EQUILIBRIO DE FASES LIQUIDO VAPOR DEL ETANOL Y EL AGUA

ETANOL(1) AGUA(2)
TC 536.78 536.78
PC 61.4 51.6
Tb 351.4 373.2
VpA -8.51838 -8.53706
VpB 0.34163 1.45838 Patm 1.01325
VpC -5.73683 -2.7758 PHI 1
VpD 8.32581 -1.23303

ESPECIFICACIONES DEL GRUPO UNIFAC

MOLECULA sub grupo k Rk Qk vk1(etanol)

ETANOL CH3 1 0.9011 0.848 1
CH2 2 0.6744 0.54 1
OH 3 1 1.2 1
AGUA H2O 4 0.92 1.4 0

PARAMETROS DE INTERACCION BINARIA aij

aij CH3 CH2 OH H2O

CH3 0 0 986.5 1318
CH2 0 0 986.5 1318
OH 156.4 156.4 0 353.5
H2O 300 300 -229.1 0

0 x1 x2 TOC TK r1 r2 R
1 0 1 99.9852989 373.135299 2.5755 0.92 0.92
2 0.05 0.95 89.3783282 362.528328 2.5755 0.92 1.002775
3 0.1 0.9 85.7542604 358.90426 2.5755 0.92 1.08555
4 0.15 0.85 84.034088 357.184088 2.5755 0.92 1.168325
5 0.2 0.8 83.0068964 356.156896 2.5755 0.92 1.2511
6 0.25 0.75 82.2708615 355.420862 2.5755 0.92 1.333875
7 0.3 0.7 81.6698231 354.819823 2.5755 0.92 1.41665
8 0.35 0.65 81.1427009 354.292701 2.5755 0.92 1.499425
9 0.4 0.6 80.6621453 353.812145 2.5755 0.92 1.5822
10 0.45 0.55 80.2169399 353.36694 2.5755 0.92 1.664975
11 0.5 0.5 79.8049139 352.954914 2.5755 0.92 1.74775
12 0.55 0.45 79.425818 352.575818 2.5755 0.92 1.830525
13 0.6 0.4 79.0824212 352.232421 2.5755 0.92 1.9133
14 0.65 0.35 78.7772498 351.92725 2.5755 0.92 1.996075
15 0.7 0.3 78.5131848 351.663185 2.5755 0.92 2.07885
16 0.75 0.25 78.2948595 351.444859 2.5755 0.92 2.161625
17 0.8 0.2 78.127961 351.277961 2.5755 0.92 2.2444
18 0.85 0.15 78.0203186 351.170319 2.5755 0.92 2.327175
19 0.9 0.1 77.9840294 351.134029 2.5755 0.92 2.40995
20 0.95 0.05 78.039995 351.189995 2.5755 0.92 2.492725
21 1 0 78.2290071 351.379007 2.5755 0.92 2.5755
NOL Y EL AGUA

