I GATE - 2001 t oC'J

It=::='"" CHEMICAL ENGINEERI=:

NG= ======:::J
SECT10N·A
ONE MARKS QUESTIONS (1-25) c. temperature. prossure. 311d liquid
composition "• only
This question consists or TWENTY f i VE sub- d. temperature. pressure, hquid

om
queslions (1 - 25) or ONT:l mark each. For each composIll on x;. and vapour
of tiJese sub-questi.OUS, (OUJ' possible 911SWI'I"$ composition y;.
(A, B, C a nd D) Ｚｾｲ･＠ given, out of which only ·L High pressure steam is e.'lumcled
one is rorrect. A nswe.1· e.1ch sn.b-queslion by adiabatically tllld re1•ersibl) ｾｲ ｯ ｵ ｧｨ＠ a well
darkening the appropriate bubble.- on the insulated turbin<l which produces some
OBJECTIVE RESPO 'SE SAEET (ORS) shnl) 1\0rl< If ｾＱ ･＠ cmthalpy change and

.c
using a sort 1\-ID pl'llcil.. Do not use the ORS fo1· entropy change across the turbine are
:my rough work. You n1:1y like to use lf•e represented by AH and AS. respecto1ely.
Answer Book for any rou_gb wo1·k, if needed. for thos process:

ce
(Marks: I " 25 = 25) a. 6 H = 0 and AS = (I
b. LI.H c: 0 and 68 ; 0
ｔｨｾ＠ l'nlue of U1e follomng deiermmant c. ｾｆｉ＠'"' ll and aS ., 0
tl II () ll
ra I
-2 1 (I () () 5.
d, <l..H = fl and LI.S ｾ＠ fl
For the case or a fuel gas undergoong
3 5 3 () IS combustion woth rur, i.f the air/fuel ratio 1s
increased, the adiabatic Onme temperature
m
-1 ｾ＠ 7 ｾ＠ I
will
-5 ｾ＠ ｾ＠ I a Increase
b decrease
xa

b. 32 c. increase or decrease depending on the

c. ·112 fwl type
d. C) d . nol change
.e

Tbe \ aJue Of{I + i)k, where I = .[-:1, IS G The Po\\er number for a Stirred tan!.
ｾ Ｍ 8 ; ..h becomes conslanl al h1sh Reynolds
number. Ill thiS liJJJJ1, the , ariatioo or
b. 8 -4i power .input wuh impeller rolntJOnaJ speed
w

c, 16 (N) is proportional to
d. 8 aNt
3, A ｲ･｡ｳｯｮ｢ｴｾ＠ gerJeral ･ｾｲｳｩｯｮ＠ for !J. Nl
w

\':tpour-Hquid phase eqwhbrfum at I0\1 to c. Nl

moderate pf\!SStrres IS
d. Nl
w

,P,y,E' = ｲ Ｎ ｸＬｽ ｾ＠
7 The opemtion of n Rota meier is based on
1\1\ere tj); is a vapour fugacit) coeJ:licienL y1 a vanable Oow area
is the liquid octov11y coeftic1enl. and IS r, b rotation of n turbine
the fugacity of pure component i l11e K: c. pressure drop across a no.ule
'alue (y, -= K;xi) ｾ ｾ＠ ､ ｬｴＡｲ･ｦＶｾＮ＠ m general. :t ｾ Ｎ＠ pre.>-sure at a slngnnlion J>.Oint
funct1on of
8. Applyu1g a pressure drop :!(:ross capillary
a ｴ･ｭｰｲ only ｴｾ ｵｲ･＠
ｲｾｳｵｬｴ＠ in a volumetric !low role Q w1der
b temperature and press11re Oil[)' lnmonar now condmons. The no" rate. for
 ｾｯｦＹ＠
the Silme pressure drop. in ｾ＠ olllpiUory of heat t.mTUf.,- ｾｯｦｬｩ｣･ｮ ｴ Ｎ＠ C; • he.,! ｣ｾｰｵｩｴｹ＠
the ｯｭｾ＠ length but half the r3dius is ofvnpQttr- f!i1i1 ｭ ｌｾｉｬ ｲ ｣Ｉ＠
u. Q/2 ｉ ｾ＠
l;i, Q/4
... -><--
k,c. ｾ＠ J
ｾ＠ Q/8
d. Q!J6 b. k,c; ｾ Ｑ＠
h,,
9. l11c bc:U ｾｦｯｲ＠ by rndialiM from a milt!
ｾ ｬ ･ ｬ＠ surface il In be redooed by reducing e,
,..
the cmissMty of the surfuce. ｦｨ ｾ＠ Clln ｢ｾ＠ k,C.

om
hestachlcvcd by
3. pamtlng the surf•ce block d. ｫＺ ｬ ｾ｡＠ = t
b. painting ｴｨ ｾ＠ surf.,,.. while
c,
c. givtns the rur.l'ace a mirror finio1t 14. Tite conversion lor u ｳｾ｣ｯｮ､＠ order.
Irreversible -reoction (constant volume},
d. roughening the $Urface

