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PART : CHEMISTRY
1. The INCORRECT match in the following is :
fuEu esa xyr feyku fdlesa gS?
(1) G° > 0, K < 1
(2) G° < 0, K < 1
(3) G° = 0, K = 1
(4) G° < 0, K > 1
Ans. (2)
Sol. G= –RTlnK
G< 0 K > 1
H3C CH
CH3
CH2
(1) 3-methyl-4-(3-methylprop-1-enyl)-1-heptyne
(2) 3,5-dimethyl-4-propylhept-1-en-6-yne
(3) 3,5-dimethyl-4-propylhept-6-en-1-yne
(4) 3-methyl-4-(1-methylprop-2-ynyl)-1-heptene
fuEUk ;kSfxd ds fy, IUPAC uke gS %
CH3
H3C CH
CH3
CH2
(1) 3-esfFky-4-(3-esfFkyizksi-1-bZfuy)-1-gsIVkbu
(2) 3,5-MkbesfFky-4-izksfiygsIV-1-bZu-6-vkbu
(3) 3,5-MkbesfFky-4-izksfiygsIV-6-bZu-1-vkbu
(4) 3-esfFky-4-(1-esfFkyizksi-2-vk;fuy)-1-gsIVhu
Ans. (2)
2 6
Sol. 3 5
1 4 7
3,5-Dimethyl-4-propylhept-1-en-6-yne
3,5-MkbZesfFky-4-izksfiygsIV-1-bZu-6-vkbZu
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| JEE (MAIN) 2019 | DATE : 12-04-2019 (SHIFT-2) | PAPER-1 | OFFICIAL PAPER | CHEMISTRY
n
(1) Polyisobutane (2) Polytert-butylene
(3) Polyisobutylene (4) Polyisoprene
fuEu cgqyd dk lgh uke gS:
H3C CH3
n
(1) ikyhvkblksC;wVsu (2) ikyhVVZ-C;wVkbyhu
(3) ikyhvkblksC;wVkbyhu (4) ikyhvkblksizhu
Ans. (3)
H3C CH3
Polymerisation
Sol. CH3–C=CH2
n
CH3
5. NO2 required for a reaction is produced by the decomposition of N2O5 in CCl4 as per the equation
2N2O5 (g) 4NO2(g) + O2 (g). The initial concentration of N2O5 is 3.00 mol L–1 and it is 2.75 mol L–1
after 30 minutes. The rate of formation of NO2 is :
,d vfHkfØ;k ds fy, vko';d NO2 dks CCl4 esa N2O5 ds vi?kVu }kjk mRiUUk djrs gS] tSlk fd uhps lehdj.k esa
gS]
2N2O5 (g) 4NO2(g) + O2 (g). N2O5 dh izkjfEHkd lkUnzrk 3.00 mol L–1 rFkk 30 feuV ds ckn dh lkUnzrk
2.75 mol L–1 gSA NO2 ds lEHkou dh nj gksxh :
(1) 8.333 × 10–3 mol L–1 min–1
(2) 2.083 × 10–3 mol L–1 min–1
(3) 1.667 × 10–2 mol L–1 min–1
(4) 4.167 × 10–3 mol L–1 min–1
Ans. (3)
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1 dN2O5 1 dNO2
2 dt 4 dt
1 1 dNO2
120 2 dt
dNO2 1
Rate of formation of NO2 (NO2 ds lEHkou dh nj½ = M min1 = 1.667 × 10–2 mol L–1 min–1
dt 60
6. Heating of 2-chloro-1-phenylbutane with EtOK/EtOH gives X as the major product. Reaction of X with
Hg(OAc)2/H2O followed by NaBH4 gives Y as the major product. Y is -
2-Dyksjkss -1-QfuyC;wVsu dks EtOK/EtOH ds lkFk xje djus ij X eq[; :Ik esa izkIr gksrk gSA Hg(OAc)2/H2O ds
lkFk X dh vfHkfØ;k rRi'pkr~ NaBH4 ds lkFk vfHkfØ;k ls izkIr Y eq[; mRikn gS :
OH
(1) Ph (2) Ph
OH
(3) Ph (4) Ph
OH
Ans. (3)
OH
HgOAc 2
Sol. Ph
EtOK
Ph Ph
EtOH(E2 elimination) NaBH 4
Cl
(Markovnikov addition product is major in step - 2)
7. 25 g of an unknown hydrocarbon upon burning produces 88g of CO2 and 9 g of H2O. This unknown
hydrocarbon contains :
(1) 22 g of carbon and 3g of hydrogen
(2) 24 g of carbon and 1g of hydrogen
(3) 20 g of carbon and 5g of hydrogen
(4) 18 g of carbon and 7g of hydrogen
,d vKkr gkbMªksdkcZu ds 25 g dks tykus ij 88g CO2 rFkk 9 g H2O mRiUUk gksrs gSA bl vKkr gkbMªksdkcZu esa ;s
lfUUkfgr gSA
(1) 22 g dkcZu rFkk 3g gkbMªkstu
(2) 24 g dkcZu rFkk 1g gkbMªkstu
(3) 20 g dkcZu rFkk 5g gkbMªkstu
(4) 18 g dkcZu rFkk 7g gkbMªkstu
Ans. (2)
Sol. Mass of CO2 = 88g
12
Mass of C = × 88 = 24g
44
Mass of H2O = 9 g
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2
Mass of H = 9 = 1g
18
CO2 dk æO;eku = 88g
12
C dk æO;eku = × 88 = 24g
44
H2O dk æO;eku = 9 g
2
H dk æO;eku = 9 = 1g
18
8. An 'Assertion' and a 'Reason' are given below. Choose the correct answer from the following options :
Assertion(A) : Vinyl halides do not undergo nucleophilic substitution easily.
