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sistema Acetona - Metanol

T(°K)= 320 a (BAR) b (BAR) c (BAR)


Acetona 4.2184 1197.01 228.06

Metanol 5.20277 1580.08 239.5

R= 8.314472 cal/gmol A12 A21 X (X1) 1-X(X2)


T= 46.85 °C 0.58 0.65 0 1
0.58 0.65 0.1 0.9
A12= 0.58 0.58 0.65 0.2 0.8
A21= 0.65 0.58 0.65 0.3 0.7
0.58 0.65 0.4 0.6
0.58 0.65 0.5 0.5
0.58 0.65 0.6 0.4
0.58 0.65 0.7 0.3
0.58 0.65 0.8 0.2
0.58 0.65 0.9 0.1
0.58 0.65 1 0

450
400
350
0.7
300
0.6
Coefcientes de actvidad

250
0.5
��

200 ln 0.4
ɣ1
150 ln 0.3
ɣ2
100
0.2
50
0.1
0
0 0.2 0.4 0.6 0.8 1 1.2 0
0 0.1 0.2 0.3 0.4
X
fraccion A
fra
0
0 0.1 0.2 0.3 0.4

fra
ln ɣ1 ln ɣ2 ɣ1 ɣ2 �^� ( j/mol) PSAT1 PSAT2 Pvan(X,T)
0.58 1.78603843 1 0 0.73149499 0.4839133 0.4839133
0.48008461 0.00528868 1.61621114 1.00530269 140.3969069785 0.73149499 0.4839133 0.55605644
0.387722 0.02162296 1.47362007 1.02185843 252.3416105862 0.73149499 0.4839133 0.61118184
0.30349357 0.04974055 1.35458288 1.05099838 334.8841962429 0.73149499 0.4839133 0.65327564
0.22802184 0.09042917 1.25611275 1.09464397 387.0319879408 0.73149499 0.4839133 0.68536374
0.16197369 0.14453037 1.17582931 1.15549679 407.7471146667 0.73149499 0.4839133 0.70963675
0.10606389 0.21294365 1.11189291 1.23731492 395.9439087158 0.73149499 0.4839133 0.72750771
0.0610588 0.29663096 1.06296142 1.34531873 350.486122191 0.73149499 0.4839133 0.73959095
0.02778061 0.39662166 1.02817009 1.48679331 270.1839466882 0.73149499 0.4839133 0.74557683
0.00711178 0.5140178 1.00713713 1.67199546 153.7908197397 0.73149499 0.4839133 0.74395427
0.65 1 1.91554083 0 0.73149499 0.4839133 0.73149499

1.2

0.7
1
0.6
Coefcientes de actvidad

0.5 0.8
X (X1)
0.4 yVan(X,T 0.6
0.3 )

0.2 0.4

0.1 0.2
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0
0 0.2 0.4 0.6
X
fraccion A x
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0
0 0.2 0.4 0.6
X
fraccion A x
yVan(X,T)
0
0.21261337
0.3527414
0.45503178
0.53626425
0.60602361
0.67079214
0.73592797
0.80700069
0.8912432
1

0.2 0.4 0.6 0.8 1 1.2


x
0.2 0.4 0.6 0.8 1 1.2
x