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alterations to the
hydrological cycle.
An emerging water quality concern is the impact of personal care products and
pharmaceuticals, such as birth control pills, painkillers and antibiotics, on aquatic
ecosystems. Little is known about their long-term human or ecosystem impacts, although
some are believed to mimic natural hormones in humans and other species.Poor water
quality has a direct impact on water quantity in a number of ways. Polluted water that
cannot be used for drinking, bathing, industry or agriculture effectively reduces the amount
of useable water within a given area.
1. The “designated uses” of the state’s waters, such as public water supply,
recreation, propagation of aquatic life and wildlife, or navigation;
2. “Criteria” specifying the amounts of various pollutants, in either
numeric or narrative form, that may be present in those waters without
impairing the designated uses (note - criteria include any one or more
of three components: magnitude, duration, and frequency); and,
3. Anti-degradation requirements providing for protection of existing water uses and
limitations on degradation of high quality waters.
enhancement of the water quality, and as basis for taking positive action in preventing,
controlling or abating water pollution.
Water quality in a body of water influences the way in which communities use the
water for activities such as drinking, swimming or commercial purposes. More specifically,
the water may be used by the community for:
criteria are set at the minimum acceptable concentration to ensure the maintenance of
biological functions.
Water quality standards are important because they help to address and solve many
types of water quality problems. Standards help to monitor and assess water quality
problems stemming from improperly treated wastewater discharges, runoff or discharges
from active or abandoned mining sites, sediment, fertilizers, and chemicals from
agricultural areas, and erosion of streambanks caused by improper grazing practices.
Water quality standards are used to:
A. Minimum Guidelines for Surface Waters. All surface waters of the country shall be
free from:
1. Domestic, industrial, agricultural, or other man-induced non-thermalcomponents of
discharges which, alone or in combination with othersubstances or in combination
with other components of discharges (whetherthermal or non-thermal)
i. That settle to form putrescent deposits or otherwise create a nuisance;or
ii. That float as debris, scum, oil, or other matter in such amounts as toform
nuisances; or
iii. That produce color, odor, taste, turbidity, or other conditions in suchdegree as to
create a nuisance; or
iv. That are acutely toxic; or
v. That are present in concentrations which are carcinogenic, mutagenic,or
teratogenic to human beings or to significant, locally occurringwildlife or aquatic
species; or
vi. That pose a serious danger to the public health, safety or welfare.
(d) - The allowable temperature increase over the average ambient temperature for each
month. This rise shall be based on the average of the maximum daily temperature readings
recorded at the site but upstream of the mixing zone over a period of one (1) month.
(e) - Sampling taken between 9:00 AM and 4:00 PM
(f) - Not more than 30% increase
(g) - Not more than 30 mg/L increase
(h) - Not more than 60 mg/L increase
(i) - Do not apply if natural background is higher in concentration. The latter will prevail
and will be used as baseline
(j) - Applicable only to lakes or reservoirs, and similarly impounded water
(k) - When applied to lakes or reservoirs, the Phosphate as P concentration should not
exceed an average of 0.05 mg/L nor a maximum of 0.1 mg/L
(l) - Not present in concentrations to affect fish flavor/taste
(m) - These values refer to the geometric mean of the most probable number of coliform
organism during a 3-month period and that the limit indicated shall not be exceeded in 20
percent of the samples taken during the same period
(n) - For spawning areas for Chanoschanos and other similar species
(o) - Limit is in terms of dissolved copper
nil - Extremely low concentration and not detectable by existing equipment
--- - Means the standard of these substances are not considered necessary for the present
time, considering the stage of the country's development and DENR capabilities, equipment
and resources.
nr - Means No Recommendation made
2. Toxic and other Deleterious Substances. The maximum limits for thesetypes of
pollutants according to classifications or use of the receiving body of water are
found in Table 4.
Table 4. Water Quality Criteria for Toxic and Other Deleterious Substances for Fresh
Waters (For the Protection of Public Health)
Table 5. Water Quality Guidelines for Conventional and Other Pollutants Affecting
Aesthetics and Exerting Oxygen Demand for Coastal and Marine Waters.
Extract)
Phenolic Substances as Phenols mg/L nil 0.01 (1) -
MPN/
Total Coliforms 70(m) 1,000(m) 5,000(m) -
100 mL
MPN/
Fecal Coliforms nil 200(m) - -
100 mL
Copper mg/L - 0.02(n)(o) 0.05 (o) -
2. Toxic and Other Deleterious Substances. The maximum limits for toxic andother
deleterious substances for waters classified as Class SA, SB, SC and SD waters are
found in Table 6.
Table 6. Water Quality Guidelines for Toxic and Other Deleterious Substances for
Coastal and Marine Waters (for the Protection of Public Health)
CLASS
PARAMETER UNIT CLASS SA CLASS SB CLASS SD
SC
Arsenic (i) mg/L 0.05 0.05 0.05 -
Cadmium (i) mg/L 0.01 0.01 0.01 -
Chromium (i) (hexavalent) mg/L 0.05 0.1 0.1 -
Cyanide mg/L 0.05 0.05 0.05 -
Lead (i) mg/L 0.05 0.05 0.05 -
Total Mercury (i) mg/L 0.002 0.002 0.002 -
Organophosphate mg/L nil nil nil -
Aldrin mg/L 0.001 - - -
DDT mg/L 0.05 - - -
Dieldrin mg/L 0.001 - - -
Heptachlor mg/L nil - - -
Lindane mg/L 0.004
Toxaphane mg/L 0.005 - - -
Methoxychlor mg/L 0.10 - - -
Methods of Analysis
For purposes of these regulations, any water sample taken for the purpose of
classification or for determining compliance with the water quality criteria shall be
analyzed in accordance with the methods enumerated in Table 8. The table also applies to
determine compliance to effluent regulations.
Coliforms
BOD5, COD, Suspended Solids, pH, Oil & Grease,
J. MEAT, FISH AND FRUIT CANNING
Dissolved Solids
BOD5, pH, Suspended Solids, Settleable Solids, Oil and
K. MEAT PRODUCTS INDUSTRY
Grease, Total Coliforms, Toxic Materials
Oil and Grease, Heavy Metals (Cr, Cd, etc.). Suspended
L. METAL FINISHING INDUSTRY
Solids, Cyanide
M. MINERAL ORE PROCESSING (Mining Suspended Solids, Heavy Metals (Hg, Cn, Cd, etc.),
Industry) Arsenic
BOD5, COD, pH, Total Suspended Solids, Total
N. ORGANIC CHEMICALS INDUSTRY
Dissolved Solids, Oil (Free-Floating)
INDUSTRY BOD5, Heavy Metals, COD, Oil (Total) pH,
O. PETROLEUM REFINING Phenols, Suspended Solids, Temperature, Total
Dissolved Solids
P. PLASTIC MATERIALS & SYNTHETIC BOD5, COD, pH, Total Suspended Solids, Oil and
INDUSTRY Grease, Phenols
BOD5, COD, pH, Total Suspended Solid, E. Coli, Color,
Q. PULP & PAPER INDUSTRY
Heavy Metals, Dissolved Solids, Oil & Grease, Phenols
INDUSTRY Oil and Grease, pH, Cyanide, Phenol,
STEEL
Suspended Solids, Temperature, Chromium
SUGAR CANE PROCESSING INDUSTRY BOD5, pH, Suspended Solids, Oil and grease
BOD5, COD, pH, Suspended Solids, Chromium,
TEXTILE MILL INDUSTRY
Phenols, Color, Oil and Grease
BOD5, Color, Chromium, Oil and Grease, pH,
THERMAL POWER GENERATION
Phosphate, Suspended Solids, Temperature
With reference to the Article 1, Section 5 of the Clean Water Act, the department, in
coordination with National Water Resources Board (NWRB), shall designate certain areas
as water quality management areas using appropriate physiographic units such as
watershed, river basins or water resources regions. Said management areas shall have
similar hydrological, hydrogeological, meteorological or geographic conditions which affect
the physicochemical, biological and bacteriological reactions and diffusions of pollutants in
the water bodies, or otherwise share common interest or face similar development
programs, prospects, or problems.
