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ACI MATERIALS JOURNAL TECHNICAL PAPER

Title No. 112-M04

Concrete Made with Recycled Glass Aggregates:


Mechanical Performance
by Diogo Serpa, Jorge de Brito, and Jorge Pontes

This study aims at characterizing the mechanical performance of the environmental impact associated with both quarries and
concrete made with varying glass content (5, 10, and 20% of the dumps for solid waste.
overall volume of aggregates) and analyzing the influence of the
size of these aggregates (fine, coarse, or both) on that performance. RESEARCH SIGNIFICANCE
The use of glass aggregates as an environmentally friendly alter-
This study assesses whether glass waste can be used
native to dumping it as waste reduces the consumption of natural
as aggregate in concrete to help solve the environmental
resources and requires the space needed for dumping grounds. The
aggregates were studied in terms of density and abrasion. Fresh problem of its disposal. The innovative aspects are linked to
concrete was tested for workability and density. Hardened concrete the use of a constant aggregate grading distribution, deter-
was tested for compressive, splitting tensile, and flexural strength; mined according to Faury’s method, and the determination
modulus of elasticity; and abrasion wear. It was found that the of the influence of different sizes and replacement ratios of
incorporation of glass aggregates in concrete leads to a loss of its glass aggregates on various characteristics of mechanical
mechanical performance, although this is not significant for ratios performance (compressive, splitting tensile, and flexural
of up to 10% of the volume of natural aggregates, except for abra- strength; modulus of elasticity; and abrasion wear) over
sion resistance, where there is an improvement. A better perfor- time. The goal was to confirm/refute results for some of the
mance was seen in concrete with coarse glass aggregates, followed properties from previous works as well as to present new
by concrete with fine glass aggregates, and finally, concrete with
data that may improve understanding of the properties of
the simultaneous incorporation of coarse and fine glass aggregates.
concrete with recycled glass aggregates. This work supple-
Keywords: mechanical performance; recycled glass aggregates; sustainability. ments those of Serpa et al.,16 which studies the alkali-silica
reaction vulnerability of concrete with recycled glass aggre-
INTRODUCTION gate, and Castro et al.,17 which evaluates the durability
The treatment and elimination of waste, frequent resort performance of similar types of concrete.
to dumping, and excessive consumption of raw materials
are growing concerns. The United Nations has estimated LITERATURE REVIEW
the annual production of waste to be around 4.409 × 1011 lb General introduction
(200 million tonnes), of which 7% is glass.1 The studies mentioned in this section have used various
In Portugal, according to INE’s national statistics,2 each materials in different conditions; therefore, it was deemed
person produced 1036 lb (470 kg) of solid waste per year necessary to detail some fundamental parameters.
in the 2004-2009 period, and the highest figure in terms of Al-Sibahy et al.4 used glass to produce lightweight
glass was for 2008 with 2.121 × 109 lb (962,041 tonnes). concrete where expanded clay was used as coarse aggre-
Meanwhile, in 2009, a total of €374.7 million of products gate, natural sand as fine aggregate, and 0.0197 to 0.0394 in.
made with glass was consumed. Oliveira et al.3 reports that (0.5 to 1 mm) and 0.0394 to 0.0788 in. (1 to 2 mm) glass
from 1999 to 2005, in Portugal, only 30% of the glass was replaced natural aggregates at ratios of 15, 30, and 45%.
recycled and 70% was dumped. According to Al-Sibahy and The glass had different colors but its origin was not stated.
Edwards,4 in the UK, 6.415 × 1010 lb (29.1 million tonnes) of Metakaolin was also used as hydraulic binder replacement
waste are produced per year, of which 4.2% are glass. Wang at ratios of 5 and 10%. Chen et al.18 used industrial glass
and Huang,5 Wang,6 and Su and Chen7 state that Taiwan from LCD production to replace fine aggregates at 10, 20,
produced 1.1 × 109 lb (500,000 tonnes) of glass per year, and 30% ratios. They also used pozzolanic materials such as
part of which comes from glass produced for LCDs, which fly ash and blast furnace slag. Wang and Huang5 used glass
is unfit for dumping because of its chemical treatment. This from LCD production to replace fine aggregates at 10, 20,
whole situation involves considerable energy consumption and 30% ratios. Blast-furnace slag was also used.
because glass is produced at high temperatures, and increased Kou and Poon19 used recycled glass from waste bottles to
environmental impacts due to raw material consumption and replace fine and coarse aggregates up to 0.394 in. (10 mm)
space taken by dumping grounds. These aspects ought to
be improved. ACI Materials Journal, V. 112, No. 1, January-February 2015.
MS No. M-2012-184.R3, doi: 10.14359/51687366, received October 25, 2012, and
Like other waste materials (plastics,8,9 rubber,10,11 reviewed under Institute publication policies. Copyright © 2015, American Concrete
concrete,12,13 and ceramics14,15), glass can be incorporated in Institute. All rights reserved, including the making of copies unless permission is
obtained from the copyright proprietors. Pertinent discussion including author’s
concrete to partly replace natural aggregates and thus reduce closure, if any, will be published ten months from this journal’s date if the discussion
is received within four months of the paper’s print publication.

