1

Case Name: final case.hsc

2 Company Name Not Available
3 Bedford, MA Unit Set: NewUser13
4 USA
Date/Time: Thu Mar 01 18:25:19 2018
5
6
Fluid Package: Basis-2
7 Material Stream: CAT1 Property Package: NRTL - Ideal
8
9
10
CONDITIONS
11 Overall Vapour Phase
12 Vapour / Phase Fraction 1.0000 1.0000
13 Temperature: (C) 70.00 * 70.00
14 Pressure: (kg/cm2_g) 1.500 * 1.500
15 Molar Flow (kgmole/h) 114.3 114.3
16 Mass Flow (tonne/h) 8.000 * 8.000
17 Std Ideal Liq Vol Flow (m3/h) 12.07 12.07
18 Molar Enthalpy (kJ/kgmole) -2.729e+004 -2.729e+004
19 Molar Entropy (kJ/kgmole-C) 233.4 233.4
20 Heat Flow (kJ/h) -3.119e+006 -3.119e+006
21 Liq Vol Flow @Std Cond (m3/h) 12.04 * 12.04
22
23
PROPERTIES
24 Overall Vapour Phase
25 Molecular Weight 70.01 70.01
26 Molar Density (kgmole/m3) 8.707e-002 8.707e-002
27 Mass Density (kg/m3) 6.096 6.096
28 Act. Volume Flow (m3/h) 1312 1312
29 Mass Enthalpy (kJ/kg) -389.9 -389.9
30 Mass Entropy (kJ/kg-C) 3.334 3.334
31 Heat Capacity (kJ/kgmole-C) 115.1 115.1
32 Mass Heat Capacity (kJ/kg-C) 1.644 1.644
33 LHV Molar Basis (Std) (kJ/kgmole) --- ---
34 LHV Mass Basis (Std) (kJ/kg) --- ---
35 Phase Fraction [Vol. Basis] 1.000 1.000
36 Phase Fraction [Mass Basis] 1.000 1.000
37 Partial Pressure of CO2 (kg/cm2_g) -1.033 ---
38 Cost Based on Flow (Cost/s) 0.0000 0.0000
39 Act. Gas Flow (ACT_m3/h) 1312 1312
40 Avg. Liq. Density (kgmole/m3) 9.469 9.469
41 Specific Heat (kJ/kgmole-C) 115.1 115.1
42 Std. Gas Flow (STD_m3/h) 2702 2702
43 Std. Ideal Liq. Mass Density (kg/m3) 662.9 662.9
44 Act. Liq. Flow (m3/s) --- ---
45 Z Factor 1.000 1.000
46 Watson K 12.38 12.38
47 User Property --- ---
48 Partial Pressure of H2S (kg/cm2_g) -1.033 ---
49 Cp/(Cp - R) 1.078 1.078
50 Cp/Cv 1.078 1.078
51 Heat of Vap. (kJ/kgmole) 2.482e+004 ---
52 Kinematic Viscosity (cSt) 1.251 1.251
53 Liq. Mass Density (Std. Cond) (kg/m3) 664.6 664.6
54 Liq. Vol. Flow (Std. Cond) (m3/h) 12.04 12.04
55 Liquid Fraction 0.0000 0.0000
56 Molar Volume (m3/kgmole) 11.48 11.48
57 Mass Heat of Vap. (kJ/kg) 354.5 ---
58 Phase Fraction [Molar Basis] 1.0000 1.0000
59 Surface Tension (dyne/cm) --- ---
60 Thermal Conductivity (W/m-K) 1.594e-002 1.594e-002
61 Viscosity (cP) 7.624e-003 7.624e-003
62 Cv (Semi-Ideal) (kJ/kgmole-C) 106.8 106.8
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Case Name: final case.hsc
2 Company Name Not Available
3 Bedford, MA Unit Set: NewUser13
4 USA
Date/Time: Thu Mar 01 18:25:19 2018
5
6
Fluid Package: Basis-2
7 Material Stream: CAT1 (continued) Property Package: NRTL - Ideal
8
9
10
PROPERTIES
11 Overall Vapour Phase
12 Mass Cv (Semi-Ideal) (kJ/kg-C) 1.525 1.525
13 Cv (kJ/kgmole-C) 106.8 106.8
14 Mass Cv (kJ/kg-C) 1.525 1.525
15 Cv (Ent. Method) (kJ/kgmole-C) --- ---
16 Mass Cv (Ent. Method) (kJ/kg-C) --- ---
17 Cp/Cv (Ent. Method) --- ---
18 Reid VP at 37.8 C (kg/cm2_g) 0.1078 0.1078
19 True VP at 37.8 C (kg/cm2_g) 0.1086 0.1086
20 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 12.04 12.04
21 Viscosity Index -49.73 ---
22 HHV Molar Basis (Std) (kJ/kgmole) --- ---
23 HHV Mass Basis (Std) (kJ/kg) --- ---
24 CO2 Loading --- ---
25 CO2 App ML Con (kgmole/m3) --- ---
26 CO2 App WT Con (kgmol/kg) --- ---
27 Phase Fraction [Act. Vol. Basis] 1.000 1.000
28 Mass Exergy (kJ/kg) 36.66 ---
29 Ideal Gas Cp/Cv 1.078 1.078
30 Ideal Gas Cp (kJ/kgmole-C) 115.1 115.1
31 Mass Ideal Gas Cp (kJ/kg-C) 1.644 1.644
32 Bubble Point Pressure (kg/cm2_g) 1.992 ---
33
34
COMPOSITION
35
36
Overall Phase Vapour Fraction 1.0000

37 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
38 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
39 n-Pentane 1.6841 * 0.0147 * 121.5098 * 0.0152 * 0.1930 * 0.0160 *
40 2M-1-butene 30.5248 * 0.2671 * 2140.8551 * 0.2676 * 3.2716 * 0.2711 *
41 3M-1-butene 0.1244 * 0.0011 * 8.7220 * 0.0011 * 0.0138 * 0.0011 *
42 2M-2-butene 65.7978 * 0.5758 * 4614.7314 * 0.5768 * 6.9279 * 0.5741 *
43 tr2-Pentene 3.6630 * 0.0321 * 256.9031 * 0.0321 * 0.3939 * 0.0326 *
44 cis2-Pentene 1.7772 * 0.0156 * 124.6430 * 0.0156 * 0.1890 * 0.0157 *
45 2M-13-C4== 7.8880 * 0.0690 * 537.3258 * 0.0672 * 0.7846 * 0.0650 *
46 1-tr3-C5== 1.0330 * 0.0090 * 70.3655 * 0.0088 * 0.1035 * 0.0086 *
47 1-ci3-C5== 0.5423 * 0.0047 * 36.9419 * 0.0046 * 0.0532 * 0.0044 *
48 13-CC5== 0.0716 * 0.0006 * 4.7341 * 0.0006 * 0.0059 * 0.0005 *
49 i-Butene 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
50 1-Pentene 0.6911 * 0.0060 * 48.4723 * 0.0061 * 0.0759 * 0.0063 *
51 i-Pentane 0.4484 * 0.0039 * 32.3500 * 0.0040 * 0.0519 * 0.0043 *
52 DMF 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
53 n-Hexane 0.0284 * 0.0002 * 2.4460 * 0.0003 * 0.0037 * 0.0003 *
54 Total 114.2741 1.0000 8000.0000 1.0000 12.0677 1.0000
55
56
Vapour Phase Phase Fraction 1.000

57 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
58 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
59 n-Pentane 1.6841 0.0147 121.5098 0.0152 0.1930 0.0160
60 2M-1-butene 30.5248 0.2671 2140.8551 0.2676 3.2716 0.2711
61 3M-1-butene 0.1244 0.0011 8.7220 0.0011 0.0138 0.0011
62 2M-2-butene 65.7978 0.5758 4614.7314 0.5768 6.9279 0.5741
63 Aspen Technology Inc. Aspen HYSYS Version 10 Page 2 of 43
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1
Case Name: final case.hsc
2 Company Name Not Available
3 Bedford, MA Unit Set: NewUser13
4 USA
Date/Time: Thu Mar 01 18:25:19 2018
5
6
Fluid Package: Basis-2
7 Material Stream: CAT1 (continued) Property Package: NRTL - Ideal
8
9
10
COMPOSITION
11
12
Vapour Phase (continued) Phase Fraction 1.000

13 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
14 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
15 tr2-Pentene 3.6630 0.0321 256.9031 0.0321 0.3939 0.0326
16 cis2-Pentene 1.7772 0.0156 124.6430 0.0156 0.1890 0.0157
17 2M-13-C4== 7.8880 0.0690 537.3258 0.0672 0.7846 0.0650
18 1-tr3-C5== 1.0330 0.0090 70.3655 0.0088 0.1035 0.0086
19 1-ci3-C5== 0.5423 0.0047 36.9419 0.0046 0.0532 0.0044
20 13-CC5== 0.0716 0.0006 4.7341 0.0006 0.0059 0.0005
21 i-Butene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
22 1-Pentene 0.6911 0.0060 48.4723 0.0061 0.0759 0.0063
23 i-Pentane 0.4484 0.0039 32.3500 0.0040 0.0519 0.0043
24 DMF 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
25 n-Hexane 0.0284 0.0002 2.4460 0.0003 0.0037 0.0003
26 Total 114.2741 1.0000 8000.0000 1.0000 12.0677 1.0000
27
28
K VALUE
29 COMPONENTS MIXED LIGHT HEAVY
30 n-Pentane --- --- ---
31 2M-1-butene --- --- ---
32 3M-1-butene --- --- ---
33 2M-2-butene --- --- ---
34 tr2-Pentene --- --- ---
35 cis2-Pentene --- --- ---
36 2M-13-C4== --- --- ---
37 1-tr3-C5== --- --- ---
38 1-ci3-C5== --- --- ---
39 13-CC5== --- --- ---
40 i-Butene --- --- ---
41 1-Pentene --- --- ---
42 i-Pentane --- --- ---
43 DMF --- --- ---
44 n-Hexane --- --- ---
45
46
UNIT OPERATIONS
47 FEED TO PRODUCT FROM LOGICAL CONNECTION
48 Distillation: K20+20a
49
50
UTILITIES
51 ( No utilities reference this stream )
52
53
PROCESS UTILITY
54
55
Fluid Package: Basis-2
56 Material Stream: CAT2 Property Package: NRTL - Ideal
57
58
59
CONDITIONS
60 Overall Vapour Phase
61 Vapour / Phase Fraction 1.0000 1.0000
62 Temperature: (C) 70.00 * 70.00
63 Aspen Technology Inc. Aspen HYSYS Version 10 Page 3 of 43
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1
Case Name: final case.hsc
2 Company Name Not Available
3 Bedford, MA Unit Set: NewUser13
4 USA
Date/Time: Thu Mar 01 18:25:19 2018
5
6
Fluid Package: Basis-2
7 Material Stream: CAT2 (continued) Property Package: NRTL - Ideal
8
9
10
CONDITIONS
11 Overall Vapour Phase
12 Pressure: (kg/cm2_g) 1.500 * 1.500
13 Molar Flow (kgmole/h) 373.5 373.5
14 Mass Flow (tonne/h) 26.00 * 26.00
15 Std Ideal Liq Vol Flow (m3/h) 39.13 39.13
16 Molar Enthalpy (kJ/kgmole) -3691 -3691
17 Molar Entropy (kJ/kgmole-C) 230.5 230.5
18 Heat Flow (kJ/h) -1.379e+006 -1.379e+006
19 Liq Vol Flow @Std Cond (m3/h) 39.04 * 39.04
20
21
PROPERTIES
22 Overall Vapour Phase
23 Molecular Weight 69.61 69.61
24 Molar Density (kgmole/m3) 8.707e-002 8.707e-002
25 Mass Density (kg/m3) 6.061 6.061
26 Act. Volume Flow (m3/h) 4289 4289
27 Mass Enthalpy (kJ/kg) -53.02 -53.02
28 Mass Entropy (kJ/kg-C) 3.312 3.312
29 Heat Capacity (kJ/kgmole-C) 118.8 118.8
30 Mass Heat Capacity (kJ/kg-C) 1.706 1.706
31 LHV Molar Basis (Std) (kJ/kgmole) --- ---
32 LHV Mass Basis (Std) (kJ/kg) --- ---
33 Phase Fraction [Vol. Basis] 1.000 1.000
34 Phase Fraction [Mass Basis] 1.000 1.000
35 Partial Pressure of CO2 (kg/cm2_g) -1.033 ---
36 Cost Based on Flow (Cost/s) 0.0000 0.0000
37 Act. Gas Flow (ACT_m3/h) 4289 4289
38 Avg. Liq. Density (kgmole/m3) 9.546 9.546
39 Specific Heat (kJ/kgmole-C) 118.8 118.8
40 Std. Gas Flow (STD_m3/h) 8831 8831
41 Std. Ideal Liq. Mass Density (kg/m3) 664.5 664.5
42 Act. Liq. Flow (m3/s) --- ---
43 Z Factor 1.000 1.000
44 Watson K 12.33 12.33
45 User Property --- ---
46 Partial Pressure of H2S (kg/cm2_g) -1.033 ---
47 Cp/(Cp - R) 1.075 1.075
48 Cp/Cv 1.075 1.075
49 Heat of Vap. (kJ/kgmole) 2.471e+004 ---
50 Kinematic Viscosity (cSt) 1.282 1.282
51 Liq. Mass Density (Std. Cond) (kg/m3) 665.9 665.9
52 Liq. Vol. Flow (Std. Cond) (m3/h) 39.04 39.04
53 Liquid Fraction 0.0000 0.0000
54 Molar Volume (m3/kgmole) 11.48 11.48
55 Mass Heat of Vap. (kJ/kg) 354.9 ---
56 Phase Fraction [Molar Basis] 1.0000 1.0000
57 Surface Tension (dyne/cm) --- ---
58 Thermal Conductivity (W/m-K) 1.691e-002 1.691e-002
59 Viscosity (cP) 7.773e-003 7.773e-003
60 Cv (Semi-Ideal) (kJ/kgmole-C) 110.4 110.4
61 Mass Cv (Semi-Ideal) (kJ/kg-C) 1.587 1.587
62 Cv (kJ/kgmole-C) 110.4 110.4
63 Aspen Technology Inc. Aspen HYSYS Version 10 Page 4 of 43
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Case Name: final case.hsc
2 Company Name Not Available
3 Bedford, MA Unit Set: NewUser13
4 USA
Date/Time: Thu Mar 01 18:25:19 2018
5
6
Fluid Package: Basis-2
7 Material Stream: CAT2 (continued) Property Package: NRTL - Ideal
8
9
10
PROPERTIES
11 Overall Vapour Phase
12 Mass Cv (kJ/kg-C) 1.587 1.587
13 Cv (Ent. Method) (kJ/kgmole-C) --- ---
14 Mass Cv (Ent. Method) (kJ/kg-C) --- ---
15 Cp/Cv (Ent. Method) --- ---
16 Reid VP at 37.8 C (kg/cm2_g) 0.1527 0.1527
17 True VP at 37.8 C (kg/cm2_g) 0.1534 0.1534
18 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 39.04 39.04
19 Viscosity Index -46.65 ---
20 HHV Molar Basis (Std) (kJ/kgmole) --- ---
21 HHV Mass Basis (Std) (kJ/kg) --- ---
22 CO2 Loading --- ---
23 CO2 App ML Con (kgmole/m3) --- ---
24 CO2 App WT Con (kgmol/kg) --- ---
25 Phase Fraction [Act. Vol. Basis] 1.000 1.000
26 Mass Exergy (kJ/kg) 37.02 ---
27 Ideal Gas Cp/Cv 1.075 1.075
28 Ideal Gas Cp (kJ/kgmole-C) 118.8 118.8
29 Mass Ideal Gas Cp (kJ/kg-C) 1.706 1.706
30 Bubble Point Pressure (kg/cm2_g) 2.086 ---
31
32
COMPOSITION
33
34
Overall Phase Vapour Fraction 1.0000

35 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
36 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
37 n-Pentane 24.6019 * 0.0659 * 1775.0545 * 0.0683 * 2.8188 * 0.0720 *
38 2M-1-butene 71.7728 * 0.1922 * 5033.7838 * 0.1936 * 7.6924 * 0.1966 *
39 3M-1-butene 12.8134 * 0.0343 * 898.6694 * 0.0346 * 1.4236 * 0.0364 *
40 2M-2-butene 111.4019 * 0.2983 * 7813.1736 * 0.3005 * 11.7296 * 0.2998 *
41 tr2-Pentene 6.0015 * 0.0161 * 420.9153 * 0.0162 * 0.6453 * 0.0165 *
42 cis2-Pentene 2.6477 * 0.0071 * 185.6979 * 0.0071 * 0.2815 * 0.0072 *
43 2M-13-C4== 125.2927 * 0.3355 * 8534.8154 * 0.3283 * 12.4624 * 0.3185 *
44 1-tr3-C5== 3.3870 * 0.0091 * 230.7194 * 0.0089 * 0.3393 * 0.0087 *
45 1-ci3-C5== 2.1451 * 0.0057 * 146.1223 * 0.0056 * 0.2103 * 0.0054 *
46 13-CC5== 0.4325 * 0.0012 * 28.5880 * 0.0011 * 0.0355 * 0.0009 *
47 i-Butene 0.4169 * 0.0011 * 23.3902 * 0.0009 * 0.0395 * 0.0010 *
48 1-Pentene 1.9858 * 0.0053 * 139.2735 * 0.0054 * 0.2180 * 0.0056 *
49 i-Pentane 10.2298 * 0.0274 * 738.0900 * 0.0284 * 1.1839 * 0.0303 *
50 DMF 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
51 n-Hexane 0.3679 * 0.0010 * 31.7067 * 0.0012 * 0.0478 * 0.0012 *
52 Total 373.4970 1.0000 26000.0000 1.0000 39.1280 1.0000
53
54
Vapour Phase Phase Fraction 1.000