A technical secretariat for each management area is hereby created which shall be
part of the Department and shall provide technical support to the governing board. They
shall be composed of at least four (4) members who shall have the following minimum
qualifications:
c) One (1) member shall be a Civil Engineer or Hydrologist or have significant training and
experience in closely related fields and mainly experience on ground water, respectively;
and
d) One (1) member shall be a Geologist or Biologist or have significant training and
experience in closely related fields.
Water quality criteria for raw water used for drinking-water treatment and supply
usually depend on the potential of different methods of raw water treatment to reduce the
concentration of water contaminants to the level set by drinking-water criteria. Drinking
water treatment can range from simple physical treatment and disinfection, to chemical
treatment and disinfection, to intensive physical and chemical treatment. Many countries
strive to ensure that the quality of raw water is such that it would only be necessary to use
near-natural conditioning processes (such as bank filtration or low-speed sand filtration)
and disinfection in order to meet drinking-water standards.
The DENR Administrative Order No. 26-A Series of 1994 or the provision of Chapter
II of the Code on Sanitation of the Philippines designated the new and updated criteria for
the drinking water in the Philippines.
Total Coliforms 0
c. Treated water in the E. Coli or Thermotolerant 0
distribution system (fecal) coliform bacteria
Selenium 0.01
The Aesthetic Objective is established for parameters that may impair the taste,
smell, or colour of water; or which may interfere with the supply of good quality water.
They do not cause adverse health effects.
Table 12. Standard Values for Physical and Chemical Quality : Aesthetic Quality
Sulfate 250
Total Dissolved Solids 500
Zinc 5*
E. Radiological Constituents
The health risk associated with the presence of naturally occurring radionuclides in
drinking-water should also be taken into consideration, although the contribution of
drinking-water to total exposure to radionuclides is very small under normal
circumstances.
Methods of Analysis
Regular examination of water will have to be carried out in order to determine its
potability.
a) Bacteriological
d) Physical as appropriate
Microbiological Requirements
Water used for drinking must be free from pathogenic organisms responsible for
waterborne diseases. These pathogenic organisms include bacteria, viruses, protozoans
and helminths.
Elimination of all these pathogenic agents from drinking-water is essential for the
protection of public health. Two approaches can be used to reduce the risk of bacterial,
viral and parasitic infection to a negligible level: providing drinking-water from a source
verified free of fecal contamination or adequately treating fecally contaminated water.
Bacteriological Requirements
In order to determine whether the water supplied is safe or acceptable for human
consumption, (i.e. free from pathogenic or disease causing organisms) samples should be
collected from the water supply system for the bacteriological examination of the water(i,e.
total coliforms, thermotolerant (fecal) coliform bacteria and E. coli). The samples should be
representative of the whole water supply system [i,e. samples from the water source,before
and after treatment if any, and from a reasonable number of points. For disinfected water,
free residual chlorine should be measured during sampling.
Frequency of Sampling
The minimum number of samples to be collected and examined periodically mustcbe based
on the mode and source of water supply (see Table 14.1). The procedure, identification and
location of sampling are indicated in Table 14.2. However, frequency of sampling should
also take into account the past frequency of records yielding unsatisfactory results, the
quality of raw water treated, the number of raw water sources, the adequacy of treatment
and capacity of the treatment plant, risks of contamination at the source and in the
distribution system, the size and complexity of the distribution system, the risk of an
epidemic and the practice of disinfection.
Sampling
a. Level I 90 - 150 Once in every three (3)
months
b. Level II 600 Once in every two (2)
months
c. Level III Less than 5,000 5,000 - 1 sample monthly 1 sample
100,000 per 5,000 population
monthly
Examining Laboratories
a. Washing clothes or bathing within 25 meters from any well or other source of
drinking water is prohibited.
b. No artesians, deep or shallow well shall be constructed within 25 meters from any
source of pollution.
WATER TREATMENT
Water must have eye appeal and taste appeal before we will drink it with much relish.
Instinctively we draw back from the idea of drinking dirty, smelly water. Actually far more
important to our well-being is whether or not water is safe to drink. If it holds disease
bacteria, regardless of its clarity and sparkle, we should avoid it. Let's consider these two
highly important aspects of water: portability and palatability.
Regardless of any other in which they can grow. These organisms gain entry into water
through a variety of sources. They enter from natural causes, surface drainage and sewage.
Many of the organisms in water are harmless. In fact, they are extremely beneficial to man.
Others have a wide nuisance value and still others are the source of disease. In general, we
are primarily concerned here with organisms
which are potential disease-producers. These
are of five types: bacteria, protozoa, worms,
viruses, fungi. The presence of certain
organisms of these various types can lead to
such infectious diseases as typhoid fever,
dysentery, cholera, jaundice, hepatitis,
undulant fever and tularaemia.
Under the broad heading of plant forms, we can classify the following:
Algae - These organisms are found throughout the world. They constitute the chief group of
aquatic plants both in sea and fresh water. Algae range in size from microscopic organisms
to giant seaweeds several hundred feet in
length. They contain chlorophyll and other
pigments which give them a variety of colors.
They manufacture their food by photosynthesis.
Algae thrive well in stagnant surface waters
especially during the warm weather. Algae
gives water fishy, grassy another even more
objectionable odors. While algae-laden waters
are repulsive to man, animals will drink them
and the presence of blue-green algae has been known to cause the death of cattle drinking
this water.
Diatoms - Diatoms belong to the algae family. Some exist as single cells; others are found as
groups or colonies. More than 15,000 forms of diatoms are known to exist. Diatoms have
silica-impregnated cell walls. At time they release essential oils which give water a fishy
taste.
Bacteria - Bacteria are another important class of fungi. Again numerous smaller groupings
are possible. Among the higher organisms in this group are the iron, manganese and
sulphur bacteria. These higher bacteria gain their energy from the oxidation of simple
organic substances. Lower forms of bacteria can be grouped as those that are helpful and
those that are harmful to man. Those harmful to man are mainly the disease-producing
organisms. Helpful organisms hasten the process of decomposing organic matter and by
feeding on waste material; they aid in the purifying of water. All bacteria are sensitive to
the temperature and pH of water. Some bacteria can tolerate acid water. But for the most
part, they thrive best in waters that have a pH between 6.5 to 7.5, that is essentially neutral
waters. As to temperature, most pathogenic or disease bacteria thrive best in water of body
temperature. Beyond this no hard and fast statements can be made. Some bacteria are
more resistant to heat than are others. Some are more sensitive to cold. At low
temperatures, for example, some bacteria may become dormant for long periods of time
but will still continue to exist. Interestingly enough, the waste products of their own growth
can hamper bacteria and may even prove toxic to them. Animal forms like plant life thrive
in water providing conditions are right. Among the higher forms of animal life found in
water are fish, amphibians (turtles and frogs), mollusks (snails and shellfish) and
anthropoids (lobsters, crabs, water insects, water mites and others). Concern here is with
those lower forms of animal life in water. Again, some are helpful to man as scavengers;
others are injurious as possible sources of infection. Principal ones of concern are as
follows:
Protozoa - Another basic classification in the animal kingdom is that group of microscopic
animals known as protozoa. These one-celled organisms live mainly in water either at or
near the surface or at great depths in the oceans. Many live as parasites in the bodies of
man and animals. Sometimes, drinking water becomes infested with certain protozoa
which are not disease-producing. When present, they give the water a fishy taste and odor.
