UNIVERSIDAD NACIONAL DE INGENIERÍA

FACULTAD DE INGENIERÍA QUÍMICA Y TEXTIL

DEPARTAMENTO ACADÉMICO DE INGENIERÍA TEXTIL

TERMODINAMICA PARA LA INGENIERIA QUIMICA I

PI-216/B

PERIODO ACADÉMICO 2016-3

TRABAJO N° 2

“GRAFICA DE 10 ISOTERMAS PARA EL n-HEXANO”

PROFESOR:

- Ing. Quiroz García Juan Antonio

REALIZADO POR:

- Machuca Zegarra Martin

- Vivanco Mamani Juan Diego

LIMA-PERÚ
 GRAFICA DE 10 ISOTERMAS PARA EL n-HEXANO

Utilizando la ecuación de Van Der Walls:

𝑎𝑛2
(𝑃 + 2 )(𝑉 − 𝑛𝑏) = 𝑛𝑅𝑇
𝑉

Para el n-hexano:

Unidades
N 1 kmol
Pc 3030000 Pa
Tc 507.9 K
R 8,314 m3.Pa/kmol.K
M 86.178

Con los datos, hallamos a y b:

27𝑅 2 𝑇𝑐2 𝑅𝑇𝑐

𝑎= 𝑦 𝑏=
64𝑃𝑐 8𝑃𝑐

a 2482728.321 m6.Pa/kmol
b 0.1742 m3/kmol

Ahora con esos valores hallados, los reemplazamos en la ecuación siguiente y luego
damos valores de T.

𝑃𝑉 3 − 𝑛𝑏𝑃𝑉 2 + 𝑎𝑛2 𝑉 − 𝑎𝑏𝑛3 = 𝑛𝑅𝑇𝑉 2

Obteniendo lo siguiente:

T V P T V P T V P T V P T V P
250 1 0.0341 260 1 0.1348 270 1 0.2354 280 1 0.3361 290 1 0.4368
250 1.2 0.3020 260 1.2 0.3831 270 1.2 0.4641 280 1.2 0.5451 290 1.2 0.6262
250 1.4 0.4288 260 1.4 0.4967 270 1.4 0.5645 280 1.4 0.6323 290 1.4 0.7001
250 1.6 0.4879 260 1.6 0.5462 270 1.6 0.6045 280 1.6 0.6628 290 1.6 0.7211
250 1.8 0.5121 260 1.8 0.5632 270 1.8 0.6144 280 1.8 0.6655 290 1.8 0.7167
250 2 0.5177 260 2 0.5632 270 2 0.6087 280 2 0.6543 290 2 0.6998
250 2.2 0.5130 260 2.2 0.5540 270 2.2 0.5951 280 2.2 0.6361 290 2.2 0.6772
250 2.4 0.5027 260 2.4 0.5401 270 2.4 0.5774 280 2.4 0.6148 290 2.4 0.6522
250 2.6 0.4895 260 2.6 0.5238 270 2.6 0.5581 280 2.6 0.5923 290 2.6 0.6266
250 2.8 0.4749 260 2.8 0.5065 270 2.8 0.5382 280 2.8 0.5698 290 2.8 0.6015
250 3 0.4596 260 3 0.4891 270 3 0.5185 280 3 0.5479 290 3 0.5773
250 3.2 0.4444 260 3.2 0.4719 270 3.2 0.4994 280 3.2 0.5269 290 3.2 0.5543
250 3.4 0.4295 260 3.4 0.4553 270 3.4 0.4811 280 3.4 0.5069 290 3.4 0.5326
250 3.6 0.4151 260 3.6 0.4394 270 3.6 0.4637 280 3.6 0.4879 290 3.6 0.5122
250 3.8 0.4013 260 3.8 0.4242 270 3.8 0.4471 280 3.8 0.4701 290 3.8 0.4930

2
250 4 0.3881 260 4 0.4098 270 4 0.4315 280 4 0.4533 290 4 0.4750
250 4.2 0.3755 260 4.2 0.3962 270 4.2 0.4168 280 4.2 0.4375 290 4.2 0.4581
250 4.4 0.3636 260 4.4 0.3833 270 4.4 0.4029 280 4.4 0.4226 290 4.4 0.4423
250 4.6 0.3523 260 4.6 0.3711 270 4.6 0.3898 280 4.6 0.4086 290 4.6 0.4274
250 4.8 0.3415 260 4.8 0.3595 270 4.8 0.3775 280 4.8 0.3955 290 4.8 0.4134