55 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
56 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
57 n-Pentane 24.6019 0.0659 1775.0545 0.0683 2.8188 0.0720
58 2M-1-butene 71.7728 0.1922 5033.7838 0.1936 7.6924 0.1966
59 3M-1-butene 12.8134 0.0343 898.6694 0.0346 1.4236 0.0364
60 2M-2-butene 111.4019 0.2983 7813.1736 0.3005 11.7296 0.2998
61 tr2-Pentene 6.0015 0.0161 420.9153 0.0162 0.6453 0.0165
62 cis2-Pentene 2.6477 0.0071 185.6979 0.0071 0.2815 0.0072
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Case Name: final case.hsc
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3 Bedford, MA Unit Set: NewUser13
4 USA
Date/Time: Thu Mar 01 18:25:19 2018
5
6
Fluid Package: Basis-2
7 Material Stream: CAT2 (continued) Property Package: NRTL - Ideal
8
9
10
COMPOSITION
11
12
Vapour Phase (continued) Phase Fraction 1.000

13 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
14 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
15 2M-13-C4== 125.2927 0.3355 8534.8154 0.3283 12.4624 0.3185
16 1-tr3-C5== 3.3870 0.0091 230.7194 0.0089 0.3393 0.0087
17 1-ci3-C5== 2.1451 0.0057 146.1223 0.0056 0.2103 0.0054
18 13-CC5== 0.4325 0.0012 28.5880 0.0011 0.0355 0.0009
19 i-Butene 0.4169 0.0011 23.3902 0.0009 0.0395 0.0010
20 1-Pentene 1.9858 0.0053 139.2735 0.0054 0.2180 0.0056
21 i-Pentane 10.2298 0.0274 738.0900 0.0284 1.1839 0.0303
22 DMF 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
23 n-Hexane 0.3679 0.0010 31.7067 0.0012 0.0478 0.0012
24 Total 373.4970 1.0000 26000.0000 1.0000 39.1280 1.0000
25
26
K VALUE
27 COMPONENTS MIXED LIGHT HEAVY
28 n-Pentane --- --- ---
29 2M-1-butene --- --- ---
30 3M-1-butene --- --- ---
31 2M-2-butene --- --- ---
32 tr2-Pentene --- --- ---
33 cis2-Pentene --- --- ---
34 2M-13-C4== --- --- ---
35 1-tr3-C5== --- --- ---
36 1-ci3-C5== --- --- ---
37 13-CC5== --- --- ---
38 i-Butene --- --- ---
39 1-Pentene --- --- ---
40 i-Pentane --- --- ---
41 DMF --- --- ---
42 n-Hexane --- --- ---
43
44
UNIT OPERATIONS
45 FEED TO PRODUCT FROM LOGICAL CONNECTION
46 Distillation: K20+20a
47
48
UTILITIES
49 ( No utilities reference this stream )
50
51
PROCESS UTILITY
52
53
Fluid Package: Basis-1
54 Material Stream: DMFA Property Package: Peng-Robinson
55
56
57
CONDITIONS
58 Overall Liquid Phase
59 Vapour / Phase Fraction 0.0000 1.0000
60 Temperature: (C) 174.8 * 174.8
61 Pressure: (kg/cm2_g) 0.6500 * 0.6500
62 Molar Flow (kgmole/h) 3725 3725
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Date/Time: Thu Mar 01 18:25:19 2018
5
6
Fluid Package: Basis-1
7 Material Stream: DMFA (continued) Property Package: Peng-Robinson
8
9
10
CONDITIONS
11 Overall Liquid Phase
12 Mass Flow (tonne/h) 272.3 * 272.3
13 Std Ideal Liq Vol Flow (m3/h) 285.6 285.6
14 Molar Enthalpy (kJ/kgmole) -2.141e+005 -2.141e+005
15 Molar Entropy (kJ/kgmole-C) 135.2 135.2
16 Heat Flow (kJ/h) -7.978e+008 -7.978e+008
17 Liq Vol Flow @Std Cond (m3/h) 285.5 * 285.5
18
19
PROPERTIES
20 Overall Liquid Phase
21 Molecular Weight 73.10 73.10
22 Molar Density (kgmole/m3) 10.92 10.92
23 Mass Density (kg/m3) 798.3 798.3
24 Act. Volume Flow (m3/h) 341.1 341.1
25 Mass Enthalpy (kJ/kg) -2930 -2930
26 Mass Entropy (kJ/kg-C) 1.849 1.849
27 Heat Capacity (kJ/kgmole-C) 185.2 185.2
28 Mass Heat Capacity (kJ/kg-C) 2.534 2.534
29 LHV Molar Basis (Std) (kJ/kgmole) 1.789e+006 1.789e+006
30 LHV Mass Basis (Std) (kJ/kg) 2.447e+004 2.447e+004
31 Phase Fraction [Vol. Basis] 0.0000 1.000
32 Phase Fraction [Mass Basis] 0.0000 1.000
33 Partial Pressure of CO2 (kg/cm2_g) -1.033 ---
34 Cost Based on Flow (Cost/s) 0.0000 0.0000
35 Act. Gas Flow (ACT_m3/h) --- ---
36 Avg. Liq. Density (kgmole/m3) 13.04 13.04
37 Specific Heat (kJ/kgmole-C) 185.2 185.2
38 Std. Gas Flow (STD_m3/h) 8.808e+004 8.808e+004
39 Std. Ideal Liq. Mass Density (kg/m3) 953.4 953.4
40 Act. Liq. Flow (m3/s) 9.476e-002 9.476e-002
41 Z Factor 4.058e-003 4.058e-003
42 Watson K 9.582 9.582
43 User Property --- ---
44 Partial Pressure of H2S (kg/cm2_g) -1.033 ---
45 Cp/(Cp - R) 1.047 1.047
46 Cp/Cv 1.438 1.438
47 Heat of Vap. (kJ/kgmole) 3.898e+004 ---
48 Kinematic Viscosity (cSt) 0.3052 0.3052
49 Liq. Mass Density (Std. Cond) (kg/m3) 953.9 953.9
50 Liq. Vol. Flow (Std. Cond) (m3/h) 285.5 285.5
51 Liquid Fraction 1.000 1.000
52 Molar Volume (m3/kgmole) 9.157e-002 9.157e-002
53 Mass Heat of Vap. (kJ/kg) 533.3 ---
54 Phase Fraction [Molar Basis] 0.0000 1.0000
55 Surface Tension (dyne/cm) 19.04 19.04
56 Thermal Conductivity (W/m-K) 0.1227 0.1227
57 Viscosity (cP) 0.2436 0.2436
58 Cv (Semi-Ideal) (kJ/kgmole-C) 176.9 176.9
59 Mass Cv (Semi-Ideal) (kJ/kg-C) 2.421 2.421
60 Cv (kJ/kgmole-C) 128.8 128.8
61 Mass Cv (kJ/kg-C) 1.763 1.763
62 Cv (Ent. Method) (kJ/kgmole-C) --- ---
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7 Material Stream: DMFA (continued) Property Package: Peng-Robinson
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PROPERTIES
11 Overall Liquid Phase
12 Mass Cv (Ent. Method) (kJ/kg-C) --- ---
13 Cp/Cv (Ent. Method) --- ---
14 Reid VP at 37.8 C (kg/cm2_g) -1.024 -1.024
15 True VP at 37.8 C (kg/cm2_g) -1.024 -1.024
16 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 285.5 285.5
17 Viscosity Index -22.49 ---
18 HHV Molar Basis (Std) (kJ/kgmole) 1.932e+006 1.932e+006
19 HHV Mass Basis (Std) (kJ/kg) 2.644e+004 2.644e+004
20 CO2 Loading --- ---
21 CO2 App ML Con (kgmole/m3) --- ---
22 CO2 App WT Con (kgmol/kg) --- ---
23 Phase Fraction [Act. Vol. Basis] 0.0000 1.000
24 Mass Exergy (kJ/kg) 66.17 ---
25 Ideal Gas Cp/Cv 1.069 1.069
26 Ideal Gas Cp (kJ/kgmole-C) 128.8 128.8
27 Mass Ideal Gas Cp (kJ/kg-C) 1.762 1.762
28 Bubble Point Pressure (kg/cm2_g) 0.6498 ---
29
30
COMPOSITION
31
32
Overall Phase Vapour Fraction 0.0000

33 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
34 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
35 n-Pentane 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
36 2M-1-butene 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
37 3M-1-butene 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
38 2M-2-butene 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
39 tr2-Pentene 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
40 cis2-Pentene 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
41 2M-13-C4== 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
42 1-tr3-C5== 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
43 1-ci3-C5== 0.0000 * 0.0000 * 0.0001 * 0.0000 * 0.0000 * 0.0000 *
44 13-CC5== 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
45 i-Butene 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
46 1-Pentene 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
47 i-Pentane 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
48 DMF 3725.1010 * 0.9999 * 272286.2597 * 0.9999 * 285.5965 * 0.9999 *
49 n-Hexane 0.2174 * 0.0001 * 18.7386 * 0.0001 * 0.0283 * 0.0001 *
50 Total 3725.3184 1.0000 272304.9985 1.0000 285.6248 1.0000
51
52
Liquid Phase Phase Fraction 1.000

53 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
54 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
55 n-Pentane 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
56 2M-1-butene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
57 3M-1-butene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
58 2M-2-butene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
59 tr2-Pentene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
60 cis2-Pentene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
61 2M-13-C4== 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
62 1-tr3-C5== 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
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Liquid Phase (continued) Phase Fraction 1.000

13 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
14 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
15 1-ci3-C5== 0.0000 0.0000 0.0001 0.0000 0.0000 0.0000
16 13-CC5== 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
17 i-Butene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 1-Pentene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 i-Pentane 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
20 DMF 3725.1010 0.9999 272286.2597 0.9999 285.5965 0.9999
21 n-Hexane 0.2174 0.0001 18.7386 0.0001 0.0283 0.0001
22 Total 3725.3184 1.0000 272304.9985 1.0000 285.6248 1.0000
23
24
K VALUE
25 COMPONENTS MIXED LIGHT HEAVY
26 n-Pentane 0.0000 0.0000 ---
27 2M-1-butene 0.0000 0.0000 ---
28 3M-1-butene 0.0000 0.0000 ---
29 2M-2-butene 0.0000 0.0000 ---
30 tr2-Pentene 0.0000 0.0000 ---
31 cis2-Pentene 0.0000 0.0000 ---
32 2M-13-C4== 0.0000 0.0000 ---
33 1-tr3-C5== 0.0000 0.0000 ---
34 1-ci3-C5== 0.0000 0.0000 ---
35 13-CC5== 0.0000 0.0000 ---
36 i-Butene 0.0000 0.0000 ---
37 1-Pentene 0.0000 0.0000 ---
38 i-Pentane 0.0000 0.0000 ---
39 DMF 0.0000 0.0000 ---
40 n-Hexane 0.0000 0.0000 ---
41
42
UNIT OPERATIONS
43 FEED TO PRODUCT FROM LOGICAL CONNECTION
44 Distillation: K20+20a Recycle: RCY-2
45
46
UTILITIES
47 ( No utilities reference this stream )
48
49
PROCESS UTILITY
50
51
Fluid Package: Basis-1
52 Material Stream: DMFA+ISOPRENE FR Property Package: Peng-Robinson
53
54
55
CONDITIONS
56 Overall Vapour Phase Liquid Phase
57 Vapour / Phase Fraction 0.0000 0.0000 1.0000
58 Temperature: (C) 123.0 123.0 123.0
59 Pressure: (kg/cm2_g) 1.540 1.540 1.540
60 Molar Flow (kgmole/h) 4609 8.737e-003 4609
61 Mass Flow (tonne/h) 334.7 6.170e-004 334.7
62 Std Ideal Liq Vol Flow (m3/h) 379.4 8.898e-004 379.4
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CONDITIONS
11 Overall Vapour Phase Liquid Phase
12 Molar Enthalpy (kJ/kgmole) -1.859e+005 -3.117e+004 -1.859e+005
13 Molar Entropy (kJ/kgmole-C) 123.8 214.2 123.8
14 Heat Flow (kJ/h) -8.570e+008 -272.4 -8.570e+008
15 Liq Vol Flow @Std Cond (m3/h) 375.3 * 8.815e-004 375.3
16
17
PROPERTIES
18 Overall Vapour Phase Liquid Phase
19 Molecular Weight 72.62 70.62 72.62
20 Molar Density (kgmole/m3) 10.84 8.093e-002 10.84
21 Mass Density (kg/m3) 787.3 5.715 787.5
22 Act. Volume Flow (m3/h) 425.1 0.1080 425.0
23 Mass Enthalpy (kJ/kg) -2560 -441.5 -2560
24 Mass Entropy (kJ/kg-C) 1.705 3.034 1.705
25 Heat Capacity (kJ/kgmole-C) 171.9 133.0 171.9
26 Mass Heat Capacity (kJ/kg-C) 2.368 1.883 2.368
27 LHV Molar Basis (Std) (kJ/kgmole) --- --- ---
28 LHV Mass Basis (Std) (kJ/kg) --- --- ---
29 Phase Fraction [Vol. Basis] 2.345e-006 2.345e-006 1.000
30 Phase Fraction [Mass Basis] 1.843e-006 1.843e-006 1.000
31 Partial Pressure of CO2 (kg/cm2_g) -1.033 --- ---
32 Cost Based on Flow (Cost/s) 0.0000 0.0000 0.0000
33 Act. Gas Flow (ACT_m3/h) 0.1080 0.1080 ---
34 Avg. Liq. Density (kgmole/m3) 12.15 9.819 12.15
35 Specific Heat (kJ/kgmole-C) 171.9 133.0 171.9
36 Std. Gas Flow (STD_m3/h) 1.090e+005 0.2066 1.090e+005
37 Std. Ideal Liq. Mass Density (kg/m3) 882.3 693.4 882.3
38 Act. Liq. Flow (m3/s) 0.1181 --- 0.1181
39 Z Factor --- 0.9467 7.066e-003
40 Watson K 10.14 12.01 10.14
41 User Property --- --- ---
42 Partial Pressure of H2S (kg/cm2_g) -1.033 --- ---
43 Cp/(Cp - R) 1.051 1.067 1.051
44 Cp/Cv 1.195 1.083 1.432
45 Heat of Vap. (kJ/kgmole) 4.535e+004 --- ---
46 Kinematic Viscosity (cSt) --- 1.511 0.3421
47 Liq. Mass Density (Std. Cond) (kg/m3) 891.9 699.9 891.9
48 Liq. Vol. Flow (Std. Cond) (m3/h) 375.3 8.815e-004 375.3
49 Liquid Fraction 1.000 0.0000 1.000
50 Molar Volume (m3/kgmole) 9.224e-002 12.36 9.222e-002
51 Mass Heat of Vap. (kJ/kg) 624.5 --- ---
52 Phase Fraction [Molar Basis] 0.0000 0.0000 1.0000
53 Surface Tension (dyne/cm) 20.46 --- 20.46
54 Thermal Conductivity (W/m-K) 0.1242 2.065e-002 0.1242
55 Viscosity (cP) 0.2694 8.636e-003 0.2694
56 Cv (Semi-Ideal) (kJ/kgmole-C) 163.6 124.7 163.6
57 Mass Cv (Semi-Ideal) (kJ/kg-C) 2.253 1.766 2.253
58 Cv (kJ/kgmole-C) 143.9 122.9 120.1
59 Mass Cv (kJ/kg-C) 1.982 1.740 1.654
60 Cv (Ent. Method) (kJ/kgmole-C) --- --- ---
61 Mass Cv (Ent. Method) (kJ/kg-C) --- --- ---
62 Cp/Cv (Ent. Method) --- --- ---
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11 Overall Vapour Phase Liquid Phase
12 Reid VP at 37.8 C (kg/cm2_g) -0.7220 -4.577e-002 -0.7220
13 True VP at 37.8 C (kg/cm2_g) -0.7176 -4.292e-002 -0.7176
14 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 375.3 8.815e-004 375.3
15 Viscosity Index -18.36 --- ---
16 HHV Molar Basis (Std) (kJ/kgmole) --- --- ---
17 HHV Mass Basis (Std) (kJ/kg) --- --- ---
18 CO2 Loading --- --- ---
19 CO2 App ML Con (kgmole/m3) --- --- ---
20 CO2 App WT Con (kgmol/kg) --- --- ---
21 Phase Fraction [Act. Vol. Basis] 2.539e-004 2.539e-004 0.9997
22 Mass Exergy (kJ/kg) 29.82 --- ---
23 Ideal Gas Cp/Cv 1.074 1.068 1.074
24 Ideal Gas Cp (kJ/kgmole-C) 120.8 130.9 120.8
25 Mass Ideal Gas Cp (kJ/kg-C) 1.664 1.854 1.664
26 Bubble Point Pressure (kg/cm2_g) 1.540 --- ---
27
28
COMPOSITION
29
30
Overall Phase Vapour Fraction 0.0000

