation of aluminium alloys that lead to a gain of thickness.

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6.8.8 Unprotected zone (Z8)

If a part of the part is exempted from protection for functional or assembly reasons, it must be indicated
precisely in the functional drawing.

The stripping zone must be protected with an adhesive to avoid running during the corrosion test. This zone
will not be considered for rating during the corrosion tests.

6.8.9 Part that must be subjected to degassing after the electrolysis processing (Z9)

If the part must be subjected to degassing after electrolysis, refer to standard 01-71-001.

6.8.10 Regulatory part (Z12)

6.8.10.1 “Engine engraving" based on specifications 34-00-160


The engraving number of the engine must be readable throughout the life of the powertrain.
At the end of the corrosion tests, reading must be possible under the condition that the corrosion phenomenon
(pick-offs, blistering, etc.) does not visibly damage the depth of the marking points. The housings in aluminium
(engines and gearboxes) are exempted from anti-corrosion protection.

To ensure the visibility and the reading of the engraved number after 20 years of life in the network, the engraved
zones must be protected either by placing an adhesive label or a clear-coat or a transparent wax.

a) Protection of engravings through an adhesive label

The test involves the following steps:

1. Contaminate the engraved surface for 15 seconds in the machining liquid (Refer to § 6.8.6) at ambient
temperature.
2. Allow the specimen to dry for 24 hours in open air.
3. Labelling: manual pressure with the thumb along the length of the label.
4. Thermal shock for 1 hour at 135°C.
5. ECC1 corrosion test during 84 cycles.

At the end of the test, the engraving must be readable to ensure a duration of protection of 20 years.

b) Protection of the engraving through a clear-coat or a transparent wax

The test involves the following steps:

1. Receive an already protected part.


2. Thermal shock induced by exposure to 135°C for 1 hour
3. ECC1 corrosion test during 84 cycles

At the end of the test, the engraving must be readable to ensure a duration of protection of 20 years.

6.8.10.2 Customs rules for China

The country's rules are particularly strict and must be observed: "no red oxidation on the parts in customs reception
area, and of course during the delivery to the customer"

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6.9 RATING OF THE AREAS OF THE PART

Note: The parts are rated to the naked eye and at a distance of about 50 cm.

Full-panel corrosion Edge corrosion

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Point of peripheral corrosion and on the SEFG weld bead Periphery joint corrosion

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Galvanic coupling

Screw made of steel Screw made of steel


coated with dichromated zinc/aluminium alloy 6060 T5 coated with lamellar zinc/aluminium alloy 6060 T5
Case of galvanic coupling Without galvanic coupling
before dismantling before dismantling

Case of galvanic coupling Without galvanic coupling


after dismantling and stripping of aluminium oxides after dismantling and stripping of aluminium oxides

Rubber in contact with aluminium

Without galvanic coupling With galvanic coupling (white salts at the periphery)

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Galvanic coupling between the joint made of rubber


and painted aluminium alloy sheet metal

Specimen made of
painted aluminium
sheet metal

Joint made
of rubber

After removing the joint made of rubber, we can see some blisters in the periphery of the

joint.

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7 CORROSION TESTS AND THEIR COSMETIC CRITERIA

7.1 FERROUS-BASED SUBSTRATES


With or without organic finishing
7.1.1 FERROUS-BASED substrates with METALLIC
coating (zinc, aluminium, tin, etc.) Metallic coating (with or without
finishing): pure zinc, lamellar zinc,
Fe substrate zinc-nickel, zinc-iron,
aluminium/silicon, etc.
Steel sheet metal, forged
steel, cast iron

The validation test that must be performed in this case is the salt spray test based on the standard D17-1058
which includes the aggressiveness of the test on zinc. This aggressiveness is mandatory for the better
characterisation of the anti-corrosion protection duration.
The test durations are as follows:

Interior part (I) External part (E)

Full panel, edge, weld Full panel, edge, weld

As0 / NV 264h (1)

As0 / VC 504h (1)

As1 / NV No requirement 288h (1)

As1 / VB 600h (1)

48h (2) 192h (2)


As1 / VA 120h (1) 600h (1)

As2 / NV No requirement 408h (1)

48h (2) 240h (2)


As2 / VA 144h (1) 816h (1)

(1) No red oxidation


(2) No change in appearance

Test conditions:
- The tests requested for in the specifications are performed on integral parts or on assemblies or on part
samples placed in vehicle configuration such that it produces a level of aggression on the vehicle. Thus, the
positioning of parts is defined in line with RENAULT.
- Also note that in the case of the Salt Spray Test standard (D171058), it’s important to notice any change
(even small) in the appearance, and "Red oxidation" is rated since the first time it appears.
- For the codded VA parts must mandatorily be compared with a specimen not having been subjected to
corrosion test to estimate the change in the appearance.