T V P T V P T V P T V P T V P
300 1 0.5375 310 1 0.6381 320 1 0.7388 330 1 0.8395 340 1 0.9402
300 1.2 0.7072 310 1.2 0.7883 320 1.2 0.8693 330 1.2 0.9504 340 1.2 1.0314
300 1.4 0.7680 310 1.4 0.8358 320 1.4 0.9036 330 1.4 0.9714 340 1.4 1.0392
300 1.6 0.7794 310 1.6 0.8377 320 1.6 0.8960 330 1.6 0.9544 340 1.6 1.0127
300 1.8 0.7678 310 1.8 0.8189 320 1.8 0.8701 330 1.8 0.9212 340 1.8 0.9723
300 2 0.7453 310 2 0.7909 320 2 0.8364 330 2 0.8819 340 2 0.9275
300 2.2 0.7182 310 2.2 0.7592 320 2.2 0.8003 330 2.2 0.8413 340 2.2 0.8824
300 2.4 0.6895 310 2.4 0.7269 320 2.4 0.7642 330 2.4 0.8016 340 2.4 0.8389
300 2.6 0.6609 310 2.6 0.6952 320 2.6 0.7294 330 2.6 0.7637 340 2.6 0.7980
300 2.8 0.6332 310 2.8 0.6648 320 2.8 0.6965 330 2.8 0.7281 340 2.8 0.7598
300 3 0.6068 310 3 0.6362 320 3 0.6656 330 3 0.6950 340 3 0.7244
300 3.2 0.5818 310 3.2 0.6093 320 3.2 0.6368 330 3.2 0.6642 340 3.2 0.6917
300 3.4 0.5584 310 3.4 0.5842 320 3.4 0.6099 330 3.4 0.6357 340 3.4 0.6615
300 3.6 0.5365 310 3.6 0.5607 320 3.6 0.5850 330 3.6 0.6093 340 3.6 0.6335
300 3.8 0.5159 310 3.8 0.5389 320 3.8 0.5618 330 3.8 0.5847 340 3.8 0.6077
300 4 0.4967 310 4 0.5185 320 4 0.5402 330 4 0.5619 340 4 0.5837
300 4.2 0.4788 310 4.2 0.4994 320 4.2 0.5201 330 4.2 0.5407 340 4.2 0.5614
300 4.4 0.4620 310 4.4 0.4816 320 4.4 0.5013 330 4.4 0.5210 340 4.4 0.5407
300 4.6 0.4462 310 4.6 0.4650 320 4.6 0.4838 330 4.6 0.5026 340 4.6 0.5213
300 4.8 0.4314 310 4.8 0.4494 320 4.8 0.4674 330 4.8 0.4853 340 4.8 0.5033

T V P T V P T V P T V P T V P
350 1 1.0408 360 1 1.1415 370 1 1.2422 380 1 1.3429 390 1 1.4435
350 1.2 1.1125 360 1.2 1.1935 370 1.2 1.2745 380 1.2 1.3556 390 1.2 1.4366
350 1.4 1.1071 360 1.4 1.1749 370 1.4 1.2427 380 1.4 1.3105 390 1.4 1.3784
350 1.6 1.0710 360 1.6 1.1293 370 1.6 1.1876 380 1.6 1.2459 390 1.6 1.3042
350 1.8 1.0235 360 1.8 1.0746 370 1.8 1.1257 380 1.8 1.1769 390 1.8 1.2280
350 2 0.9730 360 2 1.0185 370 2 1.0641 380 2 1.1096 390 2 1.1551
350 2.2 0.9234 360 2.2 0.9644 370 2.2 1.0055 380 2.2 1.0465 390 2.2 1.0875
350 2.4 0.8763 360 2.4 0.9136 370 2.4 0.9510 380 2.4 0.9883 390 2.4 1.0257
350 2.6 0.8322 360 2.6 0.8665 370 2.6 0.9008 380 2.6 0.9351 390 2.6 0.9693
350 2.8 0.7915 360 2.8 0.8231 370 2.8 0.8548 380 2.8 0.8865 390 2.8 0.9181
350 3 0.7539 360 3 0.7833 370 3 0.8127 380 3 0.8421 390 3 0.8715
350 3.2 0.7192 360 3.2 0.7467 370 3.2 0.7741 380 3.2 0.8016 390 3.2 0.8291
350 3.4 0.6873 360 3.4 0.7130 370 3.4 0.7388 380 3.4 0.7646 390 3.4 0.7903
350 3.6 0.6578 360 3.6 0.6821 370 3.6 0.7063 380 3.6 0.7306 390 3.6 0.7549
350 3.8 0.6306 360 3.8 0.6535 370 3.8 0.6764 380 3.8 0.6994 390 3.8 0.7223
350 4 0.6054 360 4 0.6271 370 4 0.6489 380 4 0.6706 390 4 0.6923

