Professional Documents
Culture Documents
FACULTY OF TECHNOLOGY
DEPARTMENT OF GEOLOGY AND MINING
MASTER OF SCIENCE
in
MINERAL GEOSCIENCES
by
Samantha C. Kromopawiro
The thesis written by Samantha C. Kromopawiro, entitled “2.12 – 2.07 Ga Late- to post-
collisional peraluminous granitoid magmatism in the Marowijne Greenstone Belt of Suriname”,
has been approved with respect to style and intellectual content and is referred to you for
judgement.
…………………………………..
Prof. Dr. Th. E. Wong
Coordinator of the Master of Science course Mineral Geosciences
Head of the department Geology and Mining
i
TO THOSE IN NEED OF SOME INSPIRATION
ii
Abstract
Granitoid magmatism within the Marowijne Greenstone Belt occurred during several episodes
between 2.19 and 2.07 Ga. The first episode emplaced TTG-suites in multiple phases between
2.19 – 2.16 Ga and 2.15 – 2.11 Ga. During the second TTG phase, processes within the
continental crust yielded within-plate granite plutons, such as the Tibiti granite (~2119 Ma), to
emerge as the result of possible lithospheric structural activities, unrelated to subduction. The
Tibiti granite is classified as a calc-alkalic peraluminous biotite granite, derived from an
intermediate to mafic magma source. The second episode of magmatism within the
greenstone belt, took place during syn- to late-, and maybe even post-collisional events
between 2.10 – 2.07 Ga. During this episode, the Phedra granite was emplaced (~2093 Ma)
within a syn-tectonic setting. This granitic unit is classified as an alkalic- to alkali-calcic
peraluminous two-mica granite, with an intermediate derived sedimentary magma source
rock. The Akinto Soela granite (~2074 Ma) was emplaced at a slightly later stage of the second
magmatic episode with late- to post collision characteristics. This granite is classified as an
alkalic- to alkali-calcic granite, with both peraluminous and metaluminous affinities, suggesting
assimilation of mafic rock material. This unit shows differentiation within its composition, from
the occasional hornblende and no muscovite, to no hornblende and minor muscovite.
Considering the ages, the Akinto Soela, Phedra and the Patamacca granites are interpreted
to be from the same magmatic pulse, showing variation in composition, mainly due to their
tectonic environment and precursor magma source rocks.
Gold mineralization related to any of these granitic occurrences is ruled out, as these units
demonstrate ages that are older than the mineralization events. Other resources such as Sn,
Nb, Ta and Be in pegmatites would be better exploration targets within close vicinity of these
plutons.
iii
Acknowledgements
Sincere gratitude goes towards Prof. Dr. Kroonenberg, whose support and encouragement
throughout the final stages of the master’s course was indispensable and truly appreciated,
and to Prof. Dr. Wong whose constant speeches of motivation ensured the completion of this
thesis. A special thank you is addressed to Dr. Kriegsman, who made time available to assist
in the age dating processes for this report. The exploration companies Hazlo Geo-Solutions,
Ponsor Mining and Kuldipsingh Mining are thanked for their field assistance. Chervin is
thanked for assisting with the petrography. And finally, the most profound gratitude goes
towards my family and friends for their support in all forms possible, especially during the final
stages of writing.
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Table of Content
Abstract................................................................................................................................. iii
Acknowledgements ............................................................................................................... iv
1. Introduction ....................................................................................................................... 1
2. Geological Setting ............................................................................................................. 2
2.1 Regional Geology ........................................................................................................ 2
2.2 Geology of Suriname ................................................................................................... 4
2.2.1 The Marowijne Greenstone Belt ............................................................................... 5
2.2.2 TTG Plutonism in the Marowijne Greenstone Belt .................................................... 5
2.3 Granitoids of the Marowijne Greenstone Belt ............................................................... 5
3. Methodology ................................................................................................................... 10
3.1 Literature study and previous work ............................................................................ 10
3.2 Field work and sampling ............................................................................................ 10
3.3 Petrographic analysis ................................................................................................ 10
3.4 Geochemical analysis ................................................................................................ 11
3.4.1 X-Ray Fluorescence ............................................................................................... 11
3.4.2 LA-ICP-MS ............................................................................................................. 11
3.5 Zircon U-Pb Age Dating ............................................................................................. 11
3.6 Assessment and Interpretation .................................................................................. 12
4. Results ............................................................................................................................ 13
4.1 Compilation of previous work ..................................................................................... 13
4.2 Field observations ..................................................................................................... 13
4.3 Petrographic Observations ........................................................................................ 18
4.3.1 Akinto Soela thin sections ....................................................................................... 18
4.3.2 Phedra thin sections ............................................................................................... 22
4.3.3 Tibiti thin sections ................................................................................................... 23
4.3.4 Mineralogical classification ..................................................................................... 23
4.4 Geochemistry ............................................................................................................ 24
4.4.1 Major element classification .................................................................................... 24
4.4.2 Trace element classification.................................................................................... 30
4.4.3 REE and Spider diagrams ...................................................................................... 33
4.5 U-Pb zircon age dating .............................................................................................. 37
5. Discussion ...................................................................................................................... 41
Magmatic evolution of the Marowijne Greenstone Belt .................................................... 42
Evidence for a granite batholith under the Marowijne Greenstone Belt ............................ 44
6. Conclusion ...................................................................................................................... 47
v
Recommendation ................................................................................................................ 50
References ......................................................................................................................... 51
Appendices ......................................................................................................................... 57
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List of Figures
vii
Figure 33: Concordia diagram of the Akinto Soela zircons measurements .......................... 39
Figure 34: Schematic diagram illustrating the possible source regions of magmatism of the
northeastern Marowijne Greenstone Belt ............................................................................ 43
Figure 35: Map illustrating the modeled topography of the granite batholith ........................ 45
Figure 36: Geological map of the area of the Stofbroekoe Mountains ................................. 46
viii
List of Tables
ix
Abbreviations
cm – centimeter
Ga – giga-annum (billion years)
GMD – Geologische en Mijnbouwkundige Dienst (Geology and Mining Services)
HREE – heavy rare earth element
I-type – igneous type
km – kilometer
LA-ICP-MS – Laser Ablation Inductively Coupled Mass Spectrometry
LREE – light rare earth element
Ma – mega-annum (million years)
mm – millimeter
MSWD – mean square of weighted deviation
n– population
ORG – ocean ridge granite
ppm – parts per million
QAPF – quartz – alkali-feldspar – plagioclase – feldspatoid
REE – rare earth element
S-type – sedimentary type
Syn-COLG – syn-collisional granite
TTG – Tonalite, Trondhjemite, Granodiorite
VAG – volcanic arc granite
WPG – within plate granite
XPL – crossed polarized light
XRF – X-Ray Fluorescence
µm – micrometer
g/cm –
3
grams per cubic centimeter
<LD – below detection limit
x
1. Introduction
The Marowijne Greenstone Belt is host to two of the largest gold districts of Suriname and its
potential for additional mineral resources is still high with more valuable discoveries yet to be
made. However, this metamorphic belt is considered underexplored in comparison to
neighboring countries. This report attempts to understand the geochronology of magmatism
within the northeastern greenstone belt and possibly identify their spatial context.
The aim of this study is to use geochemical and petrographic analyses to understand the
characteristics and chronology of several of the granite occurrences in this belt and compare
these to known granitic units in Suriname and neighboring countries. Three (3) granite units
are studied for this report, including the Akinto Soela, Tibiti and Phedra granites. Recent work
on the Brinck pluton and the Patamacca granite are used for comparison. To characterize the
granitic units and identify their place in the geological setting of the greenstone belt, the
following research question is asked:
- What is the geotectonic evolution of granitoid magmatism in the Marowijne Greenstone
Belt?