ACI Materials Journal/January-February 2015 29


at 10, 20, and 30% ratios. Fly ash was added to the mixtures. and the GA incorporation ratio. Terro23 found a CS reduction
Wang6 used glass from LCD production and replaced the for high replacement percentages, but a replacement of 50%
fine fraction at 20, 40, 60, and 80% ratios. of coarse glass aggregates (CGA) led to a lower CS than a
Ismail and Al-Hashmi20 studied the use of waste from replacement of 100%. Alhumoud et al.22 obtained a contin-
the Iraqi state company for glass production, replacing fine uous decrease of CS as the incorporation of CGA increased,
aggregates at ratios of 10, 15, and 20%. but for a 10% ratio, the CS was higher than that of the refer-
Limbachiya21 used glass bottle waste of different colors at ence concrete (RC). When replacing coarse aggregates (CA)
ratios of 65 to 70% for green glass, 25 to 30% for transparent and fine aggregates (FA) simultaneously, Kou and Poon19
glass, and 5% for brown glass. A chemical analysis showed showed that the CS fell with the ratio of replacement of NA
it was soda-lime glass. Limbachiya21 replaced 15, 20, 30, by GA, but it increased with age for each mixture. Terro23
and 50% of the fine aggregates. compared three replacement options (CA only, FA only, and
Oliveira et al.3 used amber glass crushed in a jaw-crusher CA and FA) and showed that for the same replacement ratio,
to replace natural sand with particles smaller than 0.1875 in. it was not obvious which glass aggregates’ size confers the
(4.76 mm) at replacement ratios of 15, 50, and 100%. best performance. For a fixed overall replacement ratio,
Alhumoud et al.22 used a soda-lime glass aggregate from however, the mixture of coarse and fine aggregates always
crushed bottles to replace all aggregates (fine and coarse, yielded the worst performance. Alhumoud et al.22 showed
both alternatively and simultaneously) at ratios of 10, 25, 50, that the replacement of CA led to better results than that of
and 100%. Terro,23 just like Alhumoud et al.,22 used various FA, and that the CA + FA option yielded the worst results in
sizes (fine, coarse, and both) to replace natural aggregates at terms of CS, except for the 50% replacement ratio, where the
ratios of 10, 25, 50, and 100%. FA gave better results than the CA. Park et al.24 suggested
Park et al.24 incorporated glass sand as replacement of that the decrease of CS for greater incorporation ratios of
fine natural aggregates in concrete at 30, 50, and 70% ratios. FGA could be due to a loss of adhesion between cement
Glass was procured from green-, amber-, and flint-colored paste and aggregate.
bottles and glassware.
Topçu and Canbaz1 used glass from colored bottles as Splitting tensile strength
0.1576 to 0.6304 in. (4 to 16 mm) aggregates to replace the The splitting tensile strength (STS) is also frequently
same-sized natural aggregates at 15, 30, 45, and 60% ratios. reported in the literature. Generally it decreases as the GA’s
incorporation ratio increases. Topçu and Canbaz1 found the
Workability same trend for the incorporation of CGA, and Wang6 again
When recycled glass aggregates are used to replace found this trend for 28-day STS, with incorporation of FGA.
natural aggregates, there is no agreement as to the repercus- Park et al.24 found also that the greater the percentage replace-
sions on workability: some authors report that it increases ment of FNA in concrete, the lower the resulting STS; they
workability,4,5,18,19,22,23 even though the use of additions such also found that just as for the CS, a lower-quality paste-aggre-
as pozzolans may influence the results,18 and others argue gate adhesion leads to lower STS for greater incorporation of
that it decreases due to the geometry of the material.1,3,20,21,24 recycled aggregates. For mixtures of aggregate sizes, Kou and
Poon19 also determined that the STS falls as the incorporation
Density of recycled aggregates goes up.
The literature is unanimous when it comes to concrete The authors are unaware of published studies that compare
density, because glass has a lower density than natural the STS of mixture with CGA, FGA and a mixture of
aggregates, which in turn lowers the density of concrete with both (CFGA).
glass aggregates.
Flexural strength
Compressive strength Another important characteristic of concrete is its flexural
Even though results vary from study to study, it is found strength (FS). Topçu and Canbaz1 had nonconclusive results,
that increasing the incorporation of glass aggregates in because there is an apparent decrease in FS as the incor-
concrete leads to a loss of compressive strength (CS) at poration of GA, increases but the comparison of different
the same age, but its value still increases over time, as in concrete families does not show a direct correlation between
conventional concrete. Chen et al.18 and Wang6 replaced fine CGA and FS. In concrete with FGA, Park et al.24 showed
natural aggregates (FNA) with fine glass aggregates (FGA) a decrease in 28-day FS with higher FGA content, but no
from LCDs and although the CS decreased, within each linear correlation, becuase the FS’s drop between 0 and 30%
mixture it increased over time. Park et al.24 also showed that incorporation is much less pronounced than it is between
increasing the replacement of natural aggregates (NA) by 30 and 50% and between 50 and 70%. Limbachiya21 showed
glass aggregates (GA) decreases the CS, but there is no linear there was a decrease in FS, but only for ratios of 20% or
correlation between CS and GA content. However, Limba- more; for lower ratios, the FS was the same as that of the
chiya21 demonstrated that for replacement ratios up to 20%, RC. Wang6 found a reduction of 28-day FS for greater FGA
the CS does not change significantly, but it does for higher incorporation ratios.
ratios. For bigger aggregates Topçu and Canbaz1 reported a The authors are unaware of any published literature
decrease of the CS as the replacement ratio increased and comparing the FS performance of concrete with FGA only,
noted that there was proportionality between the loss of CS CGA only, and FGA and CGA simultaneously.

30 ACI Materials Journal/January-February 2015


Table 1—Main characteristics of mixtures produced
ID RC C05C C10C C20C C05F C10F C20F C05FC C10FC C20FC
Aggregates replaced, % 0.00 5.00 10.00 19.6 5.00 10.00 20.00 5.00 10.00 20.00
Fine aggregates replaced, % 0.00 0 0 0 11.14 22.27 44.54 5.57 11.14 22.27
Coarse aggregates replaced, % 0.00 9.07 18.15 35.57 0.00 0.00 0.00 4.54 9.07 18.15
w/c 0.55 0.55 0.55 0.55 0.55 0.57 0.58 0.55 0.55 0.57