3
350 4.2 0.5820 360 4.2 0.6027 370 4.2 0.6233 380 4.2 0.6440 390 4.2 0.6646
350 4.4 0.5603 360 4.4 0.5800 370 4.4 0.5997 380 4.4 0.6193 390 4.4 0.6390
350 4.6 0.5401 360 4.6 0.5589 370 4.6 0.5777 380 4.6 0.5965 390 4.6 0.6153
350 4.8 0.5213 360 4.8 0.5392 370 4.8 0.5572 380 4.8 0.5752 390 4.8 0.5932

T V P T V P T V P T V P T V P
400 1 1.5442 410 1 1.6449 420 1 1.7455 430 1 1.8462 440 1 1.9469
400 1.2 1.5177 410 1.2 1.5987 420 1.2 1.6798 430 1.2 1.7608 440 1.2 1.8419
400 1.4 1.4462 410 1.4 1.5140 420 1.4 1.5818 430 1.4 1.6496 440 1.4 1.7175
400 1.6 1.3625 410 1.6 1.4208 420 1.6 1.4791 430 1.6 1.5374 440 1.6 1.5957
400 1.8 1.2791 410 1.8 1.3303 420 1.8 1.3814 430 1.8 1.4325 440 1.8 1.4837
400 2 1.2007 410 2 1.2462 420 2 1.2917 430 2 1.3373 440 2 1.3828
400 2.2 1.1286 410 2.2 1.1696 420 2.2 1.2107 430 2.2 1.2517 440 2.2 1.2927
400 2.4 1.0630 410 2.4 1.1004 420 2.4 1.1377 430 2.4 1.1751 440 2.4 1.2124
400 2.6 1.0036 410 2.6 1.0379 420 2.6 1.0721 430 2.6 1.1064 440 2.6 1.1407
400 2.8 0.9498 410 2.8 0.9814 420 2.8 1.0131 430 2.8 1.0448 440 2.8 1.0764
400 3 0.9010 410 3 0.9304 420 3 0.9598 430 3 0.9892 440 3 1.0186
400 3.2 0.8566 410 3.2 0.8840 420 3.2 0.9115 430 3.2 0.9390 440 3.2 0.9665
400 3.4 0.8161 410 3.4 0.8419 420 3.4 0.8677 430 3.4 0.8934 440 3.4 0.9192
400 3.6 0.7791 410 3.6 0.8034 420 3.6 0.8277 430 3.6 0.8519 440 3.6 0.8762
400 3.8 0.7452 410 3.8 0.7682 420 3.8 0.7911 430 3.8 0.8140 440 3.8 0.8369
400 4 0.7140 410 4 0.7358 420 4 0.7575 430 4 0.7792 440 4 0.8010
400 4.2 0.6853 410 4.2 0.7059 420 4.2 0.7266 430 4.2 0.7472 440 4.2 0.7679
400 4.4 0.6587 410 4.4 0.6784 420 4.4 0.6980 430 4.4 0.7177 440 4.4 0.7374
400 4.6 0.6340 410 4.6 0.6528 420 4.6 0.6716 430 4.6 0.6904 440 4.6 0.7092
400 4.8 0.6111 410 4.8 0.6291 420 4.8 0.6471 430 4.8 0.6650 440 4.8 0.6830

4
2.0000

Series1
Series2
Series3
1.5000
Series4
Series5
Series7
Series8
Series9
Series10

1.0000 Series11
Series12
Series13
Series14
Series15
Series16
Series17
0.5000
Series18
Series19
Series20
Series21

0.0000
0 5 10 15 20 25