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t = time [sec]
u = superficial linear velocity of solution [cm/sec]
y = exchange ratio in the resin phase [-]
Z = ionic valence [-]
a =ionic self-diffusivity ratio, Da/Db [-]
de == film thickness
void fraction [cm]
[-]
[* = viscosity of solution [g/cm-sec]
p = density of solution
<P = electrostatic potential
[g/cm3]
Subscripts
A, B = counter ion species
R = resin phase
S = solution phase
Y = non-counter ion Literature cited
1) Carberry, J.J.: A. I. Ch. E.Journal, 6, 460 (1960)
2) Gilliland,
35; 10 (1957) E.R. and D.J. Goldstein: Can. J. Cheni. Eng.y
3) Kataoka,
gaku Kogaku,
T.,
29,
K. Takashima,
368 (1965)
I. Furuta and K. Ueyama: Ka-
4) Kataoka,
491 (1967) T., N. Maeda, M. Sato and K. Ueyama: ibid., 31,
5) 365
Kuo,(1963)
J.C.W. and M.M. David: A. I. Ch. E.Journal, 9,
6) Moison, R.L. and H.A. O'Hern: Chem. Eng. Progr. Sym-
posium Series, No. 24, 55, 71 (1959)
7)(1964)
Rao, G.M. and M.M. David: A. I. Ch. E.Journal, 10, 213
8) Selke, W.A., Y. Bard, D. Pasternak and S.K. Aditya: A.
the other hand, the H.T.U. is generally considered InX \nZ In2.
theoretically sounder than the H.E.T.P. since the con- It can be considered that this equation holds for the
centration change in a packed column is continuous and general case where n is not an integer. Then, the
not stepwise. If the relationship between H.E.T.P. differential number of theoretical plates corresponding
and H.T.U. is clarified, the theoretical weakness of H. to the differential length of the operating line between
E.T.P. can be remedied, and the H.T.U., for which the points (x,y) and (x+dx, y+dy) is obtained by
more fundamental data are available, can be easily con- differentiation of Eq. (3).
verted into the more practical H.E.T.P. by means of dy* - dy dx ~ dx*
j y*-y - x-x* r,x
the relationship. dn= In/ ~ inJt (4)
å ^-=^
Xo - a
= r (2)
Hence
* Received on June 30, 1967 Fig. I Graphical representation of composition
** Dept. of Chem. Eng., Osaka University, Toyonaka, Osaka changes for theoretical plates
_ L [**_dx_
L Nol Jx0x-x* , .
niF - ~^r ~=rf- - -jz -j (JO;
G Nog ^rn
yj -* ay
hoy -y
Remembering that dyldx-L/G, Eq.(lO) can be rear-
ranged into
(Vn ' dy fVn mFdy.
h*y*-y Koy*.-y
Nomenclature