Modulus of elasticity at a metakaolin/glass ratio of 22%, improves the STS and


Studies indicate a general trend towards a decrease in improves the ME by as much as 43%.”
the modulus of elasticity (ME) as the incorporation of
GA in concrete increases. Topçu and Canbaz1 found that Abrasion resistance
with the highest CGA incorporation ratios in concrete the No study was found in the literature from referenced scien-
ME decreased, but just as for the FS this decrease was not tific journals in which the abrasion resistance of concrete
linear, since there were discrepancies between mixtures with with recycled glass aggregates was analyzed.
different CGA ratios. Limbachiya21 reported that FGA incor-
porations up to 20% do not change the value of the ME, EXPERIMENTAL PLAN
but, for higher ratios, the ME goes down. Kou and Poon19 Materials
showed that the 28-day ME decreases as the incorporation Natural aggregates (NA) and recycled glass aggre-
ratio of CGA and FGA increases. gates (GA) were used. The NA were limestone gravel and
We are unaware of literature that compares the ME of river sand. The glass waste came from a Portuguese waste
concrete mixtures with GA of different sizes and varying management firm and was soda-lime obtained from firms
incorporation ratios. that produce construction and automobile glass. This glass
was collected, screened, washed, and crushed to standard
Correlations between mechanical properties size ranges, all of which were used in this research. The
Eurocode 224 states that the average values of ME (Ecm) concrete was produced with CEM II A-L 42.5-type cement
can be correlated with the characteristic values of CS (fck) and tap water.
using Eq. (1)
Composition of concrete mixtures
Ecm = 0.30 × fck2/3 (1) In accordance with EN 206-1,26 a reference concrete
(RC) was produced with a target CS, measured in cubes,
The average values of STS (fctm) can also be correlated with of 6281.7 psi (44 MPa), and workability within the slump
the characteristic values of CS using Eq. (2) range (Abrams cone test) of 4.92 ± 0.39 in. (125 ± 10 mm).
According to the standard, this corresponds to a C30/37
fctm = 0.30 × fck2/3 (2) strength class (strength at 28 days of 4351.1 psi [30 MPa] in
cylinders with a diameter of 5.91 in. [15 cm] or of 5366 psi
For concrete with recycled glass aggregates, Kou and Poon19 [37 MPa] in cubes with a side of 5.91 in. [15 cm]). The
obtained a correlation between the average values of ME mixtures’ volumetric proportions are given in Table A1 in
and the average values of CS (fcm), using Eq. (3) the Appendix.*
The GA were incorporated in concrete as replacement by
Ecm = 2.9858 × fcm0.565 (3) volume of NA, according to their size (that is, keeping the
grading distribution constant in all mixtures). A total of 10
Also, for concrete with recycled glass aggregates, Park concrete mixtures were prepared.
et al.24 determined a correlation between the average values The replacement ratios were determined as a function
of STS and the average values of CS, using Eq. (4), and the of the overall volume of fine and coarse aggregates and
average values of FS (fctm,f) were correlated with the average were: 5, 10, and 20% (Table 1). In terms of glass particle
value of CS, using Eq. (5) sizes, in some mixtures, only fine aggregates (FGA) were
used; in others, only coarse (CGA); and in yet others, fine
fctm = –0.001 × fcm2 + 0.1089 × fcm (4) and coarse simultaneously. Fine particles here were those
passing through the 0.157 in. (4 mm) sieve, while coarse
fctm,f = –0.0004 × fcm2 + 0.1622 × fcm (5) particles were those passing through the 0.88 in. (22.4 mm)
sieve for NA and the 0.44 in. (11.2 mm) sieve for GA and
were retained in the 0.157 in (4 mm) sieve. The difference in
Incorporation of additions
It was found that the use of pozzolans can help to improve
the mechanical performance of concrete with GA. Al- *
The Appendix is available at www.concrete.org/publications in PDF format,
Sibahy and Edwards4 stated that the incorporation of metaka- appended to the online version of the published paper. It is also available in hard copy
from ACI headquarters for a fee equal to the cost of reproduction plus handling at the
olin as a replacement of cement improves the CS “with the time of the request.
maximum increase in compressive strength being observed

ACI Materials Journal/January-February 2015 31


Table 2—Results of aggregate tests
Sand Gravel
Fine Coarse Glass Glass 4.76 to 9.5 9.5 to 19.0 9.5 to 38.1
167.7 163.7 157.6 157.1 171.5 170.9 169.6
Apparent particle density, lb/ft3 (kg/m3)
(2687.5) (2624.0) (2526.3) (2517.3) (2749.1) (2739.3) (2718.5)
161.4 165.9 157.5 156.9 165.9 165.1 165.3
Oven-dry particle density, lb/ft3 (kg/m3)
(2587.4) (2657.9) (2524.5) (2515.2) (2657.9) (2646.3) (2648.9)
Saturated surface dry particle density, lb/ft3 161.6 163.7 157.6 157.0 168.0 167.2 166.9
(kg/m3) (2589.3) (2623.3) (2525.2) (2516.0) (2692.4) (2679.8) (2674.3)
Water absorption, % 0.07 0.01 0.03 0.03 1.22 1.29 0.97
93.6 96.3 84.5 84.5 89.7 88.9 89.0
Loose bulk density, lb/ft3 (kg/m3)
(1500.0) (1543.0) (1353.7) (1353.7) (1438.3) (1424.9) (1426.2)
Los Angeles wear, % — — — 38.37 34.16 30.84 31.92
Shape index, % — — — 30.5 18.6 17.9 10.2