In order to answer this question, several characteristics need to be identified. The tectonic
setting, the magma source, but most importantly, the ages of the granitic rocks need to be
known. Understanding these plutonic bodies and their geological setting may not only lead to
the discovery of other potential resource commodities, but might also give further insight as to
where and how to continue exploring and expanding current resources, such as gold, within
the greenstone belt.
This report is divided into several chapters that finally lead to the concluding answer to the
research question. In chapter 2, an introduction is given on the geological setting and locations
of the granitoids of the Marowijne Greenstone Belt. Chapter 3 summarizes the various
methods and analytical techniques conducted on the samples. In chapter 4, the results are
presented in the form of diagrams, followed by the corresponding discussions in chapter 5.
The concluding remarks are presented in chapter 6 and an approach for additional work is
summarized in chapter 7.
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2. Geological Setting
Figure 1: Simplified geological sketch map of the Guiana Shield (Delor et al., 2003a) with Suriname highlighted in
red.
CENOZOIC: 1 - Alluvium cover; MESOZOIC: 2 - dolerite and sediment; PALEOZOIC: 3 - Amazon margin sediment; NEOPROTEROZOIC: 4 –
alkaline basalt, 5 - alkaline plugs; MESOPROTEROZOIC: 6 - granite, 7 - sediment, 8 - basic sill/dyke (Avanavero), 9 - sediment (Roraima Group),
10 - acid plutono-volcanism; TRANSAMAZONIAN tectonothermal episode: 11 - granitoid, 12 - ultrabasic plug, 13 - greenstone belt, 14 - granulite
(Central Guiana); ARCHEAN: 15: granulite and migmatite (Imataca).
2
Delor et al. (2003a) characterizes the main stages for the formation of the Guiana Shield
(Figure 2) as follows:
- The Eorhyacian stage (2.26 – 2.20 Ga) of mantle extraction and extensive ocean floor
magmatism as result of the separation of the Amazonian and African plates.
- The Mesorhyacian stage (D1) (2.18 – 2.13 Ga) of isoclinal folding and low-grade
metamorphism (Kroonenberg et al., 2016) as the result of N-S convergence and
collision of the Amazonian and African Cratons, through southward-directed
subduction of oceanic crust, followed by dominant TTG magmatism and regionally
associated greenstone belt formation (Delor et al., 2003a).
Figure 2: A geodynamic evolution model for the Guiana Shield (Delor et al., 2003a).
- The Neorhyacian stage (D2) (2.11 – 2.06 Ga) is split up in to the deformation stage
(D2a) (2.11 – 2.08 Ga) and the tectonic stage (D2b) (2.07 – 2.06 Ga).
3
During the D2a stage, more granitic magmatism and migmatization of earlier TTG-
greenstones occurred in response to the closure of the island-arc basins, due to
sinistral sliding caused by continuing convergence. Detrital basin opening also
occurred in areas where crustal stretching was maximum (pull-apart basins).
During the late D2b stage, further crustal stretching lead to dextral shearing and
emplacement of syn-tectonic granites and high-grade metamorphism of the Bakhuis
granulite belt.
- The late-Transamazonian Orosirian stage (2.01 – 1.93 Ga) of younger high-grade
metamorphism and acid volcanic activity.
Figure 3: Simplified geological map of Suriname with the main units, after Bosma et al. (1977), modified by
Kroonenberg et al. (2016).
Suriname lies in the central part of the Guiana Shield and consists of 80% Precambrian rocks
and 20% Cretaceous to recent sediments (Figure 3). The Precambrian basement of Suriname
consists of a low-grade Marowijne Greenstone Belt in the northeast, two high-grade
metamorphic belts, the Bakhuis Granulite Belt in the northwest and the Coeroeni Gneiss Belt
in the southwest, and a vast granitoid-volcanic complex in the central part of the country. A
sandstone remnant of the Roraima Supergroup, the Tafelberg formation, overlays the
basement and Proterozoic and Early Jurassic dolerite dykes transect the older rock formations
(Kroonenberg et al., 2016).
4
2.2.1 The Marowijne Greenstone Belt
The main Paleoproterozoic Marowijne Greenstone Belt in the northeastern part of Suriname
shows an asymmetrical syncline structure with the Paramaka Formation in the outer side and
the younger Armina Formation in the core of the syncline. Diapiric TTG bodies, including small
mafic to ultramafic plutons, intruded the Paramaka Formation in the southwest, while smaller
two-mica granites intruded the Armina Formation in the northeast. The ultramafic- and TTG
plutonism is considered by Kroonenberg et al. (2016) to have occurred simultaneously with
the Paramaka Formation, but before the deposition of the Armina Formation. The Rosebel
Formation overlays both the Armina and Paramaka Formations unconformably. The
Marowijne Greenstone Belt borders a belt of migmatitic gneisses, the Sara’s Lust Gneiss, on
both flanks of the syncline structure (Kroonenberg et al., 2016).
5
crust underneath the area of influence to partially melt. Sometimes, parts of the Earth’s upper
mantle can melt as well and create magma chambers, which can feed upward lying plutonic
bodies. The rate at which a plutonic rock or body crystallizes is extremely slow and therefore,
many granitoid rocks post-date the thickening event by tens of millions of years (Pearce et al.,
1984; Harris et al., 1986).
The various granitic occurrence studied in this report are all located in the Marowijne
Greenstone Belt. Figure 4 illustrates the various units of this belt, including all granitic
occurrences, with brief descriptions of each in the following paragraphs.
Figure 4: Geological map of the Suriname after Bosma et al. (1977) and Kroonenberg et al. (2016) with the
northeastern Marowijne Greenstone Belt highlighted in black. The Greenstone Belt is comprised of an older
volcanic-sedimentary complex of the Paramaka and Armina Formation, intruded by granitoids, which are overlain
by sediments of the Rosebel Formation. Locations of the various granitic occurrences are indicated on the map.
6
big massif at the time of O’ Herne’s investigation. This is the reason that the biotite-granite,
the two-mica-granite and the magmatic gneiss in the area were classified as one single unit,
G3 (Granite 3) by O’ Herne (1958).
For the 1977 geological map of Suriname by the GMD (1977) this particular area was re-
evaluated and a new outline for the Akinto Soela granite was generated and is classified as
Unit 23, biotite-granite (Figure 4). The contact relationships with the surrounding units have
not been properly identified yet, mainly due to extensive weathering, but the combination of
topography, regolith and actual outcrop data has resulted in the particular lung-shaped outline
of this granitic unit.
After O’ Herne’s work in 1958, no other investigations were conducted on the actual Akinto
Soela biotite-granite, and this report is the first attempt since then, to understand the
relationship with other granitic units in the northwestern part of the country. Several small
mining companies have done work in the area and exposed unweathered rock, which made it
possible to continue this research.
7
A recent study on the Patamacca granite was conducted by Yang (2014). He classified this
granite as peraluminous S-type, derived from high-grade meta-pelitic parent lithology, and
suggests an origin in a syn-collisional tectonic setting, most likely emplaced during the period
of oblique plate convergence and sliding between the Amazonian and African plates.
8
Guiana (Kroonenberg et al., 2016). From the continuation of the southernmost Suriname
tonalite batholith into French Guiana a zircon Pb evaporation age of 2141 ± 8 Ma has been
obtained (Delor et al., 2003a).
9
3. Methodology
In order to answer the main research question and understand the characteristics of the
granitic occurrences, various work methods were used to come to a satisfying conclusion. This
consisted of a literature study with the compilation of previous work, new investigations and
fieldwork for the collection of additional information and samples, chemical and petrographic
analysis for compositional characteristics, U-Pb zircon age dating for determining time of
formation, and an assessment of the obtained data using various research references and
discrimination schemes.
