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TERMINOLOGIES :
Colligative property
Ideal solutions
Azeotrope
Ebullioscopic constant
Cryoscopic constant
Abnormal molar mass
Reverse osmosis
Entry questions
1. Differentiate between molarity and molality of a solution.
2. Find the mole fraction of NaOH if 20 gm of it is dissolved in 100gm of water.
3. Why is the boiling point of a liquid higher at higher altitude ?
4. If solubility product of CuS is 6x10-16 ,find the maximum molarity of CuS in aqueous
solution.
Topic: S1 S2 S3 S4
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Differentiated questions based on concepts:
Level 1
1. Which of these concentration terms are independent of temperature changes.Give reason in support
of your answer. (Molarity,molality , molefraction , parts per million )
2. A sample of drinking water is contaminated with 15 ppm (by mass) of Chloroform. Express this value
in percentage by mass. Also determine the molality of the solution.
3. Boiling point of sea water is always found to exceed 100 C. Why ?
4.a State the Henry’s law and give its equation.
b. In a saturated solution ,.5 x10 -2 gm of ethane exerts a partial pressure of 2.5 bar.Find the Henry’s
constant for the gas.
LEVEL -1
TEACHER APPRAISAL:
Level -2
1. Explain graphically how the addition of ethanol to water results in a non ideal solution.
2. The following graph of vapour pressure versus freezing point temperature was obtained when sodium
chloride was dissolved in water.
b. Explain why the graph shifts to the left in the above case.
c. Based on the above explanation account for the use of ethylene glycol in car radiators in winter.
3.
a. Explain osmotic pressure based on the above figure. Account for the fact that equimolar solutions of
KCl and glucose will not exhibit the same osmotic pressure
c.Find the osmotic pressure of a solution containing 25mg of potassium sulphate in 2 litres of water
assuming complete dissociation .
TEACHER APPRAISAL:
LEVEL-3
1. From the solubility graph given above for three gases X,Y and Z, predict the gas with highest value of
Henry’s constant .Explain your choice of answer.
2.Vant Hoff factor for 0.01 M acetic acid is 1.04.Find the pH of the solution.
3. Beaker A contains1.22gm of benzoic acid dissolved separately in 100 gm of acetone ( Kb for acetone
is 1.7) and the elevation in b.p was found to be 0.17 K. Beaker B contains1.22gm of benzoic acid
dissolved in 100 gm of benzene (Kb for Benzene is 2.6) and the elevation in b.p was found to be 0.13 K.
b. From the masses calculate,what do you deduce about the structure of benzoic acid in the two
solvents?
4. When 1 gm of a compound AB2 is dissolved in 25gm of benzene , ΔTf value is 1.60C ,whereas when
when 1 gm of a compound AB3 is dissolved in 25gm of benzene, the ΔTf value is 1.250C. If Kf for benzene
is 5.1,find the atomic masses of A and B.
TEACHER APPRAISAL:
EXIT QUESTIONS
1. What happens to the molarity of a solution when it is heated from 25 to 50oC.
3.It is impossible to separate the constituents of a 95.5% (by mass) solution of ethanol and water .
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