maximum size between the NA and the GA was due to the Hardened concrete test
unavailability of coarser GA in quantities large enough for The hardened-state concrete was subjected to the compres-
the needs, but the lower sizes of NA were replaced by GA up sive strength test at 7, 28, 56, and 91 days (NP EN 12390-
to 100% (this means that the replacement ratio of the C20C 3:200935), the splitting tensile strength test (NP EN 12390-
mixture [Table 1] is in reality 19.6%, not 20%). 6:200336), the flexural strength test (NP EN 12390-5:200937),
Every replacement was proportional in each of the aggre- the modulus of elasticity test (LNEC E 397:199338), and the
gates’ size ranges in order not to affect the size distribution; abrasion-resistance test (DIN 52108:200239).
therefore, all mixtures are identical to the RC in terms of
particle size distribution. RESULTS AND DISCUSSION
Finally, to maintain the same workability (slump within an Aggregate properties
acceptable range) the water-cement ratio (w/c) was adjusted Table 2 shows that the natural and glass aggregates have
whenever necessary (Table 1). different densities. Because bulk density depends on the
material’s density, these properties show a similar trend. The
Preparation of test specimens approximately constant ratio between bulk density and density
The concrete mixtures were prepared as follows: the mixer of the two materials proves that their void content is similar.
was prepared and prewetted and the coarse aggregates, fine The water absorption of the NA (lower than 1.4%) is real-
aggregates, half the water, the cement, and the rest of the water istic, while the value for glass is much lower than that for
were added, in that order. Three minutes were needed for the the NA, probably due to their nonporous nature (the small
mixture to become homogeneous, and the whole mixing differences between the various types of density tested
process took approximately 5 minutes. All the molds were supports that line of thinking).
lubricated with a release agent and then the concrete was cast The results of the Los Angeles wear test show that all the
and vibrated. After 24 hours, the specimens were demolded materials comply with the criteria imposed by standard LNEC
and left to cure according to the conditions prescribed for each E-373 (maximum 50%) for aggregates to be used in structural
test. Two castings were made per mixture type, according to concrete. The results for the NA are between 30 and 35%.
Table A2. The first was a test piece to adjust the compressive Glass has a higher wear (approximately 38%), which may be
strength and workability, and the second yielded all the speci- because it is more brittle than the NA. The test indicates that
mens for the hardened-state concrete. the aggregates are suitable for the intended use.
The shape index results show that the coarse glass aggre-
Aggregate tests gates have a more irregular and less spherical shape than the
To characterize the aggregates, it was necessary to perform NA, which may affect the results of the concrete tests.
tests on all aggregates, such as the size distribution (NP EN
933-1:200027 and NP EN 933-2:199928), density and water Fresh concrete properties
absorption (NP EN 1097-6:20029), and on the coarse aggre- Workability—Each line in Fig. 1 represents the slump
gates only, the bulk density test (NP EN 1097-3:200830), value for each family of concrete mixtures with the same
shape index (NP EN 933-4:200831), and Los Angeles wear recycled aggregates (coarse only, fine only, and both) as a
(LNEC E237:197032) tests. function of the replacement ratio. In Table 1, the bottom
row presents the w/c of each of the same families according
Fresh concrete tests to the replacement ratio. Even though there are differences
Fresh-state concrete was subjected to the slump test (NP EN in the slump results, all mixtures fell within the acceptable
12350-2:200933) and density test (NP EN 12350-6:200934). and the target ranges, even though the original w/c of the
reference mixture had to be changed in a few cases to meet
the criterion. These results show that the workability of the

32 ACI Materials Journal/January-February 2015


Fig. 1—Slump versus replacement ratio.
Fig. 3—Concrete density versus replacement ratio.
expected, a decreasing trend was found because glass’s density
is lower than that of the NA. The volume of fine aggregates
replaced is greater than that of coarse aggregates (Table 1)
for the 20% ratio because the coarse GA’s size range did not
match the full size range of the coarse NA, and this led to
a bigger difference in density in the corresponding mixtures.
This trend is common to all the studies analyzed. Wang
and Huang5 observed 0.6% and 1.2% reductions in density
relative to the RC for replacement ratios of 10% and 20%,
respectively. For the same ratios, the reductions in this study
were 1.2% and 2.8%, respectively. This bigger reduction
occurs because the LCD glass used by Wang and Huang5 had
a density—152.8 lb/ft3 (2450 kg/m3)—lower than that in this
study. Ismail and Al-Hashmi20 obtained reductions of 1.3 and
2.3%, which is consistent with the results of this study.

Fig. 2—SEM image of interface between fine GA and Hardened concrete properties
cement matrix. Compressive strength—Table 3 shows the average CS
of the various mixtures at different ages (7, 28, 56, and
mixtures with CGA slightly increased with their ratio, which 91 days), as well as the values relative to the RC.
may be due to their large, polished, smooth surface that Table 3 shows that the strength of the mixtures develops
makes it easier for the material to slide despite its highly differently for the same incorporation ratios, as a function
irregular shape (Fig. 2). The FGA led to a decrease in work- of the size of the recycled aggregates incorporated. For
ability, even with a higher w/c, which may be because they CGA, the mixtures with 5% (C05C), 10% (C10C), and 20%
have more edges and are rougher than the equivalent NA. (C20C) incorporation have very similar values after 28 days.
The CFGA mixture also led to a decreasing trend in work- However, after 91 days, the CS of the C05C mixture is close
ability, even though a higher w/c led to a slight increase in to that of the RC, while the CS of the C10C and C20C
the mixture with a 20% incorporation ratio. Therefore, the mixtures is similar but different from that of the first two.
finer glass aggregates’ influence outweighed that of the From 28 to 56 days, different incorporation ratios develop
coarser particles in terms of concrete workability. differently, with greater gains by C05C and lower by C20C.
These results confirm that concrete workability gener- The lowest relative value at 28 days compared with the RC
ally decreases with the incorporation of GA. The studies is 89.5% for the C20C mixture.
that report that this characteristic is not affected have used For a 15% incorporation of CGA, Topçu and Canbaz1 found
pozzolans to improve it4,18 or LCD glass with a hydrophobic a CS of 92.3% that of the RC—slightly higher than the one
nature5,18—materials with properties that might change in this study, which may be due to a lower w/c (0.54). Terro23
concrete’s workability. Out of the literature that reports reported that an incorporation of 10% CGA led to a 10%
that slump decreases as glass is incorporated, Ismail and increase in CS versus the RC, which did not happen in this
Al-Hashmi20 found that it decreased compared with the RC study and is probably due to the admixture used. Terro23 does
by 23.3% and 33.3% for 10% and 20% replacement with not explain the reason why, with an incorporation of 25%, a
FGA, respectively, but Limbachiya21 detected no changes in concrete with a CS similar to that of the RC was produced.
workability up to a 20% replacement ratio, contrary to this For fine recycled aggregates, the development over time
study. In fact, when FGA were incorporated, there was an is similar for the C05F and C10F mixtures, but the C20F
initial drop in slump that had to be offset by an increase in increases less between 56 and 91 days than in the other
the w/c. periods. The CS of the C05F, C10F, and C20F is perceptibly
Density—Figure 3 presents the density of each concrete lower than that of the RC, which may be due to the equal or
family, with GA as a function of the replacement ratio. As higher w/c of these mixtures (respectively 0.55, 0.57, and

