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The water pollution problems are spreading thorough out the world. These world-wide
problems are increasing day by day. Among many contamination materials of wastewater, one
of them is heavy metals leach out through the wastewater by the industries like oil tanneries,
textile refineries, dyes, paper pulp industries, and petrochemical industries etc. The waste
industrial water contains by these industries is polluted due to leakage of synthetic organic
compounds, hydrocarbon salts, and heavy metals. To remove these pollutants conventional,
nano-based materials characterization, adsorbents, and Bismuth-based particles are being
practiced. The heavy metals lead to a very hazardous effect on the aquatic, human, agriculture
and wildlife. Because of toxic materials, the cause of health problems, the disorder of irrigation
to crops, the marine life in sea water is also destroying rapidly and the pollution is also
increasing up to 5% as per day. The use of Bismuth Vanadate, Bi-oxyhalide, and chalcogenide,
in the wastewater treatment is mostly used and as a result decrease of contamination at about
85% to purified water is reported in the literature.
1. Introduction
Water is an essential part of our life on the earth and to sustain life every human being takes
several litters’ of water daily. All the aquatic life is dependent on water (Luo et al., 2014). With
increasing population day by day, the freshwater resources are decreasing quickly. Among
many reasons of decline in freshwater resources, polluting of water is one of them. Surface and
ground water are resources of fresh water and are vulnerable to contamination. There are
various ways to make toxic and impure water. One of them is wastewater flowing out through
industries. The industries like textile industries, ceramics industries, auto industries, leather
tanneries, oil refineries, paper industries, cosmetic industries are draining the wastewater in the
rivers, sea, canals that consist of many by-products and waste effluents (Deblonde, Cossu-
Leguille, & Hartemann, 2011). The industrial waste pollutants also accompanied by some
organic chemicals contain highly toxic organic byproducts, heavy metals, oils, and mineral
acids. This contaminated water which is polluted by toxic hydrocarbons compound, heavy
metals, toxic dyes, and metalloids is the main cause of polluting the surface as well as
groundwater. For removal of these toxic materials, different methods are adopted including
membrane filtration, electrodialysis, photocatalysis, adsorbent process, and nanomaterials
catalytic activities.
The contaminated water discharge through industries and factories are polluted and toxic to
our health as well as for agriculture and marine life. It is also the cause of irreversible
degradation of the atmosphere resulting in serious health problems (Deblonde et al., 2011). The
leather industries, fertilizers tanneries, oil refineries, textile, paper, rubber, and agrochemicals
etc. are producing wastewater that contains pollutants such as highly toxic synthetic organic
compound (O.C), oils, greases and mineral acids. These compounds are very dangerous and
injurious to all living organisms.
Lead (Pb) 0.06 Destruction of brain nerve, kidney, and nerve related
diseases
Mercury (Hg) 0.0003 A cause for kidney, circulatory, nervous problems
Overdose of heavy metals leads to hazardous and poisoned impacts on human beings. Within
limit these metals are suitable for human, the excessive and recess amount can also become the
cause of even the death of human (Jeong, Jeon, Jang, Choi, & Park, 2013). The symptoms to
the food web of man are peptide disarrangement, diarrhea, tremor, hemoglobinuria and many
other serious diseases as discussed below:
The agricultural uses of this wastewater that flow out through the rivers and canals toxins the
fertility of soil which leads the fresh water into an acidic solution that is to irrigate the fields
by the peasants. The highly poisoned metals are absorbed in soil and water and ultimately
injected into the grains during their development (Khulbe & Matsuura, 2018). As a result, when
the water is planted to crops most of the plants are dead and some of them go through the
growth process. These are deadly harmful to health and to pollute the environment. High blood
pressure, Anemia, Vomiting, Irritation, Gastric system, Immune system disorders, Blindness,
Headache. Nausea, Asthma like diseases are increasing day by day due to drinking the
wastewater and by taking the poison food.
3.2 Electrodialysis
Electrodialysis is another process in which current is passed through the solution to separate
the ion from the membrane. Membranes are the ionic solution comprising of the ion species.
When the current passes through the solution, the ions move to their irrespective electrodes.
Polyvinylflouride-membrane and perflourosulphonic-Nafon-117 membranes are used as
cations. When flow rate is increased, the separation rate decreased. At more than 500 ppm
concentration, separation is ceased. The Electrodialysis (ED) process was established in
chemistry to remove the toxic metals from solution. This process requires the precautionary
measurements like contaminated air avoidance, specific temperature, voltage and pressure
control.
3.3 Photocatalysis
In photocatalysis, the sunlight falls on the aqueous solution of the semiconductor. This light
energy is converted into the charged particle if the band-gap is less than the light energy. These
charges are removed by the semiconductor wafers like TiO2, ZnO, CdO, etc., responsible for
oxidation and reduction as shown in equation 3.4-3.6 as an example.
TiO2 + hv → iO2 + e-CB + h+VB (3.4)
TiO2 + OH- + h+ → TiO2 – OH· (3.5)
O2 + e-→ O2 (3.6)
The UV-light has to irradiate on the prepared solution to transform it into ionic solution and
then the redox reaction started (Hashmi et al., 2013).
The chromium reduction is possible by using the UV-radiation on titanium dioxide catalyst in
combination with Neodymium catalyst. The Nd ions that make a layer on the TiO2 surfaces act
like a layer deposited on the electrons. The separation of positive and negative charges
increases the oxidation-reduction reaction and the recombination reaction does not take place.
The electron acts like donor and chromium as an acceptor to the TiO2. Powder TiO2 limitation
is improved by the process of immobilization. The immobile process converts the toxic
chromium Cr(VI) to non-toxic chromium (III) under UV-characterization.
Carbon and oxide-based nano-particles have the capability to adsorb the heavy metals from the
aqueous solution. The carbon nanotubes (CNT’s) are the nano-range materials that are widely
used in different fields of life. To remove pollutants from the wastewater, the nanotechnology
is playing a vital role. The adsorption, redox, photo-catalyzation, and size exclusion process
are the widely used processes to remove the heavy metals ions from the solution. Size exclusion
is one of the processes used to remove the impurities in the form of filtration as discussed
before. The adsorption processes the nano-particles such as CNT’s, FeO3, charcoal, graphene,
MnO2, TiO2, ZnO2 are being used to remove the heavy metals. These particles are present in
the form of particles, tubes, powder etc. These nanomaterials are low cost and reliable particles
to eradicate the heavy metals (Borchers, Gray, & Thompson, 2013). Recent research has shown
that the nanomaterials as adsorbents are used in the purification of water. The polluted particles
that are characterized are Ni2+, Cr3+, Cr6+ Cu2+, Cd2+, Co2+, Hg2+, Pb2+, As3+, As2+, Th2+, Eu3+,
Sr2+, Zn2+ and U6+.
5. Conclusion
Herein, numerous sources of wastewater including industries, factories, mining and tanneries
in the form of organic compounds, heavy metals, dyes, and chemical textures have been
reviewed and discussed. The heavy metals like Pb, Zn, Cr, Hg etc. were found to be more
hazardous for human livings, aquatic system, wild animals, plants and crops. With the passage
of time, numerous techniques like filtration, electrolysis, electrodialysis were used to treat the
hazardous wastewater that contain heavy metals. However, high cost and low efficiency limited
their wide use. The photocatalysis, being a green approach, was observed to be the most
efficient and stable technique to completely degrade the heavy metals present in wastewater.
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