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This study aims at characterizing the mechanical performance of the environmental impact associated with both quarries and
concrete made with varying glass content (5, 10, and 20% of the dumps for solid waste.
overall volume of aggregates) and analyzing the influence of the
size of these aggregates (fine, coarse, or both) on that performance. RESEARCH SIGNIFICANCE
The use of glass aggregates as an environmentally friendly alter-
This study assesses whether glass waste can be used
native to dumping it as waste reduces the consumption of natural
as aggregate in concrete to help solve the environmental
resources and requires the space needed for dumping grounds. The
aggregates were studied in terms of density and abrasion. Fresh problem of its disposal. The innovative aspects are linked to
concrete was tested for workability and density. Hardened concrete the use of a constant aggregate grading distribution, deter-
was tested for compressive, splitting tensile, and flexural strength; mined according to Faury’s method, and the determination
modulus of elasticity; and abrasion wear. It was found that the of the influence of different sizes and replacement ratios of
incorporation of glass aggregates in concrete leads to a loss of its glass aggregates on various characteristics of mechanical
mechanical performance, although this is not significant for ratios performance (compressive, splitting tensile, and flexural
of up to 10% of the volume of natural aggregates, except for abra- strength; modulus of elasticity; and abrasion wear) over
sion resistance, where there is an improvement. A better perfor- time. The goal was to confirm/refute results for some of the
mance was seen in concrete with coarse glass aggregates, followed properties from previous works as well as to present new
by concrete with fine glass aggregates, and finally, concrete with
data that may improve understanding of the properties of
the simultaneous incorporation of coarse and fine glass aggregates.
concrete with recycled glass aggregates. This work supple-
Keywords: mechanical performance; recycled glass aggregates; sustainability. ments those of Serpa et al.,16 which studies the alkali-silica
reaction vulnerability of concrete with recycled glass aggre-
INTRODUCTION gate, and Castro et al.,17 which evaluates the durability
The treatment and elimination of waste, frequent resort performance of similar types of concrete.
to dumping, and excessive consumption of raw materials
are growing concerns. The United Nations has estimated LITERATURE REVIEW
the annual production of waste to be around 4.409 × 1011 lb General introduction
(200 million tonnes), of which 7% is glass.1 The studies mentioned in this section have used various
In Portugal, according to INE’s national statistics,2 each materials in different conditions; therefore, it was deemed
person produced 1036 lb (470 kg) of solid waste per year necessary to detail some fundamental parameters.
in the 2004-2009 period, and the highest figure in terms of Al-Sibahy et al.4 used glass to produce lightweight
glass was for 2008 with 2.121 × 109 lb (962,041 tonnes). concrete where expanded clay was used as coarse aggre-
Meanwhile, in 2009, a total of €374.7 million of products gate, natural sand as fine aggregate, and 0.0197 to 0.0394 in.
made with glass was consumed. Oliveira et al.3 reports that (0.5 to 1 mm) and 0.0394 to 0.0788 in. (1 to 2 mm) glass
from 1999 to 2005, in Portugal, only 30% of the glass was replaced natural aggregates at ratios of 15, 30, and 45%.
recycled and 70% was dumped. According to Al-Sibahy and The glass had different colors but its origin was not stated.
Edwards,4 in the UK, 6.415 × 1010 lb (29.1 million tonnes) of Metakaolin was also used as hydraulic binder replacement
waste are produced per year, of which 4.2% are glass. Wang at ratios of 5 and 10%. Chen et al.18 used industrial glass
and Huang,5 Wang,6 and Su and Chen7 state that Taiwan from LCD production to replace fine aggregates at 10, 20,
produced 1.1 × 109 lb (500,000 tonnes) of glass per year, and 30% ratios. They also used pozzolanic materials such as
part of which comes from glass produced for LCDs, which fly ash and blast furnace slag. Wang and Huang5 used glass
is unfit for dumping because of its chemical treatment. This from LCD production to replace fine aggregates at 10, 20,
whole situation involves considerable energy consumption and 30% ratios. Blast-furnace slag was also used.
because glass is produced at high temperatures, and increased Kou and Poon19 used recycled glass from waste bottles to
environmental impacts due to raw material consumption and replace fine and coarse aggregates up to 0.394 in. (10 mm)
space taken by dumping grounds. These aspects ought to
be improved. ACI Materials Journal, V. 112, No. 1, January-February 2015.
