1.

Critical properties
komponen BM Tb (K) Tc (K) Pc (bar)
(CH3)2CHOH 60.0964 355.41 508.31 47.64
H2O 18.0154 373.15 647.13 220.55
(CH3)2CO 58.0804 329.44 508.2 47.02
H2 2.016 2.04E+01 3.32E+01 13.13

2. Kapasitas Panas Gas

Cp = A + B*T + C*T^2 + D*T^3 + E*T^4 Tabel 2-1 Heat Capacity of Gas-Org
Cp = heat capacity of ideal gas (joule/(mol K ) Tabel 2-2 Heat Capacity of Gas-inor
T = temperature (kelvin) YAWS 1999

komponen A B C D
(CH3)2CHOH 25.535 2.12E-01 5.35E-05 -1.47E-07
H2O 33.933 -8.42E-03 2.99E-05 -1.78E-08
(CH3)2CO 35.918 9.39E-02 1.87E-04 -2.16E-07
H2 2.54E+01 2.02E-02 -3.85E-05 3.19E-08
ZnO 2.45E+01 3.50E-02 -3.98E-05 2.04E-08

3. Heat capacity of liquid

Cp = A + B*T + C*T^2 + D*T^3 Tabel 3-1 Heat Capacity of Liquid-O

Cp = heat capacity of ideal gas (joule/(mol K ) Tabel 3-2 Heat Capacity of Liquid-I
T = temperature (kelvin) YAWS 1999

komponen A B C D
(CH3)2CHOH 72.525 7.96E-01 -2.63E-03 3.65E-06
H2O 92.053 -4.00E-02 -2.11E-04 5.35E-07
(CH3)2CO 46.878 6.27E-01 2.08E-03 2.96E-06
H2 5.06E+01 -6.11E+00 3.09E-01 -4.15E-03
ZnO - - - -

4. Heat Capacity of Solid

Cp = A + B*T + C*T^2 Tabel 4-1 Heat Capacity of Solid-Or

Cp = heat capacity of ideal gas (joule/(mol K ) Tabel 4-2 Heat Capacity of Solid-In
T = temperature (kelvin) YAWS 1999

komponen A B C Tmin
(CH3)2CHOH -4.203 7.10E-01 -1.06E-03 80
 H2O 9.695 7.50E-02 -1.56E-05 150
(CH3)2CO -3.893 9.35E-01 -2.19E-03 30
H2 5.71E+00 2.18E-03 -3.84E-05 12
ZnO 1.12E+01 1.19E-01 -1.00E-04 1.50E+02

4. Enthalpy of vaporization
ΔH vap = A (1-T/Tc)^n
ΔH vap = Enthalpy of vaporization
T = temperature (K)

komponen A Tc n
(CH3)2CHOH 58.982 608.31 0.326
H2O 52.053 647.13 0.321
(CH3)2CO 49.244 506.2 0.481
H2 0.59 33.18 0.38

5. Tekanan Uap Murni

log P = A + B/T +C log T + D T +E T^2 Tabel 7-1 Vapor Pressure-Organic Compounds
P = mmHg Tabel 7-2 Vapor Pressure-Inorganic Compounds
T =K YAWS 1999

komponen A B C D
(CH3)2CHOH 38.2363 -3.55E+03 -1.00E+01 -3.47E-10
H2O 29.8605 -3.15E+03 -7.30E+00 2.42E-09
(CH3)2CO 28.5884 -2.47E+03 -7.35E+00 2.80E-10
H2 3.41E+00 -4.13E+01 1.09E+00 -6.69E-10
ZnO 10.0724 -1.58E+04 -3.01E-02 6.57E-06

6. Critical Properties
temperature kelvin Tabel 1-1 Critical Properties-Organic Compounds
tekanan bar Tabel 1-2 Critical Properties-Organic Compounds
YAWS 1999

komponen Tf (K) Tb (K) Tc (K) Pc (bar)

(CH3)2CHOH 185.28 355.41 508.31 47.64
H2O 273.15 373.15 647.13 220.55
(CH3)2CO 178.45 329.44 508.2 47.02
H2 13.95 20.39 33.18 13.13
ZnO 2248.2 - - -

7. Viscosity Of Gas
Tabel 21-1 Viscosity Of Gas-Organic Compounds
 n gas=A+BT+CT^2 Tabel 21-2 Viscosity Of Gas-Inorganic Compounds
n gas=micropoise, T=K YAWS 1999

komponen A B C Tmin
(CH3)2CHOH -10.859 3.09E-01 -4.81E-05 200
H2O -36.826 4.29E-01 -1.62E-05 280
(CH3)2CO -4.055 2.67E-01 -5.69E-06 300
H2 27.758 2.12E-01 -3.28E-05 150
ZnO - - - -

8. Enthalpy of vaporization
Tabel 5-1 Enthalpy of vaporization
Hvap=A*(1-T/Tc)^n Tabel 5-2 Enthalpy of vaporization
Hvap=kjoule/mole, T=K YAWS 1999

komponen A Tc n Tmin
(CH3)2CHOH 58.982 508.31 0.326 350
H2O 0.659 33.18 0.38 13.95
(CH3)2CO 49.244 508.2 0.481 260
H2 52.053 647.13 0.321 273.16
ZnO 539.74 8000 0.38 2223

9. Density of liquid
Tabel 8-1 Density of liquid
density=A*B^-(1-T/Tc)^n Tabel 8-2 Density of liquid
density=g/ml, T=K YAWS 1999

komponen A B n Tc
(CH3)2CHOH 0.26785 0.26475 0.243 508.31
H2O 0.3471 0.274 0.28571 647.13
(CH3)2CO 0.27728 0.2576 0.29903 508.2
H2 0.03125 0.3473 0.2756 33.18
ZnO - - - -

10. Viscosity of liquid

Tabel 22-1 Viscosity of liquid
log10 n liq=A+B/T+CT+CT^2 Tabel 22-1 Viscosity of liquid
n liq=centipoise, T=K YAWS 1999

komponen A B C D
(CH3)2CHOH -0.7009 8.42E+02 -8.61E-03 8.30E-06
H2O -10.2158 1.79E+03 1.77E-02 -1.26E-05
(CH3)2CO -7.2126 9.03E+02 1.84E-02 -2.04E-05
 H2 -7.0154 4.08E+01 2.37E-01 -4.08E-03
ZnO - - - -

11. Thermal conductivity of gas

Tabel 23-1 Thermal conductivity of gas
Kgas=A+BT+CT^2 Tabel 23-2 Thermal conductivity of gas
Kgas=W/(m K) YAWS 1999
T=K

komponen A B C Tmin
(CH3)2CHOH 0.07775 -3.60E-04 5.76E-07 355
H2O 0.00053 4.71E-05 4.96E-08 275
(CH3)2CO -0.00084 8.75E-06 1.07E-07 273
H2 0.03951 4.59E-04 -6.49E-08 150
ZnO

12. Thermal conductivity of liquid

Tabel 24-1 Thermal conductivity of liquid
log10 K liq=A+B(1-T/C)^2/7 Tabel 24-2 Thermal conductivity of liquid
K liq= W/(m K) YAWS 1999
T=K

komponen A B C Tmin
(CH3)2CHOH -1.3721 6.58E-01 5.08E+02 185
H2O -0.2758 4.61E-03 -5.54E-06 273
(CH3)2CO -1.3857 7.64E-01 5.08E+02 178
H2 -0.1433 2.36E-02 -5.15E-04 14
ZnO 71.455 -1.85E-01 1.63E-04 319

13.
 Pc (atm) Tb (C) omega P (Mpa) melting point
47.01702 82.3 0.669
217.666 100 0.345
46.405 56.29 0.306 178.55
12.958 -2.53E+02 -0.22

