Professional Documents
Culture Documents
1001
SX2006
DEMULSIFIER 1000684145 BULK DELIVERY
LIQUID/VAPOR/ The product is a proprietary blend of 10-30% solvent naphtha (TLV=5 mg/m3), 1-5%
MISTS: 1,2,4-trimethylbenezene (TLV= 25 ppm), 0-1% mesitylene (TLV= 25 ppm), 10-30%
alkoxylated phenol, 10-30% fuels, diesel, and gasoline (TLV=300 ppm and TLV-
STEL=500 ppm), 10-30% alkylene oxide polymer, and 10-30% isobutanol (TLV= 50
ppm).
EFFECTS OF OVER-EXPOSURE:
health
INHALATION: Inhalation may cause irritation of the respiratory system and mucous membranes,
drowsiness, dizziness, and disorientation, and damage the central nervous system
(CNS), liver, and kidneys. May result in cancer.
hazards
EYE/ SKIN: Eye contact may cause redness, irritation, and serious damage. Skin contact may
cause irritation, sensitization, and dermatitis.
INGESTION: Gastrointestinal distress, nausea, vomiting, diarrhea, abdominal pain, and bleeding.
May cause central nervous system depression and liver and/or kidney damage.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product flashpoint is 43°C (109°F); no explosive limits were reported. Fire fighters must wear SCBA and
protective clothing. Fires produce carbon and nitrogen oxides, and also toxic gases, vapors, fumes, and
smoke. Closed containers may rupture in fire conditions. Cool containers exposed to flames with water fire and
reactivity
spray until well after the fire is out.
REACTIVITY: Normally stable. Avoid contact with heat, sparks, flames and sources of ignition.
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY, ALCOHOL FOAM, OR CO2
USAGE: Demulsifier in oil operations. Avoid breathing vapor and mists and avoid eye and skin
contact. NO SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, use DOT-IMO Classes 3.1
hazardous warning labels (diamond): FLAMMABLE LIQUID, TOXIC, N.O.S.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves and an apron
(1000128583) must be worn when handling this material. APR (1000128213) or SCBA
(1000127427) should be worn if conditions warrant. Maintain an eyewash fountain and
emergency shower (1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-4538 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 7/6/2004
CHEMICAL HAZARD BULLETIN NO. 1008
Direct Charge 480 kg bag
ICR 147/210
CATALYST
Health 2 SOLID, 1/16 TO 1/10 INCH DIAMETER BROWN TO CAS: Mixture
Fire 0 OLIVE-GREEN EXTRUSION PARTICLES. ODORLESS UN: None
Reactivity 0 MODERATELY TOXIC DUST. NON-FLAMMABLE. GUIDE: None
DUST: Chevron Hydroprocessing catalyst consists of nickel oxide (TLV=0.2 mg/m 3), molybdenum
trioxide (TLV=10 mg/m 3) on an alumina (TLV=10 mg/m 3) and amorphous silica (TLV=10
mg/m 3) substrate.
EFFECTS OF OVER-EXPOSURE:
EYE/ SKIN: Dust is moderately irritant to the eye causing redness, tearing, pain, swelling and blurred,
impaired vision. Acute and chronic inhalation toxicity hazard causing irritation of the health
hazards
respiratory tract and may cause an allergic response, skin reaction or asthma-like
INHALATION/ symptoms, nasal discharge, sore throat, coughing, bronchitis, pulmonary edema and
INGESTION: difficult breathing. Amorphous silica causes impaired pulmonary function. Nickel and
certain compounds are considered a carcinogen by the NTP and IARC (Group 1).
Relevance to inhalation of this catalyst dust is not clear. Ingestion may cause nausea,
vomiting and diarrhea.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
fire and
Non-flammable. No flashpoint or explosive range in air reported. In contact with a fire, toxic gases and fumes
may be formed. Firefighters must use self-contained breathing apparatus (SCBA) and protective clothing. Cool
fire-exposed containers with water spray.
REACTIVITY: No incompatible materials were listed.
EXTINGUISH FIRES WITH APPROPRIATE MEDIA FOR SURROUNDING FIRE reactivity
USAGE: Hydroprocessing catalyst. Use adequate ventilation. No smoking. Do not breathe dust or
aerosol. Wash thoroughly after handling.
STORAGE/ Store in a well ventilated, cool, dry area. Store in secure poison area. Keep containers
labeled, upright, and tightly closed when not in use. Avoid storage near incompatible
materials.
TRANSPORT:
SPILLS/ LEAKS:
For transportation, no DOT-IMO hazardous warning label (diamond) is required.
Evacuate all unnecessary personnel. Wear respiratory protection if warranted. Wear handling,
storage &
protective clothing for large spills. Reduce airborne dust and prevent scattering by
moistening with water. With clean shovel, place material into a clean, dry closed container,
and label for disposal.
DISPOSAL: For proper disposal methods and locations for chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428. disposal
SAFETY Provide ventilation. Wear chemical goggles, gloves and coveralls when handling
EQUIPMENT: quantities of this material. APR respiratory protection is required for toxic dust above TLV,
APR(21-374-401) with cartridges (95-200-235). SCBA may be required. Maintain
eyewash fountain/emergency shower where material is stored or used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If irritation persists, see a doctor. If breathing is difficult,
administer oxygen. If breathing has stopped, give cardio-pulmonary resuscitation (CPR).
Keep person warm and quiet.
EYE / SKIN Flush eyes with large amounts of water for at least 15 minutes. Lift eyelids occasionally.
CONTACT: Wash skin thoroughly with water. Remove contaminated clothing and shoes promptly, and
wash clothing before re-use. first aid
INGESTION: Induce vomiting may be indicated. Call for medical advice. If conscious and no trouble
breathing, have drink milk or two-four glasses of milk or water. Keep person warm and
quite.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:3/17/2001
CHEMICAL HAZARD BULLETIN NO. 1018
DIRECT CHARGE
SODIUM
MOLYBDATE
Health H2 CAS: 7631-95-0
WHITE GRANULAR POWDER. ODORLESS
Fire F0 MODERATELY TOXIC. NON-FLAMMABLE. NON-REACTIVE. UN: N/A
Reactivity R1 RESPIRATORY TRACT, EYE, AND SKIN IRRITANT. GUIDE: N/A
EAC: N/A
DUST: Inorganic salt of sodium molybdate (99.9%). TLV = 5 mg (as molybdenum)/m3 and TLV-
STEL = 10 mg (as molybdenum)/m3.
EFFECTS OF OVER-EXPOSURE:
health
INHALATION: Inhalation of dust may irritate the mucous membrane and upper respiratory tract. Acute
exposures may cause coughing and chest discomfort.
hazards
EYE/ SKIN: May irritate the eyes. May cause skin irritation and rash. Toxic amounts may be absorbed
through the skin.
INGESTION: Gastrointestinal distress, nausea, vomiting, diarrhea, abdominal pain, high blood
pressure, and coma
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product is not flammable. Fire fighters must wear SCBA and protective clothing. Fires produces
carbon and nitrogen oxides, and also toxic gases, vapors, fumes, and smoke. Closed containers may
rupture in fire conditions. Cool containers exposed to flames with water spray until well after the fire is out. fire and
REACTIVITY: Normally stable.
INCOMPATIBLE WITH: Excessive heat, flames, and sources of ignition. Strong oxidizers. reactivity
EXTINGUISHING MEDIA: USE MEDIA SUITABLE FOR TYPE OF SURROUNDING FIRES
USAGE: Used in Utilities operations. Avoid breathing dust and avoid eye and skin contact. NO
SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, the product is not regulated.
Packages do not require DOT-IMO hazardous warning labels (diamond).
storage &
SPILLS/ Evacuate unauthorized personnel. For large solution spills, dike to prevent entry into
LEAKS: sewer. For small spills, absorb in dry sand or earth. Shovel and place into clean, dry,
labeled containers. Flush with water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 873-6676
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene gloves (1000129418) and an apron (1000128583) must be
worn when handling this material. SCBA (1000127427) should be worn if conditions
warrant. Maintain an eyewash fountain and emergency shower (1000128433) where the
material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-4538 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 3/31/2004
CHEMICAL HAZARD BULLETIN NO. 1026
S/N 45-609-005 55-gal Drum
SA 193
Corrosion
Inhibitor
USES: Corrosion inhibitor. Avoid breathing vapor and eye and skin contact. NO SMOKING.
Provide local exhaust ventilation.
STORAGE/ Store in a well-ventilated, cool, dry area, away from ignition sources keep tightly closed
TRANSPORT: when not in use. Avoid storage near incompatible materials. For transportation, always
label containers with DOT/IMO Class 8, hazardous warning label (diamond);
SPILLS/LEAKS:
CORROSIVE LIQUID.
Stop the flow if it can be done safety. Dike to prevent entry into sewer. Absorb with sand
handling
and place in clean, dry, labeled containers.
storage
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact Environmental Engineering Division at 874-6426 or 874-6428. &
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles (S/N
EQUIPMENT: 21-432-249) or face shield and neoprene gloves (S/N 21-432-080) and rubber boots (S/N
21-408-744) and apron (S/N 21-404-199) must be worn when handling this material.
disposal
SCBA should be worn if conditions warrant. Maintain an eyewash fountain and
emergency shower where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
EYE/SKIN Flush eyes with large amounts of water for 15 minutes and lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
INGESTION:
and wash clothing before re-use.
DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
first aid
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
*Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised 1/23/2001
CHEMICAL HAZARD BULLETIN NO. 1041
DUST: The product is high molecular polyanionic cellulose. It is considered as nuisance dust
(TLV = 10 mg/m3). Chronic exposure to high dust concentrations may cause non-
debilitating lung changes.
EFFECTS OF OVER-EXPOSURE:
health
INHALATION: Non-irritating to mucous membranes. However, inhaling high concentrations of the dust
may cause mechanical irritation of the nose, throat, and upper respiratory tract.
hazards
EYE/ SKIN: May produce mechanical irritation to the eyes. Prolonged contact with moistened product
with skin contact may produce slight irritation.
INGESTION: May cause some gastrointestinal upset, nausea and vomiting.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product is not flammable. Fire fighters must wear SCBA and protective clothing. Fires produce carbon
and nitrogen oxides, and also toxic gases, vapors, fumes, and smoke. Closed containers may rupture in fire
conditions. Cool containers exposed to flames with water spray until well after the fire is out. fire and
REACTIVITY: Normally stable. Incompatible with: Heat, flames, and sources of ignition. Strong oxidizing
agents. reactivity
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY/FOG, FOAM, OR CO2
USAGE: Drilling operations. Avoid breathing dust and avoid eye and skin contact. NO SMOKING.
Provide adequate exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials. Keep tightly closed
TRANSPORT: when not in use. For transportation, packages do not require DOT-IMO hazardous
warning label (diamond).
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 873-6676..
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene gloves (1000129418) must be worn when handling this
material SCBA should be worn if conditions warrant. Maintain an eyewash fountain and
emergency shower where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-4538 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 4/3/2004
CHEMICAL HAZARD BULLETIN NO. 1048
S/N 26-003-340 55 gal. Drum
LUBRICATION/
TRANSMISSION
OILS
Health 1 AMBER LIQUID, HYDROCARBON ODOR CAS: Mxiture
Fire 1 SLIGHTLY TOXIC, FLAMMABLE & REACTIVE, UN: None
Reactivity 1 IRRITATING GUIDE: None
VAPOR/LIQUID: These products are blends of highly refined mineral oils and additives. The TLV for mineral
oil mist is TLV = 5 mg/m³.
EYE/ SKIN:
EFFECTS OF OVER-EXPOSURE:
Irritating to the eyes, causing itching, redness and tearing. Repeated or prolonged skin health
hazards
contact may cause irritation and skin discoloration.
INHALATION: Vapor may cause irritation to the respiratory tract or nervous system depression,
characterized by headache, nausea and dizziness.
INGESTION: Unlikely route of exposure. Low order of acute/systemic toxicity.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The flashpoint for this product is > 162°C. Explosion range: 0.6- 6.0 %. Firefighters must wear SCBA and
protective clothing. During combustion, oxides of carbon, aldehydes, ketones, nitrogen and sulfur may be
formed; also toxic organic vapors and smoke. Closed containers may rupture in fire conditions. Keep
containers cool with water spray. Vapors are heavier than air and can flow along surfaces to distant ignition fire and
reactivity
sources and flashback.
REACTIVITY: Avoid contact with strong oxidizing agents such as liquid chlorine and concentrated oxygen.
EXTINGUISHING MEDIA: DRY CHEMICAL, CO2, FOAM, WATER FOG
USAGE: This product is highly refined mineral oil for refrigeration compressors. Avoid breathing
vapor or mist. NO smoking. Provide adequate ventilation.
TRANSPORT/ Store in a well-ventilated, cool, dry area, away from ignition sources. Keep containers
STORAGE: tightly closed when not in use. DO NOT store in direct sunlight and avoid storage near
incompatible material. Always label containers for transporting in accordance with
SPILLS/ LEAKS:
DOT/IMO/IATA hazard warning labels.
Shut off sources of ignition. Stop the flow if it can be done safely. Dike to prevent entry handling,
storage &
into sewer. Absorb with sand and place in clean, dry container.
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY
EQUIPMENT:
Provide adequate ventilation to control vapor concentrations below the TLV. Safety
goggles must be worn when handling this material. SCBA should be worn if conditions
disposal
warrant. Maintain an eyewash fountain and emergency shower where the material is being
stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
INGESTION:
and wash clothing before re-use.
Do not induce vomiting. Aspiration of material into the lungs can cause chemical
first aid
pneumonitis, which can be fatal. Drink one-two glasses of water to dilute. Keep person
warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:1/15/2001
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:1/15/2001
CHEMICAL HAZARD BULLETIN NO. 1064
SUR-GARD1700 S/N 26-000-192 232 Kg Drum
VAPOR/ LIQUID Sur-Gard 1700 is a proprietary formulation including Diethylaminoethanol (Skin, TWA=2
ppm). No TLV for the material has been established.
EFFECTS OF OVEREXPOSURE:
EYE/SKIN May cause irritation to skin and eyes. Avoid contact with skin, eyes and clothing.
health
INHALATION Vapor may cause irritation to the respiratory tract. Avoid prolonged or repeated breathing
of vapor. hazards
INGESTION May cause gastric disturbances.
WEAR RECOMMENDED PERSONAL PROTECITVE EQUIPMENT
Flashpoint for this product is reported greater than 93.4oC (200oF). Firefighters must wear self-contained breathing
apparatus (SCBA) and protective clothing. During combustion, toxic oxides of carbon and nitrogen may be
formed, also organic vapors and smoke. Closed containers may rupture in fire conditions. Keep containers cool
with water spray.
fire and
REACTIVITY: Avoid contact with strong acids, strong oxidizers (chlorine, peroxides, chromates, nitric acid,
perchlorates, oxygen, and permanganates) which can generate heat, fires, explosions and release of toxic fumes.
reactivity
EXTINGUISH FIRES WITH DRY CHEMICAL, CO2 FOAM, WATER FOG
USAGE: This product is an oxygen scavenger. Use adequate ventilation. No smoking. Avoid
breathing vapors. Avoid skin contact.
STORAGE:
handling
Store in a cool dry area. Keep containers labeled, upright and tightly closed when not in
use. Avoid storage near incompatible materials.
SPILLS: Sweep up and place in a clean, dry container.
TRANSPORT:
For transportation, packages do not require DOT-IMO hazardous warning labels
(diamonds).
storage
DISPOSAL: For proper disposal methods and locations for chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
&
SAFETY
EQUIPMENT:
Provide ventilation to control dust concentrations. Safety goggles (21-434-249), neoprene
gloves (21-432-080), and coveralls should be worn when handling this material. SCBA disposal
should be worn if conditions warrant. Maintain eyewash fountain and emergency shower
where material is being used or stored.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardio-pulmonary resuscitation (CPR). Keep person warm and quiet.
EYE/SKIN Flush eyes with large amounts of water for at least 15 minutes. Lift eyelids occasionally.
Seek medical attention. Wash skin thoroughly with water. Remove contaminated clothing
CONTACT:
INGESTION:
and shoes promptly, and laundrer clothing before re-use.
Wash out mouth with water. Do not induce vomiting. Give victim water, if conscious.
first aid
Never give drink to unconscious person.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ), or 427-2217 (JID).
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised 1/27/2003
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ), or 427-2217 (JID).
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised 1/27/2003
CHEMICAL HAZARD BULLETIN NO. 1067
INSTRU-KLENZ 1000490228 5 GA CO
Cleaner
LIQUID/MISTS: The product is a concentrated liquid detergent that contains tetra sodium EDTA. The
product is proprietary and further data is reported. No exposure
EFFECTS OF OVER-EXPOSURE:
health
INHALATION: Inhalation of mists may irritate the respiratory tract. Symptoms include coughing and
sneezing.
hazards
EYE/ SKIN: Eye contact causes severe irritation, and possible blurred vision. Skin contact causes
irritation; symptoms may include reddening or inflammation on prolonged contact.
INGESTION: Can irritate the mouth, throat, and the gastrointestinal tract, and cause vomiting and
diarrhea.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product is not flammable or combustible. Fire fighters must wear SCBA and protective clothing. Fires
produce carbon and nitrogen oxides, and also toxic gases, vapors, fumes, and smoke. Closed containers
may rupture in fire conditions. Cool containers exposed to flames with water spray until well after the fire is fire and
reactivity
out.
REACTIVITY: Normally stable. Incompatible with strong oxidizers, e.g., nitric acid and soft metals, e.g.,
aluminum and acids. Heat and sources of ignition.
EXTINGUISHING MEDIA: SUITABLE FOR SURROUNDING FIRE
USAGE: Ultrasonic cleaners, washing surgical instruments. Avoid breathing mists and avoid eye
and skin contact. NO SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, the product is not regulated and
does not require hazardous warning labels.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene gloves (1000129418) and an apron (1000128583) must be
worn when handling this material. APR”O” (1000128165/7) or SCBA (1000127427)
should be worn if conditions warrant. Maintain an eyewash fountain and emergency
shower (1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 10/16/2004
CHEMICAL HAZARD BULLETIN NO. 1073
VAPOR/MIST Material becoming airborne is unlikely, however, PEL for sodium hydroxide mist is 2
3
LIQUID: mg/m .
EFFECTS OF OVER-EXPOSURE
EYE/SKIN: Irritation results from contact with concentrated liquid. Prolong contact may result in sever health
INHALATION/
dermal irritation.
Non-Flammable, however, if engulfed in flame, thermal decomposition may yield elemental oxides. Firefighters
should wear personal protective equipment that would be consistent with other reactive and flammable chemicals
that are present in the environment. Fire fighters should wear Scott Air Pack (S/N 21-311-231) fire and
Reactivity: Avoid contact with strong oxidizers. reactivity
EXTINGUISH FIRE WITH FOAM, CO2, OR DRY CHEMICAL
USAGE: Anti-scaling agent used in water distillation units and boiler feed water. Avoid skin
contact.
STORAGE: Alkaline. Do not store around acidic materials. Keep containers closed when not in use.
Store in well ventilated area. handling
TRANSPORTATION: Label drums and containers the appropriate hazard warning labels. storage
SPILLS / LEAKS: Dike a spill with sand and absorb onto suitable media. Contact Environmental
Engineering Division at 874-6426 or 874-6428 for disposal instructions. &
SAFETY
EQUIPMENT:
Wear protective gloves neoprene gloves (S/N 21-432-080) use goggles (S/N 21-434-249)
if splashing is likely. Maintain an eyewash fountain and emergency shower (S/N 21-372-
disposal
365) where material is used or stored.
EYE/SKIN EYES, Lift eye lids and flush with copious amounts of water for a minimum of 15 minutes
CONTACT: SKIN, Remove contaminated clothing and flush with large amounts of water.
INGESTED This chemical will cause gastro-intestinal distress. Do not feed anything by mouth to an
unconscious or convulsive victim. Do not induce vomiting. If fully conscious, dilute first aid
contents of stomach using 3-4 glasses of water.
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
*Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised: 10/27/2002
CHEMICAL HAZARD BULLETIN NO. 1111
SKC-S
MAGNAFLUX S/N 08-340-468 400 ML Aerosol Can
CLEANER
Health 1 CLEAR COLORLESS LIQUID WITH NAPHTHA ODOR CAS: Mixture
Fire 4 SLIGHTLY TOXIC, EXTERMELY FLAMMABLE AND UN: 1950
Reactivity 1 SLIGHTLY REACTIVE. GUIDE: 126
LIQUID / VAPOR: This product is a proprietary formulation of light solvent naphtha (TLV=300 ppm),
Isobutane propellant (TLV=800 ppm), and carbon dioxide propellant (TLV=5000 ppm).
EYE/SKIN:
EFFECTS OF OVEREXPOSURE
Causes irritation to the eyes. Frequent or prolonged skin contact may cause redness,
health
INHALATION:
pain, defatting, drying and cracking of the skin leading to dermatitis.
Causes irritation to the respiratory tract. May cause coughing, headache, dizziness and
hazards
nausea.
INGESTION: Harmful. If swallowed causes gastro-intestinal distress, nausea, vomiting, and diarrhea.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The flashpoint for this product is 10°C (50OF), with an explosive range in air of 1% (LEL) to 6 % (UEL). Avoid static
electrical charges. Firefighters must use self-contained breathing apparatus (SCBA) and protective clothing.
During combustion, oxides of carbon, smoke and soot may be formed. Closed containers may rupture in fire fire and
conditions. Keep containers cool with water spray. Vapors are heavier than air and can flow along surfaces to
distant ignition sources and flashback.
REACTIVITY: Avoid contact with oxidizers, heat, flames, sparks and other sources of ignition.
reactivity
EXTINGUISH FIRES WITH DRY CHEMICAL, CO2, FOAM, OR WATER FOG.
USES: Spot check cleaner and remover. Use adequate ventilation. Do not spray around arcs or
flame. Avoid contact with skin and eyes. No smoking. Do not breathe vapors or aerosols.
For proper use follow directions.
STORAGE: Store in a well-ventilated, cool, dry area, away from ignition sources. Keep containers
labeled, upright, and tightly closed when not in use. Do not store in direct sunlight. handling
Aerosol cans may burst if heated above 54°C (130OF) and spray contents into a fire.
TRANSPORT: Avoid storage near incompatible material. For transportation, label packages with UN-
DOT-IMO Class 2.1 hazardous warning label (diamond): FLAMMABLE GAS.
storage
SPILLS/LEAKS: Evacuate all unnecessary personnel. Shut off sources of ignition. Stop the flow if it can be
done safely. Avoid contact with spilled material. Dike to prevent entry into sewer. Absorb
&
DISPOSAL:
with sand, place in a clean, dry, closed container and label. Use completely or empty
aerosol cans before disposal. For proper disposal methods and locations for chemical or disposal
chemical contaminated material, contact the Environmental Engineering Division at 874-
6426 or 874-6428.
SAFETY Provide ventilation to control vapor concentrations below the TLVs. Safety glasses and
EQUIPMENT: gloves should be used to reduce incidental contact. Safety goggles (S/N 21-434-249),
vinyl apron (S/N 21-404-199) and nitrile gloves (21-432-570) must be worn with spills or
when extended contact or with quantities of this material is possible. APR or SCBA should
be worn if conditions warrant. Maintain an eyewash fountain and emergency shower
where the material is being stored/used.
USE CONFINED SPACE PROCEDURES IF CONDITIONS APPLY
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardio-pulmonary resuscitation (CPR). Keep person warm and quiet.
EYE/SKIN Flush eyes with large amounts of water for at least 15 minutes. Lift eyelids occasionally.
CONTACT: Wash skin thoroughly with soap and water. Remove contaminated clothing or shoes and
wash clothing before re-use.
first aid
INGESTION: Do not induce vomiting. Aspiration of material into the lungs due to vomiting can cause
chemical pneumonitis, which can be fatal. If conscious, drink one-two glasses of water to
dilute. Keep person warm and quiet. Get medical attention.
GET MEDICAL AID IMMEDIATELY (CALL 110
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
*Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised: 10/27/2002
CHEMICAL HAZARD BULLETIN NO. 1118
INTERNATIONAL 1000647354 20 LT CN
GTA220
TRANSPORT:
storage near incompatible material.
For transportation, always label containers with DOT/IMO Class 3, hazardous warning
handling
SPILLS/LEAKS:
label (diamond); FLAMMABLE LIQUID.
Evacuate all unnecessary personnel. Shut off sources of ignition. Stop the flow if it can
storage
DISPOSAL:
be done safely. Dike to prevent entry into sewer. Absorb with sand, place in a clean, dry,
closed container, and label.
For proper disposal methods and locations for the chemical or chemical contaminated
&
SAFETY
material, contact the Environmental Engineering Division at 874-6426.
Provide ventilation to control exposures below the TLVs. Chemical goggles
disposal
EQUIPMENT: (1000129810), neoprene gloves (1000129418) and apron (1000128583) must always be
worn when handling this material. APR or SCBA should be worn if conditions warrant.
Maintain an eyewash fountain and emergency shower where the material is being
stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
EYE/SKIN Flush eyes with large amounts of water for at least 15 minutes. Lift eyelids occasionally.
CONTACT: Wash skin thoroughly with soap and water. Remove contaminated clothing and shoes
promptly, and wash clothing before re-use.
first aid
INHALATION: Remove those exposed to fresh air. If breathing is difficult administer oxygen. If breathing
has stopped, apply cardio-pulmonary resuscitation (CPR).
INGESTION: Give nothing by mouth. Do not induce vomiting. Keep warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Environmental Protection: 872-2623 (DH), 678-4902 (RT), 572-4538(ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:5/17/2003
CHEMICAL HAZARD BULLETIN NO.
1121A
health
INHALATION: Inhalation of mists and vapor may cause irritation to the respiratory tract; symptoms may
include coughing, sore throat, and shortness of breath.
hazards
EYE/ SKIN: Eye contact causes irritation, redness, pain, and possible corneal ulceration. Skin
contact causes irritation and rash. Symptoms include redness, itching, and pain. May
cause allergic skin reaction.
INGESTION: May cause dizziness, abdominal pain, vomiting, nausea, and bloody diarrhea. Harmful if
swallowed.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product is not flammable or combustible. Fire fighters must wear SCBA and protective clothing. Fires
produce carbon, sulfur, and nitrogen oxides, formaldehyde, and also toxic gases, vapors, fumes, and
smoke. Closed containers may rupture in fire conditions. Cool containers exposed to flames with water fire and
reactivity
spray until well after the fire is out.
REACTIVITY: Normally stable. Can Incompatible with strong oxidizers and alkalis. Heat, flames, and
sources of ignition.
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY/FOG, FOAM, OR CO2
USAGE: KODAK Film developing reagent. Avoid breathing mists and vapor and avoid eye and skin
contact. NO SMOKING. Provide adequate (~10 APH) or local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, use DOT-IMO Class 6.1
hazardous warning labels (diamond): TOXIC SUBSATNCE, N.O.S.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves and an apron
(1000128583) must be worn when handling this material. APR (1000128163) or SCBA
(1000127427) should be worn if conditions warrant. Maintain an eyewash fountain and
emergency shower (1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 1/1/2005
CHEMICAL HAZARD BULLETIN NO.
1121B
Direct Charge
INDUSTREX
DEVELOPER
Part B
Health 3 CAS: Mixture
AMBER LIQUID WITH VINEGER OFOR.
Fire 2 HIGHLY TOXIC, MODERATELY FLAMMABLE, AND STABLE. UN: 2789
Reactivity 0 SEVERLY IRRITANT TO THE RESPIRATORY SYSTEM, SKIN, GUIDE: 132
AND EYES. SKIN SENSITIZER. EAC: •2P
LIQUID/MISTS/ Part B of the product contains 85-90% acetic acid (TLV=10 ppm, TLV-STEL=15 ppm), 5-
3
VAPOR: 10% 1-phenyl-3-pyrazolidinone (REL=0.2 mg/m ), 1-5% nonionic surfactant, < 5-
nitroindazole, <1% hexadecyltrimethylammonia bromide, and 1-5% water.
EFFECTS OF OVER-EXPOSURE:
health
INHALATION: Inhalation of mists and vapor may cause irritation to the respiratory tract; symptoms may
include coughing, sore throat, and shortness of breath. May damage teeth and lungs.
hazards
EYE/ SKIN: Eye contact causes irritation, redness, pain, and possible corneal ulceration. Skin
contact causes irritation, rash, redness, itching, and burns. May cause allergic skin
reaction.
INGESTION: May cause dizziness, abdominal pain, vomiting, nausea, and bloody diarrhea. Can be
fatal if swallowed.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product is flammable; no flashpoint or explosive range are reported. Fire fighters must wear SCBA and
protective clothing. Fires produce carbon, sulfur, and nitrogen oxides, formaldehyde, and also toxic gases,
vapors, fumes, and smoke. Closed containers may rupture in fire conditions. Cool containers exposed to fire and
reactivity
flames with water spray until well after the fire is out.
REACTIVITY: Normally stable. Can Incompatible with strong oxidizers and alkalis. Heat, flames, and
sources of ignition.
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY/FOG, FOAM, OR CO2
USAGE: KODAK Film developing reagent. Avoid breathing mists and vapor and avoid eye and skin
contact. NO SMOKING. Provide adequate (~10 APH) or local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, use DOT-IMO Class 8 hazardous
warning labels (diamond): CORROSIVE LIQUID, N.O.S.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves and an apron
(1000128583) must be worn when handling this material. APR (1000128163) or SCBA
(1000127427) should be worn if conditions warrant. Maintain an eyewash fountain and
emergency shower (1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 1/1/2005
CHEMICAL HAZARD BULLETIN NO. 1121C
Direct Charge
INDUSTREX
DEVELOPER
Part C
Health 3 CAS: Mixture
CLEAR BROWN LIQUID WITH ALDEHYDE ODOR.
Fire 1 HIGHLY TOXIC, SLIGHTLY FLAMMABLE, AND STABLE. UN: 2927
Reactivity 0 SEVERLY IRRITANT TO THE RESPIRATORY SYSTEM, SKIN, GUIDE: 154
AND EYES. SKIN SENSITIZER. EAC: 2XE
LIQUID/MISTS/ Part C of the product is an 65-70% aqueous solution of 20-25% glutaraldehyde bis
VAPOR: (sodium bisulfite), 10-15% glutaraldehyde (TLV,C=0.05 ppm), and <1% acetic acid
(TLV=10 ppm, TLV-STEL=15 ppm)
EFFECTS OF OVER-EXPOSURE:
health
INHALATION: Inhalation of mists and vapor causes severe irritation to the respiratory tract and the
lungs; symptoms may include coughing, sore throat, and shortness of breath.
hazards
EYE/ SKIN: Eye contact cause severe irritation, redness, pain, and possible corneal ulceration. Skin
contact causes irritation, rash, redness, itching, burns, and sensitizationand allergic skin
reaction.
INGESTION: May cause dizziness, abdominal pain, vomiting, nausea, coma, and bloody diarrhea.
Can be fatal if swallowed.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product is slightly flammable; no flashpoint or explosive range are reported. Fire fighters must wear
SCBA and protective clothing. Fires produce carbon, sulfur, and nitrogen oxides, formaldehyde, and also
toxic gases, vapors, fumes, and smoke. Closed containers may rupture in fire conditions. Cool containers fire and
reactivity
exposed to flames with water spray until well after the fire is out.
REACTIVITY: Normally stable. Can Incompatible with strong oxidizers and alkalis. Heat, flames, and
sources of ignition.
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY/FOG, FOAM, OR CO2
USAGE: KODAK Film developing reagent. Avoid breathing mists and vapor and avoid eye and skin
contact. NO SMOKING. Provide adequate (~10 APH) or local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, use DOT-IMO Classes 6.1 and 8
hazardous warning labels (diamond): TOXIC, CORROSIVE LIQUID, N.O.S.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves and an apron
(1000128583) must be worn when handling this material. APR (1000128163) or SCBA
(1000127427) should be worn if conditions warrant. Maintain an eyewash fountain and
emergency shower (1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 1/1/2005
CHEMICAL HAZARD BULLETIN NO. 1121D
health
INHALATION: Inhalation of mists and vapor may cause irritation to the respiratory tract; symptoms may
include coughing, sore throat, and shortness of breath.
hazards
EYE/ SKIN: Eye contact causes irritation, redness, and pain. Skin contact causes irritation and rash.
Symptoms include redness, itching, and pain. Skin contact may cause irritation with
redness, pain, and possibly burns, and sensitization and allergic reaction.
INGESTION: May cause dizziness, abdominal pain, vomiting, nausea, and bloody diarrhea. Harmful if
swallowed.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product is not flammable or combustible. Fire fighters must wear SCBA and protective clothing. Fires
produce carbon, sulfur, and nitrogen oxides, formaldehyde, and also toxic gases, vapors, fumes, and
smoke. Closed containers may rupture in fire conditions. Cool containers exposed to flames with water fire and
reactivity
spray until well after the fire is out.
REACTIVITY: Normally stable. Can Incompatible with strong oxidizers and alkalis. Heat, flames, and
sources of ignition.
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY/FOG, FOAM, OR CO2
USAGE: KODAK Film developing reagent. Avoid breathing mists and vapor and avoid eye and skin
contact. NO SMOKING. Provide adequate (~10 APH) or local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, use DOT-IMO Classes 6.1 and 8
hazardous warning labels (diamond): TOXIC, CORROSIVE LIQUID, N.O.S..
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves and an apron
(1000128583) must be worn when handling this material. APR (1000128163) or SCBA
(1000127427) should be worn if conditions warrant. Maintain an eyewash fountain and
emergency shower (1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 1/1/2005
CHEMICAL HAZARD BULLETIN NO. 1132A
1000653651 20-L KT
SOUPLETHANE
BASE
Health 1 CAS: Mixture
GRAY OR GREEN LIQUID WITH SOLVENT ODOR.
Fire 1 SLIGHTLY TOXIC AND FLAMMABLE, AND STABLE. UN: N/A
Reactivity 0 MAY BE IRRITANT TO THE RESPIRATORY TRACT, EYES, GUIDE: N/A
AND SKIN. EAC: N/A
health
INHALATION: Inhalation of vapor and mists may irritate respiratory system.
hazards
EYE/ SKIN: Eye and skin contact may cause irritation. And Skin contact causes irritation; prolonged
or repeated contact may result in skin defatting, drying, and dermatitis.
INGESTION: May cause irritation to mouth, throat and stomach with effects including mucous build
up, irritation to the tongue and lips and pains in the stomach, which may lead to nausea,
vomiting and diarrhea.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product flashpoint is >200°C (>392°F); no explosive limits were reported. Fire fighters must wear SCBA
and protective clothing. Fires produce carbon, and nitrogen oxides, and also toxic gases, vapors, fumes,
and smoke. Closed containers may rupture in fire conditions. Cool containers exposed to flames with water fire and
reactivity
spray until well after the fire is out.
REACTIVITY: Normally stable. Incompatible with strong oxidizers, e.g., nitric acid. Heat and sources of
ignition.
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY/FOG, FOAM, OR CO2
USAGE: Anti-corrosion paint. Avoid breathing vapor and mists and avoid eye and skin contact. NO
SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, the product is not regulated, and
does require hazardous labels.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves and an apron
(1000128583) must be worn when handling this material. APR (1000128210) or SCBA
(1000127427) should be worn if conditions warrant. Maintain an eyewash fountain and
emergency shower (1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 12/11/2004
CHEMICAL HAZARD BULLETIN NO. 1154
SODIUM
1000186243 125-LB DM
FLUORIDE
health
INHALATION: Causes severe irritation to the respiratory tract. Symptoms include coughing, sore
throat, and heavy breathing. These effects may be delayed. Chronic exposure may
cause teeth and bone damage. Target organs include heart, central nervous system
(CNS), circulatory system, bones, and kidneys.
hazards
EYE/ SKIN: Eye contact may cause redness, severe irritation, and eye damage. Skin contact may
cause redness and pain. Solutions are corrosive. These adverse effects may be
delayed.
INGESTION: Fatal if swallowed. May cause salivation, nausea, vomiting, diarrhea, and abdominal
pain. Symptoms include weakness, tremors, shallow respiration, and coma. May
damage brain, kidneys, heart, and circulatory system and may lead to death.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product is not flammable or combustible. Fire fighters must wear SCBA and protective clothing. Fire
produces hydrogen fluoride, carbon and nitrogen oxides, and also toxic gases, vapors, fumes, and smoke.
Closed containers may rupture in fire conditions. Cool containers exposed to flames with water spray until fire and
reactivity
well after the fire is out.
REACTIVITY: Normally stable. Incompatible with acids and glass. Avoid exposure to heat, flames, and
sources of ignition.
EXTINGUISHING MEDIA: SUITABLE FOR SURROUNDING FIRE
USAGE: Laboratory reagent. Avoid breathing mists and dust, and avoid eye and skin contact. NO
SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, use DOT-IMO Class 6.1
hazardous warning labels (diamond): TOXIC SOLID, N.O.S.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves and an apron
(1000128583) must be worn when handling this material. APR (1000128210/165) or
SCBA (1000127427) should be worn if conditions warrant. Maintain an eyewash fountain
and emergency shower (1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 873-8291(DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 9/26/2005
CHEMICAL HAZARD BULLETIN NO. 1167
LIQUID/VAPOR/ A proprietary formulation of 10-30% methanol (TLV, Skin= 200 ppm), 10-30% xylene
MISTS: (TLV=100 ppm), 0-1% 1,2,4-trimethylbenzne (TLV= 25 ppm), 0-1% mesityene (TLV=25
ppm), 1-5% alkyl (C3-C5) benzenes, alkylbenzene sulfonic acid, 0-1% alkyl (C3-C4)
benzenes and 10-30% alkyl (C9-C10) benzenes.
health
EFFECTS OF OVER-EXPOSURE:
hazards
INHALATION: Irritates the respiratory system. Corrosive to the mucous membranes and the lungs.
EYE/ SKIN: May cause serious damage to eyes. Skin contact may cause dryness, cracking,
irritation and dermatitis. Toxic amounts may be absorbed through the skin.
INGESTION: Gastrointestinal distress, nausea, vomiting, diarrhea, and abdominal pain. May cause
central nervous system depression and liver and/or kidney damage.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The flashpoint is 9°C (48°F); no explosive range was reported. Fire fighters must wear SCBA and protective
clothing. Fires produce hydrogen fluoride, ammonia, and nitrogen oxides, and also toxic gases, vapors,
fumes, and smoke. Closed containers may rupture in fire conditions. Cool containers exposed to flames fire and
reactivity
with water spray until well after the fire is out.
REACTIVITY: Normally stable. Incompatible with: Strong oxidizers. Heat, flames, and sources of ignition.
EXTINGUISHING MEDIA: WATER SPRAY, FOAM, OR CO2
USAGE: Well stimulant and mud acid additive. Avoid breathing dust and avoid eye and skin
contact. NO SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, label containers with DOT-IMO
Class 3 hazardous warning label (diamond): FLAMMABLE LIQUID, N.O.S.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves and an apron
(1000128583) must be worn when handling this material. APR (1000128213) or SCBA
(1000127427) should be worn if conditions warrant. Maintain an eyewash fountain and
emergency shower (1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 7/11/2004
CHEMICAL HAZARD BULLETIN NO. 1169
health
INHALATION: May irritate mucous membranes and upper respiratory tract. Inhalation of excessive
concentrations may cause nuisance condition such as coughing, sneezing, and nasal
irritation.
hazards
EYE/ SKIN: Eye contact may severe mechanical irritation. Skin contact may cause irritation.
INGESTION: Can cause severe burns of the mouth, throat, and stomach, leading to death. Also,
sore throat, vomiting, diarrhea. May cause violent gastroenteritis, peripheral vascular
collapse, dizziness, intense thirst, muscle cramps, coma, abnormal bleeding, fever,
liver damage.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product is not flammable or combustible. Fire fighters must wear SCBA and protective clothing. Fires
produce carbon, calcium, and nitrogen oxides, and also toxic gases, vapors, fumes, and smoke. Closed
containers may rupture in fire conditions. Cool containers exposed to flames with water spray until well after fire and
reactivity
the fire is out.
REACTIVITY: Normally stable. Incompatible with: Strong oxidizers and acids. Heat and sources of ignition.
Exposure to strong acids will lead to decomposition.
EXTINGUISHING MEDIA: WATER SPRAY, CARBON DIOXIDE AND DRY CHEMICAL POWDER
USAGE: Drilling mud in oil operations. Avoid breathing dust and avoid eye and skin contact. NO
SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, the product is not regulated.
Packages do not require IMO-DOT warning signs.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 873-6676.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves must be worn
when handling this material. APR (100012165) or SCBA (1000127427) should be worn if
conditions warrant. Maintain an eyewash fountain and emergency shower (1000128433)
where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 574-4722 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 5/22/2004
CHEMICAL HAZARD BULLETIN NO. 1170
SOLTEX™ 1000021607 25 KG SK
ADDITIVE
DUST/FIBERS: The product is a proprietary formulation of various ingredients. It may contain <1%
crystalline silica (TLV=0.1 mg/m3).
EFFECTS OF OVER-EXPOSURE:
health
INHALATION: Chronic inhalation of dust containing crystalline silica may cause silicosis, which is
associated with impaired lung functions. Silica is classified as potential human
carcinogen.
hazards
EYE/ SKIN: Eye contact may cause severe mechanical irritation, and redness. Skin contact may
cause irritation.
INGESTION: Can cause severe burns of the mouth, throat, and stomach, leading to death. Also, sore
throat, vomiting, diarrhea. May cause violent gastroenteritis, peripheral vascular
collapse, dizziness, intense thirst, muscle cramps, coma, abnormal bleeding, fever, liver
damage.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product is not flammable or combustible. Fire fighters must wear SCBA and protective clothing. Fires
produce carbon, sulfur, and nitrogen oxides, and also toxic gases, vapors, fumes, and smoke. Closed
containers may rupture in fire conditions. Cool containers exposed to flames with water spray until well after fire and
reactivity
the fire is out.
REACTIVITY: Stable and non reactive.
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY, FOAM, OR CO2
USAGE: Drilling mud in oil operations. Avoid breathing dust and fibers and avoid eye and skin
contact. NO SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, do not require DOT-IMO
hazardous warning label (diamond) or placard.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6676.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Wear safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves when handling
this material. APR with cartridges (1000483250) or SCBA (1000127427) should be worn if
conditions warrant. Maintain an eyewash fountain and emergency shower (1000128433)
where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 574-4722 ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 5/16/2004
CHEMICAL HAZARD BULLETIN NO. 1171
KELZAN® XC 1000021930 25 KG SK
Xanthan Gum
health
INHALATION: May irritate mucous membranes and upper respiratory tract. Inhalation of excessive
concentrations may cause nuisance condition such as coughing and sneezing.
hazards
EYE/ SKIN: Eye contact may cause mechanical severe irritation. Skin contact may irritation. Prolonged
contact may cause drying or chapping of the skin.