.c
Ｎ ｉ ｾ＠ fl. in b•lch mode i• given ｢ ｾ ﾷ＠
10. l lcat transfer bv mslura1 con...·cction t.s
enbaqcod in ｳｾＭｴＮ［Ｌ ｮ＠ with a.
I
;&+ high viscosity J- k,C..,r

ce
b. high cooffic.iont ortltenna1 expansion 1>. k.,C,.t
e... low l\o."Dtpc:rntorc gradients 1 k,C<Ill
d. Low d"lllity ｣Ｎ｢ｮｧｾ＠ with ｬ､ｰ＼ｭｾｴｵｲ･＠
ra (k,C«d
11. ' l11e •urJl.cc Nnewal ftetjucucy in
Danek\\ orl5' modd of moss tout! fer io 1-k,C.,l
given bY (kL; mass tr:msfer coefficient. d. k.,C ,.r •
mM
m
( l+ kJC...,t)'
Ｇｾ＠ ｾ ｲ｣ Ｚｯｾ＠ 15 The reaction rate con$i:tnls at two differeni
b. ktD, ｬ･ｭｰｯｲ｡ｴｵｾｳ＠ T, nnd 1 1 ｾ Ｇ Ｂ＠ relutl!d by
xa

c. k' I D
' .<
a. ｬｮ Ｈ ｾ Ｉｾ ｅ ＨＧ ＮＡ ｟ ＮＡ Ｉ＠
k1 R T, lj
d. kr I D_!
12 For £tiS absorption the ll"ight of a !mnsf.:r b. ｾｴ Ｈ ＵＮ ＩＺ＠ £(..!. . _.. !. . )
.e

uniL ba•ed on !h1> gas ph•••· i.• given b} I.; R T, T,

(G: !lllperlidal molar gas vdoc.lty: 1.:
supedicial ｭｯＱｾｲ＠ liquid velocity: F0 : mau c. '"P(k,k, J=R\_
!!._(..!..._.. !._)
Tj T
w

transfer- ｣ｯ･ｦｩ ｩ ｣Ｍｮｾ＠ ｭｯｬ Ｑ

ｾＺ＠ J: interfacial 1

exp(t,):1( Ｉ ｾ＠
area per unit volu.mo of tower)
a d. ;,)
w

Fr.ll
16. The E·eul'\'1! for • non·itlcn1 l'l:>6UJr de lines
b. F;. Ute frai!'tion Of fluid havittJ! d.Sc btl\\ ecm I
w

Cia and I - dt
Gn • · at Ute inlet
c.
b. al tltc: ouUet
/. c. .in tl1e rcJctoi'
I
I.
d. owmgeil over Uteiululuud ouUet
P,,G
17. The calibt"Jliou dal-. uf a tbetmooouple
1:1. llld Lcwi• ICbliOI1 rur ••1-1<41<>1
\\ itb its .-oJd juncUUU nt 0°(: MO gi\•en
l•umjd[ijc.,lion •• given by lkv; nt;lsi
bet ow
ｬｲｾ ｭ Ａｬｩｦ･ｲ＠ cneJl1cien·l or Jtt01$tui'C in it ir. ho-:
 J uf9
d
l11e hOI junction or Ihe thennorounle 15 21. l11c ends ｾ ｾ ﾷ＠ a cvhndnllal vessel can be
placed m n bnU1 :n 80"C wbile its cold
closed by a hCIId,: ''hich can he line nf Ihe
junclion is m20'C. What is Ihe emf of lhe
fC)ur Ｕｨｴ ｬｦ ＠ｾ For Jhc ＧＢｾ＠ ｬｩ｣Ｎｵｾ＠
1ht:m1orouple? ｣ｨｯｾ･＠ tllC: one which cnn wnhstand the
a. 3.2(> mV ｨｩｧ･ＵＱｊＩｲｳｾ＠
b 0,80 mV a tla1 plate
c. 2.'16 mV b hermsphencal

om
cl 143 mV C. IOrisr h,'l'IClll
IX. A process 1s mJball)• a1 stead} state wnh d ellipsoidal
1ts: outpul y - I for an mpol u - I l'he
1npu1 Is sudden!)' changed lo 2 n1 lime r ｾ＠
:u. An mwslment of Rs, I00 lakhs is lo be
made for constructron ofa plant whrcb '" "
0 Th" outpul response IS Hll I -t :lr mke two vears to slurt produltmn. "[he

.c
The lmn.-.Fer flmcuon o f the ｰ ｲ ｯ｣ｳＮｾ＠ is
an nun! profit lr01n operation of Uu: 1llml IS
Rs. 20 l11khs. Whm wdl 1J., !he payback
umc?
.,

ce
a. s ycor:;
b It:
,••
b 7 year:;
c. 11 ycllt¥
c. ｉＫｾ＠
ra ,\ d J0 }C31S
One of ｬ ｨ ｾ＠ s11:11> t1uri11!l refiillnlJ of cnne

" ＱＮＨｾ -· l
Ｉ＠ ""Jlll'｣｡ Ｑ ＱＮｾｩｌ＠ of ndditlon of hydrated li1ne
to 1he sugar sy mp folll)"ed b)' ｣ｾｊ｢ｯｍ ｴ＠ ion
m
I !I I he mherenl clinractcfiSIICS or lUI C<jU!II of the resulting 50111\ion. ne purpose of'
pcrceptugc valve rclu.lllll! Ouw rnte q wHh dtls step ｩＮｾ＠ to
vnl''" stem movement ｾ＠ 11re dcscnl.led by 3. AdjUSLLhe pH oflbe syrup.
the equa!ion
xa

b. Remove thu coloruig nlliilCJ lh>nl lhC

II.
•Ill ＠ｾ k Syntp,
Ｂ ｾ ｶ＠ c. ｾ､ｵ｣＼Ｚ＠ｒ Ihe VI:>CI.lSily of the sylllp

.
b. <lq = kq d lmprO\oe the mre !lf cry5tail!muon or
.e

ｴ ｬｾ Ｍ suysu.
1.' -=-
,., ｾ＠ u. Stw.,ltl! Is protlureJ from ｬＡｴｨｹ｢ｯｭＺｩｾ＠ by
ｾ｟ｴＬ＠ (/ ｬｨｾ＠ prD<:ess of
w

<1<1 I . ) u. DchydrogcnnlJOII
d. -=MJ b Oxidnuon
<J.•
2(J A jJ<Irl\lraled plate. bas hnles ofdiiUtlc"'r d_., ,. Alkylnllon
w

urrnnged 1n n phGh, Pt• E.'!Ch hole h.'IS a d O.:hydrniiOil

tube of i,d . d,, pusslns 1hmu1,1h it ｔｨｾ＠ 25. 111 1hc ntud cmnlvnc ｣ｭｾ ｲ＠ (FCC). lhc
ligament ･ｦｴｬ｣ｾｮｪ＠ i; wven by cracl. ing ｲ･｡｣ ｴｩ ｯｾ＠
w