2-1 Heat Capacity of Gas-Organic Compounds

2-2 Heat Capacity of Gas-inorganic Compounds

E Tmin Tmax halaman

4.94E-11 100 1500 35
3.69E-12 100 1500 52
6.32E-11 100 1500 35
-8.76E-12 250 1500 52
-3.78E-12 298 2000 55

3-1 Heat Capacity of Liquid-Organic Compounds

3-2 Heat Capacity of Liquid-Inorganic Compounds

Tmin Tmax Cp at 25 C halaman

186 457 172.39 62
273 615 75.55 79
179 457 127.53 62
14 32 - 79
- - - 82

4-1 Heat Capacity of Solid-Organic Compounds (CH3)2CHOH dan (CH3)2CO

4-2 Heat Capacity of Solid-Inorganic Compounds H2O, H2 dan ZnO

Tmax Cp at 25 C Cp Tmin Cp Tmax Halaman

177 - 45.782 88.025 88
 273 - 20.588 29.006 105
178 - 22.195 93.325 88
14 - 5.728 5.73 105
473 37.725 26.762 45.018 108

re-Organic Compounds
re-Inorganic Compounds

E Tmin Tmax halaman

1.74E-06 185.28 508.31 164
1.81E-06 273.16 647.13 181
2.74E-06 178.45 508.2 164
1.46E-04 13.95 33.18 181
-5.49E-10 1773.1 2223.1 184

erties-Organic Compounds
erties-Organic Compounds

lnP= C1+C2/T+C3*lnT+C4*T^C5, P in Pa
OMEGA halaman komponen C1
0.669 9 (CH3)2CHOH 96.094
0.345 26 H2O 73.649
0.306 9 (CH3)2CO 69.006
-0.22 26 H2 1.27E+01
- 29

f Gas-Organic Compounds
f Gas-Inorganic Compounds

Tmax halaman
1000 457
1073 474
650 457
1500 474
- 477

vaporization
vaporization

Tmax halaman
508.31 114
33.18 131
508.2 114
647.13 131
8000 134

Tmin T max halaman

185.28 508.31 191
273.16 647.13 208
178.45 508.2 191
13.95 33.18 208
- -

Tmin Tmax halaman

187 508 484
273 643 501
223 508 484
 14 33 501
- - 504

nductivity of gas
nductivity of gas

Tmax halaman
450 510
1073 527
572 510
1500 527
530

nductivity of liquid
nductivity of liquid

Tmax halaman
483 536
633 553 k= A+BT+CT^2
483 536
33 553 k= A+BT+CT^2
418 556 k= A+BT+CT^2
YAWS 1999
nT+C4*T^C5, P in Pa (pery edisi 8)
C2 C3 C4 C5
-8.58E+03 -1.03E+01 1.67E-17 6.00E+00
-7.26E+03 -7.30E+00 4.17E-06 2.00E+00
-5.60E+03 -7.10E+00 6.22E-06 2.00E+00
-9.49E+01 1.11E+00 3.29E-04 2.00E+00
 NERACA MASSA BASIS

Kapasitas perancangan per tahun : 25.000 ton/tahun

Waktu operasi dalam satu tahun : 330 hari
Kapasitas perancangan per jam
ton 1000 kg 1 tahun 1 hari
Kapasitas = 25000.000 x x x
tahun 1 ton 330 hari 24 jam
= 3156.5657 kg/jam

komposisi produk Aseton :

(CH3)2CO= 99.50% berat
impuritas = 0.50% berat
100.00% berat

Komposisi bahan baku :

Bahan Baku Isopropil alkohol :
(CH3)2CHOH = 99.00% berat
H2 O = 1.00% berat
100.00% berat

BASIS NERACA MASSA MIX STATION TEE

1 2

INPUT (kg/jam)
KOMPONEN ARUS 1
kg/jam kmol/jam
(CH3)2CHOH 5949.5436 99
H2O 18.0154 1
(CH3)2CO 0 0
H2 0 0
TOTAL 5967.559
 NERACA MASSA REAKTOR REAKTOR FIXED BED

konversi
4 5 umpan masuk

(CH3)2CHOH (CH3)2CO + H2

mula2 99 - -
reaksi 89.1 89.1 89.1
sisa 9.9 89.1 89.1

INPUT OUTPUT
KOMPONEN ARUS 4 ARUS 5
kg/jam kmol/jam kg/jam
(CH3)2CHOH 5949.5436 99 594.95436
H2O 18.0154 1 18.0154
(CH3)2CO 0 0 5174.96364
H2 0 0 179.6256
TOTAL 5967.559 100 5967.559

FLASH DRUM

5 6
7

INPUT
KOMPONEN ARUS 5 ARUS 6
kg/jam kmol/jam kg/jam
(CH3)2CHOH 594.95436 9.9 57.6855185291
H2O 18.0154 1 0.9630918075
(CH3)2CO 5174.96364 89.1 1831.5906427626
H2 179.6256 89.1 179.6256
sub total 5967.559 189.1 2069.8648530992
TOTAL 5967.559
BM gas= 31.5576890534 kg/kmol

lnP= C1+C2/T+C3*lnT+C4*T^C5, P in Pa (Perry)

P = mmHg
 T =K

komponen C1 C2 C3
(CH3)2CHOH 96.094 -8575.4 -10.292
H2O 73.649 -7258.2 -7.3037
(CH3)2CO 69.006 -5599.6 -7.0985
H2 12.69 -94.896 1.1125

P= 1 atm 101325
T= 25 C 298.15

komponen zi F (kmol) Po (Pa)

(CH3)2CHOH 0.0523532522 9.9 6027.0215105738
H2O 0.0052882073 1 3170.3857749628
(CH3)2CO 0.4711792702 89.1 30751.845279044
H2 0.4711792702 89.1 6.806389195E+20
total 189.1

V 121.68585
L 67.41415
V/L 1.8050490884
L/V 0.554001554

nilai spericity didapatkan dari trial xi=1 dengan mengubah spericity

ABSORBER 10

umpan masuk absorber adalah hasil atas FD

komponen BM kmol/jam kg/jam

(CH3)2CHOH 60.0964 0.9598830966 57.6855185291
H2O 18.0154 0.053459363 0.9630918075
(CH3)2CO 58.0804 31.5354343765 1831.5906427626
H2 2.016 89.1 179.6256
total 121.6487768361 2069.8648530992
ABSORBEN BERUPA AIR
Kebutuhan Air
H2 diharapkan 0.1% ada diproduk bawah
Asumsi H2 0.1796256 kg/jam
Kebutuhan Air 112266 kg/jam

kelarutan (CH3)2CHOH dalam air = 0.999

kelarutan (CH3)2CO dalam air= 0.999
kelarutan H2 dalam air= 0.0000016

asumsi produk (arus 9)

99,9% aseton terserap
komponen BM kmol/jam kg/jam
(CH3)2CHOH 60.0964 0.9589232135 57.6278330106
H2O 18.0154 6231.7219207904 112266.96309181
(CH3)2CO 58.0804 31.5038989422 1829.7590521198
H2 2.016 0.0891 0.1796256
total 6264.2738429461 114154.52960254

produk atas (arus 10)

komponen BM kmol/jam kg/jam
(CH3)2CHOH 60.0964 0.0009598831 0.0576855185
H2O 18.0154 0 0
(CH3)2CO 58.0804 0.0315354344 1.8315906428
H2 2.016 89.0109 179.4459744
total 89.0433953175 181.3352505613