10
3.4 Geochemical analysis
A total of 6 samples from the Akinto Soela, Tibiti and Phedra area were sent for whole rock
geochemical analysis on major- and trace elements. The method used to determine the major
element concentrations was the XRF (X-Ray Florescence) and the samples were sent to the
Geolab of the Utrecht University for analysis, conducted by a Bachelor’s student. For the trace
element concentrations, Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-
ICP-MS) was used.
3.4.2 LA-ICP-MS
LA-ICP-MS (Laser Ablation Inductively Coupled Plasma Spectrometry) is an analytical
technique for the detection of metals and non-metals using a plasma torch to activate
elements, a laser beam and a mass spectrometer. This technique can be used directly on
solid samples with minimal preparation. The laser beam forces the release of atoms from the
surface of an object into the plasma torch and subsequently into the mass spectrometer. This
technique is able to detect low concentrations, from part per trillion (ppt) to the part per million
(ppm) and is therefore suitable to use for trace element determination (Rollinson, 1993).
Fragments of the glass beads used for the XRF analysis were used for the LA-ICP-MS
analysis of the granitic samples and the calculations of the trace element concentrations was
done using the GLITTER software.
11
zircons can be used to determine the age, as the assumption can be made that the entire lead
content in the mineral is radiogenic.
The samples were crushed to retrieve grains between 60 and 250 μm, using a jaw-crusher.
Followed by a two-step heavy liquid separation (2.9 g/cm3 and 3.3 g/cm3), the heavy fraction
of the sample was removed. Zircons were separated from other minerals according to their
magnetic properties using a Frantz magnetic seperator and subsequently hand-picked using
a microscope. The zircon samples were moulded with an epoxy-like substance to prevent the
zircons from either moving or polluting. The moulds were then abraded using silicon carbide
to such extent that the zircons were dissected (more or less in half), granting a plane to analyze
under the electron microprobe for Cathodoluminescence (CL) imaging. Additional scanning
electron images (SE) and electronic backscatter images (BSE) were taken for the most
promising (e.g. most euhedral/ undamaged) zircon crystals, to obtain measuring locations of
238 235 207 206
the LA-ICP-MS. The isotopes measured by mass spectrometry are U, U, Pb, Pb,
208 204
Pb and Pb. The Glitter software was used to analyze the LA-ICP-MS data. The ages
calculated by Glitter were based on the ratios 207Pb/206Pb.
12
4. Results
In this chapter, the results are presented using location maps, photographs and various
discrimination diagrams to illustrate the findings for this report. A combination of both
historically obtained data and results from this study are evaluated.
Figure 5: Location map of the collected samples from the different granitoids of the Marowijne Greenstone Belt with
the geological map (Bosma et al, 1977) as background. The author herself collected samples of the Tibiti, Phedra
and Akinto Soela areas, while the other locations were taken from authors that worked in each of the specific areas.
For the Akinto Soela Granite, samples were taken at three (3) different locations of the intrusive body.
Field work was conducted in the Akinto Soela and the Phedra areas for sample collection and
mapping purposes to understand the contact relationships of the intrusions with their host
rocks. However, establishing the contact boundaries was limited due to extensive weathering
conditions and identifying the contact relationships was unsuccessful.
13
In total 12 samples were collected for petrographic study, 6 samples for geochemical analysis
and 3 samples for U-Pb age dating on zircons. A summary of the collected samples is given
in Table 1 and the locations of the collected samples are illustrated in Figure 5.
Figure 6: Images of the exposed Akinto Soela Granite. a.) Exploration pit exposing large boulders of the granite on
the subsurface; b.) Boulder of the granite with geologist for scale; c.) Drill core samples of the Akinto Soela, clearly
showing the well-defined K-megacrysts in a coarse-grained texture; d.) Kuldipsingh Quarry exposing the underlying
fresh rock of the Akinto Soela; e.) Inclusion of xenolith in contact with the granitic intrusion.
From the unweathered rock it is clear that the Akinto Soela granite is medium- to coarse
grained, porphyritic in texture and is comprised of quartz, feldspars and biotite as the
groundmass with euhedral rectangular K-feldspar megacrysts (Figure 6c). The mineralogical
14
composition of this granite appears to be similar in various locations with minor differences in
the percentage of the mafic component. In total 8 samples were collected of the Akinto Soela
granite for petrographic and chemical analyses, including one (1) sample collected in a creek
bed exposing a finer grained variety of this specific granitoid rock.
Figure 7: Sample of the Phedra granite collected along the abandoned quarry of N.V. Luna.
15
Figure 8: Photographs of the pink Tibiti granite. The left photograph shows a weak banded texture in the rock and
the right photograph, the medium to coarse grained texture is presented.
16
Table 1: Sample descriptions and geographical location coordinates taken from the Akinto Soela, Phedra and Tibiti area. Several
samples were selected for two (2) or more analysis methods.
U/Pb
Sample Thin XRF/LA- Age
ID Location Section ICP-MS Dating Easting Northing Rock description
ASG-02 Akinto Soela - X X Drill core - White-gray porphyritic rock with euhedral rectangular K-feldspar
Ponsor megacrysts (up to 2-3 cm in length and 1-1.5cm in width), making up
ASG-03 X approximately 25% of the total mineralogical composition. The anhedral
Mining 735639 580679 groundmass is coarse grained (0.5 – 0.7 cm) and consists of quartz
Exploration (±30%), feldspars (±30%) and biotite (±10%) as the mafic constituent.
ASG-11 concession X X Traces of pyrite observed in fracture planes.
Porphyritic rock with euhedral K-feldspar megacrysts (up to ±20%) and an
anhedral coarse grained groundmass consisting of quartz (±30%),
feldspars (±35%) and biotite (±10%). Observable amounts of light green
ASG-05 X X 733908 577934
epidote present in the sample, as part of the groundmass. Locally pink
alteration within the sample (possible potassic alteration (?)). Traces of
sulphides observed as well.
Akinto Soela -
Sample of the contact between the Akinto Soela granite and a mafic
ASG-08 Kuldipsingh X 733928 577912 xenolith with a dark gray to dark brown color, an abundance of biotite and
Quarry a wavy schistose texture.
Sample of the Xenolith; dark gray to dark brown with schistose texture,
ASG-09 X consisting predominantly of biotite.
Light gray coarse grained rock with an observable larger amount of mafic
ASG-10 X X 733943 577922 constituents. Mineralogy consists of quartz (30-35%), feldspar (40-45%)
and biotite (15-20%, in clusters) and possible minor amounts of amphibole.
Gray medium-coarse rock with weakly layered biotite. The rock
Akinto Soela - composition consists of quartz (40%), feldspars (35%) and mafic
constituents, mainly biotite (15%). The absence of k-feldspar phenocrysts
ASG-06 Creek bed X X 731757 581974 is noticeable. The edges of the sample are slightly weathered. Finer
outcrop grained material is observed at the boundary of the sample, appearing
more aplitic.
Pinkish colored, medium to coarse grained rock, with weak banding.
ASG-12 Tibiti X X X 626703 568605 Mineralogy consist predominantly of feldspars, quartz and biotite as mafic
constituent.
ASG-13 Phedra - N.V. X X 716113 589005
White to light gray coarse grained granite with quartz (25-30%) and
Luna
ASG-14 X 716113 589005 feldspars (50%), both k-feldspar and plagioclase, as dominant minerals.
abandoned Muscovite (5%) and biotite (5-10%).
ASG-15 Quarry X X 716113 589005
17
4.3 Petrographic Observations
Petrographic analysis using thin sections provided insights on the textures, mineral composition
and relations between minerals, and in one (1) sample the contact of the Akinto Soela with a
xenolith. The thin sections confirm or exclude the presence of minerals, which are unidentifiable
to the naked eye. An estimation was made for the modal compositions and notes were taken of
any observable significance. Few noticeable differences were observed between the samples
from the granitic bodies studied for this report. In Table 1 the samples are summarized according
to their location and with the designated sample numbers and descriptions.