1s ·-<nl- and the

p. - d, regeneration ｩｾ＠ -(bl-
n
a (a I Exothermic (h) Endothem1ic.
, , - d,d,. 2
"· b, Ia) ExoJhemnc Cbl E.xo1herm1c
b c. (o\ Findoth(mlic Ch) Fndolhermk
II,
d (al EndolbemliG fb) ExoU1ennio,
p,
,,- ·1,
 I u(9
d. (1'.S/ ol' )_ = (al> I &T)r
ｔｨ quesllou rrousl>t• or n vENTY .FIVE sub·
ｬ ｾ＠ ｾＨｬ Ｎ＠ AI 11109(' \\oter Ｇｾｉ＠ ｭ ･ ｴｨ ｹ ｬ ｾｹ｣｜ｯｨ･ ｍ ･＠
questions (l6 - 50) or TWO marks each. For hnth hnve "npour ｰｲｯＺｳｾ＠ ()r
I,1) Olrn.
tlldl ｬ｢ｾ or
｣＠ sub-<tuc." ions, four po.sible Aho at 1(\0"C. tlte latent bcru.:. of
BnSW('rs (A, B, C and I>) ｡ ｲｾ＠ l:lvcn. out or .,.hlrh " apouril.ltlion of tlte;e compounc.ls ore
uuly ｯｮｾ＠ Is corr ect. tt!.Wer 1-.t<'h ｾ ｉｈｴｵ＼ｓｩｑｮ＠ 40.63- kJ mol tor wat.:r and 3J 55 IJ mol
II) llurkcniug the ｐｉｊＧｯｰｲｩｵｴｾ＠ ｢ｵｬｾ＠ "'' tho lor ｭ｣ｴｨｹｬｵ ｖ ｣ｬｵｨＮｸＺｭｾ Ｎ＠ rhc vnpour
OB.IECTI\'1! ｒｅｾｐｏ ｎｾｅ＠ SHEl):T (ORS) pressure of IY;lc't nl 150"C is 4.69 Glrn. At
ｵ ｾｩｵｧ＠ u ｾｵ ｦｴ＠ HB JWnl'll, On nnt use ｴｨ ｾ＠ ORS fur 1so•c. the "''Ite"" f't""""''
of

om
Ｂ ｾ Ｇ＠ rou gh worl<. Vou 111:1)' like to U$C the molhy lcyclohex:m" W<Juld he expe()tcd tQ
Answer Book ror any ｲｯ ｵ ｾｨ＠ •1iork, ifu eodl'<l. be:
Ｈｾ｢ｯｲｫｳＺ＠ l >< ZS - 50) a, s ignifit:mtl} ｬ ･ｾ＠ th3J14.69 alln
h. ｮＮＺｾｲｬｹ＠ equal to 4,69 :>tm
25. ·ntc luocdm• rp·,t•) =.r·+ ｯｲＭｳｹＮｊﾷｾ＠ c. ｾ ｩｧｮｦｴｬＩＧ＠ monnlr•n 4.69 ntm

.c
ｨｬｴ ｩｪ ｬｨｾ＠ d. inde1e1mi:nnu:: due to ｾｩ＠ lnck of ､ｮＱｾ＠
n. 1\lnximom at (I. I) 31. A Uingh•nt Ouid of 1-iscosity ｾ Ｍ 10 l>a ｾＮ＠
b S:oild l<: pninl nt ( I. J ｾ＠ and yield stress "to • 10 Jd'>a. ｾ＠ sbe<Lred

ce
c. Mll1jmum nt (1. 1) ｨ･ｴｷｾ＠ tlot ｰ｡ｲｾｬ･ ｬ＠ plates separnled by a
dislilnc.! 1o·• m. l'ht lop ｰ ｬ ｡ ｴ ｾ＠ i> moving
d. N"nnc of tho abo\la ol {1. 1).
with a ' 'clodty of j illls. Tho ｳ ｬｴ ｾ｡ｲ＠ s tress
27. A Fair die i'l roUCIJ Jour tim.,. Find the on t.h c p late is
ra pmbabllity those si"' 5hom; up iwicc.
a. 10 kP<t
1
•• 2
b. 20 kP,,
C. 30Jd>;L
16
m
b. d. -10 kP:o
325
n. Air enl.;:rs an. Ｚｾ､ｩＮｬ｢｡ｴ＠ compressor at 300
I K. The .:lOt h:mpernlute for 11 compression
c.
36
xa

milo of 3, aliSUmlng nir to be :to ideol gas

25 (y = C,, 1C, = 7/S) and the prQCes• 11} be
d. reveno ible. is
216
28. A bulru!l! isnuu:ril.lltion pL'OCC'!IS ptoduccOc a, 5(1()( 3"")
ＳＨＩＡ ＮＱＯｾ Ｉ＠
.e

