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Efficient Implementation of the Normal Boundary Intersection (NBI) Method on


Multiobjective Optimization Problems

Article  in  Industrial & Engineering Chemistry Research · December 2000


DOI: 10.1021/ie000400v

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648 Ind. Eng. Chem. Res. 2001, 40, 648-655

Efficient Implementation of the Normal Boundary Intersection


(NBI) Method on Multiobjective Optimization Problems

Young Il Lim, Pascal Floquet, and Xavier Joulia*


Laboratoire de Génie Chimique (LGC, UMR-CNRS 5503), INPT-ENSIGC, 18 chemin de la loge,
F-31078 Toulouse Cedex 4, France

This study attempts to address efficient implementation of the normal boundary intersection
(NBI) method for the tradeoff between economics and pollution prevention with appropriate
analysis methods. For the multiobjective optimization problem (MOOP), a noninferior solution
curve (or Pareto curve) is efficiently obtained by using an enhanced NBI method combined with
the SWOF (summation of weighted objective functions) method within a chemical process
simulator. Then, the Pareto curve is analyzed by the ideal compromise solution set, sensitivity
and elasticity analyses that give the decision basis between the conflicting objectives to the
decision maker. Through the combined use of the SWOF and NBI methods, the upper and lower
values of the ideal compromise set are exactly located. The total calculation time for the entire
Pareto curve can be reduced owing to evenly distributed Pareto points.

1. Introduction tigation (PSI).5 However, it is difficult for these MOOP


algorithms to locate an ideal compromise solution at the
During the early phases of designing a chemical norm p ) ∞ (δ∞) without Pareto curve fitting. These
process, many important decision variables should be algorithms are not clearly applicable to general cases,
based on all available information, including chemical, in particular, for obtaining Pareto points in nonconvex
technological, and economic knowledge, as well as regions.
knowledge about the environmental and health aspects. In this study, a new multiobjective optimization tool
To meet these various aims at once, multiobjective called NBI (normal boundary intersection)7 is considered
approaches are very often required to make decisions for chemical process optimization problems, extending
in process simulation and optimization problems. In the study of Lim et al. (1999). In the next section, we
engineering applications of the multiobjective optimiza- present an algorithm that can form and handle system-
tion problem (MOOP), the desired result helpful in atically the noninferior solution curve (Pareto curve) for
facilitating design is a whole collection of Pareto optimal tradeoff between the conflicting objectives within the
points, representative of the entire spectrum of nonin- chemical process simulator. Then, three MOOP methods
ferior solutions. In this context, evenly distributed (SWOF, GP, and NBI) are compared within two small
Pareto points are essential for knowledge of the entire biobjective problems. The optimization result of the
spectrum of the Pareto curve. MEK (methyl ethyl ketone) production process is also
To obtain Pareto points (solutions of the MOOP), the illustrated in the third section.
multiobjective problem is generally converted to a
parametric single-objective problem. Thus, it is very
important to efficiently select parameters so that Pareto 2. Multiobjective Optimization Programming
points are uniformly distributed even in the non- (MOOP)
convex feature of the Pareto curve. Efficient parameter
selection in the MOOP algorithm not only gives a 2-1. MOOP Based on NBI. For a multiobjective
reliable MOOP solution but also reduces total optimiza- optimization whose solution is a set of optimization
tion time. results called “Pareto points” or “noninferior solution
Ciric and Huchette (1993)1 presented a multiobjective points”, one of the most popular methods is to minimize
approach based on the SWOF (summation of weighted a convex combination of objectives and thus to convert
objective functions) method to process synthesis and the multiobjective problem into a parametric single-
optimization problems where profitability conflicts with objective problem. For the case of two objective functions
waste reduction. Parameters (weighting factors) were
selected by the SAM (sequential approximation method). min {u(f1, f2, R) ) Rf2+(1 - R)f1} (1)
For assessment of the global environmental impact and x∈Ω
profit in a chemical process, biobjective optimization was
carried out by Lim et al. (1999),2 using multiobjective where 0.0 e R e 1.0 and the utility function, u(f1, f2, R),
optimization techniques such as the SWOF method,1 is linearly combined with the objective functions
goal programming (GP),3,4 and parameter space inves- (fi) and the parametric weighting factors (R) under the
constraint set (Ω). This SWOF (summation of
* To whom correspondence should be addressed. E-mail: weighted objective functions) method suffers from
Xavier.Joulia@ensigct.fr. Phone: +33 5 6225 2355. Fax: +33 two major drawbacks: nonuniform spread of Pareto
5 6225 2318. points with respect to uniform weighting parameters
10.1021/ie000400v CCC: $20.00 © 2001 American Chemical Society
Published on Web 12/28/2000
Ind. Eng. Chem. Res., Vol. 40, No. 2, 2001 649

