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HAZARD SUMMARY
* Calcium Cyanide can affect you when breathed in and by * If you think you are experiencing any work-related health
passing through your skin. problems, see a doctor trained to recognize occupational
* Contact can irritate the skin and eyes. diseases. Take this Fact Sheet with you.
* Breathing Calcium Cyanide can irritate the nose, throat
and lungs causing coughing, wheezing and/or shortness of WORKPLACE EXPOSURE LIMITS
breath. The following exposure limits are for Hydrogen Cyanide:
* Calcium Cyanide can cause headache, nausea, vomiting,
weakness, dizziness, loss of consciousness and death. OSHA: The legal airborne permissible exposure limit
* Repeated exposure can interfere with thyroid function and (PEL) is 11 mg/m3 averaged over an 8-hour
can cause nosebleeds. workshift.
* If Calcium Cyanide is involved in a fire, it can release
Hydrogen Cyanide. CONSULT THE NEW JERSEY NIOSH: The recommended airborne exposure limit is
DEPARTMENT OF HEALTH AND SENIOR 5 mg/m3, which should not be exceeded at any
SERVICES HAZARDOUS SUBSTANCE FACT SHEET time.
ON HYDROGEN CYANIDE.
ACGIH: The recommended airborne exposure limit is
IDENTIFICATION 5 mg/m3, which should not be exceeded at any
Calcium Cyanide is a white powder with an almond-like time.
odor. It is used in stainless steel manufacturing, leaching ores,
as a fumigant, insecticide and a single dose poison. * The above exposure limits are for air levels only. When
skin contact also occurs, you may be overexposed, even
REASON FOR CITATION though air levels are less than the limits listed above.
* Calcium Cyanide is on the Hazardous Substance List
because it is regulated by OSHA and cited by ACGIH, WAYS OF REDUCING EXPOSURE
DOT, NIOSH, DEP, HHAG, NFPA and EPA. * Where possible, enclose operations and use local exhaust
* This chemical is on the Special Health Hazard Substance ventilation at the site of chemical release. If local exhaust
List because it is REACTIVE. ventilation or enclosure is not used, respirators should be
* Definitions are provided on page 5. worn.
* Wear protective work clothing.
HOW TO DETERMINE IF YOU ARE BEING * Wash thoroughly immediately after exposure to Calcium
EXPOSED Cyanide and at the end of the workshift.
The New Jersey Right to Know Act requires most employers * Post hazard and warning information in the work area. In
to label chemicals in the workplace and requires public addition, as part of an ongoing education and training
employers to provide their employees with information and effort, communicate all information on the health and
training concerning chemical hazards and controls. The safety hazards of Calcium Cyanide to potentially exposed
federal OSHA Hazard Communication Standard, 1910.1200, workers.
requires private employers to provide similar training and
information to their employees.
This Fact Sheet is a summary source of information of all Request copies of your medical testing. You have a legal
potential and most severe health hazards that may result from right to this information under OSHA 1910.1020.
exposure. Duration of exposure, concentration of the
substance and other factors will affect your susceptibility to Mixed Exposures
any of the potential effects described below. * Because smoking can cause heart disease, as well as lung
--------------------------------------------------------------------------- cancer, emphysema, and other respiratory problems, it may
worsen respiratory conditions caused by chemical
HEALTH HAZARD INFORMATION exposure. Even if you have smoked for a long time,
stopping now will reduce your risk of developing health
Acute Health Effects problems.
The following acute (short-term) health effects may occur
immediately or shortly after exposure to Calcium Cyanide: WORKPLACE CONTROLS AND PRACTICES
* Contact can irritate the skin and eyes. Unless a less toxic chemical can be substituted for a hazardous
* Breathing Calcium Cyanide can irritate the nose and substance, ENGINEERING CONTROLS are the most
throat causing coughing and wheezing. effective way of reducing exposure. The best protection is to
* Calcium Cyanide can cause headache, nausea, vomiting, enclose operations and/or provide local exhaust ventilation at
weakness, dizziness, loss of consciousness and death. the site of chemical release. Isolating operations can also
reduce exposure. Using respirators or protective equipment is
Chronic Health Effects less effective than the controls mentioned above, but is
The following chronic (long-term) health effects can occur at sometimes necessary.
some time after exposure to Calcium Cyanide and can last
for months or years: In evaluating the controls present in your workplace, consider:
(1) how hazardous the substance is, (2) how much of the
Cancer Hazard substance is released into the workplace and (3) whether
* According to the information presently available to the harmful skin or eye contact could occur. Special controls
New Jersey Department of Health and Senior Services, should be in place for highly toxic chemicals or when
Calcium Cyanide has not been tested for its ability to significant skin, eye, or breathing exposures are possible.
cause cancer in animals.