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7.1.2 STEEL SHEET METAL with or without metallic precoating Organic coating
protected with an ORGANIC coating With or without metallic precoating (with or without passivation): pure zinc,
lamellar zinc, zinc-nickel, zinc-iron, Aluminium/Silicon, etc.
Fe substrate Steel sheet metal

Note: Hanged parts must have very small contact areas; these areas are not considered in the rating.

The validation test that must be carried out in this case is the ECC1 test based on D17-2028, after the adhesive test on the dedicated part (Refer to note 2 of § 5.4 ).
The test durations are as follows:

Interior part (I) External part (E)


Full-panel Periphery of the Full-panel Periphery of the
Edge Full-panel and weld Edge Full-panel and weld
scratched joint scratched joint
5 cycles 14 cycles 14 cycles 14 cycles
As0 / NV (1) (3) (5) (6)
10 cycles 28 cycles 28 cycles 28 cycles
As0 / VC (1) (3) (5) (6)
7 cycles 18 cycles 18 cycles 18 cycles
As1 / NV No requirement (1) (3) (5) (6)
11 cycles 35 cycles 35 cycles 35 cycles
As1 / VB (1) (3) (5) (6)
3 cycles 9 cycles 9 cycles 9 cycles 11 cycles 35 cycles 35 cycles 35 cycles
As1 / VA (2) (4) (5) (7) (2) (4) (5) (7)
7 cycles 21 cycles 21 cycles 21 cycles
As2 / NV No requirement (1) (3) (5) (6)
4 cycles 11 cycles 11 cycles 11 cycles 14 cycles 42 cycles 42 cycles 42 cycles
As2 / VA (2) (4) (5) (7) (2) (4) (5) (7)

- Edge (limitations for a side of a part or cutting edge)


(1) No red corrosion is found along the length of the edges (cutting edge).
(2) No blistering or no white corrosion is found along the length of the edges (cutting edge). No unsticking of the painting film after the stripping test with the adhesive tape (procedure
described in the standard 02-00-005).

- Full-panel and weld or at the point of contact with rubber/glue


(3) No red corrosion or blistering under painting.
(4) No blistering or no white or red corrosion. No unsticking of the painting film after the stripping test with the adhesive tape (procedure described in the standard 02-00-005).

- Scratched full-panel (procedure described in the standard 02-00-005).


(5) Average unsticking of painting around the scratch < 3.5 mm for a naked steel, and < 2.5 mm for steel pre-coated with zinc (zinc, zinc-nickel, zinc-iron, etc.).

- Periphery of the joint or contact with the rubber/glue


(6) No red corrosion greater than 1 mm from the periphery of the joints.
(7) At the periphery: no blistering under the painting and no white or red corrosion from the interstice (no running). No unsticking of the painting film after the stripping test with the adhesive
tape (procedure described in the standard 02-00-005).
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Organic coating
7.1.3 Massive parts made up of FORGED STEEL AND CAST IRON With or without metallic precoating (with or without passivation):
protected with an ORGANIC coating Pure zinc, lamellar zinc, zinc-nickel, zinc-iron, Aluminium/Silicon, etc.
Fe substrate Forged steel, cast iron

Note: The thickness of the organic coating must be at least greater than the surface roughness. Hanged parts must have very small contact areas; these areas are not
considered in the rating.

The validation test that must be conducted in this case is the ECC1 test, based on the standard D17-2028.
The test durations are as follows:

Interior part (I) External part (E)

Edge Full-panel and weld Periphery of the joint Edge Full-panel and weld Periphery of the joint

4 cycles 7 cycles 7 cycles


As0 / NV (1) (3) (5)
7 cycles 21 cycles 21 cycles
As0 / VC (1) (3) (5)
5 cycles 14 cycles 14 cycles
As1 / NV No requirement (1) (3) (5)
10 cycles 28 cycles 28 cycles
As1 / VB (1) (3) (5)
4 cycles 9 cycles 9 cycles 10 cycles 28 cycles 28 cycles
As1 / VA (2) (4) (6) (2) (4) (6)
7 cycles 21 cycles 21 cycles
As2 / NV No requirement (1) (3) (5)
5 cycles 11 cycles 11 cycles 14 cycles 42 cycles 42 cycles
As2 / VA (2) (4) (6) (2) (4) (6)

- Edge (Machining edges, cast ribs, mating surface, fillet, etc.)