ACI Materials Journal/January-February 2015 33


Table 3—Compressive strength at 7, 28, 56, and 91 days (average, variation to RC, and standard deviation)
fcm,7, psi σ, psi fcm,28, psi σ, psi fcm,56, psi σ, psi fcm,91, psi σ, psi
(MPa) Δ, % (MPa) (MPa) Δ, % (MPa) (MPa) Δ, % (MPa) (MPa) Δ, % (MPa)
RC 5409.9 (37.3) — 159.5 (1.1) 6903.8 (47.6) — 43.5 (0.3) 7367.9 (50.8) — 203.0 (1.4) 7527.5 (51.9) — 101.5 (0.7)
C05F 4554.2 (31.4) 84.2 72.5 (0.5) 5859.5 (40.4) 84.7 116.0 (0.8) 6468.7 (44.6) 87.9 174.0 (1.2) 6918.3 (47.7) 91.9 130.5 (0.9)
C05FC 3132.8 (32.6) 87.6 43.5 (0.3) 5961.0 (41.1) 86.3 43.5 (0.3) 6468.7 (44.6) 87.8 159.5 (1.1) 6845.8 (47.2) 91.0 130.5 (0.9)
C05C 5235.9 (36.1) 96.9 116.0 (0.8) 6454.2 (44.5) 93.3 130.5 (0.9) 7092.3 (48.9) 96.3 159.5 (1.1) 7208.4 (49.7) 95.9 72.5 (0.5)
C10F 4554.2 (31.4) 84.3 145 (1.0) 5729.0 (39.5) 82.8 101.5 (0.7) 6294.6 (43.4) 85.4 87.0 (0.6) 6642.7 (45.8) 88.3 130.5 (0.9)
C10FC 4786.2 (33.0) 88.5 29.0 (0.2) 5743.5 (39.6) 83.1 72.5 (0.5) 6323.6 (43.6) 85.9 130.5 (0.9) 6773.3 (46.7) 90.0 101.5 (0.7)
C10C 5003.8 (34.5) 92.6 101.5 (0.7) 6309.1 (43.5) 91.2 188.5 (1.3) 6628.2 (45.7) 90.0 101.5 (0.7) 6860.3 (47.3) 91.1 87.0 (0.6)
C20F 4409.1 (30.4) 81.7 203.0 (1.4) 5496.9 (37.9) 79.5 101.5 (0.7) 6091.6 (42.0) 82.6 116.0 (0.8) 5598.5 (38.6) 74.5 97.0 (0.6)
C20FC 4003.0 (27.6) 74.2 72.5 (0.5) 5061.8 (34.9) 73.3 130.5 (0.9) 5540.4 (38.2) 75.3 290.1 (2.0) 5598.5 (38.6) 74.5 348.1 (2.4)
C20C 5105.3 (35.2) 94.5 159.5 (1.1) 6178.6 (42.6) 89.5 116.0 (0.8) 6280.1 (43.3) 85.2 130.5 (0.9) 6802.3 (46.9) 90.3 159.5 (1.1)

0.58, against 0.55 of the RC), and it is more perceptible the mixture with the best results relative to the RC at any age
bigger the difference. Another explanation can be the higher is the C05C (with figures of 96.9% at 7 days and 93.3% at
specific area of FGA by comparison with CGA and NA due 28 days), and the one with the worst results is the C20FC
to its irregular/angular shape (Fig. 2), which increases the (with 74.2% at 7 days and 73.3% at 28 days).
porosity of the FGA/cement paste ITZ (interfacial transition Terro23 and Alhumoud et al.22 compared the performance
zone) and weakens that bond. It is also found based on these of concrete mixtures with various sizes of glass aggregates
results that the strength gain lasts longer in the C05F and at 10 and 25% incorporation ratios and found that those with
C10F mixtures than in the RC, even though testing at older the best values incorporated CGA only, followed by those
ages would be needed to clarify this matter. with FGA only, and finally those with both CGA and FGA.
Ismail and Al-Hashmi20 found an increase in the CS, from Terro23 found that for a replacement ratio of 10%, the CS
5845 to 6657 psi (40.3 to 45.9 MPa), when the replacement figures relative to the RC were respectively 108%, 102%,
ratio rose from 10 to 20%, contrary to this study (the CS and 92% for the three concrete families mentioned previ-
of the RC was 6382 psi [44 MPa], lower than that of the ouslu, while for a for a replacement ratio of 15%, they were
mixture with 20% of FGA, also contrary to this study). 98%, 93%, and 66%. These values show similar trends to
Terro23 described a decrease in CS from 5874 psi (40.5 MPa) those found in this study in terms of relative CS values for
for a mixture with 10% FGA to 5366 psi (37.0 MPa) for each concrete family and replacement ratio. But Terro23 did
a mixture with 25% FGA. The values presented by Ismail not explain why some of the mixtures with GA had a better
and Al-Hashmi,20 however, have a CS higher than the RC CS than the RC.
(5729 psi [39.5 MPa]), which again can result from the Splitting tensile strength—The splitting tensile strength
admixture used. Consequently, it can be deduced that in (STS) was measured at 28 days and all results are organized
most studies an increase in the replacement ratio leads to in Table 4. Figure 4 depicts the relationship between the STS
a decrease in the CS, but the RC does not always have the of the various concretes with GA and the STS of the RC,
highest CS. compared with the results from previous studies. Overall,
As for the mixtures with a mixture of CGA and FGA, the there is a clear decrease from the RC to the mixtures with 5%
performance of C05FC and C10FC is similar to that of C05F GA incorporation for all the concrete families (around 20%).
and C10F and there is also lower strength gain in the period The comparison of the families shows that they all have a
from 56 to 91 days in both the C20FC and C20F mixtures. slightly unstable behavior as the replacement ratio increases.
Compared with the RC, there is a decrease in CS from the The worst relative performance occurs interchangeably in
C05FC and C10FC mixtures to the C20FC mixture, which is the mixtures with FGA only and with both CGA and FGA,
probably due to the w/c increasing from 0.55 in C05FC and and the best is found in the mixtures with CFA only and FGA
C10FC to 0.57 in C20FC. only, also interchangeably. Bearing in mind the natural vari-
Kou and Poon19 found that the CS of a mixture with 15% ability of this property (in conventional concrete, too), it can
incorporation of both CGA and FGA was 98.5% that of the be said that it is not significantly affected by the size of the
RC, at both 7 and 28 days. This difference from this study incorporated GA and, consequently, their greater or lesser
may be due to the different w/c used (0.37 for both mixtures roughness. In fact, for a replacement of 20% the three GA
in Kou and Poon19 and 0.55 and 0.57 in this study). options lead to very similar values of STS.
A relationship was found between the CS of the mixtures For mixtures with 15 and 30% of CGA, Topçu and
with FGA and those with CGA and FGA, indicating that Canbaz1 obtained an STS of 90.3% and 88.4% relative to
the FGA influence this property more significantly than the that of the RC, respectively, which are above the values
CGA. Generally it can be said that all the mixtures have a obtained in this study for the mixtures with 10% and 20%
similar behavior (Table 3), with the CS varying as a function CGA incorporation. It is found that the losses found rela-
of the incorporated GA ratio and the w/c. Nonetheless, the tive to the RC, due to the incorporation of GA, are much