In addition, the following control is recommended:
Reproductive Hazard
* According to the information presently available to the * Where possible, automatically transfer Calcium Cyanide
New Jersey Department of Health and Senior Services, from drums or other storage containers to process
Calcium Cyanide has not been tested for its ability to containers.
affect reproduction.
Good WORK PRACTICES can help to reduce hazardous
Other Long-Term Effects exposures. The following work practices are recommended:
* Repeated exposure can interfere with thyroid function and
can cause nosebleeds. * Workers whose clothing has been contaminated by
* Calcium Cyanide can irritate the lungs. Repeated Calcium Cyanide should change into clean clothing
exposure may cause bronchitis to develop with cough, promptly.
phlegm, and/or shortness of breath. * Do not take contaminated work clothes home. Family
members could be exposed.
MEDICAL * Contaminated work clothes should be laundered by
individuals who have been informed of the hazards of
Medical Testing exposure to Calcium Cyanide.
If symptoms develop or overexposure is suspected, the * Eye wash fountains should be provided in the immediate
following are recommended: work area for emergency use.
* If there is the possibility of skin exposure, emergency
* Urine thiocyanate levels. shower facilities should be provided.
* Evaluation of thyroid function. * On skin contact with Calcium Cyanide, immediately
wash or shower to remove the chemical. At the end of the
Any evaluation should include a careful history of past and workshift, wash any areas of the body that may have
present symptoms with an exam. Medical tests that look for contacted Calcium Cyanide, whether or not known skin
damage already done are not a substitute for controlling contact has occurred.
exposure.
CALCIUM CYANIDE page 3 of 6
* Do not eat, smoke, or drink where Calcium Cyanide is * If while wearing a filter or cartridge respirator you can
handled, processed, or stored, since the chemical can be smell, taste, or otherwise detect Calcium Cyanide, or if
swallowed. Wash hands carefully before eating, drinking, while wearing particulate filters abnormal resistance to
smoking, or using the toilet. breathing is experienced, or eye irritation occurs while
* Use a vacuum or a wet method to reduce dust during wearing a full facepiece respirator, leave the area
clean-up. DO NOT DRY SWEEP. immediately. Check to make sure the respirator-to-face
seal is still good. If it is, replace the filter or cartridge. If
PERSONAL PROTECTIVE EQUIPMENT the seal is no longer good, you may need a new respirator.
* Be sure to consider all potential exposures in your
WORKPLACE CONTROLS ARE BETTER THAN workplace. You may need a combination of filters,
PERSONAL PROTECTIVE EQUIPMENT. However, for prefilters or cartridges to protect against different forms of
some jobs (such as outside work, confined space entry, jobs a chemical (such as vapor and mist) or against a mixture of
done only once in a while, or jobs done while workplace chemicals.
controls are being installed), personal protective equipment * Where the potential for high exposure exists, use a
may be appropriate. MSHA/NIOSH approved supplied-air respirator with a full
facepiece operated in a pressure-demand or other positive-
OSHA 1910.132 requires employers to determine the pressure mode. For increased protection use in
appropriate personal protective equipment for each hazard and combination with an auxiliary self-contained breathing
to train employees on how and when to use protective apparatus operated in a pressure-demand or other positive-
equipment. pressure mode.
* Exposure to 55 mg/m3 (as Hydrogen Cyanide) is
The following recommendations are only guidelines and may immediately dangerous to life and health. If the possibility
not apply to every situation. of exposure above 55 mg/m3 (as Hydrogen Cyanide)
exists, use a MSHA/NIOSH approved self-contained
Clothing breathing apparatus with a full facepiece operated in a
* Avoid skin contact with Calcium Cyanide. Wear pressure-demand or other positive-pressure mode.
protective gloves and clothing. Safety equipment
suppliers/ manufacturers can provide recommendations on HANDLING AND STORAGE
the most protective glove/clothing material for your
operation. * Prior to working with Calcium Cyanide you should be
* All protective clothing (suits, gloves, footwear, headgear) trained on its proper handling and storage.
should be clean, available each day, and put on before * Calcium Cyanide can react with WATER or MOISTURE
work. in the air to form Hydrogen Cyanide gas.
* Calcium Cyanide is not compatible with OXIDIZING
Eye Protection AGENTS (such as PERCHLORATES, PEROXIDES,
* Wear impact resistant eye protection with side shields or PERMANGANATES, CHLORATES, NITRATES,
goggles. CHLORINE, BROMINE and FLUORINE); STRONG
* Wear a face shield along with goggles when working with ACIDS (such as HYDROCHLORIC, SULFURIC and
corrosive, highly irritating or toxic substances. NITRIC); NITRITES; and MAGNESIUM.
