CHEMISTRY 2018 M S PIEAS

1) Elementary bimolecular give which order of reaction?

1 2 3 4
2) Which of the following will not give NMR signal?
32 9 12
S F C
3) How many tons of Cu2O will require to produce 500 tons of Cu?
4) Oil in water is an example of type of polymerization?
Suspension solution bulk
5) Bakelite is example of polymer?
Condensaton addition
6) NaCl + AgNO3 AgCl + NaNO3 reaction is?
Precipitation addition
7) Valume occupied by 7.4g 0f NH3 is ?
8) Antacid is titrated with HCl whose Molarity is 0.2M and valume used is 34.5ml.Antacid
amount dissolved is 0.5g then its %age purity?
9) Determine oxidation satae of P in H3PO4 ?
10) The least polyene is
1 2 3 4
11) Four polyenes were analyzed usin UV visible spectroscopy ,They will absorb which
light?
Blue indigo yellow violet
12) Most favorable overlap order is
Sp3 >Sp>Sp2>p Sp3 >Sp2>Sp>p
13) Ordre of leaving group
TsO- >
14) Four compounds are given arrange them according to their B.P?
CH3CH2F CH3COH CH3CH2OH CH3CH2CH3
Arrange them
15) 2,2,3-trimeethyl-3-ethylpentane is isomeric to
Decane nonane heptane octane
16) Which will not be peak observed in MS of CH3Cl?
15 35 35.5 37
17) No. of molecules in 10g of CO2 ?
18) If reaction is exothermic and takes place with decrease in Valume then increase in
temperaure will shift the equilibrium to ?
Left right
19) One side of reaction was given and you have to determine other side using balanced
chemical reaction?
20) Molarity of NH3 was given along with its Kb and you have to find OH- ion concentration?
NH3 + H2O NH4+ + OH-
21) Metals on reaction with water and their oxides are
Basic in nature and hydroxides
22) Which of folllowing will not act as oxidizing agent?
Cl2 Na+
23) Allylic and benzylic hydrogens are reactive due to which effect?
Inductive resonance
24) Order of size ?
Fe4+<Fe3+<Fe2+
25) One complete reaction was given and you have to determine type of reaction?
26) Cordination number of Na and Cl in NaCl?
6 8 10
27) Change in entropy of …….g of water at 0 degree centigrade?
28) Formula of potassium fericyanide?
29) Bond order of He2+
1 ½ 3
30) Which one can possibly exist ?
31) He2 Be2 C2
32) Which of them is thermodynamically more stable?
Methyne carbene methane all
+ -
33) Molarity of H is 0.0002M find OH ion concentration ?
34) A radioactive element becomes stable after radioactive decay then which is true?
Equal no of protons and neutron
Equal no of proton and electron
Greater no of neutron than proton
Greater no of protons than neutron
35) Molar absorbitivity<10 then transition is
Forbidden allowed weakly allowed
36) How many g of anhydrous HCl is present in ml of 27% dwnsity was also given?
37) Which of them will be more stable
Resonace Hybrid form
38) Which of followings has more polarizing effect?
Greater size graeter polarizeablity
39) Which of following is not suitable catalyst for friedal craft reaction?
H3PO4 H2SO4