70 ｫｭｯｾｨ＠ of pun:: ｩｯｪ｢ｵｴＺｭｾ Ｎ＠ A purga b

11
ｳ ｴｲ･Ｚｾｭ Ｌ＠ removed continuoosly. ｣ｯｮｾＱｩｦ＠ c. 30tl{:lj )
ss•.
n-but:mc and 15". impurity (mole "o). d. ＳＨ｜Ｐｾ ＬＮ ＠Ｌ
Thc:Jecd Slrtnm i.s ｮＭ｢ｵｴｾ｣＠ oontainiug 11)6
w

impurity lmole "·•) ' l'ho flow rnte of tho

33. The energy .l'C:q_u.i:rml por unit mAss to grind
pnrge s tream will be; ILm,.tone· p>ttides o( very lnr,!!l' ｳｾ＠ to
)I)() um i• 12.7 ｾｗｨ Ｏ ｊ＾ ｴ ｮ＠ ••\n estim•ie
n. ｾ＠ ｫｭｯ ｬ ｾ ｨ＠
ＨｵｳＱｧｂｯ､ Ｇｾ＠ wm) o!d1e energy to griud
w

b. 4 kmol/h the p>tticles .from a Vet') large si2o to Su

c. 5 kmoLh fUU j$
w

d. 6 kmollb a. 6.35 k\Vlt/ton

29. Th<= M>.-.wcll relation deri\'cd .froro tlt<' b. 9.0 1:''1%/ton
､ｩｬＡ･ｲｴｾ＠ ｯＺＮｾｰｲＢＧｳｩｮ＠ for the Rclmhol12. c. 1!1 ｫｗｉｾ Ｇ ｴｯｮ＠
freeener!!Y(d..-\) 1>1· d. 25.4 kWbiton
n.. (i'T i o/')1 - (iJP as), 34, '11te S tcder-'rnte o:orrelntion ror !ten!
ｬｲｯｮｳｾ＠ in turbulent llow 10 ｾ＠ ｐｬ ･＠ giW>
b. (i"S nP). - (N' i'T),
N11 <t> Rc•·•. wltett Nil Ill !he Kusor:ll
ｾ Ｍ Ｈ ｇｖ ｉ ＼ＧｓＩ ＬＭ Ｈｲ ｾｲ Ｏ ｎ ＾ Ｉ Ｚ＠ number andRei.> tl1e l{.:ynold.< number for
the tJuw. 1\ssuroing tbnl lhls rclotion ;;.
 3 ur9
volid. tho hoat lr.lnsfo:r coefficient , .ru;es 39. In P single sl!lge extl'3ction process. 10 kg
with pipe ,Hameter (I) ) as of pure. solvent S (containing no s<l lutc A)
n. JY"" is mixed with 30 kg of t¢cd F ounrainin(l A
h, ｄＮＬｾ＠ Rl ll ｕｉｓｾ＠ ｦｲ｡ ｾ ｴ ｩｯｮ＠ ·Yf : 0.2, Tioe mixture
split$ into an ｴｾｲＮｯ｣ ｴ＠ ph••c H anrl •
ｾ＠ ｄｾ＠
rn flinote phi'-'" R. containing A a( Xp- = 0.5
tL DL8 ar1d )(JI. = 0.05. ｲ｣Ｚｳｰ･ｾｴｩｶ､ｹ ｟＠ The !Qt.' I mruo<
3 5. !bu ovcr:ill ｨ｣ｾｴ＠ I.J'Jiru,[or L'Ocmcienl1or u oflbe extract pltnlrcls (in kg)
• hell and lube heol 1!1<l:hanger for ele•n ｾＭ 6.89
ｳ ｵｲｬＧ｡ ｣･ｾ＠ i!; L'o c: 400 W!m'K. rho fouling

om
b. 6.89
ll•<tm' nflor f/00 year or upcrnliun ;•. li)\lnd ｾ Ｍ 1(1
ID be hdo ｾ＠ '2000 Wlm1K. 1ltc OYCl'OII heat
trans fercoeffi.oient at this lime is tL 8.25
11. l200 Wlm'K -Ill, •11:1t; me-an cvn,·ersi.o n lfl [he:- {;i<i"t slremn,
for a sccond-<)rdcr, liquid plra:<a rc<tction tn
b. 894 Wim1 K
u non-ideal Dol' re:t<>IOJ' ｾＡｬｩｶ･ｮ＠ by

.c
"- 333 Wim2K
tl. 287 \V!ltl K •· r A,C,,t E( l) til
• l+ k,t.,,l
36, Tite heot lltL't (from outside 10 inside)

ce
across nn JJ.. ubting wall wi01 thermal
conduotn'1ty k ｾ＠ 0.04 \Vhn 1( nnd
r b. I
" 11 k1c,./
1!( ｾ＠
thickness 0.16 m ｾ＠ IｏｗＢＧｾ＠ lne
I<:TJ\III:Tlltw:e nf the imide w• ll ｩｾ＠ -s•c The
ra
nuts ida \lOll tempotlllUt'c ;,
c.. fo 1+ /;I(' t ｾ ｯｲ＠
tHI(r )r)dl
n, 25"C r• ecxp( - k.,C...,r) ( )
b. 31)"C d.J, Ettlt
u 1- k,C.,,r
m
e. Js•t -II. f't•r J '"lM ｰｬｾ＾ ｾ･＠ e•tblylit rctoction (. \ ｾ＠ B
d. 40"C > F) '' hloh fo llow' the Ride;tl ｭ ｌＧｃ ｨｾｮ＠ ism
"!-7, rbe Jn(Cftacial ;lre:t per llni l YOhnne of •nd the n:llction step ｩ ｾ＠ r:otc: conlrolling. ｬｨｾ＠
xa

dispersion. in n gas-liquid cont3ctor, for rnlc nf reacli()n ill given by Ｈｲ･ ｡ｾｴｩｯｮ＠ s tep Is
froclinnill hold-up of gas 0.1 ;tno ga. to ＼ｎＺｦｬｩ ｾｊｩ ｯＮ＠ prqduc1 abo a<horm l
bubble diameter - 0.5 mm is given hy (in kpAf.r
m 1 1mJ) n. -r,
I+ K ,p,+K1,p,
.e

n. 500
b. ] 2J)0 b. - r, - kp! - Pr
.:..900 1+ K. p, + K1 p,
w

d" soo c. -r - kp p
38. 200 kg of solid (on dry bosis) is ｾ ｵ ｢ｪ｣ ｬｾ､＠ ' I+ K.tJI,+ K11p.-+ K, p
to a drying process for a period of 5000s.
w