Some protozoa are aerobic, that is, they exist only where free oxygen is available. Some
exist where no free oxygen is available. Others can either be aerobic or anaerobic.
Nematodes - Nematodes belong to the worm family. They have long, cylindrical bodies
which have no internal segments. Interestingly enough, those nematodes which are found
in the bodies of men and warm-blooded animals are large enough to be visible to the naked
eye; those living in fresh water or the soil are microscopic. Nematodes can be a problem in
drinking water because they impart objectionable tastes and odors to water. They are also
under suspicion of being carriers of the type of disease-bearing bacteria found in the
intestines of warm-blooded animals though studies show that possibility is somewhat
remote. Nematodes are apt to be found in
municipal waters derived from surface
supplies.
human or animal wastes in water. Coliform bacteria naturally exist in the intestines of
humans and certain animals. Thus, the presence of these bacteria in water is accepted
proof that the water has been contaminated by human or animal wastes. Although such
water may contain no pathogens, an infected person, animal or a carrier of disease, could
add pathogens at any moment! Thus, immediate corrective action must be taken. The
presence of coliform bacteria shows water is contaminated by human wastes and is
potentially contaminated with pathogens. In short, these bacteria become a measure of
guilt by association. The other side is this: the mere absence of coliform bacteria does not
assure there are no pathogens. However, this is considered unlikely. Just how can water be
tested for the presence of coliform bacteria? These organisms cause the fermentation of
lactose (the crystalline sugar compound in milk). When water containing coliform bacteria
is placed in a lactose culture, it will cause fermentation resulting in the form of gas. This
confirms the suspicions. The Maximum Acceptable Concentration (MAC) for coliforms in
drinking water is zero organisms detectable per 100 mL. Recognizing the danger, what can
be done to provide adequate protection against contamination? When a water supply
becomes contaminated, correct the problem at once. This means going beyond treatment
alone - important as this may be. It is a basic rule of water sanitation to get to the source of
the problem and eliminate it. If a well, for example, becomes badly contaminated, it is
necessary to trace the contamination to its source and, if possible, remedy the situation. It
may even be necessary to seek out a new source of supply
WATER DISINFECTION
Treatment of a water supply is a safety factor, not a corrective measure. There are a
number of ways of purifying water. Techniques such as filtration may remove infectious
organisms from water. They are, however, no substitute for disinfection. The following are
the general methods used for disinfecting water:
Boiling - This involves bringing the water to its boiling point in a container over heat. The
water must be maintained at this temperature 15 to 20 minutes. This will disinfect the
CHE 429 – Environmental Engineering: Water Treatment 72
PAMANTASAN NG LUNGSOD NG MAYNILA
College of Engineering and Technology
Department of Chemical Engineering
Ultraviolet Light - The use of ultraviolet light is an attempt to imitate nature. As you recall,
sunlight destroys some bacteria in the natural purification of water. Exposing water to
ultraviolet light destroys pathogens. To assure thorough treatment, the water must be free
of turbidity and color. Otherwise, some bacteria will be protected from the germ-killing
ultraviolet rays. Since ultraviolet light adds nothing to the water, there is little possibility of
its creating taste or odor problems. On the other hand, ultraviolet light treatment has no
residual effect. Further, it must be closely checked to assure that sufficient ultraviolet
energy is reaching the point of application at all times.
Use of Chemical Disinfectants - The most common method of treating water for
contamination is to use one of various chemical agents available. Among these are chlorine,
bromine, iodine, potassium permanganate, copper and silver ions, alkalis, acids and ozone.
Bromine is an oxidizing agent that has been used quite successfully in the disinfecting of
swimming pool waters. It is rated as a good germicidal agent. Bromine is easy to feed into
water and is not hazardous to store. It apparently does not cause eye irritation among
swimmers nor are its odors troublesome.
One of the most widely used disinfecting agents to ensure safe drinking water is
chlorine. Chlorine in cylinders is used extensively by municipalities in purification work.
However, in this form chlorine gas (Cl,) is far too dangerous for any home purpose. For use
in the home, chlorine is readdy available as sodium hypochlorite (household bleach) which
can be used both for laundering or disinfecting purposes. This product contains a 5.25%
solution of sodium hypochlorite which is equivalent to 5 % available chlorine. Chlorine is
also available as calcium hypochlorite which is sold in the form of dry granules. In this
form, it is usually 70% available chlorine. When calcium hypochlorite is used, this
chlorinated lime should be mixed thoroughly and allowed to settle, pumping only the clear
solution. For a variety of reasons not the least of which is convenience, chlorine in the
liquid form (sodium hypochlorite) is more popular for household use. Chlorine is normally
fed into water with the aid of a chemical feed pump. The first chlorine fed into the water is
likely to be consumed in the oxidation of any iron, manganese or hydrogen sulphide that
may be present. Some of the chlorine is also neutralized by organic matter normally
present in any supply, including bacteria, if present. When the "chlorine demand" due to
these materials has been satisfied, what's left over -the chlorine that has not been
consumed - remains as "chlorine residual". The rate of feed is normally adjusted with a
chemical feed pump to provide a chlorine residual of 0.5 - 1.0 ppm after 20 minutes of
contact time. This is enough to kill coliform bacteria but may or may not kill any viruses or
cysts which may be present. Such a chlorine residual not only serves to overcome
intermittent trace contamination from coliform bacteria but, also provides for minor
variations in the chlorine demand of the water. The pathogens causing such diseases as
typhoid fever, cholera and dysentery succumb most easily to chlorine treatment. The cyst-
like protozoa causing dysentery are most resistant to chlorine. As yet, little is known about
viruses, but some authorities place them at neither extreme in resistance to chlorination.
There are three basic terms used in the chlorination process: chlorine demand,
chlorine dosage and chlorine residual. Chlorine demand is the amount of chlorine which
will be reduced or consumed in the process of oxidizing impurities in the water. Chlorine
dosage is the amount of chlorine fed into the water. Chlorine residual is the amount of
chlorine still remaining in water after oxidation takes place. For example, if water has 2.0
ppm chlorine demand and is fed into the water in a chlorine dosage of 5.0 ppm, the chlorine
residual would be 3.0 ppm.
For emergency purposes, iodine may be used for treatment of drinking water. Much work
at present is being done to test the effect of iodine in destroying viruses which are now
considered among the pathogens most resistant to treatment. Tests show that 20 minutes
exposure to 8.0 ppm of iodine is adequate to render a potable water. As usual, the residual
required varies inversely with contact time. Lower residuals require longer contact time
while higher residuals require shorter contact time. While such test results are
encouraging, not enough is yet known about the physiological effects of iodine-treated
water on the human system. For this reason, its use must be considered only on an
emergency basis.