INGESTION: Can cause severe burns of the mouth, throat, and stomach, leading to death. Also, sore
throat, vomiting, diarrhea. May cause violent gastroenteritis, peripheral vascular collapse,
dizziness, intense thirst, muscle cramps, coma, abnormal bleeding, fever, liver damage.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product can form explosive mixtures if dispersed in air and forms. Fire fighters must wear SCBA and
protective clothing. Fires produce carbon and nitrogen oxides, and also toxic gases, vapors, fumes, and
smoke. Closed containers may rupture in fire conditions. Cool containers exposed to flames with water fire and
reactivity
spray until well after the fire is out.
REACTIVITY: Normally stable. Incompatible with: Strong oxidizers. Heat and sources of ignition.
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY, FOAM, OR CO2
USAGE: Drilling mud in oil operations. Avoid breathing dust and avoid eye and skin contact. NO
SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, as the product may form explosive
vapor-air mixtures; use DOT-IMO Class 4.2 hazardous warning labels (diamond):
COMBUSTIBLE SOLID, N.O.S.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene gloves (1000129418) must be worn when handling this
material. APR (1000128165) or SCBA (1000127427) should be worn if conditions
warrant. Maintain an eyewash fountain and emergency shower (1000128433) where the
material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute BUT first obtain medical authorization. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1499 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 8/25/2004
CHEMICAL HAZARD BULLETIN NO. 1203
®
VAPOR/LIQIUD: There is no TLV established for this product. None of the substances in this product is
hazardous.
EFFECTS OF OVER-EXPOSURE:
EYE/ SKIN:
INHALATION:
May cause eye & skin irritation with prolonged contact.
Not likely a route of exposure. No adverse effects expected.
health
INGESTION: Not likely a route of exposure. No adverse effects expected. hazards
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
This product is non-flammable. No expected to burn unless all the water is boiled away. The remaining organics
may be ignitable. Firefighter must wear SCBA and protective clothing. During combustion, toxic vapors (COx, NOx
and NH4) and smoke may be formed. Closed containers may rupture in fire conditions. Keep containers cool with fire and
water spray.
REACTIVITY: Avoid contact with strong oxidizers. (e.g. Chlorine , peroxides, chromates, nitric acid, percholrate,
reactivity
concentrated oxygen, and permanganate)
STORAGE: Store in a well ventilated, cool, dry area away from ignition sources. Keep containers
labeled, upright and tightly closed when not in use. DO NOT store in direct sunlight.
Avoid storage near incompatible material. Protect from freezing.
handling
TRANSPORT For transportation, packages do not require DOT-IMO hazardous warning label (diamond)
or placard. storage
SPILLS/LEAKS: Stop the flow if it can be done safely. Dike to prevent entry into sewer. Absorb with sand
and place in clean, dry labeled container. &
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428. disposal
SAFETY Provide ventilation to control airborne concentrations below the guidelines. Safety
EQUIPMENT: goggles (1000129810) and PVC gloves (1000129492) must be worn when handling this
material. SCBA should be worn if conditions warrant. Maintain an eyewash fountain and
emergency shower where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLY
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped give cardio-pulmonary resuscitation (CPR). Keep person warm and quiet.
EYE/SKIN Flush eyes with large amount of water for at least 15 minutes. Lift eyelids occasionally.
CONTACT: Wash skin thoroughly with water. Remove contaminated clothing and shoes promptly
and wash clothing before re-use. first aid
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs due to vomiting can cause
chemical pneumonitis which can be fatal. If conscious, drink one-two glasses of water to
dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Environmental Protection: 873-5853 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
6/27/2006
CHEMICAL HAZARD BULLETIN NO. 3
XYLENE 1000187257 4L Bottle
1000187259 20L Can
(Mixture of Ortho, 1000198500 5L Can
meta-and para-Xylene 1000198455 5L Can
Isomers)
EYE/SKIN:
nausea, headache, depression, excitement, pain, possible unconsciousness and even death.
Chronic overexposures may result in dermatitis, kidney, liver, and blood damage. Eye contact can health
cause severe Irritation, pain, tearing, conjunctivitis and blurred vision. Skin contact causes defatting
INGESTION:
of tissue. Prolonged skin contact may cause moderate irritation and dermatitis. Ingestion can cause
GI irritation, nausea, vomiting and diarrhea. Swallowing 15 ml. can be fatal to adults and vomiting
hazards
may damage lungs .
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
Highly flammable; The flashpoint for this product is 26°C (80° F), with an explosive range in air of 1.0% (LEL) to 7.0% (UEL).
Firefighters must use self-contained breathing apparatus (SCBA) and protective clothing. During combustion, toxic oxides of
carbon and nitrogen may be formed, also organic vapors and smoke. Closed containers may rupture in fire conditions. Keep
containers cool with water spray. Vapors are heavier than air and can flow along surfaces to distant ignition sources and
fire and
flashback.
REACTIVITY: Avoid contact with nitric and sulfuric acid and strong oxidizing agents , e.g., chlorates, peroxides, reactivity
nitrates and chlorine and halogens, active metals and acids. May attack some plastics and rubber.
EXTINGUISH AREA FIRES WITH WATER FOG, ALCOHOL, FOAM, CO2 OR DRY CHEM ICAL
USES: Paint thinner, laboratory solvent, and “aromatic hydrocarbon” solvent. Avoid contact. Do not breathe
vapors or mist. Wash hands after handling, before eating, drinking or smoking. Ground and bond
when transferring. Use a laboratory fume hood if possible.
STORAGE: Store in well ventilated, cool, dry area, away from ignition sources. Keep containers upright and
tightly closed when not in use. DO NOT store in direct sunlight. Avoid storage near incompatible
TRANSPORT:
material. If inside, it should be in a standard flammable cabinet.
For transportation, always label containers with DOT/IMO Class 3, hazardous warning label handling
(diamond); FLAMMABLE LIQUID.
SPILLS/LEAKS: Remove sources of ignition. Always wear protective clothing and air-supplied breathing apparatus.
Dike to prevent entry into drains or water sources. Soak large spills into sorbent or sand at once.
storage
DISPOSAL:
Clean small spills with water and soap.
For proper disposal methods and locations for the chemical or chemical contaminated material,
contact the Environmental Engineering Division at 874-6428.
&
SAFETY EQUIPMENT: Maintain Scoot Air Pak (S/N 21-311-231) for emergency. Wear air-supplied respirator to work in
enclosed areas. Provide ventilation to control exposures below the TLVs. Chemical goggles disposal
(1000129810) or face shield, protective gloves (1000129628), boots (1000128971) and apron
(1000128583) always be worn when handling quantities of xylene. Maintain an eyewash fountain and
emergency shower.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
EYE/SKIN CONTACT: Immediately, flush eyes with copious amounts of water for at least 15 minutes holding eyelids apart.
Remove contaminated clothing/shoes. Wash skin thoroughly with soap and water; a moisturizer
reduces dryness. Do not reuse contaminated clothing until laundered.
INHALATION: Remove those exposed to fresh air. If breathing is difficult administer oxygen. If breathing has
INGESTION:
stopped, apply cardio-pulmonary resuscitation (CPR).
DO NOT induce vomiting. Never give unconscious person drink. Aspiration of material into the lungs
first aid
due to vomiting can cause chemical pneumonitis, which can be fatal. If conscious, drink one-two
glasses of water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Environmental Protection: 872-2623 (DH), 678-4902 (RT), 572-4538 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:3/1/2004
CHEMICAL HAZARD BULLETIN NO. 8
1000183210 2.5 LT BT
HYDROCHLORIC 1000183167/232 500 ML BT
ACID 1000183214 49 LT CO
1000183218 Bulk Delivery
(Muriatic Acid; 1000186657/687 1 GA DM
Oakite No.32) 1000253977 20 GA DM
LIQUID/VAPOR: Both the TLV and PEL have a Ceiling of 5ppm for this strong acid.
EFFECTS OF OVEREXPOSURE:
INHALATION: Atmospheric levels of 1.5ppm are irritating. Above 35ppm it causes severe eye, nose and
throat irritation. Levels about 100ppm are immediately hazardous to life. health
EYE/SKIN: Severely burns eyes and skin. hazards
INGESTION: Swallowed will corrode lining of mouth, throat and stomach and may be fatal.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
Hydrochloric acid does not burn but flammable hydrogen gas is produced on contact with common metals. Fire
fighters MUST wear full protective suit, gloves and Scott Air Pak (21-311-231).
fire and
REACTIVITY: Avoid contact with metals, ethylene, ammonia, lye and sulfuric acid. Reacts with water or steam to
produce toxic and corrosive vapors.
EXTINGUISH FIRES WITH DRY CHEMICAL OR FOAM
reactivity
USES: Primarily for acidizing oil wells and cleaning boilers or other refinery equipment.
STORAGE: Post storage area with “DANGER ACID” sign. Store away from incompatible materials
listed in the reactivity section.
TRANSPORT: For transportation, label packages with DOT-IMO Class 8, hazardous warning label
(diamond): CORROSIVE. handling
SPILLS/LEAKS: Always wear full protective clothing and air-supplied breathing apparatus. storage
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6428. &
SAFETY
EQUIPMENT:
Keep Scott Air Pak (1000127427) available for emergencies. Maintain an eyewash
fountain and emergency shower (1000128433) where the acid is stored/used. Wear disposal
goggles (1000129628), coveralls (1000129180), boots (1000128971) and protective
gloves (1000129628) where eye or skin contact is likely.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Poisonous: irritates throat and eyes. Move victim to fresh air. If breathing has stopped,
wash victim’s face quickly and give artificial resuscitation.
EYE/SKIN Place victim into emergency shower at once. If in eyes, hold eyelids open and flush with
CONTACT: water for 15 minutes. first aid
INGESTION: If swallowed and victim is conscious, give victim water. Do NOT induce vomiting.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:4/12/2003
CHEMICAL HAZARD BULLETIN NO. 11
® 3
DUST/SOLID/ TLV ceiling limit is 2 mg/m .
LIQUID:
EFFECTS OF OVER-EXPOSURE:
EYE/ SKIN: Severe burns results from any contact with caustic soda including severe or permanent
eye injury. Mild skin irritations occur upon contact with dilute solutions of sodium
health
INHALATION/
hydroxide.
At higher levels than TLV, irritation of nose, violent sneezing, irritation and corrosion of the hazards
INGESTION: respiratory tract and lungs will occur. Swallowed, lye will deeply burn mouth, throat, and
stomach.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
Non-flammable but solid caustic soda in contact with moisture or water may generate sufficient heat to ignite
combustible materials. Sodium hydroxide reacts with aluminum, tin, and zinc to generate flammable and explosive
hydrogen gas. Can react violently with strong acids and with many organic chemicals, especially with nitro-carbons fire and
and chloro-carbons. A highly exothermic reaction occurs with small amounts of water. Firefighters should wear
full protective clothing, including a self-contained breathing apparatus (SCBA). Avoid splattering or splashing lye
during a fire.
reactivity
EXTINGUISH FIRES WITH WATER SPRAY, FOAM, OR CO2
USAGE: For catalyst regeneration, to maintain alkaline pH in boiler feed water, and as a laboratory
reagent.
STORAGE: Store in well-ventilated, cool, dry area, away from ignition sources. Protect containers
from moisture and keep tightly closed when not in use. Separate lye from acids, metals,
TRANSPORT:
explosives, organic peroxides, and easily ignited materials, e.g., hydrocarbon liquids.
For transportation, label packages with DOT-IMO Class 8, hazardous warning label handling
(diamond): CORROSIVE.
SPILLS / LEAKS: Evacuate all unnecessary personnel. Shut off sources of ignition. Stop the flow if it can be
done safely. Dike to prevent entry into sewer. Absorb with sand, place in clean, dry,
storage
DISPOSAL:
closed container, and label.
For proper disposal methods and locations for chemical or chemical contaminated
&
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control vapor concentrations below the TLVs. Safety goggles, disposal
EQUIPMENT: rubber or neoprene gloves, and coveralls should be worn if eye or skin contact is likely.
Mist or dust exposure requires wearing respirators (S/N 21-371-401). Maintain eyewash
fountain and emergency shower where sodium hydroxide is used or stored.
USE CONFINED SPACE PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Get medical attention.
EYE/SKIN Flush eyes with large amounts of water for at least 15 minutes. Lift eyelids occasionally.
CONTACT: All material must be flushed out or permanent damage will result. Remove contaminated
INGESTED:
clothing and shoes and flush skin with plenty of water.
DO NOT induce vomiting. Aspiration of material into the lungs due to vomiting can cause
first aid
chemical pneumonitis, which can be fatal. If conscious, drink one-two glasses of water to
dilute. Keep person warm and quiet. GET MEDICAL ATTENTION.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ), or 427-2217 (JID).
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised 1/13/2001
CHEMICAL HAZARD BULLETIN NO. 015
S/N 26-668-754 460 Ib. Net Drum
MORPHOLINE
Tetrahydro-Oxazine
® 3
VAPOR/LIQUID TLV is 20 ppm (71 mg/ m ) and STEL is 30 ppm.
EYE/SKIN Vapor may absorb through skin. Exposure to the vapor may cause severe irritation of the
respiratory tract. Slight overexposure may cause hazy vision or filming of eyes which does
not results in permanent damage. Above 100 ppm will damage lungs.
health
LIQUID: Absorb readily through intact skin: the strongly basic liquid may cause serve permanent hazards
INHALATION/ damage to the eyes. Soaked into clothes will burn stomach. Ingestion will cause
INGESTION corrosion of the digestive tract.
o o
Highly flammable liquid. The flash point is 38 C (100 F), flammable limits are 1.8%-10.8% VAPOR in air. Vapor is
heavier than air and may flashback along vapor trail. Hazardous reactions with strong acids or oxidizers, e.g.
chromates. In a fire, morpholine emits toxic oxides of carbon and nitrogen. Fire fighters MUST wear protective
fire and
gloves and reactivity.
EXTINGUISH FIRES WITH WATER SPRAY CO2, FOAM OR DRY CHEMICAL reactivity
USAGE: Corrosion inhibitor in boiler feed-water.
STORAGE: Outside or detached storage is preferable. Inside storage must be standard flammable
liquids storage room or cabinet. Separate from ignition sources, strong acids and
oxidizing agents, e.g., nitrates, peroxides, or chromates.
handling
TRANSPORT: Always label containers for transporting.
“Flammable & Poison class (6), liquid class (3)”.
Use DOT/IMO hazard warning labels storage
DISPOSAL/SPILLS / Wear protective clothing and cover spill with a 9:1 mixture of sand and soda ash. Contact
&
LEAKS: Environment Engineering (874-6426 or 874-6428) for disposal instructions.
disposal
SAFETY In confined spaces, wear goggles (S/N 21-434-249), gloves (S/N 21-432-576), and apron
EQUIPMENT: (S/N 21-404-181) to handle morpholine. Maintain eyewash fountain and emergency
shower (S/N 21-372-365) where confined entry is used.
INHALATION: Irritates eyes and skin. Remove overcome victim to fresh air, if breathing is difficult
administer oxygen. If breathing has stopped give CPR keep person warm and quite.
EYE/SKIN Burns eyes. Absorb through skin. If in eyes, hold eyelids open and flush with water for
CONTACT: 15 minutes. If on skin, wash thoroughly with soap and water. Remove contaminated
clothing and launder before reuse. first aid
INGESTION If swallowed, give large quantities of milk or water. Keep victim quiet and do NOT induce
vomiting.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
*Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised 10/21/2001
CHEMICAL HAZARD BULLETIN NO. 16
S/N 26-235-478 65% Cl2 45 Kg Drum
CALCIUM 26-235-494 65% Cl2 2.7Kg Can
HYPOCHLORITE 95-867-544 0.45Kg Container
Bleaching Powder
Hypochlorous Acid
Calcium Salt
Health 3 WHITE POWDER OR GRANULES WITH CAS: 7778-54-3
CHLORINE ODOR, HIGHLY TOXIC UN: 2880
Fire 0 AND REACTIVE, NON-FLAMMABLE GUIDE: 140
Reactivity 3
®
DUST: There is no TLV established for calcium hypochlorite. This product contains 65% calcium
hypochlorite and 35% inert substances (includes 5-10% moisture).
EFFECT OF OVER-EXPOSURE:
EYE/SKIN: Corrosive to the eyes. Contact with eyes, even for even a minute amount for short
duration can cause severe irritation and even blindness. Contact with skin may cause
severe irritation, burns, or tissue destruction.
health
INHALATION: Irritating to the nose, mouth, throat and lungs. Burns to the respiratory tract may occur
resulting in shortness of breath, wheezing, chocking, chest pain, and impairment of lung
hazards
function. Repeated exposure or high levels can result in permanent lung damage.
INGESTION: Gastrointestinal distress, nausea, vomiting, diarrhea, abdominal pain, and bleeding
WEAR PROTECTIVE EQUIPMENT TO HANDLE HYPOCHLORITE
The product is not flammable. Fire fighters must wear SCBA and protective clothing. During combustion, chlorine,
hypochlorous acid; toxic vapors and smoke will be formed. Closed containers may rupture in fire conditions. Keep
containers cool with water spray. fire and
REACTIVITY: Avoid high heat, combustible materials, strong reducing agents, acids, organic compounds, and
heavy metals. reactivity
EXTINGUISH FIRES WITH WATER SPRAY
USAGE: Drinking water disinfectant; swimming pool treatment. Algaecide, bactericide, fungicide,
deodorant, bleaching agent.
STORAGE/
TRANSPORT:
Store in a well-ventilated, cool, dry area, away from ignition sources. Avoid extreme
temperatures. Keep tightly closed when not in use. DO NOT store in direct sunlight. handling
Avoid storage near incompatible materials
SPILLS / LEAKS: Shut off sources of ignition. Stop the flow if it can be done safely. Spilled material may
make floor slippery. Dike to prevent entry into sewer. Absorb with sand and place in
storage
DISPOSAL:
clean, dry, labeled containers.
For proper disposal methods and locations for the chemical or chemical contaminated &
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY
EQUIPMENT:
Safety goggles, PVC or Neoprene gloves (21-432-570/591/080), and chemical cartridge
respirators (S/N 21-370-800). Maintain eyewash and emergency shower where material is
disposal
being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
EYE/SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
INGESTION:
and wash clothing before re-use.
DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical first aid
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ), or 427-2217 (JID).
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised 1/13/2001
CHEMICAL HAZARD BULLETIN NO. 022
S/N 26-452-801
PENTA-
CHLOROPHENOL
PCP: SODIUM
PENTA-
CHLOROPHENATE
STORAGE: Keep containers carefully sealed. Clean spills and replace damaged containers
handling
immediately.
SPILLS: Don dust/mist respirator, apron, gloves and goggles to clean a spill of powder or solution.
Mix powder with sand, transport to safe, open area for burial. Contact Environmental
Engineering (874-6426 or 874-6428) for disposal areas. AVOID CONTACT WITH PCP:
storage
WEAR PROTECTIVE CLOTHING.
&
SAFETY Wear dust/mist respirator (S/N 21-370-400 and S/N 21-370-444), goggles (S/N 21-434-
EQUIPMENT: 249) or face shield (S/N 21-426-121), PVC gloves (S/N 21-432-570) and apron (S/N 21-
404-199) to handle PCP and Sodium PCP. Replace gloves if they become soaked. In an
disposal
enclosed spac wear an air-supplied respirator. Launder work clothes before reuse.
Emergency showers and eye wash fountains must be maintained where this algicide is
handled or stored.
EYE/SKIN Hold eyelids open over running water for 15n minutes. Consult a physician. Remove
CONTACT: contaminated clothes immediately and shower with soap cleansing all affected skin.
INHALED: Wash victims face and take him to a physician at once.
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
*Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised: 12/29/2001
CHEMICAL HAZARD BULLETIN NO. 033
S/N 26-850-982 100 lb. drum
SODIUM SULFITE
(Corrosion Inhibitor)
EFFECTS OF OVER-EXPOSURE:
EYE/ SKIN: May cause mild transient eye irritation.
May cause irritation after prolonged skin contact.
health
INHALATION: May cause irritation to the respiratory tract and lungs. May also cause bronchoconstriction
resulting in shortness of breath.
hazards
INGESTION: Can be harmful.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
fire and
Non-Flammable. May release toxic oxides of sulfur under fire conditions. Firefighters must wear self-contained
breathing apparatus (SCBA) and full protective clothing.
REACTIVITY: Will release sulfur dioxide on contact with acids. Avoid contact with oxidizing agents.
EXTINGUISH FIRES WITH DRY CHEMICAL, CO2, FOAM OR WATER FOG
reactivity
USAGE: Oxygen scavenger for boiler feed water. Avoid breathing vapor or mist. No smoking.
Provide adequate ventilation.
TRANSPORT/ Store in a well ventilated, cool, dry area. Keep containers labeled, upright and tightly
STORAGE: closed when not in use. DO NOT store in direct sunlight. Avoid storage near heat, open
flames and incompatible materials. Always label containers for transporting in accordance
with DOT/IMO/IATA hazard warning labels. handling,
SPILLS/ LEAKS:
DISPOSAL:
Suppress dust with water, sweep and place in clean, dry, labeled container.
For proper disposal methods and locations for the chemical or chemical contaminated storage &
SAFETY
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
Provide ventilation to control airborne concentrations below the TLV. Chemical safety disposal
EQUIPMENT: goggles or face shield, rubber gloves, lab coat, uniform or protective suit are recommended
when handling this material. SCBA should be worn if conditions warrant. Maintain an
eyewash fountain and emergency shower where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes keeping eyelids open. Wash skin
CONTACT: thoroughly with soap and water. Remove contaminated clothing and shoes promptly, and
launder clothing before re-use.
INGESTION: Do not induce vomiting. Drink one-two glasses of water to dilute. Keep person warm and
quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:1/13/2001
CHEMICAL HAZARD BULLETIN NO. 38
S/N 26-844-818 100lb (50kg) drum
SODIUM
HEXAMETAPHOSPHATE
EFFECTS OF OVEREXPOSURE:
INHALATION: Inhalation is not generally a route of exposure.
health
EYE/SKIN: May cause temporary irritation if blown into eyes. Irritating if solution is splashed into
INGESTION:
eyes, as irritating as soapy water.
If ingested in large amounts, i.e. one pint or more, nausea, vomiting and diarrhea are
hazards
probable but no permanent damage is likely
STORAGE: No special health, flammability or reactivity hazards are associated with storage of sodium
hexametaphosphate.
SPILL: Shovel solid material into containers, re-use if possible. Spills should be diluted with
water and channeled to sewer.
handling
TRANSPORT: A DOT-IMO hazard warning label is not required for transportation. storage
DISPOSAL: For proper disposal methods and locations for chemical or chemical contaminated
&
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
disposal
SAFETY If eye contact with flakes or concentrated solution is possible, goggles (S/N 21-434-249)
EQUIPMENT: should be worn.
INGESTION: If swallowed and victim is conscious, give victim water. Do NOT induce vomiting. first aid
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:4/7/2001
CHEMICAL HAZARD BULLETIN NO. 040
S/N 26-158-075 55 gal drum
INDUSTRIAL
BACTERICIDE
Health 2 YELLOW, VOLATILE LIQUID, ALCOHOL ODOR CAS: None
Fire 3 MODERATELY TOXIC, CORROSIVE TO SKIN AND EYES UN: None
HIGHLY FLAMMABLE: WATER SOLUBLE GUIDE: None
Reactivity 0
MIST OR VAPOR: No Threshold Limit Value is established for the active ingredient, oxydiethylene bis(alkyl
dimethyl) ammonium chloride (CAS R # 64049-66-7). The TLV of methanol solvent (CAS
LIQUID:
R # 67-56-1) ppm. Spray, mist or vapor is corrosive to eyes and skin.
Splashed into eyes, may cause permanent damage. Irritating and corrosive to skin may
health
absorb through skin
Swallowed may be fatal; methanol may cause blindness.
hazards
WEAR GOGGLES AND RUBBER GLOVES TO HANDLE XC-370
This highly flammable bactericide has a flashpoint of 24oC (76oF, closed cup). XC-370 is not reactive with water.
EYE/SKIN Flush immediately with water for 15 minutes. Hold eyelids open over emergency fountain.
CONTACT:
INHALED VAPOR: Help the overcome victim into fresh air. If breathing has stopped has stopped. Begin
mouth-to-mouth resuscitation.
SWALLOWED: Have victim drink quantities of water. If available, give milk, egg white or gelatin solution.
Note to Physician: Probable mucosal damage may contraindicate the use of gastric
first aid
lavage. Measures against circulatory shock, respiratory depression and convulsions. May
be needed.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
*Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised 2/25/2001
CHEMICAL HAZARD BULLETIN NO. 45
ACID
HYDROGEN FLUORIDE
Health 4 COLORLESS FUMING LIQUID. BOTH VAPOR AND LIQUID CAS: 7664-39-3
ARE EXTREMELY CORROSIVE AND TOXIC. NON- UN: 1790
Fire 0 FLAMMABLE. HIGHLY REACTIVE. DISSOLVES GLASS GUIDE: 157
Reactivity 3
EYE/SKIN:
levels can cause fluorosis and bone deformity.
Contact with the eye will cause immediate and permanent blindness. Skin contact causes
health
INGESTION:
painful and long lasting damage. The effects of contact with dilute solutions may be
delayed for several hours but are no less serious. hazards
Intensely corrosive to the digestive tract.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The anhydrous acid, its vapor and aqueous solutions are non-flammable. In contact with a fire highly toxic fumes
may be released. Fire fighters should wear self-contained breathing apparatus (SCBA) and full protective acid
resistant clothing. fire and
REACTIVITY: The acid reacts violently with many organic materials, bases etc. It attacks and dissolves glass and
most metals. reactivity
EXTINGUISH AREA FIRES WITH WATER SPRAY, CO2 OR DRY CHEMICAL
USES: Laboratory reagent used to treat rock specimens. Oilfield chemical for acidizing wells.
Anhydrous HF is catalyst for alkylation. Avoid contact. Do not breathe vapors or mist.
STORAGE: In a cool dry well ventilated store. In polythene, polypropylene or rubber bottles, away
from incompatible materials.
TRANSPORT: For transportation, always label containers with DOT/IMO Class 8, hazardous warning
label (diamond); CORROSIVE LIQUID.
handling
SPILLS/LEAKS: Always wear full protective clothing and air-supplied breathing apparatus. Apply
magnesium sulfate to contaminated areas and isolate all material.
storage
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
&
SAFETY
EQUIPMENT:
Provide ventilation to control exposures below the TLVs. Air supplied or SCBA (21-311-
231) should be available. Chemical goggles (21-434-249), face shield, PVC gauntlet
disposal
gloves (21-432-513) or rubber gloves, PVC boots (21-408-744) and apron (21-404-181)
must always be worn when handling quantities of hydrofluoric acid. Maintain eyewash
fountain and emergency shower and calcium gluconate gel (2.5%) in storage area and
wherever used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
EYE/SKIN Immediately, flush eyes with copious amounts of water for at least 15 minutes holding
CONTACT: eyelids apart. Remove contaminated clothing/shoes. Wash skin thoroughly with soap and
water. Apply calcium gluconate gel(2.5%) liberally and massage into skin. All cases of HF
exposure must immediately be sent to emergency room of district clinic for assessment
INHALATION:
and treatment. Do not re-use any contaminated clothing even after laundering.
Remove those exposed to fresh air. If breathing is difficult administer oxygen. If breathing
first aid
has stopped, apply cardio-pulmonary resuscitation (CPR).
INGESTION: Give water to drink if conscious. DO NOT INDUCE VOMITTING. Keep warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:4/12/2003
CHEMICAL HAZARD BULLETIN NO. 048
S/N 26-015-037 500 ml Bottle
26-015-050 2.5 liter bottle
26-015-068 20 liter contain
ACETIC ACID
(100%=GLACIAL)
(VINEGAR ACID)
INGESTION:
and wash clothing before re-use.
Do not induce vomiting. Aspiration of material into the lungs can cause chemical
first aid
pneumonitis, which can be fatal. Drink one-two glasses of water to dilute. Keep person
warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:1/13/2001
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:1/13/2001
CHEMICAL HAZARD BULLETIN NO. 49
ACETYLENE 1000177863 40 CF CY
1000177903 250 CF CY
(Compressed 1000177907 250 CF CY
Welding Gas)
GAS/VAPOR: A compressed gas that acts as a “simple asphyxiant” which displaces oxygen in the air.
The NIOSH recommended ceiling is 0.25% (2,500 ppm). Impurities such as phosphine,
hydrogen sulfide, and ammonia may give the gas a mild garlic odor and are toxic.
INHALATION: Exposure to 10% (100,000 ppm) causes deep sleep or stupor, and exposure to 35%
(350,000 ppm) for five minutes causes loss of consciousness due to oxygen displacement
that may lead to death.
KEEP CYLINDERS COOL WITH WATER SPRAY & EXTINGUISH WITH WATER, CO2 or FOAM
USES: Used in acetylene torches for welding, cutting, and brazing.
STORAGE: Store cylinders UPRIGHT and no not store near sources of ignition, chlorine gas, copper,
mercury or silver.
TRANSPORT: For transportation, Label with DOT-IMO-UN Class 2 “Flammable Gas” hazardous warning
label/placard. handling
SPILLS/LEAKS: Will quickly dissipate into atmosphere. Label. storage
DISPOSAL: For proper disposal methods and locations for chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6428. &
SAFETY
EQUIPMENT:
Provide adequate ventilation. During welding use welder’s glasses and cover exposed
skin to prevent flash burns. During accidental release or use in confined spaces an SCBA disposal
(1000127427) is required.
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ), or 427-2217 (JID).
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised: 4/12/2003
CHEMICAL HAZARD BULLETIN NO. 51
ETHYLENE S/N 26-136-554 55 GAL DM
26-382-444 55 GAL DM
GLYCOL 26-382-431 1 GAL DM
C1, 2-ETHANEDIOL 26-565-043 1 GAL DM
(“DOWGUARD”)
ANTIFREEZE
EYE/SKIN:
EFFECTS OF OVEREXPOSURE:
Toxicity is usually from ingestion, as very little is absorbed through intact skin. Dermatitis
o
health
is possible from skin sensitization. Unless heated above 100 C or agitated into spray or
INHALATION: mist, ethylene glycol is not an inhalation hazard. Inhalation of mists may affect the central
nervous system (CNS). Ingestion of repeated small doses result in the deposition of
hazards
INGESTION:
calcium oxalate crystals in the brain and kidneys. The probable lethal oral dose for an
adult human is about 100 cc or lass than half a cup.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
Ethylene glycol is combustible with a flashpoint of 104°C(220°F), with an explosive range in air beginning at
3.2%(LEL) to 15.3%(UEL). Firefighters must use self-contained breathing apparatus (SCBA) and protective
clothing. During combustion, oxides of carbon and nitrogen may be formed, also toxic organic vapors and smoke.
Closed containers may rupture in fire conditions. Keep containers cool with water spray. A solid stream of water
into material may cause frothing. Vapors are heavier than air and can flow along surfaces to distant ignition
fire and
sources and flashback.
REACTIVITY: Keep away from strong acids and bases, strong oxidizing agents, and materials reactive with reactivity
hydroxyl compounds.
EXTINGUISH FIRES WITH DRY CHEMICAL, CO2, FOAM, OR WATER FOG.
USES: Diluted 50%, DOWGARD is used as antifreeze in Aramco vehicles, and in heating and
cooling systems, and as a solvent for paints. Use adequate ventilation. No smoking. Do
not breathe vapors or mist. Wash thoroughly after use.
STORAGE: No flammable or reactivity precautions are associated with storage of ethylene glycol or
DOWGARD. Do not transfer into unmarked container. Keep out of reach of children.
Store in a well-ventilated, cool, dry area. Keep containers labeled, upright, and tightly
closed when not in use. Avoid storage near incompatible material.
Evacuate all unnecessary personnel. Shut off sources of ignition. Stop the flow if it can
handling
SPILL: be done safely. Dike to prevent entry into sewer. Absorb with sand, place in a clean, dry,
closed container, and label.
storage
TRANSPORT: For transportation, no DOT-IMO hazardous warning label (diamond) is required.
For proper disposal methods and locations for chemical or chemical contaminated &
DISPOSAL: material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY
A minimum of personal protective equipment (PPE) is required to handle ethylene glycol,
unless it is heated above 100°C (212°F) in a confined area. Goggles or face shield and
disposal
EQUIPMENT: rubber or PVC gloves should be worn when handling quantities of this material. Control
mist concentrations below the TLV. APR or SCBA should be worn if conditions warrant.
Maintain an eyewash fountain and emergency shower where the material is stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardio-pulmonary resuscitation (CPR). Keep person warm and quiet.
EYE/SKIN Flush eyes with large amounts of water for at least 15 minutes. Lift eyelids occasionally.
CONTACT: Wash skin thoroughly with water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use. first aid
INGESTION: If conscious, drink three glasses of milk or water and induce vomiting at once. Keep
person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:4/8/2001
CHEMICAL HAZARD BULLETIN NO. 054
S/N 26-502-070 55-gallon Drum
DC1–4A
Corrosion
Inhibitor
handling,
indoors. DO NOT store in direct sunlight. Avoid storage near incompatible materials.
Always label containers for transporting.
Shut off sources of ignition. Stop the flow if it can be done safely. Spilled material
storage &
SPILLS/ LEAKS:
may make floor slippery. Dike to prevent entry into sewer; runoff may create
fire/explosion hazard. Absorb with sand and place in clean, dry, labeled containers.
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428. disposal
Provide ventilation to control overexposure and eye and skin contact. Safety goggles
SAFETY and neoprene gloves must be worn when handling this material. SCBA should be
EQUIPMENT: worn if conditions warrant. Maintain an eyewash fountain and emergency shower
where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If
breathing has stopped, give cardiopulmonary resuscitation (CPR). Keep person
warm and quiet.
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally.
CONTACT: Wash skin thoroughly with soap and water. Remove contaminated clothing and
shoes promptly, and wash clothing before re-use.
first aid
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can be fatal. Wash
out mouth thoroughly. Drink one-two glasses of water to dilute. Keep person warm
and quiet. Activated charcoal may be administered.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print:1/13/2001
CHEMICAL HAZARD BULLETIN NO. 56
Direct Charge
WF-1690
“Fludex”
Corrosion
Inhibitor
Health 2 DARK YELLOW LIQUID WITH ALCOHOLIC ODOR CAS: 7727-37-9
Fire 2 WATER SOLUBLE, MODERATELY FLAMMABLE UN: 1993
Reactivity 0 VAPOR IRRITATING TO EYES AND SKIN GUIDE: 128
VAPOR: This corrosion inhibitor is a solution of amines in water and methanol. There is no TLV for
the mixture: the TLV for methanol is 200 ppm. Irritation to eyes, nose and throat may
occur at level above 500 ppm. At levels above 1% by volume (10,000 ppm) this
compound may cause dizziness, headache, blindness and death. health
LIQUID: Splashed into eyes, may cause severe irritation. Prolonged or repeated skin exposure
may cause dry, cracked, reddened skin. Swallowing ½ cup of WF-1690 may cause
blindness or death.
hazards
WEAR GOGGLES AND GLOVES TO HANDLE WF-1690
FLUDEX (WF-1690) is moderately flammable with a flashpoint of 105oF (41oC). Vapor may explode if ignited in an
enclosed area: flash back along vapor trail may occur. Fludex is not reactive with water or other common
chemicals.
fire and
EXTINGUISH FIRES WITH FOAM, DRY CHEMICAL OR CO2 reactivity
USES: Water soluble corrosion inhibitor used in cooling systems. THIS MATERIAL IS NOT TO
BE USED IN DRINKING WATER WELLS.
STORAGE/
TRANSPORTATION:
Containers must be kept closed when not in use. Store in dry, well ventilated area
removed from ignition sources. For transportation, label packages with DOT-IMO class 3,
handling
SPILLS / LEAKS:
hazardous warning label (diamond); flammable liquid.
Dike with sand and absorb onto sand or vermiculite. storage
WASTE DISPOSAL: For proper disposal methods and locations, contact Environmental Engineering Division
on 874-6426 or 874-6248.
&
SAFETY
EQUIPMENT:
Handle WF-1690 in open air if possible. If used in enclosed space, chemical cartridge
respirator (S/N 21-370-400) should be worn. Wear gloves (S/N 21-432-576) and goggles disposal
(S/N 21-434-249) to use this corrosion inhibitor. Eye wash fountain should be located in
use area.
INHALED: Remove overcome victim into fresh air. If breathing stopped, give mouth-to-mouth
resuscitation.
EYE/SKIN: Hold eyelids open over eyewash fountain and flush with quantities of water. Remove
SWALLOED:
contaminated clothing and wash skin with soap and water. Launder clothes before reuse.
IF VICTIM IS CONSCIOUS, give quantities of water and INDUCE VOMITING. If victim is
first aid
UNCONSCIOUS and NOT BREATHING, give mouth-to-mouth resuscitation.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
*Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised 1/25/2003
CHEMICAL HAZARD BULLETIN NO. 58
1000183260 200 CU FT
HYDROGEN 1000183264 200 CU FT
(Compressed Gas)
LIQUID/ The product is > 99.5% hydrogen gas. There are no specific exposure limits for hydrogen,
GAS: but the gas is considered simple asphyxiants that can replace oxygen in breathing air.
Note: Oxygen levels should be maintained at or above 19.5%.
EFFECTS OF OVER-EXPOSURE:
health
INHALATION: The acute effect of this product is the inhalation of oxygen-deficient air. Symptoms include
headache, shortness of breath, wheezing, dizziness, nausea, and ringing in ears. At high
concentrations, unconsciousness or death may occur, where the victim skin becomes blue
color. No known adverse effects associated with chronic exposures.
hazards
EYE/ SKIN: No adverse health effects. However, due to rapid evaporation of the compressed product,
eye and skin frostbite can occur, causing blurred vision and white skin.
INGESTION: Unlikely route of exposure. No adverse health effects.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product is extremely flammable. Based on pure hydrogen the explosive range is between 4 to 75% in
air. Fire fighters must wear SCBA and protective clothing. Fires produce nitrogen oxides, and also toxic
gases, vapors, fumes, and smoke. Closed containers may rupture in fire conditions. Cool containers fire and
reactivity
exposed to flames with water spray until well after the fire is out.
REACTIVITY: Normally stable. Incompatible with: Heat, flames, sources of ignition and static discharges.
Strong oxidizers and acids.
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY/FOG, FOAM, OR CO2
USAGE: In power plant and refinery operations and processes. Avoid breathing gas and avoid eye
and skin contact. NO SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, label containers with DOT-IMO
Class 2.1 hazardous warning label (diamond): FLAMMABLE GASES, N.O.S.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and cold insulating gloves must be worn when handling this material. SCBA
(1000127427) should be worn if conditions warrant. Maintain an eyewash fountain and
emergency shower (1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 7/11/2004
CHEMICAL HAZARD BULLETIN NO. 60
health
INHALATION: Inhalation of vapor or mists irritates the respiratory tract. Elevated levels may cause
central nervous system (CNS) effects. Symptoms may include headache, dizziness,
nausea, vomiting, and weakness, loss of coordination, blurred vision, drowsiness,
confusion, or disorientation.
hazards
EYE/ SKIN: Eye contact may cause redness, lacrimation, severe irritation, and conjunctivitis. Skin
contact may cause ulceration, and sensitization dermatitis.
INGESTION: May cause severe gastrointestinal distress with nausea, vomiting, and diarrhea.
Aspiration into lungs may cause pulmonary oedema and chemical pneumonitis.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product flashpoint is >62°C (>144°F); no explosive limits were reported. Fire fighters must wear SCBA
and protective clothing. Fires produce carbon and nitrogen oxides, and also toxic gases, vapors, fumes,
and smoke. Closed containers may rupture in fire conditions. Cool containers exposed to flames with water fire and
reactivity
spray until well after the fire is out.
REACTIVITY: Normally Stable. Incompatible with: Strong oxidizers and acids. Heat and sources of ignition.
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY/FOG, FOAM, OR CO2
USAGE: Scale inhibitor in crude oil handling systems. Avoid breathing vapor and mists and avoid
eye and skin contact. NO SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, use DOT-IMO Class 4.2
hazardous warning labels (diamond): COMBUSTIBLE LIQUIDS
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and PVC gloves (1000129628) must be worn when handling this material.
APR (1000128213) or SCBA (1000127427) should be worn if conditions warrant.
Maintain an eyewash fountain and emergency shower (1000128433) where the material is
being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute BUT first obtain medical authorization. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 8/29/2004
CHEMICAL HAZARD BULLETIN NO.61
S/N 26-507-009 4 L bottle
ISOPROPYL 26-507-023 20 L can
26-507-108 208 L drum
ALCOHOL
ISOPROPANOL
RUBBING ALCOHOL
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:10/21/2001
CHEMICAL HAZARD BULLETIN NO. 71
1000185252 500 GM BT
PHENOL
Health 4 CAS: 108-95-2
COLORLESS TO LIGHT PINK LIQUID. SHARP, TANGY MEDICINAL
Fire 2 ODOR. EXTREMELY TOXIC, MODERATELY FLAMMABLE, SLIGHTLY UN: 2821
Reactivity 1 REACTIVE. POISONESS. CORROSIVE TO RESPIRATORY TRACT, GUIDE: 153
EYES, AND SKIN IRRITANT. SKIN NOTATION. EAC: 2X
LIQUID/VAPOR/ The product is > 99% pure phenol (TLV, Skin =5 ppm). Phenol is also known as
MISTS: carbolic acid, phenic acid, phenylic acid phenyl hydroxide, and hydroxybenzene.
monophenol, oxybenzene, , phenyl alcohol, phenylic alcohol.
EFFECTS OF OVER-EXPOSURE:
health
INHALATION: Irritates and burns the respiratory system. Corrosive to the mucous membranes and the
lungs. Other symptoms listed under ingestion may also occur.
hazards
EYE/ SKIN: Corrosive to eyes and skin. Causes eye burns with redness, pain, blurred vision may
occur. May cause severe damage and blindness. Rapidly absorbed through the skin
with systemic poisoning effects to follow. Discoloration and severe burns may occur.
May be fatal if absorbed thorough the skin.
INGESTION: Poison. Symptoms include burning pain in mouth and throat, abdominal pain, nausea,
vomiting, headache, dizziness, muscular weakness, central nervous system effects,
increase in heart rate, irregular breathing, coma, and possibly death. Acute exposure is
also associated with kidney and liver damage.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The flashpoint is 79°C (174°F); with an explosive range from 1.3 to 9.5% in air. Fire fighters must wear
SCBA and protective clothing. Fires produce carbon and nitrogen oxides, and also toxic gases, vapors,
fumes, and smoke. Closed containers may rupture in fire conditions. Cool containers exposed to flames fire and
reactivity
with water spray until well after the fire is out.
REACTIVITY: Normally stable, but may discolor in light. Incompatible with: Strong oxidizers and mineral
acids. Light, heat, flames, and sources of ignition.