(1) No red corrosion is found along the length of the edges
(2) No blistering or no white corrosion is found along the length of the edges. No unsticking of the painting film after the stripping test with the adhesive tape (procedure described in the
standard 02-00-005).

- Full-panel or at the contact zone with rubber/glue


(3) No red corrosion or blistering under painting.
(4) No blistering or no white or red corrosion. No unsticking of the painting film after the stripping test with the adhesive tape (procedure described in the standard 02-00-005).

- Periphery of the joint


(5) Red corrosion from the periphery of the joints < 5 mm.
(6) Red corrosion from the periphery of the joints < 2 mm.

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7.2 ALUMINUM ALLOY BASED SUBSTRATES

Anodic oxidation
7.2.1 ALUMINIUM ALLOY based substrate protected by an ANODIC OXIDATION
Al substrate

Note 1: The choice of the grade of aluminium alloy, as well as the design, has to be validated by the corrosion department.
Note 2: It is not required to do corrosion test on tough anodic oxidation. The layer must simply ensure its functioning of resistance to wear.
Note 3: Before performing the corrosion tests, it is required to check the thickness, the quality of clogging, etc. based on the standard 01-72-010.
In the case of non-conformity, the test will not be launched.

Two validation tests must be performed: the CASS test (based on D231001) and the Salt spray test (based on D171058). At the end of the test, the parts are rinsed
with deionized water, dried with compressed air and then wiped with a smooth chiffon cloth.
The test durations are as follows:

Interior part (I) Middle part (M) External part (E)

CASS test Salt spray test CASS test Salt spray test CASS test Salt spray test

As1 4 hours (*) 120 hours (*) 8 hours (*) 240 hours (*) 16 hours (*) 480 hours (*)
or As2 / VA

(*) No change in the appearance compared to a reference part:


the parts must not show effects of oxidation, pitting, stain, ring, white film, etc.

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7.2.2 ALUMINIUM ALLOY based substrate


Organic coating (*)
protected by an ORGANIC coating
With or without anodic
Al substrate oxidation layer

(*) For the thickness of the organic coating less than or equal to 5µm, refer to § 7.2.1 and only conduct the salt
spray test.

Note: The choice of the grade of the aluminium alloy as well as the design has to be validated by the corrosion
department.

The validation test that must be carried out in this case is the ECC1 with pre-contamination based on D23-3083
after the adhesive test on the dedicated part (Refer to note 2 of § 5.4). The parts must be compulsorily tested with
all the parts that come in contact (rubber of the casting, plastic end fitting, plastic bracket, etc.).

The test durations are as follows:

Interior part (I) External part (E)

Full-panel Full-panel scratched Periphery of the joint

NV No requirement

28 cycles 28 cycles 28 cycles


As0 / VC (1) (3) (5)
35 cycles 35 cycles 35 cycles
As1 / VB (1) (3) (5)
35 cycles 35 cycles 35 cycles
As1 / VA No requirement
(2) (4) (6)
42 cycles 42 cycles 42 cycles
As2 / VA No requirement
(2) (4) (6)

- Full-panel or at the contact zone with rubber/glue


(1) No blistering or no white corrosion.
(2) No blistering or no white corrosion. No unsticking of the painting film after the stripping test with the adhesive tape
(procedure described in the standard 02-00-005).

- Full-panel scratched
(3) Average of the number of patches ≤ 7 and maxi length ≤ 2mm.
(4) Average of the number of patches ≤ 3 and maxi length ≤ 1mm.

- Periphery of the joint


(5) No white corrosion greater than 1mm from the periphery of the joints.
(6) At the periphery of the joint: no blistering under the painting and no white corrosion from the interstice of the joints (no
running) No unsticking of the painting film after the stripping test with the adhesive tape (procedure described in the standard
02-00-005).

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7.3 PARTS MADE UP OF STAINLESS STEEL EXPOSED TO A TEMPERATURE LESS THAN 300°C
With or without organic
7.3.1 STAINLESS STEEL parts protected or not by an coating (≤ 5µm)
ORGANIC coating less than or equal to 5 µm Stainless steel

Note 1: The choice of the grade as well as the design has to be validated by the corrosion department.
Note 2: The parts made up of stainless steel must be compulsorily tested with all the parts that come in contact
(rubber of the casting, plastic end fitting, plastic bracket, etc.)