Silver in various forms has been used to destroy pathogens. It can be added to the
water as a liquid or through electrolytic decomposition of metallic silver. It has also been
fed into water through an absorption process from silver-coated filters. Various household
systems have been designed to yield water with a predetermined silver concentration.
However, fluctuations in the flow rate often result in wide variations in the amount of silver
in the water. In minute concentrations, silver can be highly destructive in wiping out
disease-bearing bacteria. While long contact time is essential, silver possesses residual
effect that can last for days. Silver does not produce offensive tastes or odors when used in
water treatment. Further, organic matter does not interfere with its power to kill bacteria
as in the case with free chlorine. Its high cost and the need for long periods of exposure
have hindered its widespread acceptance.
Copper ions are used quite frequently to destroy algae in surface waters but these
ions are relatively ineffective in killing bacteria.
Disease-bearing organisms are strongly affected by the pH of a water. They will not
survive when water is either highly acidic or highly alkaline. Thus, treatment which sharply
reduces or increases pH in relation to the normal range of 6.5 to 7.5 can be an effective
means of destroying organisms.
Water from downpours, dams, lakes, rivers, and ground water go through several
stages of treatment processes to obtain clean, odorless, and disinfected water. Some
processes are pure physical treatment such as screening, filtration and sedimentation,
while others require chemical treatment such as coagulation, disinfection, and aeration
(oxidation)
Screening
Pumps draw raw water from
reservoirs, lakes, rivers, streams, wells or
underground aquifers. Water travel from
pipelines from the water pumping
screening. Fish, aquatic plants, sticks, and
other large foreign materials are removed
by passing raw water in to a mesh. The
mesh is fitted with a scraping mechanism
that removes build-up, to allow for
continuous flow of raw water.
Aeration
Aeration is a unit process in which
air and water are brought into intimate
contact. Turbulence increases the aeration
of flowing streams (Figure 4-1). In
industrial processes, water flow is usually
directed countercurrent to atmospheric or
forced-draft air flow. The contact time and
the ratio of air to water must be sufficient
for effective removal of the unwanted gas.
Methods of Aeration
Two general methods may be used for the aeration of water. The most common in
industrial use is the water-fall aerator. Through the use of spray nozzles, the water is
broken up into small droplets or a thin film to enhance countercurrent air contact. In the
air diffusion method of aeration, air is diffused into a receiving vessel containing counter-
current flowing water, creating very small
air bubbles. This ensures good air-water
contact for "scrubbing" of undesirable
gases from the water. Water-Fall Aerators
Many variations of the water-fall principle
are used for this type of aeration. The
simplest configuration employs a vertical
riser that discharges water by free fall into
a basin. The riser usually operates on the
available head of water. The efficiency of
aeration is improved as the fall distance is
increased. Also, steps or shelves may be added to break up the fall and spread the water
into thin sheets or films, which increases contact time and aeration efficiency. Coke tray
and wood or plastic slat water-fall aerators are relatively similar in design and have the
advantage of small space requirements. Coke tray aerators are widely used in iron and
manganese oxidation because a catalytic effect is secured by contact of the
iron/manganese-bearing water with fresh precipitates. These units consist of a series of
coke-filled trays through which the water percolates, with additional aeration obtained
during the free fall from one tray to the next. Wood or plastic slat tray aerators are similar
to small atmospheric cooling towers. The tray slats are staggered to break up the free fall of
the water and create thin films before the water finally drops into the basin. Forced draft
water-fall aerators are used for many industrial water conditioning purposes. Horizontal
wood or plastic slat trays, or towers filled with packing of various shapes and materials, are
designed to maximize disruption of the falling water into small streams for greater air-
water contact. Air is forced through the unit by a blower which produces uniform air
distribution across the entire cross section, cross current or countercurrent to the fall of
the water. Because of these features, forced draft aerators are more efficient for gas
removal and require less space for a given capacity. Air diffusion systems aerate by
pumping air into water through perforated pipes, strainers, porous plates, or tubes.
Aeration by diffusion is theoretically superior to water-fall aeration because a fine bubble
of air rising through water is continually exposed to fresh liquid surfaces, providing
maximum water surface per unit volume of air. Also, the velocity of bubbles ascending
through the water is much lower than the velocity of free-falling drops of water, providing
a longer contact time. Greatest efficiency is achieved when water flow is countercurrent to
the rising air bubbles.
Iron and manganese in well waters occur as soluble ferrous and manganous
bicarbonates. In the aeration process, the water is saturated with oxygen to promote the
following reactions:
The oxidation products, ferric hydroxide and manganese dioxide, are insoluble.
After aeration, they are removed by clarification or filtration. Occasionally, strong chemical
oxidants such as chlorine (Cl2) or potassium permanganate (KMnO4) may be used
following aeration to ensure complete oxidation.
Gases dissolved in water follow the principle that the solubility of a gas in a liquid
(water) is directly proportional to the partial pressure of the gas above the liquid at
equilibrium. This is known as Henry's Law and may be expressed as follows:
Ctotal = kP
Where:
Ctotal = total concentration of the gas in solution
P = partial pressure of the gas above the solution
K = a proportionality constant known as Henry's Law Constant
However, the gases frequently encountered in water treatment (with the exception
of oxygen) do not behave in accordance with Henry's Law because they ionize when
dissolved in water. For example:
Carbon dioxide, hydrogen sulfide, and ammonia are soluble in water under certain
conditions to the extent of 1,700, 3,900, and 531,000 ppm, respectively. Rarely are these
concentrations encountered except in certain process condensates. In a normal
atmosphere, the partial pressure of each of these gases is practically zero. Consequently,
the establishment of a state of equilibrium between water and air by means of aeration
results in saturation of the water with nitrogen and oxygen and nearly complete removal of
other gases.
Gas removal by aeration is achieved as the level of gas in the water approaches
equilibrium with the level of the gas in the surrounding atmosphere. The process is
improved by an increase in temperature, aeration time, the volume of air in contact with
the water, and the surface area of water exposed to the air. As previously indicated, pH is
an important consideration. The efficiency of aeration is greater where the concentration of
the gas to be removed is high in the water and low in the atmosphere.
LIMITATIONS
Although removal of free carbon dioxide increases the pH of the water and renders
it less corrosive from this standpoint, aeration also results in the saturation of water with
dissolved oxygen. This does not generally present a problem when original oxygen content
is already high. However, in the case of a well water supply that is high in carbon dioxide
but devoid of oxygen, aeration simply exchanges one corrosive gas for another.
Clarification
Steps of Clarification
Finely divided particles suspended in surface water repel each other because most of the
surfaces are negatively charged. The following steps in clarification are necessary for
particle agglomeration:
Inorganic Coagulants
Table 5-1 lists a number of common inorganic coagulants. Typical iron and
aluminum coagulants are acid salts that lower the pH of the treated water by hydrolysis.
Depending on initial raw water alkalinity and pH, an alkali such as lime or caustic must be
added to counteract the pH depression of the primary coagulant. Iron and aluminum
hydrolysis products play a significant role in the coagulation process, especially in cases
where low-turbidity influent waters benefit from the presence of additional collision
surface areas.
always coincide with the optimum pH for hydroxide floc formation. Also, the iron and
aluminum hydroxide flocs increase volume requirements for the disposal of settled sludge.