34 ACI Materials Journal/January-February 2015


Table 4—Splitting tensile strength at 28 days (average, variation relative to RC, and standard deviation)
0 5 10 20
fctm,sp,28, Σ, psi fctm,sp,28, psi fctm,sp,28, psi fctm,sp,28, psi
psi (MPa) (MPa) (MPa) Δ, % σ, psi (MPa) (MPa) Δ, % σ, psi (MPa) (MPa) Δ, % σ, psi (MPa)
CGA 464.1 (3.2) 82.8 14.5 (0.1) 464.1 (3.2) 83.0 29.0 (0.2) 391.6 (2.7) 71.0 14.5 (0.1)
FGA 551.1 29.0 464.1 (3.2) 84.2 29.0 (0.2) 406.1 (2.8) 73.9 0.0 (0.0) 377.1 (2.6) 68.6 14.5 (0.1)
(3.8) (0.2)
CGA/
435.1 (3.0) 79.4 14.5 (0.1) 435.1 (3.0) 78.6 14.5 (0.1) 391.6 (2.7) 69.4 14.5 (0.1)
FGA

Table 5—Flexural strength at 28 days (average, variation relative to RC, and standard deviation)
0 5 10 20
σcm,sp,28, psi Σ, psi σcm,sp,28, psi σ, psi σcm,sp,28, psi σ, psi σcm,sp,28, psi
(MPa) (MPa) (MPa) Δ, % (MPa) (MPa) Δ, % (MPa) (MPa) Δ, % σ, psi (MPa)
CGA 783.2 (5.4) 92.8 0.0 (0.0) 710.7 (4.9) 83.5 29.0 (0.2) 681.7 (4.7) 80.7 14.5 (0.1)
855.7 0.0
FGA 667.2 (4.6) 79.1 14.5 (0.1) 594.7 (4.1) 69.9 14.5 (0.1) 609.2 (4.2) 71.9 0.0 (0.0)
(5.9) (0.0)
CGA/FGA 696.2 (4.8) 82.1 0.0 (0.0) 652.7 (4.5) 75.9 14.5 (0.1) 551.1 (3.8) 65.2 0.0 (0.0)

Fig. 5—Fracture surface of flexural strength test specimens


with CGA (left) and FGA (right).

Fig. 4—Splitting tensile strength of mixtures with glass


aggregates relative to RC versus replacement ratio (present
and previous studies).
higher than those obtained by Topçu and Canbaz,1 which
may be due to poorer adhesion between the cement matrix
and the GA. Kou and Poon19 found that the STS decreased
from 496.0 psi (3.42 MPa) for the RC to 472.8 and 462.7 psi
(3.26 and 3.19 MPa) for the mixtures with 15% and 30% GA
incorporation, respectively. These values have a lower STS
variation compared with the RCs than those in this study.
Flexural strength—The FS was also measured at 28 days
and the results are shown in Table 5. Figure 5 shows exam-
ples of the fracture surface of specimens subjected to this
test. The FS figures of the various mixtures with GA rela-
Fig. 6—Flexural strength of mixtures with glass aggre-
tive to that of the RC are presented in Fig. 6, compared
gates relative to RC versus replacement ratio (present and
with the results from previous studies. It was found that
previous studies).
the C05C mixture has the best relative value with 92.8%,
and the C20FC the worst with 65.2%. Individual analysis increases as the GA size decreases, proving that the lesser
of the mixtures indicates that the families with CGA and shape irregularity of the CGA versus that of the FGA can
both CGA and FGA have a similar performance. As seen be beneficial for this property. However, there are no results
before, however, the increase in GA incorporation from in the literature to check this theory against and it therefore
10 to 20% is worse for the second family than the first, prob- demands further study.
ably because of the higher w/c. The mixtures with FGA only Ismail and Al-Hashmi20 stated that the FS increased with
show a similar trend from 5 to 10% incorporation ratio, but the incorporation ratio of FGA. This contradicts the results
the result for the 20% ratio is unnatural (there is gain in FS) obtained in this study with FGA, which may be due to the
and is probably associated with an undetected experimental higher w/c for the mixtures with FGA in this study. Topçu
error. Nonetheless, it can be said that the FS goes down as and Canbaz1 showed that the FS decreased as the replace-
the GA incorporation ratio increases and that the gradient ment ratio increased, but the trend was not well defined

