Assignment UNIT - 2

SOLUTIONS
Q-1 Calculate the mole fractions in a solution that is made up of 20.0 gm of ethyl
alcohol, C2H5OH, and 80.0 gm of water, H2O.

Q-2 A solution is 25% water, 25% ethanol and 50% acetic acid by mass. Calculate the
mole fraction of each component.

Q-3 A 12 M HCl solution contains 37% HCl by mass. What is the density of the
solution?

Q-4 A solution of glucose in water is labeled as 10% w/w, what would be the molality
and mole fraction of each component in the solution? If the density of solution is
1.2 g mL−1, then what shall be the molarity of the solution?

Q-5 The partial pressure of O2 in air is 0.20 bar. The solubility of O2 in water in
presence of air at 250C is 3.2 x 10-4 M. Calculate Henry’s constant.

Q-6 Heptane and octane form an ideal solution. At 373 K, the vapour pressures of the
two liquid components are 105.2 k Pa and 46.8 k Pa respectively. What will be
the vapour pressure of a mixture of 26.0 g of heptane and 35 g of octane?

Q-7 A 5% solution (by mass) of cane sugar in water has freezing point of 271 K.
Calculate the freezing point of 5% glucose in water if freezing point of pure water
is 273.15 K.

Q-8 19.5 g of CH2FCOOH is dissolved in 500 g of water. The depression in the freezing
point of water observed is 1.0°C. Calculate the van’t Hoff factor and dissociation
constant of fluoroacetic acid.

Q-9 2.0 gm of benzoic acid dissolved in 25.0 gm of benzene shows a depression in

freezing point equal to 1.62 K. Molal depression constant (Kf) for benzene is 4.9 k
kg mol-1. What is the percentage association of the acid?

Q-10 The degree of dissociation of Ca(NO3)2 in a dilute solution containing 7.0 gm of

the salt per 100 gm of water at 1000C is 70%. If the vapour pressure of water at
1000C is 760 mm. calculate the vapour pressure of the solution.

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AjmalHasan
XII A, B & C
DPS, Indira Nagar,Lko

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