Tabel campuran arus 7 dan arus 10 yang akan masuk ke MD-01

Arus 7 Arus 9
komponen kg/jam komponen
(CH3)2CHOH 537.268841471 (CH3)2CHOH
H2O 17.0523081925 H2O
(CH3)2CO 3343.37299724 (CH3)2CO
H2 1.48142288E-14 H2
total 3897.6941469 total

MENARA DISTILASI-1

12

11
 13

Dinginkan produk atas dengan komposisi

(CH3)2CO 0.9999
(CH3)2CHOH 0.0001
H2O 0
H2 1
Diinginkn produk bawah dengan komposisi
(CH3)2CHOH 0.9999
H2O 1
(CH3)2CO 0.0001
H2 0

input
komponen BM arus 11
kmol/jam kg/jam
(CH3)2CHOH 60.0964 9.8990401169 594.8966744815
H2O 18.0154 6232.6684614275 112284.0154
(CH3)2CO 58.0804 89.0684645656 5173.1320493572
H2 2.016 0.0891 0.1796256
subtotal 9.8990401169 118052.22374944
total 118052.223749439

MENARA DISTILASI-02

14

13

15

Dinginkan produk atas dengan komposisi

(CH3)2CO 0.9999
(CH3)2CHOH 0.9999
H2O 0.0001
H2 0
Diinginkn produk bawah dengan komposisi
(CH3)2CHOH 0.0001
 H2O 0.9999
(CH3)2CO 0.0001
H2 0

input
komponen BM arus 13
kmol/jam kg/jam
(CH3)2CHOH 60.0964 9.8980502129 594.837184814
H2O 18.0154 6232.6684614275 112284.0154
(CH3)2CO 58.0804 0.0089068465 0.5173132049
H2 2.016 0 0
subtotal 6242.5754184868 112879.36989802
total 112879.369898019

NERACA MASSA OVERALL

input
komponen BM arus 1 arus 8
kg/jam kg/jam
(CH3)2CHOH 60.0964 5949.5436 0
H2O 18.0154 18.0154 112266
(CH3)2CO 58.0804 0 0
H2 2.016 0 0
subtotal 5967.559 112266
total 118233.559
 BM kg/kmol
(CH3)2CO 58.0804
(CH3)2CHOH 60.0964
H2O 18.0154
H2 2.016

BASIS 100

BASIS 100

) OUTPUT
ARUS 2 KOMPONEN BM
kmol/jam kg/jam kmol/jam
99 5949.5436 99 (CH3)2CHOH 60.0964
1 18.0154 1 H2O 18.0154
0 0 0 (CH3)2CO 58.0804
0 0 0 H2 2.016
5967.559 TOTAL
OR FIXED BED

90%
5949.5436 kg/jam

OUTPUT
ARUS 5
kmol/jam BM
9.9 60.0964
1 18.0154
89.1 58.0804
89.1 2.016
189.1

OUTPUT
ARUS 6 ARUS 7 BM
kmol/jam kg/jam kmol/jam
0.9598830966 537.2688414709 8.9401169034 60.0964
0.053459363 17.0523081925 0.946540637 18.0154
31.5354343765 3343.3729972374 57.5645656235 58.0804
89.1 1.481422882E-14 7.3483278E-15 2.016
121.6487768361 3897.6941469008 67.4512231639
5967.559 kg/jam

log 10 P= A+B/T+C*log10*T+DT+E*T^2 (Yaws)

C4 C5 halaman
1.6665E-17 6 297
4.1653E-06 2 342
6.2237E-06 2 5
0.00032915 2 183

Pa
K

ψ
Ki xi yi f(0) f(1) spericity
0.0594820776 0.1326148428 0.0078882064 0.049239172 0.827798457 0.1247266364
0.0312892749 0.0140406819 0.0004393228 0.0051227431 0.163722015 0.0136013592
0.303497116 0.8538944068 0.2591544898 0.3281777206 1.081320722 0.594739917
6.717383858E+15 1.090027507E-16 0.7322133181 -3.165092E+15 -0.4711792702 -0.7322133181
1.0005499315 0.9996953371 -3.165092E+15 1.6016619237 0.0008545944

fraksi mol fraksi berat

0.0078906103 0.0278692198
0.0004394566 0.0004652921
0.2592334687 0.8848841701
0.7324364644 0.086781318
1 1
miscible
miscible
digunakan data kelarutan H2 saja karena aseton dan isopropil alkohol miscible (larut sempurna air)

miscible suhu 298,15 K

miscible
kg/kg air suhu 293 K

masuk keluar
komponen arus 6 arus 8 arus 9 arus 10
(CH3)2CHOH 57.6855185291 0 57.6278330106 0.0576855185
H2O 0.9630918075 112266 112266.963092 0
(CH3)2CO 1831.59064276 0 1829.75905212 1.8315906428
H2 179.6256 0 0.1796256 179.4459744
subtotal 2069.8648531 112266 114154.529603 181.335250561
TOTAL 114335.864853099 114335.864853099

Arus 11
kg/jam campuran arus 7 dan arus 10 komponen kg/jam
57.6278330106 (CH3)2CHOH 594.896674481
112266.96309181 H2O 112284.0154
1829.7590521198 (CH3)2CO 5173.13204936
0.1796256 H2 0.1796256
114154.52960254 total 118052.223749
 output
arus 12 atas arus 13 bawah
kmol/jam kg/jam kmol/jam kg/jam
0.000989904 0.0594896674 9.8980502129 594.837184814
0 0 6232.66846143 112284.0154
89.0595577192 5172.6147361523 0.0089068465 0.5173132049
0.0891 0.1796256 0 0
89.1496476232 5172.8538514198 6242.57541849 112879.369898
118052.223749439 kg/jam
 output
arus 14 arus 15
kmol/jam kg/jam kmol/jam kg/jam
9.8970604079 594.7777010955 0.000989805 0.0594837185
0.6232668461 11.22840154 6232.04519458 112272.7869985
0.0089059558 0.5172614736 8.9068465E-07 5.17313205E-05
0 0 0 0
10.5292332098 606.5233641092 6232.04618528 112272.8465339
112879.369898019 kg/jam

output
arus 10 arus 12 arus 14 arus 15
kg/jam kg/jam kg/jam kg/jam
0.0576855185 0.0594896674 594.777701096 0.0594837185
0 0 11.22840154 112272.7869985
1.8315906428 5172.6147361523 0.5172614736 5.17313205E-05
179.4459744 0.1796256 0 0
181.3352505613 5172.8538514198 606.523364109 112272.8465339
118233.559 kg/jam
0
 BM
C 12.011
H 1.008
O 15.9994

kmol/jam

kmol/jam

INPUT OUTPUT
ARUS 1 ARUS 2
kg/jam fraksi berat kg/jam fraksi berat
5949.5436 0.99698111 5949.5436 0.9969811
18.0154 0.00301889 18.0154 0.0030189
0 0 0 0
0 0 0 0
5967.559 1 5967.559 1
 0.6435
xi.L yi.V
8.9401169034 0.9598831
0.946540637 0.05345936
57.5645656235 31.5354344
7.3483278E-15 89.1
67.4512231639 121.648777
(kirk othmer) pubchem.ncbi.nlm.nih.gov
(engineeringtoolbox.com) G.W.C. Kaye and T.H. Laby, "Tables of Physical and Chemical Constants," 15th ed., Lo

kg/jam
mical Constants," 15th ed., Longman, NY, 1986, p.219.
 NERACA MASSA AKTUAL

Kapasitas perancangan per tahun : 25.000 ton/tahun

Waktu operasi dalam satu tahun : 330 hari
Kapasitas perancangan per jam
ton 1000 kg 1 tahun 1 hari
Kapasitas = 25000.000 x x x
tahun 1 ton 330 hari 24 jam
= 3156.5657 kg/jam

komposisi produk Aseton :