18
Figure 9: Microphotographs of thin sections from the Akinto Soela Granite (Ponsor Mining). a.) Myrmekitic intergrowth
of plagioclase and quartz in a K-feldspar megacryst. b.) Opaque minerals, pyrite and magnetite in fractures. c.)
Muscovite and biotite minerals. d.) Biotite and muscovite with pleochroïc halos caused by radioactive decay of zircons.
e.) Fine grained equivalent of the Akinto Soela granite, primarily consisting of quartz and feldspars.
19
Kuldipsingh Quarry
Samples from the quarry showed variation in mineralogical composition, mainly in the mafic
components. Sample ASG-05 is described as a holocrystalline porphyritic rock with sub- to
euhedral microcline megacrysts and a medium coarse groundmass (1-5mm). This particular
sample has a modal composition of plagioclase (35%), quartz (25%), K-feldspar (20%), green
biotite (15%) and traces (<1%) of epidote, titanite, zircon, allanite, tourmaline and opaques
(magnetite and pyrite). Observed textures include perthite, pleochroïc halos from zircons in biotite
grains and graphic texture. Sericite is observed as a weak alteration product.
The xenolith in contact with the ASG-05 is described to be an amphibole-biotite schist with a
modal composition of green biotite (55%), amphibole (25%), K-feldspar (10%), quartz (<5%),
titanite (1%) and traces (<1%) of carbonate, zircon, allanite and sericite/epidote. The rock is
foliated, marked predominantly by orientated grains of mica and amphibole (lepido-nematoblastic
texture). Coarse grains of individual subrounded quartz and microcline with the micas oriented
and elongated along the sides of the minerals. No distinctive plagioclase observed. Distinguishing
between and identifying the finer tabular minerals was difficult, as the gray colored minerals in
XPL displayed no uniaxial positive interference, indicating that these crystals are either K-feldspar
or plagioclase. However, the twinning is also unclear in XPL. Sericite is present as possible
alteration product.
Near the contact of the granite and the xenolith the amphibole grains are not as oriented and do
not have the linear fabric texture; they form a decussate or diablastic texture (equigranular,
interlocking, randomly orientated platy, and tabular, prismatic or elongate minerals). Also
observable is the increasing amount of titanite grains towards the contact.
In the quarry mine, a more mafic variation of the Akinto Soela was sampled (ASG-10). From the
thin section the sample is described to be a holocrystalline fine to medium grained rock with
subheral mineral grains, with a modal composition of plagioclase (30%), quartz (25%), K-feldspar
(20%), biotite – green (10%), amphibole (5%), epidote (2%) and traces (< 1%) of chlorite (?),
epidote/sericite, zircon, and titanite. The biotites are clustered giving the rock a more mafic
appearance.
One significant observation of these two (2) samples (ASG-05 and ASG-10) from the Kuldipsingh
Quarry is the absence of muscovite in the thin sections, which confirms the observation made by
O’ Herne (1958) for this specific granitic unit. Microphotographs of the observations from the
quarry thin sections are given in Figure 10.
20
Figure 10: Microphotographs of thin sections from the Akinto Soela Granite (Kuldipsingh Quarry). a.) Hornblende
mineral in ASG-10. b.) Subhedral titanite grains. c.) K-feldspar megacryst showing carlsbad twinning and a perthitic
texture. d.) Epidote mineral as part of the groundmass of the granite and biotite grains with pleochroic halos. e.)
Tourmaline grains. f.) Xenolith with diablastic texture of and tabular/platy minerals interlocking K-feldspar grain.
21
Outcrop from Creekbed
The sample from the creek (ASG-06), the one with a more aplitic texture (Figure 9e) is described
to have a modal composition of k-feldspar (35%), quartz (30%), plagioclase (25%), biotite (3%),
muscovite (2%), and traces (<1%) of allanite (?), epidote, titanite, zircon and opaques.
The rock is holocrystalline equigranular with medium coarse grains (1-5mm) transitioning into a
finer grained (0.5-1mm) unit (possible aplite) via a sharp contact, which appears to be very slightly
weathered (?). Biotite inclusions in microcline is observed in the coarser parts. Observed textures
include perthite, pleochroic halos from zircons in biotite grains and a weak undulose extinction of
quartz. Sericitization is observed as an alteration product.
Figure 11: Microphotographs of thin sections from the Phedra granite. a.) Coarse grains of K-felspar with biotite and
muscovite plates. b.) Large grains of the rock forming minerals quartz, plagioclase, muscovite and biotite.
22
4.3.3 Tibiti thin sections
The Tibiti granite (ASG-12) is described as a holocrystalline coarse grained rock with an- to
subhedral grains. The sample has a modal composition of quartz (45%), plagioclase (25%), K-
feldspar (25%), biotite – brown to reddish-brown (5%) and traces (<1%) of zircon, opaques,
sericite and chlorite (<1%). The biotite grains are slightly transitioning into chlorite. No traces of
epidote or titanite observed, indicating a low Ca-content, similar to the Phedra granite.
Microphotographs of the observations sections are given in Figure 12.
Figure 12: Microphotographs of thin sections from the Tibiti granite. a.) Reddish-brown biotite grain showing weak
pleochroïc halos. b.) Rock forming minerals of the Tibiti Granite, including quartz and k-feldspars.
23
Figure 13: General classification and nomenclature of felsic plutonic rocks according to mineral content (in volume %)
by Streckeisen (1976). All samples of the various study areas plot in the granite field. The Patamacca granite plotted
as well (Yang, 2014). Only the samples analyzed for this report are labeled.
4.4 Geochemistry
The XRF and LA-ICP-MS analytical methods were used to determine the chemical composition
of the various granites studied for this report. The results are presented in Table 2. Analytical data
of other granitic units of the Marowijne Greenstone Belt from previous authors are also
incorporated into the classification schemes for comparison purposes.
24
Table 2: Analytical results of major- and trace element concentrations.
Area Akinto Soela Akinto Soela Akinto Soela Akinto Soela Tibiti Phedra
25
Table 3: Results of the major element concentrations by the TU Delft and the Utrecht University.
Figure 14: Diagram showing the XRF results of TU Delft lab versus the results of the Utrecht University. The results
from Utrecht show a higher K2O concentration and a slightly lower Na2O- and P2O5 concentration.
For this report, the author continued to use the results from the Utrecht University for the
classification schemes and discrimination diagrams, as this institute continued with the LA-ICP-
MS analysis of the trace element concentrations, using the same beads prepared for the XRF
analysis.
26
rocks. The regions of the TAS diagram are named after familiar (and unfamiliar) magma types,
defined by Le Maitre et al. (1989). The different fields were redefined for plutonic rocks by
Middlemost (1994) and in Figure 15 this diagram is illustrated. The Tibiti and Phedra samples plot
as granites, similar to the Brincks granite, while the Akinto Soela samples are classified as Quartz
Monzonites.
Figure 15: Classification of the granitoid rocks on the TAS diagram after Middlemost et al. (1994). The Tibiti and Phedra
granites plot in the Granite-field, while the Akinto Soela granite plots in the Quartz-Monzonite field.
27
Figure 16: ASI-classification of the granitoid rocks after Shand (1947), with discrimination fields for different
geochemical types of granitoids, after Maniar and Picolli (1989). The Akinto Soela granite plots in both the peraluminous
and metaluminous fields. The latter corresponds with the more mafic granitic samples of the area (ASG-05 and ASG-
10), with no muscovite in the mineral composition. The Tibiti and Phedra granites both plot in the peraluminous fields.
Only the samples analyzed for this report are labeled.
Figure 17: ASI-diagram (Al/Ca+Na+K vs SiO2) for the classification of the granitoids into I- and S-types, after Chappell
and White (1974). The granitic samples studied in this report all plot as I-type with ASI values < 1.1. Symbols are the
same as Figure 16.