Validation test that must be conducted in this case is the ECC1 corrosion test based on D17-2028. The test
process and the rating method must comply with the standard 01-70-006.
The test durations are as follows:

Interior part (I) Middle part (M) External part (E)

Full-panel, edge, weld Full-panel, edge, weld Full-panel, edge, weld

As0 / NV 7 cycles (1)

As0 / VC 14 cycles (1)

As1 / NV No requirement 7 cycles (1) 12 cycles (1)

As1 / VB 21 cycles (1)

As1 / VA 4 cycles (1) 18 cycles (1) 28 cycles (1)

As2 / NV 4 cycles (1) 7 cycles (1) 12 cycles (1)

As2 / VA 4 cycles (1) 18 cycles (1) 28 cycles (1)

(1) For intermediate analysis and at the end of the ECC1 test, the parts must not show any pitting or red oxidation
stain or blister on the painting or the clear coat (Refer to the standard 01-70-006).

Note: Before starting the corrosion test it is necessary to read 01-70-006 standard that describes the following
procedure:

- Pay attention to the cleanliness of the chamber and the racks and supports. Any ferrous ions contamination
will lead to the oxidation of the stainless steel that is very sensitive to this contamination.

- Preparation of the sample before corrosion test (cleaning, rinsing)

- Procedure of flushing and drying during (every weeks) and at the end of the test

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Organic coating (> 5µm)


7.3.2 STAINLESS STEEL parts exposed to a
temperature less than 300°C protected with an Stainless steel
ORGANIC coating greater than 5 µm of thickness

Note 1: The choice of the grade as well as the design has to be validated by the corrosion department.
Note 2: The parts made up of stainless steel must be compulsorily tested with all the parts that come in contact
(rubber of the casting, plastic end fitting, plastic bracket, etc.).

The validation test that must be carried out in this case is the ECC1 corrosion test based on D17-2028 after the
adhesive test on the dedicated part (Refer to note 2 of 5.4). The test conducting and rating methods must be in
compliance with the standard 01-70-006.

The test durations are as follows:

Interior part (I) Middle part (M) External part (E)

Full-panel, edge, weld Full-panel, edge, weld Full-panel, edge, weld

As2 or As1 / V 7 cycles (1) et (2) 21 cycles (1) et (2) 42 cycles (1) et (2)

(1) Scratched full-panel, edge, welding


At the end of the ECC1 test, the parts must not show any pinhole or red oxidation stain or blister on the paint or the clear coat
(Refer to the standard 01-70-006).

(2) Scratched full-panel


At the end of the ECC1 test, the width of the delamination under the painting must be less than 1.5 mm according to the rating
02-00-005.

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Chromium (with a sub-layer


7.4 METALLIC PARTS PROTECTED BY DECORATIVE CHROMIUM COATING ≤ 2 made of nickel/copper)
MICRONS
Ferrous materials,
Zinc and zinc alloy,
Copper and copper alloy,
Aluminium and aluminium alloy

Note: For the selection of different layers of coating, thickness, adhesive, thermal shock, refer to the standard NF EN ISO 1456.

The validation test must be performed, in this case it is the CASS test (based on D23-1001) or the salt spray test (based on D171058).
The test durations are as follows:

Interior part (I) Middle part (M) External part (E)

CASS test Salt spray test CASS test Salt spray test CASS test Salt spray test

VC 32 h (*) 96 h (*)

VB 48 h (*) 144 h (*)

VA 8 h (*) 16 h (*) 32 h (*) 96 h (*) 64 h (*) 192 h (*)

Note: At the end of the test, the parts are rinsed with deionized water, dried with compressed air and then wiped with a smooth chiffon cloth.

(*) Change in the appearance: the parts must not show effects of oxidation, pitting, stain or ring, before the duration indicated.

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Anti-wear coating with or


7.5 FERROUS-BASED SUBSTRATE PROTECTED WITH AN ANTI-WEAR COATING without a sub-layer

Ferrous material

The anti-wear coating can be a layer of chromium coat for a thickness of greater than 2 µm, a phosphorous nickel coating, a burnishing of thermo-chemical type, a carbide,
a nitride, etc.