With aluminum sulfate, optimum coagulation efficiency and minimum floc solubility
normally occur at pH 6.0 to 7.0. Iron coagulants can be used successfully over the much
broader pH range of 5.0 to 11.0. If ferrous compounds are used, oxidation to ferric iron is
needed for complete precipitation. This may require either chlorine addition or pH
adjustment. The chemical reactions between the water's alkalinity (natural or
supplemented) and aluminum or iron result in the formation of the hydroxide coagulant as
in the following:
Polyelectrolytes
The term polyelectrolytes refers to all water-soluble organic polymers used for
clarification, whether they function as coagulants or flocculants.
anionic-ionize in water solution to form negatively charged sites along the polymer
chain
cationic-ionize in water solution to form positively charged sites along the polymer
chain
nonionic-ionize in water solution to form very slight negatively charged sites along
the polymer chain
Polymeric primary coagulants are cationic materials with relatively low molecular
weights (under 500,000). The cationic charge density (available positively charged sites)
is very high. Polymeric flocculants or coagulant aids may be anionic, cationic, or nonionic.
Their molecular weights may be as high as 50,000,000. Table 5-2 describes some typical
organic polyelectrolytes.
For any given particle there is an ideal molecular weight and an ideal charge density
for optimum coagulation. There is also an optimum charge density and molecular weight
for the most efficient flocculant.
Raw waters of less than 10 NTU (Nephelometric Turbidity Units) usually cannot be
clarified with a cationic polymer alone. Best results are obtained by a combination of an
inorganic salt and cationic polymer. In-line clarification should be considered for raw
waters with low turbidities.
The use of organic polymers offers several advantages over the use of inorganic
coagulants:
The amount of sludge produced during clarification can be reduced by 50-90%. The
approximate dry weight of solids removed per pound of dry alum and ferric sulfate
are approximately 0.25 and 0.5 lb, respectively.
The resulting sludge contains less chemically bound water and can be more easily
dewatered.
Polymeric coagulants do not affect pH. Therefore, the need for supplemental
alkalinity, such as lime, caustic, or soda ash, is reduced or eliminated.
Polymeric coagulants do not add to the total dissolved solids concentration. For
example, 1 ppm of alum adds 0.45 ppm of sulfate ion (expressed as CaCO3). The
reduction in sulfate can significantly extend the capacity of anion exchange systems.
Soluble iron or aluminum carryover in the clarifier effluent may result from inorganic
coagulant use. Therefore, elimination of the inorganic coagulant can minimize the
deposition of these metals in filters, ion exchange units, and cooling systems.
desired effluent clarity. A polymeric coagulant aid added after the primary coagulant may,
by developing a larger floc at low treatment levels, reduce the amount of primary
coagulant required.
Coagulant aids have proven quite successful in precipitation softening and clarification to
achieve improved settling rates of precipitates and finished water clarity.
Color Reduction
Most organic color in surface waters is colloidal and negatively charged. Chemically,
color-producing compounds are classified as humic and fulvic acids. Color can be removed
by chlorination and coagulation with aluminum or iron salts or organic polyelectrolytes.
Chlorine oxidizes color compounds, while the inorganic coagulants can physically remove
many types of organic color by neutralization of surface charges. The use of chlorine to
oxidize organic color bodies may be limited due to the production of chlorinated organic
by-products, such as trihalomethanes. Additional color removal is achieved by chemical
interaction with aluminum or iron hydrolysis products. Highly charged cationic organic
polyelectrolytes can also be used to coagulate some types of color particles.
Coagulation for color reduction is normally carried out at pH 4.5 to 5.5. Optimum pH
for turbidity removal is usually much higher than that for color reduction. The presence of
sulfate ions can interfere with coagulation for color reduction, whereas calcium and
CHE 429 – Environmental Engineering: Water Treatment 87
PAMANTASAN NG LUNGSOD NG MAYNILA
College of Engineering and Technology
Department of Chemical Engineering
magnesium ions can improve the process and broaden the pH range in which color may be
reduced effectively.
Because the design is suited to large-capacity basins, horizontal flow units are still
used in some large industrial plants and for clarifying municipal water. The retention time
is normally long (up to 4-6 hr), and is chiefly devoted to settling. Rapid mix is typically
designed for 3-5 min and slow mix for 15-30 min. This design affords great flexibility in
establishing proper chemical addition points. Also, such units are relatively insensitive to
sudden changes in water throughput.
The long retention also allows sufficient reaction time to make necessary
adjustments in chemical and polymer feed if raw water conditions suddenly change.
However, for all but very large treated water demands, horizontal units require high
construction costs and more land space per unit of water capacity.
Upflow Clarifiers
clarifiers are termed "upflow" because the water flows up toward the effluent launders as
the suspended solids settle. They are characterized by increased solids contact through
internal sludge recirculation. This is a key feature in maintaining a high-clarity effluent
and a major difference from horizontal clarifiers.
Because retention time in an upflow unit is approximately 1-2 hr, upflow basins can
be much smaller in size than horizontal basins of equal throughput capacity. A rise rate of
0.70-1.25 gpm/ft² of surface area is normal for clarification. Combination softening-
clarification units may operate at up to 1.5 gpm/ft² of surface area due to particle size and
densities of precipitated hardness.
In order to achieve high throughput efficiency, upflow units are designed to maximize the
linear overflow weir length while minimizing the opportunity for short-circuiting through
the settling zone. In addition, the two mixing stages for coagulation and flocculation take
place within the same clarification tank.
Although upflow units may provide more efficient sedimentation than horizontal
designs, many upflow clarifiers compromise on the rapid and slow mix sequences. Some
types provide rapid, mechanical mixing and rely on flow turbulence for flocculation;
others eliminate the rapid mix stage and provide only moderate turbulence for
flocculation. However, in most cases, users can overcome rapid mix deficiencies by adding
the primary coagulant further upstream of the clarifier.
Most upflow designs are called either "sludge blanket" or "solids-contact" clarifiers.
After coagulation and/or flocculation in the sludge blanket units, the incoming water
passes through the suspended layer of previously formed floc.
Because the centerwell in these units is often shaped like an inverted cone, the rise
rate of the water decreases as it rises through the steadily enlarging cross section. When
the rise rate decreases enough to equal the settling rate of the suspended floc exactly, a
distinct sludge/liquid interface forms.
Sludge blanket efficiency depends on the filtering action as the freshly coagulated or
flocculated water passes through the suspended floc. Higher sludge levels increase the
filtration efficiency. In practice, the top sludge interface is carried at the highest safe level
to prevent upsets that might result in large amounts of floc carryover into the overflow.
Excessive sludge withdrawal or blowdown should also be avoided. The sludge blanket
level is often highly sensitive to changes in throughput, coagulant addition, and changes in
raw water chemistry and temperature.
In-Line Clarification
In-line clarification is the process of removing raw water turbidity through the
addition of coagulant just prior to filtration. In-line clarification is generally limited to raw
waters with typical turbidities of less than 20 NTU, although upflow filters may tolerate
higher loading. Polyelectrolytes and/or inorganic coagulants are used to improve filtration
efficiency and run length. Polymers are favored because they do not create additional
suspended solids loading, which can shorten filter run length.