31 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
32 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
33 n-Pentane 50.3946 0.0109 3636.0243 0.0109 5.7740 0.0152
34 2M-1-butene 137.6383 0.0299 9653.2610 0.0288 14.7518 0.0389
35 3M-1-butene 13.4357 0.0029 942.3097 0.0028 1.4927 0.0039
36 2M-2-butene 309.2544 0.0671 21689.5569 0.0648 32.5616 0.0858
37 tr2-Pentene 20.7403 0.0045 1454.6230 0.0043 2.2301 0.0059
38 cis2-Pentene 9.1327 0.0020 640.5253 0.0019 0.9711 0.0026
39 2M-13-C4== 251.3905 0.0545 17124.4676 0.0512 25.0048 0.0659
40 1-tr3-C5== 13.8959 0.0030 946.5758 0.0028 1.3922 0.0037
41 1-ci3-C5== 7.7695 0.0017 529.2537 0.0016 0.7616 0.0020
42 13-CC5== 1.2025 0.0003 79.4843 0.0002 0.0988 0.0003
43 i-Butene 0.2411 0.0001 13.5285 0.0000 0.0228 0.0001
44 1-Pentene 3.4482 0.0007 241.8393 0.0007 0.3786 0.0010
45 i-Pentane 11.5693 0.0025 834.7392 0.0025 1.3389 0.0035
46 DMF 3725.1663 0.8082 272291.0348 0.8135 285.6015 0.7528
47 n-Hexane 53.7232 0.0117 4629.7498 0.0138 6.9866 0.0184
48 Total 4609.0025 1.0000 334706.9733 1.0000 379.3671 1.0000
49
50
Vapour Phase Phase Fraction 1.896e-006

51 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
52 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
53 n-Pentane 0.0005 0.0534 0.0337 0.0546 0.0001 0.0601
54 2M-1-butene 0.0014 0.1592 0.0976 0.1581 0.0001 0.1675
55 3M-1-butene 0.0002 0.0202 0.0124 0.0200 0.0000 0.0220
56 2M-2-butene 0.0027 0.3105 0.1903 0.3084 0.0003 0.3210
57 tr2-Pentene 0.0002 0.0199 0.0122 0.0198 0.0000 0.0210
58 cis2-Pentene 0.0001 0.0087 0.0053 0.0086 0.0000 0.0090
59 2M-13-C4== 0.0020 0.2298 0.1367 0.2216 0.0002 0.2244
60 1-tr3-C5== 0.0001 0.0103 0.0061 0.0099 0.0000 0.0101
61 1-ci3-C5== 0.0000 0.0055 0.0033 0.0053 0.0000 0.0053
62 13-CC5== 0.0000 0.0008 0.0005 0.0008 0.0000 0.0007
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COMPOSITION
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Vapour Phase (continued) Phase Fraction 1.896e-006

13 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
14 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
15 i-Butene 0.0000 0.0006 0.0003 0.0005 0.0000 0.0006
16 1-Pentene 0.0000 0.0040 0.0025 0.0040 0.0000 0.0043
17 i-Pentane 0.0001 0.0149 0.0094 0.0152 0.0000 0.0169
18 DMF 0.0012 0.1339 0.0855 0.1386 0.0001 0.1008
19 n-Hexane 0.0002 0.0284 0.0214 0.0346 0.0000 0.0362
20 Total 0.0087 1.0000 0.6170 1.0000 0.0009 1.0000
21
22
Liquid Phase Phase Fraction 1.000

23 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
24 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
25 n-Pentane 50.3942 0.0109 3635.9906 0.0109 5.7739 0.0152
26 2M-1-butene 137.6369 0.0299 9653.1635 0.0288 14.7516 0.0389
27 3M-1-butene 13.4355 0.0029 942.2974 0.0028 1.4927 0.0039
28 2M-2-butene 309.2517 0.0671 21689.3666 0.0648 32.5613 0.0858
29 tr2-Pentene 20.7402 0.0045 1454.6108 0.0043 2.2301 0.0059
30 cis2-Pentene 9.1327 0.0020 640.5200 0.0019 0.9711 0.0026
31 2M-13-C4== 251.3885 0.0545 17124.3308 0.0512 25.0046 0.0659
32 1-tr3-C5== 13.8958 0.0030 946.5697 0.0028 1.3922 0.0037
33 1-ci3-C5== 7.7695 0.0017 529.2505 0.0016 0.7616 0.0020
34 13-CC5== 1.2024 0.0003 79.4838 0.0002 0.0988 0.0003
35 i-Butene 0.2411 0.0001 13.5282 0.0000 0.0228 0.0001
36 1-Pentene 3.4482 0.0007 241.8368 0.0007 0.3786 0.0010
37 i-Pentane 11.5692 0.0025 834.7299 0.0025 1.3389 0.0035
38 DMF 3725.1651 0.8082 272290.9492 0.8135 285.6014 0.7528
39 n-Hexane 53.7229 0.0117 4629.7285 0.0138 6.9865 0.0184
40 Total 4608.9938 1.0000 334706.3563 1.0000 379.3662 1.0000
41
42
K VALUE
43 COMPONENTS MIXED LIGHT HEAVY
44 n-Pentane 4.884 4.884 ---
45 2M-1-butene 5.331 5.331 ---
46 3M-1-butene 6.919 6.919 ---
47 2M-2-butene 4.628 4.628 ---
48 tr2-Pentene 4.429 4.429 ---
49 cis2-Pentene 4.371 4.371 ---
50 2M-13-C4== 4.213 4.213 ---
51 1-tr3-C5== 3.416 3.416 ---
52 1-ci3-C5== 3.244 3.244 ---
53 13-CC5== 3.187 3.187 ---
54 i-Butene 11.36 11.36 ---
55 1-Pentene 5.349 5.349 ---
56 i-Pentane 5.921 5.921 ---
57 DMF 0.1657 0.1657 ---
58 n-Hexane 2.434 2.434 ---
59
60
UNIT OPERATIONS
61 FEED TO PRODUCT FROM LOGICAL CONNECTION
62 Distillation: K-35 Distillation: K20+20a
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UTILITIES
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PROCESS UTILITY
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Fluid Package: Basis-1
16 Material Stream: DMFATORECYCLE Property Package: Peng-Robinson
17
18
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CONDITIONS
20 Overall Liquid Phase
21 Vapour / Phase Fraction 0.0000 1.0000
22 Temperature: (C) 174.8 174.8
23 Pressure: (kg/cm2_g) 0.6500 0.6500
24 Molar Flow (kgmole/h) 3725 3725
25 Mass Flow (tonne/h) 272.3 272.3
26 Std Ideal Liq Vol Flow (m3/h) 285.6 285.6
27 Molar Enthalpy (kJ/kgmole) -2.141e+005 -2.141e+005
28 Molar Entropy (kJ/kgmole-C) 135.2 135.2
29 Heat Flow (kJ/h) -7.978e+008 -7.978e+008
30 Liq Vol Flow @Std Cond (m3/h) 285.5 * 285.5
31
32
PROPERTIES
33 Overall Liquid Phase
34 Molecular Weight 73.10 73.10
35 Molar Density (kgmole/m3) 10.92 10.92
36 Mass Density (kg/m3) 798.3 798.3
37 Act. Volume Flow (m3/h) 341.1 341.1
38 Mass Enthalpy (kJ/kg) -2930 -2930
39 Mass Entropy (kJ/kg-C) 1.849 1.849
40 Heat Capacity (kJ/kgmole-C) 185.2 185.2
41 Mass Heat Capacity (kJ/kg-C) 2.534 2.534
42 LHV Molar Basis (Std) (kJ/kgmole) 1.789e+006 1.789e+006
43 LHV Mass Basis (Std) (kJ/kg) 2.447e+004 2.447e+004
44 Phase Fraction [Vol. Basis] 0.0000 1.000
45 Phase Fraction [Mass Basis] 0.0000 1.000
46 Partial Pressure of CO2 (kg/cm2_g) -1.033 ---
47 Cost Based on Flow (Cost/s) 0.0000 0.0000
48 Act. Gas Flow (ACT_m3/h) --- ---
49 Avg. Liq. Density (kgmole/m3) 13.04 13.04
50 Specific Heat (kJ/kgmole-C) 185.2 185.2
51 Std. Gas Flow (STD_m3/h) 8.809e+004 8.809e+004
52 Std. Ideal Liq. Mass Density (kg/m3) 953.4 953.4
53 Act. Liq. Flow (m3/s) 9.476e-002 9.476e-002
54 Z Factor 4.058e-003 4.058e-003
55 Watson K 9.583 9.583
56 User Property --- ---
57 Partial Pressure of H2S (kg/cm2_g) -1.033 ---
58 Cp/(Cp - R) 1.047 1.047
59 Cp/Cv 1.438 1.438
60 Heat of Vap. (kJ/kgmole) 3.898e+004 ---
61 Kinematic Viscosity (cSt) 0.3052 0.3052
62 Liq. Mass Density (Std. Cond) (kg/m3) 953.9 953.9
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PROPERTIES
11 Overall Liquid Phase
12 Liq. Vol. Flow (Std. Cond) (m3/h) 285.5 285.5
13 Liquid Fraction 1.000 1.000
14 Molar Volume (m3/kgmole) 9.157e-002 9.157e-002
15 Mass Heat of Vap. (kJ/kg) 533.3 ---
16 Phase Fraction [Molar Basis] 0.0000 1.0000
17 Surface Tension (dyne/cm) 19.04 19.04
18 Thermal Conductivity (W/m-K) 0.1227 0.1227
19 Viscosity (cP) 0.2437 0.2437
20 Cv (Semi-Ideal) (kJ/kgmole-C) 176.9 176.9
21 Mass Cv (Semi-Ideal) (kJ/kg-C) 2.421 2.421
22 Cv (kJ/kgmole-C) 128.8 128.8
23 Mass Cv (kJ/kg-C) 1.763 1.763
24 Cv (Ent. Method) (kJ/kgmole-C) --- ---
25 Mass Cv (Ent. Method) (kJ/kg-C) --- ---
26 Cp/Cv (Ent. Method) --- ---
27 Reid VP at 37.8 C (kg/cm2_g) -1.024 -1.024
28 True VP at 37.8 C (kg/cm2_g) -1.024 -1.024
29 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 285.5 285.5
30 Viscosity Index -22.49 ---
31 HHV Molar Basis (Std) (kJ/kgmole) 1.932e+006 1.932e+006
32 HHV Mass Basis (Std) (kJ/kg) 2.644e+004 2.644e+004
33 CO2 Loading --- ---
34 CO2 App ML Con (kgmole/m3) --- ---
35 CO2 App WT Con (kgmol/kg) --- ---
36 Phase Fraction [Act. Vol. Basis] 0.0000 1.000
37 Mass Exergy (kJ/kg) 66.16 ---
38 Ideal Gas Cp/Cv 1.069 1.069
39 Ideal Gas Cp (kJ/kgmole-C) 128.8 128.8
40 Mass Ideal Gas Cp (kJ/kg-C) 1.762 1.762
41 Bubble Point Pressure (kg/cm2_g) 0.6498 ---
42
43
COMPOSITION
44
45
Overall Phase Vapour Fraction 0.0000

46 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
47 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
48 n-Pentane 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
49 2M-1-butene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
50 3M-1-butene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
51 2M-2-butene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
52 tr2-Pentene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
53 cis2-Pentene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
54 2M-13-C4== 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
55 1-tr3-C5== 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
56 1-ci3-C5== 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
57 13-CC5== 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
58 i-Butene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
59 1-Pentene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
60 i-Pentane 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
61 DMF 3725.1010 0.9999 272286.2588 0.9999 285.5965 0.9999
62 n-Hexane 0.3155 0.0001 27.1889 0.0001 0.0410 0.0001
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7 Material Stream: DMFATORECYCLE (continue Property Package: Peng-Robinson
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COMPOSITION
11
12
Overall Phase (continued) Vapour Fraction 0.0000

13 Total 3725.4165 1.0000 272313.4478 1.0000 285.6375 1.0000

14
15
Liquid Phase Phase Fraction 1.000

16 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
17 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
18 n-Pentane 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 2M-1-butene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
20 3M-1-butene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
21 2M-2-butene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
22 tr2-Pentene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
23 cis2-Pentene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
24 2M-13-C4== 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
25 1-tr3-C5== 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
26 1-ci3-C5== 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
27 13-CC5== 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
28 i-Butene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
29 1-Pentene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
30 i-Pentane 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
31 DMF 3725.1010 0.9999 272286.2588 0.9999 285.5965 0.9999
32 n-Hexane 0.3155 0.0001 27.1889 0.0001 0.0410 0.0001
33 Total 3725.4165 1.0000 272313.4478 1.0000 285.6375 1.0000
34
35
K VALUE
36 COMPONENTS MIXED LIGHT HEAVY
37 n-Pentane 0.0000 0.0000 ---
38 2M-1-butene 0.0000 0.0000 ---
39 3M-1-butene 0.0000 0.0000 ---
40 2M-2-butene 0.0000 0.0000 ---
41 tr2-Pentene 0.0000 0.0000 ---
42 cis2-Pentene 0.0000 0.0000 ---
43 2M-13-C4== 0.0000 0.0000 ---
44 1-tr3-C5== 0.0000 0.0000 ---
45 1-ci3-C5== 0.0000 0.0000 ---
46 13-CC5== 0.0000 0.0000 ---
47 i-Butene 0.0000 0.0000 ---
48 1-Pentene 0.0000 0.0000 ---
49 i-Pentane 0.0000 0.0000 ---
50 DMF 0.0000 0.0000 ---
51 n-Hexane 0.0000 0.0000 ---
52
53
UNIT OPERATIONS
54 FEED TO PRODUCT FROM LOGICAL CONNECTION
55 Recycle: RCY-2 Distillation: K-35
56
57
UTILITIES
58 ( No utilities reference this stream )
59
60
PROCESS UTILITY
61
62
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7 Material Stream: ISOAM FRACT Property Package: Peng-Robinson
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9
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CONDITIONS
11 Overall Liquid Phase
12 Vapour / Phase Fraction 0.0000 1.0000
13 Temperature: (C) 31.00 31.00
14 Pressure: (kg/cm2_g) 9.000e-002 9.000e-002
15 Molar Flow (kgmole/h) 248.5 248.5
16 Mass Flow (tonne/h) 17.30 17.30
17 Std Ideal Liq Vol Flow (m3/h) 26.00 26.00
18 Molar Enthalpy (kJ/kgmole) -3.522e+004 -3.522e+004
19 Molar Entropy (kJ/kgmole-C) 102.8 102.8
20 Heat Flow (kJ/h) -8.753e+006 -8.753e+006
21 Liq Vol Flow @Std Cond (m3/h) 25.95 * 25.95
22
23
PROPERTIES
24 Overall Liquid Phase
25 Molecular Weight 69.62 69.62
26 Molar Density (kgmole/m3) 9.337 9.337
27 Mass Density (kg/m3) 650.0 650.0
28 Act. Volume Flow (m3/h) 26.62 26.62
29 Mass Enthalpy (kJ/kg) -506.0 -506.0
30 Mass Entropy (kJ/kg-C) 1.477 1.477
31 Heat Capacity (kJ/kgmole-C) 148.4 148.4
32 Mass Heat Capacity (kJ/kg-C) 2.132 2.132
33 LHV Molar Basis (Std) (kJ/kgmole) --- ---
34 LHV Mass Basis (Std) (kJ/kg) --- ---
35 Phase Fraction [Vol. Basis] 0.0000 1.000
36 Phase Fraction [Mass Basis] 0.0000 1.000
37 Partial Pressure of CO2 (kg/cm2_g) -1.033 ---
38 Cost Based on Flow (Cost/s) 0.0000 0.0000
39 Act. Gas Flow (ACT_m3/h) --- ---
40 Avg. Liq. Density (kgmole/m3) 9.558 9.558
41 Specific Heat (kJ/kgmole-C) 148.4 148.4
42 Std. Gas Flow (STD_m3/h) 5876 5876
43 Std. Ideal Liq. Mass Density (kg/m3) 665.4 665.4
44 Act. Liq. Flow (m3/s) 7.394e-003 7.394e-003
45 Z Factor 4.665e-003 4.665e-003
46 Watson K 12.32 12.32
47 User Property --- ---
48 Partial Pressure of H2S (kg/cm2_g) -1.033 ---
49 Cp/(Cp - R) 1.059 1.059
50 Cp/Cv 1.392 1.392
51 Heat of Vap. (kJ/kgmole) 2.552e+004 ---
52 Kinematic Viscosity (cSt) 0.2893 0.2893
53 Liq. Mass Density (Std. Cond) (kg/m3) 666.7 666.7
54 Liq. Vol. Flow (Std. Cond) (m3/h) 25.95 25.95
55 Liquid Fraction 1.000 1.000
56 Molar Volume (m3/kgmole) 0.1071 0.1071
57 Mass Heat of Vap. (kJ/kg) 366.6 ---
58 Phase Fraction [Molar Basis] 0.0000 1.0000
59 Surface Tension (dyne/cm) 15.34 15.34
60 Thermal Conductivity (W/m-K) 0.1059 0.1059
61 Viscosity (cP) 0.1880 0.1880
62 Cv (Semi-Ideal) (kJ/kgmole-C) 140.1 140.1
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PROPERTIES
11 Overall Liquid Phase
12 Mass Cv (Semi-Ideal) (kJ/kg-C) 2.012 2.012
13 Cv (kJ/kgmole-C) 106.6 106.6
14 Mass Cv (kJ/kg-C) 1.532 1.532
15 Cv (Ent. Method) (kJ/kgmole-C) 109.8 109.8
16 Mass Cv (Ent. Method) (kJ/kg-C) 1.577 1.577
17 Cp/Cv (Ent. Method) 1.352 1.352
18 Reid VP at 37.8 C (kg/cm2_g) 0.1243 0.1243
19 True VP at 37.8 C (kg/cm2_g) 0.1250 0.1250
20 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 25.95 25.95
21 Viscosity Index -24.77 ---
22 HHV Molar Basis (Std) (kJ/kgmole) --- ---
23 HHV Mass Basis (Std) (kJ/kg) --- ---
24 CO2 Loading --- ---
25 CO2 App ML Con (kgmole/m3) --- ---
26 CO2 App WT Con (kgmol/kg) --- ---
27 Phase Fraction [Act. Vol. Basis] 0.0000 1.000
28 Mass Exergy (kJ/kg) 0.1406 ---
29 Ideal Gas Cp/Cv 1.084 1.084
30 Ideal Gas Cp (kJ/kgmole-C) 107.3 107.3
31 Mass Ideal Gas Cp (kJ/kg-C) 1.541 1.541
32 Bubble Point Pressure (kg/cm2_g) -0.1118 ---
33
34
COMPOSITION
35
36
Overall Phase Vapour Fraction 0.0000