(CH3)2CO= 99.50% berat
impuritas = 0.50% berat
100.00% berat

Komposisi bahan baku :

Bahan Baku Isopropil alkohol :
(CH3)2CHOH = 99.00% berat
H2 O = 1.00% berat
100.00% berat

BASIS NERACA MASSA MIX STATION TEE

1 2

INPUT (kg/jam)
KOMPONEN ARUS 1
kg/jam kmol/jam
(CH3)2CHOH 3627.0141425648 60.3532681253
H2O 10.9827097635 0.609628971
(CH3)2CO 0 0
H2 0 0
TOTAL 3637.9968523283
 NERACA MASSA REAKTOR REAKTOR FIXED BED

konversi
4 5 umpan masuk

(CH3)2CHOH (CH3)2CO + H2

mula2 60.3532681253 - -
reaksi 54.3179413128 54.3179413128 54.317941313
sisa 6.0353268125 54.3179413128 54.317941313

INPUT OUTPUT
KOMPONEN ARUS 4 ARUS 5
kg/jam kmol/jam kg/jam
(CH3)2CHOH 3627.0141425648 60.353268125 362.7014142565
H2O 10.9827097635 0.609628971 10.9827097635
(CH3)2CO 0 0 3154.8077586218
H2 0 0 109.5049696865
TOTAL 3637.9968523283 60.962897096 3637.9968523283

FLASH DRUM

5 6
7

INPUT OUT
KOMPONEN ARUS 5 ARUS 6
kg/jam kmol/jam kg/jam
(CH3)2CHOH 362.7014142565 6.0353268125 35.1667633004
H2O 10.9827097635 0.609628971 0.5871286675
(CH3)2CO 3154.8077586218 54.317941313 1116.590718772
H2 109.5049696865 54.317941313 109.5049696865
sub total 3637.9968523283 115.28083841 1261.8495804264
TOTAL 3637.9968523283 3637.996
BM gas= 31.5576890534 kg/kmol

lnP= C1+C2/T+C3*lnT+C4*T^C5, P in Pa (Perry)

P = mmHg
 T =K

komponen C1 C2 C3
(CH3)2CHOH 96.094 -8575.4 -10.292
H2O 73.649 -7258.2 -7.3037
(CH3)2CO 69.006 -5599.6 -7.0985
H2 12.69 -94.896 1.1125

P= 1 atm 101325
T= 25 C 298.15

komponen zi F (kmol) Po (Pa)

(CH3)2CHOH 0.0523532522 6.0353268125 6027.0215105738
H2O 0.0052882073 0.609628971 3170.3857749628
(CH3)2CO 0.4711792702 54.317941313 30751.845279044
H2 0.4711792702 54.317941313 6.806389195E+20
total 115.28083841

V 74.1832195162
L 41.0976188928
V/L 1.8050490884
L/V 0.554001554

nilai spericity didapatkan dari trial xi=1 dengan mengubah spericity

ABSORBER 10

umpan masuk absorber adalah hasil atas FD

komponen BM kmol/jam kg/jam

(CH3)2CHOH 60.0964 0.5851725445 35.1667633004
H2O 18.0154 0.0325903764 0.5871286675
(CH3)2CO 58.0804 19.224914408 1116.590718772
H2 2.016 54.317941313 109.5049696865
total 74.160618641 1261.8495804264
ABSORBEN BERUPA AIR
Kebutuhan Air
H2 diharapkan 0.1% ada diproduk bawah
Asumsi H2 0.1095049697 kg/jam
Kebutuhan Air 68440.606054081 kg/jam

kelarutan (CH3)2CHOH dalam air = 0.999

kelarutan (CH3)2CO dalam air= 0.999
kelarutan H2 dalam air= 0.0000016

asumsi produk (arus 9)

99,9% aseton terserap
komponen BM kmol/jam kg/jam
(CH3)2CHOH 60.0964 0.5845873719 35.1315965371
H2O 18.0154 3799.0382219 68441.193182748
(CH3)2CO 58.0804 19.205689493 1115.4741280532
H2 2.016 0 0
total 3818.8284988 69591.798907338

produk atas (arus 10)

komponen BM kmol/jam kg/jam
(CH3)2CHOH 60.0964 0.0005851725 0.0351667633
H2O 18.0154 0 0
(CH3)2CO 58.0804 0.0192249144 1.1165907188
H2 2.016 54.317941313 109.5049696865
total 54.3377514 110.6567271686

Tabel campuran arus 7 dan arus 10 yang akan masuk ke MD-01

Arus 7 Arus 9
komponen kg/jam komponen
(CH3)2CHOH 327.5346509561 (CH3)2CHOH
H2O 10.3955810959 H2O
(CH3)2CO 2038.2170398498 (CH3)2CO
H2 9.03118307E-15 H2
total 2376.1472719019 total

MENARA DISTILASI-1

12

11
 13

Dinginkan produk atas dengan komposisi

(CH3)2CO 0.9999
(CH3)2CHOH 0.0001
H2O 0
H2 1
Diinginkn produk bawah dengan komposisi
(CH3)2CHOH 0.9999
H2O 1
(CH3)2CO 0.0001
H2 0

input
komponen BM arus 11
kmol/jam kg/jam
(CH3)2CHOH 60.0964 6.03474164 362.6662474932
H2O 18.0154 3799.6152605 68451.588763844
(CH3)2CO 58.0804 54.298716398 3153.691167903
H2 2.016 4.479754E-15 9.03118307E-15
subtotal 6.03474164 71967.94617924
total 71967.9461792402

MENARA DISTILASI-02

14

13

15

Dinginkan produk atas dengan komposisi

(CH3)2CO 0.9999
(CH3)2CHOH 0.9999
H2O 0.0001
H2 0
Diinginkn produk bawah dengan komposisi
(CH3)2CHOH 0.0001
 H2O 0.9999
(CH3)2CO 0.0001
H2 0

input
komponen BM arus 13
kmol/jam kg/jam
(CH3)2CHOH 60.0964 6.0341381658 362.6299808684
H2O 18.0154 3799.6152605 68451.588763844
(CH3)2CO 58.0804 0.0054298716 0.3153691168
H2 2.016 0 0
subtotal 3805.6548285 68814.534113829
total 68814.5341138292

NERACA MASSA OVERALL

input
komponen BM arus 1 arus 8
kg/jam kg/jam
(CH3)2CHOH 60.0964 3627.0141426 0
H2O 18.0154 10.982709763 68440.606054081
(CH3)2CO 58.0804 0 0
H2 2.016 0 0
subtotal 3637.9968523 68440.606054081
total 72078.6029064088

HASIL ASETON DARI MD-01

24975.0235580547
25000.000 ton/tahun
-24.976
 umpan basis 100.0000 kmol/jam
produk basis 89.14965 kmol/jam
produk aktual 54.34821 kmol/jam
hun 1 hari
x
hari 24 jam

BM kg/kmol
(CH3)2CO 58.0804
(CH3)2CHOH 60.0964
H2O 18.0154
H2 2.016

UMPAN 60.9628970963 kmol/jam

UMPAN 60.9628971

OUTPUT
ARUS 2 KOMPONEN BM
kmol/jam kg/jam kmol/jam
60.3532681253 3627.01414256 60.3532681 (CH3)2CHOH 60.0964
0.609628971 10.9827097635 0.60962897 H2O 18.0154
0 0 0 (CH3)2CO 58.0804
0 0 0 H2 2.016
3637.9968523283 TOTAL
OR FIXED BED