f he dryins occurs in the const:ml role d. r - kp.e•

period wltlt Ute <frying rate as Nr = Ｐ Ｎ ｾ＠ ' • 1 I K. p,
I0 kg/mzs. Tho initial moistul'e C:OJ!lont of -12. The t:ina-o rder. reactoon ga• phase
w

tl1" solid is ll.2 kg moistullllkg dry •olid. ａｾ＠ 28 is ccmductc!CI i.•Qthermallv i11
rhe inll....-faoi•l area •vai lable for drying jy
balch nwde. Tho ｲ｡ｊｾ＠ oJ' chnnge IJI'
-l rn: / LOU 1.-g of dry solid. J'he rntusture
c.Orwcr.sibu with lime _is givcu. h.>'
coutcul ｾ＠ the ,;ud of the dry-mg peo iod i..
(i11 kg moisture/kg tlty solid ) u. IL"i, ］ ｫＬＨｬ Ｍ ｘ Ｎｾ ＯＧＨ Ｑ ＭＺ＾｜Ｂ＠ J
rh
·- o.s
b. 0.05
c. 0. 1
11. ll.J 5
 Ｖｯｦｾ＠

ｾ Ｎ＠
dX
a/ =/;j (t-,r.,) b. LOOO(l+ O.I0) 10

d, d.t' = .l;{l - X, )I(I+XJ

dt
c. 1000( 1-.-
0
/J
43. Alt ideal PID
tlmctioo
ｾｯｵｴｭ ｕ ･ｲ＠

[ 1+ li(0.5s)+0.2s]
has -the ｴｲ｡ｮｾ･＠

The
II- IOOQ(J+ ｑｾｉ ｊ＠
.frequenc_'Y .a l wfuclt ｾｴ･＠ Magnitll(le RaLi<' or •17. P is the iuvestmeptmade on rut eqoipmen:t:,
U1e conU:oller is J,js S is ils sillvage value 311d ii is the life qf

om
0.5 tlto equipment m.years The depreciation
ｾＭ for !he m'h year ·by the Surn-of-Years-
().2
Digill! mediod will be
b. ().2
rr-s
Q.5
11
o. 0.2 .I 0,5
1-(;J

.c
I

cL b-
../0.2 . 0.5

ce
111. The block di!lgfllln of11r1 integrating level c. E!..( P-S)
process is given below. !'or unit step 1)
clcmge in U1e set poi.nl ｉｖｾＮＬ ］＠ l ,v; ill
d, 2 ("-m+l\P-S)
l!.d = O, the offi;et exlubited by the ｾｹｳｴ･ｭ＠
ra f.I(IHl)
is
48. In a cy.lindrical yeysel spbjected lo inlemal
pressure, the longitudinal stress PL- 81ld,the
circmnferential stress, <rt., ｡ｲ･ ﾷ ｲ･ ｬ ｡ｾ･､＠ by
m
a. Vj, = 2-vt.

a. _..!it_
J+K;
xa

J
b.
I+ K, d. Nil relation exists
c, 0 49. In tl1e converter of t11e conmct process for
.e

2K., tltemanufacturc uf EL,..SQ_., tlte equilibrium

cL conversion ＼Ｚ＾ｦｓｏ ｾ ＭＨ｡Ｉ ﾷ＠ witlt increase in
1+ 2K,
tlte temperature and ···(b)- with lnorcase
15 A second ｯｲ､･ｾ＠ system can. be obtained. by in the mole ratio ofS02. to air.
w

ooMeoti.ng two first order systems

a. (a) increases (b) decreases.
lf(t ts + I) and lJ('t1S + 1) b1. series. 'llte
drunping ratio of tltc rcsultrutt seCO!ld order b. (a) decreases (b) irlcroases.
w

system for ll1e case i'i "' t 2 will be c. (.'1) increases (b) ｭ｣ｾ｡ｳ･ Ｎ＠

a. > I d. (a) decreases (b) deet"ases.

For ｾｴ･＠ hydrogenation of oils, --(a)-·· is-
w

b. = I 50
c. < 1 commonly IJSed as ｣｡ｬｹｳｾ＠ ad.d ·-(b)--is
a catalystpoisoiL
cL = , ,,,,
ｾ Ｎ＠ (a) Plat.lnUnl (b) Sill firr.
46. An Investment of lts. I000 is C.1J1Ying an
b. (a) Plllladinm (b) ｏｸｹｧ･ｲｾ＠
utlerest of I0% compounded quarterly,
'T'he value of Ott! investment at the end of c. (a) Nickel (b) SnlfiiT.
liveyeurs,viO be d. (a) Nickcl (b) Oxygen.

11 ＱＰｾＩ Ｈ ＱＫ＠ ｾ［ｉ ｦ＠

 1 0 1 'I

SECTION· B 54 100 m1 of carbon dioXIde lrunally at 413 K

and 50 bar (50 10' Pal is to be
FIVE MAIIK1I QUEST10NS (!51·70) fs6ihcr'mnlly compressoo in a fncluJOlcs:>
l'h iS ｾ･｣ｴｩｯｮ＠ con>ists of 'I WENT Y quesiioos or piston nnd cylinder ､･Ｌｾ｣＠ to n final
f iVE marks each. A.'I\' FLFTEEI\ Out of these preSsure of 300 bar (300 ＱＰ Ｑ ｊ＾ｵ ｾ＠
q ｵ ｲｳｬｩｯ ｵ ｾ＠ ha"e lu be aDSIH'red on lhr Answer Assunung ideal gas behaviour (R 8.3 14
Book provided. 102 l>ur tn' II.Jnol KJ,
(Marks: 5 x 15 = 75) a. \\<me ｾ＠ general uxpn:ssmn lor the
energy balnnce lOr ｕｵ ｾ＠ ｾｴｮｳ＠ wttlun the
ptston 11t1d cylinder de'licc 115 the

om
51 The parnmetric equotion nf o curve is
S)Stem. nnd define nllthe terms
- l-
r(l ) = rl r - f 1\ hdro lis the pll!lllllclof. b. Cah::ulole ｴ ｨｾ＠ ｾｯ ｬ ｵＱＺ＠ of lhc
I
eompi'I!SScd carbon dtoxid.:. IJ<1S at 30U
11, What type uf co111c (parnbolu, cucle, l>ar.
･ｬｩ ｬ Ｚｴｓ ｾ Ｎ＠ llnd II)' IJ<'rbolul does the oorve c. Calculate the work done to compress
represent?