For more evenly distributed Pareto points, a sequen-


tial procedure of the NBI method is performed after a
Pareto point at β ) 0.5 in eq 2 is obtained. Once the
Pareto point (f̂1, f̂2) ) (µ, µ) at β ) 0.5 is located, normal
directions emanating from the slope (s1) of QB and the
slope (s2) of PB can intersect the Pareto curve more
evenly than they would through the original NBI
method.7 Accordingly, new constraints substituting for
eq 2 are formed in the case of n ) 10 for the upper (from
QB) and lower (from PB) parts of the Pareto curve. For
the upper part of the Pareto curve:

(f̂2)up ) -() (
1 1
)
f̂ + s1 + (βi)up + 1, (βi)up ) i
s1 1 s1
µ
10
,( )
1 e i e 9 (4)

and for the lower part:

(
(f̂2)down ) -s1f̂1 + s1 +
1
)
s1 i
1
(β )down - ,
s1
Figure 1. Pareto point B obtained by the NBI method and Pareto
point A obtained by the SWOF method in the normalized objective
(βi)down ) i( )
1-µ
10
+ µ, 1 e i e 9 (5)
space.
where µ corresponds to the f̂1 value at point B, as shown
in Figure 1. Here, two simple relations are introduced
and lack of information about nonconvex parts of the
such that s2 ) 1/s1 and s1 ) (µ - 1)/µ, because the two
Pareto set.7
objective functions are normalized between zero and
The NBI method is a technique motivated by a one. The modified NBI method is also efficient for
geometrical intuition to provide a better parametriza- locating more uniformly distributed Pareto points (non-
tion of the Pareto set than that provided by other inferior solution points) than the SWOF and the GP
techniques. This parametrization is better in the sense methods. Hence, reliable sensitivity (∂f2/∂f1) and elastic
that the points obtained by using the NBI method rate (∂ ln f2/∂ ln f1) can be approximated from the
produce a more even coverage of the Pareto curve and optimization results without Pareto curve fitting. For
this coverage does not miss the interesting middle part every Pareto optimal point, there exists a corresponding
of the Pareto curve. The goal programming method NBI subproblem of which it is the solution. Most NBI
constrains a parametrized value of objective functions points are guaranteed to be only locally Pareto optimal
other than the main objective function, and the SWOF points even though the Pareto curve is nonconvex.7
method uses slope values [(R - 1)/R] to obtain a set of
optimum results. In contrast, the NBI method finds The Pareto curve is analyzed by two ideal compromise
intersection points of the Pareto curve with normal points at δ1 and δ∞, for sensitivity and elasticity
directions toward the origin, emanating from any points analyses for the basis of decision-making, as mentioned
in the study of Lim et al. (1999).2 It is worth emphasiz-
of the segment PQ that connects two respective opti- ing that the Pareto points of δ1 and δ∞ will provide the
mization points (P and Q), as shown in Figure 1. In the lower and upper bounds of the ideal compromise solu-
original NBI method, an equality constraint containing tions,10 if these exist.
one parameter (β) is added to the optimization problem
2-2. Implementation of the MOOP Algorithm
(Das and Dennis, 1998).7 In the case of a biobjective
within a Chemical Process Simulator. The MOOP
problem, employing the normalization of two objective
functions (see Appendix A), approach is achieved by substituting the MOOP module
for the optimization module in the process simulator.
Figure 2 shows the MOOP algorithm using the SQP
min f̂2 optimization solver.11 The objective functions are first
x∈Ω
normalized by the SWOF method with the weighting
s.t. f̂2 ) f̂1 + (1 - 2β), 0 e β e 1.0 (2) parameters R ) 0.0 and R ) 1.0. Then, if possible, the
SWOF method at R ) 0.5 is performed to search for an
the parameter β normally is a value of f̂1 determined ideal compromise solution of δ1. In the case of β ) 0.5
by the number (n) of wanted Pareto points, as follows: in the NBI method, another ideal compromise point of
δ∞ is found. Depending on the parameters (β) of the
modified NBI method using eqs 4 and 5, Pareto points
βi ) i/n, i ) 0, 1, 2, ..., n (3)
are found to obtain the entire Pareto curve. Finally, one
can make a tradeoff between the conflicting
A problem at β0 ) 0.0 corresponds to minimization of objectives in order to understand the process charac-
f̂1 without consideration of f̂2. At βn ) 1.0, it is equivalent teristics and to determine new operating conditions
to the problem of R ) 1 in the SWOF method. When through Pareto curve analysis using ideal compromise
βn/2 ) 0.5, an ideal compromise point at norm δ∞ is solutions as well as the sensitivity and elasticity of the
obtained, i.e., f̂1 ) f̂2 ≡ µ. Pareto curve.
650 Ind. Eng. Chem. Res., Vol. 40, No. 2, 2001