90%
3627.014143 kg/jam

OUTPUT
ARUS 5 BM
kmol/jam
6.035326813 60.0964
0.609628971 18.0154
54.31794131 58.0804
54.31794131 2.016
115.2808384

OUTPUT
ARUS 6 ARUS 7 BM
kmol/jam kg/jam kmol/jam
0.585172544 327.534650956 5.45015427 60.0964
0.032590376 10.3955810959 0.57703859 18.0154
19.22491441 2038.21703985 35.0930269 58.0804
54.31794131 9.0311831E-15 4.47975E-15 2.016
74.16061864 2376.1472719 41.1202198
3637.9968523283 kg/jam

log 10 P= A+B/T+C*log10*T+DT+E*T^2 (Yaws)

C4 C5 halaman
1.6665E-17 6 297
4.1653E-06 2 342
6.2237E-06 2 5
0.00032915 2 183

Pa
K

ψ
Ki xi yi f(0) f(1) spericity
0.059482078 0.1326148428 0.00788821 0.049239172 0.827798457 0.124726636
0.031289275 0.0140406819 0.00043932 0.0051227431 0.163722015 0.013601359
0.303497116 0.8538944068 0.25915449 0.3281777206 1.081320722 0.594739917
6.71738E+15 1.0900275E-16 0.73221332 -3.165092024E+15 -0.4711792702 -0.73221332
1.0005499315 0.99969534 -3.165092024E+15 1.6016619237 0.000854594

fraksi mol fraksi berat

0.00789061 0.0278692198
0.000439457 0.0004652921
0.259233469 0.8848841701
0.732436464 0.086781318
1 1
miscible suhu 298,15 K
miscible
digunakan data kelarutan H2 saja karena aseton dan isopropil alkohol miscible (larut sempurna a
suhu 293 K

masuk keluar
komponen arus 6 arus 8 arus 9 arus 10
(CH3)2CHOH 35.1667633 0 35.1315965371 0.035166763
H2O 0.58712867 68440.606054081 68441.19318275 0
(CH3)2CO 1116.59072 0 1115.474128053 1.116590719
H2 109.50497 0 0 109.5049697
subtotal 1261.84958 68440.606054081 69591.79890734 110.6567272
TOTAL 69702.4556345069 69702.4556345069

Arus 11
kg/jam campuran arus 7 dan arus 10 komponen kg/jam
35.13159654 (CH3)2CHOH 362.6662474932
68441.19318 H2O 68451.58876384
1115.474128 (CH3)2CO 3153.691167903
0 H2 9.03118307E-15
69591.79891 total 71967.94617924
 output
arus 12 atas arus 13 bawah
kmol/jam kg/jam kmol/jam kg/jam
0.000603474 0.0362666247 6.03413817 362.6299808684
0 0 3799.61526 68451.588763844
54.29328653 3153.37579879 0.00542987 0.3153691168
4.47975E-15 9.0311831E-15 0 0
54.29389 3153.41206541 3805.65483 68814.534113829
71967.9461792402 kg/jam
0
 output
arus 14 arus 15
kmol/jam kg/jam kmol/jam kg/jam
6.033534752 362.59371787 0.00060341 0.0362629981
0.379961526 6.8451588764 3799.2353 68444.743604968
0.005429329 0.3153375799 5.42987E-07 3.1536911679E-05
0 0 0 0
6.418925607 369.754214327 3799.2359 68444.779899503
68814.5341138292 kg/jam
0

output
arus 10 arus 12 arus 14 arus 15
kg/jam kg/jam kg/jam kg/jam
0.035166763 0.0362666247 362.593718 0.0362629981
0 0 6.84515888 68444.743604968
1.116590719 3153.37579879 0.31533758 3.1536911679E-05
109.5049697 9.0311831E-15 0 0
110.6567272 3153.41206541 369.754214 68444.779899503
72078.6029064088 kg/jam
0
umpan aktual = produk aktual x umpan basis
produk basis
umpan aktual = 60.9628971 kmol/jam

BM
C 12.011
H 1.008
O 15.9994

kmol/jam

INPUT OUTPUT
ARUS 1 ARUS 2
kg/jam fraksi berat kg/jam fraksi berat
3627.01414 0.996981 3627.014 0.996981
10.9827098 0.003019 10.98271 0.003019
0 0 0 0
0 0 0 0
3637.99685 1 3638 1
 0.6435
xi.L yi.V
5.4501542681 0.58517254
0.5770385945 0.03259038
35.0930269049 19.2249144
4.47975351E-15 54.3179413
41.1202197676 74.1606186
(kirk othmer) pubchem.ncbi.nlm.nih.gov
(engineeringtoolbox.com) G.W.C. Kaye and T.H. Laby, "Tables of Physical and Chemical Constants," 15th ed., L

kg/jam
mical Constants," 15th ed., Longman, NY, 1986, p.219.
 NERACA MASSA AKTUAL RECYCLE

Kapasitas perancangan per tahun : 25.000 ton/tahun

Waktu operasi dalam satu tahun : 330 hari
Kapasitas perancangan per jam

ton 1000 kg 1 tahun 1 hari

Kapasitas = 25000.000 x x x
tahun 1 ton 330 hari 24 jam
= 3156.5657 kg/jam

komposisi produk Aseton :

(CH3)2CO= 99.50% berat
impuritas = 0.50% berat
100.00% berat

Komposisi bahan baku :

Bahan Baku Isopropil alkohol :
(CH3)2CHOH = 99.00% berat
H2 O = 1.00% berat
100.00% berat

BASIS NERACA MASSA MIX STATION TEE

1 2
Umpan
(CH3)2CHOH
H2O
14

INPUT (kg/jam)
KOMPONEN ARUS 1 ARUS 14
kg/jam kmol/jam kg/jam
(CH3)2CHOH 3264.420424694 54.3197333733 362.59371787
H2O 4.1375508871 0.2296674449 6.8451588764
(CH3)2CO 0 0 0.315369134
H2 0 0 0
SUBTOTAL 3268.557975582 54.5494008182 369.754245881
TOTAL 3638.3122214623

NERACA MASSA REAKTOR REAKTOR FIXED BED

konversi
 4 5 umpan masuk

(CH3)2CHOH (CH3)2CO + H2

mula2 60.3532681253 - -
reaksi 54.3179413128 54.3179413128 54.3179413128
sisa 6.0353268125 54.3179413128 54.3179413128

INPUT OUTPUT
KOMPONEN ARUS 4 ARUS 5
kg/jam kmol/jam kg/jam
(CH3)2CHOH 3627.014142565 60.3532681253 362.701414256
H2O 10.9827097635 0.609628971 10.9827097635
(CH3)2CO 0.315369134 0.0054298719 3155.12312776
H2 0 0 109.504969687
TOTAL 3638.312221462 60.9683269682 3638.31222146
0

FLASH DRUM

5 6
7

INPUT OU
KOMPONEN ARUS 5 ARUS 6
kg/jam kmol/jam kg/jam
(CH3)2CHOH 362.7014142565 6.0353268125 35.1667633004
H2O 10.9827097635 0.609628971 0.5871286675
(CH3)2CO 3155.123127756 54.3233711847 1116.70233833
H2 109.5049696865 54.3179413128 109.504969687
sub total 3638.312221462 115.286268281 1261.96119998
TOTAL 3638.3122214623 3638.31
BM gas= 31.5589382475 kg/kmol

lnP= C1+C2/T+C3*lnT+C4*T^C5, P in Pa (Perry)

P = mmHg
T =K

komponen C1 C2 C3
(CH3)2CHOH 96.094 -8575.4 -10.292
H2O 73.649 -7258.2 -7.3037
(CH3)2CO 69.006 -5599.6 -7.0985
 H2 12.69 -94.896 1.1125