Filter design may be downflow or upflow, depending on raw water turbidity and
particle size. The downflow dual-media unit generally consists of layers of various grades
of anthracite and sand supported on a gravel bed. After backwashing, the larger anthracite
particles separate to the top of the bed, while the more dense, smaller sand particles are at
the bottom. The purpose is to allow bed penetration of the floc, which reduces the
potential for excessive pressure drops due to blinding off the top portion of filter media.
Thus, higher filtration rates are realized without a significant loss in effluent quality.
Normal filtration rates are 5-6 gpm/ft².
The choice of a polymer coagulant and feed rate depends on equipment design and
influent water turbidity. Initially, in-line clarification was used in the treatment of low-
turbidity waters, but it is now being used on many types of surface waters. For most
waters, the use of a polymeric cationic coagulant alone is satisfactory. However, the
addition of a high-molecular-weight, anionic polymer may improve filtration efficiency.
Polymer feed rates are usually lower than those used in conventional clarification, given
the same raw water characteristics. Complete charge neutralization and bridging are not
necessary and should be avoided, because total coagulation or flocculation may promote
excessive entrapment of suspended solids in the first portion of the filter media. This can
cause blinding of the media, high pressure drops, and short operating runs.
Sufficient polymer is applied only to initiate neutralization, which allows attraction and
adsorption of particles through the entire bed. Often, polymer feed rates are regulated by
trial and error on the actual units to minimize effluent turbidity and maximize service run
length.
Because optimum flocculation is undesirable, polymers are injected just upstream of the
units. Normally, a short mixing period is required to achieve the degree of reaction most
suitable for unit operation. Dilution water may be recommended to disperse the polymer
properly throughout the incoming water. However, it may be necessary to move the
polymer injection point several times to improve turbidity removal. Due to the nature of
operation, a change of polymer feed rate will typically show a change in effluent turbidity
in a relatively short period of time.
Filtration
Filtration does not remove dissolved solids, but may be used together with a
softening process, which does reduce the concentration of dissolved solids. For example,
anthracite filtration is used to remove residual precipitated hardness salts remaining after
clarification in precipitation softening.
Typical Construction
Conventional gravity and pressure rapid filters operate downflow. The filter
medium is usually a 15-30 in. deep bed of sand or anthracite. Single or multiple grades of
sand or anthracite may be used.
A large particle bed supports the filter media to prevent fine sand or anthracite from
escaping into the underdrain system. The support bed also serves to distribute backwash
water. Typical support beds consist of 1 8-1 in. gravel or anthracite in graded layers to a
depth of 12-16 in.
Types of Media
Quartz sand, silica sand, anthracite coal, garnet, magnetite, and other materials may
be used as filtration media. Silica sand and anthracite are the most commonly used types.
When silica is not suitable (e.g., in filters following a hot process softener where the
treated water is intended for boiler feed), anthracite is usually used.
The size and shape of the filter media affect the efficiency of the solids removal.
Sharp, angular media form large voids and remove less fine material than rounded media
of equivalent size. The media must be coarse enough to allow solids to penetrate the bed
for 2-4 in. Although most suspended solids are trapped at the surface or in the first 1-2 in.
of bed depth, some penetration is essential to prevent a rapid increase in pressure drop.
Desirable media size depends on the suspended solids characteristics as well as the
effluent quality requirements and the specific filter design. In general, rapid sand filters
use sand with an effective size of 0.35-0.60 mm (0.014-0.024 in.) and a maximum
uniformity coefficient of 1.7. Coarse media, often 0.6-1.0 mm (0.024-0.04 in.), are used for
closely controlled coagulation and sedimentation.
The terms "multilayer," "in-depth," and "mixed media" apply to a type of filter bed
which is graded by size and density. Coarse, less dense particles are at the top of the filter
bed, and fine, more dense particles are at the bottom. Downflow filtration allows deep,
uniform penetration by particulate matter and permits high filtration rates and long
service runs. Because small particles at the bottom are also more dense (less space
between particles), they remain at the bottom. Even after high-rate backwashing, the
layers remain in their proper location in the mixed media filter bed.
Table 6-1 lists four media that are used in multilayer filtration. Several other mixed
media combinations have also been tested and used effectively. The use of too many
different media layers can cause severe backwashing difficulties. For example, if all four
materials listed in Table 6-1 were used in the same filter, a wash rate high enough to
expand the magnetite layer might wash the anthracite from the filter. High wash water
requirements would also result.
Rapid sand filters can be converted for mixed media operation to increase capacity
by 100%. The cost of this conversion is much lower than that of installing additional rapid
sand filters.
Capping involves the replacement of a portion of the sand with anthracite. In this
conversion, a 2-6 in. layer of 0.4-0.6 mm (0.016-0.024 in.) sand is removed from the
surface of a bed and replaced with 4-8 in. of 0.9 mm (0.035 in.) anthracite. If an increase in
capacity is desired, a larger amount of sand is replaced. Pilot tests should be run to ensure
that a reduction in the depth of the finer sand does not reduce the quality of the effluent.
Gravity Filters
Gravity filters (see Figure 6-1) are open vessels that depend on system gravity head
for operation. Apart from the filter media, the essential components of a gravity filter
include the following:
The filter shell, which is either concrete or steel and can be square, rectangular, or
circular. Rectangular reinforced concrete units are most widely used.
The support bed, which prevents loss of fine sand or anthracite through the
underdrain system. The support bed, usually 1-2 ft deep, also distributes backwash
water.
An underdrain system, which ensures uniform collection of filtered water and
uniform distribution of backwash water. The system may consist of a header and
laterals, with perforations or strainers spaced suitably. False tank bottoms with
appropriately spaced strainers are also used for underdrain systems.
Wash water troughs, large enough to collect backwash water without flooding. The
troughs are spaced so that the horizontal travel of backwash water does not exceed
3-3 ft. In conventional sand bed units, wash troughs are placed approximately 2 ft
above the filter surface. Sufficient freeboard must be provided to prevent loss of a
portion of the filter media during operation at maximum backwash rates.
Control devices that maximize filter operation efficiency. Flow rate controllers,
operated by venturi tubes in the effluent line, automatically maintain uniform
delivery of filtered water. Backwash flow rate controllers are also used. Flow rate
and head loss gauges are essential for efficient operation.
Pressure Filters
Pressure filters are typically used with hot process softeners to permit high-
temperature operation and to prevent heat loss. The use of pressure filters eliminates the
need for repumping of filtered water. Pressure filters are similar to gravity filters in that
they include filter media, supporting bed, underdrain system, and control device; however,
the filter shell has no wash water troughs.
for anthracite and 13-15 gpm/ft² for sand. Anthracite filters associated with hot process
softeners require a backwash rate of 12-15 gpm/ft² because the water is less dense at
elevated operating temperatures. Cold water should not be used to backwash a hot
process filter. This would cause expansion and contraction of the system metallurgy,
which would lead to metal fatigue. Also, the oxygen-laden cold water would accelerate
corrosion.
Upflow Filters
Upflow units contain a single filter medium–usually graded sand. The finest sand is
at the top of the bed with the coarsest sand below. Gravel is retained by grids in a fixed
position at the bottom of the unit. The function of the gravel is to ensure proper water
distribution during the service cycle. Another grid above the graded sand prevents
fluidization of the media. Air injection during cleaning (not considered backwash because
the direction of flow is the same as when in-service) assists in the removal of solids and
the reclassification of the filter media. During operation, the larger, coarse solids are
removed at the bottom of the bed, while smaller solids particles are allowed to penetrate
further into the media. Typical service flow rates are 5-10 gpm/ft².
