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C=O
Reaction I Reaction II
(a)(i) [Alkenes] If reaction I is carried out in the chemistry laboratory, not on animal
cells but with organic materials, state the mechanism, reagents and conditions of
reaction I. Industry conditions are not required. [3]
(ii) [Organic chemistry] Suggest the chemical role of NAD in reaction II, which
is carried out in animal cells. [2]
(b) Heavy toxic metals can be removed by a chelating agent, such as EDTA. The
structure of EDTA is shown:
Chelation therapy is the use of chelating agents to detoxify poisonous metal agents
such as mercury and arsenic by converting them to a chemically inert form that can
be excreted without further interaction with the body. Mercury(II) ions, Hg2+, can also
be chelated by EDTA in the laboratory.
(i) [Atomic structure] Suggest the electronic configuration of Hg2+ ion. You
may use [Xe] as an abbreviation and 4f14 orbitals in your answer. [2]
(ii) [Transition metals] Draw the structure of the complex ion when the
mercury(II) ion reacts with ethylenediamine. You may use organic
skeletal formula. [2]
(c)(i) [Ethanoic acid derivatives] Draw the formula of the organic product Z when
ethylenediamine reacts with excess ethanoyl chloride. [2]
(ii) State the reagent and condition for converting the product Z into
ethylenediamine and ethanoic acid. [1]
(ii) Draw the product when ethylamine and chloroethane react in a 1:1 mole
ratio. [2]
[Total : 20 marks]
Paracetamol
(b) [Phenols] Draw the product(s) when Paracetamol reacts with hot aqueous
sodium hydroxide. [2]
(c) State what observation is made when Paracetamol is added to a neutral
solution of iron(III) chloride. [1]
(d) [Arenes] Draw the organic product(s) obtained when dilute nitric acid is added
to Paracetamol at room temperature. Name the mechanism. [3]
(e) [Chemical energetics] The phenyl ring is part of the structure of Paracetamol.
With the use of the Data Booklet, calculate the enthalpy change of
hydrogenation of benzene into cyclohexane. [3]
(f) Explain why the value you obtained in (e) is higher than the accurate value of
-209 kJ mol-1. [2]
(b) [Electrolysis and Group VII] In the electrolysis of concentrated brine solution,
NaCl (aq), small amounts of sodium chlorate(I), NaClO, are produced.
(i) State and explain which products are formed at the cathode and anode.
[4]
(ii) Explain why sodium chlorate is produced, with the inclusion of a relevant
equation. [2]
[Total : 20 marks]
Sulfur burns with a blue flame that emits sulfur dioxide, which has a “burning
rubber” odour.
(a) [Atomic structure] Write down the electronic configuration of sulfur. [1]
(b) Explain why sulfur has a lower first ionisation energy than phosphorus. [3]
(d) A sample of sulfur dioxide is bubbled into acidified hydrogen peroxide solution.
(ii) Calculate the standard cell potential for the reaction. [2]
(iii) State a chemical test for the sulfur product. State also the observations
expected. [2]
(e) Sulfur reacts with oxygen to form sulfur dioxide, an atmospheric pollutant. Draw
an energy level diagram to calculate the bond energy of the S=O bond in sulfur
dioxide.
(f) Draw the Lewis structure of sulfur trioxide, SO3 and state the bond angle
about sulfur atom. [2]
[Total : 20 marks]
(a) The chlorides of magnesium and silicon differ considerably in their physical
and chemical properties.
• Physical property
• Chemical property
(b) Draw the Born-Haber cycle of magnesium oxide. Calculate the sum of the 1st
and 2nd electron affinities given these data:
(d) Write the chemical equation for the thermal decomposition of magnesium
nitrate. Why does magnesium nitrate decompose at a lower temperature than
calcium nitrate? [2]
(e) Magnesium oxide has a high melting point. State one use of magnesium oxide.
[1]
(g) When magnesium is burned in air, it gives the nitride, Mg3N2, in addition to its
oxide. Explain why this is so. [3]
[Total : 20 marks]