vk2(agua
0
0
0
1

q1 q2 Q O1 O2 O3 O4 T11
2.588 1.4 1.4 0 0 0 1 1
2.588 1.4 1.4594 0.05 0.05 0.05 0.95 1
2.588 1.4 1.5188 0.1 0.1 0.1 0.9 1
2.588 1.4 1.5782 0.15 0.15 0.15 0.85 1
2.588 1.4 1.6376 0.2 0.2 0.2 0.8 1
2.588 1.4 1.697 0.25 0.25 0.25 0.75 1
2.588 1.4 1.7564 0.3 0.3 0.3 0.7 1
2.588 1.4 1.8158 0.35 0.35 0.35 0.65 1
2.588 1.4 1.8752 0.4 0.4 0.4 0.6 1
2.588 1.4 1.9346 0.45 0.45 0.45 0.55 1
2.588 1.4 1.994 0.5 0.5 0.5 0.5 1
2.588 1.4 2.0534 0.55 0.55 0.55 0.45 1
2.588 1.4 2.1128 0.6 0.6 0.6 0.4 1
2.588 1.4 2.1722 0.65 0.65 0.65 0.35 1
2.588 1.4 2.2316 0.7 0.7 0.7 0.3 1
2.588 1.4 2.291 0.75 0.75 0.75 0.25 1
2.588 1.4 2.3504 0.8 0.8 0.8 0.2 1
2.588 1.4 2.4098 0.85 0.85 0.85 0.15 1
2.588 1.4 2.4692 0.9 0.9 0.9 0.1 1
2.588 1.4 2.5286 0.95 0.95 0.95 0.05 1
2.588 1.4 2.588 1 1 1 0 1
T21 T31 T41 T12 T22 T32 T42 T13
1 0.65760495 0.44753617 1 1 0.65760495 0.44753617 0.07108968
1 0.64958956 0.43713136 1 1 0.64958956 0.43713136 0.06579795
1 0.64676594 0.43349392 1 1 0.64676594 0.43349392 0.06401461
1 0.64541004 0.43175239 1 1 0.64541004 0.43175239 0.06317282
1 0.64459549 0.43070779 1 1 0.64459549 0.43070779 0.06267161
1 0.64400957 0.42995714 1 1 0.64400957 0.42995714 0.06231316
1 0.6435297 0.42934283 1 1 0.6435297 0.42934283 0.06202087
1 0.64310781 0.42880308 1 1 0.64310781 0.42880308 0.06176485
1 0.64272233 0.4283102 1 1 0.64272233 0.4283102 0.0615317
1 0.64236448 0.42785289 1 1 0.64236448 0.42785289 0.06131593
1 0.64203267 0.42742907 1 1 0.64203267 0.42742907 0.06111643
1 0.64172685 0.42703862 1 1 0.64172685 0.42703862 0.06093304
1 0.64144939 0.42668453 1 1 0.64144939 0.42668453 0.06076705
1 0.64120245 0.42636951 1 1 0.64120245 0.42636951 0.06061965
1 0.64098851 0.42609668 1 1 0.64098851 0.42609668 0.06049219
1 0.64081144 0.42587092 1 1 0.64081144 0.42587092 0.06038686
1 0.64067597 0.42569824 1 1 0.64067597 0.42569824 0.06030638
1 0.64058854 0.42558681 1 1 0.64058854 0.42558681 0.06025449
1 0.64055905 0.42554924 1 1 0.64055905 0.42554924 0.060237
1 0.64060452 0.42560719 1 1 0.64060452 0.42560719 0.06026397
1 0.640758 0.4258028 1 1 0.640758 0.4258028 0.0603551
T23 T33 T43 T14 T24 T34 T44 S11
0.07108968 1 1.84778274 0.02923961 0.02923961 0.38775657 1 2.17712594
0.06579795 1 1.88127665 0.02636869 0.02636869 0.37715606 1 2.16750747
0.06401461 1 1.89331979 0.02541823 0.02541823 0.37346076 1 2.16411913
0.06317282 1 1.89914912 0.02497265 0.02497265 0.37169348 1 2.16249204
0.06267161 1 1.90266556 0.0247083 0.0247083 0.37063405 1 2.16151459
0.06231316 1 1.9052018 0.02451967 0.02451967 0.36987302 1 2.16081148
0.06202087 1 1.9072832 0.02436613 0.02436613 0.36925039 1 2.16023564
0.06176485 1 1.90911632 0.02423184 0.02423184 0.36870346 1 2.15972937
0.0615317 1 1.9107938 0.02410971 0.02410971 0.36820414 1 2.15926679
0.06131593 1 1.91235327 0.02399682 0.02399682 0.36774094 1 2.15883737
0.06111643 1 1.91380116 0.02389256 0.02389256 0.36731174 1 2.15843921
0.06093304 1 1.9151373 0.02379683 0.02379683 0.36691641 1 2.15807222
0.06076705 1 1.9163509 0.02371026 0.02371026 0.36655793 1 2.15773926
0.06061965 1 1.91743205 0.02363345 0.02363345 0.36623907 1 2.15744294
0.06049219 1 1.91836957 0.02356708 0.02356708 0.36596293 1 2.15718622
0.06038686 1 1.91914612 0.02351227 0.02351227 0.36573447 1 2.15697373
0.06030638 1 1.91974061 0.02347042 0.02347042 0.36555973 1 2.15681116
0.06025449 1 1.92012442 0.02344344 0.02344344 0.36544699 1 2.15670624
0.060237 1 1.92025389 0.02343435 0.02343435 0.36540897 1 2.15667086
0.06026397 1 1.92005424 0.02344837 0.02344837 0.3654676 1 2.15672543