Reason (R) : Even though the intermediate carbocation is stabilized by loosely held -electrons, the
cleavage is difficult because of strong bonding.
(1) Both (A) and (R) are correct statements and (R) is the correct explanation of (A)
(2) (A) is a correct statement but (R) is a wrong statement.
(3) Both (A) and (R) are correct statement but (R) is not the correct explanation of (A).
(4) Both (A) and (R) are wrong statements.
,d dFku rFkk ,d dkj.k uhps fn;k x;k gSA fuEu fodYiks esa ls lgh mrj dk pquko dhft,
dFku (A) : foukby gSykbM dk ukfHkdjkxh izfrLFkkiu vklkuh ls ugh gksrkA
dkj.k (R) : vn`<+ -byDVªkWuksa }kjk e/;orhZ dkcksZdsVk;u ds LFkkf;Ro ds ckotwn Hkh izcy vkca/ku ds dkj.k fonyu
dfBu gSA
(1) (A) rFkk (R) nksuksa lgh gS rFkk (R), (A) dh lgh O;k[;k gSA
(2) (A) lgh gS ijURkq (R) xyr gSA
(3) (A)rFkk (R) nksuksa lgh gS ijUrq (R), (A) dh lgh O;[;k ugh gSA
(4) (A) rFkk (R) nksukas gh xyr gSaA
Ans. (2)
10. Which one of the following is likely to give a precipitate with AgNO 3 solution?
fuEUk esa ls fdldh AgNO3 foy;u ds lkFk vo{ksi nsus dh laHkkouk gS\
(1) CCl4 (2) CH2=CH–Cl
(3) (CH3)3CCl (4) CHCl3
Ans. (3)
Sol. (CH3)3CCl gives a precipitate with AgNO3 solution easily because t-butyl halides give stable
carbocation.
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11. The coordination numbers of Co and Al in [Co(Cl)(en)2]Cl and K3[Al(C2O4)3], respectively, are :
(en = ethane-1, 2-diamine)
[Co(Cl)(en)2]Cl rFkk K3[Al(C2O4)3], esa Co rFkk Al dh milgla;kstu la[;k;sa Øe'k% gS :
(en = ,sFksu -1, 2-Mkb,sehu)
(1) 3 and 3 (2) 5 and 6
(3) 6 and 6 (4) 5 and 3
(1) 3 rFkk 3 (2) 5 rFkk 6
(3) 6 rFkk 6 (4) 5 rFkk 3
Ans. (2)
Sol. In [Co(en)2Cl]Cl, co-ordination no = 2 × 2 + 1= 5
In Na3 [Al(C2O4)3], co-ordination no = 3 × 2 = 6
[Co(en)2Cl]Cl esa, leUo; la[;k = 2 × 2 + 1= 5
Na3 [Al(C2O4)3] esa, leUo; la[;k = 3 × 2 = 6
H''
H
H
29°
H H'
H
120°
H''
H
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14. What will be the major product when m-cresol is reacted with propargyl bromide (HCC–CH2Br) in
presence of K2CO3 in acetone?
