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JEE (Advanced)-2019
PAPER – 1
SECTION – A
1. A, B, C, D
Sol. Total displacement is zero.
1
Total distance travelled = 10 20 2 200m
2
2. B
Sol. Equation of motion perpendicular to inclination
10 sin 30 – g cos 30 t = 0
10 1
t= t
10 3 3
2
Time of flight T = 2t = sec
3
3. A, B
Sol. Torque about centre must be zero N fr
T = fr
T cos 45 + fr = mg sin 45
45
T
2 1 100
2 2 T
100
T
2 1
mg
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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/19 2
4. A, B, D
dU
Sol. F=
dx
5. A, D
Sol. The maximum energy of photon depends on the energy of electrons incident.
6. A, B
Sol. Optical path difference = n1L1 n2 2
2
x
7. A
8. A
Sol. (for Q.7-8)
R2 3B0 2B0 B0 R2
t t
2 2
2
20 R
t
B
9. A
10. A
Sol. (for Q.9-10)
1 1 1
f v u
1 1
30 60
1 1
f 20cm
f 20
Focal length of convex mirror
1
f 30 10 10cm
2
SECTION – D
11. 01200.00
1 q
Sol. V1
4 0 x R2
2
9 10 9 10 109
V1 3000
3 102
9 109 109 10
V2 1800
5 10 2
V 1200 V
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3 AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/19
12. 00781.25
r dB
Sol. E1 =
2 dt
R2 dB
E 2= .
2r dt
3 25
5 10 2 5 102
2 2 6
25 25 3 104
= 78.125 10–4 = 781.25 10–5
46
13. 00002.88
V2 V2 48 48
Sol. P R = 2.88
4R 4P 4 200
14. 00093.75
m 2 3 3 1 180
Sol. I= 20 =
12 4 4 12 192
15. 00010.20
Sol. Excess pressure
2T 2 7 102 2
P 700 N/m
R 0.2 103
Pressure inside bubble = 1.013 105 + 700
= 10.13 104 + 0.07 104 = 10.20 104 N/m2
16. 00026.68
GM 6.67 10 11 2
Sol. E 6.67 4 1011 26.68 10 11 N/kg
2R2 1
2
2
2
17. 00000.60
2v 2 2 2 0.9
Sol. A t Ai = 2 0.3 = 0.6
(v 1 v 2 ) 6
18. 00014.00
dP P
Sol. Slope
dV V
7 5
10 V
5
70 3 4 3
V 104 m = 14 10 m
5
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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/19 4
Chemistry PART – II
SECTION – A
19. A, C
Sol. Be also reacts directly with fluorine Except Be and Mg, other alkaline earth metals give flame test.
20. A, B
Sol. 3-
H3C H
ox
Cl
N K Cr H2O 2 C2O 4 2
Co ox
Pt paramagnetic
Cl N
CH3 ox Ni en 2 Cl2
H
diamagnetic d2sp2 paramagnetic
diamagnetic dsp2
21. B, C
Sol. F2 H2O HF O2
I2 H2O
No reaction
Cl2 H2O
HCl HClO
Br2 H2O
HBr HBrO
22. B, C, D
Sol. Peptization is the process of forming colloidal sol by freshly prepared precipitate in the presence
of small amount of electrolyte.