EXTINGUISHING MEDIA: DRY CHEMICAL, CO2, ALCOHOL FOAM, WATER SPRAY
USAGE: Laboratory reagent. Avoid breathing vapor and mists and avoid eye and skin contact. NO
SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, label containers with DOT-IMO
Class 6.1 hazardous warning label (diamond): TOXIC (POISONOUS) LIQUID, N.O.S.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 and 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves and an apron
(1000128583) must be worn when handling this material. APR (1000128213) or SCBA
(1000127427) should be worn if conditions warrant. Maintain an eyewash fountain and
emergency shower (1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 7/11/2004
CHEMICAL HAZARD BULLETIN NO. 74
PERCHLORIC 1000185197 500 ML BT
ACID
Health 3 ODORLESS, CLEAR COLORLESS LIQUID. CAS: 7601-90-3
Fire 0 HIGHLY TOXIC. EXTREMELY REACTIVE. NON-FLAMMABLE. UN: 1873
Reactivity 4 CORROSIVE AND IRRITANT TO RESPIRATORY TRACT, EYES, GUIDE: 143
AND SKIN. EAC: 2P
MISTS/FUMES: Product is an assay of 69%-72% perchloric acid. No exposure limits are established.
EFFECTS OF OVER-EXPOSURE:
health
INHALATION: May cause severe irritation of the respiratory tract with sore throat, coughing, shortness
of breath and delayed lung edema. Prolonged or repeated inhalation may cause
nosebleeds, nasal congestion, erosion of the teeth, and perforation of the nasal
septum, chest pain and bronchitis.
hazards
EYE/ SKIN: Burns and may cause serious damage to eyes and skin. Prolonged or repeated eye
contact may cause conjunctivitis. Prolonged or repeated skin contact may cause
sensitization dermatitis and possible destruction and/or ulceration.
INGESTION: Gastrointestinal distress, nausea, vomiting, diarrhea, and abdominal pain. Chronic
ingestion may cause effects similar to those of acute ingestion.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product is not flammable or combustible. Fire fighters must wear SCBA and protective clothing. Fires
produce chloride dioxide which may be spontaneously explosive, nitrogen oxides, and also toxic gases,
vapors, fumes, and smoke. Closed containers may rupture in fire conditions. Cool containers exposed to fire and
reactivity
flames with water spray until well after the fire is out.
REACTIVITY: Combines vigorously with water with the evolution of heat. May undergo spontaneous and
explosive decomposition. This material is a strongly acidic, powerful oxidizing substance. The anhydrous
form of this material is an explosion hazard. Incompatible with: Organic and alkaline materials, wood, paper
heat, flames, and sources of ignition.
EXTINGUISHING MEDIA: WATER SPRAYS
USAGE: Laboratory reagent. Avoid breathing fumes and vapor avoid eye and skin contact. NO
SMOKING. Provide process enclosure and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions. Do
TRANSPORT: not freeze or store on a wooden floor. Shelves and floors should be non-combustible and
acid-resistant. Keep tightly closed when not in use. For transportation, label containers
with DOT-IMO Class 5.1 hazardous warning label (diamond): OXIDIZER (UNSTABLE).
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and nitrile (1000129636) or PVC (1000129492) gloves and an apron
(1000128583) must be worn when handling this material. APR (100012165) or SCBA
(1000127427) should be worn if conditions warrant. Maintain an eyewash fountain and
emergency shower (1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 8/17/2004
CHEMICAL HAZARD BULLETIN NO. 94B
1000184858 500-GM BT
OXALIC ACID
Health H2 CAS: 6153-56-6
WHITE, CRYSTALLINE POWDER WITH SLIGHT ODOR.
Fire F0 MODERATLEY TOXIC, NON-FLAMMABLE, AND STABLE. UN: 2449
Reactivity R0 CORROSIVE AND IRRITAN TO RESPIRATORY TRACT, EYES, GUIDE: 154
AND SKIN. EAC: N/A
DUST/MISTS: The product is an assay > 99% oxalic acid. No exposure limits have been established.
EFFECTS OF OVER-EXPOSURE:
health
INHALATION: Irritates nose, and throat. May cause inflammation of the respiratory system. Symptoms
include sore throat, coughing, headache, nausea, and difficultly breathing.
hazards
EYE/ SKIN: May cause serious irritation and damage to eyes. Skin contact may cause dryness,
cracking, irritation and dermatitis. Toxic amounts may be absorbed through the skin. May
be absorbed through skin.
INGESTION: Gastrointestinal distress, nausea, vomiting, diarrhea, and abdominal pain. May cause
central nervous system depression and liver and/or kidney damage.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product is not flammable or combustible. Fire fighters must wear SCBA and protective clothing. Fires
produce ammonia, carbon, and nitrogen oxides, and also toxic gases, vapors, fumes, and smoke. Closed
containers may rupture in fire conditions. Cool containers exposed to flames with water spray until well after fire and
reactivity
the fire is out.
REACTIVITY: Normally stable. Incompatible with strong oxidizers and acids. Heat, flames, and sources of
ignition.
EXTINGUISHING MEDIA: DRY CHEMICAL, ALCOHOL FOAM, WATER SPRAY
USAGE: Laboratory reagent. Avoid breathing dust and mists and avoid eye and skin contact. NO
SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, label containers with DOT-IMO
Class 6.1 hazardous warning label (diamond): TOXIC (POINSONOUS) SOLID, N.O.S.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 and 874-6676.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves and an apron
(1000128583) must be worn when handling this material. APR (1000128210) or SCBA
(1000127427) should be worn if conditions warrant. Maintain an eyewash fountain and
emergency shower (1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-4538 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 12/18/2004
CHEMICAL HAZARD BULLETIN NO. 94C
DUST/MISTS: The product is an assay > 99% sodium oxalate. Synonyms include disodium oxalate;
Ethanedioic acid, disodium salt.
EFFECTS OF OVER-EXPOSURE:
health
INHALATION: Irritation may lead to chemical pneumonitis and pulmonary edema. May cause severe
irritation of the upper respiratory tract with pain, burns, and inflammation. May cause
effects similar to those described for ingestion.
hazards
EYE/ SKIN: Contact may cause severe eye irritation and possible eye damage. May cause severe
skin irritation. May be absorbed through the skin.
INGESTION: Gastrointestinal distress, nausea, vomiting, diarrhea, and abdominal pain. May cause
central nervous system depression and kidney damage.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product is not flammable or combustible. Fire fighters must wear SCBA and protective clothing. Fires
produce ammonia, carbon, and nitrogen oxides, and also toxic gases, vapors, fumes, and smoke. Closed
containers may rupture in fire conditions. Cool containers exposed to flames with water spray until well after fire and
reactivity
the fire is out.
REACTIVITY: Normally stable. INCOMPATIBLE WITH: Strong oxidizers and acids. Heat, flames, and
sources of ignition.
EXTINGUISHING MEDIA: DRY CHEMICAL, ALCOHOL FOAM, WATER SPRAY
USAGE: Laboratory reagent. Avoid breathing dust and mists and avoid eye and skin contact. NO
SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, label containers with DOT-IMO
Class 6.1 hazardous warning label (diamond): TOXIC (POINSONOUS) SOLID, N.O.S.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 and 874-6676.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves and an apron
(1000128583) must be worn when handling this material. APR (1000128210) or SCBA
(1000127427) should be worn if conditions warrant. Maintain an eyewash fountain and
emergency shower (1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-4538 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 12/18/2004
CHEMICAL HAZARD BULLETIN NO. 94
MIST OR DUST: There is no TLV set for salts of oxalic acid; the TLV for oxalic acid is 1 mg/M3.
Solution, mist or dust irritates eyes. Continuous exposure causes chronic inflammation of
nose and throat.
SOLUTION: Solution of 5-10% are irritating with prolonged exposure. CORROSIVE TO SKIN, YES health
hazards
AND MUCOUS MEMBRANCES, frequent exposure may cause slow-healing ulcers.
Swallowed, acute oxalic acid poisoning results: swelling and corrosion of mouth, throat
and stomach, vomiting, abdominal pain, death may follow quickly. A DOSE OF 5 GRAMS
MAY BE FATAL.
handling
STORAGE: Keep in contains marked POISON: do not transfer to unmarked container. Do not store
near bleaching agents or chlorine cylinders.
SPILLS: Wear dust mask and rubber gloves to sweep up spilled ammonium oxalate crystals; wash
down area with water. Absorb solution into sand and cart to landfill site. Do not allow
storage
spilled material to enter waterway. Contact Environmental Engineering (874-6426 or 874-
6428) for disposal instructions. &
SAFETY
EQUIPMENT:
Wear chemical cartridge respirator (S/N 21-371-401) when handling ammonium oxalate.
Wear rubber gloves to handle oxalate solutions. EYEWASH FOUNTAINS MUST BE
disposal
MAINTAINED wherever chemicals are used or stored.
EYE/SKIN Hold eyelids open over eyewash fountain; wash skin thoroughly with water and soap.
CONTACT:
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
*Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised: 3/4/2003
CHEMICAL HAZARD BULLETIN NO. 104
CALCIUM S/N 26-236-023 500 gm bottle CaO
26-501-340 Bulk Delivery
HYDROXIDE 09-251-364 25 kg sack
SLAKED LIME 45-601-151 25 kg sack
INGESTION:
dryness and irritation
May cause gastro-intestinal upsets.
hazards
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
Neither calcium oxide nor calcium hydroxide is flammable, but calcium oxide may react violently with water or
humidity to ignite combustible materials. Calcium oxide also reacts violently with fluorine compounds and with
phosphorus pentoxide. Calcium hydroxide reacts violently with maleic anhydride and with nitro ethane, nitro
methane, nitro propane and nitro paraffins. Fire fighters must wear self-contained breathing apparatus (SCBA) and
full protective clothing.
fire and
REACTIVITY: Avoid contact with acids and nitroparaffins reactivity
EXTINGUISH FIRES WITH WATER SPRAY, CO2, DRY CHEMICAL OR FOAM
USES: Water treatment chemical and drilling mud additive.
STORAGE: Keep containers tightly sealed away from water and moisture. Calcium hydroxide reacts
with CO2 in air to form calcium carbonate, an insoluble and essentially non-toxic
compound. Store well removed from organics.
INHALATION: Remove those exposed to fresh air. If breathing is difficult administer oxygen. If breathing
has stopped, apply cardio-pulmonary resuscitation (CPR).
first aid
INGESTION: Give water to drink if conscious. Do not induce vomiting.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:2/21/2001
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:2/21/2001
CHEMICAL HAZARD BULLETIN NO. 106
HALLIBURTON 1000021939 55 GA DM
AF-61
Health 2 CAS: 064742-94-5
DARK BROWN SOLUTION WITH MUSTY ODOR.
Fire 2 MODERATELY TOXIC AND FLAMMABLE. STABLE. UN: 3082
Reactivity 0 IRRITANT TO THE RESPIRATORY TRACT, EYES, AND SKIN. GUIDE: 171
EAC: 2X
LIQUID/VAPOR/ The product is a proprietary formulation of 30-40% heavy aromatic naphtha. No
MISTS: exposure limits are established. It also contains naphthalene (TLV= 10 and IDLH=250
ppm).
EFFECTS OF OVER-EXPOSURE:
health
INHALATION: Inhalation of vapor or mists irritates the respiratory tract. Depresses the nervous
system. In high enough concentrations, may cause dizziness, headaches, breathing
difficulties, drowsiness, loss of consciousness.
hazards
EYE/ SKIN: Eye contact may cause redness and irritation. Skin contact may cause irritation.
Frequent or prolonged contact may defat and dry the skin, leading to discomfort and
dermatitis.
INGESTION: Can cause severe gastrointestinal distress, stomach pain, vomiting, and diarrhea.
Swallowed may be regurgitated and aspired into lungs causing pneumonia.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product flashpoint ranges from 68 to 79 °C (155-175 °F); explosive limits are 1.8 and 11.8% in air. Fire
fighters must wear SCBA and protective clothing. Fires produce carbon, sulfur, and nitrogen oxides, and
also toxic gases, vapors, fumes, and smoke. Closed containers may rupture in fire conditions. Cool fire and
reactivity
containers exposed to flames with water spray until well after the fire is out.
REACTIVITY: Normally stable. Incompatible with strong oxidizers, e.g., nitric acid. Heat, flames, and
sources of ignition.
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY/FOG, FOAM, OR CO2
USAGE: Emulsifier in drilling operations. Avoid breathing vapor and mists and avoid eye and skin
contact. NO SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, use DOT-IMO Class 9 hazardous
warning labels (diamond) HAZARDOUS SUBSTANCES, LIQUID
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810), PVC gloves (1000129492) must be worn when handling this material.
APR”O” (1000128213) or SCBA (1000127427) should be worn if conditions warrant.
Maintain an eyewash fountain and emergency shower (1000128433) where the material is
being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 10/23/2004
CHEMICAL HAZARD BULLETIN NO. 108
SURFLO B-17 S/N 45-601-027 55-GL DM
LIQUID/VAPOR/ The product is a proprietary formulation of 85% formaldehyde (Skin, TLV, C=0.3ppm)
MISTS: and amines.
EFFECTS OF OVER-EXPOSURE:
health
INHALATION: Very toxic by Inhalation of vapor and mists is corrosive to the mucous membranes and
upper respiratory tract. May damage kidneys, probable human carcinogen, and may
cause heritable genetic damage.
hazards
EYE/ SKIN: Eye contact may cause redness, severe irritation, and blurred vision. Higher
concentrations or splashes may cause irreversible eye damage. Skin contact may
cause redness, pain, and possibly burns. Formaldehyde is a severe skin irritant and
sensitizer. Skin absorption may occur with symptoms paralleling those from ingestion.
INGESTION: Cause severe gastrointestinal distress, vomiting, and diarrhea. May be fatal or cause
blindness if swallowed.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The flashpoint is 26°C (79°F); no explosive range was reported. Explosive range for formaldehyde is 7 to
73%. Fire fighters must wear SCBA and protective clothing. Fire produce carbon, chromium, and nitrogen
oxides, and also toxic gases, vapors, fumes, and smoke. Closed containers may rupture in fire conditions. fire and
reactivity
Cool containers exposed to flames with water spray until well after the fire is out.
REACTIVITY: Can polymerize spontaneously. Incompatible with strong bases, strong acids, strong
oxidizing agents, aniline, phenol, isocyanates, anhydrides. Heat, flames, and sources of ignition.
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY/FOG, FOAM, OR CO2
USAGE: Bactericide reagent. Avoid breathing vapor and mists and avoid eye and skin contact. NO
SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, use DOT-IMO Classes 3 and 8,
hazardous warning labels (diamond): FLAMMABLE, CORROSIVE LIQUID, N.O.S.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves and an apron
(1000128583) must be worn when handling this material. APR”O” (1000128213/163) or
SCBA (1000127427) should be worn if conditions warrant. Maintain an eyewash fountain
and emergency shower (1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 873-8291 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 12/5/2004
CHEMICAL HAZARD BULLETIN NO. 112
1000022028 50 KG BG
GUAR GUM
SOLID/DUST: The product is 99.9% guar gum (galactomannan), and 0.1% other salts. No exposure
limits were reported. It may be considered nuisance dust (TLV=10 mg/m3).
EFFECTS OF OVER-EXPOSURE:
health
INHALATION: Inhalation of chromate dusts may cause mild irritation to the respiratory tract. High
airborne concentrations can cause sneezing and may result in mild allergic reaction.
hazards
EYE/ SKIN: Eye and skin contact may cause mild irritation.
INGESTION: Can cause gastrointestinal distress, stomach pain, vomiting, and diarrhea.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product is not flammable or combustible. Fire fighters must wear SCBA and protective clothing. Fires
produce carbon and nitrogen oxides, and also toxic gases, vapors, fumes, and smoke. Closed containers
may rupture in fire conditions. Cool containers exposed to flames with water spray until well after the fire is fire and
reactivity
out.
REACTIVITY: Normally stable. Incompatible with strong oxidizers, e.g., nitric acid. Heat and sources of
ignition.
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY/FOG, FOAM, OR CO2
USAGE: Gelling reagent or water absorbent in fracturing processes. Avoid breathing dust and
avoid eye and skin contact. NO SMOKING. Provide adequate and local exhaust
ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, the product is not regulated and
does not require hazardous warning labels.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene gloves (1000129418) must be worn when handling this
material. APR”O” (1000128213) or SCBA (1000127427) should be worn if conditions
warrant. Maintain an eyewash fountain and emergency shower (1000128433) where the
material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 10/23/2004
CHEMICAL HAZARD BULLETIN NO. 116
VAPOR: The Threshold Limit Value (STEL) of potassium hydroxide is 2 milligrams per cubic
meter of air. This is a “ceiling” limit which may not be exceeded even for short periods.
Potassium hydroxide is a powerful caustic. The Kodak chemical is 10% KOH and the pH
is 13.6 in confined spaces, vapors from the Kodak developer could irritate eye, nose and
LIQUID OR
throat.
Potassium hydroxide is nonflammable but EXPLOSIVE ON CONTACT WITH GASEOUS CIO2 AND POTASSIUM
PEROXODISULFATE. Potassium hydroxide may also react violently with tetrahydrofuran, a cement for PVC pipes.
Contact with metals produces hydrogen gas, a further explosive hazard. Kodak developer has no flashpoint and is
fire and
non-combustible; may react violently with strong acids. Water is the preferred extinguishing agent, but care should
be taken to avoid splashing or spattering. reactivity
USES: Laboratory reagent and color photograph developer, alkaline battery electrolyte.
STORAGE: Lye should be kept in tightly sealed non-corroded containers. Kodak chemicals should be
kept in air-conditioned storage. handling
SPILLS: Wear chemical goggles and protective clothing to clean up lye materials. Shovel solids
into waste container, adsorb Kodak chemical into sand. Contact Environmental
storage
Engineering (874-6426 or 874-6428) for disposal procedure. &
SAFETY
EQUIPMENT:
Wear chemical goggles (S/N 21-434-249) wherever lye is used. Wear rubber or neoprene
gloves, apron and boots when skin contact is possible. Maintain eyewash fountain (S/N disposal
21-333-573) and chemical shower (S/N 21-372-365) wherever caustic potash or alkaline
electrolyte is handled.
EYE CONTACT: Hold lids open over eyewash fountain for 15 minutes continuous. Seek medical attention.
SKIN CONTACT: Remove splashed clothes and wash skin with soap and water.
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
*Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised: 3/4/2003
CHEMICAL HAZARD BULLETIN NO. 131
S/N 26-000-195
VEZ D-13
Tretolite
Antifoam
EFFECTS OF OVEREXPOSURE:
EYE/SKIN: Eyes, nose and throat will be irritated if vapor levels build up in confined spaces.
Splashed into eyes, will be very irritating. Skin exposed to clothing soaked in VEZ D-13
becomes reddened and cracked: may absorb through skin.
health
INHALATION: Irritating to nose and throat.
hazards
INGESTION: Swallowed, large quantities will poison: vomited fluid aspirated into lungs may be fatal.
STORAGE: Keep container tightly closed. Store in a well-ventilated area. Empty containers may be
hazardous due to retained vapor or liquid. Separate VEZ D-13 from oxidizing materials, handling
SPILLS/LEAKS: Cover with sand or dirt. Pick up and place in suitable container.
storage
DISPOSAL: For proper disposal methods and locations for chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428. &
SAFETY
EQUIPMENT:
Neoprene gloves (S/N 21-432-080), apron (S/N 21-404-181) and goggles (S/N 21-434-
249) should be worn to handle VEZ D-13. Eyewash fountain and emergency shower must
disposal
be maintained in chemical storage area.
EYE/SKIN Flush eyes with large amounts of water for 15 minutes keeping eyelids open. Wash skin
CONTACT: thoroughly with soap and water. Remove contaminated clothing and shoes promptly and
launder clothing before re-use. first aid
INGESTION: DO NOT INDUCE VOMITING. Give one-two glasses water to dilute IF VICTIM IS
CONSCIOUS.
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:10/21/2001
CHEMICAL HAZARD BULLETIN NO. 143
S/N 26-493-661 500 ml bottle
HYDROGEN
PEROXIDE
“Super Oxol”
Hydrogen Dioxide
LIQUID: The Threshold Limit Value (TLV) of hydrogen peroxide is 1 ppm (part per million parts of
air).
EFFECTS OF OVEREXPOSURE:
EYE/SKIN: Corrosive irritant to skin, eyes and mucous membranes. Can cause irreversible damage health
to eyes. May blister skin if contaminant is not removed.
INHALATION: Extremely irritating to nose, throat and respiratory tract. Levels of 100 ppm cause fatal
hazards
pulmonary edema.
INGESTION: Swallowed, is corrosive to mouth, throat and stomach.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
Hydrogen peroxide is not a flammable liquid, but contributes to the propagation of a fire through release of oxygen.
Fire fighters should wear Scott Air Pak (S/N 21-311-231).
REACTIVITY: POWERFUL OXIDIZER: Contamination with metal or dust causes rapid decomposition, generating fire and
large quantities of oxygen gas and high pressures. Container may explode in a fire. Contact with glycerin,
hydrazine, alcohol, heavy metallic dusts, oxides, grain powder, cotton, wool, wood dusts, carbon, oil, resins,
organic acids, ketones, aldehydes can result in fire or an explosion. Contact with combustible material may cause
reactivity
a fire.
EXTINGUISH FIRES WITH FLOODS OF WATER
USES: Bleaching, laboratory oxidizer, disinfectant, fungicide.
STORAGE: Separate from combustible materials or any of the above incompatible chemicals. Store in
SPILL:
cool, well-ventilated fire resistant area. PROTECT AGAINST SUNLIGHT.
Dilute and drain into sewer with abundant water. AVOID SPLASHING ON HANDS, EYES
handling
OR CLOTHING.
DISPOSAL: For proper disposal methods and locations for chemical or chemical contaminated
storage
material, contact the Environmental Engineering Division at 874-6426 or 874-6428. &
SAFETY
EQUIPMENT:
Use under chemical hood if possible. If ventilation is inadequate, wear chemical cartridge
(S/N 21-371-401). Always wear goggles (S/N 21-434-249), neoprene gloves (S/N 21- disposal
432-570), and apron. Maintain eyewash fountain and emergency shower wherever
hydrogen peroxide is used or stored.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Remove victim to fresh air. If breathing is difficult, administer oxygen. If breathing has
stopped, give cardiopulmonary resuscitation (CPR).
EYE/SKIN ACT FAST! Flush eyes with large amounts of water for 15 minutes keeping eyelids open.
CONTACT: Wash skin thoroughly with soap and water. Remove contaminated clothing and shoes
promptly. Treat skin for burns.
first aid
INGESTION: Induce vomiting. Drink one-two glasses of water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:1/13/2001
CHEMICAL HAZARD BULLETIN NO. 144
DIETHYLENE S/N 26-306-273 235 kg. Drum
GLYCOL 26-922-105 55 gal. Drum
TRIETHYLENE 26-922-110 Bulk delivery
GLYCOL
Diglycol, Triglycol
Antifreeze
EFFECTS OF OVEREXPOSURE:
EYE/SKIN: May be irritating to skin and eyes.
INHALATION: Both diethylene and triethylene glycol are non-volatile at normal temperatures, and toxic health
concentrations of vapor will not occur. Inhalation hazards to either glycol may exist only
from repeated prolonged exposure to operations where the materials are heated or mists
and fogs generated.
hazards
INGESTION: Liver and Kidney damage may result if repeated doses of diethylene glycol or triethylene
glycol is swallowed.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
o o
Neither glycol is considered a flammable liquid. The flashpoint of diethylene glycol is 138 C (280 F) and of
o o
triethylene glycol is 165 C (330 F). Chemically, both are stable, presenting a hazard only at high temperatures or
where mist is generated.
fire and
REACTIVITY: Avoid contact with strong oxidizers.
EXTINGUISH FIRES WITH DRY CHEMICAL, CO2, FOAM, OR WATER SPRAY
reactivity
USES: Both are used for antifreeze solutions, petroleum-refining solvents, Triethylene glycol is
also used as an air-disinfectant in hospital air conditioning systems.
STORAGE: Store in a cool, dry, ventilated area away from heat sources and incompatible materials.
Keep container tightly closed and protect from damage.
SPILL: Dike a spill with sand and absorb into sand.
TRANSPORT: For transportation, packages do not require DOT-IMO hazardous warning label
(diamond).
handling
DISPOSAL: For proper disposal methods and locations for chemical or chemical contaminated
storage
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
&
SAFETY Provide adequate ventilation. Wear PVA gloves (S/N 21-432-624) and safety goggles
EQUIPMENT: (S/N 21-434-249) if splashing is likely. Maintain eyewash fountain and emergency
shower wherever chemicals are stored or handled.
disposal
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardio pulmonary resuscitation (CPR). Keep person warm and quiet,
EYE/SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly, first aid
and wash clothing before re-use.
INGESTION: Induce vomiting. Keep person warm and quiet.
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:7/2/2001
CHEMICAL HAZARD BULLETIN NO. 149
S/N 26-494-865 100 gm bottle
HYDROXYLAMINE
HYDROCHLORIDE
(Hydroxyl Ammonium
Chloride)
CRYSTALS OR There is no Threshold Limit Value set for this salt or for hydroxylamine. Solid crystalline
SOLUTION: material. It’s an inhalation and skin hazard. Extremely corrosive to mucous membranes
and respiratory tract.
Hydroxylamine hydrochloride is a salt of hydroxylamine, an unstable chemical which explodes at 129oC (265oF) or
when heated over flame in a test tube. This hydrochloride salt has no flashpoint but decomposes releasing
hydrogen chloride gas.
fire and
Fire fighters should wear SCBAs.
EXTINGUISH FIRES WITH WATER SPRAY OR FOG reactivity
USES: As a reducing agent in photography: antioxidant for fatty acids and soaps.
STORAGE: KEEP CONTAINERS TIGHTLY CLOSED. Store in cool, dark area well removed from
ignition sources or strong acids or oxidizing agents.
handling
SPILLS: Wear goggles and gloves to clean spill. Scrape up solid material, mix with sodium
bisulfate, dilute with quantities of water and pour into sewer. storage
DISPOSAL; For proper disposal methods and locations for chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
&
SAFETY Wear rubber or neoprene gloves (S/N 21-432-080), goggles (S/N 21-434-249) and apron disposal
EQUIPMENT: (S/N 21-404-181) to handle hydroxylamine hydrochloride. Maintain eyewash fountain and
emergency shower wherever chemicals are used or stored.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardio--pulmonary resuscitation (CPR). Keep person warm and quiet.
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
first aid
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly
and wash clothing before re-use.
INGESTION: Don’t induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. If conscious, give large quantity of water to dilute. Keep
person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:7/2/2001
CHEMICAL HAZARD BULLETIN NO. 150
S/N 26-850-690 500 gm bottle
SODIUM
SULFIDE
Sodium Monosulfide
Sodium Sulfret
SOLID CRYSTALS There is no Threshold Limit Value established for solid sodium sulfide. Exposure of the
OR SOLUTION: crystals to air or strong acids liberates very toxic hydrogen sulfide gas, with a TLV of 10
ppm (parts per million gas in air). Crystals absorb water rapidly from the air; dissolve
readily in water. Aqueous solutions are strongly alkaline.
REACTIVITY: Unstable: may explode on percussion, friction or rapid heating contact with acids produces
fire and
hydrogen sulfide gas. Sodium sulfide reacts violently with carbon, diazonium salts, and dichloromethylamine.
reactivity
EXTINGUISH FIRES WITH DRY CHEMICAL, CO2, WATER SPRAY OR FOG
USES: Laboratory reducing agent.
STORAGE: Keep well closed and in a cool dark place, Do not handle with bare hands. Keep away
from oxidizers, acids, heat, sparks and open flame. Protect containers from physical
damage.
SPILLS: Wear goggles, chemical resistant gloves and apron to clean spill; wear air-supplied
respirator in confined space. Sweep up carefully to avoid raising dust and place in handling
suitable container for disposal.
DISPOSAL: For proper disposal methods and locations for chemical or chemical contaminated
storage
SAFETY
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
Wear air-supplied respirator (S/N 21-330-347) to handle in confined spaces and poorly &
EQUIPMENT: ventilated space. Always wear goggles (S/N 21-434-249) and gloves (S/N 21-432-080) to
handle sodium sulfide. In laboratories, use in chemical fume hoods. Maintain eyewash
fountain and emergency fountain wherever used or stored.
disposal
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move victim into fresh air. If breathing is difficult, administer oxygen. If breathing has
stopped, give cardiopulmonary resuscitation (CPR).
EYE/SKIN Flush eyes with large amounts of water for 15 minutes keeping eyelids open. Wash skin
CONTACT: thoroughly with soap and water. Remove contaminated clothing and shoes promptly. first aid
INGESTION: Do not induce vomiting. If victim is conscious, wash out mouth with water and give water
(or milk IF AVAILABLE).
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:1/13/2001
CHEMICAL HAZARD BULLETIN NO. 159
IODINE 1000183803 0.25 LB BT
DUST/ A proprietary product of aqueous solution of 20-40% zinc phosphate (TLV-STEL and
VAPORS: TLV, Ceiling= 0.1 ppm). Iodine sublimes at room temperature and exposure to the vapor
is very harmful.
EFFECTS OF OVER-EXPOSURE:
health
INHALATION: May irritate the respiratory tract; corrosive to the mucous membranes and the lungs.
Chronic exposure may cause insomnia, conjunctivitis, inflammation of the nasal
mucous, bronchitis, tremor, rapid heart beat, diarrhea, and weight loss.
hazards
EYE/ SKIN: Corrosive! Vapors are severely irritating and may cause damage to the eyes and skin.
Contact may cause severe burns and permanent eye damage. Allergic sensitization of
skin may occur. Iodine may be absorbed through skin.
INGESTION: Gastrointestinal distress, nausea, vomiting, diarrhea, and abdominal pain. Can be fatal.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
Iodine is not flammable or combustible. Fire fighters must wear SCBA and protective clothing. Fires
produce hydrogen fluoride, ammonia, and nitrogen oxides, and also toxic gases, vapors, fumes, and smoke.
Closed containers may rupture in fire conditions. Cool containers exposed to flames with water spray until fire and
reactivity
well after the fire is out. Iodine is a strong oxidizer and its heat of reaction with reducing agents or
combustibles may cause ignition.
REACTIVITY: Sublimes slightly at room temperature. Incompatible with: ammonia, powdered metals, alkali
metals, or strong reducing agents. Reaction can be violent or explosive with acetaldehyde and acetylene.
Reacts with ammonium hydroxide to form shock-sensitive iodides on drying.
EXTINGUISHING MEDIA: DRY CHEMICAL, ALCOHOL-RESISTANT FOAM, CO2, WATER SPRAY.
USAGE: Laboratory reagent. Avoid breathing dust and vapors and avoid eye and skin contact. NO
SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, iodine is not regulated, and no
DOT-IMO labels are required. Yet, packages shall be labeled as TOXIC, N.O.S.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and nitrile (1000129636) or PVC (1000129492) gloves and an apron
(1000128583) must be worn when handling this material. SCBA (1000127427) should be
worn if conditions warrant. Maintain an eyewash fountain and emergency shower
(1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 7/11/2004
CHEMICAL HAZARD BULLETIN NO. 166
1000185194 5 GA CN
PENTANE
LIQUID/ Product is liquid pentane (TLV=600 ppm). Synonyms are Normal Pentane or n-Pentane,
VAPOR: and Amyl hydride.
EFFECTS OF OVER-EXPOSURE:
health
INHALATION: Inhalation may irritate the respiratory system, and may cause drowsiness and dizziness.
Pentane may cause damage to the central nervous system (CNS). Vapors have a mild
narcotic effect. Inhalation of high concentrations may cause unconsciousness and death.
hazards
EYE/ SKIN: May cause eye, redness and pain. Skin contact may cause irritation, dryness, cracking or
dehydration and deffating. Toxic amounts may be absorbed through the skin.
INGESTION: Gastrointestinal distress, nausea and omitting. When swallowed, it tends to aspire into the
lungs. The result can be reduced oxygen content with asphyxia and consequent brain
damage or cardiac arrest.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The flashpoint is -49 °C (-56°F); with an explosive range between 1.4 to 7.8%. Vapor may cause flash fires.
Fire fighters must wear SCBA and protective clothing. Fires produce carbon and nitrogen oxides, and also
toxic gases, vapors, fumes, and smoke. Closed containers may rupture in fire conditions. Cool containers fire and
reactivity
exposed to flames with water spray until well after the fire is out. Vapor explosion hazard exists indoors,
outdoors, or in sewers.
REACTIVITY: Normally stable. Incompatible with: Sparks, flames, hot surfaces, and sources of ignition.
Strong oxidizers and acids.
EXTINGUISHING MEDIA: DRY CHEMICAL, FOAM, OR CO2
USAGE: Demulsifier in crude oil operations. Avoid breathing vapors and avoid eye and skin
contact. NO SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, bond, ground, and label,
containers with DOT-IMO Class 3 hazardous warning label (diamond): FLAMMABLE
LIQUID, N.O.S.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 873-6676.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) and an apron (1000128583) must be worn
when handling this material. SCBA (1000127427) should be worn if conditions warrant.
Maintain an eyewash fountain and emergency shower (1000128433) where the material is
being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-4538 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 3/24/2004
CHEMICAL HAZARD BULLETIN NO. 169
Routes of Exposure:
STORAGE: Store in a cool dry place and keep container tightly closed. Do not store in close
proximity to incompatible materials.
TRANSPORT: For transportation, packages do not require DOT-IMO hazardous warning label handling
storage
(diamond).
SPILLS/ LEAKS: Absorb onto sand or vermiculite and place in closed container for disposal.
SKIN/EYE Flush eyes with copious amounts of water for at least 15 minutes holding eyelids apart.
CONTACT: Call a physician. Remove contaminated clothing and shoes. Wash skin thoroughly with
soap and water. Launder clothing before reuse. first aid
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can be fatal. Wash out
mouth thoroughly. Drink one-two glasses of water to dilute. Keep person warm and
quiet. Activated charcoal may be administered.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
*Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised: 10/27/2002
CHEMICAL HAZARD BULLETIN NO. 170
S/N 26-454-570 4 liter can
GLYCEROL 26-454-579 200 liter drum
(Glycerin)
DUST/ LIQUID: Threshold Limit Value TLV= 10 mg/m3. and Respirable fraction= 5 mg/m3.
Very low volatility; this material will not be an inhalation problem from vapor.
EYE/ SKIN:
EFFECTS OF OVER EXPOSURE:
If glycerol is stirred violently or highly agitated in some operation, a mist is given off which
is irritating to eyes, skin, throat and lungs.
health
INHALATION: Mist cause irritation of respiratory tract.
hazards
INGESTION: If swallowed, low toxicity Cause nausea, headache, and diarrhea.
Chronic exposures cause kidney injury.
WEAR RESPIRATOR WHERE GLYCEROL MIST IS GENERATED
Glycerol or glycerin is a slight fire hazard. It will burn when exposed to heat, flame or powerful oxidizers. The
fire and
o o o
flashpoint is 160 C (320 F), density is 1.26 at 20 C, vapor pressure is 0.0025 mm at 50oC, vapor density 3.17.
Toxic gases and vapors will release in fire and Form corrosive gases (acrolein).
Fire fighter must wear Scott Air Pak (S/N 21-311-231).
REACTIVITY: Strong Oxidizers; react violently with acetic anhydride, calcium oxychloride, chromium oxides &
alkali metal hydrides. Avoid: heat, flames & ignition sources.
reactivity
EXTINGUISH FIRES WITH ALCOHOL FOAM, DRY CHEMICAL OR CO2
INGESTION:
PHYSICIAN. BE SURE THE DOCTOR Know EXPOSURE TO GLYCEROL MIST.
Get Medical Attention immediately.
first aid
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
*Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised 10/27/2002
ﻥﺸﺮة أﺥﻄﺎر اﻟﻤﻮاد اﻟﻜﻴﻤﻴﺎﺋﻴﺔ رﻗﻢ ١٧٣
اﻟﺼﺤﺔ ٢ ﻣﺎدة ﺳﺎﺋﻠﺔ ﻟﺰﺟﺔ ﺻﻔﺮاء ،ﺗﺤﻮي %١٠ﻣﻦ ﻣﺴﺠﻞ ﺧﺪﻣﺎت اﻟﺘﺠﺮﻳﺪ اﻟﻜﻴﻤﻴﺎﺋﻲ٨-٩١-١١٠ :
اﻟﻤﻮرﻓﻮﻟﻴﻦ ،وﻟﻬﺎ راﺋﺤﺔ ﻣﻤﻴﺰة ﺗﺸﺎﺑﻪ راﺋﺤﺔ اﻟﻤﻮاد
اﻻﺷﺘﻌﺎل ١ ﺕﺼﻨﻴﻒ اﻷﻣﻢ اﻟﻤﺘﺤﺪة٢٠٥٤ :
اﻟﺒﺘﺮوﻟﻴﺔ.
اﻟﺘﻔﺎﻋﻞ ١ اﻟﺪﻟﻴﻞ :ﻻ ﻳﻮﺝﺪ
ﻣﻦ ﻏﻴﺮ اﻟﻤﺤﺘﻤﻞ أن ﺕﻨﺘﺸﺮ هﺬﻩ اﻟﻤﺎدة ﻓﻲ اﻟﻬﻮاء ،وﻣﻊ ذﻟﻚ ﻓﺈن ﺡﺪ اﻟﺘﻌﺮض اﻟﻤﺴﻤﻮح ﺑﻪ ﻟﺰذاذ/أﺑﺨﺮة اﻟﻤﺎدة اﻟﻤﺸﺘﻤﻠﺔ ﻋﻠﻰ اﻟﺒﺨﺎر/اﻟﺮذاذ
%١٠ﻣﻦ اﻟﻤﻮرﻓﻮﻟﻴﻦ هﻮ ٢٠ﺝﺰءًا ﻣﻦ اﻟﻤﻠﻴﻮن ﻓﻲ ﺛﻤﺎﻥﻲ ) (٨ﺱﺎﻋﺎت .أﻣﺎ ﺡﺪ اﻟﺘﻌﺮض اﻟﻤﺴﻤﻮح ﺑﻪ ﻋﻠﻰ اﻟﻤﺪى اﻟﻘﺼﻴﺮ اﻟﺴﺎﺋﻞ:
ﻓﻲ ﺡﺎﻻت اﻟﺘﻌﺮض ﻟﻔﺘﺮات ﻗﺼﻴﺮة ﻓﻬﻮ ٣٠ﺝﺰءًا ﻣﻦ اﻟﻤﻠﻴﻮن.
ﺁﺛﺎر اﻟﺘﻌﺮض اﻟﺰاﺋﺪ:
اﻟﻤﺨﺎﻃﺮ ﺕﺴﺒﺐ ﺕﻬﻴﺠًﺎ ﺵﺪﻳﺪًا ﻟﻠﻌﻴﻨﻴﻦ ،ﻣﻤﺎ ﻗﺪ ﻳﺆدي إﻟﻰ اﻹﺹﺎﺑﺔ ﺑﻐﺸﺎوة اﻟﺒﺼﺮ .إﻣﺎ إذا ﻻﻣﺴﺖ اﻟﺠﻠﺪ ،ﻓﻴﻨﺘﺞ ﻋﻦ ذﻟﻚ اﻟﺸﻌﻮر ﺑﺎﻟﺤﻜﺔ اﻟﻌﻴﻨﻴﻦ/اﻟﺠﻠﺪ:
وﻳﺼﺎب اﻟﻤﻮﺿﻊ اﻟﻤﺼﺎب ﻣﻦ اﻟﺠﻠﺪ ﺑﺎﻻﺡﻤﺮار وﻳﻨﻜﻤﺶ وﻳﺼﺒﺢ ﺝﺎﻓًﺎ .ﻳﻤﻜﻦ ﻟﻠﺠﻠﺪ اﻣﺘﺼﺎص ﻣﺎدة اﻟﻤﻮرﻓﻮﻟﻴﻦ ،ﻣﻤﺎ ﻳﺆدي
اﻟﺼﺤﻴﺔ إﻟﻰ اﻹﺹﺎﺑﺔ ﺑﺎﻟﻨﻮام واﻟﺮﻋﺸﺔ وﻳﺴﻴﻞ اﻟﻠﻌﺎب ﺑﻐﺰارة .هﺬﻩ اﻟﻤﺎدة ﻏﻴﺮ ﻣﺴﺮﻃﻨﺔ.
اﺱﺘﻨﺸﺎق اﻟﻤﺎدة ﻳﺆدي إﻟﻰ ﺕﻬﻴﺞ اﻷﻥﻒ واﻟﺤﻨﺠﺮة وﻣﺠﺮى اﻟﻬﻮاء ﻓﻲ اﻟﺮﺋﺘﻴﻦ ،آﻤﺎ ﻳﺆدي إﻟﻰ اﻟﺪوار واﻟﺼﺪاع واﻟﻐﺜﻴﺎن. اﻻﺱﺘﻨﺸﺎق:
ﻋﻨﺪ اﺑﺘﻼﻋﻬﺎ ﺕﻜﻮن أآﺎﻟﺔ ﻟﻠﺠﻬﺎز ﻣﻌﻮي ﺑﻜﺎﻣﻠﻪ. اﻻﺏﺘﻼع:
اﺱﺘﻌﻤﻞ اﻟﻨﻈﺎرات اﻟﻮاﻗﻴﺔ واﻟﻘﻔﺎزات اﻟﻤﻄﺎﻃﻴﺔ ﻋﻨﺪ ﻣﻨﺎوﻟﺔ هﺬﻩ اﻟﻤﺎدة
هﺬﻩ اﻟﻤﺎدةﻗﻠﻴﻠﺔ اﻟﻘﺎﺑﻠﻴﻪ ﻟﻼﺵﺘﻌﺎل .ﻥﻘﻄﺔ اﻟﻮﻣﻴﺾ ﺕﺰﻳﺪ ﻋﻦ ١٠٠درﺝﺔ ﻣﺌﻮﻳﺔ ،وهﻲ ﺱﺮﻳﻌﺔ اﻟﺬوﺑﺎن ﻓﻲ اﻟﻤﺎء .وإذا ﻣﺎ ﺕﺤﻠﻠﺖ ﺑﺴﺒﺐ اﻟﺤﺮارة ﻓﺈﻥﻬﺎ
ﺕﻮﻟﺪ أآﺴﻴﺪات اﻟﻜﺮﺑﻮن وﺛﺎﻥﻲ أآﺴﻴﺪ اﻟﻜﺮﺑﻮن وأول أآﺴﻴﺪ اﻟﻜﺮﺑﻮن .ﻋﻠﻰ رﺝﺎل اﻹﻃﻔﺎء اﺱﺘﺨﺪام أﺝﻬﺰة اﻟﺘﻨﻔﺲ اﻟﻤﺴﺘﻘﻞ ﺱﻜﻮت )رﻗﻢ اﻟﺘﺨﺰﻳﻦ -٢١
اﻟﺤﺮیﻖ .(٢٣١-٣١١وﻳﻼﺡﻆ أن اﻟﻤﺎء ﻻ ﻳﻤﻜﻦ اﺱﺘﻌﻤﺎﻟﻪ ﻹﻃﻔﺎء ﺡﺮاﺋﻖ هﺬﻩ اﻟﻤﺎدة.