In Figure 17, the ASI diagram after Chappell and White (1974), the samples studied for this report,
all plot as I-type granites with ASI values < 1.1. This is not uncommon as many I-type granites
can be peraluminous (Chappell and White, 1974; Chappel et al., 1998). I-types are considered
28
rocks formed from magmas derived from igneous sources (Chappell and White, 1974) and are
supposed to be Al undersaturated, but crystal fractionation can convert the restite melt to become
felsic with ASI values slightly converging towards greater than one, so that they are slightly
oversaturated in Al (Chappell et al., 1998). However, this criteria alone is insufficient to classify
these occurrences as strong I-type granites and more evidence is required to validate such
statements.
Figure 18: MALI index after Frost et al. (2001) illustrating the Akinto Soela and Phedra granites having an alkalic to
alkali-calcic character and the Tibiti granite to have a calc-alkalic character similar to the Brink pluton.
Harker Diagrams
The samples of the Akinto Soela granite show some differentiation in composition, but from the
linear trends of some of the major elements (Figure 19), these samples can be considered as part
of the same pluton with ASG-10 as the most mafic component, containing hornblende, and ASG-
29
06 as the most felsic. In the Harker diagrams SiO2 shows negative correlations with CaO, MgO
and Fe2O3 suggesting fractionation of mafic minerals, such as hornblende. A positive correlation
with Na2O3 indicates plagioclase fractionation of the melt.
The Harker diagrams in Figure 20 show a strong negative correlation of SiO2 with MgO and CaO,
and weak correlations with Fe2O3 and K2O for the Akinto Soela, Phedra and the Patamacca
granites. This suggests possible influence of the same magmatic episode for these rocks and will
be further investigated using the trace elements discrimination schemes.
Figure 19: Harker diagrams of the Akinto Soela granite samples. Negative correlations of SiO2 with MgO, CaO and
Fe2O3 observed and a positive correlation with Na2O, indicating plagioclase fractionation.
Figure 20: Harker diagrams of the Akinto Soela (red), Phedra (green) and Patamacca (black) samples. Strong negative
correlations of SiO2 with MgO and CaO. Symbols are the same as Figure 16.
30
Figure 21: Tectonic discriminant diagrams after Pearce et al. (1984). a.) Nb-Y diagram in which all samples plot in the
VAG and syn-COLG field. b.) Ta-Yb diagram showing the Akinto Soela and Phedra samples plotting as syn-COLG,
and the Tibiti sample plotting as WPG. c.) Rb-(Yb+Ta) diagram illustrating the Tibiti sample plotting as a WPG, the
Phedra sample as syn-COLG and the Akinto Soela samples occupying the triple corner of the WPG, the VAG and the
syn-COLG fields. d.) Rb-(Nb+Y) diagram showing the Akinto Soela and Tibiti samples plotting as VAG and the Phedra
sample plotting as syn-COLG.
In the Y vs Nb diagram (Figure 21a), all samples are plotted within the VAG and syn-COLG field,
but this diagram does not distinguish between VAG and syn-COLG (Pearce et al., 1984). The
Akinto Soela and the Phedra granites plot as syn-COLG in the Yb vs Ta discrimination diagram,
while the Tibiti granite plots as WPG (Figure 21b). In the Rb vs (Yb+Ta) diagram, the Akinto Soela
samples plot on the border of VAG and syn-COLG, the Tibiti granite plots as WPG and the Phedra
granite as syn-COLG (Figure 21c). In the Rb vs (Nb+Y) diagram, all samples plot as VAG, except
for the Phedra granite, which plots as syn-COLG (Figure 21d). However, the two latter diagrams
are unreliable as Rb is slightly mobile in volatile phase during hydrothermal conditions (Pearce et
al., 1984; Harris et al., 1986). Out of the four diagrams, the Yb vs Ta diagram is the most reliable
for characterizing the samples, as this diagram well distinguishes between the different tectonic
settings. Thus, based on this classification scheme, the Akinto Soela and the Phedra granites are
classified as syn-collisional, similar to the Patamacca granite, indicating emplacement during
31
collision, while the Tibiti granite is classified as a within-plate granite, suggesting emplacement
after deformation.
It appears that the classification scheme by Pearce et al. (1984) exhibits uncertainties regarding
the tectonic environments of the granitic rocks studied in this report. The scattering between VAG,
syn-COLG and WPG zones in the variation diagrams of Figure 21 (especially for the Akinto Soela
granite), suggest possible variable mixtures of mantle- and crust derived magmas. Such
compositions point out to late- to post-collision granites. The Ta-Hf-Rb classification scheme by
Harris et al. (1986) is used to elaborate on this. This triangular plot distinguishes between four
groups of intrusions, pre-collision calc-alkaline (volcanic-arc) intrusions, syn-collision
peraluminous intrusions, late- to post collision calc-alkaline intrusions and post-collision alkaline
intrusions. The diagram in Figure 22 illustrates the fields in which the granite samples plot.
The Tibiti granite plots as a within-plate intrusion and the Phedra granite plots on the border of
late- to post- and syn-collision instrusion, most likely leaning more towards the syn-collision field,
considering the plots from Figure 21. The Akinto Soela granite plots as a late-to post collisional
intrusion. This particular group cannot be explained in terms of a single, well-defined mantle or
crust source, as these granites can result from both melting of the lower crust and/or upper mantle,
which may be of within-plate or arc composition (Pearce et al., 1984).
Figure 22: Rb-Hf-Ta triangular plot for acid-intermediate intrusive magmatism by Harris et al. (1986). The Akinto Soela
granite (red) plotting as late and post collisional, the Tibiti granite as within plate and the Phedra granite on the border
of the two collisional fields, but considered as syn-collisional, considering the tectonic discriminant diagrams from Figure
21.
32
The affinity of the resulting granites may depend on the geometry of the collision event, which in
turns controls the nature of the crust and mantle that undergo melting (Pearce et al., 1984). Such
granites show strong variation in the Rb vs (Y + Nb) space, plotting near the top of VAG or at the
lower end of syn-COLG and sometimes at the triple point of the VAG, syn-COLG and WPG
(Pearce et al., 1984), as is the case with the Akinto Soela granite.
On the normalization diagrams of Sun and McDonough et al. (1989) (Figure 24) of a CI Chondrite
and primordial mantle, the REE patterns of the granites are similar in shape compared to Figure
23, with values at a slightly lower magnitude in the primordial mantle normalization. Considering
the ASI- and MALI classifications from Figure 16, Figure 17 and Figure 18, the sedimentary
character of having excessive detrital zircons in the sedimentary precursor rock, can explain the
erratic behavior of some of the elements of the REE diagram.
33
Figure 23: REE patterns of the Akinto Soela (red), Phedra (green) and Tibiti (magenta) granites, normalized to an
average CI chondrite, after Evensen et al. (1978).
Figure 24: REE normalization patterns for the Akinto Soela (red), Phedra (green) and Tibiti (magenta) granites, after
Sun and McDonough et al. (1989). On the left, normalized to CI Chondrite and on the right, normalized to a primordial
mantle. In these diagrams, the patterns are similar to the REE normalization shapes of Evensen et al. (1978).
Spider diagrams
Using the primordial mantle normalization by Sun and McDonough et al. (1989), the samples are
compared with the composition of the upper continental crust, the lower continental crust and the
average continental crust. Note that for P no value is given as the norm value for this element is
omitted in the normalization scheme, and thus no mark is shown in the patterns for the element
P. The element concentrations of K and Ti are calculated using the weight percentages of K2O
and TiO2, determined through XRF. According to the patterns illustrated in Figure 25, the granitic
rocks mostly reflect uppercrust influences with few element concentrations coinciding more to
34
average continental crust values. Pb enrichment for the Phedra granite (ASG-14) observed and
Sr values below average for the Tibiti granite (ASG-12).
