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GHS02 flame
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 05.04.2017 V-1 Revision: 05.04.2017
(Contd. of page 1)
GHS07
GHS02 GHS07
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Safety data sheet
according to 1907/2006/EC, Article 31
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(Contd. of page 2)
· Active substance (528/2012/EC)
55406-53-6 3-Iodo-2-propynylbutylcarbamate
2634-33-5 1,2-benzisothiazol-3(2H)-one
2682-20-4 2-methyl-2H-isothiazol-3-one
52-51-7 bronopol (INN)
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
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CAS: 2682-20-4 2-methyl-2H-isothiazol-3-one <0.1%
EINECS: 220-239-6 Acute Tox. 3, H301; Acute Tox. 3, H311; Acute Tox. 2, H330;
Skin Corr. 1B, H314; Aquatic Acute 1, H400; Aquatic
Chronic 2, H411; Skin Sens. 1A, H317; STOT SE 3, H335
CAS: 52-51-7 bronopol (INN) <0.1%
EINECS: 200-143-0 Eye Dam. 1, H318; Aquatic Acute 1, H400 (M=10); Aquatic
Chronic 2, H411; Acute Tox. 4, H302; Acute Tox. 4, H312; Skin
Irrit. 2, H315; STOT SE 3, H335
· Additional information: For the wording of the listed hazard phrases refer to section 16.
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(Contd. of page 4)
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
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Safety data sheet
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(Contd. of page 5)
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Safety data sheet
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(Contd. of page 6)
0.000147 mg/l (marine water)
0.0147 mg/l (intermittent releases)
PNEC sediment 0.0062 mg/kg (freshwater)
0.00062 mg/kg (marine water)
PNEC STP 6.25 mg/l
PNEC soil 0.0043 mg/kg (soil dw)
7575-23-7 pentaerythritol tetrakis (3-mercapto propionate)
PNEC aqua 0.00003 mg/l (freshwater)
0.0000034 mg/l (marine water)
0.00034 mg/l (intermittent releases)
PNEC sediment 0.00102 mg/kg (freshwater)
0.000102 mg/kg (marine water)
PNEC STP 2.39 mg/l
PNEC soil 0.000184 mg/kg (soil dw)
7779-90-0 trizinc bis(orthophosphate)
PNEC aqua 0.0206 mg/l (freshwater)
0.0061 mg/l (marine water)
PNEC sediment 117.8 mg/kg (freshwater)
56.5 mg/kg (marine water)
PNEC STP 0.052 mg/l
PNEC soil 35.6 mg/kg (soil dw)
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Do not inhale gases / fumes / aerosols.
Avoid contact with the eyes and skin.
Wash hands before breaks and at the end of work.
Keep away from foodstuffs, beverages and feed.
Do not eat, drink, smoke or sniff while working.
Store protective clothing separately.
After contact with skin, wash immediately with plenty of soap and water.
Take off contaminated clothing.
Use skin protection cream for skin protection.
· Respiratory protection:
Ensure good ventilation/exhaustion at the workplace.
Adhere to the workplace limit values and / or other threshold values.
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.
Filter A/P2
· Protection of hands:
Protective gloves
(Contd. on page 8)
GB
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Safety data sheet
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The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
Check the permeability prior to each anewed use of the glove.
Preventive skin protection by use of skin-protecting agents is recommended.
· Material of gloves
DIN EN 374
Chloroprene rubber, CR
Recommended thickness of the material: 0.65 mm
Butyl rubber, BR
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
· Penetration time of glove material
Value for the permeation: Level 6 ( 480 min)
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:
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Safety data sheet
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(Contd. of page 9)
2634-33-5 1,2-benzisothiazol-3(2H)-one
Oral LD50 1193 mg/kg (rat)
Dermal LD50 4115 mg/kg (rat)
2682-20-4 2-methyl-2H-isothiazol-3-one
Oral LD50 120 mg/kg (rat)
Dermal LD50 242 mg/kg (rabbit)
52-51-7 bronopol (INN)
Oral LD50 305 mg/kg (rat) (OECD 401)
Dermal LD50 > 2000 mg/kg (rat) (OECD 402)
Inhalative LC50 /4h 0.588 mg/l (rat) (Aerosol)
· Primary irritant effect:
· Skin corrosion/irritation
Causes skin irritation.
· Serious eye damage/irritation
Causes serious eye irritation.
· Subacute to chronic toxicity:
67-64-1 acetone
Oral NOAEL 900 mg/kg (rat) (OECD 408, rat (male), 13 weeks)
15625-89-5 2,2-bis(acryloyloxymethyl)butyl acrylate
Oral NOAEL >250 mg/kg (rat) (28d)
Dermal NOAEL >200 mg/kg (rat) (16d)
· Sensitisation
Sensitisation possible through skin contact.
May cause an allergic skin reaction.
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
No further relevant information available.
· Carcinogenicity
15625-89-5 2,2-bis(acryloyloxymethyl)butyl acrylate
Dermal NOAEL (carcinogenicity) 50 mg/kg (mouse) (80 weeks)
· Reproductive toxicity/Teratogenicity
15625-89-5 2,2-bis(acryloyloxymethyl)butyl acrylate
Oral NOAEL (developmental toxicity) 500 mg/kg (rat) (10d)
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposure
May cause drowsiness or dizziness.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.
GB
(Contd. on page 11)
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Safety data sheet
according to 1907/2006/EC, Article 31
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Safety data sheet
according to 1907/2006/EC, Article 31
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 05.04.2017 V-1 Revision: 05.04.2017
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Safety data sheet
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· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
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