MS No. M-2012-184.R3, doi: 10.14359/51687366, received October 25, 2012, and
Like other waste materials (plastics,8,9 rubber,10,11 reviewed under Institute publication policies. Copyright © 2015, American Concrete
concrete,12,13 and ceramics14,15), glass can be incorporated in Institute. All rights reserved, including the making of copies unless permission is
obtained from the copyright proprietors. Pertinent discussion including author’s
concrete to partly replace natural aggregates and thus reduce closure, if any, will be published ten months from this journal’s date if the discussion
is received within four months of the paper’s print publication.
maximum size between the NA and the GA was due to the Hardened concrete test
unavailability of coarser GA in quantities large enough for The hardened-state concrete was subjected to the compres-
the needs, but the lower sizes of NA were replaced by GA up sive strength test at 7, 28, 56, and 91 days (NP EN 12390-
to 100% (this means that the replacement ratio of the C20C 3:200935), the splitting tensile strength test (NP EN 12390-
mixture [Table 1] is in reality 19.6%, not 20%). 6:200336), the flexural strength test (NP EN 12390-5:200937),
Every replacement was proportional in each of the aggre- the modulus of elasticity test (LNEC E 397:199338), and the
gates’ size ranges in order not to affect the size distribution; abrasion-resistance test (DIN 52108:200239).
therefore, all mixtures are identical to the RC in terms of
particle size distribution. RESULTS AND DISCUSSION
Finally, to maintain the same workability (slump within an Aggregate properties
acceptable range) the water-cement ratio (w/c) was adjusted Table 2 shows that the natural and glass aggregates have
whenever necessary (Table 1). different densities. Because bulk density depends on the
material’s density, these properties show a similar trend. The
Preparation of test specimens approximately constant ratio between bulk density and density
The concrete mixtures were prepared as follows: the mixer of the two materials proves that their void content is similar.
was prepared and prewetted and the coarse aggregates, fine The water absorption of the NA (lower than 1.4%) is real-
aggregates, half the water, the cement, and the rest of the water istic, while the value for glass is much lower than that for
were added, in that order. Three minutes were needed for the the NA, probably due to their nonporous nature (the small
mixture to become homogeneous, and the whole mixing differences between the various types of density tested
process took approximately 5 minutes. All the molds were supports that line of thinking).
lubricated with a release agent and then the concrete was cast The results of the Los Angeles wear test show that all the
and vibrated. After 24 hours, the specimens were demolded materials comply with the criteria imposed by standard LNEC
and left to cure according to the conditions prescribed for each E-373 (maximum 50%) for aggregates to be used in structural
test. Two castings were made per mixture type, according to concrete. The results for the NA are between 30 and 35%.
Table A2. The first was a test piece to adjust the compressive Glass has a higher wear (approximately 38%), which may be
strength and workability, and the second yielded all the speci- because it is more brittle than the NA. The test indicates that
mens for the hardened-state concrete. the aggregates are suitable for the intended use.
The shape index results show that the coarse glass aggre-
Aggregate tests gates have a more irregular and less spherical shape than the
To characterize the aggregates, it was necessary to perform NA, which may affect the results of the concrete tests.
tests on all aggregates, such as the size distribution (NP EN
933-1:200027 and NP EN 933-2:199928), density and water Fresh concrete properties
absorption (NP EN 1097-6:20029), and on the coarse aggre- Workability—Each line in Fig. 1 represents the slump
gates only, the bulk density test (NP EN 1097-3:200830), value for each family of concrete mixtures with the same
shape index (NP EN 933-4:200831), and Los Angeles wear recycled aggregates (coarse only, fine only, and both) as a
(LNEC E237:197032) tests. function of the replacement ratio. In Table 1, the bottom
row presents the w/c of each of the same families according
Fresh concrete tests to the replacement ratio. Even though there are differences
Fresh-state concrete was subjected to the slump test (NP EN in the slump results, all mixtures fell within the acceptable
12350-2:200933) and density test (NP EN 12350-6:200934). and the target ranges, even though the original w/c of the
reference mixture had to be changed in a few cases to meet
the criterion. These results show that the workability of the
Fig. 2—SEM image of interface between fine GA and Hardened concrete properties
cement matrix. Compressive strength—Table 3 shows the average CS
of the various mixtures at different ages (7, 28, 56, and
mixtures with CGA slightly increased with their ratio, which 91 days), as well as the values relative to the RC.
may be due to their large, polished, smooth surface that Table 3 shows that the strength of the mixtures develops
makes it easier for the material to slide despite its highly differently for the same incorporation ratios, as a function
irregular shape (Fig. 2). The FGA led to a decrease in work- of the size of the recycled aggregates incorporated. For
ability, even with a higher w/c, which may be because they CGA, the mixtures with 5% (C05C), 10% (C10C), and 20%
have more edges and are rougher than the equivalent NA. (C20C) incorporation have very similar values after 28 days.