Figure 25: Spider diagram after Sun and McDonough (1992) normalized to a primordial mantle. The granitic samples
mostly reflect influences from the uppercrust with minor element concentrations similar to the average continental crust.
Using spider diagrams of the geochemical patterns from representative granites by Pearce et al.
(1984), normalized to a hypothetical ocean ridge granite (ORG), the tectonic environments of the
granitic samples of this report are further sought out. The Akinto Soela granite shows the most
similarities to syn-COLG of both continent-continent as well as continent-arc collision zones, with
a relatively strong enrichment of Ba and Ta (Figure 26). However, similarities to the WPG granites
of intra continental ring complexes and graben are observed, as well as similarities to VAG
granites of active continental margins (Figure 26). The Phedra granite shows a similar pattern
shape to syn-COLG and VAG granites, with a stronger correlation to continent-arc collision
granites (Figure 27). The pattern of the Tibiti granite strongly reflects both the syn-COLG and
VAG patterns, with stronger similarities to active continental margin granites (Figure 28). It
appears that these diagrams do not clearly discriminate against the different tectonic settings of
the samples and the classification scheme by Harris et al. (1986) in combination with the Yb vs
Ta diagram by Pearce et al. (1984) seem the most reliable to classify the tectonic environments
of the granitic rocks.
35
Figure 26: Geochemical patterns of the Akinto Soela samples (ASG-02, ASG-06, ASG-06 and ASG-10), normalized to
a hypothetical ocean ridge granite (ORG), with data for representative granites used from Pearce et al. (1986). Akinto
Soela granite all show similar shapes with resemblance to syn-COLG of both continent-continent and continent-arc
collision zones, WPG of intra continental ring complexes and grabens and to VAG of active continental margins.
Figure 27: Geochemical patterns of the Phedra sample (ASG-14), normalized to a hypothetical ocean ridge granite
(ORG), with data for representative granites used from Pearce et al. (1986). The Phedra granite pattern shows
resemblance to syn-COLG of both continent-continent and continent-arc collision zones and to VAG of active
continental margins. Stronger correlation appears to be with continent-arc collision zones.
Figure 28: Geochemical patterns of the Tibiti sample (ASG-12), normalized to a hypothetical ocean ridge granite (ORG),
with data for representative granites used from Pearce et al. (1986). The Tibiti granite pattern shows resemblance to
syn-COLG of both continent-continent and continent-arc collision zones, but a stronger correlation to VAG of active
continental margins.
36
4.5 U-Pb zircon age dating
Age dating of the granitoids was done to understand the chronology of magmatism within the
Marowijne Greenstone Belt and assess their occurrences in a regional context, mainly French
Guiana. Samples from the Tibiti, Akinto Soela and Phedra granites were sent to the Utrecht
University for analysis.
27 measurements on selected zircons of the Tibiti granite yielded a 207Pb/206Pb age of 2119 ± 33
Ma (n=20, MSWD=2.9), which dates the intrusion of this granite, and average inherited ages of
2235 ± 19 Ma (n=6, MSWD=0.78) and 2361 ± 23 Ma (n=1) (Postema, report in progress). CL-
images show oscillatory zoning (Figure 29) and locally weak recrystallization patches (Figure
29b). The external morphology of the zircons represent those of typical granites and pegmatites
(Corfu, 2003; Pupin, 1980).
Figure 29: CL images of the Tibiti granite (ASG-12) with zircons showing oscillatory zoning. Zircon on figure b exhibits
a recrystallization patch.
11 measurements on selected zircons were conducted for the Phedra granite with the youngest
zircon population having a 207Pb/206Pb age of 2093 ± 40 Ma (n=8, MSWD=2.5), dating the intrusion
of this granite (Kriegsman, report in progress). There is indication of two subpopulation (both n=4)
within this group, one ~35 Ma older and the other ~35 Ma younger, but more data are required to
confirm this. All zircons appear igneous from CL images, showing almost perfect tetragonal
shaped zircons with faint oscillatory zoning with possible xenocryst cores (Figure 30). Three (3)
older grains were measured in the range of 2.4 – 2.8 Ga, indicating late Archean to early
Proterozoic inheritance. A concordia diagram is provided in Figure 31.
37
Figure 30: CL images of zircons from the Phedra granite (ASG-13) showing faint oscillatory zoning with possible
xenocryst cores. Measuring locations indicated by red circles.
Figure 31: Concordia diagram of the Phedra zircon measurements. Data processed by Dr. Kriegsman (report in
progress).
A total of 23 measurements were conducted on selected zircons of the Akinto Soela granite with
locations including both core and rims. The results show evidence for multiple populations with
207
the youngest group having a Pb/206Pb age of 2074 ± 29 Ma (n=11, MSWD=1.7) (Kriegsman,
report in progress), which may date the intrusion of this particular granite. An older, probably
207
inherited population has a Pb/206Pb age of 2202 ± 28 Ma (n=7, MSWD=1.7). Even older ages
38
of ~2.3 Ga (n=3) and ~2.5 Ga (n=3) were obtained, most likely from inherited zircons or potential
xenocrysts. CL images from the Akinto Soela sample show zircons containing faint visible
oscillatory zoning patterns (Figure 32), indicating weak compositional variation during
crystallization (Corfu, 2003). Their external morphology reflect those of granites and pegmatites
(Corfu, 2003; Pupin, 1980). A concordia diagram is provided in Figure 33.
Figure 32: CL images of selected zircons of the Akinto Soela granite with measuring locations in red circles. Zircons
show faint visible oscillatory zoning patterns.
Figure 33: Concordia diagram of the Akinto Soela zircon measurements. Data processed by Dr. Kriegsman (report in
progress).
39
Given the uncertainties, the Akinto Soela and Phedra granites are considered coeval, with a
combined intrusion age of 2.08 ± 0.03 Ga (Kriegsman, report in progress). In French Guiana,
similar ages were obtained for the Organabo biotite-granite and Petit Saut monzogranite.
Considering the ages of the various granitic occurrences studied for this report, these rocks show
no significant age difference, aside from the Tibiti granite (slightly older), and can be considered
of the same magmatic episode. However, they do have undergone compositional differentiation
or have had different source rocks anatexis. Interestingly, the 2.08 Ga old granites have the same
age as the Sara’s Lust gneiss (2081 ± 21 Ma) (Postema – report in progress) and is therefore
possible that partial melting of the Sara’s Lust gneiss led to the genesis of the granitic magma
that has formed the granites. This age also coincides with the ages of the metamorphic Bakhuis
and Coeroeni Belts (Kroonenberg et al., 2016), indicating an important young episode of the
Trans-Amazonian Orogeny in Suriname.
40
5. Discussion
The granitoids of the Marowijne Greenstone Belt were formed between 2.19 – 2.07 Ga, during
convergence and collision of the Amazonian and African cratons, continuing during the closure of
the island-arc basins leading to the emplacement of syn-tectonic granites as result of crustal
stretching (Delor et al., 2003a). TTG plutonism started with multiphased magmatism of the Kabel
tonalites (2180 – 2130 Ma) (Delor et al., 2003a; Kroonenberg et al., 2016) and the Brinck pluton
(2.19 – 2.16 Ga and 2.12 – 2.11 Ga) (Ramlal, 2018). The emplacement of the Tibiti biotite-granite
(2119 Ma) most likely occurred simultaneously with the second phase of the TTG magmatism.
The Phedra two-mica and Akinto Soela granites, with a combined intrusion age of 2.08 Ga, are
considered to be the youngest magmatic occurrences discovered to date in the Marowijne
Greenstone Belt. The Patamacca two-mica granite would fall within this last group as an age of
2.06 Ga is retrieved for this unit in French Guiana (Delor et al., 2003a; Kroonenberg et al., 2016).
Considering the ages, the Akinto Soela, Phedra and Patamacca granites are considered of the
same magmatic pulse (Figure 20), but due to differentiation, these granites exhibit varying
compositions.