23. B, C
Sol. As temperature decreases or molar mass decreases
H increases
L decreases
w decreases
24. A, C, D
Sol. O O O O
O O
Br2 , NaOH H3 O
NaOH,CaO
O O O
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5 AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/19
Br MgBr OMgBr OH
COOH
hot KMnO4 / OH HI/Red P
H
COOH
25. C
26. B
Sol. CH3 COOH
O HO CH2 CH2 OH
Glyptal
CH3 COOH
'P '
1 CrO3 , Ac 2O
2 H3O O
CHO COOH C NH2
KMnO 4 ,H NH3 ,
CHO COOH C NH2
'Q '
O
Strong
O
COOK
Ac 2O/Py KOH, Br2 N H
NaOH,CaO
NH2 Br NH2
Br
O
HN Ac
H3O
Br2 /Ac 2 O
'S'
NHAc NH2
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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/19 6
CHO CH2OH
KOH
H3 O ,
O
CHO COOK
O
NH3 ,
Ac O, Py LiAlH
N Ac
2
N H
4 N H
'T' O
27. C
28. B
Sol. O
i CH2 COOC2H5 / Zn O
|
Br
ii H3O , C CH C OH
'H' CH3
i CH3Li
ii H3O O
OH C CH
i CH3Li CH3
C CH C CH3
ii H3 O
CH3
CH3 CH3
'P '
H3 O
3
i O O
ii H2 O/Zn
CHO
OH
KOH
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7 AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/19
SECTION – D
29. 00010.00
Z m
Sol. d
NA a 3
4 108 20 10 10
90 10 3 Distance between X & Y
6 10 23 a 3 2
10 10 10 m
4 108
a3
6 9 1021
a 8 10 21
3
a 2 10 7 cm
a 2 10 9 m
a 20 10 10 m
30. 00051.20
2
200
Sol. QP 3
100
2 50
G Go RTnQ
2500
31.06 4.6
1000
31.06 2.5 4.6
31.06 11.5
19.56
G H TS
19.56 4.2 TS
15.36 TS
15.36
S 1000 JK 1
300
51.2 JK 1
31. 00010.22
Sol.
H3N COOH NaOH H3N COO
2mmol 2.5 mmol
2.5 2 2mol
22
H3N COO NaOH H2N COO
2 0.5 0.5 0.5 0.5
pH pK a2 log
C.B
Acid
0.5 / V
10.7 log
15 / V
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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/19 8
1
pH 10.7 log
3
= 10.7 – 0.48
= 10.22
32. 00001.25
Sol. 2x 4xx 2 3xx 2 = 4x
k1 G1 R 2
k1 for Ba OH2 k 2 for KCl
k 2 G2 R1
k1 1 k2 0.002x
k1
k 2 4000 4000 4000
k 1000 0.002x 1000 0.2x 2x x
cm 1 2
M 4000 10 4 40 20
c
x 1
m 10 1 0.125 101
M 20 4x 8
1.25 102
33. 00013.20
Sol. A g 2B g C s D g
Po
10 min Po P 2P P
Po Po 2Po Po
3Po 27 1 60 9
k ln
Po 9 bar 10 96
6n3
PT Po P 2P P
6 1.1
PT Po 2P 6.6 min1
21 9 2P
r k A
2P 12
P 6atm 6.6 2
-1
=13.2 mole/litre min
34. 00000.82
Sol.
AgBr s
Ag Br
G1o RT nK SP
Ag e
Ag Go2 nFE1o
AgBr e
Ag Br
Go3 nFE o2
Go3 G1o Go2
1FEo2 1FE1o RTnK SP
RT
Eo2 E1o nK SP
F
0.0725 E1o 0.025 29.9
0.0725 E1o 0.7475
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9 AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/19
35. 00000.80
Sol. O O O O O O O O
O
i O ,H O HO
ii H3O
O
O
3 2 2
HO
O O O O O O O O O
36. 00001.50
Sol.