ACI Materials Journal/January-February 2015 35


Table 6—Modulus of elasticity at 28 days (average, variation relative to RC, and standard deviation)
0 5 10 20
Ecm,sp,28, ksi Ecm,sp,28, ksi σ, ksi Ecm,sp,28, ksi Ecm,sp,28, ksi
(GPa) σ, ksi (GPa) (GPa) Δ, % (GPa) (GPa) Δ, % σ, ksi (GPa) (GPa) Δ, % σ, ksi (GPa)
5772.5 58.0 5424.4 5642.0
CGA 105.0 98.6 159.5 (1.1) 102.6 493.1 (3.4)
(39.8) (04) (37.4) (38.9)
5496.9 101.5 5076.3 72.5 5192.3 5264.9
FGA 92.2 94.5 58.0(0.4) 95.8 58.0 (0.4)
(37.9) (0.7) (35.0) (0.5) (35.8) (36.3)
5221.4 203.1 5322.9 5322.9.9
CGA/FGA 95,0 96,8 58.0 (0.4) 96.7 58.0 (0.4)
(36.0) (1.4) (36.7) (36.7)

Table 7—Abrasion wear at 91 days (average, variation relative to RC, and standard deviation)
0 5 10 20
ΔL, in. σ, in.
(mm) (mm) ΔL, in. (mm) Δ, % σ, in. (mm) ΔL, in. (mm) Δ, % σ, in. (mm) ΔL, in. (mm) Δ, % σ, in. (mm)
CGA 0.167 (4.24) 90.9 0.02 (0.6) 0.165 (4.18) 89.7 0.02 (0.4) 0.156 (3.96) 84.8 0.01 (0.3)
0.184 0.02
FGA 0.182 (4.62) 99.1 0.00 (0.1) 0.192 (4.87) 104.5 0.01 (0.2) 0.186 (4.72) 101.1 0.02 (0.6)
(4.66) (0.4)
CGA/FGA 0.182 (4.63) 99.3 0.01 (0.3) 0.179 (4.53) 97.2 0.02 (0.4) 0.173 (4.40) 94.4 0.01 (0.3)

Fig. 7—Modulus of elasticity of mixtures with glass aggre- Fig. 8—Abrasion wear of mixtures with glass aggregates
gates relative to RC versus replacement ratio (present and relative to RC versus replacement ratio.
previous studies).
grade, while in this study, the w/c was increased to keep
and therefore it cannot be compared with these results for the workability constant, which negatively affected all the
mixtures with CGA. mechanical properties. For concrete with a mixture of CGA
Modulus of elasticity—The modulus of elasticity (MO) was and FGA, Kou and Poon19 determined that the MO decreased
measured at 28 days and the results are presented in Table 6 as the GA ratio increased (RC = 4320.1 ksi [29.8 GPa]; 15%
and Fig. 7, compared with the results from previous studies. GA = 4235.1 ksi [29.2 GPa]; and 30% GA = 4104.6 ksi
They show that there is no significant variation in the MO [28.3 GPa]). These absolute values and the relative varia-
between the RC and any of the mixtures of the three fami- tions are smaller than in this study but they show the general
lies of GA—that is, neither the incorporation of GA nor their same trend.
size seem to have a noticeable repercussion on the MO of Abrasion resistance—The specimens’ abrasion resistance
concrete. However, one can detect a similar behavior of the (AR) was determined at 91 days and the results are summa-
concrete mixtures with FGA and with both FGA and CGA, rized in Table 7 and represented in Fig. 8. Figures greater than
where the MO is slightly below that of the mixtures with CGA 100% indicate that the wear in mixtures with replacement of
only. Here again it is not possible to confirm this premise in NA by GA is higher than in the RC and vice-versa. The AR
the literature and therefore further study is required. depends fundamentally on the cohesivity of the cement paste
For concrete with CGA, Topçu and Canbaz1 could not and on its capacity to hold the coarse aggregates; therefore,
obtain a clear trend in terms of the MO (RC = 5366.4 ksi it is highly dependent on the adhesion between the paste
[37 GPa]; 15% CGA = 8702.3 ksi [60 GPa]; and 30% and the coarse aggregates. When coarse natural aggregates
CGA = 3625.9 ksi [25 GPa]), and therefore these results (CNA) are replaced by CGA, the greater roughness of the
cannot be compared with those from this study. For concrete latter improves the AR, as noted in the concrete family with
with FGA, Limbachiya21 determined that there was no vari- CGA only, where the AR increases with the replacement
ation of the MO for replacement ratios up to 20%, which ratio. The effect is less pronounced in the family with both
differs slightly from these conclusions. In fact, Limbachiya21 CGA and FGA and practically vanishes in the family with
kept the w/c constant in all mixtures of the same strength FGA only, meaning that the incorporation of FGA does not