Figure 2. MOOP algorithm in the process simulator.

Figure 3. Comparison of the three MOOP methods at even parameter spread in the small biobjective problem.

3. Case Studies points is measured as a standard deviation of the Pareto

3-1. A Biobjective Problem for a Convex Pareto


point arc lengths (∆si ) x(∆f̂1)2i +(∆f̂2)2i )

x∑
Curve. The test example is n
1
(sj - ∆si)2

[ ]
η) (7)
n
x21
f1(x) ) + + + +x22 x23 x24 x25 i)1

min x3 3
(6) where sj denotes the mean arc length. Thus, as the
x f2(x) ) 3x1 + 2x2 - + 0.001(x4 - x5) equidistribution index approaches zero, the points ob-
3
tained are more uniformly distributed for the same
s.t. x1 + 2x2 - x3 - 0.5x4 + x5 - 2.0 ) 0.0 number of parameters (R, , and β for the SWOF, GP,
and NBI methods, respectively). Using an even spread
4x1 - 2x2 + 0.8x3 + 0.6x4 + 0.5x25 ) 0.0 of parameters (with 21 points at 0.05 step size, 0.0 e R,
, or β e 1.0), three Pareto curves are shown in Figure
x21 + x22 + x23 + x24 + x25 - 10.0 e 0.0 3. Note that Pareto points obtained by the SWOF
method in this example are clustered near the minimum
point of f1, and the middle part for the ideal compromise
First of all, the three methods such as SWOF, GP and zone is not well captured. In contrast, the GP method
the original NBI are compared by their numerical provides poor information in the steep regions of the
results for this biobjective problem. For the solution Pareto curve. Employing the NBI method with even
quality, a positive equidistribution index (η) of Pareto spread of parameters, more uniformly distributed Pare-
Ind. Eng. Chem. Res., Vol. 40, No. 2, 2001 651

method, it is impossible to obtain Pareto points. In


Figure 6, even though the Pareto curve is nonconvex
(or one objective function is nonconvex), Pareto points
are captured using the GP and the original/modified
NBI methods with 21 uniform parameters.
The equidistribution indexes (η) are 0.0344, 0.0046,
and 0.0024 for the GP, original NBI, and modified NBI
(this study) methods, respectively. Therefore, the results
of the modified NBI method are more evenly distributed
than those of the original NBI method. Figure 7 shows
objective function values (f1 and f2) with respect to
sensitivity (df2/df1) of the Pareto curves obtained by the
three methods. Whereas the GP method gives an
insufficient resolution in certain regions, the two NBI
methods give reliable solutions in any regions. The
modified NBI method shows results superior to those
of the original NBI method in the region of high
variation of the Pareto curve.
Figure 4. Pareto points obtained by the modified NBI method 3-3. MEK Process with 100% Recycle of the
within the normalized objective space. Waste SBA Stream. MEK is predominantly produced
by the dehydration of SBA (sec-butyl alcohol or 2-bu-
to points are assured. The equidistribution indexes (η) tanol), which is carried out in a vapor-phase isothermal
are 0.1219, 0.0269, and 0.0038 for the SWOF, GP, and reaction over an air-oxidized brass catalyst (composition
NBI methods, respectively. ) 60% Cu + 40% Zn) at temperatures of ∼500-700K
Using the proposed MOOP algorithm, 22 Pareto under a pressure slightly above atmospheric.
points are plotted in Figure 4 within the normalized
sec-C4H9OH f CH3COC2H5 + H2 (9)
objective space. Two black square points found by the
SWOF method (R ) 0.5) and the NBI method (β ) 0.5)
are upper and lower values of the ideal compromise In the interesting temperature zone (∼623.15-
solution set at δ1 and δ∞, respectively. The modified NBI 673.15K), the catalytic reaction rate (rA, kmol/h)13 is
method enhances a little equidistribution as η ) 0.0021
due to parametrization of the two parts. The values of
sensitivity and elastic rate shown in Figure 5, which (
C PA -
K )
PKPH