F F O F
Xe
Cl F Se F Xe F Cl F
O O O
F F
F
F O
S Cl S
N S F I I I
Cl O O O
F
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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/19 10
SECTION – A
37. B, C, D
2 2 2
Sol. Consider ABC, where A A , B B , C C
3 3 3
1
Now apply triangle inequality to get S
3
38. A, B, C
Sol. Take base as the x – y plane with one vertex as origin. A, B be vertices along the x, y-axes
respectively
OA 2iˆ , OB 2ˆj , OC ˆi ˆj 2kˆ , where C is the apex
OA OB 4kˆ ; OA OC 2kˆ 4ˆj ; OB OC 2kˆ 4iˆ
1 8
Volume is parallelopiped =
3 3
4
Tetrahedron with half of pyramid’s base and the pyramid’s apex has volume =
3
39. C, D
n
xu xu
Sol. Fx du ; u [1, n] is strictly monotonic in x
1
u u
F(x) is strictly monotonic
n n u n n n u n
du x du du x du
x du xn as x 1+ and x du xn as x 1–
1
u 1
u 1
u 1
u 1
u 1
u
lim F x ln n
x 1
40. A, B
n 1 n n 1 n 1
1 nx n 1
Sol. f x dx f x dx nx n dx
0 0 n nn lnn n ln n
n 1
n 1
n 1 n n 1
n x n 1
g x dx g x dx x n dx
n1
n 1
0 0 n
n
t t
t (0, 1) f x dx 0 , t 1, 2 f x dx 2 1
0 0
t
t = 1 g x dx 1
0
n n
1
lim g x dx lim i 1 Divergent series
n n
0 i0
41. A, B, D
Sol. For x 0, , f(x) = 0
2
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11 AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/19
For x , , f(x) = – x – x = – 2x < 0
2
3
For x , , f(x) = – x – (2 – x) = – < 0
2
for x , , f(x) = –( + x) – (–x) = – < 0
2
42. D
Sol. Incident ray, if extended, passes through one focus (2, 0). So reflected ray will follow the path to
pass through the other focus (–2, 0)
43. A
1 9 cos2 sin2
4
3
Sol. Area = 2 d
2 0 cos3 sin3 2 2
44. C
1 2 1 1
dr 1 1 1
Sol. Length = r 2 d 2 1d 1 2 ln 1 2 = ln 1 2
0
d 0
2 2 0 2 2
45. A
46. C
Sol. (for Q.45.-46)
Let A(h, k), C(x 0, y0), B(x1, y1)
1 1
h + x0 = 9(k + y0) and h2 + k2 = x 20 y02 x 0 40h 9k , y 0 9h 40k
41 41
h x1 k y1 and h2 k 2 x12 y12 x1 k, y1 h
5 y1 5 y 0
4h2 + 4k2 + 41k = 0
4 x1 4 x 0
SECTION – D
47. 00001.00
Sol. Two bishops attack each other if they are in squares along the same diagonal. The number of
ways of choosing two squares along the same diagonal on a 8 8 chessboard is
2 2 2
C2 3 C2 ..... 7 C2 8 C2 = 2 8
C3 9 C3
P 1
2 8
C3 9 C3 1 280 2 1
1
64
C2 64 63 P
48. 00000.20
x x 2 1 yz
Sol. y y 2 1 zx x y y z z x 1 xy yz zx
z z2 1 xy
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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/19 12
49. 00002.00
Sol. |adj A| = |A|2 = 6|A|2 = 6 (as A is orthogonal)
2 12
|Adj(adj A)| = |adj A| =
12
6 6 16 [2| = 3 16 2
50. 00003.00
1 1 1 1 1
n
xk 1 3k n
xk 3k 3x xe3x e3x 2e3 1
Sol. lim
n
k! dx nk0 k!
x lim dx xe dx
3
9
9
0 k 0 0 0 0 0
51. 00000.60
1 1 1
Sol. Probability that (i) Dice shows 2 and A reports it correctly,
6 3 18
5 2 1 1
(ii) Dice did not show 2 and A reported it as 2,
6 3 5 9
2 2 1 2
(iii) Dice showed 4 or 6 and A reported it as 2,
6 3 5 45
1 2
3
P 18 45
1 1 5
18 9
52. 00000.50
1 1 1 1 1 1 n2 1
Sol. a
Cn n C1 n Cn1 i2 n C2
n n nC
C0 n Cn 0
n
53. 00000.02
51! 1 1
Sol. Tk
50 k 1 ..... k 50 k 2 k 3 ..... k 51
1
S
50
54. 00000.05
Sol. Other 2 vertices lie on the director circle
L= 2 5
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