P= 1 atm 101325
T= 25 C 298.15

komponen zi F (kmol) Po (Pa)

(CH3)2CHOH 0.0523507865 6.0353268125 6027.02151057
H2O 0.0052879582 0.609628971 3170.38577496
(CH3)2CO 0.4712041772 54.3233711847 30751.845279
H2 0.4711570781 54.3179413128 6.806389E+20
total 115.286268281

V 74.1867136388
L 41.0995546422
V/L 1.8050490884
L/V 0.554001554

nilai spericity didapatkan dari trial xi=1 dengan mengubah spericity

ABSORBER 10

umpan masuk absorber adalah hasil atas FD

komponen BM kmol/jam kg/jam

(CH3)2CHOH 60.0964 0.5851725445 35.1667633004
H2O 18.0154 0.0325903764 0.5871286675
(CH3)2CO 58.0804 19.2268362189 1116.70233833
H2 2.016 54.3179413128 109.504969687
total 74.1625404526 1261.96119998

ABSORBEN BERUPA AIR

Kebutuhan Air
H2 diharapkan 0.1% ada diproduk bawah
Asumsi H2 0.1095049697 kg/jam
Kebutuhan Air 68440.60605408 kg/jam

kelarutan (CH3)2CHOH dalam air = 0.999

kelarutan (CH3)2CO dalam air= 0.999
kelarutan H2 dalam air (kg/kg air)= 0.0000016
asumsi produk (arus 9)
99,9% aseton terserap
komponen BM kmol/jam kg/jam
(CH3)2CHOH 60.0964 0.5845873719 35.1315965371
H2O 18.0154 3799.0382219 68441.1931827
(CH3)2CO 58.0804 19.2076093827 1115.58563599
H2 2.016 0.0543179413 0.1095049697
total 3818.88473659 69592.0199202

produk atas (arus 10)

komponen BM kmol/jam kg/jam
(CH3)2CHOH 60.0964 0.0005851725 0.0351667633
H2O 18.0154 0 0
(CH3)2CO 58.0804 0.0192268362 1.1167023383
H2 2.016 54.2636233714 109.395464717
total 54.2834353802 110.547333818

NERACA MASSA MIX STATION-02

input output
komponen arus 7 arus 9 arus 11
kg/jam kg/jam kg/jam
(CH3)2CHOH 327.5346509561 35.1315965371 362.666247493
H2O 10.3955810959 68441.1931827 68451.5887638
(CH3)2CO 2038.420789426 1115.58563599 3154.00642542
H2 9.03118307E-15 0.1095049697 0.1095049697
subtotal 2376.351021478 69592.0199202 71968.3709417
total 71968.3709417243 71968.3709417243

MENARA DISTILASI-1

12

11

13

Dinginkan produk atas dengan komposisi

(CH3)2CO 0.9999
(CH3)2CHOH 0.0001
H2O 0
H2 1
Diinginkn produk bawah dengan komposisi
(CH3)2CHOH 0.9999
H2O 1
(CH3)2CO 0.0001
H2 0

input
komponen BM arus 11
kmol/jam kg/jam
(CH3)2CHOH 60.0964 6.03474164 362.666247493
H2O 18.0154 3799.61526049 68451.5887638
(CH3)2CO 58.0804 54.3041443485 3154.00642542
H2 2.016 0.0543179413 0.1095049697
subtotal 6.03474164 71968.3709417
total 71968.3709417243

MENARA DISTILASI-02

14

13

15

Dinginkan produk atas dengan komposisi

(CH3)2CO 0.9999
(CH3)2CHOH 0.9999
H2O 0.0001
H2 0
Diinginkn produk bawah dengan komposisi
(CH3)2CHOH 0.0001
H2O 0.9999
(CH3)2CO 0.0001
H2 0

input
komponen BM arus 13
kmol/jam kg/jam
(CH3)2CHOH 60.0964 6.0341381658 362.629980868
H2O 18.0154 3799.61526049 68451.5887638
(CH3)2CO 58.0804 0.0054304144 0.3154006425
H2 2.016 0 0
subtotal 3805.65482907 68814.5341454
total 68814.534145355
NERACA MASSA OVERALL

input
komponen BM arus 1 arus 8
kg/jam kg/jam
(CH3)2CHOH 60.0964 3264.42042469 0
H2O 18.0154 4.1375508871 68440.6060541
(CH3)2CO 58.0804 0 0
H2 2.016 0 0
subtotal 3268.55797558 68440.6060541
total 71709.164030

HASIL ASETON DARI MD-01

24978.387427245
25000.000 ton/tahun
-21.613
 umpan basis 100.0000 kmol/jam
produk basis 89.1496 kmol/jam
produk aktual 54.3482 kmol/jam

ahun 1 hari
x
0 hari 24 jam

BM kg/kmol
(CH3)2CO 58.0804
(CH3)2CHOH 60.0964
H2O 18.0154
H2 2.016

UMPAN 60.9628970963 kmol/jam

3627.01414 kg/jam
10.9827098 kg/jam
3637.99685 kg/jam UMPAN 60.9628970963

) OUTPUT
ARUS 14 ARUS 2 KOMPONEN BM
kmol/jam kg/jam kmol/jam
6.03353475 3627.0141426 60.3532681253 (CH3)2CHOH 60.0964
0.37996153 10.982709763 0.609628971 H2O 18.0154
0.00542987 0.315369134 0.0054298719 (CH3)2CO 58.0804
0 0 0 H2 2.016
6.41892615 3638.3122214623 TOTAL
3 3638.3122214623
0
KTOR FIXED BED Arus recycle (14)
Komponen kg/jam
90% (CH3)2CHOH 362.59371787
 60.3532681 kmol/jam H2O 6.8451588764
(CH3)2CO 0.315369134
H2 0
TOTAL 369.754245881

OUTPUT
ARUS 5 BM
kmol/jam
6.03532681 60.0964
0.60962897 18.0154
54.3233712 58.0804
54.3179413 2.016
115.286268

OUTPUT
ARUS 6 ARUS 7 BM
kmol/jam kg/jam kmol/jam
0.58517254 327.53465096 5.4501542681 60.0964
0.03259038 10.395581096 0.5770385945 18.0154
19.2268362 2038.4207894 35.0965349658 58.0804
54.3179413 9.031183E-15 4.479753507E-15 2.016
74.1625405 2376.3510215 41.1237278284
3638.3122214623 kg/jam
0

log 10 P= A+B/T+C*log10*T+DT+E*T^2 (Yaws)