0.0603551 1 1.91938059 0.02349575 0.02349575 0.36566554 1 2.1569096
S21 S31 S41 S12 S22 S32 S42 N1
2.17712594 1.29867247 0.50589247 0.62655064 0.62655064 2.58689584 1.4 0.62655064
2.16750747 1.29132755 0.48918702 0.6119839 0.6119839 2.63378731 1.4 0.68976008
2.16411913 1.28885228 0.48343342 0.60689149 0.60689149 2.65064771 1.4 0.76261425
2.16249204 1.28768387 0.48069422 0.60445334 0.60445334 2.65880876 1.4 0.83815915
2.16151459 1.2869882 0.47905597 0.60299091 0.60299091 2.66373179 1.4 0.91469564
2.16081148 1.28649066 0.47788092 0.60193999 0.60193999 2.66728253 1.4 0.99165786
2.16023564 1.28608497 0.47692065 0.60107996 0.60107996 2.67019648 1.4 1.06882666
2.15972937 1.28572961 0.47607795 0.60032431 0.60032431 2.67276284 1.4 1.14611608
2.15926679 1.285406 0.47530925 0.59963428 0.59963428 2.67511131 1.4 1.22348729
2.15883737 1.28510651 0.47459672 0.59899405 0.59899405 2.67729458 1.4 1.30092354
2.15843921 1.2848296 0.47393697 0.5984007 0.5984007 2.67932163 1.4 1.37841995
2.15807222 1.28457506 0.47332968 0.59785407 0.59785407 2.68119222 1.4 1.45597405
2.15773926 1.28434467 0.47277936 0.59735834 0.59735834 2.68289126 1.4 1.53358689
2.15744294 1.28414008 0.47229011 0.59691732 0.59691732 2.68440487 1.4 1.61125898
2.15718622 1.28396316 0.47186663 0.59653535 0.59653535 2.6857174 1.4 1.68899096
2.15697373 1.28381696 0.47151641 0.59621929 0.59621929 2.68680456 1.4 1.76678512
2.15681116 1.28370526 0.47124862 0.59597753 0.59597753 2.68763685 1.4 1.84464444
2.15670624 1.28363323 0.47107588 0.59582154 0.59582154 2.68817419 1.4 1.92257354
2.15667086 1.28360895 0.47101764 0.59576894 0.59576894 2.68835545 1.4 2.00058067
2.15672543 1.2836464 0.47110746 0.59585006 0.59585006 2.68807594 1.4 2.07868166
2.1569096 1.28377288 0.47141075 0.59612392 0.59612392 2.68713283 1.4 2.1569096
N2 N3 N4 lnK1 K1 lnK2 K2 alfa1
0.62655064 2.58689584 1.4 1.90977158 6.75154644 0 1 0.30486363
0.68976008 2.56666432 1.35445935 1.52491431 4.59474983 0.00986304 1.00991184 0.324624
0.76261425 2.51446817 1.30834334 1.21884402 3.38327448 0.0346609 1.03526859 0.3313755
0.83815915 2.45314003 1.26210413 0.97789012 2.65884048 0.06901033 1.07144728 0.334580111
0.91469564 2.38838307 1.21581119 0.78688252 2.19653808 0.10943314 1.11564547 0.33649373
0.99165786 2.32208456 1.16947023 0.63416417 1.88544556 0.15367186 1.16610817 0.33786493
1.06882666 2.25496303 1.1230762 0.51111159 1.66714335 0.20024736 1.22170493 0.33898464
1.14611608 2.18730121 1.07662728 0.41131955 1.50880742 0.24819336 1.28170774 0.33996665
1.22348729 2.11922919 1.0301237 0.32996541 1.39092001 0.29689847 1.34567867 0.34086191
1.30092354 2.05080995 0.98356852 0.26336484 1.3013014 0.34600969 1.41341632 0.34169131
1.37841995 1.98207562 0.93696849 0.20866456 1.23203165 0.39537612 1.4849426 0.3424589
1.45597405 1.91305278 0.89033133 0.16362741 1.17777541 0.44502136 1.56052353 0.34316514
1.53358689 1.84376331 0.84366761 0.12648367 1.13483092 0.49513671 1.64072253 0.34380487
1.61125898 1.77423275 0.79698857 0.09582616 1.10056772 0.5460948 1.72649752 0.34437339
1.68899096 1.70448943 0.75030664 0.07053946 1.07308692 0.5984843 1.81935911 0.34486534
1.76678512 1.63456386 0.7036373 0.04975543 1.05101402 0.65317193 1.92162645 0.34527207
1.84464444 1.56449157 0.65699889 0.03283175 1.03337666 0.71140214 2.03684521 0.34558299
1.92257354 1.49431438 0.6104145 0.01935563 1.01954416 0.77495258 2.17048919 0.34578353
2.00058067 1.4240836 0.56391588 0.00917859 1.00922084 0.84637656 2.33118463 0.34585113
2.07868166 1.35386787 0.51755208 0.00249624 1.00249936 0.92938476 2.53295033 0.34574687
2.1569096 1.28377288 0.47141075 0 1 1.02945153 2.79952997 0.34539475