واﻟﺘﻔﺎﻋﻞ اﻟﺘﻔﺎﻋﻞ :ﺕﺘﻔﺎﻋﻞ اﻟﻤﺎدﻩ ﻣﻊ اﻟﻌﻮاﻣﻞ اﻟﻤﺆآﺴﺪة اﻟﺸﺪﻳﺪة.
وﺱﺎﺋﻞ اﻻﻃﻔﺎء :اﻟﺮﻏﻮة أو ﺛﺎﻥﻲ أآﺴﻴﺪ اﻟﻜﺮﺏﻮن أو اﻟﻤﻮاد اﻟﻜﻴﻤﻴﺎﺋﻴﺔ اﻟﺠﺎﻓﺔ
ﺕﺴﺘﻌﻤﻞ آﻤﺎﻥﻊ ﻟﺘﻜﻮن اﻟﻘﺸﻮر وﺕﺴﺘﺨﺪم ﻓﻲ ﻣﻌﺎﻟﺠﺔ ﻣﻴﺎﻩ اﻟﻐﻼﻳﺎت .ﺕﺠﻨﺐ ﻣﻼﻣﺴﺔ اﻟﻤﺎدة ﻟﻠﺠﻠﺪ. اﻻﺱﺘﻌﻤﺎل:
اﻟﻤﻨﺎوﻟﺔ اﻟﻤﺎدة ﻗﻠﻮﻳﺔ .ﻻ ﺕﺨﺰن ﻗﺮب اﻟﻤﻮاد اﻟﺤﻤﻀﻴﺔ .ﺕﺨﺰن ﻓﻲ ﻣﻜﺎن ﺝﻴﺪ اﻟﺘﻬﻮﻳﺔ. اﻟﺘﺨﺰیﻦ:
واﻟﺘﺨﺰیﻦ ﺿﻊ ﺑﻄﺎﻗﺔ اﻟﺘﻌﺮﻳﻒ اﻟﺨﺎﺹﻪ ﺑﺎﻟﻤﺎدﻩ ﻟﻠﺘﺤﺬﻳﺮ ﻣﻦ اﻟﺨﻄﺮ ﻋﻠﻰ ﺑﺮاﻣﻴﻞ وﺡﺎوﻳﺎﺕﻬﺎ. اﻟﻨﻘﻞ:
وإﺝﺮاءات ﺕﻄﻮق اﻟﻤﺎدة اﻟﻤﻨﺴﻜﺒﺔ وﻳﺴﺘﻌﻤﻞ اﻟﺮﻣﻞ أو ﻏﻴﺮﻩ ﻣﻦ اﻟﻤﻮاد اﻟﻤﻨﺎﺱﺒﺔ ﻻﻣﺘﺼﺎﺹﻬﺎ .اﺕﺼﻞ ﺑﻘﺴﻢ هﻨﺪﺱﺔ اﻟﺒﻴﺌﺔ ﻋﻠﻰ اﻟﻬﺎﺕﻒ رﻗـﻢ اﻟﺘﺴﺮب/
٨٧٤-٦٤٢٨ﻟﻠﺤﺼﻮل ﻋﻠﻰ اﻟﺘﻌﻠﻴﻤﺎت اﻟﺼﺤﻴﺤﺔ ﻟﻠﺘﺨﻠﺺ ﻣﻦ اﻟﻤﺎدة. اﻻﻥﺴﻜﺎب:
اﻟﺘﺨﻠﺺ
ﺕﺴﺘﻌﻤﻞ اﻟﻘﻔﺎزات اﻟﻤﻄﺎﻃﻴﺔ اﻟﻮاﻗﻴﺔ ) .(١٠٠٠١٢٩٤١٨ﺕﺴﺘﻌﻤﻞ ﻥﻈﺎرات اﻟﺴﻼﻣﻪ اﻟﻮاﻗﻴﺔ ) .(١٠٠٠١٢٩٨١٠وﻓﺮ ﻣﻐﺎﺱﻞ ﻣﻌﺪات اﻟﺴﻼﻣﺔ:
ﻣﻦ اﻟﻤﺎدة ﻟﻐﺴﻞ اﻟﻌﻴﻨﻴﻦ و دش ﻟﻠﺤﺎﻻت اﻟﻄﺎرﺋﺔ ) (١٠٠٠١٢٨٤٣٣ﻓﻲ أﻣﺎآﻦ ﺕﺨﺰﻳﻦ/اﺱﺘﻌﻤﺎل اﻟﻤﺎدة.
ﺕﻐﺴﻞ اﻟﻌﻴﻨﺎن ﺑﻜﻤﻴﺎت واﻓﺮة ﻣﻦ اﻟﻤﺎء ﻟﻤﺪة ١٥دﻗﻴﻘﺔ ﻣﻊ رﻓﻊ اﻟﺠﻔﻨﻴﻦ ﻣﻦ ﺡﻴﻦ ﻻﺧﺮ .ﺕﺨﻠﻊ اﻟﻤﻼﺑﺲ اﻟﻤﻠﻮﺛﺔ وﻳﻐﺴﻞ اﻟﺠﻠﺪ ﻣﻼﻣﺴﺔ
ﺑﻜﻤﻴﺎت واﻓﺮة ﻣﻦ اﻟﻤﺎء. اﻟﻌﻴﻨﻴﻦ/اﻟﺠﻠﺪ:
اﻹﺱﻌﺎﻓﺎت
ﻳﺒﻌﺪ اﻟﻤﺼﺎب ﻋﻦ اﻟﻤﻨﻄﻘﺔ اﻟﻤﻠﻮﺛﺔ وﻳﻨﻘﻞ إﻟﻰ اﻟﻬﻮاء اﻟﻄﻠﻖ ،وﺕﺒﺎﺵﺮ اﻟﻌﻼﺝﺎت اﻷوﻟﻴﺔ ﺡﺴﺐ اﻟﻀﺮورة. اﻻﺱﺘﻨﺸﺎق:
اﻷوﻟﻴﺔ
إذا آﺎن اﻟﻤﺼﺎب ﻓﺎﻗﺪًا ﻟﻮﻋﻴﻪ أو آﺎن ﻣﺘﺸﻨﺠﺎً ،ﻓﻼ ﻳﻌﻄﻰ أي ﺵﻲء ﻋﻦ ﻃﺮﻳﻖ اﻟﻔﻢ .ﻻ ﺕﺤﻤﻞ اﻟﻤﺼﺎب ﻋﻠﻰ اﻟﺘﻘﻴﺆ .أﻣﺎ إذا اﻻﺏﺘﻼع:
آﺎن ﻣﺤﺘﻔﻈًﺎ ﺑﻮﻋﻴﻪ ﺕﻤﺎﻣﺎً ،واﺱﻘﻪ ٤-٣آﺆوس ﻣﺎء ﻟﻠﺘﺨﻔﻴﻒ ﻣﻦ ﺕﺮآﻴﺰ اﻟﻤﺎدة ﻓﻲ ﻣﻌﺪﺕﻪ.
اﻃﻠﺐ اﻟﻤﺴﺎﻋﺪة اﻟﻄﺒﻴﺔ ﻓﻮرًا واﺕﺼﻞ ﻋﻠﻰ هﺎﺕﻒ ١١٠
ﻟﻤﺰﻳﺪ ﻣﻦ اﻟﻤﻌﻠﻮﻣﺎت اﺕﺼﻞ ﺑﺤﻤﺎﻳﺔ اﻟﺒﻴﺌﺔ ﻋﻠﻰ اﻟﻬﺎﺕﻒ رﻗﻢ ) ٨٧٢-٢٦٢٣اﻟﻈﻬﺮان( أو رﻗﻢ ) ٦٧٨-٤٩٠٢رأس ﺕﻨﻮرة( أو ) ٥٧٢-٣٥٥٣ﺑﻘﻴﻖ( أو ) ٤٢٧-٢٢١٧ﺝﺪة(
٢٠٠٣/٥/٢٦م درﺝﺔ اﻟﺨﻄﻮرة :ﺹﻔﺮ= ﻏﻴﺮ ﺧﻄﻴﺮ =١ ،ﻗﻠﻴﻞ = ٢ ،ﻣﺘﻮﺱﻂ =٣ ،ﺵﺪﻳﺪ =٤ ،ﺵﺪﻳﺪ ﺝﺪًا
CHEMICAL HAZARD BULLETIN NO. 173
VAPOR/MIST Material becoming airborne is unlikely; however, PEL for the 10% constituent Morpholine
LIQUID: as a mist/vapors is 20 ppm for 8 hours. Short Term exposure Limit PEL-STEL=30 ppm.
EFFECTS OF OVER-EXPOSURE
EYE/SKIN: Strong irritation to eyes, which may result in blurred vision. Skin contact will cause
itching, redness and deflating and drying of skin. Morpholine can be absorbed through
the skin, resulting in lethargy, tremors and excessive salivation. It is not a carcinogen.
health
INHALATION Inhalation will cause irritation to nose, throat and airways of the lungs resulting in
hazards
dizziness, headache and nausea.
Slightly flammable. Flash point is >100ºC. Highly soluble in water. Thermal decomposition will produce oxides of
carbon, carbon dioxide and carbon monoxide.
fire and
Fire fighters should wear Scott Air Pack (S/N 21-311-231). Water is not a suitable extinguishing media.
Reactivity: May react with strong oxidizers. reactivity
EXTINGUISH FIRE WITH FOAM, CO2, OR DRY CHEMICAL
USAGE: Scale inhibitor, used in boiler water treatment. Avoid skin contact.
STORAGE: Alkaline. Do not store around acidic materials. Store in well ventilated area. handling
TRANSPORTATION: Label drums and containers the appropriate hazard warning labels. storage
SPILLS / LEAKS: Dike a spill. Absorb onto sand or other suitable media. Contact Environmental
Engineering Division at 874-6426 or 874-6428 for further instructions. &
SAFETY
EQUIPMENT:
Wear protective gloves neoprene gloves (S/N 21-432-080). Use goggles (S/N 21-434-
249). Maintain an eyewash fountain and emergency shower (S/N 21-372-365) where
disposal
material is used or stored.
EYE/SKIN EYES, Lift eye lids and flush with copious amounts of water for a minimum of 15 minutes
CONTACT: SKIN, Remove contaminated clothing and flush with large amounts of water.
INHALATION: Remove victim from contaminated area to fresh air. Apply first treatment as necessary.
INGESTED: Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce
first aid
vomiting. If fully conscious, dilute contents of stomach by giving 3-4 glasses of water.
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
*Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised: 10/28/2002
CHEMICAL HAZARD BULLETIN NO. 175
EMFLOC MRE
1000022170 25 KG BG
Drilling Mud
Health H2 CAS: Mixture
YELLOW-WHITE FINE POWDER. CHARACTERISTIC ODOR
Fire F0 MODERATELY TOXIC, NON-FLAMMABLE, AND STABLE. UN: N/A
Reactivity R1 RESPIRATORY TRACT, EYE, AND SKIN IRRITANT. GUIDE: N/A
SOLUBLE IN WATER. EAC: N/A
EFFECTS OF OVER-EXPOSURE:
health
INHALATION: Inhalation may irritate the nose and upper respiratory system.
hazards
EYE/ SKIN: May cause serious damage to eyes. Skin contact may cause dryness, cracking, irritation
and dermatitis. Toxic amounts may be absorbed through the skin.
INGESTION: Gastrointestinal distress, nausea, vomiting, diarrhea, abdominal pain, and bleeding. May
cause central nervous system depression and liver and/or kidney damage.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product is not flammable. However, it may explode is confined spaces. The minimum explosion
concentration 0.044 mg/m3 in air. Fire fighters must wear SCBA and protective clothing. Fires produce
carbon and nitrogen oxides, and also toxic gases, vapors, fumes, and smoke. Closed containers may fire and
reactivity
rupture in fire conditions. Cool containers exposed to flames with water spray until well after the fire is out.
REACTIVITY: Normally stable. Incompatible with: Heat, flames, sources of ignition, humidity, water and
oxidizing agents.
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY/FOG, FOAM, OR CO2
USAGE: Drilling mud in oil drilling operations. Avoid breathing vapors and avoid eye and skin
contact. NO SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, the product is not regulated.
Packages do not require DOT-IMO warning labels (Diamond).
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 873-6676.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves and an apron
(1000128583) must be worn when handling this material. SCBA (1000127427) should be
worn if conditions warrant. Maintain an eyewash fountain and emergency shower
(1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-4538 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 3/31/2004
CHEMICAL HAZARD BULLETIN NO. 183
SODIUM NITRITE S/N 26-846-211 500 Gm Bottle
(Nitrous acid) 26-846-219 100 Lb (45 Kg) DM
(Sodium salt)
(Diazotizing salt)
NaNO3
GRANULES OR There is no established Threshold Limit Value established for sodium nitrite. Acutely
POWDER: toxic in high concentrations or by ingestion.
EFFECTS OF OVEREXPOSURE:
health
EYE/SKIN:
INHALATION:
Irritating to the eye and skin.
Most toxic effects are acute. Repeated small doses cause a fall in blood pressure, rapid hazards
pulse, headache and visual disturbances. Toxic nitric oxide gas is formed from contact
with weak acids.
INGESTION Swallowed, nitrites may cause nausea, vomiting, cyanosis, collapse, coma and may be
fatal. Sodium nitrite, a common food additive, has been implicated in causing cancer.
DO NOT TRANSFER CHEMICALS TO AN UNMARKED CONTAINER
Sodium nitrite is not a flammable compound, with no flash point or flammable limits reported. In heat of a fire
generates toxic nitrous oxide and Na2O. Sodium nitrite is a STRONG OXIDIZING AGENT. In contract with organic
material it will ignite by friction. Wood impregnated with solutions of nitrite over a long period may be accidentally
ignited, and burn fiercely.
REACTIVITY: A strong inorganic oxidizer, EXPLOSIONS ARE LIKELY to occur on heating mixtures of sodium
fire and
nitrite with ammonium salts, metal cyanides, phthalic acid or anhydride, sodium amide, barium or sodium
thiocyanate or sodium thiosulfate. Violent reactions occur on heating with sodium, metal powders, amidosulfates,
reactivity
mercury salts, permanganates or sulfites. In contact with organic material, charcoal, and powder or dust, sodium
nitrite will explode or ignite. Reported to explode when heated above 100oF(38oC). Potentially carcinogenic
nitrosoamines may be formed in contact with amines. Sensitive to mechanical impact.
EXTINGUISH FIRES WITH WATER SPRAY
USES: Laboratory reagent; photography, curing and preserving of meat. Avoid forming,
accumulating and breathing dust. No smoking. Provide adequate ventilation. Wash hands
after handling.
handling
STORAGE: Store in a well-ventilated, cool, dry area, well removed from all acids and incompatible
materials (including wooden floors) and in a noncombustible building. KEEP storage
TRANSPORT:
SPILLS:
CONTAINER TIGHTLY CLOSED and labeled. For transportation, label packages with
DOT-IMO, Class 5.1 hazardous warning label (diamond): OXIDIZER.
Evacuate unnecessary personnel. Keep combustibles away from spilled sodium nitrite.
&
For small spills, place into bucket of water and run to waste, diluting with quantities of
water. Wash spill site with water to remove all oxidizer, which may otherwise render
disposal
wood, paper or clothing highly combustible when dry. Clothing wetted with nitrite solutions
DISPOSAL: must be washed thoroughly before reuse. For proper disposal methods and locations for
chemical or chemical contaminated material, contact the Environmental Engineering
Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to avoid overexposure. APR or SCBA should be worn if conditions
EQUIPMENT: warrant. Goggles (S/N 21-434-249) and gloves (S/N 21-432-080) should be worn if
splashing or direct contact s possible. Maintain eyewash fountain and chemical shower
where chemicals are stored or used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
EYE/SKIN
has stopped, give cardio-pulmonary resuscitation (CPR). Keep person warm and quiet.
Flush eyes with large amounts of water. Lift eyelids occasionally. Seek medical
first aid
CONTACT: attention. Wash skin thoroughly with water. Remove contaminated clothing and shoes
promptly, and wash clothing before re-use.
INGESTION: Wash out mouth with water. Do not induce vomiting. Give victim water, if conscious.
Never give drink to unconscious person. Tell the doctor that sodium nitrite was swallowed.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
*Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised 10/21/2002
CHEMICAL HAZARD BULLETIN NO. 184
INHALATION:
eye damage. Diluted solutions are only mildly irritating to the skin.
Causes irritation to the respiratory tract. High concentrations can cause pulmonary
health
INGESTION:
edema.
Ingestion of solid or high concentrations causes sever distress of gastro-intestinal system
hazards
with possible burns. May be fatal when swallowed from the throat swelling and shutting of
the throat, suffocating. Possible kidney failure.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
Potassium permanganate is not a combustible solid. There is no flash point and no flammable limits, but is a
strong oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition. Contact with
oxidizable substances may cause extreme violent combustion. Sealed containers may rupture when heated. fire and
Firefighters must use self-contained breathing apparatus (SCBA) and full protective clothing.
REACTIVITY: Risk of explosion when this oxidizer is mixed with sulfuric acid, acetic acid, hydrochloric acid,
reactivity
glycerol, hydrogen peroxide. Strong oxidants may explode when shocked or if exposed to heat, flame, or friction.
Potassium permanganate reacts violently with all organic dusts or fibers. Incompatible with alcohols, bromides,
iodides, charcoal, mercurous salts, sulfites and oxalates.
EXTINGUISHING MEDIA: WATER SPRAY
USAGE: Laboratory reagent, oxidizer for cleaning tanks and purifying water. Avoid breathing
vapor or mist or dispersing dust. No Smoking. Provide adequate local exhaust
ventilation.
TRANSPORT/ Store in a well ventilated, cool, dry area away from ignition sources. Keep containers
STORAGE: labeled, upright and tightly closed when not in use. Avoid storage near incompatible
material. Avoid storage on wood floors. Containers of this material may be hazardous
when empty since they retain product residues. For transportation, always label handling
containers with DOT/IMO Class 5.1, hazardous warning label (diamond); OXIDIZER.
SPILLS/LEAKS: Shut off sources of ignition. Ventilate area and wear PPE. Wet with water to avoid dust storage
generation. With a chemical scoop retrieve as much uncontaminated oxidizer as
DISPOSAL:
possible. Mix the remainder with sand, scoop into a clean plastic or glass container,
For proper disposal methods and locations for the chemical or chemical contaminated
&
SAFETY
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
Provide ventilation to control airborne concentrations below the guidelines. Safety
disposal
EQUIPMENT: goggles (1000129810), neoprene gloves (1000129418), boots (1000128971), and aprons
(1000128583) must be worn when handling this material. SCBA should be worn if
conditions warrant. Maintain an eyewash fountain and emergency shower where the
material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLY
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped give cardio-pulmonary resuscitation (CPR). Keep person warm and quiet.
EYE/SKIN Flush eyes with large amount of water for at least 15 minutes. Lift eyelids occasionally.
CONTACT: Wash skin thoroughly with water. Remove contaminated clothing and shoes promptly
and wash clothing before re-use.
first aid
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs due to vomiting can cause
chemical pneumonitis which can be fatal. If conscious, drink large quantities of water to
dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Environmental Protection: 873-5853 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
6/27/2006
CHEMICAL HAZARD BULLETIN NO. 185
LIQUID/ The product is not less than 99.95% gaseous argon gas. There are no specific exposure
VAPOR: limits for argon. Argon gas is considered a simple asphyxiant that can replace oxygen in
breathing air.
Note: Oxygen levels should always be maintained above 19.5%.
EFFECTS OF OVER-EXPOSURE:
health
INHALATION: The acute effect of this product is the inhalation of oxygen-deficient atmospheres.
Symptoms include respiratory difficulty, ringing in ears, headaches, shortness of breath,
wheezing, headache, dizziness, indigestion, nausea. At high concentrations,
unconsciousness or death may occur. The skin of a victim of over-exposure may have a
blue color. No known adverse health effects associated with chronic exposure.
hazards
EYE/ SKIN: May cause eye irritation. Due to rapid evaporation, the liquid may cause eye and skin
frostbite with redness. This may also result in blurred vision and hard and white skin.
INGESTION: Unlikely route of exposure. Frostbites damage lips, mouth, and mucous membranes.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
Non-flammable product. Fire fighters must wear SCBA and protective clothing. Fires produces carbon and
nitrogen oxides, and also toxic gases, vapors, fumes, and smoke. Closed containers may rupture in fire
conditions. Cool containers exposed to flames with water spray until well after the fire is out. fire and
REACTIVITY: Normally stable. Incompatible with: Heat. Cylinders may explode in heat of fires.
reactivity
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY/FOG, FOAM, OR CO2
USAGE: Lab equipment, welding operations. Avoid breathing gases and avoid eye and skin
contact. NO SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed. For transportation, label containers with DOT-IMO Class 2.2
hazardous warning label (diamond): NON-FLAMMABLE COMPRESSED GASES.
storage &
SPILLS/ Evacuate unauthorized personnel. Shut off ignition sources. Stop leak if possible without
LEAKS: risk. Use plenty of water to reduce vapors. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and PVC gloves (1000129628) must be worn when handling this material.
Positive pressure air line with full-face mask and escape bottle or SCBA (1000127427)
should be worn if conditions warrant. Maintain an eyewash fountain and emergency
shower (1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Wear a scott air pack to rescue asphyxiated person. Pull victim to fresh air and give
mouth-to-mouth resuscitation immediately. Keep person warm and quiet.
first aid
EYE / SKIN Frozen tissues should be immersed in warm water. DO NOT USE HOT WATER, DO NOT
CONTACT: RUB SKIN. Blistered or deeply frozen skin should be examined by a doctor.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1447 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 10/31/2004
CHEMICAL HAZARD BULLETIN NO. 194
1000022134 55 GِِA DM
COAT 415
Baroid Corrosion
Inhibitor
Health 3 CAS: Mixture
BROWN LIQUID, WITH AROMATIC ODOR.
Fire 2 HIGHLY TOXIC, MODERATELY FLAMMABLE, AND STABLE. UN: 1993
Reactivity 1 IRRITANT TO THE RESPIRATORY TRACT, EYES, AND SKIN. GUIDE: 128
MAY BE CARCINOGEN. EAC: •3YE
health
INHALATION: Inhalation of vapor and mists may irritate the respiratory tract, nose, and throat.
Symptoms include dizziness, drowsiness, and incoordination. Prolonged or repeated
exposure may cause chronic respiratory tract irritation. May cause blood cancer due to
benzene presence.
hazards
EYE/ SKIN: Eye contact may cause redness, severe irritation, and eye damage. Skin contact may
cause defatting, dryness, ulceration, and sensitization contact allergy dermatitis.
INGESTION: Can cause gastrointestinal distress, severe burns of the mouth, throat, and stomach
pain. leading to death. Also, sore throat, vomiting, diarrhea. May cause violent
gastroenteritis, peripheral vascular collapse, dizziness, intense thirst, muscle cramps,
coma, abnormal bleeding, fever, liver damage.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The flashpoint is 60°C (140°F); no explosive range was reported. Fire fighters must wear SCBA and
protective clothing. Fire produces carbon, and nitrogen oxides, and also toxic gases, vapors, fumes, and
smoke. Closed containers may rupture in fire conditions. Cool containers exposed to flames with water fire and
reactivity
spray until well after the fire is out.
REACTIVITY: Normally stable. Incompatible with strong oxidizers, e.g., nitric acid. Heat, flames, and
sources of ignition.
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY/FOG, FOAM, OR CO2
USAGE: Corrosion inhibitor in oil operations. Avoid breathing vapor and mists and avoid eye and
skin contact. NO SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, use DOT-IMO Class 4.2
hazardous warning labels (diamond): COMBUSTIBLE, LIQUID, N.O.S.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) and an apron (1000128583) must be worn
when handling this material. APR (1000128213/163) or SCBA (1000127427) should be
worn if conditions warrant. Maintain an eyewash fountain and emergency shower
(1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Environmental Protection: 873-8591(DH), 678-4902 (RT), 574-4722 (ABQ), or 427-0155 (JID).
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 5/15/2006
CHEMICAL HAZARD BULLETIN NO. 195
health
INHALATION: May cause irritation to the respiratory tract and mucous membranes, sore throat,
coughing, dizziness, shortness of breath, and fainting. May be absorbed through
inhalation. Symptoms may parallel ingestion.
hazards
EYE/ SKIN: Eye contact causes irritation, redness, pain, and blurred vision. Skin contact irritation,
redness, and pain. May be absorbed through the skin; symptoms may parallel ingestion.
INGESTION: Highly Toxic! May cause breathlessness, pulmonary edema and rapid heart beat within 5
minutes. Nausea, vomiting, headache, restlessness, and diarrhea may occur within 15
minutes. Other symptoms may include low blood pressure, abnormal breathing, reduced
body temperature, reduced body pH, convulsions, collapse and death.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product is combustible. Fire fighters must wear SCBA and protective clothing. Fires produce carbon
and nitrogen oxides, and also toxic gases, vapors, fumes, and smoke. Closed containers may rupture in fire
conditions. Cool containers exposed to flames with water spray until well after the fire is out. fire and
reactivity
REACTIVITY: Decomposes explosively upon heating, shock, concussion, or friction. Incompatible with both
copper and lead to produce explosive azides. Explosions in laboratory plumbing containing these metals are
possible. Sensitive to mechanical impact. Also incompatible with strong oxidizers, e.g., nitric acid. Heat,
flames, and sources of friction and ignition.
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY/FOG, FOAM, OR CO2
USAGE: Laboratory reagent. Avoid breathing dust and mists and avoid eye and skin contact. NO
SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, use DOT-IMO Class 6.1
hazardous warning labels (diamond): POISONOUS SOLID
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves and an apron
(1000128583) must be worn when handling this material. APR (1000128213) or SCBA
(1000127427) should be worn if conditions warrant. Maintain an eyewash fountain and
emergency shower (1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 10/31/2004
CHEMICAL HAZARD BULLETIN NO. 197
Sodium S/N 26-840-718 500 gram bottle
26-840-916 50 kg sack
Carbonate
“Sal Soda”
“Soda Ash”
“Washing Soda”
Health 2 WHITE ODORLESS POWDER, HIGHLY CORROSIVE TO CAS: 497-19-8
Fire 0 SKIN, EYES AND RESPIRATORY TRACT, UN: None
Reactivity 1 NON-FLAMMABLE AND MODERATELY REACTIVE GUIDE: None
LIQUID: There is no Permissible Exposure Limits for sodium carbonate.
EFFECTS OF OVEREXPOSURE:
EYE/SKIN: Severe eye Irritant with possible corneal damage and eye burns. Irritating to the skin with
possibility of burns, skin damage and ‘soda ulcers’ of hands and wrists.
health
INHALATION: Severe irritant of the respiratory tract causing burning pain, wheezing, coughing and
pulmonary edema. Chronic exposures can lead to bronchitis and perforation of the nasal
septum.
hazards
INGESTION: Ingested, large quantities produce corrosion of the gastro-intestinal tract, vomiting,
diarrhea, circulatory collapse and death.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
Sodium Carbonate is nonflammable. Firefighters should use SCBA and full-protective suits to prevent contact with
skin and eyes and to protect against thermal decomposition products.
fire and
REACTIVITY: Avoid contact with aluminum, phosphorous pentoxide, or sulfuric acid.
EXTINGUISH FIRES WITH DRY CHEMICAL, CO2, FOAM, OR WATER FOG reactivity
USES: Used in water treatment, reverse osmosis units, and as admixture for drilling fluids.
STORAGE: Keep containers tightly closed as sodium carbonate absorbs water upon exposure to air.
Store in a cool, dry, well-ventilated area.
SPILL: Mix solid sodium carbonate with sand, cart to disposal site, wash down spill area with
quantities of water. Wear gloves, goggles, apron and boots to clean a spill of
concentrated solution.
handling
TRANSPORT: For transportation, packages do not require DOT-IMO hazardous warning label
(diamond).
storage
DISPOSAL: For proper disposal methods and locations for chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
&
SAFETY Wear goggles (S/N 21-434-249) and neoprene gloves (S//N 21-432-080) to handle. disposal
EQUIPMENT: Wear a dust mask (S/N 21-370-600) when handling dust powder. MAINTAIN EYEWASH
FOUNTAIN wherever sodium carbonate is handled or stored.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardio pulmonary resuscitation (CPR). Keep person warm and quiet,
EYE/SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
INGESTION:
and wash clothing before re-use.
DO NOT induce vomiting. Aspiration of material into the lungs due to vomiting can cause
first aid
chemical pneumonitis which can be fatal. If conscious, drink one-two glasses of water to
dilute. Keep person warm and quiet.
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:7/2/2001
CHEMICAL HAZARD BULLETIN NO. 206
SOLID/DUST: The product is > 99.5 assay of sodium thiosulfate 5-hydrate;. Synonyms include sodium
thiosulfate pentahydrate; disodium thiosulfate; sodium hyposulfite solutions. No exposure
limits were reported.
EFFECTS OF OVER-EXPOSURE:
health
INHALATION: May cause respiratory tract irritation. Low hazard for usual industrial handling.
hazards
EYE/ SKIN: May cause eye and skin irritation. Prolonged skin contact and/or repeated contact may
cause irritation and/or dermatitis.
INGESTION: Ingestion of large amounts may cause gastrointestinal irritation, burns of the mouth,
throat, and stomach, leading to death. Also, sore throat, vomiting, diarrhea.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product is not flammable or combustible. Fire fighters must wear SCBA and protective clothing. Fires
produce sulfur, sodium, and nitrogen oxides, and also toxic gases, vapors, fumes, and smoke. Closed
containers may rupture in fire conditions. Cool containers exposed to flames with water spray until well after fire and
reactivity
the fire is out.
REACTIVITY: Normally stable, but it can absorb moisture from air. Incompatible with strong oxidizers, e.g.,
nitric acid. Heat and sources of ignition.
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY/FOG, FOAM, OR CO2
USAGE: Laboratory reagent. Avoid breathing dust and avoid eye and skin contact. NO SMOKING.
Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, the product is not regulated, and
does not require hazardous warning signs.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) must be worn when handling this material. APR (1000128165) or SCBA
(1000127427) should be worn if conditions warrant. Maintain an eyewash fountain and
emergency shower (1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 10/24/2004
CHEMICAL HAZARD BULLETIN NO. 208
health
INHALATION: Inhalation may cause nose and throat irritation, nausea, vomiting, dizziness and
drowsiness. May also adversely affect pulmonary edema and central nervous system
(CNS) depression, and lower blood pressure. Chronic exposures can cause severe
kidney and brain problems.
hazards
EYE/ SKIN: May cause eye irritation, pain, and damage. May cause skin irritation with prolonged
contact.
INGESTION: Very toxic when swallowed. It may cause central nervous system (CNS) depression,
nausea, dizziness, vomiting, or unconsciousness. Can cause blindness, liver and
kidney damage.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product flashpoint is 37°C (98°F); no explosive limits were reported. Fire fighters must wear SCBA and
protective clothing. Fires produce carbon and nitrogen oxides, and also toxic gases, vapors, fumes, and
smoke. Closed containers may rupture in fire conditions. Cool containers exposed to flames with water fire and
reactivity
spray until well after the fire is out.
REACTIVITY: Normally stable. Incompatible with: Strong oxidizers, e.g., nitric acid and chlorine. Heat and
sources of ignition.
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY/FOG, FOAM, OR CO2
USAGE: Scale inhibitor in water treatment systems. Avoid breathing vapor and mists and avoid eye
and skin contact. NO SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, use DOT-IMO Class 3.1
hazardous warning labels (diamond): FLAMMABE LIQUID, N.O.S.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 873-6676.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves must be worn
when handling this material. APR (1000128213) or SCBA (1000127427) should be worn
if conditions warrant. Maintain an eyewash fountain and emergency shower
(1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 574-4472 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 5/17/2004
CHEMICAL HAZARD BULLETIN NO. 214
S/N 26-502-090/093 Bulk Delivery
DODIGEN 1641D
Corrosion
Inhibitor
INHALATION: Not expected to present an inhalation hazard unless vapor and/or mists are
generated, where both may cause drowsiness and narcosis.
health
EYE/ SKIN: May cause irritation to the eye. Can cause skin irritation. Prolonged contact can have
a degreasing effect. It may cause dryness and cracking leading to dermatitis. hazards
INGESTION: Low acute oral toxicity, but aspiration into lungs during ingestion may cause
pulmonary injury. The onset of the respiratory symptoms may be delayed for several
hours after exposure.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The flash point for this product is >61°C(>141°F); no flammability range is defined. Fire fighters must wear
SCBA and protective clothing. During combustion, oxides of carbon, sulfur and nitrogen may be formed;
also toxic vapors and smoke. Closed containers may rupture in fire conditions. Keep containers cool with fire and
reactivity
water spray. Bond and ground all equipment when transferring from one vessel to another.
REACTIVITY: Avoid high heat, contact with strong reducing agents, acids, and organic compounds.
EXTINGUISH FIRES WITH DRY CHEMICAL, CO2, FOAM OR WATER SPRAY
USAGE: This product is a corrosion inhibitor. Avoid breathing vapor and mists. Avoid eye and
skin contact. No smoking. Provide adequate ventilation.
TRANSPORT/ Store in a well-ventilated, cool, dry area, away from ignition sources. Avoid extreme
handling,
STORAGE: temperatures. Keep tightly closed when not in use. Do not store in direct sunlight.
Avoid storage near incompatible materials. Always label containers for transporting.
SPILLS/ LEAKS: Shut off sources of ignition. Stop the flow if it can be done safely. Dike to prevent
DISPOSAL:
entry into sewer. Absorb with sand and place in clean, dry, labeled containers.
For proper disposal methods and locations for the chemical or chemical contaminated
storage &
SAFETY
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
Provide ventilation to control overexposure. Safety goggles or full-face visor and
disposal
EQUIPMENT: neoprene gloves must be worn when handling this material. SCBA should be worn if
conditions warrant. Maintain an eyewash fountain and emergency shower where the
material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If
breathing has stopped, give cardiopulmonary resuscitation (CPR). Keep person
warm and quiet.
EYE / SKIN Flush eyes with large amounts of water for 15 minutes keeping eyelids apart. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes
promptly, and wash clothing before re-use. first aid
INGESTION: Do not induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Keep person warm
and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print:1/13/2001
CHEMICAL HAZARD BULLETIN NO. 215
S/N 26-863-433 25 Kg Drum
SULFAMIC
ACID
INGESTION:
depending on length of contact.
Solution is corrosive to the digestive tract.
hazards
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
Non-flammable. In contact with fire will decompose to form oxides of carbon, nitrogen and sulfur in addition to
fumes and smoke. Fire fighters should wear self-contained breathing apparatus (SCBA) and full protective
clothing. fire and
REACTIVITY: Avoid contact with oxidizing agents, bases, ammonia and amines, nitric acid and chlorine reactivity
EXTINGUISH FIRES WITH WATER SPRAY, CO2, DRY CHEMICAL OR FOAM
STORAGE: Store in tightly sealed containers in a cool, dry area away from incompatible materials.
TRANSPORT: For transportation use DOT-IMO class 8 hazard warning label (diamond ) CORROSIVE
handling
SPILLS/LEAKS: Shovel into clean containers. storage
DISPOSAL: Contact Environmental Engineering (874-6426 or 874-6428) for disposal procedure and
locations.
&
SAFETY
EQUIPMENT:
Wear faceshield (S/N 21-426-121), goggles, (S/N 21-434-249) and neoprene gloves (S/N
21-432-080). Maintain eyewash fountain and emergency shower in storage area and disposal
wherever used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
EYE/SKIN Flush eyes with copious amounts of water for at least 15 minutes holding eyelids apart.
CONTACT: Remove contaminated clothing or shoes. Wash skin thoroughly with soap and water.
Launder clothing before re-use.
INHALATION: Remove those exposed to fresh air. If breathing is difficult administer oxygen. If breathing first aid
has stopped, apply cardio-pulmonary resuscitation (CPR).
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
*Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised: 7/2/2001
CHEMICAL HAZARD BULLETIN NO. 217
The Threshold Limit Value for silver nitrate is 0.01 mg/m as silver soluble compounds.
3
DUST/SOLID:
Silver nitrate is highly corrosive to skin and eyes. Concentrated solutions will cause
corneal burns that result in blurred vision or blindness. Upon contact it will blacken body
tissues, membranes or organic material.
EYES/SKIN: Destructive to tissues of mucous membranes and upper respiratory tract. Causes burning
sensation, coughing, laryngitis, shortness of breath, headache. May be absorbed into the
health
body through lungs. Chronic dust exposure results in pneumoconiosis.
hazards
INHALATION/ Ingestion causes severe burns of mouth, throat and stomach. Symptoms include vomiting
INGESTION: black material, diarrhea, burning in mouth, abdomen, collapse, death.
STORAGE: Store in the dark, cool location and keep containers tightly sealed. Do not store near
combustible or reactive materials. Exposure to light and organic material turns crystals handling
DISPOSAL:
grey-black and increase fire risk.
Vacuum, sweep or mop up material into suitable container. Wash solution with plenty of
storage
water and run to waste. Contact Environmental Engineering Division (874-6426 or 874-
6428) for disposal procedure.
&
SAFETY Wear nitrile gloves and goggles (S/N 21-434-780), lab coat and handle under a chemical disposal
EQUIPMENT: hood. Maintain an eyewash fountain and emergency shower where silver nitrate is used
or stored.
EYES: Hold eyelids open and flush with copious amounts of water for at least 15 minutes; have a
physician examine eyes.
SKIN: Remove contaminated clothing and wash affected area with soap and water. first aid
INGESTED: Give large quantity of water if victim is conscious. Do not induce vomiting.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
*Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised: 10/28/2002
CHEMICAL HAZARD BULLETIN NO. 227
1000118420 25-LB EA
SILVER SOLDER 1000118591 25-LB EA
“SIL-FOS”
Health 4 CAS: Alloy
METALLIC ALLOY SOLDER.
Fire 0 EXTREMELY TOXIC (AT USE). NON-FLAMMABLE. STABLE. UN: N/A
Reactivity 0 IRRITANT TO THE RESPIRATORY TRACT, EYES, AND SKIN. GUIDE: N/A
POTENTIAL CARCINOGEN. DAMAGE CNS. EAC: N/A
3 3
FUMES/VAPOR/ The product is a proprietary alloy of silver (TLV=0.01 mg/m ), copper (PEL=0.1 mg/m ),
3
DUST: and phosphorus (PEL=0.1mg/m ).
EFFECTS OF OVER-EXPOSURE:
health
INHALATION: Inhalation of welding fumes can result in metal fume fever; this condition resembles
influenza and is characterized by fever, chills, headache, nausea, shortness of breath,
muscle pain, and a metallic taste in the mouth. Chronic exposure to welding fumes and
dust can result in respiratory effects including coughing, wheezing, and decreased
pulmonary function. Overexposure may cause anemia, and muscular weakness, and
damage to the blood-forming organs, kidneys, nervous and reproductive systems.
hazards
EYE/ SKIN: Eye contact during soldering can be an irritant, causing eye burns. Skin Contact: Molten
solder will cause burns. Prolonged or repeated contact can cause defatting dermatitis.
May also cause an allergic reaction such as rash.
INGESTION: Can cause gastrointestinal distress, severe burns of the mouth, throat, and stomach
pain. leading to death. Also, sore throat, vomiting, diarrhea. May cause violent
gastroenteritis, peripheral vascular collapse, dizziness, intense thirst, muscle cramps,
coma, abnormal bleeding, fever, liver damage.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product is not flammable or combustible. Fire fighters must wear SCBA and protective clothing. Fire
produces silver, phosphorous, cop, and nitrogen oxides, and also toxic gases, vapors, fumes, and smoke.
Closed containers may rupture in fire conditions. Cool containers exposed to flames with water spray until fire and
reactivity
well after the fire is out.
REACTIVITY: Normally stable. Incompatible with strong oxidizers, e.g., nitric acid. Heat, flames, and
sources of ignition.
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY/FOG, FOAM, OR CO2
USAGE: Soldering of electrical equipment. Avoid breathing fumes, vapor, and dust and avoid eye
and skin contact. NO SMOKING. Provide adequate and local exhaust ventilation
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions. For
TRANSPORT: transportation, the product is not regulated, and does not require hazardous labels.
storage &
SPILLS/ No special requirements.
LEAKS:
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY During use, provide ventilation to control overexposure and eye and skin contact. Safety
EQUIPMENT: goggles (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves and an
apron (1000128583) must be worn when handling this material. APR”O”
(1000128213/163) should be worn if conditions warrant. Maintain an eyewash fountain
and emergency shower (1000128433) where the material is being used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 12/18/2004
CHEMICAL HAZARD BULLETIN NO. 229
1000213792 400-ML CN
PIF-PAF 1000213796 400-ML CN
INSECTICIDE
Health 1 CAS: Mixture
AEROSOL SPRAY, WITH MILD ODOR.
Fire 4 EXTREMELY FLAMMABLE WHEN SPRAYED. STABLE. UN: 3077
Reactivity 0 IRRITANT TO THE EYES, AND SKIN, IF ABSORBED. GUIDE: 171
SIMPLE ASPHYXINAT (Air should not be less than 19.5%) EAC: 2X
AEROSOL/VAPOR/ The product is a proprietary formulation of piperonyl butoxide (WHO daily intake
3
MISTS: =0.03 mg/kg) and pyrethrum (TLV=5mg/m ). The propellant is butane
(TLV=800ppm).
EFFECTS OF OVER-EXPOSURE:
health
INHALATION: Inhalation of mists and product vapor may cause chemical intoxication at high
concentrations. It may cause dizziness, loss of coordination, and consciousness.
Butane is a simple asphyxiant, and effects occur due to lack of oxygen.
hazards
EYE/ SKIN: Will cause irritation if sprayed directly into the eyes, and illness if absorbed through
the skin.
INGESTION: Can cause gastrointestinal distress and serious illnesses if taken internally, where
aspiration may occur and cause chemical pneumontis.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product is extremely flammable when sprayed. Avoid spray in confined spaces. Fire fighters must wear
SCBA and protective clothing. Fire produces carbon and nitrogen oxides, and also toxic gases, vapors,
fumes, and smoke. Closed containers may rupture in fire conditions. Cool containers exposed to flames fire and
reactivity
with water spray until well after the fire is out.
REACTIVITY: Normally stable. Incompatible with strong oxidizers, e.g., nitric acid. Heat, flames, and
sources of ignition.
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY/FOG, FOAM, OR CO2
USAGE: Insecticide reagent. Avoid breathing vapor and mists and avoid eye and skin contact. NO
SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, use DOT-IMO Class 9 hazardous
warning labels (diamond): ENVIRONMENTALLY HAZARDOUS , MISCELLANEOUS
SUBSTANCE, N.O.S.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves and an apron
(1000128583) must be worn when handling this material. APR (1000128163) or SCBA
(1000127427) should be worn if conditions warrant. Maintain an eyewash fountain and
emergency shower (1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 12/18/2004
CHEMICAL HAZARD BULLETIN NO. 231
DIRECT CHARGE
VINYL CHLORIDE
Health 4 CAS: 75-01-4
COLORLESS GAS, WITH SWEET ODOR.
