CORRELACIONES PARA PROPIEDADES FISICAS DE FRACCIONES INDEFINIDAS DE

HIDROCARBUROS

RIAZI-DAUBERT

θ = aTbbγ c

Propiedad (θ) a b c
MW 4.5673x10-5 2.1962 -1.0164
Tc, °R 24.2787 0.58848 0.3596
Pc, Psia 3.12281x109 -2.3125 2.3201
Vc, ft3/lb 7.5214x10
-3
0.2896 -0.7666

θ aTbbγ c EXP [ dTb + eγ + fTbγ ]

Propiedad (θ) a b c d e f
MW 581.96 0.97476 6.51274 5.43076x10-4 -9.53384 1.11056x10-3
Tc, °R 10.6443 0.81067 0.53691 -5.1747x10-4 -0.54444 3.5995x10-4
Pc, Psia 6.162x106 -0.4844 4.0846 -4.725x10-3 -4.8014 3.1939x10-3
Vc, ft3/lb 6.233x10-4 0.7506 -1.2028 -1.4679x10-3 -0.26404 1.095x10-3

θ aMW bγ c EXP [ d ( MW ) + eγ + f ( MW )γ ]

Propiedad (θ) a b c d e f
-4
Tc, °R 544.4 0.2998 1.0555 -1.3478x10 -0.61641 0.00
4 -3
Pc, Psia 4.52030x10 -0.8063 1.6015 -1.8078x10 -0.3084 0.00
Vc, ft3/lb 1.206x10
-2
0.20378 -1.3036 -2.657x10
3
0.5287 2.6012x10-3
Tb, °R 6.77857 0.401673 -1.58262 3.77409x10-3 2.984036 -4.25288x10-3

CAVETT

• Temperatura Crítica

Tc =a0 + a1Tb + a2Tb 2 + a3 ( API )(Tb ) + a4Tb 3 + a5 ( API )(Tb ) 2 + a6 ( API ) 2 (Tb ) 2

• Presión Crítica

Pc = 10 X

X =b0 + b1Tb + b2Tb 2 + b3 ( API )(Tb ) + b4Tb 3 + b5 ( API )(Tb ) 2 + b6 ( API ) 2 (Tb )
+b7 ( API ) 2 (Tb ) 2
T b = Temperatura de Ebullición (°F)

i ai bi
0 768.07121 2.82904060
1 1.7133693 0.94120109x10-3
2 –0.0010834003 –0.30474749x10-5
3 –0.0089212579 –0.20876110x10-4
4 0.38890584x10-6 0.15184103x10-8
5 0.5309492x10-5 0.11047899x10-7
6 0.327116x10-7 –0.48271599x10-7
7 - 0.13949619x10-9

KESLER-LEE

• Presión Crítica

Pc = e X

0.0566  2.2898 0.11857  −3  3.648 0.47227  −7

X = 8.3634 − −  0.24244 + +  x10 Tb + 1.4685 + +  x10 Tb
2

γ  γ γ 2
  γ γ 2

 1.6977  −10 3
−  0.42019 +  x10 Tb
 γ 2


• Temperatura Crítica

Tc =341.7 + 811.1γ + ( 0.4244 + 0.1174γ ) Tb +

( 0.4669 − 3.26238γ ) x105
Tb

• Peso Molecular

 720.79  107
MW = −12272.6 + 9486.4γ + ( 4.6523 − 3.3287γ ) Tb + (1 − 0.77084γ − 0.02058γ 2 ) 1.3437 − x
 Tb  Tb

2  181.98  1012
+ (1 − 0.80882γ + 0.02226γ ) 1.8828 − x
 Tb  Tb3

• Factor Acéntrico

(T )
1/3
Tb
KW = b θ=
γ Tc
Para θ ≥ 0.8

1.408 − 0.01063K w
ϖ=
−7.094 + 0.1352 K w − 0.007465 K w 2 + 8.359θ +
θ
Para θ < 0.8

− ln ( Pc /14.7 ) − 5.92714 + 6.09648 / θ + 1.28862 ln (θ ) − 0.169347θ 6

ϖ=
15.2518 − 15.6875 / θ − 13.4721ln (θ ) + 0.43577θ 6

WINN-SIM-DAUBERT

• Presión Crítica

Pc = 3.48242 x109 Tb−2.3177γ 2.4853

• Peso Molecular

MW = 1.4350476 x10−5 Tb2.3776γ −0.9371

• Temperatura Crítica

Tc = EXP ( 3.9934718Tb0.08615γ 0.04614 )

WATANSIRI-OWENS-STARLING

• Temperatura Crítica

ln(Tc ) =
−0.0650504 − 0.0005217Tb + 0.03095ln( MW ) + 1.11067 ln(Tb )
+ MW 0.078154γ 1/2 − 0.061061γ 1/3 − 0.016943γ 

• Volumen Crítico (ft3/Lb-mol)

ln(Vc ) = 76.313887 − 129.8038γ + 63.1750γ 2 − 13.175γ 3 + 1.10108ln( MW )

+42.1958ln(γ )

• Presión Crítica

0.8
6.6418853 + 0.01617283  c  − 8.712  MW  − 0.08843889  b 
T T
ln( Pc ) = 
 Vc   Tc  MW 
• Factor Acéntrico

 −4  Tb  + 382.904 + 0.074691x10−5  Tb  
2

 5.12316667 x10 T + 0.281826667     

 MW   γ  
b
 MW
  5 b 
T
 −0.12027778 x10−4 (Tb )( MW ) + 0.001261(γ )( MW ) + 0.1265 x10−4 ( MW ) 2
ϖ=
 1/3 2/3
  9 MW 
 +0.2016 x10−4 (γ )( MW ) 2 − 66.29959(T b )
−
0.00255452 T b 
 γ 2 
 MW 

EDMISTER

3 log ( Pc /14.7 ) 
ϖ −1
T 
7  c − 1
 Tb 

FACTORES DE COMPRESIBILIDAD CRÍTICOS

PV
Zc = c c

RTc

Vc = Volumen Crítico (ft3/lb-mol)

R = Constante de los gases – 10.73

PV
c c MW
Zc =
RTc

Vc = Volumen Crítico (ft3/lb)

Método Año Z
c

Haugen et al 1959 =Z c 1/ (1.28ϖ + 3.41)

Sherwood 1977 Z c 0.291 − 0.08ϖ

=

Salermo et al 1985 Z c =0.291 − 0.08ϖ − 0.016ϖ 2

Nath 1985 =Z c 0.2918 − 0.0928ϖ