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𝑑 [𝐴− ]
= 𝑘1 [𝐴𝐻][𝐵] − 𝑘2 [𝐴− ][𝐵𝐻 + ] − 𝑘3 [𝐴− ][𝐻𝐴] = 0
𝑑𝑡
Catatan : tanda (-) apabila A- berada pada reaktan, sedangkan tanda (+) apabila A- berada pada
produk
Mencari [A-]
𝑘1 [𝐴𝐻][𝐵] − 𝑘2 [𝐴− ][𝐵𝐻 + ] − 𝑘3 [𝐴− ][𝐻𝐴] = 0
𝑘1 [𝐴𝐻][𝐵] ………………………………. (2)
[A-] = 𝑘 [𝐵𝐻 + ]+ 𝑘 [𝐻𝐴]
2 3
𝑑[B. ]
= 0 = 𝑘2 [A. ] − 𝑘3 [𝐴𝐻][𝐵. ] − 𝑘4 [A. ][B. ]
𝑑𝑡
𝑘3 [𝐴𝐻][𝐵. ] + 𝑘4 [A. ][B. ] = 𝑘2 [A. ]
[B. ](𝑘3 [𝐴𝐻] + 𝑘4 [A. ]) = 𝑘2 [A. ]
𝑘2 [A.] ……………………………………………………(2)
[B. ] =
𝑘3 [𝐴𝐻]+ 𝑘4 [A.]
𝑑[A. ]
= 0 = 𝑘1 [𝐴𝐻] − 𝑘2 [A. ] + 𝑘3 [𝐴𝐻][𝐵. ] − 𝑘4 [A. ][B. ]
𝑑𝑡
𝑘2 [A. ] + 𝑘4 [A. ][B. ] = 𝑘1 [𝐴𝐻] + 𝑘3 [𝐴𝐻][𝐵. ]
[A. ] = (𝑘2 + 𝑘4 [B. ]) = 𝑘1 [𝐴𝐻] + 𝑘3 [𝐴𝐻][𝐵. ]
𝑘1 [𝐴𝐻]+ 𝑘3 [𝐴𝐻][𝐵.] ……………………………………………………(3)
[A. ] =
𝑘2 +𝑘4 [B.]
Disubstitusi persamaan 3 ke persamaan 2
𝑘2 [A. ]
[B. ] =
𝑘3 [𝐴𝐻] + 𝑘4 [A. ]
𝑘1 [𝐴𝐻]+ 𝑘3 [𝐴𝐻][𝐵.]
𝑘2 +𝑘4 [B.]
[B. ] = 𝑘2 𝑘 [𝐴𝐻]+ 𝑘 [𝐴𝐻][𝐵.]
𝑘3 [𝐴𝐻]+ 𝑘4 [ 1 𝑘 +𝑘 3[B.] ]
2 4
𝑘2 𝑘1 [𝐴𝐻] + 𝑘2 𝑘3 [𝐴𝐻][𝐵. ]
𝑘2 + 𝑘4 [B. ]
[B. ] =
𝑘 [𝐴𝐻] + 𝑘3 [𝐴𝐻][𝐵. ]
𝑘3 [𝐴𝐻] + 𝑘4 [ 1 ]
𝑘2 + 𝑘4 [B. ]
𝑘2 𝑘1 [𝐴𝐻] + 𝑘3 𝑘2 [𝐴𝐻][𝐵. ]
( )
𝑘2 + 𝑘4 [B. ]
[B. ] =
𝑘 𝑘 [𝐴𝐻] + 𝑘2 𝑘4 [𝐴𝐻][𝐵. ] + 𝑘1 𝑘4 [𝐴𝐻] + 𝑘4 𝑘3 [𝐴𝐻][𝐵. ]
( 3 2 )
𝑘2 + 𝑘4 [B. ]
𝑘1 𝑘2 [𝐴𝐻]+𝑘2 𝑘3 [𝐴𝐻][𝐵.] 𝑘2 +𝑘4 [B.]
[B. ] = x𝑘
𝑘2 +𝑘4 [B.] 2 𝑘3 [𝐴𝐻]+𝑘3 𝑘4 [𝐴𝐻][𝐵.]+𝑘1 𝑘4 [𝐴𝐻]+𝑘4 𝑘3 [𝐴𝐻][𝐵.]