.c
the carbon dto<tde gus.
b Find the unit lllnJ,,.mt to the ｣ｵ ｴ Ｇ｜Ｑｾ＠ nt 1 d Calculate the ｨ･｡ｾ＠ now on
I ｣ｯｭｰｲｾｳ ｩ ｯｮ＠

ce
c. Pmd the unll normal to the curve ot r • Normnl p<:nume is tsomenzed w
I
tsopentan<: and neop.:mnoe at SOO K and
52. l..aplsce o:nnsforms. atmospltenc pressure Determme tbe
a. Show that the I aplace ｴＱ ｮｾｦ＼ｬｲｭ＠
ra of e"1 equilibnum composirlon (mole % ) of the
is lhrec ｣ｯｭｰ ｮ ･ｮｾ＠ St.tte an,v ussumpttons
made. Constder the re<lctwns to be:
.t[.-].. _1_ Ｌ Ｑ
S- Ill a. 11-( Ｑ ｊＯ ＰＱ Ｈ ｾ Ｉ＠
ＱＰ ＨｾＺＩＮ＼ Ｑ Ｍｦ＠
m
b Show from !gJ lhol b. II- ( 5 H" (X) (:::) Ｑｾ ＱＭＨ＠ ｾ Ｑ Ｑ Ｑ＠ (.\l)
.t{alnh{Oilt)j a , Ill , 8quilibnum ｾＧＨｭ ｭｮｴ＠ for rcaclion (:t l Ut
• - OJ
SOOK. K1 = ｜ｾ Ｑ Ｙ＠
xa

ｾ Ｎ＠ Sh<lW Oum lb! thot

Equilibnufll c<msnmt for nmtl•on l b) ut
Ｎｴｦ ｩｮＨ｣ＮｾＩｪ＠ • "'· ,
, . +41 500 K, K1 = 0.682.
The mlet ｾ ＼ｬ ｬ ＨＩ＼Ａｲﾥ＠ of wuter (n 1000
l'be proc<!Ss sc.hemauc of 11 propone
kgltn') in a til!ltl onjjled bend· rcdt•<Cr" v,
.e

dt'hydrogcnatton plnnl is shown bclol\ lt

Is deslrc:J ld set up u sitnphlitd ｾ｣ｲ ｳ ｬｯｮ＠ of • I mls, '"' sbowo bel01\ The mlcl
the ma lctiitl balance for tins plant Assume diameler ｾ＠ Dt - t) 8 m and lhe oullel
that the ooly rencuon il> the: d.tameler Is Dl = OA m The 11011 Ts
w

duhydrog.,nauou of propane to propy lene. turbulem and the veii'Cny prolilcs 01 the
there ure no std.: f'C<lctions. The ytcld of mlc1 und outlet ""' flat 1plug now )
ｇｲ｡ｾｴｮｯｭ ｬ＠ ｦｵｾ＠ are ｮ ･ｧｬｾ ｢ｬ ･＠
prupy lenc per pu.s IS 3U0 'o (I ｾ Ｌ＠ 3Q•,. of the
w

pmpane entcnng (he r;:actor L' c.onvcrted

to propylene), Assume dlllt the amount or
c:,lrbon fom1ed on rhc catni)'Stts ncglitliblc
w

Th<l product now mt" (strcnn• S ; ) is 50

lrtnol h. Caltulnte the Oow rates of all the
oth.er streams N01icc thut all stre:uns