( )
are obtained directly from optimization results without rA ) S (10)
PA
Pareto curve fitting, are reliable because of the evenly PK 1 + KAPA + KAK
distributed Pareto points. PK
3-2. A Biobjective Problem for a Nonconvex
Pareto Curve. A nonconvex biobjective problem pre- The notation is explained in the nomenclature, and the
sented by Li et al. (1999)12 is described as constants such as C, K, KA, and KAK are calculated from

[ ]
the relation equations with the reaction temperature,
f1 ) 1 - x1x2 which were developed by Perona and Thodos (1957).13
min 1 (8) The catalyst surface area (S) is assumed to be equal to
x f2 ) 3(2x1 + x2) 2500 m2.
In Figure 8, the MEK process flowsheet2,8,14 is shown.
s.t. 0.0 e x1, x2 e 1.0 The SBA feed containing 0.1 mol % water is mixed at a
fixed feedrate (45.8128 kmol/h at 15 °C and 1 atm) with
It is easy to verify that this example problem is a recycle stream from the purification column. The
nonconvex because the Hessian matrix of the objective combined liquid stream is fed to a hydrogen scrubber
function f1 is negative definite. Applying the SWOF where the SBA scrubs residual MEK from the hydrogen

Figure 5. Sensitivity and elasticity analyses of the Pareto curve in the small biobjective problem.
652 Ind. Eng. Chem. Res., Vol. 40, No. 2, 2001

Figure 6. Comparison of the three MOOP methods in the case of the nonconvex Pareto curve.