Fire 4 EXTREMELY TOXIC an, FLAMMABLE. MODERATELY REACTIVE. UN: 1086
Reactivity 2 IRRITANT TO THE RESPIRATORY TRACT, EYES, GUIDE: 116P
KNOWN CARCINOGEN. EAC: 2WE
LIQUID/VAPOR/ Vinyl chloride (TLV=1ppm) may be present as a possible hazard at many operations;
GAS: e.g., NGL loading facilities.
EFFECTS OF OVER-EXPOSURE:
health
INHALATION: Inhalation of gas and vapor can cause headache, dizziness, lung irritation, narcosis and
unconsciousness. It may cause central nervous system depression with noticeable
anesthetic effects. Pressure drop through valves and piping may cause extreme cold
and frostbite on contact. Chronic effects include liver tumors, and CNS, depression.
hazards
EYE/ SKIN: Eye contact may cause irritation, eye damage. Skin contact may cause irritation,
frostbite, and blisters.
INGESTION: Can cause gastrointestinal distress, severe burns of the mouth, throat, and stomach
pain. leading to death. Also, sore throat, vomiting, diarrhea. May cause violent
gastroenteritis, peripheral vascular collapse, dizziness, intense thirst, muscle cramps,
coma, abnormal bleeding, fever, liver damage.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The flashpoint is -78°C (-108°F); explosive limits are 3.3 to 33%. Fire fighters must wear SCBA and
protective clothing. Fire produces phosgene, hydrogen chloride, carbon, chromium, and nitrogen oxides,
and also toxic gases, vapors, fumes, and smoke. Closed containers may rupture in fire conditions. Cool fire and
reactivity
containers exposed to flames with water spray until well after the fire is out.
REACTIVITY: May polymerize. Incompatible with strong oxidizers, e.g., nitric acid. Heat, flames, and
sources of ignition.
EXTINGUISHING MEDIA: DRY POWDER, HALOGENATED GAS, OR CO2
USAGE: Laboratory reagent. Avoid breathing vapor and gas and avoid eye and skin contact. NO
SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, use DOT-IMO Classes 2.1 and
2.3 hazardous warning labels (diamond): TOXIC, FLAMMABLE GAS.
storage &
SPILLS/ Evacuate unauthorized personnel For large leaks, dike to prevent entry into sewer. keep
LEAKS: area free from ignition sources until spilled liquid completely evaporated. Area. For small
spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled containers.
Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves and an apron
(1000128583) must be worn when handling this material. Supplied-air respirator with full
facepiece and operated in a pressure-demand or SCBA (1000127427) should be worn if
conditions warrant. Maintain an eyewash fountain and emergency shower (1000128433)
where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 12/18/2004
CHEMICAL HAZARD BULLETIN NO. 233
ETHANE
Saudi Aramco Product
Gas or Liquefied
LIQUID/Gas: The product is > 95% ethane with TLV=1000ppm, and is classified as a simple
asphyxiant. It is heavier than air, and high levels may accumulate and replace oxygen in
confined spaces. Ethane acts as an anesthetic or narcotic at high levels.
EFFECTS OF OVER-EXPOSURE:
health
INHALATION: Inhalation of ethane in oxygen-deprived environments can lead to abnormal fatigue,
drowsiness, dizziness and loss of consciousness. At low levels of oxygen (<6%), death
can occur. Chronic exposure to ethane may damage the CNS and heart.
hazards
EYE/ SKIN: Eye and skin contact with cryogenic liquid or rapidly expanding ethane may cause
frostbite, with symptoms including change in skin color to white or grayish-yellow. The
pain after contact can quickly subside.
INGESTION: Not a likely route of exposure.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The flashpoint of ethane is -130°C (-202°F); with explosive limits of 3.0 to 12.5%. Fire fighters must wear
SCBA and protective clothing. Fire produces carbon and nitrogen oxides, and also toxic gases, vapors,
fumes, and smoke. Closed containers may rupture in fire conditions. Cool containers exposed to flames fire and
reactivity
with water spray or fog until well after the fire is out. WARNING: Cryogenic ethane can rapidly freeze water.
REACTIVITY: Normally stable. Incompatible with strong oxidizers, e.g., nitric acid, heat, flames, and
sources of ignition.
EXTINGUISHING MEDIA: SUITABE FOR SURROUNDING FIRES
USAGE: In petrochemicals industry. Avoid breathing gas and avoid eye and skin contact. NO
SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, use DOT-IMO Class 2.1
hazardous warning labels (diamond): FLAMMABLE/COMPRESSED GAS , N.O.S.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, locate and seal leak sources prior to
LEAKS: entry. Allow gas to dissipate until its level is <0.3% in air. Spray involved personnel with
water. Use only non-sparking tools and equipment.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves and an apron
(1000128583) must be worn when handling this material. APR (1000128213) or SCBA
(1000127427) should be worn if conditions warrant. Maintain an eyewash fountain and
emergency shower (1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 873-5853 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 4/23/2006
CHEMICAL HAZARD BULLETIN NO. 237
HAZARDOUS GAS
SULFUR DIOXIDE
Health 3 CAS: 7446-09-5
COLORLESS GAS, WITH "NOTICEABLE & SUFFOCATING ODOR.
Fire 0 HIGHLY TOXIC. MODERATELY REACTIVE. NON-FLAMMABLE. UN: 1079
Reactivity 2 CORROSIVE TO BODY TISSUES. GUIDE: 125
EAC: 2RE
GAS/MISTS: Major air pollutant as well as occupational hazard (TLV=2ppm, STEL-TLV=5ppm; IDLH:
100 ppm). Synonymous include sulfurous anhydride, sulfurous oxide.
EFFECTS OF OVER-EXPOSURE:
health
INHALATION: Gas and mists are corrosive and irritating to the upper and lower respiratory tract and
all mucosal tissues. Symptoms include nose and throat irritation, becoming steadily
worse, suffocating and painful; irritation extends to the chest causing a cough reflex
which may be violent and painful, and include the discharge of blood or vomiting with
eventual collapse. Chemical pneumonitis and pulmonary edema may result from
exposure to the lower respiratory tract and deep lung. High concentrations may be fatal
due to spasm, inflammation and edema of the lungs.
hazards
EYE/ SKIN: Corrosive and irritating to the eyes. Contact with the liquid or vapor causes painful
burns and ulcerations. Burns to the eyes result in lesions and possible loss of vision.
Corrosive and irritating to the skin and all living tissue. Toxic level exposure to dermal
tissue causes acid-like burns and skin lesions resulting in early necrosis and scarring.
INGESTION: Ingestion unlikely. Gas at room temperature.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product is not flammable. Fire fighters must wear SCBA and protective clothing. Fire produces carbon,
sulfur and nitrogen oxides, and also toxic gases, vapors, fumes, and smoke. Closed containers may rupture
in fire conditions. Cool containers exposed to flames with water spray until well after the fire is out. fire and
REACTIVITY: Reacts with water and moisture in air to form sulfurous acid. Incompatible with peroxides,
chromates, bichromates, permanganates and oxygen difluoride. reactivity
EXTINGUISHING MEDIA: SUITABLE FOR SURROUNDING FIRE
USAGE: General air and occupational pollutant. Avoid breathing gas and mists and avoid eye and
skin contact. NO SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, use DOT-IMO Class 2.3
hazardous warning labels (diamond): FLAMMABLE GAS.
storage &
SPILLS/ Evacuate unauthorized personnel. For large leak, evacuate and ventilate till gas dissipate.
LEAKS: Dike to prevent formed acids entry into sewer. For small spills, absorb in dry sand or
earth. Shovel and place into clean, dry, labeled containers. Flush with plenty of water to
clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves and an apron
(1000128583) must be worn when handling this material. APR (1000128213) or SCBA
(1000127427) should be worn if conditions warrant. Maintain an eyewash fountain and
emergency shower (1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 12/18/2004
CHEMICAL HAZARD BULLETIN NO. 241
S/N 45-605-875 5 gallon pail
45-605-880 55 gallon drum
SLIK NO.5 BAROID
OIL RIG
DEGREASER
INHALATION:
clothing or shoes, may cause reddening and mild irritation.
SLIK NO.5 vaporizes at the same rate as water, and the vapor would be only mildly health
irritating even in a confined space.
INGESTION: May cause irritation of the mouth, throat and gastro-intestinal distress, nausea, vomiting
and diarrhea.
hazards
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
This product is not flammable. Fire fighters must wear SCBA and protective clothing. During combustion, oxides
of carbon and nitrogen may be formed; also toxic organic vapors and smoke. Closed containers may rupture in
fire conditions. Keep containers cool with water spray. fire and
REACTIVITY: Manufacturer lists no incompatible materials. reactivity
EXTINGUISHING MEDIA: DRY CHEMICAL, CO2, FOAM, WATER FOG
USAGE: General purpose cleaning of oil mud systems and as oil slick dispersant. Avoid breathing
vapors, mist or aerosol. NO smoking. Provide adequate ventilation.
TRANSPORT/ Store in a well ventilated, cool, dry area. Keep containers labeled, upright and tightly
STORAGE: closed when not in use. DO NOT store in direct sunlight. Avoid storage near heat, open
flames and incompatible materials. Always label containers for transporting in accordance handling
with DOT/IMO/IATA hazard warning labels.
SPILLS/ LEAKS: Stop the flow if it can be done safely. Dike to prevent entry into sewer. Absorb with sand
and place in clean, dry container.
storage
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
&
SAFETY Provide ventilation to control airborne concentrations below the guidelines. If there is high
EQUIPMENT: wind or a chance of splashing, safety goggles (S/N 21-434-249) should be worn to protect disposal
the eyes. Maintain an eyewash fountain and emergency shower where the material is
being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
INGESTION:
and wash clothing before re-use.
Do not induce vomiting. Aspiration of material into the lungs can cause chemical
first aid
pneumonitis, which can be fatal. Drink one-two glasses of water to dilute. Keep person
warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ), or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised 1/13/2001
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ), or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised 1/13/2001
CHEMICAL HAZARD BULLETIN NO. 254
S/N: 26-315-518 30 Gal Drum
26-315-475
GASOLINE DYE
Automate Red-B
(Ethyl Corporation)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised: 7/2/2001
CHEMICAL HAZARD BULLETIN NO. 256
S/N: 33-112-346
HARCO SOLV
(Chlorinated
Hydrocarbon
Solvent )
Health 3 BLUE MOBILE LIQUID WITH SOLVENT ODOR. MODERATELY CAS: 127-18-4
FLAMMABLE, HIGHLY VOLATILE, HIGHLY UN: 1897
Fire 2 IRRITATING TO EYES, NOSE AND THROAT. GUIDE: 160
Reactivity 2
HARCO SOLV is a moderately flammable liquid. It may burn moderately but will not ignite readily; the flashpoint
o o
is 63 C (145 F, T.C.C). In the event of a fire or upon exposure to intense short wave ultraviolet light, HARCO
SOLV can decompose to form highly toxic PHOSGENE GAS and HYDROCHLORIC ACID. FIREFIGHTERS
fire and
MUST WEAR SCOTT AIR PAKS (S/N 21-311-231).
EXTINGUISH FIRE WITH FOAM, CO2, STEAM, DRY CHEMICAL reactivity
USES: HARCO SOLV is an all-purpose solvent-degreaser.
STORAGE: Treat as a combustible material: avoid storage near sources of ignition or strong
SPILLS &
oxidizing materials. DO NOT STORE IN CONFINED SPACE SUCH AS A FLEXIVAN.
HARCO SOLV is 100% volatile; ventilate the spill area until all solvent evaporates. Shut handling
DISPOSAL : down nearby ignition sources and remove workers from immediate vicinity. Dispose by
ventilation/evaporation. Contact Environmental Engineering Division (874-6426 or 874-
6428) for disposal procedure.
storage &
SAFETY
EQUIPMENT:
Wear PVA-coated gloves (S/N 21-432-624) and goggles (S/N 21-434-249) to handle
HARCO SOLV. No respirator is needed if ventilation is very good; and organic cartridge disposal
(S/N 21-370-400) may be used when odor is detectable. In confined space wear an air-
supplied respirator. Maintain an eyewash fountain where handled.
VAPOR INHALED: Remove overcome or disoriented persons into fresh air. If breathing has stopped, give
mouth-to-mouth resuscitation.
EYE/SKIN
first aid
Hold eyelids open over a gentle stream of water. Wash exposed skin with soap and
CONTACT: water.
SWALLOWED: DO NOT INDUCE VOMITING: take victim to clinic, carry container or label from
container to inform doctor what was swallowed.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
*Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised: 5/13/2001
CHEMICAL HAZARD BULLETIN NO. 266
1000502460 100-ML BT
PERMOUNT
(Slide Set)
Health 2 CAS: Mixture
YELLOW LIQUID, WITH SOLVENT ODOR
Fire 4 EXTREMELY FLAMMABLE, MODERATELY TOXIC, AND STABLE. UN: 2925
Reactivity 0 IRRITANT TO THE RESPIRATORY TRACT, EYES, AND SKIN. GUIDE: 134
SKIN NOTATION. EAC: 1W
LIQUID/VAPOR: The product is a organic solution of 60% resins and 40% toluene (Skin,TLV=50ppm).
EFFECTS OF OVER-EXPOSURE:
health
INHALATION: Inhalation of vapor may cause irritation of the upper respiratory tract. Symptoms of
overexposure may include fatigue, confusion, headache, dizziness and drowsiness..
Chronic poisoning describe anemia, and decreased blood cell count. Liver and kidney
damage may occur.
hazards
EYE/ SKIN: Eye contact causes severe eye irritation with redness and pain. Skin contact may cause
irritation; may be absorbed through skin. Repeated or prolonged contact has a defatting
action, causing drying, redness, dermatitis.
INGESTION: Swallowing may cause abdominal spasms and other symptoms that parallel over-
exposure from inhalation. Aspiration of material into the lungs can cause chemical
pneumonitis, which may be fatal.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The flashpoint is 7°C (45°F); with explosive limits of 1.4 to 6.7%. Fire fighters must wear SCBA and
protective clothing. Fire produces carbon sulfur, and nitrogen oxides, and also toxic gases, vapors, fumes,
and smoke. Closed containers may rupture in fire conditions. Cool containers exposed to flames with water fire and
reactivity
spray until well after the fire is out.
REACTIVITY: Normally stable. Incompatible with strong oxidizers, e.g., nitric acid. Heat, flames, and
sources of ignition.
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY/FOG, FOAM, OR CO2
USAGE: For microscopic analysis in histology Labs. Avoid breathing vapor and avoid eye and skin
contact. NO SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, use DOT-IMO Class 3 hazardous
warning labels (diamond): FLAMMABLE LIQUID N.O.S.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves and an apron
(1000128583) must be worn when handling this material. APR”O” (1000128163) or SCBA
(1000127427) should be worn if conditions warrant. Maintain an eyewash fountain and
emergency shower (1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 12/18/2004
CHEMICAL HAZARD BULLETIN NO. 270
INVERMUL 1000022175 55 GA DM
(Oil Mud Emulsifier)
EFFECTS OF OVER-EXPOSURE:
EYE/ SKIN: May cause skin irritation and severe eye irritation.
May cause respiratory irritation. May cause central nervous system depression including
health
INHALATION:
headache, dizziness drowsiness, incoordination, slowed reaction time, and
unconsciousness. hazards
Aspiration into the lungs may cause chemical pneumonitis including coughing, difficulty
INGESTION:
breathing, wheezing, coughing up blood and pneumonia, which can be fatal.
WEAR GOGGLES, RUBBER GLOVES & APRON TO HANDLE INVERMUL
Invermul is a combustible liquid. The flashpoint is 69 ºC (156 oF) (Pensky Martin Closed Cup), the flammable
limits are not reported by the manufacturer. Hazardous products of decomposition include oxides of nitrogen,
hydrocarbons, carbon monoxide and carbon dioxide. Firefighters should wear Self-Contained-Breathing-Apparatus fire and
reactivity
(1000127491).
REACTIVITY: This material is stable but incompatible with strong oxidizers such as chromates, perchlorates or
strong acids.
EXTINGUISH AREA FIRES WITH WATER SPRAY, CO2 FOAM OR DRY CHEMICAL
USES:
Invermul is used to emulsify the muds used in drilling. Avoid breathing vapor, and avoid
eye and skin contact. NO SMOKING. Provide adequate ventilation
STORAGE: Do not store near flames, sparks, or welding operations. Store in well ventilated, cool, dry
area away from incompatible materials. Store separately from oxidizers/acids. Keep
TRANSPORT:
containers upright and tightly closed when not in use.
For transportation, label with a DOT-IMO class 3 hazard warning placard.
handling
SPILLS/LEAKS: If spill occurs in a confined space, wear a supplied air respirator. Wear goggles and
gloves in an open space with adequate ventilation to clean; contain with sand and flush
storage
DISPOSAL:
spills with water. Clean up with sand or vermiculite- TOXIC TO FISH.
For proper disposal methods and locations for the chemical or chemical contaminated &
disposal
material, contact the Environmental Engineering Division at 874-6426 or 873-6676.
SAFETY Wear goggles (1000129810), rubber gloves (1000129628) apron (1000128583), and
EQUIPMENT: rubber boots (1000128971) to handle Invermul. If there is a potential for exposure to
high concentrations, use an organic vapor respirator with a dust/mist filter. If containers
must be open in a confined space, supplied air breathing apparatus should be worn.
Maintain an eyewash fountain (1000128023) where this material is handled or stored.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
EYE/SKIN Remove overcome worker into fresh air; give mouth-to-mouth resuscitation if breathing
CONTACT: has stopped. If breathing is difficult give oxygen.
INHALATION: IMMEDIATELY flush affected skin area and/or eyes with water for at least 15 minutes
first aid
while holding eyelids open. If symptoms persist, seek medical advice. Remove
contaminated clothing and launder before reuse.
INGESTION: Do not induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Give water. Wash out mouth thoroughly. Drink one-two
glasses of water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Environmental Protection: 872-2623 (DH), 678-4902 (RT), 574-4722 (ABQ) or 427-0155(JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:6/20/2004
CHEMICAL HAZARD BULLETIN NO. 276
1000022176 5-GL DM
OMC
health
INHALATION: Inhalation of vapor and mists may irritate the respiratory tract, the nose and throat.
Symptoms include headache, nausea, and vomiting. Prolonged or repeated exposure
may cause chronic respiratory tract irritation. May affect CNS.
hazards
EYE/ SKIN: Eye contact may cause irritation, characterized by burning sensation, redness, tearing,
inflammation, and possible corneal injury. Skin contact may cause defatting
sensitization, an allergic reaction and dermatitis.
INGESTION: Can cause gastrointestinal distress, throat, and stomach pain. Also, vomiting, diarrhea.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The flashpoint is 24°C (76°F); no explosive range was reported. Fire fighters must wear SCBA and
protective clothing. Fire produces carbon, sulfur, and nitrogen oxides, and also toxic gases, vapors, fumes,
and smoke. Closed containers may rupture in fire conditions. Cool containers exposed to flames with water fire and
reactivity
spray until well after the fire is out.
REACTIVITY: Normally stable. Incompatible with strong oxidizers, e.g., nitric acid. Heat, flames, and
sources of ignition.
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY/FOG, FOAM, OR CO2
USAGE: Additive to drilling mud in oil operations. Avoid breathing vapor, mists, dust and mists and
avoid eye and skin contact. NO SMOKING. Provide adequate exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, use DOT-IMO Class 3 hazardous
warning labels (diamond): FLAMMABLE LIQUID, N.O.S.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves and an apron
(1000128583) must be worn when handling this material. APR (1000128163) or SCBA
(1000127427) should be worn if conditions warrant. Maintain an eyewash fountain and
emergency shower (1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 1/1/2005
CHEMICAL HAZARD BULLETIN NO. 281
S/N 26-375-546 1 Pint bottle
ETHYL 26-375-555 5 Gal. can
26-375-656 5 Gal. can
ALCOHOL 26-375-678 5 Gal. can
[Ethanol]
VAPOR: The Threshold Limit Value for ethyl alcohol is 1,000 ppm.
EFFECTS OF OVER-EXPOSURE:
EYE/ SKIN: Highly irritating if splashed into eyes. Prolonged skin exposure may cause dermatitis with
INHALATION:
drying and fissuring.
High vapor concentration may cause upper respiratory tract irritation, chest pain, and
health
INGESTION:
coughing.
May cause dizziness, faintness, decreased awareness and responsiveness, nausea, hazards
vomiting and coma.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
0 0
The flashpoint for this product is >58 F (>14 C) with a given explosive range in air of 3.3% (LEL) to 19% %(UEL).
Firefighters must wear SCBA and protective clothing. Vapors may travel to a source of ignition and flash back.
During combustion, oxides of carbon, nitrogen and sulfur may be formed; also toxic vapors and smoke. Closed
containers may rupture in fire conditions. Keep containers cool with water spray. fire and
REACTIVITY: Avoid contact with strong oxidizers such as chlorates, chromates, peroxides, nitric acid and
permanganates. reactivity
EXTINGUISH FIRES WITH ALCOHOL FOAM CO2, OR DRY CHEMICALS
USAGE: Solvent in medical and dental laboratory and pharmacy. Avoid breathing vapor or mist.
NO smoking. Provide adequate ventilation.
TRANSPORT/ STORE IN FLAMMABLE LIQUIDS STORAGE CABINET well removed from incompatible
STORAGE: chemicals. Keep containers labeled and tightly closed when not in use. DO NOT store in
direct sunlight. Always label containers for transporting in accordance with DOT/IMO/IATA
handling
hazard warning labels.
SPILLS/ LEAKS: Shut off ignition sources and clean spill immediately. Absorb onto vermiculite, shovel into
container and dispose in flameproof container.
storage
DISPOSAL: For proper disposal methods and disposal sites, contact the Environmental Engineering
Division at 874-6426 or 874-6428.
&
SAFETY
EQUIPMENT:
Provide ventilation to control airborne concentrations below the TLVs. Safety goggles
and neoprene gloves must be worn when handling this material. SCBA should be worn if disposal
conditions warrant. Maintain an eyewash fountain and emergency shower where the
material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
INGESTION:
and wash clothing before re-use.
Do not induce vomiting. Aspiration of material into the lungs can cause chemical
first aid
pneumonitis, which can be fatal. Drink one-two glasses of water to dilute. Keep person
warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ), or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised 1/13/2001
CHEMICAL HAZARD BULLETIN NO. 282
1000186821 500-GM BT
TANNOUS
CHLORIDE
health
INHALATION: Inhalation of dust and mists may irritate and burn the respiratory tract, cause tissue
destruction of the nose and throat. Symptoms include may include sore throat,
coughing and labored breathing. Target organs: Liver, kidneys, respiratory tract.
hazards
EYE/ SKIN: Contact with skin or eyes may cause severe irritation or burns. Prolonged contact may
cause skin sensitization. Substance is readily absorbed through the skin.
INGESTION: Ingestion may cause burning in mouth and throat, vomiting, abdominal pain, diarrhea,
reduced blood pressure, stomach bleeding, collapse and Convulsions. May cause liver
and kidney damage.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product is not flammable or combustible. Fire fighters must wear SCBA and protective clothing. Fire
produces hydrogen chloride and carbon, lead, and nitrogen oxides, and also toxic gases, vapors, fumes,
and smoke. Closed containers may rupture in fire conditions. Cool containers exposed to flames with water fire and
reactivity
spray until well after the fire is out.
REACTIVITY: Hygroscopic, absorbs moisture from air . Incompatible with strong oxidizers, e.g., nitric acid.
Heat, flames, and sources of ignition.
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY/FOG, FOAM, OR CO2
USAGE: Laboratory reagent. Avoid breathing dust and mists and avoid eye and skin contact. NO
SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, use DOT-IMO Class 8 hazardous
warning labels (diamond): CORROSIVE SOLID, N.O.S.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves and an apron
(1000128583) must be worn when handling this material. APR (1000128210) or SCBA
(1000127427) should be worn if conditions warrant. Maintain an eyewash fountain and
emergency shower (1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 1/1/2005
CHEMICAL HAZARD BULLETIN NO. 286
ALDEHYDE
(Polymerized
formaldehyde)
VAPOR: There is no TLV set for paraformaldehyde, which decomposes into formaldehyde when
heated. The TLV for formaldehyde (1984) is 0.3 ppm.
STORAGE: KEEP CONTAINERS TIGHTLY CLOSED when not in use, to avoid absorption of water
and release of formaldehyde vapor. Store well removed from heat, sources of ignition
handling
and oxidizers.
storage
SPILLS: Sweep up solid into a closed container. Contact Environmental Engineering (874-6426 or
874-6428) for disposal procedure and locations. &
SAFETY
EQUIPMENT:
Wear chemical cartridge respirator with organic vapor cartridge: keep Scott Air Pak for
emergency. ALWAYS WEAR GOGGLES and PVC GLOVES to handle
disposal
paraformaldehyde. Eyewash fountains and emergency fountains must be maintained in
storage and handling areas.
EYE/SKIN Hold eyelids open over steady stream of water for 15 minutes. Wash skin with soap and
CONTACT: water.
VAPOR INHALED: Remove victim to fresh air. If breathing has stopped, give mouth-to-mouth resuscitation. first aid
SWALLOWED: Give water; carry victim to clinic. Inform doctor paraformaldehyde was swallowed.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
*Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised: 10/21/2001
CHEMICAL HAZARD BULLETIN NO. 293
THIOPHENE
(CS CAPTAN,
gas odorant)
VAPOR: There is no Threshold Limit Value for thiophene, an organic sulfur compound. Thiophene
is moderately volatile (vapor pressure is 40 mm Hg) and vapor may accumulate in a
confined space to irritate eyes, nose and throat. The lethal vapor concentration in animal
experiments is 8700 ppm.
health
LIQUID: Splashed into eyes, may strongly irritate. A non-water soluble solvent.
Prolonged skin exposure may cause drying, defatting and reddening, dermatitis.
Swallowed, this solvent may be regurgitated and a small amount aspirated into the lungs
hazards
can cause chemical pneumonia.
o o
THIOPHENE IS AN EXTREMELY FLAMMABLE MATERIAL. The flashpoint is –1.1 C (30 F). Vapor is heavier
than air, may travel some distance to an ignition source and flashback. Incompatible with oxidizing materials.
THIOPENE MAY EXPLODE ON CONTACT WITH NITRIC ACID (HNO3). Hazardous products of decomposition
fire and
include sulfur oxides. Firefighters should wear Scott Air Pak (S/N 21-311-231).
reactivity
EXTINGUISH FIRES WITH DRY FOAM, CO2 DRY CHEMICAL
USES: Found in coal tar and coal gas, an impurity in technical benzene, thiophene is used in
many industrial process as a solvent. ARAMCO uses it as an odorant for natural gas and
LPG.
STORAGE: OBSERVE PRECAUTIONS FOR FLAMMABLE LIQUIDS. Store in cool or shaded open
handling
area, well removed from ignition sources and from oxidizing agents.
SPILLS: SHUT DOWN ALL IGNITION SOURCES. Dike a large spill with sand, pump into drum for
storage
removal to redundant chemical storage facility. Wash down spill area with water. Contact
Environmental Engineering (874-6426 or 874-6428) for disposal procedure and locations.
&
SAFETY Organic vapor respirator will protect except in a confined space, where a supplied air disposal
EQUIPMENT: respirator should be worn. Wear rubber gloves and goggles or face shield. Maintain an
emergency shower and eye wash fountain where chemicals are used or stored.
VAPOR / INHALED: Remove overcome victim into fresh air. Give mouth-to-mouth resuscitation if breathing
has stopped.
EYE/SKIN Hold eyelids open over running water for 15 minutes. Remove contaminated clothing and
CONTACT: wash skin with soap and water. Launder clothing before reuse.
first aid
SWALLOWED: DO NOT INDUCE VOMITING. Tell the doctor an organic sulfur compound was
swallowed.
GET MEDICAL AID
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
*Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised: 10/21/2001
CHEMICAL HAZARD BULLETIN NO. 294
ZINC AND
ZINC OXIDE
POWDER DUST OR The Threshold Limit Value for zinc oxide fume is 5 mg/m3. Zinc oxide dust is classified as
FUME: an irritant.
Pure zinc powder is a skin irritant. When heated to its boiling point (509oC), zinc forms a
fume which rapidly oxidizes. (also known as zinc chills and brass founder’s ague).
Symptoms include delayed onset of fever, chills, muscular pain, nausea and vomiting. health
However, complete recovery occurs within one to two days. Exposure to metal fumes
other than zinc may cause these same symptoms. Finely powdered zinc oxide inhaled
may have the same effect. “Metal fume fever” is an annoying but temporary condition,
hazards
and not considered serious. Swallowing powders or dusts for zinc may lead to gastritis
and vomiting.
WEAR A RESPIRATOR TO HANDLE ZINC COMPOUNDS
Zinc dusts or powders, when exposed to heat or flame, are a moderate fire hazard. If stored in damp places, there
is a danger of spontaneous combustion. Powdered zinc metal and oxide are incompatible with ammonium nitrate,
barium compounds, cadmium, chlorate and chlorides, hydroxylamine, chlorinated rubber, catalytic metals,
fire and
halogenated carbon compounds, oxidants and transition metal halides. Zinc oxide reacts violently with chlorinated
rubber, magnesium or linseed oil. Firefighters should wear a Scott Air Pak (S/N 21-311-231). reactivity
EXTINGUISH FIRES WITH PULVERISED MINERAL CARBONATE OR DOLOMITE
USES: Metallic zinc is used in galvanizing metals, electroplating, and alloy to make brass and
bronze. Zinc oxide is used in pigments, rubber, cosmetics and ointments and electronic
devices.
STORAGE: No special precautions need be taken to store, other than to keep lids tightly closed. handling
Store in dry area.
SPILLS: Wear a dust respirator. Sweep spilled material into a container, dispose in a sanitary
storage
landfill. Contact Environmental Engineering (874-6426 or 874-6428) for disposal
procedure and locations. &
SAFETY
EQUIPMENT:
Wear a dust respirator to handle powdered zinc and zinc oxide. A chemical cartridge
respirator must be worn where fumes are generated. Rubber gloves and goggles should
disposal
be worn if handling powder. Maintain an eyewash fountain where chemicals are used.
FUMES / INHALED: Remove overcome worker into fresh air. Wrap victim in blanket if he has chills. Take
victim to clinic.
EYE/SKIN Hold eyelids open over running water for 15 minutes. If irritation persists, see a physician.
CONTACT: Wash exposed skin with soap and water. first aid
SWALLOWED: Give water and take victim to doctor. Tell the doctor zinc was swallowed.
GET MEDICAL AID
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
*Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised: 10/21/2001
CHEMICAL HAZARD BULLETIN NO. 295
3
MIST OR DUST: The Threshold Limit Value for zirconium compounds is 5 mg/m , adopted to protect
against a slightly toxic metal. Animals exposed for one year to a mist of zirconium
3
oxychloride (3.5 mg Zr/m ), exhibited no symptoms or adverse effects. Workers exposed
to fumes of the zirconium reduction process for one to five years experienced no serious
problems referable to zirconium exposure. In the same study, guinea pigs were exposed
continuously at several steps of the zirconium process for 2 to 6 months and showed no
pulmonary changes or lung damage from the exposure. health
SOLUTION: H
Water solutions of zirconyl chloride are irritating to skin or eyes. The p is equal to that of
hydrochloric acid of the same concentration. Zirconium compounds are used in underarm
hazards
deodorants. An inorganic zirconium salt, Na Zr, is a skin sensitizer and formed zirconium
granulomas in allergic individuals. Zirconyl chloride is used in deodorants, apparently
without causing granulomas.
Swallowed, animal studies indicate zirconium compounds have very low oral toxicity.
Finely divided zirconium metals is easily ignited in air. Molten zirconium is extremely reactive. Zirconium and
zirconium alloys react violently with acid solutions. Zirconium fires and explosions have occurred upon reaction
with carbon tetrachloride, nitrogen, zirconium tetrachloride, magnesium chloride and potassium bisulfate.
fire and
ZIRCONIUM FIRES CANNOT BE EXTINGUISHED BY ORDINARY MEANS: reactivity
MUST BE SMOTHERED WITH SOME PULVERISED MINERAL CARBONATE, SUCH AS DOLOMITE
STORAGE: Keep in dry area with lids tightly sealed, well removed from oxidizing agents.
handling
SPILLS: Wear gloves. Scoop material up into disposable container. Cart to redundant chemical storage
storage. Contact Environmental Engineering (874-6426 or 874-6428) for disposal
procedure and locations. &
SAFETY
EQUIPMENT:
Rubber gloves and safety goggles should be worn to handle zirconium compounds.
Maintain an eyewash fountain where chemicals are used. disposal
EYE/SKIN Hold eyelids open and wash out with plenty of water for 15 minutes. Remove clothes and
CONTACT: wash skin with soap and water. Launder clothes before reuse.
first aid
SWALLOWED: Give water but DO NOT INDUCE VOMITING. Take victim to clinic.
GET MEDICAL AID
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
*Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised: 10/21/2001
CHEMICAL HAZARD BULLETIN NO. 307
(Chlorinated
Hydrocarbon
Solvent)
Health 3 THIN, COLORLESS LIQUID WITH ETHER-LIKE ODOR, CAS: Mixture
IRRITATING TO SKIN, EYES, RESPIRATORY TRACT AND UN: 2810
Fire 2 GASTROINTESTINAL TRACT, GUIDE: 153
Reactivity 2 MODERATELY FLAMMABLE AND REACTIVE
LIQUID: Mixture of methylene chloride (OSHA PEL 25 ppm, STEL 125 ppm), perchloroethylene
®
(TLV 25 ppm, STEL 100 ppm), and aliphatic hydrocarbon (TLV 150 ppm). Methylene
chloride and perchloroethylene are considered to be suspected human carcinogens by
some governmental agencies.
EFFECTS OF OVEREXPOSURE:
EYE/SKIN: Eye irritant with possible pain. Repeated exposure causes dry, cracked skin. May be
absorbed through skin in toxic amounts.
health
INHALATION: Upper respiratory tract irritant. Excessive exposure causes anesthesia, headaches,
hazards
dizziness and nausea. Prolonged inhalation can damage kidneys and liver. CNS
depressant.
INGESTION:
May irritate gastrointestinal tract.
EYE/SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
first aid
INGESTION: DO NOT induce vomiting. If conscious, drink one-two glasses of water to dilute. Keep
person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:4/10/2001
CHEMICAL HAZARD BULLETIN NO. 322
AQUAGEL 1000021551 SK
(Bentonite) 1000021552 LB
1000021553 SK
POWDER/ The product is anhydrous silicate of alumina. It is also known as Wyoming sodium
DUST: Bentonite or Sodium monotmorillonite. It contains >1% free crystalline silica (TLV
3
respirable =0.05 mg/m ).
EFFECTS OF OVER-EXPOSURE:
health
INHALATION: Repeated or prolonged inhalation may cause serious chronic health hazards such as
pneumoconiosis or silicosis and cancer. Symptoms include cough, short of breath, and
wheezing. Delay effects can be disabling and fatal illness.
EYE/ SKIN: May cause eye and skin irritation as nuisance dust. hazards
INGESTION: Gastrointestinal distress, nausea, vomiting, diarrhea, and abdominal pain.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product in not flammable or combustible. However, fire fighters must wear SCBA and protective clothing
for protection from hazardous products from surrounding fires such as carbon and nitrogen oxides, toxic
gases, vapors, fumes, and smoke. Closed containers may rupture in fire conditions. Cool containers fire and
reactivity
exposed to flames with water spray until well after the fire is out.
REACTIVITY: Normally stable.
EXTINGUISHING MEDIA: USE MEDIA SUITABLE FOR SURROUNDING FIRES
USAGE: Emulsifier in crude oil operations. Avoid breathing dusts and avoid eye and skin contact.
NO SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area. Keep tightly closed when not in use. For
TRANSPORT: transportation, product is not regulated. Packages do not require DOT-IMO warning labels
(Diamond).
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer.
LEAKS: Shovel and place into clean, dry, labeled containers. Product cause slippery surfaces
when wet. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 873-6676.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves and an apron
(1000128583) must be worn when handling this material. SCBA (1000127427) should be
worn if conditions warrant. Maintain an eyewash fountain and emergency shower
(1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-4538 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 3/28/2004
CHEMICAL HAZARD BULLETIN NO. 334
health
INHALATION: Inhalation of THF vapor may cause irritation of the mucous membranes and upper
respiratory tract. Symptoms include severe headache, coughing, sneezing, and difficulty
in breathing. THF is a central nervous system depressant, it and liver and kidney damage.
Long-term exposure may lead to kidney or liver damage, and narcotic effects.
hazards
EYE/ SKIN: Eye contact may cause irritation, redness and inflammation of the eyes and eyelids. Skin
contact may cause irritation, dryness, cracking, and defatting.
INGESTION: Can cause distress of the gastrointestinal system, with symptoms include vomiting, and
diarrhea. Swallowed will damage liver and kidney. If regurgitated, it may be aspirated into
lungs causing chemical pneumonia.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product extremely volatile and flammable. Fire fighters must wear SCBA and protective clothing. Fires
produce fluorine, carbon, and nitrogen oxides, and also toxic gases, vapors, fumes, and smoke. Closed
containers may rupture in fire conditions. Cool containers exposed to flames with water spray until well after fire and
reactivity
the fire is out.
REACTIVITY: Normally stable, but may form explosives on contact with air. Incompatible with strong
oxidizers, e.g., oxygen and nitric acid. Heat, flames, and sources of ignition. Tetrahydrofuran forms
explosive peroxides around containers if stored for prolonged periods.
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY/FOG, FOAM, OR CO2
USAGE: Adhesive for PVC conduits. Avoid breathing vapor and avoid eye and skin contact. NO
SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, use DOT-IMO Class 3 hazardous
warning labels (diamond): FLAMMABE LIQUIDS
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene gloves (1000129418) must be worn when handling this
material. APR”O” (1000128213) or SCBA (1000127427) should be worn if conditions
warrant. Maintain an eyewash fountain and emergency shower (1000128433) where the
material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 10/26/2004
CHEMICAL HAZARD BULLETIN NO. 336
S/N 27-876-000 25 Kg Drum
TANNIC ACID
PTB
SOLID/DUST: No occupational exposure limits have been assigned for this complex mixture of
substances. Tannic acid occurs naturally and is found in many foods. Humans may ingest
up to 1 g/day.
INHALATION: Dust will cause irritation of the respiratory tract, bronchitis and possibly pneumonia
following high exposures. health
EYE/SKIN: Moderate eye irritant but permanent damage may be caused if not treated promptly.
INGESTION:
Prolonged skin contact will cause pain and irritation owing to astringent action.
Nausea, vomiting and abdominal pain. Ingestion of large amounts will cause liver and
hazards
kidney damage.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
o
Moderately flammable, flashpoint is 138 F. Acrid smoke and fumes will be emitted if in contact with a fire. Fire
fighters should wear self-contained breathing apparatus (SCBA) and full protective clothing. fire and
REACTIVITY: Avoid contact with oxidising agents, heavy metal salts, proteins
reactivity
EXTINGUISH FIRES WITH WATER SPRAY, CO2, DRY CHEMICAL OR FOAM
INHALATION: Remove those exposed to fresh air. If breathing is difficult administer oxygen. If breathing
has stopped, apply cardio-pulmonary resuscitation (CPR).
first aid
INGESTION: Give water or milk to drink if conscious. DO NOT INDUCE VOMITTING
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
*Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised: 4/8/2001
CHEMICAL HAZARD BULLETIN NO. 337
Health 2 PALE BROWN OR YELLOW POWDER WITH A MILD ASTRINGENT CAS: 1401-5504
ODOR. SKIN ABSORBENT,
Fire 1 MODERATELY TOXIC. NON-FLAMMABLE UN: None
Reactivity 2 MODERATELY REACTIVE. GUIDE: None
SOLID/DUST: No occupational exposure limits have been assigned for this complex mixture of
substances. Tannic acid occurs naturally and is found in many foods. Most adults may
ingest up to 1 g/day from these natural sources without health effects.
EYE/SKIN:
EFFECTS OF OVER EXPOSURE:
Moderate eye irritant but permanent damage may be caused if not treated promptly. health
hazards
Prolonged skin contact will cause pain and irritation owing to astringent action. Tannic
acid may be absorbed through the skin in harmful amounts.
INHALATION: Inhalation causes irritation of the respiratory tract, bronchitis and possibly pneumonia
following high exposures.
INGESTION: Ingestion of significant quantities causes nausea, vomiting and abdominal pain. Ingestion
of large amounts will cause liver and kidney damage.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
Non-flammable, but combustible when exposed to flame, the flash point for dust is given as 390o F (200o C) and no
explosive range is given. Acrid smoke and fumes will be emitted if in contact with a fire. During a fire irritating and
highly toxic gases may be generated by thermal decomposition or combustion. Fire fighters should wear self- fire and
contained breathing apparatus (SCBA) and full protective clothing.
REACTIVITY: Avoid contact with oxidizing agents, strong bases, heavy metal salts, and proteins. Decomposition
o o
temperature is given as 424 F (218 C).
reactivity
EXTINGUISH FIRES WITH WATER SPRAY, CO2, DRY CHEMICAL OR FOAM
USES: Water treatment chemical in RO plants. Tanning agent. Avoid generating and breathing
dust and avoid eye and skin contact. No smoking. Provide adequate ventilation.
STORAGE: Keep containers tightly closed. Store in a well ventilated, cool dry area, away from
incompatible materials.
TRANSPORT: For transportation, no DOT-IMO hazardous warning label (diamond) is required.
handling
SPILLS/LEAKS: Evacuate unnecessary personnel. Avoid the generation of dust by using wet methods.
DISPOSAL:
Shovel into a clean, dry closed container and label.
Contact Environmental Engineering (874-6426 or 874-6428) for disposal procedure and
storage
locations.
&
SAFETY
EQUIPMENT:
Wear appropriate chemical protective gloves (neoprene, S/N 21-432-080), chemical
goggles (21-434-249) and dust mask (21-21-370-500) and protective clothing if handling
large quantities. Maintain eyewash fountain (S/N 21-333-573) and emergency shower
disposal
where stored and used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
EYE/SKIN Flush eyes with copious amounts of water for at least 15 minutes holding eyelids apart.
CONTACT: Remove contaminated clothing or shoes. Launder clothing before re-use. Wash skin
thoroughly with soap and water. Seek medical attention.
INHALATION: Remove those exposed to fresh air. If breathing is difficult administer oxygen. If breathing
INGESTION:
has stopped, apply cardio-pulmonary resuscitation (CPR). Keep warm and quiet.