37 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
38 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
39 n-Pentane 15.5373 0.0625 1121.0352 0.0648 1.7802 0.0685
40 2M-1-butene 45.7869 0.1842 3211.2613 0.1856 4.9073 0.1887
41 3M-1-butene 4.5551 0.0183 319.4719 0.0185 0.5061 0.0195
42 2M-2-butene 87.4066 0.3517 6130.2618 0.3543 9.2031 0.3540
43 tr2-Pentene 5.9720 0.0240 418.8437 0.0242 0.6421 0.0247
44 cis2-Pentene 2.5975 0.0105 182.1740 0.0105 0.2762 0.0106
45 2M-13-C4== 77.1286 0.3104 5253.9224 0.3037 7.6717 0.2951
46 1-tr3-C5== 2.5350 0.0102 172.6844 0.0100 0.2540 0.0098
47 1-ci3-C5== 1.4509 0.0058 98.8341 0.0057 0.1422 0.0055
48 13-CC5== 0.3387 0.0014 22.3863 0.0013 0.0278 0.0011
49 i-Butene 0.2428 0.0010 13.6237 0.0008 0.0230 0.0009
50 1-Pentene 1.0929 0.0044 76.6521 0.0044 0.1200 0.0046
51 i-Pentane 3.8651 0.0156 278.8741 0.0161 0.4473 0.0172
52 DMF 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
53 n-Hexane 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
54 Total 248.5094 1.0000 17300.0251 1.0000 26.0010 1.0000
55
56
Liquid Phase Phase Fraction 1.000

57 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
58 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
59 n-Pentane 15.5373 0.0625 1121.0352 0.0648 1.7802 0.0685
60 2M-1-butene 45.7869 0.1842 3211.2613 0.1856 4.9073 0.1887
61 3M-1-butene 4.5551 0.0183 319.4719 0.0185 0.5061 0.0195
62 2M-2-butene 87.4066 0.3517 6130.2618 0.3543 9.2031 0.3540
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COMPOSITION
11
12
Liquid Phase (continued) Phase Fraction 1.000

13 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
14 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
15 tr2-Pentene 5.9720 0.0240 418.8437 0.0242 0.6421 0.0247
16 cis2-Pentene 2.5975 0.0105 182.1740 0.0105 0.2762 0.0106
17 2M-13-C4== 77.1286 0.3104 5253.9224 0.3037 7.6717 0.2951
18 1-tr3-C5== 2.5350 0.0102 172.6844 0.0100 0.2540 0.0098
19 1-ci3-C5== 1.4509 0.0058 98.8341 0.0057 0.1422 0.0055
20 13-CC5== 0.3387 0.0014 22.3863 0.0013 0.0278 0.0011
21 i-Butene 0.2428 0.0010 13.6237 0.0008 0.0230 0.0009
22 1-Pentene 1.0929 0.0044 76.6521 0.0044 0.1200 0.0046
23 i-Pentane 3.8651 0.0156 278.8741 0.0161 0.4473 0.0172
24 DMF 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
25 n-Hexane 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
26 Total 248.5094 1.0000 17300.0251 1.0000 26.0010 1.0000
27
28
K VALUE
29 COMPONENTS MIXED LIGHT HEAVY
30 n-Pentane 0.0000 0.0000 ---
31 2M-1-butene 0.0000 0.0000 ---
32 3M-1-butene 0.0000 0.0000 ---
33 2M-2-butene 0.0000 0.0000 ---
34 tr2-Pentene 0.0000 0.0000 ---
35 cis2-Pentene 0.0000 0.0000 ---
36 2M-13-C4== 0.0000 0.0000 ---
37 1-tr3-C5== 0.0000 0.0000 ---
38 1-ci3-C5== 0.0000 0.0000 ---
39 13-CC5== 0.0000 0.0000 ---
40 i-Butene 0.0000 0.0000 ---
41 1-Pentene 0.0000 0.0000 ---
42 i-Pentane 0.0000 0.0000 ---
43 DMF --- --- ---
44 n-Hexane 0.0000 0.0000 ---
45
46
UNIT OPERATIONS
47 FEED TO PRODUCT FROM LOGICAL CONNECTION
48 Distillation: K20+20a
49
50
UTILITIES
51 ( No utilities reference this stream )
52
53
PROCESS UTILITY
54
55
Fluid Package: Basis-1
56 Material Stream: ISOPISOAMPIPERILENE FRA Property Package: Peng-Robinson
57
58
59
CONDITIONS
60 Overall Liquid Phase
61 Vapour / Phase Fraction 0.0000 1.0000
62 Temperature: (C) 65.91 65.91
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CONDITIONS
11 Overall Liquid Phase
12 Pressure: (kg/cm2_g) 1.550 1.550
13 Molar Flow (kgmole/h) 268.3 268.3
14 Mass Flow (tonne/h) 18.70 18.70
15 Std Ideal Liq Vol Flow (m3/h) 28.05 28.05
16 Molar Enthalpy (kJ/kgmole) -3.420e+004 -3.420e+004
17 Molar Entropy (kJ/kgmole-C) 122.3 122.3
18 Heat Flow (kJ/h) -9.177e+006 -9.177e+006
19 Liq Vol Flow @Std Cond (m3/h) 28.00 * 28.00
20
21
PROPERTIES
22 Overall Liquid Phase
23 Molecular Weight 69.69 69.69
24 Molar Density (kgmole/m3) 8.785 8.785
25 Mass Density (kg/m3) 612.2 612.2
26 Act. Volume Flow (m3/h) 30.55 30.55
27 Mass Enthalpy (kJ/kg) -490.7 -490.7
28 Mass Entropy (kJ/kg-C) 1.755 1.755
29 Heat Capacity (kJ/kgmole-C) 161.9 161.9
30 Mass Heat Capacity (kJ/kg-C) 2.324 2.324
31 LHV Molar Basis (Std) (kJ/kgmole) --- ---
32 LHV Mass Basis (Std) (kJ/kg) --- ---
33 Phase Fraction [Vol. Basis] 0.0000 1.000
34 Phase Fraction [Mass Basis] 0.0000 1.000
35 Partial Pressure of CO2 (kg/cm2_g) -1.033 ---
36 Cost Based on Flow (Cost/s) 0.0000 0.0000
37 Act. Gas Flow (ACT_m3/h) --- ---
38 Avg. Liq. Density (kgmole/m3) 9.566 9.566
39 Specific Heat (kJ/kgmole-C) 161.9 161.9
40 Std. Gas Flow (STD_m3/h) 6344 6344
41 Std. Ideal Liq. Mass Density (kg/m3) 666.6 666.6
42 Act. Liq. Flow (m3/s) 8.485e-003 8.485e-003
43 Z Factor 1.023e-002 1.023e-002
44 Watson K 12.32 12.32
45 User Property --- ---
46 Partial Pressure of H2S (kg/cm2_g) -1.033 ---
47 Cp/(Cp - R) 1.054 1.054
48 Cp/Cv 1.054 1.054
49 Heat of Vap. (kJ/kgmole) 2.419e+004 ---
50 Kinematic Viscosity (cSt) 0.2240 0.2240
51 Liq. Mass Density (Std. Cond) (kg/m3) 667.9 667.9
52 Liq. Vol. Flow (Std. Cond) (m3/h) 28.00 28.00
53 Liquid Fraction 1.000 1.000
54 Molar Volume (m3/kgmole) 0.1138 0.1138
55 Mass Heat of Vap. (kJ/kg) 347.1 ---
56 Phase Fraction [Molar Basis] 0.0000 1.0000
57 Surface Tension (dyne/cm) 11.71 11.71
58 Thermal Conductivity (W/m-K) 9.586e-002 9.586e-002
59 Viscosity (cP) 0.1371 0.1371
60 Cv (Semi-Ideal) (kJ/kgmole-C) 153.6 153.6
61 Mass Cv (Semi-Ideal) (kJ/kg-C) 2.205 2.205
62 Cv (kJ/kgmole-C) 153.6 153.6
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PROPERTIES
11 Overall Liquid Phase
12 Mass Cv (kJ/kg-C) 2.205 2.205
13 Cv (Ent. Method) (kJ/kgmole-C) --- ---
14 Mass Cv (Ent. Method) (kJ/kg-C) --- ---
15 Cp/Cv (Ent. Method) --- ---
16 Reid VP at 37.8 C (kg/cm2_g) 6.694e-002 6.694e-002
17 True VP at 37.8 C (kg/cm2_g) 6.759e-002 6.759e-002
18 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 28.00 28.00
19 Viscosity Index -43.41 ---
20 HHV Molar Basis (Std) (kJ/kgmole) --- ---
21 HHV Mass Basis (Std) (kJ/kg) --- ---
22 CO2 Loading --- ---
23 CO2 App ML Con (kgmole/m3) --- ---
24 CO2 App WT Con (kgmol/kg) --- ---
25 Phase Fraction [Act. Vol. Basis] 0.0000 1.000
26 Mass Exergy (kJ/kg) 6.000 ---
27 Ideal Gas Cp/Cv 1.078 1.078
28 Ideal Gas Cp (kJ/kgmole-C) 115.5 115.5
29 Mass Ideal Gas Cp (kJ/kg-C) 1.657 1.657
30 Bubble Point Pressure (kg/cm2_g) 1.550 ---
31
32
COMPOSITION
33
34
Overall Phase Vapour Fraction 0.0000

35 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
36 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
37 n-Pentane 23.8190 0.0888 1718.5667 0.0919 2.7291 0.0973
38 2M-1-butene 22.8661 0.0852 1603.7134 0.0858 2.4507 0.0874
39 3M-1-butene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 2M-2-butene 126.2802 0.4706 8856.6593 0.4736 13.2961 0.4740
41 tr2-Pentene 8.1420 0.0303 571.0417 0.0305 0.8755 0.0312
42 cis2-Pentene 3.6180 0.0135 253.7506 0.0136 0.3847 0.0137
43 2M-13-C4== 79.4427 0.2961 5411.5608 0.2894 7.9019 0.2817
44 1-tr3-C5== 1.9984 0.0074 136.1319 0.0073 0.2002 0.0071
45 1-ci3-C5== 1.2537 0.0047 85.4034 0.0046 0.1229 0.0044
46 13-CC5== 0.3872 0.0014 25.5960 0.0014 0.0318 0.0011
47 i-Butene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
48 1-Pentene 0.3184 0.0012 22.3321 0.0012 0.0350 0.0012
49 i-Pentane 0.1976 0.0007 14.2599 0.0008 0.0229 0.0008
50 DMF 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
51 n-Hexane 0.0050 0.0000 0.4351 0.0000 0.0007 0.0000
52 Total 268.3286 1.0000 18699.4508 1.0000 28.0514 1.0000
53
54
Liquid Phase Phase Fraction 1.000

55 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
56 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
57 n-Pentane 23.8190 0.0888 1718.5667 0.0919 2.7291 0.0973
58 2M-1-butene 22.8661 0.0852 1603.7134 0.0858 2.4507 0.0874
59 3M-1-butene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
60 2M-2-butene 126.2802 0.4706 8856.6593 0.4736 13.2961 0.4740
61 tr2-Pentene 8.1420 0.0303 571.0417 0.0305 0.8755 0.0312
62 cis2-Pentene 3.6180 0.0135 253.7506 0.0136 0.3847 0.0137
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COMPOSITION
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Liquid Phase (continued) Phase Fraction 1.000

13 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
14 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
15 2M-13-C4== 79.4427 0.2961 5411.5608 0.2894 7.9019 0.2817
16 1-tr3-C5== 1.9984 0.0074 136.1319 0.0073 0.2002 0.0071
17 1-ci3-C5== 1.2537 0.0047 85.4034 0.0046 0.1229 0.0044
18 13-CC5== 0.3872 0.0014 25.5960 0.0014 0.0318 0.0011
19 i-Butene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
20 1-Pentene 0.3184 0.0012 22.3321 0.0012 0.0350 0.0012
21 i-Pentane 0.1976 0.0007 14.2599 0.0008 0.0229 0.0008
22 DMF 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
23 n-Hexane 0.0050 0.0000 0.4351 0.0000 0.0007 0.0000
24 Total 268.3286 1.0000 18699.4508 1.0000 28.0514 1.0000
25
26
K VALUE
27 COMPONENTS MIXED LIGHT HEAVY
28 n-Pentane 0.0000 0.0000 ---
29 2M-1-butene 0.0000 0.0000 ---
30 3M-1-butene 0.0000 0.0000 ---
31 2M-2-butene 0.0000 0.0000 ---
32 tr2-Pentene 0.0000 0.0000 ---
33 cis2-Pentene 0.0000 0.0000 ---
34 2M-13-C4== 0.0000 0.0000 ---
35 1-tr3-C5== 0.0000 0.0000 ---
36 1-ci3-C5== 0.0000 0.0000 ---
37 13-CC5== 0.0000 0.0000 ---
38 i-Butene 0.0000 0.0000 ---
39 1-Pentene 0.0000 0.0000 ---
40 i-Pentane 0.0000 0.0000 ---
41 DMF 0.0000 0.0000 ---
42 n-Hexane 0.0000 0.0000 ---
43
44
UNIT OPERATIONS
45 FEED TO PRODUCT FROM LOGICAL CONNECTION
46 Distillation: K-187 Distillation: K-70+70a
47
48
UTILITIES
49 ( No utilities reference this stream )
50
51
PROCESS UTILITY
52
53
Fluid Package: Basis-1
54 Material Stream: ISOPRENE Property Package: Peng-Robinson
55
56
57
CONDITIONS
58 Overall Liquid Phase
59 Vapour / Phase Fraction 0.0000 1.0000
60 Temperature: (C) 43.84 43.84
61 Pressure: (kg/cm2_g) 0.5500 0.5500
62 Molar Flow (kgmole/h) 129.5 129.5
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Fluid Package: Basis-1
7 Material Stream: ISOPRENE (continued) Property Package: Peng-Robinson
8
9
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CONDITIONS
11 Overall Liquid Phase
12 Mass Flow (tonne/h) 9.000 9.000
13 Std Ideal Liq Vol Flow (m3/h) 13.61 13.61
14 Molar Enthalpy (kJ/kgmole) -2.354e+004 -2.354e+004
15 Molar Entropy (kJ/kgmole-C) 94.09 94.09
16 Heat Flow (kJ/h) -3.049e+006 -3.049e+006
17 Liq Vol Flow @Std Cond (m3/h) 13.58 * 13.58
18
19
PROPERTIES
20 Overall Liquid Phase
21 Molecular Weight 69.49 69.49
22 Molar Density (kgmole/m3) 9.099 9.099
23 Mass Density (kg/m3) 632.3 632.3
24 Act. Volume Flow (m3/h) 14.23 14.23
25 Mass Enthalpy (kJ/kg) -338.8 -338.8
26 Mass Entropy (kJ/kg-C) 1.354 1.354
27 Heat Capacity (kJ/kgmole-C) 155.3 155.3
28 Mass Heat Capacity (kJ/kg-C) 2.236 2.236
29 LHV Molar Basis (Std) (kJ/kgmole) --- ---
30 LHV Mass Basis (Std) (kJ/kg) --- ---
31 Phase Fraction [Vol. Basis] 0.0000 1.000
32 Phase Fraction [Mass Basis] 0.0000 1.000
33 Partial Pressure of CO2 (kg/cm2_g) -1.033 ---
34 Cost Based on Flow (Cost/s) 0.0000 0.0000
35 Act. Gas Flow (ACT_m3/h) --- ---
36 Avg. Liq. Density (kgmole/m3) 9.519 9.519
37 Specific Heat (kJ/kgmole-C) 155.3 155.3
38 Std. Gas Flow (STD_m3/h) 3062 3062
39 Std. Ideal Liq. Mass Density (kg/m3) 661.4 661.4
40 Act. Liq. Flow (m3/s) 3.954e-003 3.954e-003
41 Z Factor 6.474e-003 6.474e-003
42 Watson K 12.35 12.35
43 User Property --- ---
44 Partial Pressure of H2S (kg/cm2_g) -1.033 ---
45 Cp/(Cp - R) 1.057 1.057
46 Cp/Cv 1.365 1.365
47 Heat of Vap. (kJ/kgmole) 2.428e+004 ---
48 Kinematic Viscosity (cSt) 0.2663 0.2663
49 Liq. Mass Density (Std. Cond) (kg/m3) 663.0 663.0
50 Liq. Vol. Flow (Std. Cond) (m3/h) 13.58 13.58
51 Liquid Fraction 1.000 1.000
52 Molar Volume (m3/kgmole) 0.1099 0.1099
53 Mass Heat of Vap. (kJ/kg) 349.3 ---
54 Phase Fraction [Molar Basis] 0.0000 1.0000
55 Surface Tension (dyne/cm) 13.50 13.50
56 Thermal Conductivity (W/m-K) 0.1004 0.1004
57 Viscosity (cP) 0.1684 0.1684
58 Cv (Semi-Ideal) (kJ/kgmole-C) 147.0 147.0
59 Mass Cv (Semi-Ideal) (kJ/kg-C) 2.116 2.116
60 Cv (kJ/kgmole-C) 113.8 113.8
61 Mass Cv (kJ/kg-C) 1.638 1.638
62 Cv (Ent. Method) (kJ/kgmole-C) --- ---
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7 Material Stream: ISOPRENE (continued) Property Package: Peng-Robinson
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PROPERTIES
11 Overall Liquid Phase
12 Mass Cv (Ent. Method) (kJ/kg-C) --- ---
13 Cp/Cv (Ent. Method) --- ---
14 Reid VP at 37.8 C (kg/cm2_g) 0.2752 0.2752
15 True VP at 37.8 C (kg/cm2_g) 0.2759 0.2759
16 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 13.58 13.58
17 Viscosity Index -28.94 ---
18 HHV Molar Basis (Std) (kJ/kgmole) --- ---
19 HHV Mass Basis (Std) (kJ/kg) --- ---
20 CO2 Loading --- ---
21 CO2 App ML Con (kgmole/m3) --- ---
22 CO2 App WT Con (kgmol/kg) --- ---
23 Phase Fraction [Act. Vol. Basis] 0.0000 1.000
24 Mass Exergy (kJ/kg) 1.338 ---
25 Ideal Gas Cp/Cv 1.078 1.078
26 Ideal Gas Cp (kJ/kgmole-C) 114.7 114.7
27 Mass Ideal Gas Cp (kJ/kg-C) 1.650 1.650
28 Bubble Point Pressure (kg/cm2_g) 0.5500 ---
29
30
COMPOSITION
31
32
Overall Phase Vapour Fraction 0.0000