(H2O and H2) are considered to be nonpollutants.14 The


impact of fugitive emissions is also ignored. In sum-
mary:
(a) Objective functions
Minimize f1(Imp kmol-1 SBA-1) ) [(three effluent
flowrates of SBA) × 92.09 + (two effluent flowrates
of MEK) × 2361.17]/(SBA feed)
Minimize f2($ kmol-1 SBA-1) ) [(cooling water heat
duty) × 2.512 × 10-6 + (compressing power) × 0.135
+ (steam heat duty) × 3.1694 × 10-5 + (SBA feed) ×
0.095 - (MEK product) × 1.014]/(SBA feed)
(b) Independent decision variables
Dehydration column reflux ratio [(reflux flowrate)/
(vapor distillate)]: 40.0 e R1 e 80.0
Purification column reflux ratio ([(reflux flowrate)/
(liquid distillate)]: 2.0 e R2 e 10.0
Ratio of liquid distillate to input feed in purification
column [(liquid distillate)/(input feed)]: 0.550 e RLD
e 0.950
Figure 7. Sensitivity analysis of the Pareto curve according to Reaction temperature (K): 623.15 e TR e 673.15
the MOOP methods in a nonconvex case.
(c) Constraints
MEK product molar fraction: xMEK g 0.9900
byproduct stream subject to the maximum MEK flow- MEK flowrate in H2 exit stream: FMEK e 1.0 kmol/h
rate of 1.0 kmol/h. The SBA feed is then pumped up to Molar ratio of removing H2O to input H2O in dehy-
the reaction pressure and heated to the reaction tem- dration column: Rwater g 0.9900
perature via a heat exchanger. Once at the reaction Note that the severe product purity of 0.99 mol % is
temperature, the highly endothermic reaction takes employed in this problem and this constraint is almost
place in the isothermal catalytic reactor. The mixture active over the optimization procedures. The process is
of MEK, H2 and unconverted SBA is cooled further and simulated and optimized using the process simulator
then sent to a separator where the hydrogen is flashed ProSim, which simultaneously performs simulation of
off. Hydrogen is further scrubbed, and the liquid phase flowsheet and optimization of design variables. A par-
of the separator is fed to a dehydration column where ticular thermodynamic model (MHV2 model)15 is used
water over 99 mol % of feedwater into the column is for the water-hydrocarbon system. The simulation time
removed as the phase of H2O-MEK azeotrope. MEK of is 2.2s at the nominal value of decision variables on a
at least 99 mol % purity is produced as the top product bi-processor Digital Alpha server 4000 in double preci-
of the purification column. The bottom product is sion. According to the objective functions, the optimiza-
completely recycled. tion time varies from 20 to 130 s (average 61.8 s).
Twenty-two Pareto points, 19 points by the modified
For convenience, the SBA feed flowrate is fixed and NBI method, and three points by the SWOF method,
the objective functions of the SBA feed basis are used. are obtained at a convergence tolerance (KTE) of 1.0 ×
The simplified cost-benefit function (f2, $/kmol-SBA) is 10-5 and a proportional numerical perturbation of 1.0
calculated by using the following costs: cooling water, × 10-4, as shown in Figure 9. Two ideal compromise
2.512 × 10-6 $/kcal; compressing power, 0.135 $ kW-1 solutions (points A and B) are identified by the SWOF
h-1; heating steam, 3.1694 × 10-5 $/kcal; and raw method at R ) 0.50 and by the NBI method at β ) 0.50.
material, 0.095 $/kg. The sale price for MEK is taken As mentioned above, the Pareto points obtained by NBI
to be 1.014 $/kg based on 1996 prices. With three output are evenly distributed on the Pareto curve, which seems
streams indicated in Figure 5, the pollution function, to be nonconvex in the upper part. In fact, this biobjec-
Φp,8,14 is calculated only about SBA (ψi ) 100 × 0.9209 tive problem shows a nonconvex feature on the Pareto
Imp/kmol) and MEK (ψi ) 100 × 23.6117 Imp/kmol) curve because of the active constraints, the nonlinear
except for the MEK product, as the other components reaction rate, and the complex thermodynamics such
Ind. Eng. Chem. Res., Vol. 40, No. 2, 2001 653

Figure 8. Flowsheet of the MEK process with 100% recycle.

The characteristic value (γ, $/Imp) is

(
fU
)
L
2 - f 2
γ) ) (56.525 - 52.138)/(71.446 -
fU L
1 - f 1
57.397) ) 0.31225 (11)

With the characteristic value, the sensitivity curve (û


vs ∂f2/∂f1) and the elasticity curve (û vs ∂ ln f2/∂ ln f1)
can be derived from the optimization results, as shown
in Figure 11. Point A is located at the marginal cost )
-0.31225; in other words, $0.31225 of the cost is
consumed by decreasing the pollution impact by one
unit. Also, point B can be found at the same value of
the two normalized objective functions, which is the
maximum point of the utility function (ûmax ) 0.3616).
The nonconvex feature of the Pareto curve is more
clearly shown as zigzag forms of the objective functions
in Figure 11.
In the elasticity curve of Figure 11, the elasticity [(∂f2/
∂f1) (f1/f2)] is positive because we let the cost-benefit
Figure 9. Pareto points and two ideal compromise points (A and function be negative and the marginal cost is always
B) in the normalized objective space.
negative. However, intrinsically, this implies opposing
action between the two objective functions.
as are found in an azeotropic system. In the nonconvex Suppose that a decision-maker wants to operate this
parts, we can see abrupt changes of the dehydration process within an ideal compromise solution zone. In
column reflux ratio (R1), which is a very sensible other words, this process would be operated at a point
independent variable to the objective functions in between points A (R ) 0.50 in the SWOF method) and
certain regions, as shown in Figure 10. Slight perturba- B (β ) 0.5 in the NBI method). In Table 1, the ideal
tions of the other variables are also found in the compromise solutions are compared with nominal points
nonconvex parts. of the decision variables, minimum points of the pollu-
654 Ind. Eng. Chem. Res., Vol. 40, No. 2, 2001

Figure 10. Profiles of four independent variables with respect to the pollution function values. (a) Dehydration column reflux ratio (R1).
(b) Purification column reflux ratio (R2). (c) Ratio of liquid distillate (RLD). (d) Reaction temperature.