Wash out mouth with water . Give water or milk to drink if conscious. DO NOT INDUCE
first aid
VOMITTING.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
*Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised: 10/27/2002
CHEMICAL HAZARD BULLETIN NO. 343
SURFLO-H35
(Baroid scale
preventive)
VAPOR: There is no Threshold Limit Value established for SURFLO-H35, which consists of
sodium methylphosphonate in water. This material is 60% volatile by volume: primarily
water vapor evaporates. Overexposure to vapor in a confined space may cause slight
and transitory irritation to eyes, nose and throat. health
LIQUID: Splashed into eyes, causes moderate irritation, similar to that caused by soap.
Prolonged and repeated skin contact may result in dry, cracked and reddened skin. hazards
Swallowed, SURFLO-H35 causes nausea.
Slightly reactive, the water-based alkaline SURFLO-H35 corrodes mild steel, copper, brass, or aluminum pump
fire and
parts. Injection pump parts and lines should be stainless steel or plastic.
reactivity
EXTINGUISH FIRES WITH WATER, FOAM, OR CO2
USES: For inhibition of scale deposits such as calcium carbonate, calcium sulfate or barium
sulfate and removal of scale deposits in producing wells, water injection systems,
cooling water systems. handling
STORAGE: No special storage precautions are required.
storage
SPILLS: Flush a spill into sewer with copious amounts of water. Contact Environmental
Engineering Division at 874-6426 or 874-6428 for disposal procedures. &
SAFETY
EQUIPMENT:
Direct skin or eye contact with SURFLO H35 should be avoided. Wear chemical
goggles and neoprene gloves to handle this scale preventive. Respiratory protection
disposal
should not be necessary. Maintain an eyewash fountain where chemicals are stored or
handled.
EYE/SKIN Hold eyelids open over a gentle stream of water for 15 minutes. If irritation persists,
CONTACT: see a physician. Wash skin with soap and water. Launder clothes before reuse.
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
*Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised: 10/21/2002
CHEMICAL HAZARD BULLETIN NO. 350
health
concentrations of 8,000 to 13,500 ppm. Irritation and respiratory arrest occurs at lower
levels of octane than for other alkkanes. NIOSH has recommended a workplace. TWA
STANDARD OF 756 ppm for octane.
LIQUID: Splashed into eyes, is very irritating, may cause burns. Prolonged skin contact cuase
hazards
drying and defatting, cracked skin may result in bacterial infections.
Swallowed, regurgitated and aspirated into lungs, octane may cause rapid death from
cardiac arrest, respiratory paralysis and asphyxia.
WEAR GLOVES, GOGGLES AND RUBBER APRON TO HANDLE OCTANE
OCTANE IS AN EXTREMELY FLAMMABLE LIQUID. The flashpoint of m-octane is 56oF, and of iso-octane is
10oF (closed cap). The flammable limits of octanes are 0.96 to 4.66% by volume.
A POTENTIAL FIRE AND DISASTER HAZARD, OCTANE IS DANGEROUS IF EXPOSED TO HEAT OF
FLAME: CAN REACT VIGOROUSLY WITH OXIZIERS.
fire and
Firefighter should wear Scott Air Pak (S/N 21-311-231). reactivity
EXTINGUISH FIRES WITH CO2 FOAM OR DRY CHEMICAL
USES: High octane hydrocarbon and lead compound supply the most important property of
gasoline, the “octane number”. Iso-Octane is the standard for antiknock properties of
gasoline (petrol).
STORAGE: Flammable liquid storage cabinet is preferred. Store well removed form heat, sparks,
flames or any sources of ignition. Store removed from oxidizers such as nitric acid, handling
chromates or peroxide compounds.
SPILLS: SHUT OFF IGNITION SOURCES. Wear supplied-air respirator if large spill occurs in
storage
confined space. Adsorb spill on sand, ventilate to remove vapor. Cart sand to outlying
area, removed from ignition sources. Contact Environmental Engineering Division at &
disposal
874-6426 or 874-6428 for disposal procedures.
SAFETY Wear rubber gloves and apron; protect eyes with goggles or face shield. To enter
EQUIPMENT: storage tank or work with octane in a confined space, a supplied – air respirator must
be worn.
INHALED VAPOR: DON A SCOTT AIR PAK TO RESCUE VICTIM. Remove to fresh air, if breathing has
stopped give mouth-to-mouth resuscitation.
EYE/SKIN Hold eyelids open over water stream for 15 minutes. Remove contaminated clothes
CONTACT: and wash with soap and water.
first aid
SWALLOWED: Give water but DO NOT INDUCE VOMITING unless instructed by a doctor. Take
victim to hospital.
GET MEDICAL AID
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
*Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised: 10/21/2002
CHEMICAL HAZARD BULLETIN NO. 366
SILICONE
S/N 26-010-037 Dow Corning 200 Fluid-100cst
EMULSION 26-010-087 Dow Corning 200 Fluid-1000cst
(Dimethylpolysilixane, 26-301-748 SF81-50
26-301-776 Dow Corning DB-310
hexamethyldisiloxane, 26-301-777 Dow Corning DB-310
antifoam emulsion) 26-319-734 Dow Corning Antifoam AF
EYE/SKIN:
EFFECTS OF OVEREXPOSURE:
Direct eye contact with liquid produces temporary discomfort with mild redness and health
dryness. No adverse effects with prolonged skin contact of up to 48 hours.
INHALATION:
Not irritating to respiratory tract. No injury with exposures of less than 8 hours. hazards
INGESTION: Ingesting large amounts may cause digestive discomfort.
TRANSPORT: For transportation, packages do not require DOT-IMO hazardous warning label
handling
(diamond).
storage
DISPOSAL: For proper disposal methods and locations for chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428. &
SAFETY
EQUIPMENT:
Provide general ventilation. Safety glasses should be worn when handling this material.
Maintain an eyewash fountain and emergency shower where the material is being
disposal
stored/used.
EYE/SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
first aid
INGESTION: No first aid required. Treat symptomatically.
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:7/2/2001
CHEMICAL HAZARD BULLETIN NO. 375
POLY
CHLORINATED DIRECT CHARGE
BIPHENOL
(PCB)
chlorodiphenyls
Health 3 TINTED LIQUID. LIQUID IS HIGHLY TOXIC (CHRONIC). CAS: 1336-36-3
SLIGHTLY FLAMMABLE AND REACTIVE. UN: 2315
Fire 1 SKIN NOTATION. GUIDE: 171
Reactivity 1
LIQUID: Polychlorinated Biphenyls (PCBS) consist of mixture of homologous and /or isomeric
chlorinated biphenyl. The TLV for chlorodiphenyls 60 and 54%(Arochlor 1254) by weight
is 0.5 PPM and 42% (Arochor 1242) is 1 PPM.
EFFECTS OF OVEREXPOSURE:
EYE/SKIN: Vapor and liquid my cause eye irritation. Skin contact causes moderate irritation. May be
absorbed through skin to affect liver and systemic poisoning. Degree of injury depends on health
the amount absorbed. Can cause dermatitis, chloracne and skin discoloration. IARC lists
INHALATION: as can probably cause cancer. Degradation inhalation may cause respiratory tract
irritation including sore throat, coughing, bronchitis, pulmonary edema and difficulty
hazards
breathing. Degree of injury depends on airborne concentration and duration of exposure.
INGESTION: Toxic if swallowed and causes nausea, digestive disturbances, vomiting, abdominal pain
and can possibly cause death.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The flashpoint for this product is >135°C (275°F). Firefighters must use self-contained breathing apparatus (SCBA)
and protective clothing. During combustion, toxic hydrogen chloride, polychlorinated dibenzodioxins, furan,
phenolics, aldehydes, oxides of carbon and other toxic compounds may be formed. A major toxic concern is fire and
reactivity
inhalation of heat degradation products. Closed containers may rupture in fire conditions. Keep containers cool
with water spray. Vapors are heavier than air and can flow along surface to distant ignition sources and flashback.
REACTIVITY: May react with strong oxidizing agents, including chlorates, nitrates and peroxides.
EXTINGUISH AREA FIRES WITH WATER SPRAY OR MEDIA APPROPRIATE TO SURROUNDING FIRE
USES: This product may be present in capacitors, transformers, heat exchangers, circuit
breakers, natural gas compressors and hydraulic systems. Use adequate ventilation. No
smoking. Avoid skin contact. Do not breathe vapors or mist. Wash hands thoroughly
before eating or smoking.
STORAGE: Store in a well-ventilated, cool, dry area, away from ignition sources. Keep containers
labeled, upright, and tightly closed when not in use. Avoid storage near incompatible handling
TRANSPORT: material, food, feed or drinking water. For transportation, packages do not require DOT-
SPILLS/LEAKS:
IMO hazardous warning label (diamond).
Evacuate all unnecessary personnel. Wear SCBA and PPE. Replace gloves immediately
storage
if any evidence of degradation or chemical breakthrough. Stop the flow if it can be done
safely. Dike to prevent entry into sewer. Absorb with sand, place in a clean, dry, closed &
disposal
DISPOSAL: container, and label. For proper disposal methods and locations for the chemical or
chemical contaminated material, contact the Environmental Engineering Division at 874-
6426. Follow all MSDS and label warnings even after container is empty.
SAFETY Provide ventilation to control exposures below the TLVs. Air supplied or SCBA
EQUIPMENT: (1000127427) should be available. Chemical goggles (1000129810), face shield,
neoprene gloves (1000129418), apron (1000128583), and boots (1000128971) must be
worn when handling this material. APR or SCBA should be worn if conditions warrant.
Maintain an eyewash fountain and emergency shower where the material is being
stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
EYE/SKIN Flush eyes with large amounts of water for at least 15 minutes. Lift eyelids occasionally.
CONTACT: Wash skin thoroughly with soap and water. Remove contaminated clothing and shoes
promptly, and wash clothing. Discard contaminated and non-water proof shoes and boots.
INHALATION: Remove those exposed to fresh air. If breathing is difficult administer oxygen. If breathing
INGESTION:
has stopped, apply cardio-pulmonary resuscitation (CPR).
DO NOT induce vomiting unless physican orders. Aspiration of material into the lungs can
first aid
cause fatal chemical pneumonitis. If conscious, have drink one-two glasses of milk or
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:4/20/2003
CHEMICAL HAZARD BULLETIN NO. 400
S/N 26-865-425 0.5 L Bottle
26-865-434 2.5 L Bottle
26-865-469 95 lb carboy
SULFURIC 26-865-601 Bulk delivery
ACID
(OIL OF VITRIOL)
MIST / Mist may be generated mechanically or by condensation of vaporized acid. The TLV for
3 3
LIQUID: acid mist is 1.0 mg/m and STEL-C=3 mg/m
EFFECTS OF OVER-EXPOSURE:
EYE/ SKIN: Severely irritating to the eyes and may cause irreversible eye damage. Repeated or
INHALATION:
prolonged skin contact will cause severe irritation and burns.
May cause severe irritation or burns of the respiratory system, pulmonary edema or lung
health
INGESTION:
inflammation.
Gastro-intestinal distress, nausea, vomiting, diarrhea. Will cause damage and burns to
mucous membrane of the mouth, throat, esophagus and stomach. Possible adverse
hazards
effects on kidney function.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
Non-flammable. No flashpoint or explosive range in air reported. In contact with a fire, toxic oxides of carbon and
sulfur will be formed. Fire fighters must use self-contained breathing apparatus (SCBA) and protective clothing.
Closed containers exposed to heat may explode. Cool fire-exposed containers with water spray. fire and
REACTIVITY: Avoid contact with water, most common metals, organic materials, bases, cyanides.
EXTINGUISHING MEDIA: DRY CHEMICAL, CO2
reactivity
USAGE: This product is used in Utilities for water treatment and as a laboratory reagent. Avoid
breathing mists and eye and skin contact. NO SMOKING. Provide adequate ventilation.
TRANSPORT/ Store in a well ventilated, cool, dry area. Keep containers labeled, upright and tightly
STORAGE: closed when not in use. DO NOT store in direct sunlight. Avoid storage near heat, open
flames and incompatible materials. Always label containers for transporting in accordance
SPILLS/ LEAKS:
with DOT/IMO/IATA hazard warning labels.
Stop the flow if it can be done safely. DO NOT USE WATER. Neutralize spill with soda
ash or lime. Dike to prevent entry into sewer. Absorb with sand and place in a clean, dry
handling,
DISPOSAL:
container.
For proper disposal methods and locations for the chemical or chemical contaminated
storage &
SAFETY
EQUIPMENT:
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
Provide ventilation to control airborne concentrations below the TLVs. Chemical safety disposal
goggles (21-434-249) with full-length face shield (21-426-121), acid resistant gloves (21-
432-080), rubber aprons (21-404-181), must be used when handling this material. SCBA
should be worn if conditions warrant. Maintain an eyewash fountain and emergency
shower where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
INGESTION:
and wash clothing before re-use.
Do not induce vomiting. Aspiration of material into the lungs can cause chemical
first aid
pneumonitis, which can be fatal. Drink one-two glasses of water to dilute. Keep person
warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
*Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised: 1/13/2001
CHEMICAL HAZARD BULLETIN NO. 403
Premium Grade
VAPOR/MISTS: The TLV for gasoline is 300 ppm and STEL (ACGIH) is 500 ppm. Other components
may include low percentage of benzene, toluene, xylene, ethyl benzene, methyl tetra-
butyl ether, n-hexane, 1,2,4-trimethylbenzene, and tetraethyl lead.
EFFECTS OF OVER-EXPOSURE:
health
INHALATION: Effects of vapor exposure may include irritation of nose, throat, and respiratory tract,
nausea, vomiting, dizziness, weakness or loss of coordination.
hazards
EYE/ SKIN: May cause mild skin irritation. Prolonged exposure may cause skin to dry and crack.
INGESTION: Toxic by ingestion. Potential for aspiration into lungs during swallowing or vomiting.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
Extremely flammable liquid and vapor. Flash point (-45 0 F), UEL 7.6 %-LEL 1.4%. Vapor may accumulate in
low area and travel to sources of ignition and flash back.
fire and
REACTIVITY: May react with strong oxidizing agents. Bonds and ground all equipment when transferring
from one vessel to another. reactivity
EXTINGUISHING MEDIA: WATER SPRAY, DRY CHEMICAL FOAM, OR CO2
USAGE: Motor fuel. Avoid breathing vapor and mists and avoid eye and skin contact. NO
SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from heat or ignition sources and from
TRANSPORT: oxidizers. Keep tightly closed when not in use. For transportation, use DOT-IMO Classes
3.1 hazardous warning labels (diamond): FLAMMABLE LIQUID, TOXIC, N.O.S.
storage &
SPILLS/ Keep unauthorized personnel away. Shut off sources of ignition. Stop the flow if it can be
LEAKS: done safely. Dike to prevent entry into sewer. Absorb with sand and place in clean, dry,
labeled container.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene gloves (1000129418) must be worn when handling this
material. APR (1000128213) or SCBA (1000127427) should be worn if conditions
warrant. Maintain an eyewash fountain and emergency shower (1000128433) where the
material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 7/7/2004
CHEMICAL HAZARD BULLETIN NO. 404
SA Product # A-888 Bulk Delivery
DIESEL
(Fuel Oil)
Reactivity 1
LIQUID/VAPOR: No occupational exposure limits have been set for this complex mixture of hydrocarbons.
EFFECTS OF OVEREXPOSURE:
INHALATION: Vapor or mist may irritate respiratory tract. Excessive exposure may lead to CNS effects
EYE/SKIN:
that could lead to unconsciousness and more severe results.
Slight to moderate eye irritant but permanent harm unlikely. Repeated or prolonged skin health
contact may cause irritation.
INGESTION: May cause gastrointestinal disturbances including irritation, nausea, vomiting, diarrhea,
and CNS effects that could lead to loss of consciousness and more severe results.
hazards
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
Flashpoint is a minimum of 52 C (125 F) with an LEL of 0.6% and UEL of 7.5%. Toxic oxides of carbon may be
released during combustion in addition to smoke. Fire fighters should wear self-contained breathing apparatus
(SCBA) and full protective clothing. fire and
REACTIVITY: Avoid contact with nitric acid and strong oxidizing agents. reactivity
EXTINGUISH FIRES WITH WATER SPRAY, CO2, DRY CHEMICAL OR FOAM
USES: Fuel for trucks, heavy equipment, generators, marine equipment, and certain
automobiles. No smoking. Do not breathe vapors. handling
STORAGE: Dispense in well-ventilated areas. Store in a cool, dry area out of direct sunlight, away
from ignition sources and oxidizers. storage
TRANSPORT:
SPILLS/LEAKS:
For transportation, label with a DOT-IMO Class 3 hazard warning placard.
Shut off sources of ignition. Stop the flow if it can be done safely. Absorb with sand and
&
DISPOSAL:
transfer to clean, dry, labeled containers.
Contact Environmental Engineering (874-6426 or 874-6428) for proper disposal
disposal
procedures and locations.
SAFETY Under normal conditions, respiratory protection is not required. Chemical goggles (S/N
EQUIPMENT: 21-434-249) and protective gloves (S/N 21-432-576) should be worn if extensive contact
is likely. Maintain eyewash fountain and emergency shower in storage area and
wherever used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
EYE/SKIN Flush eyes with copious amounts of water for at least 15 minutes holding eyelids apart.
CONTACT: Remove contaminated clothing or shoes. Wash skin thoroughly with soap and water.
Launder clothing before re-use.
first aid
INHALATION: Remove those exposed to fresh air. If breathing is difficult administer oxygen. If breathing
has stopped, apply cardio-pulmonary resuscitation (CPR).
INGESTION: Give water to drink if conscious. Do NOT induce vomiting.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
*Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised 12/26/2001
CHEMICAL HAZARD BULLETIN NO. 407
combustion include corrosive and irritant oxides of sulfur. Firefighters must wear Scott air Pak (1000127427).
Sulfur oxides will produce acids in contact with skin or water, corrosive to personal protective equipment. Fire fire and
hazard is increased if hydrogen sulfide and carbon disulfide are produced by reaction with hydrocarbons. Sulfur
dust may be generated which can be ignited and explode if not controlled. reactivity
REACTIVITY: Stable under normal conditions but reacts violently with strong oxidizers and powdered metals.
Crude molten sulfur may evolve extremely toxic H2S gas. Burning sulfur produces corrosive sulfur oxide gas.
EXTINGUISH AREA FIRES WITH DRY CHEMICAL, ALCOHOL-RESISTANT FOAM, WATER SPRAY
USES: Produced in sulfur recovery plants and transported in molten form in top-loaded tankers
for the manufacturing of sulfuric acid and for export. Pharmaceutical component. Has
been used as parasiticide (pesticide). Avoid skin and eye contact with molten sulfur. Do
not breathe vapors, dust or mist. No smoking. Provide adequate/ local ventilation.
STORAGE: Store in a cool dry well ventilated area, away from ignition sources. Keep tightly closed
when not in use.
handling
TRANSPORT: For transportation, packages require Class 4 DOT-IMO hazardous warning label
(diamond) and placard: FLAMMABLE SOLID. storage
SPILLS/LEAKS: Stop the flow if it can be done safely. Dike to prevent entery into sewer. Absorb in dry
sand and place into clean, dry, labeled containers. Flush with plenty of water to clean
spillage area.
&
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426.
disposal
SAFETY Provide ventilation to control exposures below the TLVs. Chemical goggles
EQUIPMENT: (1000129810), PVC or neoprene gloves (1000129628), rubber boots (1000128971) and
faceshield (1000129345) must always be worn when handling quantities of this material.
SCBA should be worn if conditions warrant. Maintain eyewash fountain and emergency
shower in storage area and wherever used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
EYE/SKIN Immediately, flush eyes with copious amounts of water for at least 15 minutes holding
CONTACT: eyelids apart. Remove contaminated clothing/shoes. Wash skin thoroughly with soap and
water. Wash contaminated clothing before use.
first aid
INHALATION: Remove those exposed persons to fresh air. If breathing is difficult administer oxygen. If
breathing has stopped, apply cardio-pulmonary resuscitation (CPR). Keep person quite
and warm.
INGESTION: Do not induce vomiting. Wash out mouth thoroughly. Give water to drink if conscious to
dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Environmental Protection: 872-2623 (DH), 678-4868 (RT), 574-6796 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:9/20/2003
CHEMICAL HAZARD BULLETIN NO. 414
Saudi Aramco Product:
ARAB EXTRA LIGHT
ARAB LIGHT, ARAB MEDIUM and
ARAB HEAVY
PETROLEUM
CRUDE OIL
LIQUID: Avoid contact with eyes. Frequent or prolonged skin contact may cause dryness and health
cracking leading to irritant dermatitis and infection. Ingestion can be fatal. May cause
gastro-intestinal upset, nausea/vomiting, narcosis, dizziness, drowsiness, loss of
coordination, coma and death. As with other hydrocarbon liquids, aspiration into the
hazards
lungs, for example following ingestion and vomiting, is likely to cause fatal chemical
pneumonitis.
WEAR RECOMMENDED GLOVES TO HANDLE CRUDE OIL
Flammable liquid. The flash point is -25ºC (-13ºF) and the flammable range in air is 0.9%(LEL) to 7.0%(UEL).
Products of thermal decomposition include toxic oxides of carbon and sulfur. Firefighters must wear SCBA. fire and
REACTIVITY: Stable under normal temperatures and pressures. Reacts with strong oxidizers and strong acid
or alkali. reactivity
EXTINGUISH FIRES WITH WATER SPRAY, DRY CHEMICAL, FOAM, HALON OR CO2
USAGE: Raw material for hydrocarbon fuels and petrochemical processing. No smoking. Bond
and ground containers when transferring from one vessel to another.
STORAGE & Usually stored in bulk tanks. Store in well ventilated area, removed from heat or
TRANSPORTATION: ignition source and from oxidizers. Always label containers. For transportation,
SPILLS/
should be labeled with DOT-IMO hazardous warning label: FLAMMABLE LIQUID.
Evacuate all non-essential personnel. Eliminate sources of ignition and absorb spill .
handling
LEAKS: Call Environmental Engineering Division at 874-6426 or 874-6428 for disposal
procedures. and
SAFETY
EQUIPMENT:
If skin exposure is frequent, neoprene (S/N 21-432-080) or Buna-N or Polyvinyl
Alcohol (PVA, 21-432-624) gloves should be used and safety goggles or face shield storage
for eye protection. Eye wash fountains should be maintained where chemicals are
used. For concentrations exceeding the recommended exposure limit, wear
respirator recommended per Industrial Hygiene approval.
USE CONFINED SPACE ENTRY PROCEDURES WHEN APPROPRIATE
INHALATION Move victim to fresh air. If breathing is difficult, administer oxygen. If breathing has
stopped, give cardio-pulmonary resuscitation (CPR).
EYE/SKIN Avoid contact with eyes and skin. Hold eyes open and flush with water for 15
CONTACT: minutes. Remove contaminated clothing and shoes and wash skin thoroughly with
soap and water. If irritation persists seek medical attention. Laundry contaminated
clothing before rewearing. first aid
INGESTION: Keep victim quiet. Aspiration hazard. DO NOT induce vomiting. Immediately take
victim to hospital.
CALL 110 FOR MEDICAL AID
For further information, call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ), or 427-2217 (JID).
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, and 4=Extreme
Revised:10/22/2001
CHEMICAL HAZARD BULLETIN NO. 417
S/N SA PRODUCTS A-418
26-12-350 Bulk
26-12-550 Bulk (JET A-1)
KEROSENE 26-111-223 118 ML Bottle
Jet A-1
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ), or 427-2217 (JID).
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised 10/23/2001
CHEMICAL HAZARD BULLETIN NO. 420
NEAT STABILIZED
KHUFF SA PRODUCT # A-060 BULK DELIVERY
CONDENSATE
Health 3 CLEAR TO YELLOW LIQUID, WITH A HYDROCARBON ODOR CAS: Mixture
HIGHLY TOXIC, EXTREMELY FLAMMABLE AND
Fire 4 SLIGHTLY REACTIVE UN: 1992
GUIDE: 131
Reactivity 1 EAC: ● 3WE
VAPOR/LIQUID: Neat/ stabilized Khuff Condensate is a complex blend of hydrocarbons (saturates and
aromatics including benzene), mercaptans and may contain traces of hydrogen sulfide
3
(TWA= 10ppm) and mercury (TWA= 0.01 mg/m ).
EYE/ SKIN:
EFFECTS OF OVER-EXPOSURE:
May cause irritation to eyes and skin. Prolonged skin contact may cause dermatitis. health
INHALATION:
INGESTION:
Inhaling vapors can be highly toxic as they may contain hydrogen sulfide and mercury.
Harmful or fatal if liquid is aspirated into lungs.
hazards
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
Extremely flammable. Flash point -22 to -580 C (-8 to-740 F) with an LEL of 1%. Easily ignitable by flame or spark.
Vapors are heavier than air and may travel to sources of ignition and flashback. Keep away from ignition sources.
During combustion, carbon, nitrogen and sulfur oxides may be formed. Firefighters must wear SCBA (1000127427 fire and
and protective clothing. Keep containers cool with water spray. Use adequate ventilation.
REACTIVITY: Stable. Avoid contact with strong oxidizers, chlorine, peroxides and strong acids. Avoid heat, sparks reactivity
and open flame.
EXTINGUISHING MEDIA: DRY CHEMICAL, CARBON DIOXIDE, FOAM, STEAM OR WATER FOG
USAGE: This product is a naturally occurring liquid associated with natural gas used as a refinery
and chemical industry feedstock. Avoid breathing vapor or mist. No Smoking. Provide
adequate ventilation.
STORAGE: Store in a well ventilated, cool, dry area away from ignition sources. Keep containers
labeled, upright and tightly closed when not in use. DO NOT store in direct sunlight.
Avoid storage near incompatible material. If inside, it should be in a standard flammable
cabinet. handling
TRANSPORT: For transportation, label packages with DOT-IMO Class 3, hazardous warning label
(diamond) or placard: FLAMMABLE LIQUID. storage
SPILLS/LEAKS: Shut off sources of ignition. Stop the flow if it can be done safely. Dike to prevent entry
into sewer. Absorb with sand and place in clean, dry container. &
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6428. disposal
SAFETY Use explosion–proof mechanical ventilation. Local exhaust ventilation to keep vapors
EQUIPMENT: below allowable limits. Safety goggles (1000129810), neoprene gloves (1000129624and
face shield (1000129345) must be worn when handling this material. SCBA should be
worn if conditions warrant. Maintain an eyewash fountain and emergency shower where
the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLY
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped give cardio-pulmonary resuscitation (CPR). Keep person warm and quiet.
EYE/SKIN Flush eyes with large amount of water for at least 20 minutes. Lift eyelids occasionally.
Wash skin thoroughly with water. Remove contaminated clothing and shoes promptly
first aid
CONTACT:
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs due to vomiting can cause
chemical pneumonitis which can be fatal. If conscious, drink one-two glasses of water to
dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Environmental Protection: 873-5853 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
6/11/2006
CHEMICAL HAZARD BULLETIN NO. 510
POTASSIUM S/N 26-768-837 60-g bottle
HYDROGEN
PHTHALATE
INHALATION:
EFFECTS OF OVER-EXPOSURE:
Dust may cause irritation to the respiratory tract. health
EYE/ SKIN: Irritating to the eyes, causing itching, redness and tearing. Repeated or prolonged skin
contact will cause irritation.
hazards
INGESTION: Gastrointestinal distress, narcosis, nausea, vomiting, diarrhea and coma.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
This product is slightly flammable. Firefighters must wear SCBA and protective clothing. During combustion,
oxides of carbon and potassium may be formed, also toxic vapors and smoke. Closed containers may rupture
in fire conditions. Keep containers cool with water spray. fire and
REACTIVITRY: Non-reactive.
EXTINGUISH FIRES WITH DRY CHEMICAL, CO2, FOAM OR WATER FOG
reactivity
USAGE: This product is a laboratory reagent. Use adequate ventilation. No smoking. Avoid
breathing dust.
STORAGE: Store in a well ventilated, cool, dry area. Keep tightly closed when not in use. DO NOT
store in direct sunlight. Avoid storage near incompatible materials.
TRANSPORT:
SPILLS / LEAKS:
Mark with hazardous warning labels.
Evacuate all unnecessary personnel. Shut off sources of ignition. Stop the flow if it can
handling,
DISPOSAL:
be done safely. Dike to prevent entry into sewer. Sweep up and place in clean, dry,
labeled container.
For proper disposal methods and locations for chemical or chemical contaminated
storage &
SAFETY
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
Provide ventilation to control exposures below the TLVs. Safety goggles, neoprene
disposal
EQUIPMENT: gloves, cover-all’s and rubber safety boots must be worn when handling this material.
APR or SCBA should be worn if conditions warrant. Maintain an eyewash fountain and
emergency shower where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardio-pulmonary resuscitation (CPR). Keep person warm and quiet.
EYE / SKIN Flush eyes with large amounts of water for at least 15 minutes. Lift eyelids occasionally.
CONTACT: Wash skin thoroughly with water. Remove contaminated clothing and shoes promptly,
INGESTION:
and wash clothing before re-use.
DO NOT induce vomiting. Aspiration of material into the lungs due to vomiting can cause
first aid
chemical pneumonitis, which can be fatal. If conscious, drink one-two glasses of water to
dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ), or 427-2217 (JID).
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised 1/13/2001
CHEMICAL HAZARD BULLETIN NO. 521
S/N 26-301-826 Bulk Delivery
DISSOLVAN
2841
(DEMULSIFIER)
EFFECTS OF OVER-EXPOSURE:
INHALATION: Vapor or mist may cause respiratory irritation and coughing. Higher concentrations may
be narcotic. health
EYE/SKIN: May cause skin irritation or dermatitis following repeated or prolonged contact. Moderate
eye irritant
hazards
INGESTION: May cause digestive upset, nausea and vomiting.
STORAGE: Store in well ventilated cool, dry area away from ignition sources. Do not store in direct
sunlight.
TRANSPORT: For transportation label with DOT-IMO Class 3 warning label FLAMMABLE LIQUID handling
SPILLS/LEAKS: Absorb with sand and place in clean, dry, labeled containers.
storage
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact Environmental Engineering Division at 874-6426 or 874-6428. &
SAFETY
EQUIPMENT:
Provide ventilation to control overexposure and eye and skin contact. Chemical goggles
(21-434-249) or face shield plus rubber or neoprene gloves (21-432-080) should be worn disposal
when handling bulk material. Maintain eyewash fountain and emergency shower in
storage area and wherever used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
EYE/SKIN Flush eyes with copious amounts of water for at least 15 minutes holding eyelids apart.
CONTACT: Remove contaminated clothing or shoes. Wash skin thoroughly with soap and water.
Launder clothing before re-use.
INHALATION: Remove those exposed to fresh air. If breathing is difficult administer oxygen. If breathing
INGESTION:
has stopped, apply cardio-pulmonary resuscitation (CPR).
Give water to drink if conscious. DO NOT INDUCE VOMITTING. Aspiration of even small
first aid
amounts of hydrocarbons may cause potentially fatal chemical pneumonitis. Keep warm
and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:2/13/2001
CHEMICAL HAZARD BULLETIN NO. 530
S/N 41-319-880 12 oz Aerosol can
ETHYL
CHLORIDE
o o
The flashpoint is –43 C (-42 F) and the explosive range in air is 3.6 to 15.4 %. Closed containers may rupture
during fire conditions and should be kept cool with water spray. Products of combustion will include oxides of
carbon and hydrogen chloride in addition to fumes and smoke. Fire fighters should wear self-contained breathing
apparatus (SCBA) and full protective clothing.
fire and
REACTIVITY: Avoid contact with reactive metals such as magnesium, aluminum, sodium etc, reactivity
EXTINGUISH FIRES WITH WATER SPRAY, CO2, DRY CHEMICAL OR FOAM
USES: Chemical intermediate and topical anesthetic working by its cooling action on
evaporation.
STORAGE: Store in a cool, dry, well-ventilated area away from incompatible materials and sources of
ignition.
handling
TRANSPORT: For transportation use DOT-IMO hazard warning label (diamond) class 3, FLAMMABLE
LIQUID storage
SPILLS/LEAKS: Stop the source of the leak if this can be done safely. Evacuate personnel and allow to
DISPOSAL:
evaporate
Contact Environmental Engineering Division (874-6426 or 874-6428) for disposal
&
SAFETY
procedure and locations.
Wear goggles (21-434-249). Maintain an eyewash fountain and emergency shower in
disposal
EQUIPMENT: storage area and wherever used.
EYE/SKIN Flush eyes with copious amounts of water for at least 15 minutes holding eyelids apart.
CONTACT: Remove contaminated clothing or shoes. Wash skin thoroughly with soap and water.
Launder clothing before re-use.
INHALATION: Move those exposed to fresh air. If breathing is difficult administer oxygen. If breathing
has stopped, apply cardio-pulmonary resuscitation (CPR).
first aid
INGESTION: Give water to drink if conscious. DO NOT INDUCE VOMITTING
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
*Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised: 7/2/2001
CHEMICAL HAZARD BULLETIN NO. 532
S/N 26-008-330 19-L (5 gal) can
SOLUBLE
OIL GP
INHALATION:
EFFECTS OF OVER-EXPOSURE:
Vapor may cause irritation and discomfort to the respiratory tract. health
EYE/ SKIN: Irritating to the eyes, causing itching, redness and tearing. Repeated or prolonged skin
contact will cause dryness, defatting, irritation and discoloration.
hazards
INGESTION: Gastrointestinal distress, nausea, vomiting and diarrhea.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The flash point for this product is 170°C (338° F) with explosion range not reported. Fire fighters must wear SCBA
and protective clothing. During combustion, oxides of carbon, aldehydes and ketones may be formed; also toxic
nitrogen and sulfur oxides and smoke. Closed containers may rupture in fire conditions. Keep containers cool with fire and
water spray. Vapors are heavier than air and can flow along surfaces to distant ignition sources and flashback.
SAFETY
contact the Environmental Engineering Division at 874-6426 or 874-6428.
Provide ventilation to control exposures below the TLVs. Safety goggles and neoprene gloves disposal
EQUIPMENT: and coveralls must be worn when handling this material. APR or SCBA should be worn if
conditions warrant. Maintain an eyewash fountain and emergency shower where the material
is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing has
stopped, give cardio-pulmonary resuscitation (CPR). Keep person warm and quiet.
EYE / SKIN Flush eyes with large amounts of water for at least 15 minutes. Lift eyelids occasionally.
CONTACT: Wash skin thoroughly with water. Remove contaminated clothing and shoes promptly, and
INGESTION:
wash clothing before re-use.
DO NOT induce vomiting. Aspiration of material into the lungs due to vomiting can cause
first aid
chemical pneumonitis which can be fatal. Drink one-two glasses of water to dilute. Keep
person warm and quiet.
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-4587 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:3/17/2001
CHEMICAL HAZARD BULLETIN NO. 545
S/N 26-450-050 2.5-L Bottle
n-HEXANE
Demulsifier
Reactivity 1
LIQUID / VAPOR: The TLV for n-Hexane is 50ppm. Skin notation.
EFFECTS OF OVER- EXPOSURE:
INHALATION: Exposure to 1000-5000ppm may produce headache, nausea, and dizziness. Other
effects may include giddiness, coughing, numbness in the extremities, difficulty walking,
EYES/ SKIN:
defects of memory and excitement.
Vapor may cause irritation with redness. Repeated or prolonged contact may cause health
hazards
dermatitis due to defatting. Blister formation, itching, arrhythmia, pigmentation and pain
have been reported.
Repeated or prolonged contact with irritants may cause conjunctivitis.
INGESTION: May cause nausea, vomiting and general intestinal irritation with abdominal swelling and
pain.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The flash point for this product is -22°C (-7° F) with LEL of 1.1% and UEL of 7.5%. Fire-fighters must wear
SCBA and protective clothing. During combustion, oxides of carbon and nitrogen may be formed, also toxic
organic vapors and smoke. Closed containers may rupture in fire conditions. Keep containers cool with water fire and
reactivity
spray. Vapors are heavier than air and can flow along surfaces to distant ignition sources and flash back.
REACTIVITY: Avoid contact with strong oxidizing agents.
EXTINGUISHING MEDIA: DRY CHEMICAL, CO2, FOAM, WATER FOG
USAGE: n-Hexane is used by laboratories in analysis of pesticide residues. Use adequate ventilation.
No smoking. Do not breathe vapors or mist.
STORAGE: Store in a well-ventilated, cool, dry area, away from ignition sources. Keep tightly closed
when not in use. DO NOT store in direct sunlight. Avoid storage near incompatible
TRANSPORT:
materials.
Mark with hazardous warning labels. handling,
storage &
SPILLS / LEAKS: Shut off sources of ignition. Stop the flow if it can be done safely. Dike to prevent entry
into sewer. Absorb with sand and place in clean, dry, labeled container.
DISPOSAL: For proper disposal methods and locations for chemical or chemical contaminated
SAFETY
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
Provide ventilation to control exposures below the TLVs. Safety goggles and neoprene
disposal
EQUIPMENT: gloves must be worn when handling this material. APR or SCBA should be worn if
conditions warrant. Maintain an eye wash fountain and emergency shower where the
material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLY
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally.
CONTACT: Wash skin thoroughly with soap and water. Remove contaminated clothing promptly,
and wash clothing before reuse. first aid
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs due to vomiting can cause
chemical pneumonitis which can be fatal. Drink one-two glasses of water to dilute. Keep
person warm and quiet.
GET MEDICAL ATTENTION IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:1/13/2001
CHEMICAL HAZARD BULLETIN NO. 548
S/N 26-841-823 500-g bottle
SODIUM
CHLORIDE
INHALATION:
EFFECTS OF OVER-EXPOSURE:
Mild nasal and mucous membrane irritant.
health
EYE/ SKIN:
INGESTION:
Irritating to the eyes. High or prolonged skin contact will cause dermatitis.
Gastrointestinal distress, nausea, vomiting and diarrhea in large doses. hazards
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
fire and
This product is non-flammable. During combustion acrid smoke and irritating fumes may be released.
EXTINGUISH FIRES WITH DRY CHEMICAL, CARBON DIOXIDE, FOAM OR WATER FOG.
reactivity
USAGE: This product is a laboratory agent. Avoid breathing powder.
STORAGE: Store in a well-ventilated, cool, dry area. Keep containers labeled, upright, and tightly
closed when not in use. DO NOT store in direct sunlight. Avoid storage near
incompatible materials.
TRANSPORT: Packages do not require DOT-IMO hazardous warning labels for transportation. handling,
SPILLS / LEAKS: Sweep up and place in suitable container for reclamation or disposal. storage &
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428. disposal
SAFETY Provide general ventilation. Safety goggles must be worn when handling this material.
EQUIPMENT: Maintain an eyewash fountain and emergency shower where the material is being
stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardio-pulmonary resuscitation (CPR). Keep person warm and quiet.
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly
and wash clothing before re-use.
first aid
INGESTION: Induce vomiting. Drink one-two glasses of water to dilute. Keep person warm and quiet.
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:3/17/2001
CHEMICAL HAZARD BULLETIN NO. 557
S/N 09-738-220 20-L can
T-11 ZINC
THINNER
EFFECTS OF OVER-EXPOSURE:
INHALATION: Irritation of the respiratory tract, headache, nausea, dizziness and possible
unconsciousness and respiratory arrest. health
hazards
EYES/ SKIN: Causes irritation, redness and tearing. May cause defatting, irritation and dermatitis.
INGESTION: Gastrointestinal distress, nausea, vomiting and diarrhea. Note: Repeated and prolonged
overexposure to solvents have been shown to cause permanent brain and nervous
system damage.
handling,
TRANSPORT: For transportation, label packages with DOT-IMO Class 3, hazardous warning label
(diamond): FLAMMABLE LIQUID.
storage &
SPILLS / LEAKS: Shut off sources of ignition. Stop the flow if it can be done safely. Dike to prevent entry
into sewer. Absorb with sand and place in clean, dry, labeled container.
DISPOSAL:
SAFETY
For proper disposal methods and locations for chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
Provide ventilation to control exposures below the TLVs. Safety goggles, neoprene
disposal
EQUIPMENT: gloves, cover-all’s and safety rubber boots must be worn when handling this material.
APR or SCBA should be worn if conditions warrant. Maintain an eyewash fountain and
emergency shower where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardio-pulmonary resuscitation (CPR). Keep person warm and quiet.
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: thoroughly with soap and water. Remove contaminated clothing and shoes promptly and
wash before re-use. first aid
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs due to vomiting can cause
chemical pneumonitis, which can be fatal. Drink one-two glasses of water to dilute. Keep
person warm and quiet.
GET MEDICAL ATTENTION IMMEDIATELY (DIAL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:2/24/2001
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:2/24/2001
CHEMICAL HAZARD BULLETIN NO. 567
S/N 09-687-330 5-L can
INTERBOND 50
health
EFFECTS OF OVER-EXPOSURE:
INHALATION: Irritating to the respiratory tract. May cause coughing, tightness in the chest, nausea,
central nervous system depression or unconsciousness.
EYES/ SKIN: Extremely irritating, can cause redness, tearing and blurred vision. May cause skin hazards
irritation, redness, defatting and dermatitis.
INGESTION: Causes gastrointestinal distress, nausea, diarrhea and vomiting.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The flash point for this product is 23°C (73°F) with explosion limits in air not reported. Firefighters must wear
SCBA and protective clothing. During combustion, oxides of carbon and nitrogen may be formed, also toxic
organic vapors and smoke. Closed containers may rupture in fire conditions. Keep containers cool with water
spray. Vapors are heavier than air and can flow along surfaces to distant ignition sources and flashback.
fire and
REACTIVITY: Avoid contact with strong oxidizing agents.
EXTINGUISH FIRES WITH DRY CHEMICAL, CARBON DIOXIDE OR FOAM.
reactivity
USAGE: High temperatures coating for steel surfaces. Use adequate ventilation. No smoking.
Do not breathe vapors or mist.
STORAGE: Store in a well ventilated, cool, dry area, away from ignition sources. Keep tightly closed
when not in use. DO NOT store in direct sunlight. Avoid storage near incompatible
materials.
handling,
TRANSPORT: For transportation, label packages with DOT-IMO Class 3, hazardous warning label
(diamond): FLAMMABLE LIQUID.
SPILLS / LEAKS: Shut off sources of ignition. Stop the flow if it can be done safely. Dike to prevent entry
DISPOSAL:
into sewer. Absorb with sand and place in clean, dry, labeled container.
For proper disposal methods and locations for chemical or chemical contaminated
storage &
SAFETY
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
Provide ventilation to control exposures below the TLVs. Safety goggles, neoprene disposal
EQUIPMENT: gloves and cover-all's must be worn when handling this material. APR or SCBA should
be worn if conditions warrant. Maintain an eye wash fountain and emergency shower
where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
EYE/SKIN Flush with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: thoroughly with soap and water. Remove contaminated clothing and shoes promptly and
wash clothing before re-use. Consult a Physician if irritation persists. first aid
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs due to vomiting can cause
chemical pneumonitis, which can be fatal. Drink one - two glasses of water to dilute.
Keep person warm and quiet.