41
composition such as the alumina saturation (Figure 16 and Figure 17). However, their ages
suggest them to be from the same magmatic pulse.
42
Figure 34: Schematic diagram illustrating the possible source regions of magmatism of the northeastern Marowijne
Greenstone Belt, modified after Harris et al. (1986). a.) Pre- to early collision magmatism of the TTG suites such as the
Brinck pluton. b.) Second phase of the TTG magmatism and emplacement of within plate granites (Tibiti granite) that
have not been hydrated by subduction processes. c.) Syn-collision magmatism resulting from crustal thickening and
the emplacement of the peraluminous two-mica granites. d.) Late- to post collision magmatism resulting from possible
subsidiary subduction (Akinto Soela granite).
43
post-collision subsidiary subduction (Figure 34d) (Harris et al., 1986). The peraluminous and
metaluminous nature of the Akinto Soela granite, suggests possible contamination with melts
from a mafic rock source (Ellis & Thompson, 1986; Patino Douce, 1999).
Syn- and late- to post collision granites do not necessarily occur sequentially and their timing
depends on the relative rates of crustal thickening and of subsidiary subduction (Harris et al.,
1986). Therefore, similar occurrences can still be discovered with varying ages, dating younger
than the collision event.
44
Figure 35: Map illustrating the modeled topography of the granite batholith, after Van Boeckel (1968). The depth of the
contours of the upper surface of the model batholith are indicated by isohypses at every two (2) kilometers. The overall
depth of the bottom of the batholith is estimated at 15 km. The greater part of the negative belt can be explained by the
occurrence of a batholith of this shape. The locations of the granites studied for this report are marked for reference
purposes.
The metamorphic belt in Suriname has undergone major tectonic and erosional processes that
have removed an extensive amount of the crustal material (Hsu, 1965). Whether these processes
have already exposed parts of the so-called granite batholith or the rocks now exposed on surface
are still part of the roof of the batholith, is still arguable. However, Schols (1956) stated in his
research that small dykes of granite, diorite, aplites and pegmatites are frequent within the
Marowijne Greenstone Belt and that these rocks form part of, or are related to an enormous
massif, from which the dimensions are equal to those of the largest batholiths. Thus, meaning
that evidence for the granite batholith might possibly be exposed on surface as individual or
isolated units. Still, this does not verify whether or not the isolated granitic bodies studied for this
report, could be part of this batholith and therefore additional research is required on more of such
rock units within the Marowijne Greenstone Belt.
45
Figure 36: Geological map of the area of the Stofbroekoe Mountains as given by Beckering Vinckers (1956) and Brabers
(1961), after O’ Herne (1958). The location of the Granite 3 in the northwest corner of this map sheet just coincides
with the center of the negative belt.
46
6. Conclusion
The magmatic evolution of the Marowijne Greenstone Belt compares to the model built by Delor
et al. (2003a). Granitoid magmatism occurred in several phases during the Trans-Amazonian
Orogeny. The first episode initiated the emplacement of the TTG-suites in multiple phases
between 2.19 – 2.16 Ga and 2.15 – 2.11 Ga, during convergence and collision of the Amazonian
and African cratons. TTG plutons that arose include the Brinck pluton, the Kabel Tonalite and the
Saramacca batholith. Convergence during the second phase of the TTG magmatism, led to
crustal processes resulting in the formation of the Tibiti biotite-granite from melts of crustal source
rocks within a continental setting. Between 2.10 – 2.07 Ga another magmatic event presented
itself, marking continuing convergence and the emplacement of syn-tectonic peraluminous
granites such as the Phedra and the Patamacca, and at a later stage of the formation of the Akinto
Soela granite. Variation between the granitoids from the latter stage that were studied for this
report, are summarized as follows:
- The Tibiti biotite-granite with an average age of 2119 ± 33 Ma, shows a calc-alkalic
peraluminous nature, derived from possible mafic to intermediate magma source rock.
This unit has a strong resemblance to the pink granite, formed during the second phase
of magmatism of the Brinck pluton, as described by Ramlal (2018). However, the
compositional variation and its tectonic environment make it questionable as to whether
the Tibiti granite should also be considered part of the TTG-suite.
- The peraluminous Phedra two-mica granite has yielded an average age of 2093 ± 40 Ma,
emplaced during syn-collisional events. Its alkali- to alkali-calcic affinity leans more
towards an intermediate derived sedimentary magma source. Inherited zircons with ages
between 2.4 – 2.8 Ga suggest early Proterozoic and late-Archean sources, demonstrating
that much older crustal components of the Guiana Shield possibly exist in the underlying
blocks. Mineralogically, the Phedra granite is similar to the Patamacca two-mica granite,
but shows chemical variation in alumina saturation.
- The Akinto Soela biotite-granite has an average age of 2074 ± 29 Ma, suggesting
emplacement during the late stages of the collision events and making this yet the
youngest granitic occurrence within the Marowijne Greenstone Belt. Its alkalic to alkali-
calcic character and both weak peraluminous and metaluminous nature indicate possible
magma derivation from sedimentary sources with assimilation of mafic rock material.
There appears to be a certain differentiation trend in this pluton from the slightly more
47
mafic Kuldipsingh granite with occasional hornblende and no muscovite, to the slight more
felsic creekbed and Ponsor granites with small amounts of muscovite and no hornblende.
The smaller granitic intrusives of the Marowijne Greenstone Belt do not show significant age
differences and can therefore, be considered as part of the same magmatic episode, only intruded
during multiple phases. However, grouping them as one single unit on the geological map of
Suriname would be inconvenient, mostly because of their significant differentiation in composition.
The different tectonic settings in which these granites were emplaced should also be taken into
account in keeping them as separate individual units on the map. Challenges lie with identifying
the precursor rocks of these granites, but data retrieved about the inherited zircon ages suggest
the exclusion of the Armina sediments as the source rock, mainly because of the absence of
detrital zircons with ages of around 2.16 Ga (Kriegsman & Kroonenberg, personal
communication). This is not the case for the Sara’s Lust gneisses (report in progress by
Goumans). This exclusion thus suspects other sources for the magma melts of the granites.
An age of ~2.12 Ga for the Tibiti biotite-granite, suggests that the greenstone belt with its
associated granitoid rocks, stretches further west than originally mapped by Bosma et al. (1977)
and that possibilities exist of misclassification of units in between the Tibiti sampling area and the
western border of the northeastern greenstone belt.
A granite batholith under the northeastern metamorphic belt of Suriname was interpreted by Van
Boeckel (1968) based on extreme negative gravity anomalies. Such large batholith are presumed
to emerge from post-peak metamorphic events underneath large mountain ranges at
considerable depths (Van Boeckel, 1968; Howel, 1959). As post-collision metamorphic events of
the Guiana Shield and in particular the Marowijne Greenstone Belt is assumed to start at around
2.06 Ga (Delor et al., 2003a), the thought emerges whether or not this large batholith could have
had anything to do with the deposition of gold mineralization. Gold mineralization within the
Guiana Shield is limited to two phases between ~2.08 – 2.02 Ga and ~2.0 – 1.95 Ga and are
coeval to post-peak metamorphism at both shallow and crustal levels (Ramlal, 2018), the latter
reflecting high-grade metamorphic gneiss and granulite terrains (Voicu et al., 2001). Ruling out
the small granite plutons of the northeastern Marowijne Greenstone Belt for influencing gold
mineralization, mainly based on their slightly older age, a younger magmatic source would have
been required to activate hydrothermal activity. The so-called granite batholith, which is presumed
to be younger, could have provided sufficient heat sources and magmatic fluids to evoke chemical
48
interaction to mobilize gold and transporting it along pre-existing structures. This is quite far-
fetched as the existence of the batholith still needs to be proved. However, the core of the negative
gravity belt, which is supposed to correspond with the center of this batholith between the
Saramacca and Tibiti rivers (Figure 36), shows various gold prospects wrapping around this so-
called center, including the Saramacca deposit of the Rosebel Gold Mines N.V. This permits the
idea of this batholith possibly having a direct relation to gold mineralization, not impossible. If
indeed, such large volumes of magmatic sources exist, with proven gold prospects near its center,
which also happens to be highest elevation for its roof with possible exposures on surface, the
possibility of hydrothermal fluids circulating within close vicinity of the borders of this batholith
could provide the required pressures and temperatures for wallrock interaction and gold
deposition processes. This of course is speculative, but does not exclude the theory from being
true.