Table 1. Operating Conditions by the MOOP Approach in the MEK Process


optimum values
decision lower upper nominal Pareto point Pareto point
variables value value value min f1 min f2 at δ1 at δ∞
1. reflux ratio R1 40.0 80.0 60.0 80.0 40.00 40.00 40.14
(RF/VD)
2. reflux ratio R2 2.0 10.0 5.0 10.0 2.813 5.776 5.990
(RF/LD)
3. liquid distillate ratio 0.550 0.950 0.820 0.6718 0.9383 0.8268 0.8155
RLD (LD/Feed)
4. reaction temperature 623.2 673.2 648.2 623.2 673.2 640.9 639.1
TR (K)
f1 (Imp/kmol-SBA) 92.951 57.397 71.446 62.979 62.442
objective f̂1 2.5307 0.000 1.000 0.3973 0.3629
functions
(f1 and f2) f2 ($/kmol-SBA) -54.938 -52.138 -56.525 -55.085 -54.969
f̂2 0.3715 1.000 0.000 0.3282 0.3631

It is pointed out that the new operating conditions


between the ideal compromise solution points are an
advanced level for the decision-maker to simultaneously
satisfy increases in profit and reductions in pollution.

4. Conclusions
Within a chemical process simulator, a new MOOP
algorithm (normalization, the combined use of SWOF
and NBI, and finally Pareto curve analysis) is employed
in terms of economics and potential environmental
impact through the MEK process. The modified NBI
method gives evenly distributed Pareto points and
reliable optimization results even in a nonconvex feature
of the Pareto curve.
Decision information for making a tradeoff between
profitability and pollution is obtained by performing
sensitivity and elasticity analyses of the Pareto curve.
Figure 11. Sensitivity and elasticity analyses of the Pareto curve. It is worth noting that the sensitivity of the Pareto curve
tion function (R ) 0.0), and traditional operating condi- is a marginal cost, that is, the cost change over a unit
tions of the minimum cost-benefit function (R ) 1.0). change of environmental impact. The elasticity of the
Ind. Eng. Chem. Res., Vol. 40, No. 2, 2001 655

Pareto curve means the ratio of cost change rates to a The point (f L1 , f L2 ) can be defined in the objective
unit rate of the environmental impact change. space as the utopia point. The utopia point (or shadow
The ideal compromise solution set between δ1 and δ∞ minimum) will generally be infeasible because it will
on the Pareto curve is thought of as a mild condition to lie outside the attainable objectives (Λ, inside the
simultaneously satisfy two objectives. The proposed noninferior solution curve) given by
MOOP algorithm has exactly identified its upper and
lower values. Λ ) {(f1, f2) |x ∈ Ω}
Acknowledgment
Also, the following normalization can be employed:
We thank the Ministry of Foreign Affairs of France
and the Embassy of France in Korea, which support our (f1 - f L1 ) (f2 - f L2 )
research in the framework of France-Korea collabora- f̂1 ) , f̂ 2 )
tion. fU1 - f 1
L
fU2 - f 2
L

Nomenclature where f̂1 and f̂2 represent the normalized objective


A ) Point at norm p ) 1 functions, and explicitly
B ) Point at norm p ) ∞
C ) Kinetic constant in rate equation (kmol h-1 m-2) 0 e f̂1 e 1, 0 e f̂2 e 1
fi ) Objective function i
K ) Chemical equilibrium constant (atm)
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min f1(x) ) f 1 and at this optimum point, f2 ) f 2
x∈Ω Received for review April 11, 2000
L U Accepted October 19, 2000
min f2(x) ) f 2 and at this optimum point, f1 ) f 1
x∈Ω IE000400V

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