The CFGA mixture also led to a decreasing trend in work- However, after 91 days, the CS of the C05C mixture is close
ability, even though a higher w/c led to a slight increase in to that of the RC, while the CS of the C10C and C20C
the mixture with a 20% incorporation ratio. Therefore, the mixtures is similar but different from that of the first two.
finer glass aggregates’ influence outweighed that of the From 28 to 56 days, different incorporation ratios develop
coarser particles in terms of concrete workability. differently, with greater gains by C05C and lower by C20C.
These results confirm that concrete workability gener- The lowest relative value at 28 days compared with the RC
ally decreases with the incorporation of GA. The studies is 89.5% for the C20C mixture.
that report that this characteristic is not affected have used For a 15% incorporation of CGA, Topçu and Canbaz1 found
pozzolans to improve it4,18 or LCD glass with a hydrophobic a CS of 92.3% that of the RC—slightly higher than the one
nature5,18—materials with properties that might change in this study, which may be due to a lower w/c (0.54). Terro23
concrete’s workability. Out of the literature that reports reported that an incorporation of 10% CGA led to a 10%
that slump decreases as glass is incorporated, Ismail and increase in CS versus the RC, which did not happen in this
Al-Hashmi20 found that it decreased compared with the RC study and is probably due to the admixture used. Terro23 does
by 23.3% and 33.3% for 10% and 20% replacement with not explain the reason why, with an incorporation of 25%, a
FGA, respectively, but Limbachiya21 detected no changes in concrete with a CS similar to that of the RC was produced.
workability up to a 20% replacement ratio, contrary to this For fine recycled aggregates, the development over time
study. In fact, when FGA were incorporated, there was an is similar for the C05F and C10F mixtures, but the C20F
initial drop in slump that had to be offset by an increase in increases less between 56 and 91 days than in the other
the w/c. periods. The CS of the C05F, C10F, and C20F is perceptibly
Density—Figure 3 presents the density of each concrete lower than that of the RC, which may be due to the equal or
family, with GA as a function of the replacement ratio. As higher w/c of these mixtures (respectively 0.55, 0.57, and
0.58, against 0.55 of the RC), and it is more perceptible the mixture with the best results relative to the RC at any age
bigger the difference. Another explanation can be the higher is the C05C (with figures of 96.9% at 7 days and 93.3% at
specific area of FGA by comparison with CGA and NA due 28 days), and the one with the worst results is the C20FC
to its irregular/angular shape (Fig. 2), which increases the (with 74.2% at 7 days and 73.3% at 28 days).
porosity of the FGA/cement paste ITZ (interfacial transition Terro23 and Alhumoud et al.22 compared the performance
zone) and weakens that bond. It is also found based on these of concrete mixtures with various sizes of glass aggregates
results that the strength gain lasts longer in the C05F and at 10 and 25% incorporation ratios and found that those with
C10F mixtures than in the RC, even though testing at older the best values incorporated CGA only, followed by those
ages would be needed to clarify this matter. with FGA only, and finally those with both CGA and FGA.
Ismail and Al-Hashmi20 found an increase in the CS, from Terro23 found that for a replacement ratio of 10%, the CS
5845 to 6657 psi (40.3 to 45.9 MPa), when the replacement figures relative to the RC were respectively 108%, 102%,
ratio rose from 10 to 20%, contrary to this study (the CS and 92% for the three concrete families mentioned previ-
of the RC was 6382 psi [44 MPa], lower than that of the ouslu, while for a for a replacement ratio of 15%, they were
mixture with 20% of FGA, also contrary to this study). 98%, 93%, and 66%. These values show similar trends to
Terro23 described a decrease in CS from 5874 psi (40.5 MPa) those found in this study in terms of relative CS values for
for a mixture with 10% FGA to 5366 psi (37.0 MPa) for each concrete family and replacement ratio. But Terro23 did
a mixture with 25% FGA. The values presented by Ismail not explain why some of the mixtures with GA had a better
and Al-Hashmi,20 however, have a CS higher than the RC CS than the RC.