33 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
34 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
35 n-Pentane 3.1556 0.0244 227.6802 0.0253 0.3616 0.0266
36 2M-1-butene 56.2072 0.4340 3942.0905 0.4380 6.0242 0.4427
37 3M-1-butene 8.3876 0.0648 588.2611 0.0654 0.9319 0.0685
38 2M-2-butene 1.7207 0.0133 120.6815 0.0134 0.1812 0.0133
39 tr2-Pentene 1.0090 0.0078 70.7691 0.0079 0.1085 0.0080
40 cis2-Pentene 0.2563 0.0020 17.9757 0.0020 0.0273 0.0020
41 2M-13-C4== 50.1527 0.3872 3416.3553 0.3796 4.9885 0.3666
42 1-tr3-C5== 0.0012 0.0000 0.0822 0.0000 0.0001 0.0000
43 1-ci3-C5== 0.0001 0.0000 0.0036 0.0000 0.0000 0.0000
44 13-CC5== 0.0559 0.0004 3.6974 0.0004 0.0046 0.0003
45 i-Butene 0.1741 0.0013 9.7684 0.0011 0.0165 0.0012
46 1-Pentene 1.5813 0.0122 110.9029 0.0123 0.1736 0.0128
47 i-Pentane 6.8152 0.0526 491.7213 0.0546 0.7887 0.0580
48 DMF 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
49 n-Hexane 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
50 Total 129.5169 1.0000 8999.9891 1.0000 13.6066 1.0000
51
52
Liquid Phase Phase Fraction 1.000

53 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
54 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
55 n-Pentane 3.1556 0.0244 227.6802 0.0253 0.3616 0.0266
56 2M-1-butene 56.2072 0.4340 3942.0905 0.4380 6.0242 0.4427
57 3M-1-butene 8.3876 0.0648 588.2611 0.0654 0.9319 0.0685
58 2M-2-butene 1.7207 0.0133 120.6815 0.0134 0.1812 0.0133
59 tr2-Pentene 1.0090 0.0078 70.7691 0.0079 0.1085 0.0080
60 cis2-Pentene 0.2563 0.0020 17.9757 0.0020 0.0273 0.0020
61 2M-13-C4== 50.1527 0.3872 3416.3553 0.3796 4.9885 0.3666
62 1-tr3-C5== 0.0012 0.0000 0.0822 0.0000 0.0001 0.0000
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7 Material Stream: ISOPRENE (continued) Property Package: Peng-Robinson
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COMPOSITION
11
12
Liquid Phase (continued) Phase Fraction 1.000

13 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
14 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
15 1-ci3-C5== 0.0001 0.0000 0.0036 0.0000 0.0000 0.0000
16 13-CC5== 0.0559 0.0004 3.6974 0.0004 0.0046 0.0003
17 i-Butene 0.1741 0.0013 9.7684 0.0011 0.0165 0.0012
18 1-Pentene 1.5813 0.0122 110.9029 0.0123 0.1736 0.0128
19 i-Pentane 6.8152 0.0526 491.7213 0.0546 0.7887 0.0580
20 DMF 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
21 n-Hexane 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
22 Total 129.5169 1.0000 8999.9891 1.0000 13.6066 1.0000
23
24
K VALUE
25 COMPONENTS MIXED LIGHT HEAVY
26 n-Pentane 0.0000 0.0000 ---
27 2M-1-butene 0.0000 0.0000 ---
28 3M-1-butene 0.0000 0.0000 ---
29 2M-2-butene 0.0000 0.0000 ---
30 tr2-Pentene 0.0000 0.0000 ---
31 cis2-Pentene 0.0000 0.0000 ---
32 2M-13-C4== 0.0000 0.0000 ---
33 1-tr3-C5== 0.0000 0.0000 ---
34 1-ci3-C5== 0.0000 0.0000 ---
35 13-CC5== 0.0000 0.0000 ---
36 i-Butene 0.0000 0.0000 ---
37 1-Pentene 0.0000 0.0000 ---
38 i-Pentane 0.0000 0.0000 ---
39 DMF 0.0000 0.0000 ---
40 n-Hexane 0.0000 0.0000 ---
41
42
UNIT OPERATIONS
43 FEED TO PRODUCT FROM LOGICAL CONNECTION
44 Distillation: K-70+70a
45
46
UTILITIES
47 ( No utilities reference this stream )
48
49
PROCESS UTILITY
50
51
Fluid Package: Basis-1
52 Material Stream: ISOPRENE FRACT Property Package: Peng-Robinson
53
54
55
CONDITIONS
56 Overall Liquid Phase
57 Vapour / Phase Fraction 0.0000 1.0000
58 Temperature: (C) 37.11 37.11
59 Pressure: (kg/cm2_g) 0.1100 0.1100
60 Molar Flow (kgmole/h) 397.8 397.8
61 Mass Flow (tonne/h) 27.70 27.70
62 Std Ideal Liq Vol Flow (m3/h) 41.66 41.66
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Fluid Package: Basis-1
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CONDITIONS
11 Overall Liquid Phase
12 Molar Enthalpy (kJ/kgmole) -3.410e+004 -3.410e+004
13 Molar Entropy (kJ/kgmole-C) 104.7 104.7
14 Heat Flow (kJ/h) -1.357e+007 -1.357e+007
15 Liq Vol Flow @Std Cond (m3/h) 41.57 * 41.57
16
17
PROPERTIES
18 Overall Liquid Phase
19 Molecular Weight 69.62 69.62
20 Molar Density (kgmole/m3) 9.235 9.235
21 Mass Density (kg/m3) 642.9 642.9
22 Act. Volume Flow (m3/h) 43.08 43.08
23 Mass Enthalpy (kJ/kg) -489.8 -489.8
24 Mass Entropy (kJ/kg-C) 1.503 1.503
25 Heat Capacity (kJ/kgmole-C) 151.0 151.0
26 Mass Heat Capacity (kJ/kg-C) 2.169 2.169
27 LHV Molar Basis (Std) (kJ/kgmole) --- ---
28 LHV Mass Basis (Std) (kJ/kg) --- ---
29 Phase Fraction [Vol. Basis] 0.0000 1.000
30 Phase Fraction [Mass Basis] 0.0000 1.000
31 Partial Pressure of CO2 (kg/cm2_g) -1.033 ---
32 Cost Based on Flow (Cost/s) 0.0000 0.0000
33 Act. Gas Flow (ACT_m3/h) --- ---
34 Avg. Liq. Density (kgmole/m3) 9.550 9.550
35 Specific Heat (kJ/kgmole-C) 151.0 151.0
36 Std. Gas Flow (STD_m3/h) 9407 9407
37 Std. Ideal Liq. Mass Density (kg/m3) 664.9 664.9
38 Act. Liq. Flow (m3/s) 1.197e-002 1.197e-002
39 Z Factor 4.706e-003 4.706e-003
40 Watson K 12.33 12.33
41 User Property --- ---
42 Partial Pressure of H2S (kg/cm2_g) -1.033 ---
43 Cp/(Cp - R) 1.058 1.058
44 Cp/Cv 1.388 1.388
45 Heat of Vap. (kJ/kgmole) 2.543e+004 ---
46 Kinematic Viscosity (cSt) 0.2766 0.2766
47 Liq. Mass Density (Std. Cond) (kg/m3) 666.3 666.3
48 Liq. Vol. Flow (Std. Cond) (m3/h) 41.57 41.57
49 Liquid Fraction 1.000 1.000
50 Molar Volume (m3/kgmole) 0.1083 0.1083
51 Mass Heat of Vap. (kJ/kg) 365.2 ---
52 Phase Fraction [Molar Basis] 0.0000 1.0000
53 Surface Tension (dyne/cm) 14.63 14.63
54 Thermal Conductivity (W/m-K) 0.1040 0.1040
55 Viscosity (cP) 0.1779 0.1779
56 Cv (Semi-Ideal) (kJ/kgmole-C) 142.7 142.7
57 Mass Cv (Semi-Ideal) (kJ/kg-C) 2.049 2.049
58 Cv (kJ/kgmole-C) 108.8 108.8
59 Mass Cv (kJ/kg-C) 1.563 1.563
60 Cv (Ent. Method) (kJ/kgmole-C) --- ---
61 Mass Cv (Ent. Method) (kJ/kg-C) --- ---
62 Cp/Cv (Ent. Method) --- ---
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PROPERTIES
11 Overall Liquid Phase
12 Reid VP at 37.8 C (kg/cm2_g) 0.1348 0.1348
13 True VP at 37.8 C (kg/cm2_g) 0.1354 0.1354
14 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 41.57 41.57
15 Viscosity Index -26.90 ---
16 HHV Molar Basis (Std) (kJ/kgmole) --- ---
17 HHV Mass Basis (Std) (kJ/kg) --- ---
18 CO2 Loading --- ---
19 CO2 App ML Con (kgmole/m3) --- ---
20 CO2 App WT Con (kgmol/kg) --- ---
21 Phase Fraction [Act. Vol. Basis] 0.0000 1.000
22 Mass Exergy (kJ/kg) 0.5305 ---
23 Ideal Gas Cp/Cv 1.082 1.082
24 Ideal Gas Cp (kJ/kgmole-C) 109.4 109.4
25 Mass Ideal Gas Cp (kJ/kg-C) 1.571 1.571
26 Bubble Point Pressure (kg/cm2_g) 0.1100 ---
27
28
COMPOSITION
29
30
Overall Phase Vapour Fraction 0.0000

31 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
32 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
33 n-Pentane 26.9746 0.0678 1946.2469 0.0703 3.0906 0.0742
34 2M-1-butene 79.0733 0.1988 5545.8039 0.2002 8.4749 0.2034
35 3M-1-butene 8.3876 0.0211 588.2611 0.0212 0.9319 0.0224
36 2M-2-butene 128.0009 0.3217 8977.3407 0.3241 13.4773 0.3235
37 tr2-Pentene 9.1511 0.0230 641.8108 0.0232 0.9840 0.0236
38 cis2-Pentene 3.8743 0.0097 271.7264 0.0098 0.4120 0.0099
39 2M-13-C4== 129.5955 0.3257 8827.9162 0.3187 12.8904 0.3094
40 1-tr3-C5== 1.9996 0.0050 136.2141 0.0049 0.2003 0.0048
41 1-ci3-C5== 1.2538 0.0032 85.4069 0.0031 0.1229 0.0030
42 13-CC5== 0.4432 0.0011 29.2934 0.0011 0.0364 0.0009
43 i-Butene 0.1741 0.0004 9.7684 0.0004 0.0165 0.0004
44 1-Pentene 1.8997 0.0048 133.2350 0.0048 0.2086 0.0050
45 i-Pentane 7.0128 0.0176 505.9812 0.0183 0.8116 0.0195
46 DMF 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
47 n-Hexane 0.0050 0.0000 0.4351 0.0000 0.0007 0.0000
48 Total 397.8455 1.0000 27699.4402 1.0000 41.6580 1.0000
49
50
Liquid Phase Phase Fraction 1.000

51 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
52 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
53 n-Pentane 26.9746 0.0678 1946.2469 0.0703 3.0906 0.0742
54 2M-1-butene 79.0733 0.1988 5545.8039 0.2002 8.4749 0.2034
55 3M-1-butene 8.3876 0.0211 588.2611 0.0212 0.9319 0.0224
56 2M-2-butene 128.0009 0.3217 8977.3407 0.3241 13.4773 0.3235
57 tr2-Pentene 9.1511 0.0230 641.8108 0.0232 0.9840 0.0236
58 cis2-Pentene 3.8743 0.0097 271.7264 0.0098 0.4120 0.0099
59 2M-13-C4== 129.5955 0.3257 8827.9162 0.3187 12.8904 0.3094
60 1-tr3-C5== 1.9996 0.0050 136.2141 0.0049 0.2003 0.0048
61 1-ci3-C5== 1.2538 0.0032 85.4069 0.0031 0.1229 0.0030
62 13-CC5== 0.4432 0.0011 29.2934 0.0011 0.0364 0.0009
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COMPOSITION
11
12
Liquid Phase (continued) Phase Fraction 1.000