C4 C5 halaman
1.6665E-17 6 297
4.1653E-06 2 342
6.2237E-06 2 5
 0.00032915 2 183

Pa
K

ψ
Ki xi yi f(0) f(1) spericity
0.05948208 0.1326085967 0.0078878348 0.0492368529 0.8277594685 0.1247207619
0.03128927 0.0140400206 0.0004393021 0.0051225018 0.1637143038 0.0136007186
0.30349712 0.8539395444 0.259168189 0.3281950684 1.0813778815 0.5947713554
6.7174E+15 1.089976E-16 0.7321788316 -3.164943E+15 -0.4711570781 -0.7321788316
1.0005881618 0.9996741575 -3.164943E+15 1.6016945756 0.0009140043

fraksi mol fraksi berat

0.00789041 0.0278667548
0.00043945 0.000465251
0.25925266 0.884894352
0.73241748 0.0867736422
1 1

miscible suhu 298,15 K

miscible
digunakan data kelarutan H2 saja karena aseton dan isopropil alkohol miscible (larut sempurna air)
 suhu 293 K

masuk keluar
komponen arus 6 arus 8 arus 9 arus 10
(CH3)2CHOH 35.1667633004 0 35.1315965371 0.0351667633
H2O 0.5871286675 68440.6060541 68441.193182748 0
(CH3)2CO 1116.7023383301 0 1115.5856359918 1.1167023383
H2 109.5049696865 0 0.1095049697 109.395464717
subtotal 1261.9611999845 68440.6060541 69592.019920247 110.547333818
TOTAL 69702.5672540651 69702.5672540651
0

output

kg/jam
35.1315965
68441.1932
1115.58564
0.10950497
69592.0199
71968.3709417243 kg/jam
0
 output
arus 12 atas arus 13 bawah
kmol/jam kg/jam kmol/jam kg/jam
0.00060347 0.0362666247 6.0341381658 362.629980868
0 0 3799.6152604907 68451.5887638
54.2987139 3153.6910248 0.0054304144 0.3154006425
0.05431794 0.1095049697 0 0
54.3536353 3153.8367964 3805.654829071 68814.5341454
71968.3709417243 kg/jam
0

output
arus 14 arus 15
kmol/jam kg/jam kmol/jam kg/jam
6.03353475 362.59371787 0.0006034138 0.0362629981
0.37996153 6.8451588764 3799.2352989647 68444.743605
0.00542987 0.3153691025 0.000000543 3.1540064E-05
0 0 0 0
6.41892615 369.75424585 3799.2359029215 68444.7798995
68814.534145355 kg/jam
 0

output
arus 10 arus 12 arus 15
kg/jam kg/jam kg/jam
0.03516676 0.0362666247 0.0362629981
0 0 68444.743604968
1.11670234 3153.6910248 3.154006425E-05
109.395465 0.1095049697 0
110.547334 3153.8367964 68444.779899506
71709.164030 kg/jam
0.00000
umpan aktual = produk aktual x umpan basis
produk basis
umpan aktual = 60.962897096 kmol/jam

BM
C 12.011
H 1.008
O 15.9994

kmol/jam

INPUT OUTPUT
ARUS 1 ARUS 2
kg/jam kmol/jam kg/jam fraksi berat
3627.0141425648 60.353268125 3627.01414256 60.353268125
10.9827097635 0.609628971 10.9827097635 0.609628971
0 0 0 0
0 0 0 0
3637.9968523283 60.962897096 3637.99685233 60.962897096

kmol/jam
6.033534752
 0.379961526
0.0054298714
0
6.4189261494
 0.6435
xi.L yi.V
5.4501542681 0.5851725445
0.5770385945 0.0325903764
35.0965349658 19.226836219
4.479753507E-15 54.317941313
41.1237278284 74.162540453

(kirk othmer) pubchem.ncbi.nlm.nih.gov

(engineeringtoolbox.com) G.W.C. Kaye and T.H. Laby, "Tables of Physical and Chemical Constants," 15
kg/jam
hemical Constants," 15th ed., Longman, NY, 1986, p.219.
 NERACA PANAS
KAPASITAS PANAS LIQUID

Cp = A + B*T + C*T^2 + D*T^3 Tabel 3-1 Heat Capacity of Liquid-Organic Com

Cp = heat capacity of ideal gas (joule/(mol K ) Tabel 3-2 Heat Capacity of Liquid-Inorganic Co
T = temperature (kelvin) YAWS 1999

komponen A B C D
(CH3)2CHOH 72.525 7.96E-01 -2.63E-03 3.65E-06
H2O 92.053 -4.00E-02 -2.11E-04 5.35E-07
(CH3)2CO 46.878 6.27E-01 2.08E-03 2.96E-06
H2 5.06E+01 -6.11E+00 3.09E-01 -4.15E-03
ZnO - - - -

KAPASITAS PANAS GAS

Cp = A + B*T + C*T^2 + D*T^3 + E*T^4 Tabel 2-1 Heat Capacity of Gas-Organic Compo
Cp = heat capacity of ideal gas (joule/(mol K ) Tabel 2-2 Heat Capacity of Gas-inorganic Com
T = temperature (kelvin) YAWS 1999

komponen A B C D
(CH3)2CHOH 25.535 2.12E-01 5.35E-05 -1.47E-07
H2O 33.933 -8.42E-03 2.99E-05 -1.78E-08
(CH3)2CO 35.918 9.39E-02 1.87E-04 -2.16E-07
H2 2.54E+01 2.02E-02 -3.85E-05 3.19E-08
ZnO 2.45E+01 3.50E-02 -3.98E-05 2.04E-08

1. NERACA PANAS MIX STATION TEE

Panas masuk TEE-01 dari ARUS 1 (tangki)

T ref= 25 C = 298.15 K
T in= 30.00 C = 303.15 K
P= 1 atm
Cair
komponen kg/jam kmol/jam ʃCp dT
(CH3)2CHOH 3264.42042469 54.3197333733 864.4550679096
H2O 4.1375508871 0.2296674449 377.4863815882
(CH3)2CO 0 0 2516.5254277359
H2 0 0 -432811.957765722

Panas masuk TEE-01 dari arus 14 (Bottom MD-2)

T ref= 25 C = 298.15 K
T in= 77.43 C = 350.58 K
P= 1 atm
Cair
komponen kg/jam kmol/jam ʃCp dT Q= (kJ/jam)
(CH3)2CHOH 362.59371787 6.033534752 9349.3710401 56409.75508007
H2O 6.8451588764 0.379961526 3943.4329637 1498.352806753
(CH3)2CO 0.315369134 0.0054298714 29919.814763 162.4607462785
H2 0 0 -5862311.8128 0

Panas keluar TEE-01

T ref= 25 C = 298.15 K
T out= 35.00 C = 308.15 K
Cair
komponen kg/jam kmol/jam ʃCp dT Q= (kJ/jam)
(CH3)2CHOH 3627.01414256 60.3532681253 1734.0460542 104655.3464488
H2O 10.9827097635 0.609628971 754.46076576 459.9411402613
(CH3)2CO 0.315369134 0.0054298719 5100.5733312 27.6954599905
H2 0 0 -889679.90292 0

NERACA PANAS TEE-01

komponen Qin Qout
(CH3)2CHOH 103366.72388 104655.34645
H2O 1585.0491395 459.94114026
(CH3)2CO 162.46074628 27.69545999
H2 0 0
TOTAL 105114.23377 105142.98305

2. NERACA PANAS MIX STATION TEE 2

Panas masuk TEE-02 dari arus 7 (OUTPUT FLASH DRUM)

T ref= 25 C = 298.15 K
T in= 33.00 C = 306.15 K
P= 1 atm
Cair
komponen kg/jam kmol/jam ʃCp dT Q= (kJ/jam)
(CH3)2CHOH 327.534650956 5.4501542681 1385.5822371 7551.636943303
H2O 10.3955810959 0.5770385945 603.72802863 348.3743731209
(CH3)2CO 2038.42078943 35.0965349658 4058.7751018 142448.9422797
H2 9.0311831E-15 4.4797535E-15 -703990.44747 -3.15370368E-09

Panas masuk TEE-02 dari arus 9 (OUTPUT bawah absorber)

T ref= 25 C = 298.15 K
T in= 31.00 C = 304.15 K
P= 1 atm
Cair
komponen kg/jam kmol/jam ʃCp dT Q= (kJ/jam)
(CH3)2CHOH 35.1315965371 0.5845873719 1037.9568793 606.7764842281
H2O 68441.1931827 3799.0382219 452.92001306 1720660.441065
(CH3)2CO 1115.58563599 19.2076093827 3027.8950604 58158.62557237
H2 0.1095049697 0.0543179413 -522233.33813 -28366.63981205