(5729 psi [39.5 MPa]), which again can result from the Splitting tensile strength—The splitting tensile strength
admixture used. Consequently, it can be deduced that in (STS) was measured at 28 days and all results are organized
most studies an increase in the replacement ratio leads to in Table 4. Figure 4 depicts the relationship between the STS
a decrease in the CS, but the RC does not always have the of the various concretes with GA and the STS of the RC,
highest CS. compared with the results from previous studies. Overall,
As for the mixtures with a mixture of CGA and FGA, the there is a clear decrease from the RC to the mixtures with 5%
performance of C05FC and C10FC is similar to that of C05F GA incorporation for all the concrete families (around 20%).
and C10F and there is also lower strength gain in the period The comparison of the families shows that they all have a
from 56 to 91 days in both the C20FC and C20F mixtures. slightly unstable behavior as the replacement ratio increases.
Compared with the RC, there is a decrease in CS from the The worst relative performance occurs interchangeably in
C05FC and C10FC mixtures to the C20FC mixture, which is the mixtures with FGA only and with both CGA and FGA,
probably due to the w/c increasing from 0.55 in C05FC and and the best is found in the mixtures with CFA only and FGA
C10FC to 0.57 in C20FC. only, also interchangeably. Bearing in mind the natural vari-
Kou and Poon19 found that the CS of a mixture with 15% ability of this property (in conventional concrete, too), it can
incorporation of both CGA and FGA was 98.5% that of the be said that it is not significantly affected by the size of the
RC, at both 7 and 28 days. This difference from this study incorporated GA and, consequently, their greater or lesser
may be due to the different w/c used (0.37 for both mixtures roughness. In fact, for a replacement of 20% the three GA
in Kou and Poon19 and 0.55 and 0.57 in this study). options lead to very similar values of STS.
A relationship was found between the CS of the mixtures For mixtures with 15 and 30% of CGA, Topçu and
with FGA and those with CGA and FGA, indicating that Canbaz1 obtained an STS of 90.3% and 88.4% relative to
the FGA influence this property more significantly than the that of the RC, respectively, which are above the values
CGA. Generally it can be said that all the mixtures have a obtained in this study for the mixtures with 10% and 20%
similar behavior (Table 3), with the CS varying as a function CGA incorporation. It is found that the losses found rela-
of the incorporated GA ratio and the w/c. Nonetheless, the tive to the RC, due to the incorporation of GA, are much
Table 5—Flexural strength at 28 days (average, variation relative to RC, and standard deviation)
0 5 10 20
σcm,sp,28, psi Σ, psi σcm,sp,28, psi σ, psi σcm,sp,28, psi σ, psi σcm,sp,28, psi
(MPa) (MPa) (MPa) Δ, % (MPa) (MPa) Δ, % (MPa) (MPa) Δ, % σ, psi (MPa)
CGA 783.2 (5.4) 92.8 0.0 (0.0) 710.7 (4.9) 83.5 29.0 (0.2) 681.7 (4.7) 80.7 14.5 (0.1)
855.7 0.0
FGA 667.2 (4.6) 79.1 14.5 (0.1) 594.7 (4.1) 69.9 14.5 (0.1) 609.2 (4.2) 71.9 0.0 (0.0)
(5.9) (0.0)
CGA/FGA 696.2 (4.8) 82.1 0.0 (0.0) 652.7 (4.5) 75.9 14.5 (0.1) 551.1 (3.8) 65.2 0.0 (0.0)
Table 7—Abrasion wear at 91 days (average, variation relative to RC, and standard deviation)
0 5 10 20
ΔL, in. σ, in.