36 ACI Materials Journal/January-February 2015


Fig. 9—Splitting tensile strength versus 28-day compres- Fig. 11—Modulus of elasticity versus 28-day compres-
sive strength. sive strength.
CONCLUSIONS
An experimental plan was performed to study the feasi-
bility of using recycled glass aggregates to replace natural
aggregates up to a 20% replacement ratio, in the production
of concrete. The results demonstrate that:
1. The compressive strength is more affected by fine
aggregates than by coarse ones; this effect can be minimized
by using superplasticizers to keep both the workability and
the w/c constant in all mixtures;
2. In terms of splitting and flexural tensile strength, the fine
aggregates lead to worse results, but again, this can be mini-
mized by using superplasticizers and keeping the workability
Fig. 10—Flexural strength versus 28-day compressive strength. and the w/c constant, so as not to jeopardize durability;
significantly influence this property (the slight worsening in 3. There is no noticeable influence on the modulus of elas-
some mixtures is related to changes in the w/c). ticity, which remained practically constant for the various
In the absence of other works on the AR of concrete with replacement ratios; the fine aggregates, however, lead to a
GA, similar studies with other recycled aggregates are used. slight decrease in the modulus of elasticity;
Evangelista et al.,12 using fine recycled concrete aggregates, 4. There is a general improvement in abrasion resistance in
found that the aggregate-paste bond is the main factor in concrete with coarse glass aggregates, with optimal results
improving the results of the abrasion wear test. De Brito for the mixture with a 10% replacement ratio; for fine aggre-
et al.40 found that the w/c influenced the AR of concrete gates, this trend is negligible;
with coarse ceramic aggregates; therefore, the AR results 5. By comparing the various results obtained and with
in concrete with FGA may have been influenced by the those from the EN 1992-1-1:2004 standard,25 it is concluded
increase in that ratio. Park et al.,24 using FGA as replace- that it is viable to replace natural aggregates by glass aggre-
ment of natural aggregates, put forward the hypothesis that gates in concrete production.
the poor adhesion between the FGA’s surface and the cement Therefore, the use of these aggregates is possible, but a
paste led to worse results in the mechanical tests. general trend of poorer mechanical behavior must be taken
Correlations between properties—To determine into account. When using these aggregates in concrete, it is
possible mathematical models of the mechanical behavior preferable to use coarse ones; but if it is planned to use fine
of the mixtures studied and because the 28-day CS is the aggregates, mixed or not with coarse ones, superplasticizers
most frequently used/studied mechanical property, it was should be used to maintain the workability without jeopar-
compared with the MO, the STS and the FS. Figures 9 dizing the mechanical performance by increasing the w/c.
through 11 show that the GA led to concrete with mechanical
behavior compatible with the mathematical models proposed AUTHOR BIOS
Diogo Serpa received his MSc in civil engineering at the Technical Univer-
in the EN 1992-1-1:2004 standard.25 When compared with sity of Lisbon (IST), Lisbon, Portugal. His research interests include the
the models proposed by Park et al.24 or even Kou and Poon,19 mechanical performance of concrete made with recycled glass aggregates.
there is some difference, which may be due to the fact that Jorge de Brito is a Full Professor at IST. He received his MSc and PhD
these authors only studied one type of replacement (in terms in civil engineering from IST. His research interests include deterioration,
of size of the GA) and at greater ratios. The low values of the rehabilitation and management of concrete structures and sustainable
construction.
correlation factor in two of the three relationships devised
are due to the narrow range of the different properties’ values Jorge Pontes is a Chemical Engineer at Faculdade de Ciências e Tecno-
obtained in this experimental work. logia da Universidade Nova de Lisboa (FCT-UNL), Caparica, Portugal,
and a Project Researcher at IST. He receive his MSc in civil engineering
at FCT-UNL.

ACI Materials Journal/January-February 2015 37


ACKNOWLEDGMENTS Concrete Composites, V. 31, No. 2, 2009, pp. 107-113. doi: 10.1016/j.
The authors gratefully acknowledge the support of the ICIST Research cemconcomp.2008.12.002
Institute, IST, Technical University of Lisbon and the FCT (Foundation for 20. Ismail, Z. Z., and Al-Hashmi, E. A., “Recycling of Waste Glass as
Science and Technology). a Partial Replacement for Fine Aggregate in Concrete,” Waste Manage-
ment (New York, N.Y.), V. 29, No. 2, 2009, pp. 655-659. doi: 10.1016/j.
wasman.2008.08.012
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2009, pp. 335-341. doi: 10.1016/j.wasman.2008.03.005 27. NP EN 933-1:2000, “Tests for Geometrical Properties of Aggregates,
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No. 4, 2002, pp. 259-274. doi: 10.1016/S0921-3449(02)00007-1 28. NP EN 933-2:1999, “Tests for Geometrical Properties of Aggregates,
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38 ACI Materials Journal/January-February 2015


Table A1 - Composition of the reference concrete (RC)

Sieves range [in] (mm) Material retained [%] Volumes [ft3/ft3] (m3/m3)
1.24-1.77 (31.5-45) 0.0 0.0000
0.88-1.24 (22.4-31.5) 0.0 0.0000
0.63-0.88 (16-22.4) 17.8 0.1202
Coarse
0.44-0.63 (11.2-16) 17.7 0.1195
0.31-0.44 (8-11.2) 6.8 0.0459
0.22-0.31 (5.6-8) 6.8 0.0459
0.16-0.22 (4-5.6) 6.0 0.0405
0.08-0.16 (2-4) 11.1 0.0750
0.04-0.08 (1-2) 9.6 0.0648
0.02-0.04 (0.5-1) 6.0 0.0405
Fine

0.01-0.02 (0.25-0.5) 14.2 0.0959


0.005-0.01 (0.125-0.25) 4.0 0.0270
0.002-0.005 (0.063-0.125) 0.0 0.0000
0-0.002 (0-0.063) 0.0 0.0000
Cement 0.1148
Water 0.1925
Void volume 0.0174
Total volume 1.0000

Table A2 - Summary of the tests performed on hardened concrete in 1st and 2nd casting

Property Age [days] No. of specimens Shape and size [in] (mm)
Compressive Cubic
1st casting 28 3
strength 5.91 × 5.91 × 5.91 (150 × 150 × 150)
7 3
Compressive 28 5 Cubic
strength 56 3 5.91 × 5.91 × 5.91 (150 × 150 × 150)
91 3
Prismatic
2nd casting
Flexural strength 28 2 5.91 × 5.91 × 23.62 (150 × 150 × 600)
(a·b·h)
Cylindrical
Splitting tensile
28 3 5.91 × 11.81 (150 × 300)
strength
(ø·h)

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