* Store in tightly closed containers in a cool, well-ventilated
Respiratory Protection area.
IMPROPER USE OF RESPIRATORS IS DANGEROUS.
Such equipment should only be used if the employer has a QUESTIONS AND ANSWERS
written program that takes into account workplace conditions,
requirements for worker training, respirator fit testing and
Q: If I have acute health effects, will I later get chronic
medical exams, as described in OSHA 1910.134.
health effects?
A: Not always. Most chronic (long-term) effects result
* For field applications check with your supervisor and your
from repeated exposures to a chemical.
safety equipment supplier regarding the appropriate
respiratory equipment.
Q: Can I get long-term effects without ever having short-
* NIOSH has established new testing and certification
term effects?
requirements for negative pressure, air purifying,
A: Yes, because long-term effects can occur from repeated
particulate filter and filtering facepiece respirators. The
exposures to a chemical at levels not high enough to
filter classifications of dust/mist/fume, paint spray or
make you immediately sick.
pesticide prefilters, and filters for radon daughters, have
been replaced with the N, R, and P series. Each series has
three levels of filtering efficiency: 95%, 99%, and 99.9%.
Check with your safety equipment supplier or your
respirator manufacturer to determine which respirator is
appropriate for your facility.
CALCIUM CYANIDE page 4 of 6
Public Presentations
Presentations and educational programs on occupational
health or the Right to Know Act can be organized for labor
unions, trade associations and other groups.
DEFINITIONS
ACGIH is the American Conference of Governmental NAERG is the North American Emergency Response
Industrial Hygienists. It recommends upper limits (called Guidebook. It was jointly developed by Transport Canada,
TLVs) for exposure to workplace chemicals. the United States Department of Transportation and the
Secretariat of Communications and Transportation of Mexico.
A carcinogen is a substance that causes cancer. It is a guide for first responders to quickly identify the specific
or generic hazards of material involved in a transportation
The CAS number is assigned by the Chemical Abstracts incident, and to protect themselves and the general public
Service to identify a specific chemical. during the initial response phase of the incident.
A combustible substance is a solid, liquid or gas that will NCI is the National Cancer Institute, a federal agency that
burn. determines the cancer-causing potential of chemicals.
A corrosive substance is a gas, liquid or solid that causes NFPA is the National Fire Protection Association. It
irreversible damage to human tissue or containers. classifies substances according to their fire and explosion
hazard.
DEP is the New Jersey Department of Environmental
Protection. NIOSH is the National Institute for Occupational Safety and
Health. It tests equipment, evaluates and approves respirators,
DOT is the Department of Transportation, the federal agency conducts studies of workplace hazards, and proposes
that regulates the transportation of chemicals. standards to OSHA.
EPA is the Environmental Protection Agency, the federal NTP is the National Toxicology Program which tests
agency responsible for regulating environmental hazards. chemicals and reviews evidence for cancer.
A fetus is an unborn human or animal. OSHA is the Occupational Safety and Health Administration,
which adopts and enforces health and safety standards.
A flammable substance is a solid, liquid, vapor or gas that
will ignite easily and burn rapidly. PEOSHA is the Public Employees Occupational Safety and
Health Act, a state law which sets PELs for New Jersey public
The flash point is the temperature at which a liquid or solid employees.
gives off vapor that can form a flammable mixture with air.
PIH is a DOT designation for chemicals which are Poison
HHAG is the Human Health Assessment Group of the federal Inhalation Hazards.
EPA.
ppm means parts of a substance per million parts of air. It is a
IARC is the International Agency for Research on Cancer, a measure of concentration by volume in air.
scientific group that classifies chemicals according to their
cancer-causing potential. A reactive substance is a solid, liquid or gas that releases
energy under certain conditions.
A miscible substance is a liquid or gas that will evenly
dissolve in another. A teratogen is a substance that causes birth defects by
damaging the fetus.
mg/m3 means milligrams of a chemical in a cubic meter of
air. It is a measure of concentration (weight/volume). TLV is the Threshold Limit Value, the workplace exposure
limit recommended by ACGIH.
MSHA is the Mine Safety and Health Administration, the
federal agency that regulates mining. It also evaluates and The vapor pressure is a measure of how readily a liquid or a
approves respirators. solid mixes with air at its surface. A higher vapor pressure
indicates a higher concentration of the substance in air and
A mutagen is a substance that causes mutations. A mutation therefore increases the likelihood of breathing it in.
is a change in the genetic material in a body cell. Mutations
can lead to birth defects, miscarriages, or cancer.
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