Several manufacturers have developed gravity filters that are backwashed automatically
at a preset head loss. Head loss (water level above the media) actuates a backwash siphon
and draws wash water from storage up through the bed and out through the siphon pipe
to waste. A low level in the backwash storage section breaks the siphon, and the filter
returns to service.
Automatic gravity filters are available in diameters of up to 15 ft. When equipped with a
high-rate, multilayer media, a single large-diameter unit can filter as much as 1,000 gpm.
In-Line Clarification
In-line clarification is the removal of suspended solids through the addition of in-
line coagulant followed by rapid filtration. This process is also referred to as in-line
filtration, or contact filtration. The process removes suspended solids without the use of
sedimentation basins. Coagulation may be achieved in in-line clarification by either of two
methods:
an inorganic aluminum or iron salt used alone or with a high molecular weight
polymeric coagulant
a strongly cationic organic polyelectrolyte
Because metal hydroxides form precipitates, only dual-media filters should be used
with inorganic coagulant programs. Floc particles must be handled in filters with coarse-
to-fine graded media to prevent rapid blinding of the filter and eliminate backwashing
difficulties. Where a high molecular weight polymeric coagulant is used, feed rates of less
than 0.1 ppm maximize solids removal by increasing floc size and promoting particle
absorption within the filter. This filtration technique readily yields effluent turbidities of
less than 0.5 NTU.
The second method of coagulant pretreatment involves the use of a single chemical,
a strongly charged cationic polyelectrolyte. This treatment forms no precipitation floc
particles, and usually no floc formation is visible in the filter influent. Solids are removed
within the bed by adsorption and by flocculation of colloidal matter directly onto the
surface of the sand or anthracite media. The process may be visualized as seeding of the
filter bed surfaces with positive cationic charges to produce a strong pull on the negatively
charged particles. Because gelatinous hydroxide precipitates are not present in this
process, single- media or upflow filters are suitable for poly-electrolyte clarification.
In-line clarification provides an excellent way to improve the efficiency of solids removal
from turbid surface waters. Effluent turbidity levels of less than 1 NTU are common with
this method.
Softening
Precipitation softening processes are used to reduce raw water hardness, alkalinity,
silica, and other constituents. This helps prepare water for direct use as cooling tower
In almost every raw water supply, hardness is present as calcium and magnesium
bicarbonate, often referred to as carbonate hardness or temporary hardness. These
compounds result from the action of acidic, carbon dioxide laden rain water on naturally
occurring minerals in the earth, such as limestone. For example:
If the proper chemical control is maintained on lime feed, the calcium hardness may
be reduced to 35-50 ppm. Magnesium reduction is a function of the amount of hydroxyl
(OH-) alkalinity excess maintained.
For example, in cold lime treatment of a water containing 110 ppm of calcium, 95
ppm of magnesium, and at least 110 ppm of alkalinity (all expressed as calcium
carbonate), calcium could theoretically be reduced to 35 ppm and the magnesium to about
70 ppm. However, an additional 25 ppm of calcium would be expected in the treated water
due to the following reactions:
The warm lime softening process operates in the temperature range of 120-140°F (49-
60°C). The solubilities of calcium, magnesium, and silica are reduced by increased
temperature. Therefore, they are more effectively removed by warm lime softening than
by cold lime softening. This process is used for the following purposes:
In any warm lime or warm lime-soda ash process, temperature control is critical
because temperature variations of as little as 4°F/hr (2°C/hr) can cause gross carryover of
the softener precipitates.
Silica Reduction
Hot process softening can also provide very good silica reduction. The silica
reduction is accomplished through adsorption of the silica on the magnesium hydroxide
precipitate. If there is insufficient magnesium present in the raw water to reduce silica to
the desired level, magnesium compounds (such as magnesium oxide, magnesium sulfate,
magnesium carbonate, or dolomitic lime) may be used. Magnesium oxide is the preferred
chemical because it does not increase the dissolved solids concentration of the water.
Good sludge contact enhances silica reduction. To ensure optimum contact, sludge is
frequently recirculated back to the inlet of the unit.
Cold or warm process softening is not as effective as hot process softening for silica
reduction. However, added magnesium oxide and good sludge contact will improve
results.
Predicted analyses of a typical raw water treated by various lime and lime-soda
softening processes are presented in Table 7-1.
Treatment by lime converts the sodium bicarbonate in the raw water to sodium
carbonate as follows:
Calcium sulfate (gypsum) may be added to reduce the carbonate to required levels.
The reaction is as follows:
Lime softening processes, with the usual filters, will reduce oxidized iron and
manganese to about 0.05 and 0.01 ppm, respectively. Raw water organics (color-
contributing colloids) are also reduced.
Turbidity, present in most surface supplies, is reduced to about 1.0 NTU with
filtration following chemical treatment. Raw water turbidity in excess of 100 NTU may be
tolerated in these systems; however, it may be necessary to coagulate raw water solids
with a cationic polymer before the water enters the softener vessel to assist liquid-solids
separation.
Oil may also be removed by adsorption on the precipitates formed during treatment.
However, oil in concentrations above about 30 ppm should be reduced before lime
treatment because higher concentrations of oil may exert a dispersing influence and cause
floc carryover.
Coagulants/Flocculants/Sludge Conditioners
Organic polymer flocculants and coagulants are preferred over inorganic salts of
aluminum or iron. Polymers add minimal dissolved solids to the water and their use
results in reduced sludge quantity compared to the use of inorganic coagulants. Inorganic
coagulants must react with raw water alkalinity to form the metallic precipitate that aids
in clarification and sludge bed conditioning. For example, alum reacts as follows:
The inorganic salt reduces the alkalinity. This converts the hardness to noncarbonate
hardness, which is not affected by lime. As a result, inorganic salts increase hardness
in water that is naturally deficient in bicarbonate alkalinity.
When the water is to be treated further by ion exchange, regenerant consumption is
increased.This is due to the higher hardness and the added soluble sulfate/chloride
load.
The carbon dioxide generated by the reaction has a lime demand which is twice that of
the bicarbonate. Therefore, increased chemical addition is required.
Soluble aluminum in the softener effluent interferes with softened water alkalinity
titrations, even when very low levels of soluble aluminum exist. This interference,
which necessitates an increase in lime feed, causes falsely low (2P - M) readings and
may be partly responsible for the additional removal of magnesium seen when
aluminum salts are used.
Limitations
Given proper consideration of raw water quality and ultimate end use of the treated
water, the application of precipitation processes has few limitations. However, operational
difficulties may be encountered unless the following factors are controlled:
Temperature. Cold and warm units are subject to carryover if the temperature varies
more than 4°F/hr (2°C/hr). Hot process units are less sensitive to slight
temperature variations. However, a clogged or improper spray pattern can prevent
proper heating of the water, and carryover can result.
Hydraulics. In any system, steady-state operation within design limits optimizes the
performance of the equipment. Rapid flow variations can cause severe system
upsets. Suitable treated water storage capacity should be incorporated into the total
system design to minimize load swings on the softener.