eq[; mRikn D;k gksxk tc m-fØlkWy dks ,lhVksu esa K2CO3 dh mifLFkfr esa izksiftZy czksekbM (HCC–CH2Br) ds
lkFk vfHkd`r fd;k tkrk gSA
OH OH
(1) (2)
CH3 CH3
OH
O
(3) (4)
CH3
CH3
Ans. (4)
OH OK O–CH2–CCH
+ CHC–CH2–Br
K CO SN 2 reaction
Sol. 2
3
Acetone
CH3 CH3 CH3
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16. The molar solubility of Cd(OH)2 is 1.84 × 10–5 M in water. The expected solubility of Cd(OH)2 in a buffer
solution of pH = 12 is :
ty esa Cd(OH)2 dh eksyj foys;rk 1.84 × 10–5 M gSA pH = 12 ds ,d cQj foy;u esa Cd(OH)2 dh lEHkkfor
foys;rk gksxh :
(1) 2.49 × 10–10 M (2) 6.23 × 10–11 M
2.49
(3) 10– 9 M (4) 1.84 × 10–9 M
1.84
Ans. (1)
Sol. Ksp = 4s3 = 4 × (1.84 × 10–5)3 = 24.9 × 10–15
s 10–2
17. The temporary hardness of a water sample is due to compound. X. Boiling this sample converts X to
compound Y. X and Y, respectively, are :
(1) Mg(HCO3)2 and MgCO3 (2) Ca(HCO3)2 and CaO
(3) Mg(HCO3)2 and Mg(OH)2 (4) Ca(HCO3)2 and Ca(OH)2
ty izfrn'kZ dh vLFkk;h dBksjrk ;kSfxd X ds dkj.k gSA bl izfrn'kZ dks mckyus ij X cnydj ;kSfxd Y gks tkrk
gSA X rFkk Y Øe'k% gS :
(1) Mg(HCO3)2 rFkk MgCO3 (2) Ca(HCO3)2 rFkk CaO
(3) Mg(HCO3)2 rFkk Mg(OH)2 (4) Ca(HCO3)2 rFkk Ca(OH)2
Ans. (3)
Sol. 2Mg(HCO3)2 2MgCO3 + H2O + CO2
– –
CO3–2 +H2O HCO3 + OH
–
Mg+2 + 2OH Mg(OH)2
X : Mg(HCO3)2
Y : Mg(OH)2
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19. Benzene diazonium chloride on reaction with aniline in the presence of dilute hydrochloric acid gives :
ruq gkbMªksDyksfjd vEy dh mifLFkfr esa csaTk+hu Mkbtksfu;e DyksjkbM] ,fuyhu ds lkFk vfHkfØ;k djds nsrk gS %
(2) NH2
(3) N=N–NH
N=N
(4) H2N
Ans. (1)
+
N2 NH2
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22. The decreasing order of electrical conductivity of the following aqueous solution is :
0.1 M Formic acid (A)
0.1 M Acetic acid (B)
0.1 M Benzoic acid (C)
fuEUk tyh; foy;uksa dh fo|`rh; pkydrk dk ?kVrk Øe gSA
0.1 M QkfeZd ,flM (A)
0.1 M ,flfVd ,flM (B)
0.1 M csUtksbd ,flM (C)
(1) A > B > C
(2) A > C > B
(3) C > A > B
(4) C > B > A
Ans. (2)
Sol. Since acidic strength follows order HCOOH > C6H5COOH > CH3COOH
pwafd vEyh; lkeF;Z fuEu Øe dk vuqlj.k djrh gS HCOOH > C6H5COOH > CH3COOH
lkUnz NaOH foy;u dk iz;ksx djrs gq;s] ckDlkbM dk fu{kkyu lksfM;e ,yqehusV rFkk lksfM;e flyhdsV nsrk gSA
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25. Thermal decomposition of a Mn compound (X) at 513K results in compound Y, MnO 2 and a gaseous
product. MnO2 reacts with NaCl and concentrated H2SO4 to give a pungent gas Z. X, Y and Z,
respectively are :
(1) KMnO4, K2MnO4 and Cl2
(2) K2MnO4, KMnO4 and SO2
(3) K3MnO4, K2MnO4 and Cl2
(4) K2MnO4, KMnO4 and Cl2
513K ij ,d Mn ;kSfxd (X) ds rkih; vi?kVu ls ;kSfxd Y, MnO2 rFkk ,d xSlh; mRikn izkIRk gksrk gSA NaCl
RkFkk lkUnz H2SO4 ls MnO2 vfHkfØ;k djds ,d rh[kh xSl Z nsrk gSA X, Y rFkk Z Øe'k% gS :
(1) KMnO4, K2MnO4 rFkk Cl2
(2) K2MnO4, KMnO4 rFkk SO2
(3) K3MnO4, K2MnO4 rFkk Cl2
(4) K2MnO4, KMnO4 rFkk Cl2
Ans. (1)
Sol. KMnO4 K2MnO4 + MnO2 + O2 (g)
(X) (Y)
MnO2 + 2NaCl + 2H2SO4
MnSO4 + Na2SO4 + Cl2 +H2O
(Z)
Ag2O
ppt
A
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30. A solution is prepared by dissolving 0.6 g of urea (molar mass = 60g mol–1) and 1.8g of glucose (molar
mass = 180 g mol–1) in 100 mL of water at 27°C. The osmotic pressure of the solution is :
(R = 0.08206 L atm K–1 mol–1)
27°C ij] ,d foy;u dks 100 mL ty esa 0.6 g ;wfj;k (eksyj nzO;eku = 60g mol–1) rFkk 1.8g Xywdkst (eksyj
nzO;eku = 180 g mol–1) ?kksydj rS;kj fd;k x;kA foy;u dk ijklj.k nkc gksx :
(R = 0.08206 L atm K–1 mol–1)
(1) 8.2 atm (2) 1. 64 atm
(3) 2.46 atm (4) 4.92 atm
Ans. (4)
Sol. = CRT
(n n ) 1000 0.6 1.8 1000
= 1 2 RT = 60 180 100 0.082 300
V
= [(0.01 + 0.01) × 10] × 0.082 × 300 = 4.92 atm
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