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4. Lattice Periodicity
4.1 Intro
A crystal is a solid having an essentially discrete diffraction
pattern (International Union of Crystallography).
Periodic crystals form a subset. They are quite frequent:
diamond, quartz, salts, metals, etc.
Now we consider full periodicity. Later we will briefly
address “quasi crystals”.
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Translation operator:
honyecomb structure.
The black dots don’t
parallelepiped is
form a Bravais lattice
a three- but the centers of the
dimensional dumbbells do.
figure formed by
six This structure is a
parallelograms
Bravais lattice with
basis: Each Bravais
lattice points
represents 2 atoms.
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body centered
cubic
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Symmetry Groups
Translations are the simplest symmetry operations. They
form an Abelian Group: OANI (operation, associative,
neutral and inverse elements) and commutative.
There are more symmetry operations:
Rϕ Rotations by angle ϕ
Cn normal rotations; ϕ = 2 π/ n
Sn improper rotations
σ Reflection
Screw Rotations
Glide reflections
These also form a group (typically not Abelian). The
subgroups without translations are called point groups.
There are 32 different point groups.
… or by an
improper
σ Mirror
rotation
T Translation
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Symmetry Groups
Translations are the simplest symmetry operations. They
form an Abelian Group: OANI (operation, associative,
neutral and inverse elements) and commutative.
There are more symmetry operations:
Rϕ Rotations by angle ϕ
Cn normal rotations; ϕ = 2 π/ n
Sn improper rotations
σ Reflection A point group is a group of
Screw Rotations symmetry operations that
keep at least one point fixed.
Glide reflections
These also form a group (typically not Abelian). The
subgroups without translations are called point groups.
There are 32 different point groups.
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base centered
(upper & lower facet)
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4. Lattice Periodicity
4.2 Bloch Theorem
Implications of the symmetry of and of the
commutation of the resulting fact that
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… continue at blackboard
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