a. Fend the pressure drop ll't - 1'2) noross

tbe bend assumm¥ ncglli!Jblc ｃｲｬ･ｾ ｴ ｯｮ＠
oｾ ... ﾷ＠ ｬｯｾＢｓ Ｎ＠
T

b If tho actual prcssw'e drop is (P, - P>)
= 3.25 kPa, find the friction loss factor
(K,) bnsed on the veloc1ty v 1
57 l'he wlumctrie now rate duru1g constant
pressure filirat1on 1S
til" I 1; -
eft K,l. I lq,
where V ｾ ｾ＠ the total volumc or filtl'!ltll
collected m ume. r. <md K, and '!<• are
conSlants
a. Integrate. the above equatton to obtain
a relat ion between V and l
b. M@ke ｾ＠ sketch of t/V versus V rrom
your results.
.c
c GIVen V ｾ＠ 1.0 litre all ｾ＠ 41J sand V -
2,0 liternt.t - IOSJ s, und .K..
58. A :!00 W heater has a spbencaJ casiJ1g of
ce
diameter 0,: m, ille beat IJ:ansfer
coel'ficoenl fur conduct 1011 and COII\'IlClJon
from the castng lo the nmb1cnt a.r 1s
obtamecl from N•I = :::.+O6 Re11 Pr1 1 with
ra
tl e ｾ＠ 1D' anu Pr = o 6<J, 'The temperature
of the ambieot ;111' is Jo•c and the the1mal
｣ｮ ｮ､ ｵｾｴｮｯｹ＠ of air IS k = 0.02 Wlm K.
m
a. Find the heat Jlux from tho sutface at
steady state
b. Find the steady state sttllace
ｴｾ ｭ ｰ･ｲ｡ｬ＠ of the casmg.
xa
c. Find the temperature of the casutg at
Steady State ro1• SWgualll tlJIC \Vby IS
this sitwtllon ｰｨｹｾｴ｣ｵｬ＠ utfCliSihle?
59 A 1-2 shell. and tube lte;n exchanger has
.e
Jlqutd (specific heat Cv) llowmg at a mass
flow nne. til 10 the tubes and saturated
steam \temperature T.l condeusmg oa lhe
ｾｨ ･ｬ＠
w
Sld O.
ot Gall)' out a ､ ｴＱ･ｲ ｮｾｬ＠ energy ｢ｮ
on u smgle tuf?e to sho"'' lllllt
w
r m ur -
N , J=
Jr!JI ' ('r -1')
• scquc!lllally (iu sertcs) Find U1e vnluas of
where T 1S tbe ternpemrure ol' lh<t
w
llquid, N is lbe nuUlber of tubes 1U a
pass, z IS ｬ｢ｾ＠ ､ｩｯｴ｡ｮｾ･＠ ulong U1o tube, D
ts the mner dmn<eter oft he tubes and U
is tho overall heat b·anst'cr ｡ｯ ｣ｬｩｴｾｮ＠
based no the ms1de surface area
b O.btmn an ex.press1011 for the
temperature of the Iiqutd at 1he cx1t of
the heat exch:mgsr, T 1 The length ,,r
the. tube« is L qnd ｬ ｩｱｾｴ､＠ entero the ｨ･ｾｴ＠
exchanger at tempernture T11
8 uf'l
GO For ll counter-current, multistage contact,
show that it' the drrving force for ｳ ｯｬｴｾ＠
transfer IS constant lnr all trays, then the
number of stases 1s grvcn by
N, )•.Ｌｾ＠ - I;
IILY 0
Y1 .._ j X,
om
ｲｾＮﾷ ﾷ＠ • "' ＾ｴｾＮ＠
(I l A sugary subslance A 1s added lo a pol of
milk (inlually c.;unammg no AJ and stirred
vtgorously by a spO<.m so that the
concentratton of A, C A, IS unifom1
everywhere. The mass transfer cocflic,cnt
for the. trnn$fer of A mto the liqt;Ud is k,J ｾ＠
I • lcr" m/s, Soltd t\ is 11dded 1n great
eltCess compared ro the. saturation•capacity
of milk to dissolve A. Assume ｾｭ ｴ＠ tho
soluj-ltq111d mterf.1cml area SIJIYS constant
throughout the dissol1ttion process nnd Ｑｾ＠
given ｾｹ＠ s : tOOO em· Den ve the
expressiQn fo1· CA versus time, t Pind the
time laken for('' 1 /C ·: ｾ Ｐ Ｎ ＹＵ＠
I·,; : 5•1 o- kmtllm"; V1 = 1000 cm1
2
1>2. The. concentration versus botch tome data
ror a COrlSUWI VOIWlle. ISOthermal batch
reactor lS given 111 the Table below.
1\ssumlllg the reacuon to be tirst order m
A find the best value of l<t by least
squan.<s regression
, (&) 0 30 tJU 90 120 ＱＡｾ＠ 1$0
LC,(1<mol/mf i i.OO 10.9110,&9 10;11 10;16 10,12 0:70
63. A CSTR and a PfR of equal volume V
ｬ ｾｮ ｣･＠ !each) are ｾｩ ･ｮ＠ ｶ for ｾＱ ･＠ condl1ct or a
second-order, ISOthermal, ltquid phase
reac.t10n 1l1e reactors are 10 be arranged
the converswnr for 1he rwo possthle
reacror arrnngemenl.$
A ....!L.. B,k, = tm' /k.rnol s. r 1,. = 0. 1
kmolitn1s and t = 5 s \lor volun1e V)
f>4 ftnd the ･ｾｰｲｳ Ｑ Ｐｾ＠ f'or the effec11 veness
factor of a cataly st pellet· 111 the form of a
thin slab such tl\at the area oftW\) opposite
faces ｩｾ＠ much larger than the area of the
other four faces Material A can diffuse
l'rorn both the ｬ ｡ｲｧｾ＠ faces. Assume a first
order r<!<Jttion and isolbol1'11lll, trtevcrs1ble
 ll<lndiliOnt. 111C (1\0 lal'gO ｦｾｃｓ＠ are
"' - L {E:
separnle..l h)' a ､Ｑｾｕ｣･＠
<lill\JSI\-il\ llf A in the ｾｬｯｨ＠
21\, lht e1l'cc1ivc
i1 0,, an<J the a vJJ:
role l)(>uslonl ;. donolcd h\' ｾ Ｑ ＠ C'otculate the diameter ｯｦｴｬｾ･＠ conbctor.
65. The hnl juncJiun nf • ｨｾｮｵｬ ｸＺｯ ｵｲｬ｣Ｚ＠ hi\ ing 08. A plant designer bas to cbou.c bd\\..CO
1;mc ｣ｮｾｵｬ＠ r mm Ｇｾ＠ｉ miti:a1l\ at room equipment l Md equipment L Equipment
lcmllefOIUI-.: nf ｾｏ Ｇ ｃ Ｎ＠ •\I 11mt 1 .:_ (I min.. it 1 L< made of special maten•l •ncl rcqui""'
il pLl•ed 1R • h3th held 31 IOO'C ｔｨｾ＠ no mamten•nce. I he cost or the equ ipment
1hcrmocouplc: i• cunn<eted 10 • n:corder ｾ＠ Rt. 3.00.000 Eqwpmc:nt 2 rs of • lo\\ a
1\luch ha1 fMt ､ｾｮ｡ｭｩ｣ｳ＠ ,-\tt - '2 ｭｩｮＮＬｬｨｾ＠ cost DlJitcri•l lllld costs Jb. 1.50.000. for

om
hot junohon i. Ｑ｜ｩｴｨ､ｲｊｾ＾ｮ＠ liurn the ｨｾｴｬ＠ matnlel\.ln<:e of equipment 2. •
ond held in the: •ir \\ hi.:h ｾ＠ •I ;lO (" From maintenance Cffil nf Rl< I O,t]()() h3< lo he
11M: n:cmded d••• Ihe uluc of d I ell •• 1 ｾ＠ p•KI >1 l,hc end of ach '""'· 1,11c of
2 mtn. 1> Ｘｾｃｏ＠ IO \OU ell dt - - equipment 2 i$ four >=• "hile that of
2.5°C min. AI I 2· m10. Js llu> 11<111 equipment l"' S Y""r> Interest r•te is 15°o
•uffident lo c:.akulolo tho llmc contllnt of ""'mpounded annllllll\ <"•lculat<: the