13 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
14 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
15 i-Butene 0.1741 0.0004 9.7684 0.0004 0.0165 0.0004
16 1-Pentene 1.8997 0.0048 133.2350 0.0048 0.2086 0.0050
17 i-Pentane 7.0128 0.0176 505.9812 0.0183 0.8116 0.0195
18 DMF 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 n-Hexane 0.0050 0.0000 0.4351 0.0000 0.0007 0.0000
20 Total 397.8455 1.0000 27699.4402 1.0000 41.6580 1.0000
21
22
K VALUE
23 COMPONENTS MIXED LIGHT HEAVY
24 n-Pentane 0.0000 0.0000 ---
25 2M-1-butene 0.0000 0.0000 ---
26 3M-1-butene 0.0000 0.0000 ---
27 2M-2-butene 0.0000 0.0000 ---
28 tr2-Pentene 0.0000 0.0000 ---
29 cis2-Pentene 0.0000 0.0000 ---
30 2M-13-C4== 0.0000 0.0000 ---
31 1-tr3-C5== 0.0000 0.0000 ---
32 1-ci3-C5== 0.0000 0.0000 ---
33 13-CC5== 0.0000 0.0000 ---
34 i-Butene 0.0000 0.0000 ---
35 1-Pentene 0.0000 0.0000 ---
36 i-Pentane 0.0000 0.0000 ---
37 DMF 0.0000 0.0000 ---
38 n-Hexane 0.0000 0.0000 ---
39
40
UNIT OPERATIONS
41 FEED TO PRODUCT FROM LOGICAL CONNECTION
42 Distillation: K-70+70a Distillation: K-35
43
44
UTILITIES
45 ( No utilities reference this stream )
46
47
PROCESS UTILITY
48
49
Fluid Package: Basis-1
50 Material Stream: PIPERYLENE FRACT Property Package: Peng-Robinson
51
52
53
CONDITIONS
54 Overall Liquid Phase
55 Vapour / Phase Fraction 0.0000 1.0000
56 Temperature: (C) 59.43 59.43
57 Pressure: (kg/cm2_g) 1.000 1.000
58 Molar Flow (kgmole/h) 109.8 109.8
59 Mass Flow (tonne/h) 7.700 7.700
60 Std Ideal Liq Vol Flow (m3/h) 11.59 11.59
61 Molar Enthalpy (kJ/kgmole) -6.144e+004 -6.144e+004
62 Molar Entropy (kJ/kgmole-C) 125.4 125.4
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Fluid Package: Basis-1
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CONDITIONS
11 Overall Liquid Phase
12 Heat Flow (kJ/h) -6.748e+006 -6.748e+006
13 Liq Vol Flow @Std Cond (m3/h) 11.56 * 11.56
14
15
PROPERTIES
16 Overall Liquid Phase
17 Molecular Weight 70.11 70.11
18 Molar Density (kgmole/m3) 8.804 8.804
19 Mass Density (kg/m3) 617.2 617.2
20 Act. Volume Flow (m3/h) 12.47 12.47
21 Mass Enthalpy (kJ/kg) -876.4 -876.4
22 Mass Entropy (kJ/kg-C) 1.789 1.789
23 Heat Capacity (kJ/kgmole-C) 158.4 158.4
24 Mass Heat Capacity (kJ/kg-C) 2.260 2.260
25 LHV Molar Basis (Std) (kJ/kgmole) --- ---
26 LHV Mass Basis (Std) (kJ/kg) --- ---
27 Phase Fraction [Vol. Basis] 0.0000 1.000
28 Phase Fraction [Mass Basis] 0.0000 1.000
29 Partial Pressure of CO2 (kg/cm2_g) -1.033 ---
30 Cost Based on Flow (Cost/s) 0.0000 0.0000
31 Act. Gas Flow (ACT_m3/h) --- ---
32 Avg. Liq. Density (kgmole/m3) 9.478 9.478
33 Specific Heat (kJ/kgmole-C) 158.4 158.4
34 Std. Gas Flow (STD_m3/h) 2597 2597
35 Std. Ideal Liq. Mass Density (kg/m3) 664.5 664.5
36 Act. Liq. Flow (m3/s) 3.465e-003 3.465e-003
37 Z Factor 8.191e-003 8.191e-003
38 Watson K 12.38 12.38
39 User Property --- ---
40 Partial Pressure of H2S (kg/cm2_g) -1.033 ---
41 Cp/(Cp - R) 1.055 1.055
42 Cp/Cv 1.055 1.055
43 Heat of Vap. (kJ/kgmole) 2.526e+004 ---
44 Kinematic Viscosity (cSt) 0.2338 0.2338
45 Liq. Mass Density (Std. Cond) (kg/m3) 666.1 666.1
46 Liq. Vol. Flow (Std. Cond) (m3/h) 11.56 11.56
47 Liquid Fraction 1.000 1.000
48 Molar Volume (m3/kgmole) 0.1136 0.1136
49 Mass Heat of Vap. (kJ/kg) 360.3 ---
50 Phase Fraction [Molar Basis] 0.0000 1.0000
51 Surface Tension (dyne/cm) 12.38 12.38
52 Thermal Conductivity (W/m-K) 9.784e-002 9.784e-002
53 Viscosity (cP) 0.1443 0.1443
54 Cv (Semi-Ideal) (kJ/kgmole-C) 150.1 150.1
55 Mass Cv (Semi-Ideal) (kJ/kg-C) 2.141 2.141
56 Cv (kJ/kgmole-C) 150.1 150.1
57 Mass Cv (kJ/kg-C) 2.141 2.141
58 Cv (Ent. Method) (kJ/kgmole-C) --- ---
59 Mass Cv (Ent. Method) (kJ/kg-C) --- ---
60 Cp/Cv (Ent. Method) --- ---
61 Reid VP at 37.8 C (kg/cm2_g) -1.421e-002 -1.421e-002
62 True VP at 37.8 C (kg/cm2_g) -1.349e-002 -1.349e-002
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Fluid Package: Basis-1
7 Material Stream: PIPERYLENE FRACT (contin Property Package: Peng-Robinson
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PROPERTIES
11 Overall Liquid Phase
12 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 11.56 11.56
13 Viscosity Index -38.52 ---
14 HHV Molar Basis (Std) (kJ/kgmole) --- ---
15 HHV Mass Basis (Std) (kJ/kg) --- ---
16 CO2 Loading --- ---
17 CO2 App ML Con (kgmole/m3) --- ---
18 CO2 App WT Con (kgmol/kg) --- ---
19 Phase Fraction [Act. Vol. Basis] 0.0000 1.000
20 Mass Exergy (kJ/kg) 4.207 ---
21 Ideal Gas Cp/Cv 1.082 1.082
22 Ideal Gas Cp (kJ/kgmole-C) 110.0 110.0
23 Mass Ideal Gas Cp (kJ/kg-C) 1.568 1.568
24 Bubble Point Pressure (kg/cm2_g) 1.000 ---
25
26
COMPOSITION
27
28
Overall Phase Vapour Fraction 0.0000

29 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
30 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
31 n-Pentane 7.6555 0.0697 552.3555 0.0717 0.8771 0.0757
32 2M-1-butene 0.2440 0.0022 17.1111 0.0022 0.0261 0.0023
33 3M-1-butene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
34 2M-2-butene 88.5219 0.8060 6208.4804 0.8063 9.3205 0.8044
35 tr2-Pentene 2.7107 0.0247 190.1184 0.0247 0.2915 0.0252
36 cis2-Pentene 1.5860 0.0144 111.2330 0.0144 0.1686 0.0146
37 2M-13-C4== 5.8800 0.0535 400.5423 0.0520 0.5849 0.0505
38 1-tr3-C5== 1.8736 0.0171 127.6290 0.0166 0.1877 0.0162
39 1-ci3-C5== 1.2351 0.0112 84.1367 0.0109 0.1211 0.0104
40 13-CC5== 0.1110 0.0010 7.3402 0.0010 0.0091 0.0008
41 i-Butene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
42 1-Pentene 0.0015 0.0000 0.1076 0.0000 0.0002 0.0000
43 i-Pentane 0.0002 0.0000 0.0146 0.0000 0.0000 0.0000
44 DMF 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
45 n-Hexane 0.0050 0.0000 0.4351 0.0001 0.0007 0.0001
46 Total 109.8247 1.0000 7699.5037 1.0000 11.5875 1.0000
47
48
Liquid Phase Phase Fraction 1.000

49 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
50 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
51 n-Pentane 7.6555 0.0697 552.3555 0.0717 0.8771 0.0757
52 2M-1-butene 0.2440 0.0022 17.1111 0.0022 0.0261 0.0023
53 3M-1-butene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
54 2M-2-butene 88.5219 0.8060 6208.4804 0.8063 9.3205 0.8044
55 tr2-Pentene 2.7107 0.0247 190.1184 0.0247 0.2915 0.0252
56 cis2-Pentene 1.5860 0.0144 111.2330 0.0144 0.1686 0.0146
57 2M-13-C4== 5.8800 0.0535 400.5423 0.0520 0.5849 0.0505
58 1-tr3-C5== 1.8736 0.0171 127.6290 0.0166 0.1877 0.0162
59 1-ci3-C5== 1.2351 0.0112 84.1367 0.0109 0.1211 0.0104
60 13-CC5== 0.1110 0.0010 7.3402 0.0010 0.0091 0.0008
61 i-Butene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
62 1-Pentene 0.0015 0.0000 0.1076 0.0000 0.0002 0.0000
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COMPOSITION
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Liquid Phase (continued) Phase Fraction 1.000

13 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
14 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
15 i-Pentane 0.0002 0.0000 0.0146 0.0000 0.0000 0.0000
16 DMF 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
17 n-Hexane 0.0050 0.0000 0.4351 0.0001 0.0007 0.0001
18 Total 109.8247 1.0000 7699.5037 1.0000 11.5875 1.0000
19
20
K VALUE
21 COMPONENTS MIXED LIGHT HEAVY
22 n-Pentane 0.0000 0.0000 ---
23 2M-1-butene 0.0000 0.0000 ---
24 3M-1-butene 0.0000 0.0000 ---
25 2M-2-butene 0.0000 0.0000 ---
26 tr2-Pentene 0.0000 0.0000 ---
27 cis2-Pentene 0.0000 0.0000 ---
28 2M-13-C4== 0.0000 0.0000 ---
29 1-tr3-C5== 0.0000 0.0000 ---
30 1-ci3-C5== 0.0000 0.0000 ---
31 13-CC5== 0.0000 0.0000 ---
32 i-Butene 0.0000 0.0000 ---
33 1-Pentene 0.0000 0.0000 ---
34 i-Pentane 0.0000 0.0000 ---
35 DMF 0.0000 0.0000 ---
36 n-Hexane 0.0000 0.0000 ---
37
38
UNIT OPERATIONS
39 FEED TO PRODUCT FROM LOGICAL CONNECTION
40 Distillation: K-187
41
42
UTILITIES
43 ( No utilities reference this stream )
44
45
PROCESS UTILITY
46
47
Fluid Package: Basis-2
48 Material Stream: RECYCLE E-190 Property Package: NRTL - Ideal
49
50
51
CONDITIONS
52 Overall Liquid Phase
53 Vapour / Phase Fraction 0.0000 1.0000
54 Temperature: (C) 41.88 * 41.88
55 Pressure: (kg/cm2_g) 0.5500 * 0.5500
56 Molar Flow (kgmole/h) 158.5 * 158.5
57 Mass Flow (tonne/h) 11.00 11.00
58 Std Ideal Liq Vol Flow (m3/h) 16.46 16.46
59 Molar Enthalpy (kJ/kgmole) -2.033e+004 -2.033e+004
60 Molar Entropy (kJ/kgmole-C) 145.6 145.6
61 Heat Flow (kJ/h) -3.222e+006 -3.222e+006
62 Liq Vol Flow @Std Cond (m3/h) 16.44 * 16.44
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Fluid Package: Basis-2
7 Material Stream: RECYCLE E-190 (continued) Property Package: NRTL - Ideal
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PROPERTIES
11 Overall Liquid Phase
12 Molecular Weight 69.40 69.40
13 Molar Density (kgmole/m3) 9.236 9.236
14 Mass Density (kg/m3) 641.0 641.0
15 Act. Volume Flow (m3/h) 17.16 17.16
16 Mass Enthalpy (kJ/kg) -292.9 -292.9
17 Mass Entropy (kJ/kg-C) 2.098 2.098
18 Heat Capacity (kJ/kgmole-C) 157.8 157.8
19 Mass Heat Capacity (kJ/kg-C) 2.274 2.274
20 LHV Molar Basis (Std) (kJ/kgmole) --- ---
21 LHV Mass Basis (Std) (kJ/kg) --- ---
22 Phase Fraction [Vol. Basis] 0.0000 1.000
23 Phase Fraction [Mass Basis] 0.0000 1.000
24 Partial Pressure of CO2 (kg/cm2_g) -1.033 ---
25 Cost Based on Flow (Cost/s) 0.0000 0.0000
26 Act. Gas Flow (ACT_m3/h) --- ---
27 Avg. Liq. Density (kgmole/m3) 9.627 9.627
28 Specific Heat (kJ/kgmole-C) 157.8 157.8
29 Std. Gas Flow (STD_m3/h) 3748 3748
30 Std. Ideal Liq. Mass Density (kg/m3) 668.1 668.1
31 Act. Liq. Flow (m3/s) 4.767e-003 4.767e-003
32 Z Factor 6.418e-003 6.418e-003
33 Watson K 12.27 12.27
34 User Property --- ---
35 Partial Pressure of H2S (kg/cm2_g) -1.033 ---
36 Cp/(Cp - R) 1.056 1.056
37 Cp/Cv 1.357 1.357
38 Heat of Vap. (kJ/kgmole) 2.554e+004 ---
39 Kinematic Viscosity (cSt) 0.2657 0.2657
40 Liq. Mass Density (Std. Cond) (kg/m3) 669.2 669.2
41 Liq. Vol. Flow (Std. Cond) (m3/h) 16.44 16.44
42 Liquid Fraction 1.000 1.000
43 Molar Volume (m3/kgmole) 0.1083 0.1083
44 Mass Heat of Vap. (kJ/kg) 368.0 ---
45 Phase Fraction [Molar Basis] 0.0000 1.0000
46 Surface Tension (dyne/cm) 14.29 14.29
47 Thermal Conductivity (W/m-K) 0.1032 0.1032
48 Viscosity (cP) 0.1703 0.1703
49 Cv (Semi-Ideal) (kJ/kgmole-C) 149.5 149.5
50 Mass Cv (Semi-Ideal) (kJ/kg-C) 2.154 2.154
51 Cv (kJ/kgmole-C) 116.2 116.2
52 Mass Cv (kJ/kg-C) 1.675 1.675
53 Cv (Ent. Method) (kJ/kgmole-C) --- ---
54 Mass Cv (Ent. Method) (kJ/kg-C) --- ---
55 Cp/Cv (Ent. Method) --- ---
56 Reid VP at 37.8 C (kg/cm2_g) 0.1376 0.1376
57 True VP at 37.8 C (kg/cm2_g) 0.1382 0.1382
58 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 16.44 16.44
59 Viscosity Index -29.07 ---
60 HHV Molar Basis (Std) (kJ/kgmole) --- ---
61 HHV Mass Basis (Std) (kJ/kg) --- ---
62 CO2 Loading --- ---
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PROPERTIES
11 Overall Liquid Phase
12 CO2 App ML Con (kgmole/m3) --- ---
13 CO2 App WT Con (kgmol/kg) --- ---
14 Phase Fraction [Act. Vol. Basis] 0.0000 1.000
15 Mass Exergy (kJ/kg) -34.39 ---
16 Ideal Gas Cp/Cv 1.081 1.081
17 Ideal Gas Cp (kJ/kgmole-C) 111.5 111.5
18 Mass Ideal Gas Cp (kJ/kg-C) 1.606 1.606
19 Bubble Point Pressure (kg/cm2_g) 0.3089 ---
20
21
COMPOSITION
22
23
Overall Phase Vapour Fraction 0.0000

24 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
25 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
26 n-Pentane 16.1813 * 0.1021 * 1167.4975 * 0.1061 * 1.8540 * 0.1126 *
27 2M-1-butene 22.5749 * 0.1424 * 1583.2932 * 0.1439 * 2.4195 * 0.1470 *
28 3M-1-butene 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 2M-2-butene 37.8417 * 0.2387 * 2654.0268 * 0.2413 * 3.9844 * 0.2420 *
30 tr2-Pentene 5.4364 * 0.0343 * 381.2852 * 0.0347 * 0.5846 * 0.0355 *
31 cis2-Pentene 2.0350 * 0.0128 * 142.7229 * 0.0130 * 0.2164 * 0.0131 *
32 2M-13-C4== 73.5010 * 0.4637 * 5006.8179 * 0.4552 * 7.3109 * 0.4440 *
33 1-tr3-C5== 0.1251 * 0.0008 * 8.5227 * 0.0008 * 0.0125 * 0.0008 *
34 1-ci3-C5== 0.0186 * 0.0001 * 1.2693 * 0.0001 * 0.0018 * 0.0001 *
35 13-CC5== 0.2765 * 0.0017 * 18.2790 * 0.0017 * 0.0227 * 0.0014 *
36 i-Butene 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
37 1-Pentene 0.3160 * 0.0020 * 22.1655 * 0.0020 * 0.0347 * 0.0021 *
38 i-Pentane 0.1967 * 0.0012 * 14.1939 * 0.0013 * 0.0228 * 0.0014 *
39 DMF 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
40 n-Hexane 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
41 Total 158.5034 1.0000 11000.0739 1.0000 16.4642 1.0000
42
43
Liquid Phase Phase Fraction 1.000