GET MEDICAL ATTENTION IMMEDIATELY (Dial 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:1/13/2001
CHEMICAL HAZARD BULLETIN NO. 588
DUST/ SOLID: This product contains silicon (TLV=10 mg/m³), zirconium (TLV=5 mg/m³, STEL= 10
mg/m³), potassium perchlorate (TLV=5 mg/m³ respirable fraction), cyclonite (TLV=0.5
mg/m³), catalyst(s) (TLV=0.1 mg/m³), boron or potassium nitrate, and silicon epoxy.
EYE/ SKIN:
EFFECTS OF OVEREXPOSURE:
Contact with dust may cause eye irritation, redness and tearing and skin irritation. health
hazards
INHALATION Inhalation of dust may cause irritation to mucous membranes.
INGESTION For ingestion seek medical attention immediately. Boron/Potassium nitrate can cause
convulsions, vomiting and diarrhea. Cumulative poison when ingested, can be fatal
without immediate medical attention.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
Material likely to explode when subjected to heat, flame or other sources of ignition. Auto ignition= 4000F. No flash
points or explosive range in air are reported. Don not use mechanical ventilation due to explosive nature of
ruptured units. Firefighters must use self-contained breathing apparatus (SCBA) and protective clothing. Do not fire and
use dry chemicals as perchlorates supply their own oxygen to feed a fire. During combustion, oxides of chlorine or
potassium perchlorate may be formed, also toxic vapors and smoke. Containers may rupture in fire conditions:
designed to explode and release extinguishing agent. Keep containers cool with water spray.
reactivity
REACTIVITY: Avoid contact with sources of ignition, strong oxidizing agents, and strong evolution of light.
EXTINGUISH FIRES BY FLOODING WITH WATER AND USING WATER FOG
USAGE: Aviation fire extinguisher cartridge with explosively charged release. DO NOT remove
electrical shunt until ready for installation. Use adequate ventilation. No smoking. Do not
breathe dust. Avoid impacts and electrical charges.
STORAGE/ Store in an isolated well ventilated, cool, dry area, away from ignition sources. Keep
containers labeled, upright, and tightly closed when not in use. DO NOT store in direct
sunlight. Avoid storage near incompatible material. Do not expose to unnecessary handling
TRANSPORT: impact. For transportation, label with DOT-IMO Class 4 hazardous warning label
SPILLS / LEAKS:
(diamond): FLAMMABLE SOLID.
Evacuate all unnecessary personnel. Shut off sources of ignition. Avoid dust formation.
storage
DISPOSAL:
Sweep up carefully using static free broom and a non sparking tool and place in a clean,
dry, closed container, and label. &
disposal
For proper disposal methods and locations for chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY DO NOT provide ventilation due to the explosive hazard of ruptured units. Face sheild
EQUIPMENT: (1000129345), hearing protection (1000128143), conductive shoes, and all cotton
clothing and neoprene gloves (1000129418) must be worn when handling quantities of
this material. APR or SCBA should be worn if conditions warrant. Maintain an eyewash
fountain and emergency shower where the material is being stored/used.
USE CONFINED SPACE PROCEDURES IF CONDITIONS APPLY
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardio-pulmonary resuscitation (CPR). Keep person warm and quiet.
EYE / SKIN Flush eyes with large amounts of water for at least 15 minutes. Lift eyelids occasionally.
CONTACT: Wash skin thoroughly with water. Remove contaminated clothing and shoes promptly and
INGESTION:
wash clothing before re-use.
DO NOT induce vomiting. If conscious, drink one-two glasses of water to dilute. Keep
first aid
person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Environmental Protection: 872-2623 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:9/7/2004
CHEMICAL HAZARD BULLETIN NO. 620
INSULATION
1000199241 1 GA CN
ADHESIVE
Health 3 RED LIQUID WITH PAINT SOLVENT ODOR. HIGHLY TOXIC. CAS: Mixture
VAPOUR / LIQUID: This product contains n-hexane (TLV=50 ppm) and hexane isomers (TLV=500 ppm,
STEL=1000 PPM). Also contains a proprietary synthetic rubber base.
EFFECTS OF OVER-EXPOSURE:
INHALATION: Inhalation may cause respiratory tract irritation, nausea, dizziness, confusion and central
nervous system depression. Note: Repeated overexposures to n-hexane may cause
damage to the peripheral nervous system. Reports have associated prolonged or health
repeated occupational overexposure to solvents with permanent brain and central
EYE/SKIN:
nervous system (CNS) damage. hazards
Eye contact may cause irritation, redness and tearing.
Skin Contact may cause dryness, defatting, irritation and dermatitis.
INGESTION:
May cause gastrointestinal upset, nausea, vomiting and diarrhea.
SPILLS / LEAKS:
(diamond) or placard: FLAMMABLE LIQUID.
Evacuate all unnecessary personnel. Shut off sources of ignition. Stop the flow if it can
&
be done safely. Dike to prevent entry into sewer. Absorb with sand, label, and place in a
clean, dry, labeled container.
disposal
DISPOSAL:
For proper disposal methods and locations for chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control exposures below the TLVs. Safety goggles (1000129810),
EQUIPMENT: and neoprene gloves (1000129418) must be worn when handling this material. APR or
SCBA (1000127427) should be worn if conditions warrant. Maintain eyewash fountain
and emergency shower where the material is being stored / used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
EYE/SKIN Flush eyes with large amounts of water for at least 15 minutes. Lift eyelids occasionally.
CONTACT: Remove contaminated clothing / shoes. Wash skin thoroughly with soap and water. Wash
contaminated clothing before use.
INHALATION: Remove exposed persons to fresh air. If breathing is difficult administer oxygen. If
breathing has stopped, apply cardio-pulmonary resuscitation (CPR).Keep person quiet
and warm.
first aid
INGESTION: Do not induce vomiting. Aspiration of material into lungs can cause chemical pneumonitis,
which can be fatal. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Environmental Protection: 872-2623 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:10/17/2004
CHEMICAL HAZARD BULLETIN NO. 621
S/N 26-011-127 1-L (1-qt) bottle
INHALATION:
EFFECTS OF OVER-EXPOSURE:
Vapor may cause irritation to the respiratory tract.
health
EYE/ SKIN: Irritating to the eyes, causing itching, redness and tearing. Repeated or prolonged skin
contact will cause irritation. hazards
INGESTION: Gastrointestinal distress, nausea, vomiting and diarrhea.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The flash point for this product is 260°C (500°F) with LEL of 0.6% and UEL of 7.0%. Firefighters must wear
SCBA and protective clothing. During combustion, oxides of carbon may be formed; also toxic vapors and
smoke. Closed containers may rupture in fire conditions. Keep containers cool with water spray. Vapors are fire and
reactivity
heavier than air and can flow along surfaces to distant ignition sources and flashback.
REACTIVITY: Avoid contact with strong oxidizing agents.
EXTINGUISH FIRES WITH DRY CHEMICAL, CARBON DIOXIDE, FOAM OR WATER FOG.
USAGE: This product is a vacuum pump oil. Use adequate ventilation. No smoking. Do not
breathe vapors, dust, or mist.
STORAGE: Store in a well-ventilated, cool, dry area, away from ignition sources. Keep containers
labeled, upright, and tightly closed when not in use. DO NOT store in direct sunlight.
Avoid storage near incompatible materials.
handling,
TRANSPORT: For transportation of bulk quantities place DOT-IMO Class 3, hazardous warning placard
(diamond): COMBUSTIBLE LIQUID.
storage &
SPILLS / LEAKS: Evacuate all unnecessary personnel. Shut off sources of ignition. Stop the flow if it can
be done safely. Dike to prevent entry into sewer. Absorb with sand and place in clean,
dry, labeled container.
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428. disposal
SAFETY Provide ventilation to control exposures below the TLVs. Safety goggles and neoprene
EQUIPMENT: gloves must be worn when handling this material. APR or SCBA should be worn if
conditions warrant. Maintain an eyewash fountain and emergency shower where the
material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardio--pulmonary resuscitation (CPR). Keep person warm and quiet.
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally.
CONTACT: Wash skin thoroughly with soap and water. Remove contaminated clothing and shoes
promptly and wash clothing before re-use. first aid
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Drink one-two glasses of water to dilute. Keep person
warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:2/13/2001
CHEMICAL HAZARD BULLETIN NO. 632
S/N 31-738-137 850-g canister
SUPERIOR
SMOKE
EYE/ SKIN:
EFFECTS OF OVER-EXPOSURE:
Irritating to the eyes, causing itching, redness and tearing. health
INHALATION:
INGESTION:
Repeated or prolonged skin contact will cause irritation.
Dust may cause irritation to the respiratory tract, and mucous membranes.
Not a significant route of exposure.
hazards
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
This product is not flammable. Firefighters must wear SCBA and protective clothing. During combustion,
fire and
oxides of carbon may be formed, also toxic organic vapors and smoke. Closed containers may rupture in fire
conditions. Keep containers cool with water spray.
REACTIVITY: Non-reactive.
handling,
TRANSPORT: Mark with hazardous warning labels.
SPILLS / Evacuate all unnecessary personnel. Shut off sources of ignition. Stop the flow if it can
storage &
LEAKS: be done safely. Place in a clean, dry, labeled container.
DISPOSAL: For proper disposal methods and locations for chemical or chemical contaminated
SAFETY
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
Provide ventilation to control exposures below the TLVs and to dissipate smoke. Safety disposal
EQUIPMENT: goggles must be worn when handling this material. APR or SCBA should be worn if
conditions warrant. Maintain an eyewash fountain and emergency shower where the
material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardio-pulmonary resuscitation (CPR). Keep person warm and quiet.
EYE / SKIN Flush eyes with large amounts of water for at least 15 minutes. Lift eyelids occasionally.
CONTACT: Wash skin thoroughly with water. Remove contaminated clothing and shoes promptly and
wash clothing before re-use. first aid
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs due to vomiting can cause
chemical pneumonitis, which can be fatal. If conscious, drink one-two glasses of water to
dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ), or 427-2217 (JID).
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised: 1/14/2001
CHEMICAL HAZARD BULLETIN NO. 643
VAPOUR / LIQUID: This material contains mineral spirits (TLV=100ppm), lead drier (TLV=0.05 mg/m³) and
cobalt (TLV=0.02 mg/m³).
EFFECTS OF OVER-EXPOSURE:
health
INHALATION: Vapor may cause respiratory tract irritation or central nervous system (CNS) depression
characterized by giddiness, nausea, dizziness and unconsciousness and possibly death. hazards
EYE/SKIN: Irritating to the eyes, causing itching, redness and tearing. Repeated or prolonged skin
contact will cause dryness, defatting, irritation and dermatitis. Toxic amounts of this
material may be absorbed through the skin.
For further information call Environmental Protection: 872-2623 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:11/22/2004
CHEMICAL HAZARD BULLETIN NO. 659
SURFATRON 1000186027 55 GA DM
KDP-64
LIQUID/ A proprietary formulation of 23% methanol (Skin, TLV=200 ppm) and cationic surfactants.
VAPOR:
EFFECTS OF OVER-EXPOSURE:
health
INHALATION: Inhalation irritates the respiratory system, and may cause drowsiness and dizziness. It
can result in chemical pneumonia if inspired into the lungs. Repeated over exposure to
methanol may affect the central nervous system, especially the optic nerve (CNS).
hazards
EYE/ SKIN: Eye contact may cause irritation, burning, itching, and pain. Overexposure to methanol
impairs vision and may cause blindness. Skin contact may cause irritation and redness. It
removes oils form the skin, which becomes dry and eventually develops cracks or
dermatitis. Toxic amounts may be absorbed through the skin.
INGESTION: Gastrointestinal distress. May shown signs of methanol poisoning; staggering and lack of
Coordination; headache, mental confusion, and visual disturbance, and tiredness.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
Based on pure methanol, the minimum flashpoint is 33°C (92°F); with an explosive range from 6.7% to 36%.
Fire fighters must wear SCBA and protective clothing. Fires produce carbon and nitrogen oxides, and also
toxic gases, vapors, fumes, and smoke. Closed containers may rupture in fire conditions. Cool containers fire and
reactivity
exposed to flames with water spray until well after the fire is out.
REACTIVITY: Normally stable. Incompatible with: Avoid heat, flames, and sources of ignition strong acids
and oxidizers.
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY/FOG, FOAM, OR CO2
USAGE: Surfactant in oil operations. Avoid breathing vapors and avoid eye and skin contact. NO
SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, label containers with DOT-IMO
Class 3 hazardous warning label (diamond): FLAMMABLE LIQUID, N.O.S.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 873-6676.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene gloves (1000129418) must be worn when handling this
material. SCBA (1000127427) should be worn if conditions warrant. Maintain an
eyewash fountain and emergency shower (1000128433) where the material is being
stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-4538 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 3/24/2004
CHEMICAL HAZARD BULLETIN NO. 674
ISOPAR G 1000478178 1 LT BT
VAPOUR / LIQUID: This product contains petroleum solvents which are predominantly C8-C14 and
isoparafinic hydrocarbons.
EFFECTS OF OVER-EXPOSURE:
Vapor may cause respiratory tract irritation or central nervous system (CNS) depression
INHALATION:
characterized by giddiness, nausea, dizziness and unconsciousness and possibly death. health
EYE/SKIN: Eye irritant causing itching, redness, tearing. Toxic amounts of this material may be
absorbed through the skin. May cause burns and allergic reaction. Repeated or prolonged
skin contact will cause dryness, defatting, irritation and dermatitis.
hazards
INGESTION:
May cause gastrointestinal upset, nausea, vomiting and diarrhea.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The flash point for this product is 38°C (100°F) with LEL of 0.8% and UEL of 7.0%. Firefighters must wear SCBA
and protective clothing. During combustion, oxides of carbon and aldehydes may be formed, also toxic organic
vapors and smoke. Closed containers may rupture in fire conditions. Keep containers cool with water spray. Do not fire and
pressurize, cut, weld / solder etc empty containers as they may explode causing injury / death. Vapors are heavier
than air and can flow along surfaces to distant ignition sources and flashback. reactivity
REACTIVITY: Avoid contact with strong oxidizing agents.
EXTINGUISH MEDIA: DRY CHEMICAL, CO2, FOAM, WATER FOG
USEAGE: This material is a liquid dispersant. Use adequate ventilation. No smoking. Do not
breathe vapors or mist.
STORAGE: Store in a well ventilated, cool, dry area. Keep tightly closed when not in use. Do not
store in direct sunlight. Avoid storage near incompatible materials.
TRANSPORT:
For transportation, label packages with DOT-IMO Class 3, hazardous warning label handling
(diamond) or placard: FLAMMABLE LIQUID.
SPILLS / LEAKS: Evacuate all unnecessary personnel. Shut off sources of ignition. Stop the flow if it can storage
DISPOSAL:
be done safely. Dike to prevent entry into sewer. Absorb with sand and place in a clean,
dry, labeled container. &
For proper disposal methods and locations for chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428. disposal
SAFETY Provide ventilation to control exposures below the TLVs. Safety goggles (1000129810)
EQUIPMENT: and neoprene gloves (1000129418) must be worn when handling this material. APR or
SCBA (1000127427) should be worn if conditions warrant. Maintain eyewash fountain
and emergency shower where the material is being stored / used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
EYE/SKIN Flush eyes with large amounts of water for at least 15 minutes. Lift eyelids occasionally.
CONTACT: Remove contaminated clothing / shoes. Wash skin thoroughly with soap and water. Wash
contaminated clothing before use.
INHALATION: Move exposed persons to fresh air. If breathing is difficult administer oxygen. If breathing
has stopped, apply cardio-pulmonary resuscitation (CPR).Keep person quiet and warm. first aid
INGESTION: Do not induce vomiting. Aspiration of material into lungs can cause chemical pneumonitis,
which can be fatal. Wash out mouth thoroughly. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Environmental Protection: 872-2623 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:9/26/2004
CHEMICAL HAZARD BULLETIN NO. 675
POWDER: Sodium Acetate. No TLVs have been established for this product.
INHALATION:
EFFECTS OF OVER-EXPOSURE
Not expected to be a route of entry.
health
EYE/SKIN: Eye irritant causing itching, redness, tearing and pain. Repeated or prolonged skin
contact will cause irritation, redness and pain.
hazards
INGESTION: Gastrointestinal upset, nausea, vomiting and diarrhea.
For further information call Environmental Protection: 872-2623 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:9/27/2004
CHEMICAL HAZARD BULLETIN NO. 683
Odor-Armor
S/N 26-000-238 55 gallon drum
LIQUID/ VAPOR: This product is a proprietary formation including ethoxylated nonylphenol, branched and
essential oil. No occupational exposure limits have been assigned for this mixture.
EFFECTS OF OVER-EXPOSURE:
This product is not expected to present an inhalation hazard.
health
INHALATION:
EYE/SKIN: Cause irritation to the eyes, redness and tearing. Prolonged or repeated contact with the
INGESTION:
skin may cause skin irritation.
hazards
Gastro-intestinal distress, nausea, vomiting, and diarrhea.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The flashpoint for this product is 62.8 °C (145 °F), with no explosive range in the air. Fire fighters must wear self-
contained breathing apparatus (SCBA) and full protective clothing. During combustion, carbon monoxide and
carbon dioxide may be formed. Closed containers may rupture in fire conditions. Keep containers cool with water fire and
reactivity
spray. Vapors are heavier than air and can flow along surfaces to distant ignition sources and flashback.
REACTIVITY: Avoid contact with strong oxidizing agents.
EXTINGUISH AREA FIRES WITH: WATER FOG, FOAM, CO2 OR DRY CHEMICAL
USES: This product is used as odor control for mercaptan. Use adequate ventilation. No
smoking.
STORAGE: In a cool dry well ventilated area, away from hear or ignition sources. Keep containers
labeled, upright, and tightly closed when not in use. Do not store in direct sunlight. Avoid
storage near incompatible material. handling
TRANSPORT:
SPILLS/LEAKS:
For transportation, Package do not require DOT/IMO, hazardous warning label (diamond).
Evacuate all unnecessary personnel, Shut off sources of ignition. Stop the flow if it can be
storage
done safely. Dike to prevent entry into sewer. Absorb with sand, place in a clean, dry,
closed container, and label.
&
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428. disposal
SAFETY Provide ventilation to control exposures below the TLVs. Safety goggles (21-434-249)
EQUIPMENT: and neoprene gloves (21-432-080), must be worn when handling this material. .APR or
SCBA should be worn if conditions warrant. Maintain eyewash fountain and emergency
shower and in storage area and wherever used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
EYE/SKIN Flush eyes with large amounts of water for at least 15 minutes while holding eyelids apart.
CONTACT: Remove contaminated clothing/shoes and wash clothing before re-use. Wash skin
thoroughly with soap and water.
first aid
INHALATION: Move effected person to fresh air. If breathing is difficult administer oxygen. If breathing
has stopped, apply cardio-pulmonary resuscitation (CPR).Keep person warm & quiet.
INGESTION: Do Not Induce Vomiting. Aspiration of material into lungs due to vomiting can cause
chemical pneumonitis, which can be fatal. If conscious, drink one-two glasses of water to
dilute. Keep warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Environmental Compliance Unit: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:3/5/2003
CHEMICAL HAZARD BULLETIN NO. 700
S/N 26-234-226 500-g bottle
CALCIUM
CHLORIDE
Health 1 COLORLES, ODORLESS GRANULES, FLAKES OR CAS: 10035-04-8
Fire 0 POWDER.SLIGHTLY TOXIC, NON FLAMMABLE AND UN: NONE
Reactivity 0 NOT REACTIVE. GUIDE: NONE
DUST/LIQUID: The product is 100% calcium chloride. No TLV has been set for this chemical.
EFFECTS OF OVER-EXPOSURE:
INHALATION:
EYE/ SKIN:
Dust may cause irritation to the nasal membrane.
Irritating to the eyes with redness and pain. Skin contact will cause severe irritation and
health
INGESTION:
erythema, ulcerations, necrosis and scarring.
Gastrointestinal distress and nausea. High doses may cause cardio-vascular hazards
irregularities.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
fire and
This product is non-flammable. Use fire-fighting techniques for surrounding fire.
REACTIVITY: Avoid contact with moisture, boric and calcium oxide and zinc metal.
EXTINGUISH FIRES WITH DRY CHEMICAL, CARBON DIOXIDE, FOAM OR WATER FOG.
reactivity
USAGE: This product is used as a laboratory reagent. Use adequate ventilation. No smoking. Do
not breathe vapors, dust, or mist.
STORAGE: Store in a well ventilated, cool, dry area. Keep containers labeled, upright, and tightly
closed when not in use. DO NOT store in direct sunlight. Avoid storage near
incompatible materials.
handling,
storage &
TRANSPORT: For transportation, packages do not require DOT-IMO hazardous warning label
(diamond).
SPILLS / LEAKS: Sweep up and place in clean, dry container. Do not flush spilt material into sewer. disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control exposures below the TLVs. Safety glasses, cotton gloves
EQUIPMENT: and coveralls must be worn when handling this material. Maintain an eyewash fountain
and emergency shower where ethyl chloride is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardio--pulmonary resuscitation (CPR). Keep person warm and quiet.
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally.
CONTACT: Wash skin thoroughly with soap and water. Remove contaminated clothing and shoes
promptly.
first aid
INGESTION: Induce vomiting. If conscious, give large quantities of water. Keep person warm and
quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:1/14/2001
CHEMICAL HAZARD BULLETIN NO. 712
S/N 26-766-961 500-gm bottle
POTASSIUM
IODATE
Health 2 WHITE ODORLESS CRYSTALLINE POWDER. CAS: 7758-05-6
Fire 0 MODERATELY TOXIC, NON- FLAMMABLE UN: 1479
Reactivity 3 AND HIGHLY REACTIVE. GUIDE: 140
fire and
This product is non-flammable. Firefighters must wear SCBA and protective clothing. During combustion,
oxides of iodine and potassium may be formed; also toxic vapors and smoke. Closed containers may rupture in
fire conditions. Keep containers cool with water spray.
REACTIVITY: Avoid contact with strong oxidizing agents, combustibles and organic material.
EXTINGUISH FIRES WITH DRY CHEMICAL, CARBON DIOXIDE, FOAM OR WATER FOG.
reactivity
USAGE: This product is a laboratory reagent. Use adequate ventilation. No smoking. Do not
breathe vapors, dust, or mist.
STORAGE: Store in a well ventilated, cool, dry area. Keep containers labeled, upright, and tightly
closed when not in use. DO NOT store in direct sunlight. Strong oxidizer. Contact with
other materials may cause a fire.
handling,
TRANSPORT: For transportation, label packages with DOT-IMO hazardous warning label (diamond):
ORGANIC PEROXIDE.
SPILLS / LEAKS: Evacuate all unnecessary personnel. Cover spill with ferrous sulfate or sodium sulfite and
moisten with diluted sulfuric acid to form a reducing slurry. Collect slurry and neutralize
with soda ash.
storage &
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
disposal
SAFETY Provide ventilation to control exposures below the TLVs. Safety goggles, neoprene gloves
EQUIPMENT: and coveralls must be worn when handling this material. APR or SCBA should be worn if
conditions warrant. Maintain an eyewash fountain and emergency shower where the
material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardio- pulmonary resuscitation (CPR). Keep person warm and quiet.
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly
and wash clothing before re-use. first aid
INGESTION: Induce vomiting immediately after giving 2 glasses of water. Avoid aspiration of material
into the lungs which can cause chemical pneumonitis and be fatal. Keep person warm
and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Reviewed:1/14/2001
CHEMICAL HAZARD BULLETIN NO. 723
S/N 26-007-130 19-L (5-gal) can
PENETRATING
OIL
INGESTION:
wash clothing before re-use.
DO NOT induce vomiting. Aspiration of material into the lungs due to vomiting can cause
first aid
chemical pneumonitis, which can be fatal. If conscious, drink one-two glasses of water to
dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ), or 427-2217 (JID).
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised 2/24/2001
CHEMICAL HAZARD BULLETIN NO. 736
1000170906 Water-Test kit
1000177936 50 KG DM
CITRIC ACID 1000179760 500 GM BT
1000179766 113 KG DM
1000186682 1 GA DM
health
INHALATION: Inhalation of dusts may irritate and may burn the respiratory tract and mucous
membranes.
hazards
EYE/ SKIN: Eye contact may cause severe irritation, and possible injury. Skin contact may causes
sensitization, an allergic reaction, which becomes evident upon re-exposure to this
material. Repeated exposure may cause sensitization dermatitis.
INGESTION: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Excessive intake
of citric acid may cause erosion of the teeth.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product is not flammable or combustible; however, heavy dust can form explosive mixture with air. Fire
fighters must wear SCBA and protective clothing. Fires produce carbon and nitrogen oxides, and also toxic
gases, vapors, fumes, and smoke. Closed containers may rupture in fire conditions. Cool containers fire and
reactivity
exposed to flames with water spray until well after the fire is out.
REACTIVITY: Normally stable, but can absorb atmospheric moisture. Incompatible with strong alkalis,
metal nitrates. Heat and sources of ignition.
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY/FOG, FOAM, OR CO2
USAGE: Laboratory reagent and water testing. Avoid breathing dust and avoid eye and skin
contact. NO SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, the product is not regulated, and
does not require hazardous warning labels.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 873-6676.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene gloves (1000129418) must be worn when handling this
material. APR (1000128165 or 10001281657) or SCBA (1000127427) should be worn if
conditions warrant. Maintain an eyewash fountain and emergency shower (1000128433)
where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 10/17/2004
CHEMICAL HAZARD BULLETIN NO. 745
health
INHALATION: Inhalation of vapors and dust which may be released at elevated temperatures may
irritate the respiratory tract. Effects may be minor due to the low vapor pressure of
hazards
EYE/ SKIN: Eye contact causes irritation and injury if not removed promptly. Skin contact results in
irritation, sensitization, and dermatitis rash.
INGESTION: May cause nausea, vomiting and diarrhea.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product flashpoint is 110 °C (230 °F). Fire fighters must wear SCBA and protective clothing. Fires
produce carbon, and nitrogen oxides, and also toxic gases, vapors, fumes, and smoke. Closed containers
may rupture in fire conditions. Cool containers exposed to flames with water spray until well after the fire is fire and
reactivity
out.
REACTIVITY: Stable, but polymerization may occur, particularly at elevated temperatures. Incompatible
with metals. Heat, sunlight, heat, and sources of ignition.
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY/FOG, FOAM, OR CO2
USAGE: Anaerobic sealant and adhesive. Avoid breathing vapor and dust and avoid eye and skin
contact. NO SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, the product is not regulated and
does not require hazardous label signs.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves and an apron
(1000128583) must be worn when handling this material. APR (1000128163) or SCBA
(1000127427) should be worn if conditions warrant. Maintain an eyewash fountain and
emergency shower (1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 1/1/2005
CHEMICAL HAZARD BULLETIN NO. 767
S/N 20-727-468 2.7 KG Container
WELDING
POWDER
EYE/SKIN:
EFFECTS OF OVEREXPOSURE:
Irritation to the eyes, causing itching, redness and tearing. Repeated or prolonged skin
health
INHALATION/
contact with dust causes irritation.
Inhalation of welding fumes is detrimental to health, may cause irritation of the respiratory hazards
INGESTION: tract, and contain copper, aluminum and iron. Dust inhalation or ingestion may be
harmful.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
This product is nonflammable particulate and therefore has no flashpoint. Metal powders may be moderate fire
hazard in the form of dust when exposed to flame. During welding, oxides of copper, aluminum, iron and nitrogen
will be formed, also toxic gases and smoke. Chlorinated hydrocarbons present near welding ultraviolet emissions
may be decomposed into toxic phosgene gas. Firefighters must use self-contained breathing apparatus (SCBA) fire and
and protective clothing. Closed containers may rupture in fire conditions. Keep containers cool with water spray.
Vapors are heavier than air and can flow along surfaces to distant ignition sources and flashback.
REACTIVITY: Avoid contact with strong oxidizing agents and chlorinated hydrocarbons during welding.
reactivity
EXTINGUISH AREA FIRES WITH DRY CHEMICAL, CO2, FOAM, OR WATER FOG.
USES: Copper alloy containing aluminum and iron welding material for CastoDyn spray systems,
for protective coatings on steels, alloy steels and other suitable industrial metals except
pure copper. Use adequate ventilation to evacuate fumes from the breathing area of the
welding operators. No eating, drinking or smoking during work. Use good work hygiene
and wash hands after job completion. Do not breathe fume or dust. Live electrical parts
must not be touched.
STORAGE: Store in a well-ventilated, cool, dry area, away from ignition sources. Keep containers
labeled, upright, and tightly closed when not in use. Avoid storage near incompatibles.
handling
SPILL: Evacuate all unnecessary personnel. Shut off sources of ignition. Prevent entry into
sewer. Collect, place in a clean, dry, closed container, and label.
storage
TRANSPORT: For transportation, no DOT-IMO hazardous warning label (diamond) is required.
For proper disposal methods and locations for chemical or chemical contaminated &
DISPOSAL: material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY
Provide ventilation to control vapor concentrations below the TLVs. During brazing,
welding, or thermal spraying, the eyes must be protected with approved colored welding
disposal
EQUIPMENT: goggles, and leather gloves and apron must be worn. APR or SCBA should be worn if
conditions warrant. Maintain an eyewash fountain and emergency shower where the
material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardio-pulmonary resuscitation (CPR). Keep person warm and quiet.
EYE/SKIN Flush eyes with large amounts of water for at least 15 minutes. Lift eyelids occasionally.
CONTACT: Wash skin thoroughly with water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use. first aid
INGESTION: Induce vomiting if accidentally ingested. If conscious, drink one-two glasses of water to
dilute. Keep person warm and quiet. GET MEDICAL ATTENTION.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:2/24/2001
CHEMICAL HAZARD BULLETIN NO. 770
S/N 24-620-339 3.8 Liter (1 Gal) Can
WELLRUN
BRAKE FLUIDS
Gastrointestinal distress, nausea, vomiting and diarrhea. May cause adverse central
hazards
INGESTION:
nervous system (CNS), renal effects, pulmonary edema and acidosis.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The flashpoint for this product is 135°C(275°F), with an explosive range in air not reported. Firefighters must use
self-contained breathing apparatus (SCBA) and protective clothing. During combustion, oxides of carbon and
nitrogen may be formed, also toxic organic vapors and smoke. Closed containers may rupture in fire conditions.
Keep containers cool with water spray. Vapors are heavier than air and can flow along surfaces to distant ignition fire and
sources and flashback.
EXTINGUISH FIRES WITH DRY CHEMICAL, CO2, ALCOHOL FOAM, OR WATER FOG
USES: Product is a hydraulic brake fluid. Practice reasonable care and personal cleanliness.
Use adequate ventilation. No smoking. Do not breathe vapors or mist.
STORAGE: Store in a well-ventilated, cool, dry area, away from ignition sources. Keep containers
handling
labeled, upright, and tightly closed when not in use. Avoid storage near incompatible
material.
Evacuate all unnecessary personnel. Shut off sources of ignition. Stop the flow if it can
SPILL: be done safely. Dike to prevent entry into sewer. Absorb with sand, place in a clean, dry,
closed container, and label.
storage
TRANSPORT:
DISPOSAL:
For transportation, no DOT-IMO hazardous warning label (diamond) is required.
For proper disposal methods and locations for chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
&
SAFETY
EQUIPMENT:
Provide ventilation to control vapor concentrations. Goggles (21-434-249) and neoprene
gloves (21-432-080) should be worn when handling quantities of this material. APR or
disposal
SCBA should be worn if conditions warrant. Maintain an eyewash fountain and
emergency shower where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardio-pulmonary resuscitation (CPR). Keep person warm and quiet.
EYE/SKIN Flush eyes with large amounts of water for at least 15 minutes. Lift eyelids occasionally.
CONTACT: Wash skin thoroughly with water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use. first aid
If ingested induce vomiting and call a physician immediately. If conscious, have drink
INGESTION: one-two glasses of water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:5/13/2001
CHEMICAL HAZARD BULLETIN NO. 776
S/N 26-004-340
GREASE
SR122
EYE/SKIN
EFFECTS OF OVER-EXPOSURE:
Vapor may cause irritation to the respiratory tract.
health
INHALATION: Irritating to the eyes, causing itching, redness and tearing. Repeated or prolonged skin
contact will cause irritation and discoloration. hazards
INGESTION: Gastrointestinal distress.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
This product is non-flammable. Fire fighters must use self-contained breathing apparatus (SCBA) and protective
clothing. During combustion oxides of carbon may be formed; also toxic organic vapors and smoke. Keep
containers cool with water spray.
fire and
REACTIVITY: Avoid contact with strong oxidizing agents.
EXTINGUISH MEDIA: DRY CHEMICAL, CO2, FOAM OR WATER FOG
reactivity
USAGE: This product is a ball-bearing grease. Avoid breathing vapor and mist. NO SMOKING.
Provide adequate ventilation.
TRANSPORTATION/ Store in a well-ventilated, cool, dry area. Keep containers labeled, upright and tightly
STORAGE: closed when not in use. DO NOT store in direct sunlight. Avoid storage near incompatible
material. Always label containers for transporting.
handling
SPILLS/LEAKS: Stop the flow if it can be done safely. Dlike to prevent entry into sewer. Absorb with sand
and place in clean, dry container. storage
For proper disposal methods and locations for the chemical or chemical contaminated
DISPOSAL:
material, contact the Environmental Engineering Division at 874-6426 or 874-6428. &
SAFETY Provide ventilation to control exposures below the guidelines. Safety goggles, neoprene
EQUIPMENT: gloves and coveralls must be worn when handling this material. SCBA should be worn if
conditions warrant. Maintain an eyewash fountain and emergency shower where the
disposal
material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quite,
and get medical attention.
EYE/SKIN Flush eye with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use. first aid
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis which can be fatal. Drink one-two glasses of water to dilute. Keep person
warm and quite.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:3/3/2001
CHEMICAL HAZARD BULLETIN NO. 778
S/N 26-111-042 55 Gal. Drum
DIETHANOLAMINE
(DEA)
EFFECTS OF OVER-EXPOSURE:
EYE/ SKIN: Severe skin irritation from repeated skin contact and possibly tissue destruction. Eye
contact will result in irritation, swelling of the conjunctiva and corneal injury may occur. health
INHALATION: Vapors or mists may cause irritation to the respiratory tract. Repeated overexposure may
cause damage to kidneys and liver. hazards
INGESTION: May cause irritation of the mouth, throat and gastro-intestinal distress, nausea, vomiting
and diarrhea.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
0 0
The flashpoint for this product is 179 C (355 F) with a given explosive range in air of 1.6% (LEL) to 9.8%
%(UEL). Fire-fighters must wear SCBA and protective clothing. During combustion, oxides of carbon, nitrogen
and sulfur may be formed; also toxic vapors and smoke. Closed containers may rupture in fire conditions. Keep
containers cool with water spray. fire and
REACTIVITY: Avoid contact with strong oxidizing agents, strong acids and strong bases. reactivity
EXTINGUISHING MEDIA: DRY CHEMICAL, CO2, FOAM, WATER FOG
USAGE: This product is used as an absorbent of acidic gases. Avoid breathing vapor or mist. NO
smoking. Provide adequate ventilation.
TRANSPORT/ Store in a well ventilated, cool, dry area. Keep containers labeled, upright and tightly
STORAGE: closed when not in use. DO NOT store in direct sunlight. Avoid storage near heat, open
flames and incompatible materials. Always label containers for transporting in accordance
SPILLS/ LEAKS:
with DOT/IMO/IATA hazard warning labels.
Stop the flow if it can be done safely. Dike to prevent entry into sewer. Absorb with sand
handling,
DISPOSAL:
and place in clean, dry container.
For proper disposal methods and locations for the chemical or chemical contaminated storage &
SAFETY
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
Provide ventilation to control airborne concentrations below the TLVs. Safety goggles, disposal
EQUIPMENT: rubber apron and rubber gloves must be worn when handling this material. SCBA should
be worn if conditions warrant. Maintain an eyewash fountain and emergency shower
where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
INGESTION:
and wash clothing before re-use.
Do not induce vomiting. Aspiration of material into the lungs can cause chemical
first aid
pneumonitis, which can be fatal. Drink one-two glasses of water to dilute. Keep person
warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print:7/3/2001
CHEMICAL HAZARD BULLETIN NO. 783
S/N 26-008-230 18 Liter can
SULTEX D
Cutting oil
Health 1 DARK LIQUID WITH A SULFUR ODOR, CAS: 6474-25-47
Fire 1 SLIGHTLY TOXIC, FLAMMABLE UN: 1993
Reactivity 1 AND REACTIVE GUIDE: 128
MIST/ LIQUID: Sultex D contains solvent-dewaxed heavy paraffinic petroleum distellates, fatty acid
material and a proprietary addative containing sulfur. TLV for mineral oil mists is 5
mg/m 3.
EYE/ SKIN:
EFFECTS OF OVER-EXPOSURE:
Irritating to the eyes, causing itching, redness and tearing. Repeated or prolonged skin health
INHALATION:
contact may cause irritation and discoloration.
Mist may cause irritation to the respiratory tract.
hazards
INGESTION: Gastro-intestinal distress.
The flashpoint for this product is 192ºC (378ºF). Fire fighters must wear SCBA and protective clothing. During
combustion, oxides of carbon nitrogen and sulfur may be formed; also toxic organic vapors and smoke.
Closed containers may rupture in fire conditions. Keep containers cool with water spray. Vapors are heavier
than air and can flow along surfaces to distant ignition sources and flashback.
fire and
REACTIVITY: Avoid contact with strong oxidizing agents and copper reactive material.
reactivity
EXTINGUISH FIRES WITH DRY CHEMICAL, CO2, FOAM OR WATER FOG
USAGE: Avoid breathing vapor or mist. NO SMOKING. Provide adequate ventilation. This product
is a heavy duty cutting oil.
TRANSPORT/ Store in a well ventilated, cool, dry area away from ignition sources. Keep containers
handling,
STORAGE: labeled, upright, and tightly closed when not in use. DO NOT store in direct sunlight.
Avoid storage near incompatible material. Always label containers for transporting. Use
DOT/IMO hazard warning labels.
SPILLS/ LEAKS: Shut off sources of ignition. Stop the flow if it can be done safely. Dike to prevent entry
into sewer. Absorb with sand a nd place in clean, dry container.
storage &
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428. disposal
SAFETY Provide ventilation to control vapor concentrations below the guidelines. Safety goggles
EQUIPMENT: and neoprene gloves and vinyl apron must be worn when handling this material. SCBA
should be worn if conditions warrant. Maintain an eyewash fountain and emergency
shower where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet,
and get medical attention.
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes
promptly, and wash clothing before re-use.
first aid
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print:3/17/2001
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis which can be fatal. Drink one-two glasses of water to dilute. Keep person
warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
ma440441
CHEMICAL HAZARD BULLETIN NO. 814
health
INHALATION: Inhalation of vapor and mists may irritate the respiratory tract, nose, and throat.
Symptoms include dizziness, drowsiness, incoordination, and chest. Prolonged or
repeated exposure may cause pulmonary sensitization, and CNS depression.
hazards
EYE/ SKIN: Eye contact may cause redness, severe irritation, and eye damage. Skin contact may
cause defatting, dryness, ulceration, and sensitization dermatitis.
INGESTION: Can cause gastrointestinal distress, vomiting, diarrhea. May cause violent
gastroenteritis, peripheral vascular collapse, dizziness, intense thirst, muscle cramps,
and coma.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The flashpoint ranges from 23 to 61°C (73 - 142°F); no explosive range was reported. Fire fighters must
wear SCBA and protective clothing. Fire produces carbon, sulfur, and nitrogen oxides, and also toxic gases,
vapors, fumes, and smoke. Closed containers may rupture in fire conditions. Cool containers exposed to fire and
reactivity
flames with water spray until well after the fire is out.
REACTIVITY: Normally stable. Incompatible with strong oxidizers. Heat, flames, and sources of ignition.
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY/FOG, FOAM, OR CO2
USAGE: Emulsifier in oil operations. Avoid breathing vapor and mists and avoid eye and skin contact.
NO SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions. Keep
TRANSPORT: tightly closed when not in use. For transportation, use DOT-IMO Class 3, hazardous warning
labels (diamond): FLAMMABLE LIQUID, N.O.S.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves and an apron
(1000128583) must be worn when handling this material. APR (1000128213/163) or SCBA
(1000127427) should be worn if conditions warrant. Maintain an eyewash fountain and
emergency shower (1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 1/10/2005
CHEMICAL HAZARD BULLETIN NO. 815
1612
Health H2 AMBER LIQUID WITH AROMATIC ODOR. CAS: Mixture
health
INHALATION: Inhalation may cause drowsiness, difficulty in breathing, and loss of coordination. The
product contains middle distillates which may cause cancer based on animal data.
hazards
EYE/ SKIN: May cause from mild to severe eye irritation. Skin contact may cause slight irritation.
Repeated or prolonged skin contact may cause dryness and cracking. Toxic amounts
may be absorbed through skin into body.
INGESTION: Gastrointestinal distress, nausea, vomiting, diarrhea, abdominal pain, and bleeding.
Amounts aspirated into lungs during ingestion may cause pulmonary injury after few
hours.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The minimum flashpoint of this product is 23°C (73°F); no explosive range was reported. Fire fighters must
wear SCBA and protective clothing. Fires produces carbon and nitrogen oxides, and also toxic gases,
vapors, fumes, and smoke. Do NOT use water jets. Closed containers may rupture in fire conditions. Cool fire and
reactivity
containers exposed to flames with water spray until well after the fire is out.
REACTIVITY: Normally stable. Incompatible with: Heat, flames, and sources of ignition. Strong oxidizers,
and rubbers and plastics.
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY/FOG, FOAM, OR CO2
USAGE: Dehydration of crude oil. Avoid breathing vapors and avoid eye and skin contact. NO
SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, label containers with DOT-IMO
Class 3 hazardous warning label (diamond): FLAMMABLE LIQUID, N.O.S.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 873-6676.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves and an apron
(1000128583) must be worn when handling this material. SCBA (1000127427) should be
worn if conditions warrant. Maintain an eyewash fountain and emergency shower
(1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-4538 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 4/3/2004
CHEMICAL HAZARD BULLETIN NO. 818
health
INHALATION: Repeated or prolonged inhalation may irritate the respiratory tract.
hazards
EYE/ SKIN: May cause mild irritation to the eyes and skin. Possible risk of irreversible adverse
effects of skin. Toxic amounts may be absorbed through skin into the body.
INGESTION: Gastrointestinal distress, nausea and vomiting. Can cause chemical pneumonia if
aspirated into lungs following ingestion. Can cause central nervous system depression.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product flashpoint is 28°C (83°F); no explosive range was reported. Fire fighters must wear SCBA and
protective clothing. Fires produces carbon and nitrogen oxides, and also toxic gases, vapors, fumes, and
smoke. Closed containers may rupture in fire conditions. Cool containers exposed to flames with water spray fire and
reactivity
until well after the fire is out.
