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Example :
(i) O2, H2, C12, gases are adsorbed on the surface of charcoal.
(ii) Silica gels adsorb water molecules from air.
Charcoal, silica gel, metals such as Ni, Cu, Ag, Pt and colloids are some adsorbents
Freundlich Adsorption isotherm: The relationship between and pressure of the gas
at constant temperature is called adsorption isotherm and is given by
Application of adsorption :
Catalyst: Substances which alter the rate of a chemical reaction and
themselves remain chemically and quantitatively unchanged after the
reaction are known as catalysts and the phenomenon is known as catalysis.
Promoters: Those substances which increase the activity of catalyst are called
promoters. Example: Mo is promoter whereas Fe is catalyst in Haber’s Process.
Catalytic poisons (Inhibitors): The substances which decrease the activity of
catalyst are called catalytic poisons or inhibitors e.g., arsenic acts as catalytic
poison in the manufacture of sulphuric acid by ‘contact process.’
Types of catalysis:
a. Homogeneous catalysis: When the catalyst and the reactants are in the same
phase, this kind of catalytic process is known as homogeneous catalysis.
b. Heterogeneous catalysis: When the catalyst and the reactants are in different
phases, the catalytic process is said to be heterogeneous catalysis.
Activity of catalyst: The ability of a catalyst to increase the rate of a chemical reaction is called activity of
a catalyst. The activity of a catalyst depends upon the strength of chemisorption to a
large extent. The adsorption should be reasonably strong but not so strong that they
become immobile and no space is available for other reactants to get adsorbed
Enzyme Catalysis
Enzymes are complex nitrogenous organic compounds which are Produced by living
plants and animals. They are actually protein molecules of high molecular mass and
form colloidal solutions in water.
They are also known as biochemical catalysis
Eg:
Mechanism of enzyme catalysis
Colloids :
Colloids: A colloid is a heterogeneous system in which one substance is dispersed
as very fine particles in another substance called dispersed medium.
Colloidal solutions are intermediate between true solutions and suspensions.
Their size ranges in the order 1 nm to 1000 nm.
Dispersed phase: The substance which is dispersed as very fine particles is called
dispersed phase.
Since size of impure particle is less than colloidal particle ,it will diffuse through the
membrane into outer water & pure colloidal solution is left behind
Colloidal particle move towards oppositely charged electrode
The minimum number of millimoles of the electrolyte required for complete coagulation
of one litre of a colloidal sol is called its coagulation or flocculation
value. Smaller the value of coagulation value of an electrolyte,greator is its
coagulating power
It can be done by:
Emulsion :is a colloidal dispersion in which both dispersed phase and dispersed
medium are liquids
Type of emulsion:
a. Water dispersed in oil: When water is the dispersed phase and oil is the
dispersion medium. E.g. butter ,cold cream
b. Oil dispersed in water: When oil is the dispersed phase and water is the
dispersion medium. E.g. milk ,vanishing cream
Emulsifying agent: The substances which are added to stabilize the emulsions are
called emulsifying agents or emulsifiers. E.g. soaps, gum
Examples of colloids:
industrial use :