44 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
45 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
46 n-Pentane 16.1813 0.1021 1167.4975 0.1061 1.8540 0.1126
47 2M-1-butene 22.5749 0.1424 1583.2932 0.1439 2.4195 0.1470
48 3M-1-butene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
49 2M-2-butene 37.8417 0.2387 2654.0268 0.2413 3.9844 0.2420
50 tr2-Pentene 5.4364 0.0343 381.2852 0.0347 0.5846 0.0355
51 cis2-Pentene 2.0350 0.0128 142.7229 0.0130 0.2164 0.0131
52 2M-13-C4== 73.5010 0.4637 5006.8179 0.4552 7.3109 0.4440
53 1-tr3-C5== 0.1251 0.0008 8.5227 0.0008 0.0125 0.0008
54 1-ci3-C5== 0.0186 0.0001 1.2693 0.0001 0.0018 0.0001
55 13-CC5== 0.2765 0.0017 18.2790 0.0017 0.0227 0.0014
56 i-Butene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
57 1-Pentene 0.3160 0.0020 22.1655 0.0020 0.0347 0.0021
58 i-Pentane 0.1967 0.0012 14.1939 0.0013 0.0228 0.0014
59 DMF 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
60 n-Hexane 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
61 Total 158.5034 1.0000 11000.0739 1.0000 16.4642 1.0000
62
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K VALUE
11 COMPONENTS MIXED LIGHT HEAVY
12 n-Pentane 0.0000 0.0000 ---
13 2M-1-butene 0.0000 0.0000 ---
14 3M-1-butene 0.0000 0.0000 ---
15 2M-2-butene 0.0000 0.0000 ---
16 tr2-Pentene 0.0000 0.0000 ---
17 cis2-Pentene 0.0000 0.0000 ---
18 2M-13-C4== 0.0000 0.0000 ---
19 1-tr3-C5== 0.0000 0.0000 ---
20 1-ci3-C5== 0.0000 0.0000 ---
21 13-CC5== 0.0000 0.0000 ---
22 i-Butene 0.0000 0.0000 ---
23 1-Pentene 0.0000 0.0000 ---
24 i-Pentane 0.0000 0.0000 ---
25 DMF 0.0000 0.0000 ---
26 n-Hexane 0.0000 0.0000 ---
27
28
UNIT OPERATIONS
29 FEED TO PRODUCT FROM LOGICAL CONNECTION
30 Distillation: K20+20a Recycle: RCY-1
31
32
UTILITIES
33 ( No utilities reference this stream )
34
35
PROCESS UTILITY
36
37
Fluid Package: Basis-1
38 Material Stream: RECYCLE E-59 Property Package: Peng-Robinson
39
40
41
CONDITIONS
42 Overall Vapour Phase Liquid Phase
43 Vapour / Phase Fraction 0.8233 0.8233 0.1767
44 Temperature: (C) 48.41 * 48.41 48.41
45 Pressure: (kg/cm2_g) 0.2990 * 0.2990 0.2990
46 Molar Flow (kgmole/h) 485.9 400.0 85.89
47 Mass Flow (tonne/h) 34.70 * 28.42 6.283
48 Std Ideal Liq Vol Flow (m3/h) 52.08 42.65 9.433
49 Molar Enthalpy (kJ/kgmole) -2.862e+004 -2.025e+004 -6.760e+004
50 Molar Entropy (kJ/kgmole-C) 179.6 193.8 113.1
51 Heat Flow (kJ/h) -1.391e+007 -8.103e+006 -5.806e+006
52 Liq Vol Flow @Std Cond (m3/h) 51.93 * 42.53 9.398
53
54
PROPERTIES
55 Overall Vapour Phase Liquid Phase
56 Molecular Weight 71.42 71.04 73.16
57 Molar Density (kgmole/m3) 6.207e-002 5.117e-002 8.664
58 Mass Density (kg/m3) 4.433 3.635 633.9
59 Act. Volume Flow (m3/h) 7828 7818 9.913
60 Mass Enthalpy (kJ/kg) -400.8 -285.1 -924.0
61 Mass Entropy (kJ/kg-C) 2.514 2.728 1.546
62 Heat Capacity (kJ/kgmole-C) 124.7 116.3 163.8
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Fluid Package: Basis-1
7 Material Stream: RECYCLE E-59 (continued) Property Package: Peng-Robinson
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PROPERTIES
11 Overall Vapour Phase Liquid Phase
12 Mass Heat Capacity (kJ/kg-C) 1.746 1.637 2.238
13 LHV Molar Basis (Std) (kJ/kgmole) --- --- ---
14 LHV Mass Basis (Std) (kJ/kg) --- --- ---
15 Phase Fraction [Vol. Basis] 0.8189 0.8189 0.1811
16 Phase Fraction [Mass Basis] 0.8189 0.8189 0.1811
17 Partial Pressure of CO2 (kg/cm2_g) -1.033 --- ---
18 Cost Based on Flow (Cost/s) 0.0000 0.0000 0.0000
19 Act. Gas Flow (ACT_m3/h) 7818 7818 ---
20 Avg. Liq. Density (kgmole/m3) 9.330 9.379 9.105
21 Specific Heat (kJ/kgmole-C) 124.7 116.3 163.8
22 Std. Gas Flow (STD_m3/h) 1.149e+004 9459 2031
23 Std. Ideal Liq. Mass Density (kg/m3) 666.3 666.3 666.1
24 Act. Liq. Flow (m3/s) 2.753e-003 --- 2.753e-003
25 Z Factor --- 0.9550 5.640e-003
26 Watson K 12.37 12.36 12.43
27 User Property --- --- ---
28 Partial Pressure of H2S (kg/cm2_g) -1.033 --- ---
29 Cp/(Cp - R) 1.071 1.077 1.053
30 Cp/Cv 1.069 1.091 1.372
31 Heat of Vap. (kJ/kgmole) 2.624e+004 --- ---
32 Kinematic Viscosity (cSt) --- 1.948 0.2798
33 Liq. Mass Density (Std. Cond) (kg/m3) 668.3 668.2 668.6
34 Liq. Vol. Flow (Std. Cond) (m3/h) 51.93 42.53 9.398
35 Liquid Fraction 0.1767 0.0000 1.000
36 Molar Volume (m3/kgmole) 16.11 19.54 0.1154
37 Mass Heat of Vap. (kJ/kg) 367.4 --- ---
38 Phase Fraction [Molar Basis] 0.8233 0.8233 0.1767
39 Surface Tension (dyne/cm) 14.01 --- 14.01
40 Thermal Conductivity (W/m-K) --- 1.464e-002 0.1027
41 Viscosity (cP) --- 7.082e-003 0.1773
42 Cv (Semi-Ideal) (kJ/kgmole-C) 116.4 108.0 155.4
43 Mass Cv (Semi-Ideal) (kJ/kg-C) 1.630 1.520 2.125
44 Cv (kJ/kgmole-C) 116.7 106.6 119.4
45 Mass Cv (kJ/kg-C) 1.634 1.501 1.631
46 Cv (Ent. Method) (kJ/kgmole-C) --- --- ---
47 Mass Cv (Ent. Method) (kJ/kg-C) --- --- ---
48 Cp/Cv (Ent. Method) --- --- ---
49 Reid VP at 37.8 C (kg/cm2_g) 2.320e-003 2.257e-002 -9.152e-002
50 True VP at 37.8 C (kg/cm2_g) 3.684e-003 2.377e-002 -8.956e-002
51 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 51.93 42.53 9.398
52 Viscosity Index -28.94 --- ---
53 HHV Molar Basis (Std) (kJ/kgmole) --- --- ---
54 HHV Mass Basis (Std) (kJ/kg) --- --- ---
55 CO2 Loading --- --- ---
56 CO2 App ML Con (kgmole/m3) --- --- ---
57 CO2 App WT Con (kgmol/kg) --- --- ---
58 Phase Fraction [Act. Vol. Basis] 0.9987 0.9987 1.266e-003
59 Mass Exergy (kJ/kg) 21.91 --- ---
60 Ideal Gas Cp/Cv 1.077 1.078 1.075
61 Ideal Gas Cp (kJ/kgmole-C) 115.6 114.8 119.6
62 Mass Ideal Gas Cp (kJ/kg-C) 1.619 1.615 1.635
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7 Material Stream: RECYCLE E-59 (continued) Property Package: Peng-Robinson
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PROPERTIES
11 Overall Vapour Phase Liquid Phase
12 Bubble Point Pressure (kg/cm2_g) 0.4260 --- ---
13
14
COMPOSITION
15
16
Overall Phase Vapour Fraction 0.8233

17 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
18 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
19 n-Pentane 23.4646 * 0.0483 * 1692.9977 * 0.0488 * 2.6885 * 0.0516 *
20 2M-1-butene 58.5527 * 0.1205 * 4106.5903 * 0.1183 * 6.2755 * 0.1205 *
21 3M-1-butene 5.0530 * 0.0104 * 354.3902 * 0.0102 * 0.5614 * 0.0108 *
22 2M-2-butene 181.6195 * 0.3738 * 12737.8868 * 0.3671 * 19.1228 * 0.3672 *
23 tr2-Pentene 11.6114 * 0.0239 * 814.3631 * 0.0235 * 1.2485 * 0.0240 *
24 cis2-Pentene 5.2703 * 0.0108 * 369.6354 * 0.0107 * 0.5604 * 0.0108 *
25 2M-13-C4== 121.8372 * 0.2507 * 8299.4309 * 0.2392 * 12.1187 * 0.2327 *
26 1-tr3-C5== 11.8859 * 0.0245 * 809.6526 * 0.0233 * 1.1908 * 0.0229 *
27 1-ci3-C5== 6.5144 * 0.0134 * 443.7542 * 0.0128 * 0.6385 * 0.0123 *
28 13-CC5== 0.7605 * 0.0016 * 50.2695 * 0.0014 * 0.0625 * 0.0012 *
29 i-Butene 0.0671 * 0.0001 * 3.7620 * 0.0001 * 0.0063 * 0.0001 *
30 1-Pentene 1.5482 * 0.0032 * 108.5801 * 0.0031 * 0.1700 * 0.0033 *
31 i-Pentane 4.5596 * 0.0094 * 328.9795 * 0.0095 * 0.5277 * 0.0101 *
32 DMF 0.0653 * 0.0001 * 4.7751 * 0.0001 * 0.0050 * 0.0001 *
33 n-Hexane 53.1094 * 0.1093 * 4576.8586 * 0.1319 * 6.9068 * 0.1326 *
34 Total 485.9190 1.0000 34701.9260 1.0000 52.0835 1.0000
35
36
Vapour Phase Phase Fraction 0.8233

37 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
38 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
39 n-Pentane 19.7650 0.0494 1426.0626 0.0502 2.2646 0.0531
40 2M-1-butene 50.4752 0.1262 3540.0760 0.1246 5.4098 0.1268
41 3M-1-butene 4.5456 0.0114 318.8063 0.0112 0.5050 0.0118
42 2M-2-butene 151.2119 0.3780 10605.2502 0.3732 15.9212 0.3733
43 tr2-Pentene 9.7791 0.0244 685.8537 0.0241 1.0515 0.0247
44 cis2-Pentene 4.4251 0.0111 310.3554 0.0109 0.4705 0.0110
45 2M-13-C4== 103.9563 0.2599 7081.4001 0.2492 10.3401 0.2424
46 1-tr3-C5== 9.7756 0.0244 665.9013 0.0234 0.9794 0.0230
47 1-ci3-C5== 5.2919 0.0132 360.4814 0.0127 0.5187 0.0122
48 13-CC5== 0.6419 0.0016 42.4290 0.0015 0.0527 0.0012
49 i-Butene 0.0637 0.0002 3.5746 0.0001 0.0060 0.0001
50 1-Pentene 1.3401 0.0034 93.9911 0.0033 0.1472 0.0035
51 i-Pentane 3.9797 0.0099 287.1366 0.0101 0.4606 0.0108
52 DMF 0.0073 0.0000 0.5325 0.0000 0.0006 0.0000
53 n-Hexane 34.7753 0.0869 2996.8625 0.1055 4.5224 0.1060
54 Total 400.0336 1.0000 28418.7134 1.0000 42.6504 1.0000
55
56
Liquid Phase Phase Fraction 0.1767

57 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
58 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
59 n-Pentane 3.6997 0.0431 266.9351 0.0425 0.4239 0.0449
60 2M-1-butene 8.0775 0.0940 566.5142 0.0902 0.8657 0.0918
61 3M-1-butene 0.5074 0.0059 35.5839 0.0057 0.0564 0.0060
62 2M-2-butene 30.4076 0.3540 2132.6366 0.3394 3.2016 0.3394
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7 Material Stream: RECYCLE E-59 (continued) Property Package: Peng-Robinson
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COMPOSITION
11
12
Liquid Phase (continued) Phase Fraction 0.1767

13 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
14 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
15 tr2-Pentene 1.8323 0.0213 128.5094 0.0205 0.1970 0.0209
16 cis2-Pentene 0.8452 0.0098 59.2801 0.0094 0.0899 0.0095
17 2M-13-C4== 17.8809 0.2082 1218.0308 0.1939 1.7785 0.1885
18 1-tr3-C5== 2.1103 0.0246 143.7513 0.0229 0.2114 0.0224
19 1-ci3-C5== 1.2225 0.0142 83.2728 0.0133 0.1198 0.0127
20 13-CC5== 0.1186 0.0014 7.8405 0.0012 0.0097 0.0010
21 i-Butene 0.0033 0.0000 0.1874 0.0000 0.0003 0.0000
22 1-Pentene 0.2080 0.0024 14.5890 0.0023 0.0228 0.0024
23 i-Pentane 0.5799 0.0068 41.8429 0.0067 0.0671 0.0071
24 DMF 0.0580 0.0007 4.2425 0.0007 0.0044 0.0005
25 n-Hexane 18.3341 0.2135 1579.9961 0.2515 2.3843 0.2528
26 Total 85.8854 1.0000 6283.2126 1.0000 9.4331 1.0000
27
28
K VALUE
29 COMPONENTS MIXED LIGHT HEAVY
30 n-Pentane 1.147 1.147 ---
31 2M-1-butene 1.342 1.342 ---
32 3M-1-butene 1.924 1.924 ---
33 2M-2-butene 1.068 1.068 ---
34 tr2-Pentene 1.146 1.146 ---
35 cis2-Pentene 1.124 1.124 ---
36 2M-13-C4== 1.248 1.248 ---
37 1-tr3-C5== 0.9945 0.9945 ---
38 1-ci3-C5== 0.9294 0.9294 ---
39 13-CC5== 1.162 1.162 ---
40 i-Butene 4.096 4.096 ---
41 1-Pentene 1.383 1.383 ---
42 i-Pentane 1.473 1.473 ---
43 DMF 2.695e-002 2.695e-002 ---
44 n-Hexane 0.4072 0.4072 ---
45
46
UNIT OPERATIONS
47 FEED TO PRODUCT FROM LOGICAL CONNECTION
48 Distillation: K20+20a Recycle: RCY-3
49
50
UTILITIES
51 ( No utilities reference this stream )
52
53
PROCESS UTILITY
54
55
Fluid Package: Basis-2
56 Material Stream: TO E-190 Property Package: NRTL - Ideal
57
58
59
CONDITIONS
60 Overall Liquid Phase
61 Vapour / Phase Fraction 0.0000 1.0000
62 Temperature: (C) 41.89 41.89
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Fluid Package: Basis-2
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9
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CONDITIONS
11 Overall Liquid Phase
12 Pressure: (kg/cm2_g) 0.5500 0.5500
13 Molar Flow (kgmole/h) 158.5 158.5
14 Mass Flow (tonne/h) 11.00 11.00
15 Std Ideal Liq Vol Flow (m3/h) 16.46 16.46
16 Molar Enthalpy (kJ/kgmole) -2.027e+004 -2.027e+004
17 Molar Entropy (kJ/kgmole-C) 145.6 145.6
18 Heat Flow (kJ/h) -3.212e+006 -3.212e+006
19 Liq Vol Flow @Std Cond (m3/h) 16.44 * 16.44
20
21
PROPERTIES
22 Overall Liquid Phase
23 Molecular Weight 69.40 69.40
24 Molar Density (kgmole/m3) 9.236 9.236
25 Mass Density (kg/m3) 641.0 641.0
26 Act. Volume Flow (m3/h) 17.16 17.16
27 Mass Enthalpy (kJ/kg) -292.0 -292.0
28 Mass Entropy (kJ/kg-C) 2.098 2.098
29 Heat Capacity (kJ/kgmole-C) 157.8 157.8
30 Mass Heat Capacity (kJ/kg-C) 2.274 2.274
31 LHV Molar Basis (Std) (kJ/kgmole) --- ---
32 LHV Mass Basis (Std) (kJ/kg) --- ---
33 Phase Fraction [Vol. Basis] 0.0000 1.000
34 Phase Fraction [Mass Basis] 0.0000 1.000
35 Partial Pressure of CO2 (kg/cm2_g) -1.033 ---
36 Cost Based on Flow (Cost/s) 0.0000 0.0000
37 Act. Gas Flow (ACT_m3/h) --- ---
38 Avg. Liq. Density (kgmole/m3) 9.627 9.627
39 Specific Heat (kJ/kgmole-C) 157.8 157.8
40 Std. Gas Flow (STD_m3/h) 3748 3748
41 Std. Ideal Liq. Mass Density (kg/m3) 668.1 668.1
42 Act. Liq. Flow (m3/s) 4.767e-003 4.767e-003
43 Z Factor 6.418e-003 6.418e-003
44 Watson K 12.27 12.27
45 User Property --- ---
46 Partial Pressure of H2S (kg/cm2_g) -1.033 ---
47 Cp/(Cp - R) 1.056 1.056
48 Cp/Cv 1.357 1.357
49 Heat of Vap. (kJ/kgmole) 2.554e+004 ---
50 Kinematic Viscosity (cSt) 0.2657 0.2657
51 Liq. Mass Density (Std. Cond) (kg/m3) 669.2 669.2
52 Liq. Vol. Flow (Std. Cond) (m3/h) 16.44 16.44
53 Liquid Fraction 1.000 1.000
54 Molar Volume (m3/kgmole) 0.1083 0.1083
55 Mass Heat of Vap. (kJ/kg) 368.0 ---
56 Phase Fraction [Molar Basis] 0.0000 1.0000
57 Surface Tension (dyne/cm) 14.29 14.29
58 Thermal Conductivity (W/m-K) 0.1032 0.1032
59 Viscosity (cP) 0.1703 0.1703
60 Cv (Semi-Ideal) (kJ/kgmole-C) 149.5 149.5
61 Mass Cv (Semi-Ideal) (kJ/kg-C) 2.154 2.154
62 Cv (kJ/kgmole-C) 116.2 116.2
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PROPERTIES
11 Overall Liquid Phase
12 Mass Cv (kJ/kg-C) 1.675 1.675
13 Cv (Ent. Method) (kJ/kgmole-C) --- ---
14 Mass Cv (Ent. Method) (kJ/kg-C) --- ---
15 Cp/Cv (Ent. Method) --- ---
16 Reid VP at 37.8 C (kg/cm2_g) 0.1377 0.1377
17 True VP at 37.8 C (kg/cm2_g) 0.1384 0.1384
18 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 16.44 16.44
19 Viscosity Index -29.07 ---
20 HHV Molar Basis (Std) (kJ/kgmole) --- ---
21 HHV Mass Basis (Std) (kJ/kg) --- ---
22 CO2 Loading --- ---
23 CO2 App ML Con (kgmole/m3) --- ---
24 CO2 App WT Con (kgmol/kg) --- ---
25 Phase Fraction [Act. Vol. Basis] 0.0000 1.000
26 Mass Exergy (kJ/kg) -34.40 ---
27 Ideal Gas Cp/Cv 1.081 1.081
28 Ideal Gas Cp (kJ/kgmole-C) 111.5 111.5
29 Mass Ideal Gas Cp (kJ/kg-C) 1.606 1.606
30 Bubble Point Pressure (kg/cm2_g) 0.3093 ---
31
32
COMPOSITION
33
34
Overall Phase Vapour Fraction 0.0000