49
Recommendation
This study proves that the geodynamic model of French Guiana by Delor et al. (2003a) is reflecting
in the Marowijne Greenstone Belt of Suriname, especially with regards to the granitoid
magmatism. The results, however, do leave some question marks in terms of properly classifying
the units chemically. Additional sampling is required of each of the individual granitic bodies,
especially the Tibiti and Phedra granites, to come to a more reliable conclusion, as only one
sample of each area is used for the interpretations of this study.
The age dating calculations showed an excess amount of ‘common Pb’ ( 204Pb) in the zircons,
which causes disturbance of the isotropic patterns. This has been observed in several of the
younger granites of the Marowijne Greenstone Belt, including the Patamacca granite (Kriegsman,
personal communication). Further work is required, including additional zircon dating, to eliminate
uncertainties, as well as reprocessing of recent work with the correction of the ‘common Pb’, which
is a different calculation process altogether.
Other isolated bodies of granitoids should also be evaluated as these could identify possible
evidence for the interpreted granite batholith underneath the metamorphic belt. Isotopic studies,
of both radiogenic and oxygen, on the gold occurrences near these granitoids, as well as the
granitoids, would help identify the fluids responsible for gold deposition and maybe even provide
more evidence of this large magmatic body to exist underneath. Because if such a voluminous
magmatic body exists, chances of it feeding dykes hosting mineral deposits of Sn, Be and Li are
more likely to occur. Few of such deposits have already been discovered and mined. Amblygonite
for example, was mined for Li along the Marowijne River and beryl from the Rama pegmatites for
Be. These occurrences have not been properly dated yet, except by Priem et al. (1977), but his
work consisted of Rb-Sr and K-Ar measurements on micas and the ages retrieved can no longer
be considered accurate. U-Pb dating and geochemical work is recommended for the pegmatites
to establish their relations to the various granitic occurrences.
50
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56
Appendices
Lab ID ASG02-7 ASG02-8 ASG05-9 ASG05-10 ASG06-11 ASG06-12 ASG10-13 ASG10-14 ASG12-17 ASG12-18 ASG14-21 ASG14-22
Si29 309257.8 309257.8 318700.1 318700.1 322907 322907 300096 300096 354272.3 354272.3 335013.8 335013.8
Ca43 57150.74 58235.74 47236.19 44601.8 66499.99 51644.14 69615.51 73832.47 58963 54627.81 32158.88 43477.99
Sc45 10.57 10.32 10.71 7.57 7.38 8.1 11.35 11.8 10.68 5.6 6.41 5.76
Ti49 2968.9 3281.57 3341.41 3043.47 2534.58 2653.72 5880.28 6609.01 1181.49 903.13 1337.68 1534.08
V51 52.72 53.1 44.46 35.18 32.95 33.49 58.65 64.95 13.23 22.91 28.3 29.74
Cr52 83.32 87.83 55.27 57.39 59.26 54.12 86.37 153.07 19.91 3.99 11.65 31.2
Mn55 367.47 383.52 353.43 325.18 256.6 246.45 491.44 536.45 340.77 357.17 164.38 166.59
Cu63 <LD <LD <LD <LD <LD <LD 31.38 33.65 20318.59 35680.85 4890.14 6430.44
Zn66 16.77 42.2 509.46 421.28 <LD 52.16 114.55 80.58 52263.02 69126.48 362.9 427.3
Ga69 60.38 66.83 64.47 52.98 58.86 55.41 59.89 67.83 68.39 72.21 40.04 43.34
As75 3.55 9.6 6.77 2.13 9.99 3.96 3.01 9.53 <LD <LD 2.16 3.1
Rb85 173.7 194.87 203.91 165.09 200.38 192.33 186.54 195.4 123.31 118.96 297.61 337.13
Sr88 785.74 854.85 1085.48 976.85 733.12 708.92 1067.86 1099.85 166.35 184.23 228.45 251.73
Y89 10.82 11.07 14.99 13.66 14.29 12.65 18.31 19.62 34.39 32.26 6.14 3.8
Zr90 170.98 177.29 243.16 249.2 227.01 193.98 342.85 357.06 194.1 181.8 90.97 94.28
Nb93 10.03 9.8 17.61 15.94 15.86 15.26 19.64 20.64 9.17 12.6 6.75 6.7
Cs133 7.22 8.22 9.2 9.99 8.06 8.34 3.72 4.06 1.14 0.29 8.94 8.59
Ba137 1325.67 1437.5 1371.07 1181.74 1223.99 1118.43 1268.81 1432.84 1285.72 1194.26 539.93 584.31
La139 50.48 51.63 75.81 75.2 83.63 82.96 93.57 104.36 49.28 44.86 20.17 24.43
Ce140 103.02 110.34 182.65 142.21 150 143.94 192.41 213.4 94.9 91.69 48.91 53.88
Pr141 10.53 12.06 15.65 15.9 15.35 15.41 22.32 24.65 10.15 10.01 5.52 5.74
Nd146 40.53 39.21 54.79 56.49 58.92 49.14 84.62 91.18 37.01 34.06 19.16 19.48
Sm147 6.31 6.33 11.32 8.45 8.18 8.08 13.77 14.97 7.7 10.91 2.43 4.47
Eu151 1.69 1.5 5.09 2.12 2.13 1.34 3.44 3.95 0.49 1.08 0.12 0.65
Eu153 1.6 1.82 3.13 3.08 1.35 1.54 3.44 3.84 0.35 0.62 1.77 1.32
Gd157 4.45 3.61 7.29 6.28 5.67 4.35 9.29 7.86 4.11 6.52 4.03 3.14
Tb159 0.536 0.444 0.65 0.71 0.64 0.537 0.826 0.838 1.01 1.36 0.18 0.058
Dy163 2.3 2.1 2.46 2.5 2.37 2.01 3.95 3.99 4.65 11.19 1.44 2.23
Ho165 0.224 0.32 0.42 0.4 0.516 0.31 0.57 0.564 0.93 0.91 0.15 0.26
Er166 1.26 0.88 0.45 1.3 1.17 0.85 1.04 1.61 4.96 3.56 0.52 0.92
Yb172 0.77 0.88 0.24 0.83 1.26 1.28 1.44 1.82 4.16 2.74 1.32 0.89
Lu175 0.03 0.102 0.119 0.199 0.122 <LD 0.154 0.184 0.34 0.29 0.37 <LD
Hf178 5.99 4.51 5.4 5.65 5.56 4.53 8.37 8.61 9.02 4.44 3.52 4.67
Ta181 4.37 4.59 5.85 4.2 5.51 4.52 4.31 4.44 2.58 5.13 3.21 3.74
Pb208 31.85 30.12 32.03 35.13 42.17 41.51 34.09 38.53 26.14 37.7 48.38 42.79
Th232 11.96 12.41 15.69 16.07 22.87 20.49 14.24 14.91 14.87 17.34 7.67 8.06
U238 3.59 4.16 7.61 8.33 12.57 11.89 3.76 3.56 1.93 1.18 5.54 5.91
57