Tabla Nº1: Datos experimentales en la

titulación de H3PO4
Volumen (ml) pH
0 2
1 2.11
2 2.22
3 2.39
4 2.67
5 3.21
6 3.45
7 3.62
8 3.93
8.5 4.07
9 4.53
9.5 5.04
Chart Title
10 5.32
8
10.5 5.42
11 5.51 7
11.5 5.64 f(x) = 1.28948725807302E-05x^6 - 0.0005945518x^5 + 0.0101112932x^4 - 0.078819576x^3 + 0
6R² = 0.9929335627
12 6.2
5
13 6.32
14 6.56 4
15 6.75 3
16 6.9
2
17 7.07
18 7.24 1
19 7.44 0
20 7.63 0 2 4 6 8 10 12 14 16

21 7.97
22 8.8
23 10.51 Chart Title
24 10.95
12
25 11.18 f(x) = - 2.96479531082629E-07x^6 + 2.96784833352484E-05x^5 - 0.0004418156x^4 - 0.0494732252x^3 + 2.4
R² = 0.9812721002
26 11.34 11
27 11.45
28 11.55 10
29 11.62
9
30 11.68
31 11.74
8
32 11.8
33 11.83 7
34 11.87
35 11.92 6
15 20 25 30 35 40
36 11.96
37.5 12 Titulación potenciómetrica de H3PO4 con
38.5 12.04 12
39.5 12.05
40 12.06 10

6
pH
 12

10

pH
4

0
0 5 10 15 20 25 3

Volumen titulante de NaOH (ml)

 Chart Title

-05x^6 - 0.0005945518x^5 + 0.0101112932x^4 - 0.078819576x^3 + 0.2993735123x^2 - 0.2605629198x + 2.0376791724

6 8 10 12 14 16

Chart Title
^6 + 2.96784833352484E-05x^5 - 0.0004418156x^4 - 0.0494732252x^3 + 2.4108855296x^2 - 40.3424329812x + 240.8759052058

25 30 35 40
enciómetrica de H3PO4 con NaOH
 15 20 25 30 35 40

olumen titulante de NaOH (ml)

 0 2.32
1 2.45 Chart Title
2 2.64 8
2.9 2.99 f(x)
7 = 0.0407533665x^6 - 0.7178469214x^5 + 4.7196815095x^4 - 14.1797865743x^3 + 19.1433829308x^2 - 8.9101878358x + 2.323329
3.3 3.23 R² = 0.9820137104

3.4 3.34 6

3.5 3.53 5
3.6 3.86
4
3.7 4.07
3
3.8 4.98
3.9 5.67 2
4.1 6.16 1
4.2 6.33
0
4.3 6.45 0 1 2 3 4 5 6
4.9 6.92
5.1 7.06
5.3 7.2
5.4 7.37
5.6 7.5
5.8 7.68
5.9 7.8 Chart Title
6 7.94
12
6.1 8.42 f(x) = - 0.1582152404x^6 + 6.4688530811x^5 - 109.1159328873x^4 + 971.6218857302x^3 - 4815.8724487258x^2 + 12597.8380265112x - 13583.6
R² = 0.9932530236
6.2 8.82 10
6.3 9.28
6.4 9.47 8
6.5 9.94
6.6 10.03 6
6.7 10.12
4
6.8 10.29
6.9 10.4 2
7 10.48
7.5 10.82 0
4.5 5 5.5 6 6.5 7 7.5 8 8.5 9 9.5
8 10.97
9 11.22
10.5 11.42
11.5 11.51
12.5 11.58
14 11.67
16 11.76
18 11.83
20.5 11.92
23 11.97
26 12.05
29 12.1
31 12.13
32 12.15
34 12.17
36 12.19
38 12.27
40 12.28
65743x^3 + 19.1433829308x^2 - 8.9101878358x + 2.3233292163

5 6

857302x^3 - 4815.8724487258x^2 + 12597.8380265112x - 13583.6139297029

9 9.5
 0 2.22
1 2.28
2 2.4
3 2.41
Chart Title
4 2.5 7
5 2.6
6
6 2.72 f(x) = - 0.0001576691x^6 + 0.0049532351x^5 - 0.0569309088x^4 + 0.2966571086x^3 - 0.6842349428x^2 + 0.6161442684x + 2.1966
7 2.88 5R² = 0.9925994202
8 3.1
4
9 3.5
9.5 4.2 3
9.6 4.33
2
9.7 4.42
9.8 4.6 1
9.9 4.97
0
10 5.12 0 2 4 6 8 10 12 14
10.1 5.23
10.2 5.32
10.3 5.43
10.6 5.62
10.7 5.67
10.9 5.74
11.1 5.82
11.3 5.87
11.5 5.94
11.7 5.98
11.9 6.04
12 6.05
12.5 6.16
13 6.24
13.5 6.34
14 6.39
15 6.51
15.5 6.57
16.5 6.63
17.5 6.77
18.5 6.86
17.5 6.77
18.5 6.86
19.5 6.97
20.5 7.05
21.5 7.15
22.7 7.26
23.5 7.35
24.5 7.47
25.5 7.6
26.5 7.79
27.5 8.02
28.5 8.47
29.5 9.83
30 10.28
30.6 10.57
31 10.72
31.5 10.84
32 10.91
66571086x^3 - 0.6842349428x^2 + 0.6161442684x + 2.1966298981

12 14