(mm) (mm) ΔL, in. (mm) Δ, % σ, in. (mm) ΔL, in. (mm) Δ, % σ, in. (mm) ΔL, in. (mm) Δ, % σ, in. (mm)
CGA 0.167 (4.24) 90.9 0.02 (0.6) 0.165 (4.18) 89.7 0.02 (0.4) 0.156 (3.96) 84.8 0.01 (0.3)
0.184 0.02
FGA 0.182 (4.62) 99.1 0.00 (0.1) 0.192 (4.87) 104.5 0.01 (0.2) 0.186 (4.72) 101.1 0.02 (0.6)
(4.66) (0.4)
CGA/FGA 0.182 (4.63) 99.3 0.01 (0.3) 0.179 (4.53) 97.2 0.02 (0.4) 0.173 (4.40) 94.4 0.01 (0.3)
Fig. 7—Modulus of elasticity of mixtures with glass aggre- Fig. 8—Abrasion wear of mixtures with glass aggregates
gates relative to RC versus replacement ratio (present and relative to RC versus replacement ratio.
previous studies).
grade, while in this study, the w/c was increased to keep
and therefore it cannot be compared with these results for the workability constant, which negatively affected all the
mixtures with CGA. mechanical properties. For concrete with a mixture of CGA
Modulus of elasticity—The modulus of elasticity (MO) was and FGA, Kou and Poon19 determined that the MO decreased
measured at 28 days and the results are presented in Table 6 as the GA ratio increased (RC = 4320.1 ksi [29.8 GPa]; 15%
and Fig. 7, compared with the results from previous studies. GA = 4235.1 ksi [29.2 GPa]; and 30% GA = 4104.6 ksi
They show that there is no significant variation in the MO [28.3 GPa]). These absolute values and the relative varia-
between the RC and any of the mixtures of the three fami- tions are smaller than in this study but they show the general
lies of GA—that is, neither the incorporation of GA nor their same trend.
size seem to have a noticeable repercussion on the MO of Abrasion resistance—The specimens’ abrasion resistance
concrete. However, one can detect a similar behavior of the (AR) was determined at 91 days and the results are summa-
concrete mixtures with FGA and with both FGA and CGA, rized in Table 7 and represented in Fig. 8. Figures greater than
where the MO is slightly below that of the mixtures with CGA 100% indicate that the wear in mixtures with replacement of
only. Here again it is not possible to confirm this premise in NA by GA is higher than in the RC and vice-versa. The AR
the literature and therefore further study is required. depends fundamentally on the cohesivity of the cement paste
For concrete with CGA, Topçu and Canbaz1 could not and on its capacity to hold the coarse aggregates; therefore,
obtain a clear trend in terms of the MO (RC = 5366.4 ksi it is highly dependent on the adhesion between the paste
[37 GPa]; 15% CGA = 8702.3 ksi [60 GPa]; and 30% and the coarse aggregates. When coarse natural aggregates
CGA = 3625.9 ksi [25 GPa]), and therefore these results (CNA) are replaced by CGA, the greater roughness of the
cannot be compared with those from this study. For concrete latter improves the AR, as noted in the concrete family with
with FGA, Limbachiya21 determined that there was no vari- CGA only, where the AR increases with the replacement
ation of the MO for replacement ratios up to 20%, which ratio. The effect is less pronounced in the family with both
differs slightly from these conclusions. In fact, Limbachiya21 CGA and FGA and practically vanishes in the family with
kept the w/c constant in all mixtures of the same strength FGA only, meaning that the incorporation of FGA does not
Sieves range [in] (mm) Material retained [%] Volumes [ft3/ft3] (m3/m3)
1.24-1.77 (31.5-45) 0.0 0.0000
0.88-1.24 (22.4-31.5) 0.0 0.0000
0.63-0.88 (16-22.4) 17.8 0.1202
Coarse
0.44-0.63 (11.2-16) 17.7 0.1195
0.31-0.44 (8-11.2) 6.8 0.0459
0.22-0.31 (5.6-8) 6.8 0.0459
0.16-0.22 (4-5.6) 6.0 0.0405
0.08-0.16 (2-4) 11.1 0.0750
0.04-0.08 (1-2) 9.6 0.0648
0.02-0.04 (0.5-1) 6.0 0.0405
Fine
Table A2 - Summary of the tests performed on hardened concrete in 1st and 2nd casting
Property Age [days] No. of specimens Shape and size [in] (mm)
Compressive Cubic
1st casting 28 3
strength 5.91 × 5.91 × 5.91 (150 × 150 × 150)
7 3
Compressive 28 5 Cubic
strength 56 3 5.91 × 5.91 × 5.91 (150 × 150 × 150)
91 3
Prismatic
2nd casting
Flexural strength 28 2 5.91 × 5.91 × 23.62 (150 × 150 × 600)
(a·b·h)
Cylindrical
Splitting tensile
28 3 5.91 × 11.81 (150 × 300)
strength
(ø·h)