The validation test that must be carried out in this case is the Salt spray test (based on D171058).
The parts of the part that are not exposed to friction or exposed to friction but not lubricated must be in accordance with the requirements of § 7.1.2.
The parts of the part exposed to friction and lubricated are subjected to the following test durations:

Interior part (I) External part (E)

NV No requirement 96 h (*)

VC 96 h (*)

VB 144 h (*)

VA 16 h (*) 192 h (*)

Note: at the end of the test, the parts are rinsed with deionized water, dried in compressed air and then wiped with a smooth chiffon cloth.

(*) change in appearance: the parts must not show effects of oxidation, pin hole, stain or ring, before the duration indicated.

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7.6 ZAMAC OR MAGNESIUM SUBSTRATES: SHEET METAL OR CASTING

7.6.1 ZAMAC or MAGNESIUM substrates: rough


Layer: passivation, surface
parts or with a protective layer processing, metallic coating,
organic coating ≤ 5µm

ZAMAC or magnesium

Notice: ZAMAC must not be used when we put a mechanical strain on the parts.

The validation test that must be performed in this case is the salt spray test based on D17-1058.
The tests requested in the specifications are performed on all the parts or on the assembly on which or on the part
samples placed in vehicle configuration to reproduce the level of damage on the vehicle. Thus, the positioning of
parts is defined in line with the RENAULT standards.
The test durations are as follows:

Interior part (I) External part (E)

Full panel, edge, weld Full panel, edge, weld

NV No requirement No requirement

As0 / VC No requirement

As1 / VB No requirement

AS1 / VA 48h (*) 192h (*)

AS2 / VA 72h (*) 240h (*)

(*) change in appearance: the part must compulsorily be compared with a sample that is not subjected to
corrosion test.

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7.6.2 ZAMAC or MAGNESIUM substrates: protected SHEET metal OR CASTING Organic coating > 5µm
METAL, with an ORGANIC coating > 5 µm With or without metallic pre-coating (with or
without passivation): pure zinc, lamellar zinc, zinc-
nickel, zinc-iron, aluminium/silicon, etc.

ZAMAC or magnésium

Notice: ZAMAC must not be used when we put a mechanical strain on the parts.

The validation test that must be carried out in this case is the ECC1 test based on D17-2028 after the adhesive test on the dedicated part (Refer to note 2 of § 5.4 ).
The test durations are as follows:

Interior part (I) External part (E)

Edge Full-panel or weld Scratched full-panel Edge Full-panel or weld Scratched full-panel

NV No requirement

10 cycles 28 cycles 28 cycles


As0 / VC (1) (3) (5)

11 cycles 35 cycles 35 cycles


As1 / VB (1) (3) (5)

3 cycles 9 cycles 9 cycles 11 cycles 35 cycles 35 cycles


As1 / VA (2) (4) (5) (2) (4) (5)

4 cycles 11 cycles 11 cycles 14 cycles 42 cycles 42 cycles


As2 / VA (2) (4) (5) (2) (4) (5)

- Edge (Cutting edges, cast ribs, mating surface, fillet, etc.)


(1) No white corrosion is found along the length of the edges
(2) No blistering or no white or red corrosion is found along the length of the edges. No unsticking of the painting film after the stripping test with the adhesive tape (procedure described in the
standard 02-00-005).

- Full-panel or weld
(3) No white corrosion
(4) No blistering or no white corrosion. No separation of the painting film after the stripping test with the adhesive tape (procedure described in the standard 02-00-005).

- Removed full-panel (procedure described in the standard 02-00-005).


(5) Average unsticking of the painting around the scratch < 2.5 mm.

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7.7 PARTS ASSEMBLED WITH DIFFERENT SUBSTRATES: CORROSION AT THE JOINT PERIPHERY

Joint Periphery
METAL 2 or
RUBBER

METAL 1

For example, see pictures in page 20.

Note: The metallic surfaces in contact must be minimal. All the metallic contacts must be electrically isolated.

Rubber materials must also be taken into account. The corrosion test will be not performed if the material data
sheet gives a seal resistivity value of 10 9 .cm.

The validation test that must be conducted in this case is the ECC1 test, based on the standard D17-2028.
The test durations are as follows:

External part (E)

NV No requirement

28 cycles
As0 / VC (1)

35 cycles
As1 / VB (1)

35 cycles
AS1 / VA (1)

42 cycles
AS2 / VA (1)

(1) Bi-metallic corrosion requirements:

measurement of the difference in the damage between the full-skin and the coupling zone:

{(maximum pit depth inside the joint µm) – (maximum depth on full-skin µm)} < 50 µm
{(maximum pit depth at the periphery of the joint µm) – (maximum depth on full-skin µm)} < 50 µm

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