Panas keluar TEE-02 (ARUS 11)

T ref= 25 C = 298.15 K
T out= 70.00 C = 343.15 K
Cair
komponen kg/jam kmol/jam ʃCp dT Q= (kJ/jam)
(CH3)2CHOH 362.666247493 6.03474164 7981.7005685 48167.50077877
H2O 68451.5887638 3799.61526049 3385.0625022 12861935.14108
(CH3)2CO 3154.00642542 54.3041443485 25181.498751 1367459.743091
H2 0.1095049697 0.0543179413 -4836661.4765 -262717.4942315

NERACA PANAS TEE-01

komponen Qin Qout
(CH3)2CHOH 606.77648423 48167.500779
H2O 1720660.4411 12861935.141
(CH3)2CO 58158.625572 1367459.7431
H2 -28366.63981 -262717.4942
TOTAL 1751059.2033 14014844.891

3. VAPORIZER

BM kg/kmol
(CH3)2CO 58.0804
(CH3)2CHOH 60.0964
H2O 18.0154
H2 2.016

VAPOUR PRESSURE
log P = A + B/T +C log T + D T +E T^2 Tabel 7-1 Vapor Pressure-Organic Compounds
P = mmHg Tabel 7-2 Vapor Pressure-Inorganic Compounds
T =K YAWS 1999

komponen A B C D
(CH3)2CHOH 38.2363 -3.55E+03 -1.00E+01 -3.47E-10
H2O 29.8605 -3.15E+03 -7.30E+00 2.42E-09
(CH3)2CO 28.5884 -2.47E+03 -7.35E+00 2.80E-10
H2 3.41E+00 -4.13E+01 1.09E+00 -6.69E-10
ZnO 10.0724 -1.58E+04 -3.01E-02 6.57E-06

T bubble= 30 K 3.03E+02 C
P= atm mmHg

Komponen kg/jam Kmol/jam Fraksi kmol (xi Pi s

(CH3)2CHOH 3627.01414256 60.3532681253 0.9899118301
H2O 10.9827097635 0.609628971 0.0099991094
(CH3)2CO 0.315369134 0.0054298719 8.9060537E-05
H2 0 0 0
Total 3638.31222146 60.9683269682 1
A PANAS

3-1 Heat Capacity of Liquid-Organic Compounds ʃCpdT= A(T-298)+B/2*(T^2-298^2)+C/3*(T^3-298^3)+D/4*(T^4

3-2 Heat Capacity of Liquid-Inorganic Compounds

Tmin Tmax Cp at 25 C halaman

186 457 172.39 62
273 615 75.55 79
179 457 127.53 62
14 32 - 79
- - - 82

2-1 Heat Capacity of Gas-Organic Compounds ʃCpdT= A(T-298)+B/2*(T^2-298^2)+C/3*(T^3-298^3)+D/4*(T^4

2-2 Heat Capacity of Gas-inorganic Compounds T reaksi=
T standar=

E Tmin Tmax halaman Cp (J/molCp (kJ/mol K)

4.94E-11 100 1500 35
3.69E-12 100 1500 52
6.32E-11 100 1500 35
-8.76E-12 250 1500 52
-3.78E-12 298 2000 55

Q (kJ/jam)
46956.968802037
86.696332749
0
0
ASUMSI SUHU
 BM
C 12.011
H 1.008
O 15.9994

ure-Organic Compounds
ure-Inorganic Compounds

E Tmin Tmax halaman

1.74E-06 185.28 508.31 164
1.81E-06 273.16 647.13 181
2.74E-06 178.45 508.2 164
 1.46E-04 13.95 33.18 181
-5.49E-10 1773.1 2223.1 184

Ki = Pis/P Yi = Ki*Xi
8^2)+C/3*(T^3-298^3)+D/4*(T^4-298^4) kJ/kmol.K

8^2)+C/3*(T^3-298^3)+D/4*(T^4-298^4)+E/5*(T^5-298^5) kJ/kmol.K
ENTALPHY OF FORMATION

Hf= A+ BT+ CT^2 Tabel 12-1 Entalphy of formation-Organ

Hf= kJoule/mol Tabel 12-2 Entalphy of formation-inorga
T = temperature (kelvin) YAWS 1999

komponen A B C Tmin
(CH3)2CHOH -250.362 -8.79E-02 4.32E-05 298
H2O
(CH3)2CO -199.175 -7.15E-02 3.25E-05 298
H2

GIBBS OF FORMATION

Gf= A+ BT+ CT^2 Tabel 13-1 Gibbs Energy of formation of

Gf= kJoule/mol Tabel 13-2 Gibbs Energy of formation of
T = temperature (kelvin) YAWS 1999

komponen A B C Tmin
(CH3)2CHOH -274.608 3.29E-01 2.92E-05 298
H2O
(CH3)2CO -218.777 2.12E-01 2.66E-05 298
H2

KAPASITAS PANAS GAS

Cp = A + B*T + C*T^2 + D*T^3 + E*T^4 Tabel 2-1 Heat Capacity of Gas-Organic

Cp = heat capacity of ideal gas (joule/(mol K ) Tabel 2-2 Heat Capacity of Gas-inorgani
T = temperature (kelvin) YAWS 1999

komponen A B C D
(CH3)2CHOH 25.535 2.12E-01 5.35E-05 -1.47E-07
H2O 33.933 -8.42E-03 2.99E-05 -1.78E-08
(CH3)2CO 35.918 9.39E-02 1.87E-04 -2.16E-07
H2 2.54E+01 2.02E-02 -3.85E-05 3.19E-08
ZnO 2.45E+01 3.50E-02 -3.98E-05 2.04E-08

T standar= 298 K
T reaksi= 623 K
ΔH 298 K= 55.02 kJ/mol dari perhitungan diperoleh hasil ΔHf bernilai positif sehin
ΔH 623 K=

ΔGf 298 K= 20.54 kJ/mol

ΔGf= -RT ln K R= 0.008314 kJ/mol K

ln K= ΔGf /(-RT)
ln K= -8.290374609
K= 0.0002509204

menghitung nilai konstanta kesetimbangan pada kondisi operasi di reaktor (623K)

ln K2/K1= (-ΔH/R)(1/T2 - 1/T1)
ln K2/3985.32685300229= 11.584828692
K2/3985.32685300229= 107455.1351
K2= 26.962690657 karena nilai konstanta kesetimbangan lebih besar dari 0 maka reaksinya b
bel 12-1 Entalphy of formation-Organic Compounds
bel 12-2 Entalphy of formation-inorganic Compounds

Tmax Hf 298 K Hf 500 K Uf 298 K S 298 K halaman

1000 -272.59 -283.52 293
-241.8 -240.56 188.8 310
1000 -217.57 -226.78 293
0 0 130.7 310

bel 13-1 Gibbs Energy of formation of gas-Organic Compounds

bel 13-2 Gibbs Energy of formation of gas-Inorganic Compounds

Tmax Gf 298 K Gf 500 K Af 298 K Sf 298 K halaman

1000 -173.59 -102.73 319
-228.6 -227.36 -0.0443 336
1000 -153.05 -106.24 319
0 0 0 336

bel 2-1 Heat Capacity of Gas-Organic Compounds

bel 2-2 Heat Capacity of Gas-inorganic Compounds

E Tmin Tmax halaman

4.94E-11 100 1500 35
3.69E-12 100 1500 52
6.32E-11 100 1500 35
-8.76E-12 250 1500 52
-3.78E-12 298 2000 55
diperoleh hasil ΔHf bernilai positif sehingga reaksi bersifat endotermis

gan lebih besar dari 0 maka reaksinya bersifat irreversible (tidak dapat balik)