35 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
36 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
37 n-Pentane 16.1635 0.1020 1166.2112 0.1060 1.8519 0.1125
38 2M-1-butene 22.6221 0.1427 1586.6022 0.1442 2.4246 0.1473
39 3M-1-butene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 2M-2-butene 37.7583 0.2382 2648.1789 0.2407 3.9756 0.2415
41 tr2-Pentene 5.4313 0.0343 380.9233 0.0346 0.5840 0.0355
42 cis2-Pentene 2.0320 0.0128 142.5177 0.0130 0.2161 0.0131
43 2M-13-C4== 73.5627 0.4641 5011.0184 0.4555 7.3170 0.4444
44 1-tr3-C5== 0.1248 0.0008 8.5029 0.0008 0.0125 0.0008
45 1-ci3-C5== 0.0186 0.0001 1.2667 0.0001 0.0018 0.0001
46 13-CC5== 0.2762 0.0017 18.2558 0.0017 0.0227 0.0014
47 i-Butene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
48 1-Pentene 0.3169 0.0020 22.2245 0.0020 0.0348 0.0021
49 i-Pentane 0.1974 0.0012 14.2453 0.0013 0.0228 0.0014
50 DMF 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
51 n-Hexane 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
52 Total 158.5039 1.0000 10999.9470 1.0000 16.4639 1.0000
53
54
Liquid Phase Phase Fraction 1.000

55 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
56 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
57 n-Pentane 16.1635 0.1020 1166.2112 0.1060 1.8519 0.1125
58 2M-1-butene 22.6221 0.1427 1586.6022 0.1442 2.4246 0.1473
59 3M-1-butene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
60 2M-2-butene 37.7583 0.2382 2648.1789 0.2407 3.9756 0.2415
61 tr2-Pentene 5.4313 0.0343 380.9233 0.0346 0.5840 0.0355
62 cis2-Pentene 2.0320 0.0128 142.5177 0.0130 0.2161 0.0131
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COMPOSITION
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Liquid Phase (continued) Phase Fraction 1.000

13 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
14 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
15 2M-13-C4== 73.5627 0.4641 5011.0184 0.4555 7.3170 0.4444
16 1-tr3-C5== 0.1248 0.0008 8.5029 0.0008 0.0125 0.0008
17 1-ci3-C5== 0.0186 0.0001 1.2667 0.0001 0.0018 0.0001
18 13-CC5== 0.2762 0.0017 18.2558 0.0017 0.0227 0.0014
19 i-Butene 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
20 1-Pentene 0.3169 0.0020 22.2245 0.0020 0.0348 0.0021
21 i-Pentane 0.1974 0.0012 14.2453 0.0013 0.0228 0.0014
22 DMF 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
23 n-Hexane 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
24 Total 158.5039 1.0000 10999.9470 1.0000 16.4639 1.0000
25
26
K VALUE
27 COMPONENTS MIXED LIGHT HEAVY
28 n-Pentane 0.0000 0.0000 ---
29 2M-1-butene 0.0000 0.0000 ---
30 3M-1-butene 0.0000 0.0000 ---
31 2M-2-butene 0.0000 0.0000 ---
32 tr2-Pentene 0.0000 0.0000 ---
33 cis2-Pentene 0.0000 0.0000 ---
34 2M-13-C4== 0.0000 0.0000 ---
35 1-tr3-C5== 0.0000 0.0000 ---
36 1-ci3-C5== 0.0000 0.0000 ---
37 13-CC5== 0.0000 0.0000 ---
38 i-Butene 0.0000 0.0000 ---
39 1-Pentene 0.0000 0.0000 ---
40 i-Pentane 0.0000 0.0000 ---
41 DMF 0.0000 0.0000 ---
42 n-Hexane 0.0000 0.0000 ---
43
44
UNIT OPERATIONS
45 FEED TO PRODUCT FROM LOGICAL CONNECTION
46 Recycle: RCY-1 Distillation: K-187
47
48
UTILITIES
49 ( No utilities reference this stream )
50
51
PROCESS UTILITY
52
53
Fluid Package: Basis-1
54 Material Stream: TO E-59 Property Package: Peng-Robinson
55
56
57
CONDITIONS
58 Overall Vapour Phase Liquid Phase
59 Vapour / Phase Fraction 0.8259 0.8259 0.1741
60 Temperature: (C) 48.46 48.46 48.46
61 Pressure: (kg/cm2_g) 0.2990 0.2990 0.2990
62 Molar Flow (kgmole/h) 485.7 401.2 84.56
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Fluid Package: Basis-1
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CONDITIONS
11 Overall Vapour Phase Liquid Phase
12 Mass Flow (tonne/h) 34.69 28.51 6.189
13 Std Ideal Liq Vol Flow (m3/h) 52.07 42.78 9.291
14 Molar Enthalpy (kJ/kgmole) -2.862e+004 -2.035e+004 -6.784e+004
15 Molar Entropy (kJ/kgmole-C) 179.8 193.8 113.1
16 Heat Flow (kJ/h) -1.390e+007 -8.164e+006 -5.737e+006
17 Liq Vol Flow @Std Cond (m3/h) 51.92 * 42.66 9.257
18
19
PROPERTIES
20 Overall Vapour Phase Liquid Phase
21 Molecular Weight 71.43 71.05 73.19
22 Molar Density (kgmole/m3) 6.187e-002 5.116e-002 8.661
23 Mass Density (kg/m3) 4.419 3.635 633.8
24 Act. Volume Flow (m3/h) 7851 7842 9.764
25 Mass Enthalpy (kJ/kg) -400.6 -286.4 -926.9
26 Mass Entropy (kJ/kg-C) 2.517 2.728 1.546
27 Heat Capacity (kJ/kgmole-C) 124.6 116.4 163.8
28 Mass Heat Capacity (kJ/kg-C) 1.745 1.638 2.239
29 LHV Molar Basis (Std) (kJ/kgmole) --- --- ---
30 LHV Mass Basis (Std) (kJ/kg) --- --- ---
31 Phase Fraction [Vol. Basis] 0.8216 0.8216 0.1784
32 Phase Fraction [Mass Basis] 0.8216 0.8216 0.1784
33 Partial Pressure of CO2 (kg/cm2_g) -1.033 --- ---
34 Cost Based on Flow (Cost/s) 0.0000 0.0000 0.0000
35 Act. Gas Flow (ACT_m3/h) 7842 7842 ---
36 Avg. Liq. Density (kgmole/m3) 9.328 9.378 9.101
37 Specific Heat (kJ/kgmole-C) 124.6 116.4 163.8
38 Std. Gas Flow (STD_m3/h) 1.149e+004 9486 1999
39 Std. Ideal Liq. Mass Density (kg/m3) 666.3 666.3 666.1
40 Act. Liq. Flow (m3/s) 2.712e-003 --- 2.712e-003
41 Z Factor --- 0.9550 5.642e-003
42 Watson K 12.37 12.36 12.43
43 User Property --- --- ---
44 Partial Pressure of H2S (kg/cm2_g) -1.033 --- ---
45 Cp/(Cp - R) 1.071 1.077 1.053
46 Cp/Cv 1.069 1.091 1.372
47 Heat of Vap. (kJ/kgmole) 2.625e+004 --- ---
48 Kinematic Viscosity (cSt) --- 1.948 0.2799
49 Liq. Mass Density (Std. Cond) (kg/m3) 668.3 668.2 668.6
50 Liq. Vol. Flow (Std. Cond) (m3/h) 51.92 42.66 9.257
51 Liquid Fraction 0.1741 0.0000 1.000
52 Molar Volume (m3/kgmole) 16.16 19.55 0.1155
53 Mass Heat of Vap. (kJ/kg) 367.5 --- ---
54 Phase Fraction [Molar Basis] 0.8259 0.8259 0.1741
55 Surface Tension (dyne/cm) 14.01 --- 14.01
56 Thermal Conductivity (W/m-K) --- 1.465e-002 0.1027
57 Viscosity (cP) --- 7.083e-003 0.1774
58 Cv (Semi-Ideal) (kJ/kgmole-C) 116.3 108.0 155.5
59 Mass Cv (Semi-Ideal) (kJ/kg-C) 1.628 1.521 2.125
60 Cv (kJ/kgmole-C) 116.6 106.7 119.4
61 Mass Cv (kJ/kg-C) 1.633 1.501 1.632
62 Cv (Ent. Method) (kJ/kgmole-C) --- --- ---
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PROPERTIES
11 Overall Vapour Phase Liquid Phase
12 Mass Cv (Ent. Method) (kJ/kg-C) --- --- ---
13 Cp/Cv (Ent. Method) --- --- ---
14 Reid VP at 37.8 C (kg/cm2_g) 1.888e-003 2.196e-002 -9.282e-002
15 True VP at 37.8 C (kg/cm2_g) 3.257e-003 2.316e-002 -9.085e-002
16 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 51.92 42.66 9.257
17 Viscosity Index -28.94 --- ---
18 HHV Molar Basis (Std) (kJ/kgmole) --- --- ---
19 HHV Mass Basis (Std) (kJ/kg) --- --- ---
20 CO2 Loading --- --- ---
21 CO2 App ML Con (kgmole/m3) --- --- ---
22 CO2 App WT Con (kgmol/kg) --- --- ---
23 Phase Fraction [Act. Vol. Basis] 0.9988 0.9988 1.244e-003
24 Mass Exergy (kJ/kg) 22.00 --- ---
25 Ideal Gas Cp/Cv 1.077 1.078 1.075
26 Ideal Gas Cp (kJ/kgmole-C) 115.7 114.8 119.7
27 Mass Ideal Gas Cp (kJ/kg-C) 1.619 1.616 1.635
28 Bubble Point Pressure (kg/cm2_g) 0.4274 --- ---
29
30
COMPOSITION
31
32
Overall Phase Vapour Fraction 0.8259

33 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
34 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
35 n-Pentane 23.4200 0.0482 1689.7774 0.0487 2.6833 0.0515
36 2M-1-butene 58.5650 0.1206 4107.4571 0.1184 6.2769 0.1205
37 3M-1-butene 5.0481 0.0104 354.0486 0.0102 0.5609 0.0108
38 2M-2-butene 181.2535 0.3731 12712.2160 0.3664 19.0843 0.3665
39 tr2-Pentene 11.5893 0.0239 812.8123 0.0234 1.2461 0.0239
40 cis2-Pentene 5.2584 0.0108 368.7989 0.0106 0.5591 0.0107
41 2M-13-C4== 121.7950 0.2507 8296.5513 0.2391 12.1145 0.2327
42 1-tr3-C5== 11.8963 0.0245 810.3617 0.0234 1.1919 0.0229
43 1-ci3-C5== 6.5158 0.0134 443.8468 0.0128 0.6387 0.0123
44 13-CC5== 0.7593 0.0016 50.1909 0.0014 0.0624 0.0012
45 i-Butene 0.0670 0.0001 3.7600 0.0001 0.0063 0.0001
46 1-Pentene 1.5485 0.0032 108.6043 0.0031 0.1700 0.0033
47 i-Pentane 4.5565 0.0094 328.7581 0.0095 0.5273 0.0101
48 DMF 0.0653 0.0001 4.7759 0.0001 0.0050 0.0001
49 n-Hexane 53.4026 0.1099 4602.1258 0.1326 6.9449 0.1334
50 Total 485.7406 1.0000 34694.0850 1.0000 52.0717 1.0000
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Vapour Phase Phase Fraction 0.8259

53 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
54 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
55 n-Pentane 19.7881 0.0493 1427.7278 0.0501 2.2672 0.0530
56 2M-1-butene 50.6214 0.1262 3550.3299 0.1245 5.4255 0.1268
57 3M-1-butene 4.5501 0.0113 319.1180 0.0112 0.5055 0.0118
58 2M-2-butene 151.4013 0.3774 10618.5278 0.3725 15.9411 0.3726
59 tr2-Pentene 9.7905 0.0244 686.6560 0.0241 1.0527 0.0246
60 cis2-Pentene 4.4289 0.0110 310.6226 0.0109 0.4709 0.0110
61 2M-13-C4== 104.2169 0.2598 7099.1537 0.2490 10.3661 0.2423
62 1-tr3-C5== 9.8181 0.0245 668.7962 0.0235 0.9837 0.0230
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Fluid Package: Basis-1
7 Material Stream: TO E-59 (continued) Property Package: Peng-Robinson
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COMPOSITION
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Vapour Phase (continued) Phase Fraction 0.8259

13 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
14 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
15 1-ci3-C5== 5.3125 0.0132 361.8804 0.0127 0.5207 0.0122
16 13-CC5== 0.6428 0.0016 42.4920 0.0015 0.0528 0.0012
17 i-Butene 0.0637 0.0002 3.5762 0.0001 0.0060 0.0001
18 1-Pentene 1.3439 0.0034 94.2579 0.0033 0.1476 0.0034
19 i-Pentane 3.9868 0.0099 287.6519 0.0101 0.4614 0.0108
20 DMF 0.0074 0.0000 0.5425 0.0000 0.0006 0.0000
21 n-Hexane 35.2061 0.0878 3033.9836 0.1064 4.5785 0.1070
22 Total 401.1784 1.0000 28505.3164 1.0000 42.7803 1.0000
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Liquid Phase Phase Fraction 0.1741

25 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
26 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
27 n-Pentane 3.6320 0.0430 262.0496 0.0423 0.4161 0.0448
28 2M-1-butene 7.9436 0.0939 557.1271 0.0900 0.8514 0.0916
29 3M-1-butene 0.4980 0.0059 34.9306 0.0056 0.0553 0.0060
30 2M-2-butene 29.8523 0.3530 2093.6883 0.3383 3.1432 0.3383
31 tr2-Pentene 1.7988 0.0213 126.1563 0.0204 0.1934 0.0208
32 cis2-Pentene 0.8295 0.0098 58.1763 0.0094 0.0882 0.0095
33 2M-13-C4== 17.5780 0.2079 1197.3976 0.1935 1.7484 0.1882
34 1-tr3-C5== 2.0782 0.0246 141.5655 0.0229 0.2082 0.0224
35 1-ci3-C5== 1.2033 0.0142 81.9664 0.0132 0.1179 0.0127
36 13-CC5== 0.1165 0.0014 7.6989 0.0012 0.0096 0.0010
37 i-Butene 0.0033 0.0000 0.1839 0.0000 0.0003 0.0000
38 1-Pentene 0.2046 0.0024 14.3464 0.0023 0.0225 0.0024
39 i-Pentane 0.5697 0.0067 41.1061 0.0066 0.0659 0.0071
40 DMF 0.0579 0.0007 4.2335 0.0007 0.0044 0.0005
41 n-Hexane 18.1966 0.2152 1568.1422 0.2534 2.3664 0.2547
42 Total 84.5622 1.0000 6188.7686 1.0000 9.2913 1.0000
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K VALUE
45 COMPONENTS MIXED LIGHT HEAVY
46 n-Pentane 1.148 1.148 ---
47 2M-1-butene 1.343 1.343 ---
48 3M-1-butene 1.926 1.926 ---
49 2M-2-butene 1.069 1.069 ---
50 tr2-Pentene 1.147 1.147 ---
51 cis2-Pentene 1.125 1.125 ---
52 2M-13-C4== 1.250 1.250 ---
53 1-tr3-C5== 0.9958 0.9958 ---
54 1-ci3-C5== 0.9306 0.9306 ---
55 13-CC5== 1.163 1.163 ---
56 i-Butene 4.100 4.100 ---
57 1-Pentene 1.385 1.385 ---
58 i-Pentane 1.475 1.475 ---
59 DMF 2.701e-002 2.701e-002 ---
60 n-Hexane 0.4078 0.4078 ---
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UNIT OPERATIONS
11 FEED TO PRODUCT FROM LOGICAL CONNECTION
12 Recycle: RCY-3 Distillation: K-35
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UTILITIES
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