Chemical Control. This should be as precise as possible to prevent poor water
quality. Because of the comparatively constant quality of most well waters, changes
in chemical feed rates are largely a function of flow only. However, surface water
quality may vary hourly. Therefore, for proper control, it is imperative that users
perform frequent testing of the raw water as well as the treated effluent, and adjust
chemical feed accordingly.
Ozonation
Ozone is a colorless gas that has an odor similar to the smell of the air after a major
thunderstorm.Ozone has a greater disinfection effectiveness against bacteria and viruses
compared to chlorination. In addition, the oxidizing properties can also reduce the
concentration of iron, manganese, sulfur and reduce or eliminate taste and odor problems.
Ozone oxides the iron, manganese, and sulfur in the water to form insoluble metal oxides or
elemental sulfur. These insoluble particles are then removed by post-filtration. Organic
particles and chemicals will be eliminated through either coagulation or chemical
oxidation. Ozone is unstable, and it will degrade over a time frame ranging from a few
seconds to 30 minutes. The rate of degradation is a function of water chemistry, pH and
water temperature.
Ozonation Process
The formation of oxygen into ozone occurs with the use of energy. This process is
carried out by an electric discharge field as in the CD-type ozone generators (corona
discharge simulation of the lightning), or by ultraviolet radiation as in UV-type ozone
generators (simulation of the ultraviolet rays from the sun). In addition to these
commercial methods, ozone may also be made through electrolytic and chemical reactions.
In general, an ozonation system includes passing dry, clean air through a high voltage
electric discharge, i.e., corona discharge, which creates and ozone concentration of
CHE 429 – Environmental Engineering: Water Treatment 107
PAMANTASAN NG LUNGSOD NG MAYNILA
College of Engineering and Technology
Department of Chemical Engineering
The raw water is then passed through a venturi throat which creates a vacuum and
pulls the ozone gas into the water or the air is then bubbled up through the water being
treated. Since the ozone will react with metals to create insoluble metal oxides, post
filtration is required.
1. Ozone is effect over a wide pH range and rapidly reacts with bacteria, viruses, and
protozoans and has stronger germicidal properties then chlorination. Has a very
strong oxidizing power with a short reaction time.
Disadvantages to Ozone
1. There are higher equipment and operational costs and it may be more difficult to
find professional proficient in ozone treatment and system maintenance.
3. Ozonation by-products are still being evaluated and it is possible that some by-
products by be carcinogenic. These may include brominated by-products, aldehydes,
ketones, and carboxylic acids. This is one reason that the post-filtration system may
include an activate carbon filter.
4.The system may require pretreatment for hardness reduction or the additional of
polyphosphate to prevent the formation of carbonate scale.
6.Potential fire hazards and toxicity issues associated with ozone generation.
Ozone is a more effective disinfectant than chlorine, chloramines, and even chlorine
dioxide. An ozone dose of 0,4 mg L-1 for 4 minutes is usually effective for pre-treated water
(low NOM concentration) [39]. Several studies proved that ozone, unlike chlorine products,
can deactivate resistant micro-organisms (see resistant microorganisms page). However,
as ozone rapidly decomposes in water, its life-span in aqueous solutions is very short (less
than one hour). Therefore ozone is less suitable for residual disinfection and can be used
only in particular cases (mainly in short distribution systems). Chlorine and chlorine
dioxide often replace ozone as a final disinfectant. For primary disinfection (prior to the bio
filtration), ozone is very suitable. This will lead to a more complete disinfection and a lower
disinfectant concentration.
Odor and taste production in drinking water can have several causes. Odor and taste
forming compounds can be present in raw water, but they can also be formed during water
treatment. These compounds may derive from the decomposition of plant matter, but
normally they are a result of the activity of living organisms present in the water [5].
Inorganic compounds such as iron, copper and zinc can also generate some taste. Another
possibility is that the chemical oxidation (chlorine treatment) leads to an unpleasant tastes
and odors.
Odor and taste forming compounds are often very resistant. This causes elimination
to be a very intensive process [33]. For the elimination of taste and odor, several processes
can be appropriate, such as oxidation, aeration, granular active carbon (GAC) filtration or
sand filtration. Usually, a combination of these techniques is applied.
Generally, the most effective way to remove taste and odor components appears to
be a combination of pre-oxidation and filtration [5]. Table 2 shows several combinations of
techniques to improve taste. Ozone with sand filtration and GAC filtration is the most
efficient combination (82% removal).
1. Chlorine treatment
Chlorine readily combines with chemicals dissolved in water, microorganisms, small
animals, plant material, tastes, odors, and colors. These components "use up" chlorine and
comprise the chlorine demand of the treatment system. It is important to add sufficient
chlorine to the water to meet the chlorine demand and provide residual disinfection.
The chlorine that does not combine with other components in the water
is free (residual) chlorine, and the breakpoint is the point at which free chlorine is available
for continuous disinfection. An ideal system supplies free chlorine at a concentration of 0.3-
0.5 mg/l. Simple test kits, most commonly the DPD colorimetric test kit (so called because
diethyl phenylenediamine produces the color reaction), are available for testing breakpoint
and chlorine residual in private systems. The kit must test free chlorine, not total chlorine.
CHE 429 – Environmental Engineering: Water Treatment 110
PAMANTASAN NG LUNGSOD NG MAYNILA
College of Engineering and Technology
Department of Chemical Engineering
The contact (retention) time (Table 1) in chlorination is that period between the
introduction of the disinfectant and when the water is used. A long interaction between
chlorine and the microorganisms results in an effective disinfection process. The contact
time varies with chlorine concentration, the type of pathogens present, pH, and
temperature of the water. The calculation procedure is given below.
Contact time must increase under conditions of low water temperature or high pH
(alkalinity). Complete mixing of chlorine and water is necessary, and often a holding tank is
needed to achieve appropriate contact time. In a private well system, the minimum-size
holding tank is determined by multiplying the capacity of the pump by 10. For example, a
5-gallons-per-minute (GPM) pump requires a 50-gallon holding tank. Pressure tanks are
not recommended for this purpose since they usually have a combined inlet/outlet and all
the water does not pass through the tank.
Chlorination levels
If a system does not allow adequate contact time with normal dosages of
chlorine, superchlorination followed by dechlorination (chlorine removal) may be
necessary.
Chlorination Guidelines
Chlorine solutions lose strength while standing or when exposed to air or sunlight.
Make fresh solutions frequently to maintain the necessary residual. Maintain a free
chlorine residual of 0.3-0.5 mg/l after a 10-minute contact time. Measure the residual
frequently. Once the chlorine dosage is increased to meet greater demand, do not decrease
it.Locate and eliminate the source of contamination to avoid continuous chlorination. If a
water source is available that does not require disinfection, use it.
Public water systems use chlorine in the gaseous form, which is considered too
dangerous and expensive for home use. Private systems use liquid chlorine (sodium
hypochlorite) or dry chlorine (calcium hypochlorite). To avoid hardness deposits on
equipment, manufacturers recommend using soft, distilled, or demineralized water when
making up chlorine solutions.
Suction Device:
The line from chlorine supply to the suction side of water pump,
chlorine drawn into the water held in the well pump,
dosage uniformity not assured with this system,
some suction devices inject chlorine directly into well water, increasing the contact time
between microorganisms and disinfectant; water/chlorine mixture is then drawn into the
well pump
Batch disinfection:
used for fluctuating chlorine demand,
three tanks, each holding 2 to 3 days' water supply, alternately filled, treated and used