.c
the thcmlOCO\lplc? lr so. SliSjil'll a ｰｮＺｯｾ＼ｬｩｈ＾ｦｨ＠ of ｩｮｬｴｾｵＺ＠ to 1><: uoallc for
pto«dure fol eolc:ubhon or ltmc II•• cocb equipment and cho<,.e the upti<on
c.onstnnt 't. ｾｨｩ ｣ｨ＠ h;,• 1he lo\\er presen1 \\Orth

ce
66. ll1c trunsli::r function of o "Y'I<:tn Fqu.ipmc:nt I has 3 •3hage •·alue 1)1 R1
30.000 ｜ｬｨｾ･＠ equipment '2 hM n<) ｳ｡ ｬ ｶｯｳｾ＠
coNmting of • th.:nnal ｶＺｾｬ･＠ P"''"''"·
ond
\'Q ｬｵ ｾ Ｎ＠
mcasurmg 'ysk:m ｩｾｴ＠ gl\"tn by
69 ｬ ｲ ｾＧｩｮＡ＠appmpriillc nrucwral fonnulac.
ra t.T(.r) 5
1>Titc lhc Cljllllti011! rt:pn:.,mtlng the
V(o) ＨｓｳＮ ｬ Ｉｬｏ Ｎ ｓｾ＠ r ii(O. I• 1) follo11 ing o·eaelio"" uo the
lniliolly " pmpm1ionnl c<IIHI'HIIcr \lith sloidtiometriC<ltlv babnced fonn.
pro1wo1innn I Ｂｴｮｾｩ ｵｶｩｬ ｹ＠ f., i• ｵｾ ･､＠ l'hc a. Oehydrogen..'lion nf ISopropanol 10
m
.:oolroll•1· Q(IUMlon I• a.:.:(C)IId.
6/(• ｜Ｍ ｋ ＬＮ Ｈ ａｔ Ｎ ｾＤ Ｑ＠ .ar( •·J) where r.., I• b. II) dtofonnylalion of propylom. lo
the Set poinl l'ind the Volue o f h., - !{.,,.,..
boiTI'llldohyde.
c. Nil111tlon ofloluene tu ｯＭｮｬｴｭ･ｾ Ｎ＠
xa

>h<>vc wludo U1e cloocd loop "ill be

urulllblc:. Cnn you us' 1l1c ｲｯｾｵｬｳ＠ oJ tl1c d. lhidalion u[ " urncne lo c umcnc
K, to tunc byclroparoxidc us in!\ oxygen.
dO<cocl loo1lrt1ponsc 31 f...,...,.
3 PID conLmller 10 ＠ ｾ ｨ u\cd in ptuco of the e. lsomonsallon of n·hntane to ISO\>I<Ione
proportiollJII conlrollc• 'IIJ oo. ＠ Ｚ Ｎ ｨ ･ ｴ ｾ ｬ ｵ ｫ ｮ ｣ 70. t\Mwer each of the Jollowmg questions ln
.e

one ｟［Ｌ｣ｮｊ･ｾＮ＠
tuning pnrnmctctli of tho ccnltotlcr
•· \\lhol function doc. the mcc'10bnnc
6 7. i\ pad-ed sa. llquod contactor employ,
p<:rfonn in the membnlne cell lor the
ccl'3mlc ｉｊｯｾ＠ uddlt:s (38 mm). TI1c ga1
ntanufacture of 1\aoH?
w

ｬｵｾ＼＠ raie. G U ｾｓ＠ • and l!" d•11sitv. 1111

b. \\'Jut is the J!<DcDe clu:cnieal nJtnc rur
- l .S kwn1 '. TI1c t.quMI llo" rate. L 30
the class of ｰｯｬｾｮｵＺ＠ whicl> ano
k!! • and liquid dcnsol) l't. IOOU ksm 1
＼ｏｭＮＺｲ､ｾｬ＠
w

i;nol' n •• nylon•?
fhc column i• to be dc:sogned for a fur
c. "Name the COmmonly U.'«:c.l ｰｲｯｾ＠
(lr>::S.<UI't dmp ul ｾＲ＠ m1n II:(), No1to11't ll1e mdJiufactUfC of •)nth,.,;. g.. liu111
com:lotion for lloi.s pr<J.<Un: drop;.
the n•lllnl gu .
w

•• d \\ h31 cllan!!¢ in the d""il!ll of the

ｐＳＱｇｾ＠ ｾ ｉ＠ 6)ntllcsis ｧ［ｾ＼＠ comf"'e8S<>n. ba!
K- fl.
=olulio>nW:d Inc ｾｭｯｮｩ＠
, (p, p )
ｭｬｵｦｾｲ･＠ during the recent )CArl'/
wheN " no\\ .:oc;llidc:nl ,.... tiquod e Slate the m;tior 3d\ :mt•gc: of the f...n ll
\ iscosity 11)'1 :-.s m2, 0,. @AJ iJOW rotC pro<.'es.> Ill cr liter Olhcr pf(I<...,SC> (or the:
l"'r nn11 CI'Q'" •ceuor1.3l 3rc3 kg (mJ• ｾ＠ Fp = m•nuf•olurc or r'pcl' pulp?
packing foetor • 170m f... is given by ＱｾＺ＠
1

cquotion: K 0.62 • O.S(m • O.Sj for O.S _

m _ 1.0 1\ hcac