𝑘1 𝑘2 [𝐴𝐻] + 𝑘2 𝑘3 [𝐴𝐻][𝐵. ]
[B. ] =
𝑘2 𝑘3 [𝐴𝐻] + 𝑘3 𝑘4 [𝐴𝐻][𝐵. ] + 𝑘1 𝑘4 [𝐴𝐻] + 𝑘4 𝑘3 [𝐴𝐻][𝐵. ]
𝑘 𝑘 [𝐴𝐻]
[ B.] = 𝑘1 𝑘2 [𝐴𝐻]
1 4
𝑘2
[ B.] =
𝑘4
𝑑[𝐴𝐻]
= −𝑘1 [𝐴𝐻] − 𝑘3 [𝐴𝐻][B. ]
𝑑𝑡
𝑘
= −𝑘1 [𝐴𝐻] − 𝑘3 [𝐴𝐻][𝑘2 ]
4
𝑘2 𝑘3 [𝐴𝐻]
= −𝑘1 [𝐴𝐻] −
𝑘4
−𝑘1 − 𝑘2 𝑘3
=( ) [𝐴𝐻]1
𝑘4
𝑑 [𝐴𝐻]
= 𝑘 [𝐴𝐻]1 (terbukti bahwa reaksi dekomposisi AH adalah reaksi orde 1)
𝑑𝑡
𝑑 [𝑁𝑂]
= k2 [NO2][NO3] – k3[NO][N2O5] ...............................................(2)
𝑑𝑡
= 0 → pada steady state
𝑑 [𝑁2 𝑂5 ]
= k1[N2O5]+ k-1 [NO2][NO3] – k3[NO][N2O5] ...............................................(3)
𝑑𝑡
𝑘1 𝑘2 ...............................................(6)
=𝑘 (𝑘−1 +𝑘2 )
3
𝑘 𝑘 𝑘1 𝑘2
= [N2O5] (𝑘1 − (𝑘 −1+𝑘1 ) + (𝑘−1 +𝑘2 )
)
−1 2
𝑑 [𝑁2 𝑂5 ] 2 𝑘1 𝑘2 [𝑁2 𝑂5 ] 𝑘1
=− (𝑘−1 +𝑘2 )
atau −2 k2 [𝑁2 𝑂5 ]
𝑑𝑡 𝑘−1
Terminasi
𝑑[𝐶𝐻4 ]
(b) = k2 [CH3] [CH3CHO] .....................................(persamaan 1)
𝑑𝑡
𝑑[𝐶𝐻3 ]
= k1 [CH3CHO] – k2 [CH3] [CH3CHO] + k3 [CH3CO] – 2k4 [CH3]2...(persamaan 2)
𝑑𝑡
𝑑[𝐶𝐻3 𝐶𝑂]
= k2 [CH3] [CH3CHO] – k3 [CH3CO] ........(persamaan 3)
𝑑𝑡
𝑑[𝐶𝐻3 ]
= k1 [CH3CHO] – k2 [CH3] [CH3CHO] + k3 [CH3CO] – 2k4 [CH3]2
𝑑𝑡
𝑑[𝐶𝐻3 𝐶𝑂]
= k2 [CH3] [CH3CHO] – k3 [CH3CO]
𝑑𝑡
+
0 = k1 [CH3CHO] – 2k4[CH3]2
2k4[CH3]2 = k1[CH3CHO]
𝑘1 [𝐶𝐻3 𝐶𝐻𝑂]
[CH3]2 = 2𝑘4
𝑘1 [𝐶𝐻3 𝐶𝐻𝑂]
[CH3] = √ 2𝑘4
𝑘
= (2𝑘1 )½ [CH3CHO] ½..............(persamaan 4)
4
𝑑[𝐶𝐻4 ]
= k2 [CH3] [CH3CHO]
𝑑𝑡
𝑘
= k2 (2𝑘1 )½ [CH3CHO] ½ [CH3CHO]
4
𝑘
= k2 (2𝑘1 )½ [CH3CHO]3/2
4
𝑑[𝐶𝐻4 ] 𝑘
(c) r = = k2 (2𝑘1 )½ [CH3CHO]3/2
𝑑𝑡 4
k
3/2
r = k [CH3CHO]