REACTIVITY: Normally stable. Incompatible with: Heat, flames, and sources of ignition, including static
charges. Strong oxidizers.
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY/FOG, FOAM, OR CO2
USAGE: Demulsifier in wet-crude operations. Avoid breathing dust and avoid eye and skin contact.
NO SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, label containers with DOT-IMO
Class 3 hazardous warning label (diamond): FLAMMABLE LIQUID, N.O.S.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 873-6676.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves and an apron
(1000128583) must be worn when handling this material. SCBA (1000127427) should be
worn if conditions warrant. Maintain an eyewash fountain and emergency shower
(1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-4538 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 3/31/2004
CHEMICAL HAZARD BULLETIN NO. 826
CHLORIDE
Health 1 COLORLESS OR WHITE CRYSTALS WITH NO ODOR, CAS: 7447-40-7
UN: None
Fire 0 SLIGHTLY TOXIC AND REACTIVE GUIDE: None
EAC: None
Reactivity 1 NONFLAMMABLE. IRRITANT
DUST/SOLID: 100 % potassium chloride. No TLVs have been established for this product.
EFFECT OF OVER-EXPOSURE:
EYE/SKIN: Moderately Irritating to the eyes, causing itching, redness and tearing. Repeated or
prolonged skin contact will cause irritation, burning and dermatitis in particular with moist
INHALATION:
skin.
Dust may cause irritation to the nasal or respirator tract.
health
INGESTION: Gastro-intestinal upset, nausea, vomiting and diarrhea. Large quantities May affect the
heart producing weakness and circulatory problems. May be fatal.
hazards
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
This product is nonflammable, with explosion range in air not reported. Firefighters must wear SCBA and
protective clothing. During combustion, oxides of contained metals and halogens may be formed. Keep containers
cool with water spray. fire and
REACTIVITY: Avoid contact with strong oxidizing agents. (e.g potassium permanganate ), sulfuric acid trifluoride
bromine. reactivity
EXTINGUISH MEDIA: DRY CHEMICAL, CO2, FOAM, WATER FOG
USAGE: This product is a laboratory reagent. Avoid generating dust. Avoid breathing vapor, mist
or dust and contact with eyes, skin or clothing. No smoking and provide adequate
ventilation.
TRANSPORT/
STORAGE:
Store in a well ventilated, cool, dry area away from ignition sources. Keep containers
labeled, upright and tightly closed when not in use. Do not store in direct sunlight. Avoid
handling
storage near incompatible material. For transportation, packages do not require DOT-IMO
hazardous warning label (diamond) or placard. storage
SPILLS/LEAKS: Small amounts may be washed to chemical sewage. Dike to prevent entry into sewer.
Avoiding the generation of the dust shovel and place in clean, dry container.
&
DISPOSAL:
For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at (874-6426 or 874-6428).
disposal
SAFETY Provide ventilation to control vapor concentrations below the guidelines. Safety goggles
EQUIPMENT: (1000129810) and neoprene gloves (1000129418) must be worn when handling this
material. SCBA should be worn if conditions warrant. Maintain an eyewash fountain and
emergency shower where the material is being stored/used.
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet,
and get medical attention.
EYE/SKIN
CONTACT:
Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly, first aid
and wash clothing before re-use.
INGESTION: Physician may recommend to induce vomiting. Give several glasses of water to drink to
dilute. Keep person warm and quite.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
*Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised: 9/12/2004
CHEMICAL HAZARD BULLETIN NO. 827
POTASSIUM S/N 26-768-011 500 gm bottle
26-111-063 275 lb Drum
NITRATE
health
EYE/ SKIN: Irritating to the eyes, causing itching, redness and tearing. Repeated or prolonged skin
contact may cause irritation, itching and pain.
hazards
INHALATION: Dust may cause irritation to the respiratory tract characterized by coughing and shortness
of breath.
INGESTION: Gastro-intestinal distress, nausea, vomiting and diarrhea.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
This product is non-flammable but can start fires in its reaction with combustion. Fire fighters must wear
SCBA and protective clothing. During combustion, oxides of nitrogen, toxic vapors and smoke are formed.
Closed containers may rupture in fire conditions. Keep containers cool with water spray. fire and
REACTIVITY: Avoid contact with strong acids, carbonaceous material and organic compounds.
reactivity
EXTINGUISH FIRES WITH DRY CHEMICAL, CO2, FOAM, OR WATER FOG
USAGE: This product is a laboratory reagent. Avoid breathing dust. NO SMOKING. Provide
adequate ventilation.
STORAGE/ Store in a well-ventilated, cool, dry area, away from ignition sources. Keep containers
TRANSPORT: labeled, upright and tightly closed when not in use. DO Not store in direct sunlight. Avoid
storage near incompatible material. Always label containers for transporting. Use
DOT/IMO hazard warning labels “Oxidizer”. handling,
storage &
SPILLS/ Shut off sources of ignition. Stop the flow if it can be done safely. Dike to prevent entry
LEAKS: into sewer. Sweep up and place in clean, dry container.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control dust concentrations below the guidelines. Safety goggles
EQUIPMENT: (21-434-249) and neoprene gloves (21-432-080) must be worn when handling this
material. SCBA should be worn if conditions warrant. Maintain an eyewash fountain and
emergency shower where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet,
and get medical attention.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes and lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: Induce vomiting. Aspiration of material into the lungs can cause chemical pneumonitis,
which can be fatal. Drink one-two glasses of water to dilute. Keep person warm and
quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised: 10/23/2001
CHEMICAL HAZARD BULLETIN NO. 835
1000140226 10-OZ CN
PC DUSTER
health
INHALATION: Inhalation of high concentrations of vapor and mists may cause anesthesia, rapid
breathing, lung congestion microscopic liver change, and CNS depression. It may lead
to asphyxiation in oxygen-deficient atmosphere (<19.5%).
hazards
EYE/ SKIN: The compound is a skin irritant and a slight eye irritant.
The product is not flammable or combustible. Fire fighters must wear SCBA and protective clothing. Fire
produces chlorine and fluorine oxides, and also toxic gases, vapors, fumes, and smoke. Closed containers
may rupture in fire conditions. Cool containers exposed to flames with water spray until well after the fire is fire and
reactivity
out.
REACTIVITY: Normally stable. Incompatible with alkali or alkaline earth metals such as sodium and
potassium.. Heat, flames, and sources of ignition.
EXTINGUISHING MEDIA: SUITABLE MEDIA FOR SURROUNDING FIRE
USAGE: Office equipment duster. Avoid breathing vapor and mists and avoid eye and skin contact.
NO SMOKING. Provide adequate ventilation.
handling,
STORAGE/ Store in a ventilated, cool (<120F), dry area, away from incompatible materials and
TRANSPORT: conditions. Keep tightly closed when not in use. For transportation, use DOT-IMO Class
2.2 hazardous warning labels (diamond): NON-FLAMMABLE GAS, N.O.S.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, ventilate area to disperse vapors. May
LEAKS: use water may to reduce vapors. Toxic to the environment; depletes the ozone layer.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety equipment
EQUIPMENT: are optional; e.g, goggles (1000129810). APR (1000128213/163) or SCBA (1000127427)
should be worn if conditions warrant. Maintain an eyewash fountain and emergency
shower (1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 1/10/2005
CHEMICAL HAZARD BULLETIN NO. 856
health
INHALATION: Inhalation of vapor may irritate the respiratory tract, nose, and throat.
hazards
EYE/ SKIN: Eye and skin contact may cause dryness, irritation, itching, and redness.
The product is not flammable, but combustible; flashpoint is 204°C (400°F). Fire fighters must wear SCBA
and protective clothing. Fire produces silicone, carbon and nitrogen oxides, and also toxic gases, vapors,
fumes, and smoke. Closed containers may rupture in fire conditions. Cool containers exposed to flames fire and
reactivity
with water spray until well after the fire is out.
REACTIVITY: Normally stable. Incompatible with strong oxidizers, e.g., nitric acid. Heat, flames, and
sources of ignition.
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY/FOG, FOAM, OR CO2
USAGE: Silicon fluid lubricant. Avoid breathing vapor and avoid eye and skin contact. NO
SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, the product is not regulated, and
does not require hazardous labels.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves and an apron
(1000128583) may be worn when handling this material. APR (1000128213/163) or
SCBA (1000127427) should be worn if conditions warrant. Maintain an eyewash fountain
and emergency shower (1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 1/10/2005
CHEMICAL HAZARD BULLETIN NO. 873
PVC CEMENT 10000182431 0.95-L CN
health
INHALATION: Inhalation of vapor and dust (if dry) may cause irritation of mucous membranes, nose,
and throat. Symptoms include headache, dizziness, and nausea, numbness of the
extremities, narcosis (at high concentration), CNS depression, and liver damage. Silica
is classified as potential carcinogen.
hazards
EYE/ SKIN: Eye contact may cause irritation. Skin contact causes irritation, and sensitization
dermatitis. May be absorbed through skin.
INGESTION: May be aspired into the lungs or cause systemic effects described under inhalation.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product flashpoint is -15 °C (5 °F) with an explosive range from 1.8 to 11.8%. Fire fighters must wear
SCBA and protective clothing. Fires produce carbon, hydrogen chloride, and nitrogen oxides, and also toxic
gases, vapors, fumes, and smoke. Closed containers may rupture in fire conditions. Cool containers fire and
reactivity
exposed to flames with water spray until well after the fire is out.
REACTIVITY: Normally stable. Incompatible with strong oxidizers, e.g., nitric acid. Heat, flames, and
sources of ignition.
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY/FOG, FOAM, OR CO2
USAGE: Cement solvent. Avoid breathing vapor and dust (if dry) and avoid eye and skin contact.
NO SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed when not in use. For transportation, use DOT-IMO Class 3.3
hazardous warning labels (diamond): FLAMMABLE LIQUID, N.O.S.
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 974-6428.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves and an apron
(1000128583) must be worn when handling this material. APR (1000128163) or SCBA
(1000127427) should be worn if conditions warrant. Maintain an eyewash fountain and
emergency shower (1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 12/11/2004
CHEMICAL HAZARD BULLETIN NO.904
1000172836/864/866/922/925/926/928/929 5-55 Gallon Drum
TURBINE & 1000172838/868
1000173065/093/152/540
Bulk Delivery
55 Gallon Drum
ENGINE OILS 1000176139 55 Gallon Drum
1000645830 55 Gallon Drum
VAPOR/LIQUID: These products contain heavy paraffinic petroleum distillates, ditertiarybutylphenol and
additive packages of sulfur, phosphorus and alkylated amines. The TLV for oil mist is 5
mg/m³.
EFFECTS OF OVER-EXPOSURE:
EYE/ SKIN: Slightly irritating to the eyes, causing itching, redness and tearing. Repeated or prolonged
skin contact may cause defatting of tissues, irritation and skin discoloration. health
INHALATION: Vapor may cause irritation to the respiratory tract or nervous system depression,
characterized by headache, nausea and dizziness. hazards
INGESTION: Unlikely route of exposure.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The flashpoint for this product without propellant is 224°C (435°F), with explosion range in air 1-6 %. Fire-fighters
must wear SCBA and protective clothing. During combustion, oxides of carbon, aldehydes, ketones, nitrogen and
sulfur may be formed; also toxic organic vapors and smoke. Closed containers may rupture in fire conditions. fire and
Keep containers cool with water spray. Vapors are heavier than air and can flow along surfaces to distant ignition
sources and flashback. reactivity
REACTIVITY: Avoid contact with strong oxidizing agents.
USAGE: Turbine/engine oils. Avoid breathing vapor or mist. NO smoking. Provide adequate
ventilation.
TRANSPORT/ Store in a well-ventilated, cool, dry area, away from ignition sources. Keep containers
STORAGE: tightly closed when not in use. DO not store in direct sunlight and avoid storage near
incompatible material. Always label containers for transporting in accordance with
handling
DOT/IMO/IATA hazard warning labels.
storage
SPILLS/ LEAKS: Shut off sources of ignition. Stop the flow if it can be done safely. Dike to prevent entry
into sewer. Absorb with sand and place in clean, dry container. &
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428. disposal
SAFETY Provide adequate ventilation to control vapor concentrations below the TLV. Safety
EQUIPMENT: goggles (1000129810) and PVC gloves (1000129628) must be worn when handling this
material. SCBA should be worn if conditions warrant. Maintain an eyewash fountain and
emergency shower where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use. first aid
INGESTION: Do not induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Drink one-two glasses of water to dilute. Keep person
warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Environmental Protection: 873-5853 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:12/13/2005
CHEMICAL HAZARD BULLETIN NO. 915
OXYGEN/
1000176047 M43.8-L CR
NITROGEN
CALIBRATION
GAS
Health H0 CAS: Mixture
CLEAR, ODORLESS GAS.
Fire F0 NON-FLAMMABLE, NON-TOXIC, AND STABLE. UN: 1002
Reactivity R0 SIMPLE ASPHYXIANT. GUIDE: 122
EAC: 2T
LIQUID/ The product is a gaseous blend of 7% oxygen and 93% nitrogen gas. There are no
GAS: specific exposure limits for oxygen or nitrogen. Nitrogen gas is considered a simple
asphyxiant that can replace oxygen in breathing air.
Note: Oxygen levels should be maintained above 19.5%.
EFFECTS OF OVER-EXPOSURE:
health
INHALATION: The acute effect of this product is the inhalation of oxygen-deficient atmospheres.
Symptoms include shortness of breath, ringing in ears, headaches, wheezing, headache,
dizziness, indigestion, nausea. At high concentrations, unconsciousness or death may
occur. The skin of a victim of over-exposure may have a blue color. No known adverse
health effects associated with chronic exposure
hazards
EYE/ SKIN: May cause eye irritation. Due to rapid evaporation, the liquid may cause eye and skin
frostbite with redness. This may also result in blurred vision and hard and white skin.
INGESTION: Unlikely route of exposure. Frostbites damage lips, mouth, and mucous membranes.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
Non-flammable product. Fire fighters must wear SCBA and protective clothing. Fires produces carbon and
nitrogen oxides, and also toxic gases, vapors, fumes, and smoke. Closed containers may rupture in fire
conditions. Cool containers exposed to flames with water spray until well after the fire is out. fire and
REACTIVITY: Normally stable. Incompatible with: Heat. Cylinders may explode in heat of fires
reactivity
EXTINGUISHING MEDIA: DRY POWDER, WATER SPRAY/FOG, FOAM, OR CO2
USAGE: Calibration gas for Lab equipment. Avoid breathing gases and avoid eye and skin contact.
NO SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials and conditions.
TRANSPORT: Keep tightly closed. For transportation, label containers with DOT-IMO Class 2.2
hazardous warning label (diamond): NON-FLAMMABLE COMPRESSED GASES.
storage &
SPILLS/ Evacuate unauthorized personnel. Shut off ignition sources. Stop leak if possible without
LEAKS: risk. Use plenty of water to reduce vapors. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves and an apron
must be worn when handling this material. SCBA (1000127427) should be worn if
conditions warrant. Maintain an eyewash fountain and emergency shower (1000128433)
where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-4538 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 3/27/2004
CHEMICAL HAZARD BULLETIN NO. 926
KXZ-1031
STORAGE: Store in a cool, dry area away from sources of ignition and incompatible materials.
TRANSPORT: For transportation use DOT-IMO hazard warning label class 3 FLAMMABLE LIQUID
handling
SPILLS/LEAKS: Evacuate all unnecessary personnel. Isolate and shut off sources of ignition. Stop the
DISPOSAL: flow if it can be done safely. Avoid contact with spilled material. Wear adequate PPE.
Use completely or empty aerosol cans before disposal. For proper disposal methods and
storage
locations for chemical or chemical contaminated material, contact the Environmental
Engineering Division at 874-6426. &
SAFETY
EQUIPMENT:
Provide normal ventilation to atmosphere. Air supplied or SCBA should be available.
Safety goggles (1000129810) and must be worn and neoprene gloves (1000129418)
disposal
when handling quantities of this chemical. Maintain eyewash fountain and emergency
shower in storage area and wherever used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
EYE/SKIN Flush eyes with large amounts of water for at least 15 minutes. Lift eyelids occasionally.
CONTACT: Wash skin thoroughly with soap and water. Remove contaminated clothing and shoes
promptly, and wash clothing before re-use.
first aid
INHALATION: Remove those exposed to fresh air. If breathing is difficult administer oxygen. If breathing
has stopped, apply cardio-pulmonary resuscitation (CPR).
INGESTION: Give nothing by mouth. Do not induce vomiting. Keep warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Environmental Protection: 872-2623 (DH), 678-4902 (RT), 572-4538 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:5/17/2003
CHEMICAL HAZARD BULLETIN NO. 933
POTASSIUM 1000185453
1000185448
1 LT BT
500 GM BT
IODIDE
Health 2 COLORLESS, ODORLESS WHITE CRYSTALS CAS: 7681-11-0
Fire 0 OR GRANULES, MODERATELY TOXIC AND UN: None
Reactivity 2 REACTIVE, NON-FLAMMABLE GUIDE: None
EAC: None
DUST/SOLID: 100% potassium iodide. No TLVs have been established for this product.
EFFECT OF OVER-EXPOSURE:
EYE/SKIN: Irritating to the eyes, causing itching, redness and tearing. Repeated or prolonged skin
contact will cause irritation.
This product is non-flammable. Firefighters must wear self-container breathing apparatus SCBA and protective
clothing. During combustion, oxides of iodine may be formed; also toxic iodine vapors and smoke. Closed
containers may rupture in fire conditions. Keep containers cool with water spray. fire and
REACTIVITY: On long exposure to air becomes yellow due to release of iodine. Avoid contact with diazonium
salts, diisopropyl peroxydicarbonate, oxidants, bromine and chlorine trifluorides, fluorine perchlorate, calomel,
reactivity
potassium chlorate metallic salts, tartaric and other acids.
EXTINGUISH MEDIA: DRY CHEMICAL, CO2, FOAM, WATER FOG
USAGE: This product is a laboratory reagent. Avoid breathing dust. No smoking. Provide adequate
ventilation.
handling
STORAGE/ Store in a well ventilated, cool, dry area away from ignition sources. Keep containers
TRANSPORT: labeled, upright and tightly closed when not in use. Do not store in direct sunlight. Avoid
storage near incompatible material. For transportation, packages do not require DOT-
SPILLS/LEAKS:
IMO hazardous warning labels.
Sweep up and place in clean, dry container.
storage
DISPOSAL:
For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at (874-6426 or 874-6428).
&
SAFETY
EQUIPMENT:
Provide ventilation to control vapor concentrations. Safety goggles (1000129810) and
neoprene gloves (100012418) must be worn when handling this material. SCBA should
disposal
be worn if conditions warrant. Maintain an eyewash fountain and emergency shower
where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet,
and get medical attention.
EYE/SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT:
INGESTION:
skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
Induce vomiting. Aspiration of material into the lungs can cause chemical pneumonitis
first aid
which can be fatal. Keep person warm and quite.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
*Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised: 9/12/2004
CHEMICAL HAZARD BULLETIN NO. 934
SULFATE
Health 1 WHITE GRANULAR SOLID OR POWDER WITH NO ODOR CAS: 7778-80-5
Fire 0 SLIGHTLY TOXIC AND REACTIVE UN: None
Reactivity 1 NON-FLAMMABLE GUIDE: None
EAC: None
INGESTION:
Dust may cause irritation to the respiratory tract, characterized by sneezing and coughing.
hazards
Gastro-intestinal distress, nausea, vomiting and diarrhea.
EYE/SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
first aid
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis which can be fatal. Drink one-two glasses of water to dilute (BUT first obtain
medical authorization). Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
*Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised: 9/12/2004
CHEMICAL HAZARD BULLETIN NO. 937
DUST/SOLID: No threshold limit value has been established for this alkaline material commonly referred
to as baking soda and used for stomach antacid.
EFFECT OF OVER-EXPOSURE:
EYE/SKIN: Irritating to the eyes, causing itching, redness and tearing. Repeated or prolonged skin
INHALATION:
contact may cause irritation.
Dust may cause irritation to the respiratory tract, characterized by sore throat and
health
INGESTION:
coughing, increased mucous flow in nose.
Large doses could cause gastrointestinal upset, nausea, vomiting and diarrhea.
hazards
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
This chemical and its decomposition products are not flammable. If involved in a fire firefighters must wear
personal protection that is consistent with other materials in the environment. Combustion products include: CO2
SO, sodium carbonate & sodium oxide. fire and
REACTIVITY: Avoid contact with strong acids. eg. (Hydrochloric and sulfuric acid ) and other chemicals such as:
monoaluminium phosphate, sodium-potassium alloy & 2-Furaldehyde. reactivity
EXTINGUISH MEDIA: DRY CHEMICAL, CO2, FOAM, WATER FOG
USAGE: This product is a laboratory reagent and water treatment chemical. Avoid breathing dust.
No smoking.
handling
STORAGE/ Store in a well ventilated, cool, dry area away from ignition sources. Keep containers
TRANSPORT: labeled, upright and tightly closed when not in use. Do not store in direct sunlight. Avoid
storage near incompatible material. For transportation, packages do not require DOT-
SPILLS/LEAKS:
IMO hazardous warning labels.
Sweep up and place in a clean, dry container.
storage
DISPOSAL:
For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at (874-6426 or 874-6428).
&
SAFETY
EQUIPMENT:
Provide ventilation to control dust concentrations. Safety goggles (1000129810) and
neoprene gloves (1000129418) should be worn when handling this material. SCBA
disposal
should be worn if conditions warrant. Maintain an eyewash fountain and emergency
shower where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
For further information call Industrial Hygiene: 872-2623 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
*Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised: 9/12/2004
CHEMICAL HAZARD BULLETIN NO. 952
MICATEX 1000021678 25 KG SK
TRANSPORT:
Avoid storage near incompatible materials.
For transportation, packages do not require DOT-IMO hazardous warning label
handling
SPILLS/LEAKS:
(diamond).
Shut off sources of ignition. Stop the flow if it can be done safely. Dike to prevent entery
storage
DISPOSAL:
into sewer. Absorb in dry sand and place into clean, dry, labeled containers. Flush with
plenty of water to clean spillage area. &
disposal
For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control exposures below the TLVs. Chemical goggles (1000129810)
EQUIPMENT: and neoprene gloves (1000129418) must always be worn when handling this material.
SCBA should be worn if conditions warrant. Maintain eyewash fountain and emergency
shower in storage area and wherever used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
EYE/SKIN Immediately, flush eyes with copious amounts of water for at least 15 minutes holding
CONTACT: eyelids apart. Remove contaminated clothing/shoes. Wash skin thoroughly with soap and
water. Wash contaminated clothing before use.
first aid
INHALATION: Remove those exposed persons to fresh air. If breathing is difficult administer oxygen. If
breathing has stopped, apply cardio-pulmonary resuscitation (CPR).Keep person quiet
and warm.
INGESTION: Do not induce vomiting. Aspiration of material into lungs can cause chemical pneumonitis,
which can be fatal. Wash out mouth thoroughly. Give water to drink if conscious to dilute
BUT first obtain medical authorization. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Environmental Protection: 872-2623 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:9/1/2004
CHEMICAL HAZARD BULLETIN NO. 954
COTTON 1000021603 25 KG SK
SEED HULLS
DUST/SOLID: Fibrous, plant by product. Cotton dust is classed as nuisance dust TLV=10mg/m3.
EFFECT OF OVER-EXPOSURE:
EYE/SKIN: May cause eye & skin irritation. Repeated or prolonged skin contact will cause dryness,
irritation and dermatitis.
INHALATION: A powerful allergen dust may cause respiratory tract irritation, bronchial asthma &
sneezing.
health
INGESTION:
Gastro-intestinal upset, nausea, vomiting and diarrhea.
hazards
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
This product is slightly flammable when exposed to heat. Spontaneous heating may occur if piled/stored wet and
hot, when dangerous amount of heat may be generated. Firefighters must wear SCBA and protection clothing.
fire and
REACTIVITY: Non-Reactive. Avoid heat and wetness.
EXTINGUISH MEDIA: DRY CHEMICAL, CO2, FOAM, WATER FOG
reactivity
USAGE: This product is a drilling mud admixture. Avoid breathing dust. No Smoking. Provide
adequate ventilation.
handling
STORAGE/ Store in a well ventilated, cool, dry area away from ignition sources. Keep containers
TRANSPORT: labeled, upright and tightly closed when not in use. Do not store in direct sunlight. Avoid
storage near incompatible material. For transportation, packages do not require DOT-IMO
SPILLS/LEAKS:
hazardous warning label (diamond) or placard.
Shut off sources of ignition. Sweep up and place in clean, dry container.
storage
DISPOSAL:
For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at (874-6426 or 874-6428).
&
SAFETY
EQUIPMENT:
Provide ventilation to control dust concentrations. Safety goggles (1000129810) and
normal work gloves (1000129418) must be worn when handling this material. SCBA
disposal
should be worn if conditions warrant. Maintain an eyewash fountain and emergency
shower where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet,
and get medical attention.
EYE/SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT:
INGESTION:
skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
Do not induce vomiting. Aspiration of material into the lungs can cause chemical
first aid
pneumonitis which can be fatal. Drink one-two glasses of water to dilute. Keep person
warm and quite.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4868 (RT), 572-1449 (ABQ) or 427-0155 (JID)
*Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised: 9/12/2004
CHEMICAL HAZARD BULLETIN NO. 959
S/N 26-111-049 200 lb bag
POTASSIUM
CARBONATE
EFFECTS OF OVER-EXPOSURE:
EYE/ SKIN: Extremely irritating to the eyes, causing itching, redness, pain and possibly corneal
damage. Repeated or prolonged skin contact with dry material may cause irritation.
Aqueous solution is corrosive and may cause dryness, defatting, irritation and dermatitis. health
INHALATION: Causes irritation to the respiratory tract. Symptoms may include coughing and shortness of
breath. hazards
INGESTION: Ingestion of large amounts may be corrosive to the mouth, throat and GI tract and may
produce gastro-intestinal distress, nausea, vomiting, diarrhea and circulatory collapse.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The flashpoint for this product and explosion range in air are not reported. Fire-fighters must wear SCBA and
protective clothing. During combustion, oxides of carbon, sulfur, phosphorous and nitrogen may be formed; also
toxic organic vapors and smoke. Closed containers may rupture in fire conditions. Keep containers cool with
water spray. fire and
REACTIVITY: Avoid contact with acids, chlorine trifluoride and magnesium. reactivity
EXTINGUISHING MEDIA: DRY CHEMICAL, CO2, FOAM, WATER FOG
USAGE: Potassium carbonate is used in the Benfield process. Avoid breathing dust or mist. NO
SMOKING. Provide adequate ventilation.
TRANSPORT/ Store in a well ventilated, cool, dry area away from ignition sources. Keep containers
handling,
STORAGE: labeled, upright and tightly closed when not in use. DO NOT store in direct sunlight. Avoid
storage near incompatible material. Always label containers for transporting in accordance
with DOT/IMO/IATA hazard warning labels.
SPILLS/ LEAKS: Shut off sources of ignition. Stop the flow if it can be done safely. Dike to prevent entry
into sewer. Absorb with sand and place in clean, dry container.
storage &
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
disposal
SAFETY Safety goggles, rubber apron and rubber gloves must be worn when handling this material.
EQUIPMENT: SCBA should be worn if conditions warrant. Maintain an eyewash fountain and emergency
shower where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
INGESTION:
and wash clothing before re-use.
Do not induce vomiting. Aspiration of material into the lungs can cause chemical
first aid
pneumonitis, which can be fatal. Drink one-two glasses of water to dilute. Keep person
warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:1/14/2001
CHEMICAL HAZARD BULLETIN NO. 964
1000021449 50-LB SK
BARITE 1000021550 BULK DELIVERY
(Barium Sulfate)
Health H4 CAS: 7727-43-7
PINK TO TAN TO GRAY POWDER. ODORLESS.
Fire F0 EXTREMELY TOXIC, NON-FLAMMABLE, AND STABLE. UN: N/A
Reactivity R1 RESPIRATORY TRACT, EYE, AND SKIN IRRITANT. GUIDE: N/A
MAY CAUSE LUNG DISEASES DUE TO PRESENCE OF EAC: N/A
CRYSTALLINE SILICA.
DUST: The product contains 60 -100% barium sulfate (TLV=10 mg/m3) and 1-5% crystalline silica
(TLV=0.1 mg/m3).
EFFECTS OF OVER-EXPOSURE:
health
INHALATION: Harmful by inhalation. Irritates the nose, throat, and respiratory passages. Chronic
exposure to crystalline silica can cause lung disease, including silicosis and lung cancer.
Crystalline silica may also be associated with kidney disease.
hazards
EYE/ SKIN: May cause mild eye irritation. Skin contact may produce dryness and itching.
INGESTION: Gastrointestinal distress, nausea, vomiting, diarrhea, and abdominal pain. Feeling of
weakness, unsteady walk, and Dalton of blood vessels. May also affect the heart.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product is not flammable. Fire fighters must wear SCBA and protective clothing. Fires produces
carbon, sulfur, barium, nitrogen oxides, toxic gases, vapors, fumes, and smoke. Closed containers may
rupture in fire conditions. Cool containers exposed to flames with water spray until well after the fire is out. fire and
REACTIVITY: Normally stable. Incompatible with: Heat, flames, and sources of ignition. Aluminum and
phosphorous. reactivity
EXTINGUISHING MEDIA: USE MEDIA SUITABLE FOR SURROUNDING FIRES
USAGE: Weight additive in drilling operations. Avoid breathing dust and avoid eye and skin
contact. NO SMOKING. Provide adequate and local exhaust ventilation.
handling,
STORAGE/ Store in a ventilated, cool, dry area, away from incompatible materials. Keep tightly closed
TRANSPORT: when not in use. For transportation, the product is not regulated. Packages do not require
DOT-IMO hazardous warning label (Diamond).
storage &
SPILLS/ Evacuate unauthorized personnel. For large spills, dike to prevent entry into sewer. For
LEAKS: small spills, absorb in dry sand or earth. Shovel and place into clean, dry, labeled
containers. Flush with plenty of water to clean spillage area. Toxic to aquatic organisms.
disposal
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426 or 873-6676.
SAFETY Provide ventilation to control overexposure and eye and skin contact. Safety goggles
EQUIPMENT: (1000129810) and neoprene (1000129418) or PVC (1000129492) gloves and an apron
(1000128583) must be worn when handling this material. SCBA (1000127427) should be
worn if conditions warrant. Maintain an eyewash fountain and emergency shower
(1000128433) where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
first aid
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
and wash clothing before re-use.
INGESTION: DO NOT induce vomiting. Aspiration of material into the lungs can cause chemical
pneumonitis, which can be fatal. Wash out mouth thoroughly. Drink one-two glasses of
water to dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2619 (DH), 678-4868 (RT), 572-4538 (ABQ) or 472-0155 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print: 3/31/2004
CHEMICAL HAZARD BULLETIN NO. 971
S/N 26-301-886 Bulk Delivery
PHASETREAT
1616
DEMULSIFIER
Reactivity 1
3
VAPOR/MIST/ This product contains 5-20% diesel TLV=100 mg/m , 15-25% isobutanol TLV=50 ppm,
LIQUID: and 15-25% aromatic solvents. It contains middle distillates, which may cause cancer
based on animal data.
INHALATION:
EFFECTS OF OVER-EXPOSURE:
Vapor may cause drowsiness and narcosis.
health
EYE/ SKIN: May cause mild eye irritation. Slight skin irritant. Repeated or prolonged skin contact may
have a degreasing action where it may cause dryness and cracking. hazards
INGESTION: Gastrointestinal distress. If aspirated into the lungs it may cause pulmonary injury. The
onset of the respiratory symptoms may be delayed for several hours after exposure.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The flash point of this product is from 23-61°C (73-142°F). No explosive limits are given. Firefighters must wear
SCBA and protective clothing. During combustion, toxic vapors and smoke may be formed. Closed containers
may rupture in fire conditions. Keep containers cool with water spray.
fire and
REACTIVITY: Avoid contact with strong oxidizing agents.
EXTINGUISH FIRES WITH DRY CHEMICAL, CO2, FOAM OR WATER FOG
reactivity
USAGE: Demulsifier for oil/water mixtures. Use adequate ventilation. No smoking. Avoid breathing
vapor or mist.
STORAGE: Store in a well-ventilated, cool, dry area, away from sources of ignition. Keep tightly closed
when not in use. DO NOT store in direct sunlight. Avoid storage near incompatible
handling,
materials.
TRANSPORT: Mark with hazardous warning labels.
SPILLS / LEAKS: Evacuate all unnecessary personnel. Stop the flow if it can be done safely. Dike to prevent
DISPOSAL:
entry into sewer. Absorb with sand and place in clean, dry, labeled container.
For proper disposal methods and locations for chemical or chemical contaminated material, storage &
disposal
contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control exposures. Safety goggles, neoprene gloves, cover-all’s and
EQUIPMENT: rubber safety boots must be worn when handling this material. APR or SCBA should be
worn if conditions warrant. Maintain an eyewash fountain and emergency shower where
the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLY
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardio-pulmonary resuscitation (CPR). Keep person warm and quiet.
EYE / SKIN Flush eyes with large amounts of water for at least 15 minutes. Lift eyelids occasionally.
CONTACT: Wash skin thoroughly with water. Remove contaminated clothing and shoes promptly and
wash clothing before re-use.
DO NOT induce vomiting. Aspiration of material into the lungs due to vomiting can cause
first aid
INGESTION:
chemical pneumonitis, which can be fatal. If conscious, drink one-two glasses of water to
dilute. Keep person warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print:2/24/2001
CHEMICAL HAZARD BULLETIN NO. 972
S/N 26-301-902 Bulk Delivery
PHASETREAT
1618
DEMULSIFIER
Health 3 AMBER LIQUIED WITH AROMATIC ODOR. HIGHLY TOXIC, HIGHLY CAS: None
FLAMMABLE AND SLIGHTLY REACTIVE. UN: 1993
Fire 3 GUIDE: 128
Reactivity 1
VAPOR/MIST/ This product contains 18-21% diesel (no reported TLV), 13-16% isobutanol (TLV=50 ppm).
LIQUID: It contains middle distillates, which may cause cancer based on animal data.
health
EFFECTS OF OVER-EXPOSURE:
INHALATION: Vapor may cause drowsiness and narcosis.
EYE/ SKIN: May cause mild eye irritation. Slight skin irritant. Repeated or prolonged skin contact may
INGESTION:
have a degreasing action where it may cause dryness and cracking.
Gastrointestinal distress. If aspirated into the lungs it may cause pulmonary injury. The hazards
onset of the respiratory symptoms may be delayed for several hours after exposure.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The flash point of this product is from 23-61°C (73-142°F). No explosive limits are given. Firefighters must wear
SCBA and protective clothing. During combustion, toxic vapors and smoke may be formed. Closed containers
may rupture in fire conditions. Keep containers cool with water spray. fire and
REACTIVITY: Avoid contact with strong oxidizing agents.
reactivity
EXTINGUISH FIRES WITH DRY CHEMICAL, CO2, FOAM OR WATER FOG
USAGE: Demulsifier for oil/water mixtures. Use adequate ventilation. No smoking. Avoid breathing
vapor or mist.
STORAGE: Store in a well-ventilated, cool, dry area, away from sources of ignition. Keep tightly closed
when not in use. DO NOT store in direct sunlight. Avoid storage near incompatible materials.
TRANSPORT:
SPILLS / LEAKS:
Mark with hazardous warning labels.
Evacuate all unnecessary personnel. Stop the flow if it can be done safely. Dike to prevent handling,
DISPOSAL:
entry into sewer. Absorb with sand and place in clean, dry, labeled container.
For proper disposal methods and locations for chemical or chemical contaminated material,
contact the Environmental Engineering Division at 874-6426 or 874-6428.
storage &
SAFETY
EQUIPMENT:
Provide ventilation to control exposures. Safety goggles, neoprene gloves, cover-all’s and
rubber safety boots must be worn when handling this material. APR or SCBA should be
disposal
worn if conditions warrant. Maintain an eyewash fountain and emergency shower where the
material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLY
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing has
stopped, give cardio-pulmonary resuscitation (CPR). Keep person warm and quiet.
EYE / SKIN Flush eyes with large amounts of water for at least 15 minutes. Lift eyelids occasionally.
CONTACT: Wash skin thoroughly with water. Remove contaminated clothing and shoes promptly and
INGESTION:
wash clothing before re-use.
DO NOT induce vomiting. Aspiration of material into the lungs due to vomiting can cause
first aid
chemical pneumonitis, which can be fatal. If conscious, drink one-two glasses of water to
dilute. Keep person warm and quiet.
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
First Print:2/24/2001
CHEMICAL HAZARD BULLETIN NO. 975
S/N 26-235-600 30-L Container
26-000-040
SODIUM
HYPOCHLORITE
EFFECTS OF OVER-EXPOSURE:
health
EYE/ SKIN: May cause irritation to the eye, and also burns resulting to vision and corneal damage.
Can cause skin irritation and burns where symptoms include redness, swelling and scab
formation of contacted areas. Prolonged contact can cause damage to the secondary
INHALATION:
tissues of the skin, resulting in the skin inability for regeneration.
Irritating to the nose, mouth, throat and lungs. Burns to the respiratory tract may occur
hazards
resulting in shortness of breath, wheezing, chocking, chest pain, and impairment of lung
function. Repeated exposure or high levels can result in permanent lung damage.
INGESTION: Gastrointestinal distress, nausea, vomiting, diarrhea, abdominal pain, and bleeding.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
The product is not flammable. Closed containers may rupture in fire conditions. Keep containers cool with water
spray. In contact with a fire, chlorine, hypochlorous acid, toxic oxides of carbon and nitrogen will be formed. Fire-
fighters must use self-contained breathing apparatus (SCBA) and protective clothing. Closed containers
exposed to heat may explode. Cool fire-exposed containers with water spray. fire and
REACTIVITY: Avoid high heat, contact with strong reducing agents, acids, organic compounds, and
heavy metals.
reactivity
EXTINGUISHING MEDIA: DRY CHEMICAL, CO2, FOAM, WATER FOG
USAGE: This product is used for the disinfection of water. Avoid breathing mists and eye and skin
contact. NO SMOKING. Provide adequate ventilation.
TRANSPORT/ Store in a well ventilated, cool, dry area. Keep containers labeled, upright and tightly
STORAGE: closed when not in use. DO NOT store in direct sunlight. Avoid storage near heat, open
flames and incompatible materials. Always label containers for transporting in accordance
handling,
with DOT/IMO/IATA hazard warning labels.
SPILLS/ LEAKS: Stop the flow if it can be done safely. Dike to prevent entry into sewer. Absorb with sand
storage &
and place in clean, dry container.
DISPOSAL: For proper disposal methods and locations for the chemical or chemical contaminated
disposal
material, contact the Environmental Engineering Division at 874-6426 or 874-6428.
SAFETY Provide ventilation to control airborne concentrations below the TLVs. Chemical safety
EQUIPMENT: goggles with full-length face shield, neoprene gloves, are recommended when handling
this material. SCBA should be worn if conditions warrant. Maintain an eyewash fountain
and emergency shower where the material is being stored/used.
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
INHALATION: Move affected person to fresh air. If breathing is difficult, administer oxygen. If breathing
has stopped, give cardiopulmonary resuscitation (CPR). Keep person warm and quiet.
EYE / SKIN Flush eyes with large amounts of water for 15 minutes. Lift eyelids occasionally. Wash
CONTACT: skin thoroughly with soap and water. Remove contaminated clothing and shoes promptly,
INGESTION:
and wash clothing before re-use.
Do not induce vomiting. Aspiration of material into the lungs can cause chemical
first aid
pneumonitis, which can be fatal. Drink one-two glasses of water to dilute. Keep person
warm and quiet.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Industrial Hygiene: 872-2623 (DH), 678-4902 (RT), 572-3553 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:10/23/2001
CHEMICAL HAZARD BULLETIN NO. 997
SODIUM DIRECT CHARGE
DODECYLBENZENE
SULPHONATE
(DETERGENT)
Health 1 CAS 25155-30-0
WHITE TO YELLOWISH COLORED POWDER WITH
UN: 9146
Fire 0 SOAP ODOR, SLIGHTLY TOXIC GUIDE: 171
Reactivity 1 SLIGHTLY REACTIVE EAC: None
LIQUID/ MISTS: Not TLV established. However, inhalation of mist or fine particles is irritating to nasal
passage, mucus membranes and upper respiratory tract.
INHALATION:
EFFECTS OF OVER-EXPOSURE:
Inhalation of mist or powder is irritating to the nasal passages, mucus and upper
health
EYE/SKIN:
respiratory tract.
Solid or solution is an irritant to open soars and eyes. Prolonged exposure to skin results
hazards
may result in irritation of skin. Symptoms usually clear after exposure ceases..
INGESTION: Ingestion of material may cause irritation of gastro-intestinal tract followed by nausea,
vomiting and diarrhea.
WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT
Not combustible. However, if engulfed in flames products resulting from incomplete combustion may be released,
which include carbon monoxide, carbon dioxide plus fumes of sulfur oxides. Fire fighting media should be
dedicated to extinguishing flames resulting from the surrounding burning materials. First Responders and fire and
Firefighters must wear a Self Contained Breathing Apparatus (SAP# 1000127491).
REACTIVITY: Avoid contact with strong acids . reactivity
EXTINGUISH AREA FIRES WITH FOAM, CO2, OR DRY CHEMICAL
USES: Soap. Depending on concentration its use ranges from hand soap to machinery
detergent. Avoid skin and eye contact. Do not breathe vapors or mist. No smoking.
Provide adequate/ local ventilation.
STORAGE: Store in a cool dry well ventilated area, away from incompatible materials.
TRANSPORT:
Keep tightly closed when not in use. For transportation, packages do not require DOT-
IMO hazardous warning label (diamond).
handling
SPILLS/LEAKS: Scrape material from surfaces and wash with water and rags. Avoid skin contact or wash storage
off skin immediately.
DISPOSAL:
For proper disposal methods and locations for the chemical or chemical contaminated
material, contact the Environmental Engineering Division at 874-6426.
&
SAFETY Wear protective neoprene gloves (SAP# 1000129635). Splashing is a possibility; wear disposal
EQUIPMENT: goggles (SAP# 1000129817). Where material is stored or used maintain an eyewash
fountain and emergency shower (SAP# 1000128470).
USE CONFINED SPACE ENTRY PROCEDURES IF APPLICABLE
EYE/SKIN Eye contact, hold eyelids open and flush for a minimum of 15 minutes with copious
CONTACT: amounts of water.
Skin contact, wipe excess material with a towel and wash affected areas with soap and
INHALATION:
water.
If overcome with mist or air borne powder, removed to fresh air. If not breathing, give
first aid
CPR.
INGESTION: Do not induce vomiting. If conscious have the victim drink water or milk.
GET MEDICAL AID IMMEDIATELY (CALL 110)
For further information call Environmental Protection: 872-2623 (DH), 678-4902 (RT), 572-4538 (ABQ) or 427-2217 (JID)
Hazard Ratings: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme
Revised:7/14/2003