ln(Pvp/Pc) Pvp alfa2 ln(pvp/pc) Pvp y1 y2 y1+y2
-3.87737511 1.2712933 0.30486363 -3.50548895 1.54965562 0 1.52939118 1.52939118
-4.27701345 0.85248163 0.324624 -3.84674246 1.10161712 0.19328595 1.04308844 1.23637439
-4.42003401 0.73887673 0.3313755 -3.9684687 0.97536158 0.24671333 0.89690114 1.14361447
-4.48912537 0.68955037 0.334580111 -4.02720758 0.91972009 0.27141442 0.82666355 1.09807798
-4.53075978 0.66143078 0.33649373 -4.06258426 0.88775223 0.28677185 0.78197228 1.06874413
-4.56076796 0.6418773 0.33786493 -4.08807345 0.8654101 0.29859973 0.74697394 1.04557367
-4.5853814 0.62627133 0.33898464 -4.10897501 0.84750941 0.30912926 0.71530668 1.02443594
-4.607049 0.61284749 0.33996665 -4.1273711 0.83206108 0.31940202 0.68413366 1.00353568
-4.62686881 0.60082055 0.34086191 -4.14419527 0.81817944 0.32990607 0.65196543 0.98187151
-4.64528738 0.58985559 0.34169131 -4.15982735 0.80548904 0.34089411 0.61798198 0.95887609
-4.66238206 0.57985789 0.3424589 -4.1743336 0.79388876 0.35253061 0.58173167 0.93426228
-4.67815205 0.57078526 0.34316514 -4.18771387 0.78333707 0.36490625 0.54289382 0.90780008
-4.69247149 0.56267017 0.34380487 -4.19986184 0.77387867 0.37811133 0.50124655 0.87935789
-4.70522455 0.55553997 0.34437339 -4.21067975 0.76555204 0.39221918 0.45655396 0.84877314
-4.7162808 0.54943162 0.34486534 -4.2200574 0.75840652 0.4073146 0.40853111 0.81584571
-4.7254367 0.54442403 0.34527207 -4.22782258 0.75254017 0.42353612 0.3567977 0.78033382
-4.73244493 0.54062192 0.34558299 -4.23376592 0.74808083 0.44108843 0.3007599 0.74184834
-4.7369691 0.53818158 0.34578353 -4.23760246 0.74521628 0.46029598 0.23944987 0.69974585
-4.73849506 0.53736097 0.34585113 -4.23889646 0.7442526 0.48170175 0.17123022 0.65293197
-4.73614187 0.53862697 0.34574687 -4.23690097 0.74573923 0.5062665 0.09321098 0.59947747
-4.72820097 0.54292118 0.34539475 -4.23016686 0.75077807 0.53582154 0 0.53582154
x1 y1 TK y1exp Texp K1 K2
0 0 373.135299 0 100 373 6.75154644 1
0.05 0.19328595 362.528328 0.323 90.8 363.8 4.59474983 1.00991184
0.1 0.24671333 358.90426 0.432 86.8 359.8 3.38327448 1.03526859
0.15 0.27141442 357.184088 0.496 84.5 357.5 2.65884048 1.07144728
0.2 0.28677185 356.156896 0.534 83.2 356.2 2.19653808 1.11564547
0.25 0.29859973 355.420862 0.56 82.4 355.4 1.88544556 1.16610817
0.3 0.30912926 354.819823 0.575 81.8 354.8 1.66714335 1.22170493
0.35 0.31940202 354.292701 0.595 81.3 354.3 1.50880742 1.28170774
0.4 0.32990607 353.812145 0.621 80.8 353.8 1.39092001 1.34567867
0.45 0.34089411 353.36694 0.636 80.4 353.4 1.3013014 1.41341632
0.5 0.35253061 352.954914 0.654 80 353 1.23203165 1.4849426
0.55 0.36490625 352.575818 0.673 79.7 352.7 1.17777541 1.56052353
0.6 0.37811133 352.232421 0.698 79.35 352.35 1.13483092 1.64072253
0.65 0.39221918 351.92725 0.729 79 352 1.10056772 1.72649752
0.7 0.4073146 351.663185 0.757 78.76 351.76 1.07308692 1.81935911
0.75 0.42353612 351.444859 0.784 78.56 351.56 1.05101402 1.92162645
0.8 0.44108843 351.277961 0.827 78.37 351.37 1.03337666 2.03684521
0.85 0.46029598 351.170319 0.867 78.22 351.22 1.01954416 2.17048919
0.9 0.48170175 351.134029 0.897 78.16 351.16 1.00922084 2.33118463
0.95 0.5062665 351.189995 0.948 78.23 351.23 1.00249936 2.53295033
1 0.53582154 351.379007 1 78.32 351.32 1 2.79952997
LnK1/K2
1.90977158
1.51505127
1.18418313
0.90887979
0.67744938 0 0
0.48049231 1 1
0.31086423
0.16312619
0.03306693
-0.08264486
-0.18671156
-0.28139395
-0.36865303
-0.45026864
-0.52794484
-0.6034165
-0.6785704
-0.75559695
-0.83719797
-0.92688852
-1.02945153