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Sedimentology of Hirnantian glaciomarine deposits in the Balkan Terrane,
western Bulgaria: Fixing a piece of the north peri-Gondwana jigsaw puzzle
Athanas Chatalov
PII: S0037-0738(17)30016-7
DOI: doi:10.1016/j.sedgeo.2017.01.004
Reference: SEDGEO 5154
Please cite this article as: Chatalov, Athanas, Sedimentology of Hirnantian glaciomarine
deposits in the Balkan Terrane, western Bulgaria: Fixing a piece of the north peri-
Gondwana jigsaw puzzle, Sedimentary Geology (2017), doi:10.1016/j.sedgeo.2017.01.004
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4 Athanas Chatalov
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6 Department of Mineralogy, Petrology and Economic Geology, Faculty of Geology and Geography,
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7 Sofia University St. Kliment Ohridski, 15 Tsar Osvoboditel Bd., BG-1504 Sofia, Bulgaria
8 Tel: +359887732049
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9 Fax: +35929446487
12 ABSTRACT
13 Glaciomarine deposits of late Hirnantian age in the western part of the Palaeozoic Balkan Terrane
14 have persistent thickness (~7 m) and lateral uniformity in rock colour, bedding pattern, lithology, and
15 sedimentary structures. Four lithofacies are distinguished from base to top: lonestone-bearing
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16 diamictites, interbedded structureless mudstones, crudely laminated diamictites, and finely laminated
17 mudstones. The diamictites are clast-poor to clast-rich comprising muddy to sandy varieties. Their
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18 compositional maturity is evidenced by the very high amount of detrital quartz compared to the
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19 paucity of feldspar and unstable lithic grains. Other textural components include extraclasts derived
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20 from the local Ordovician basement, mudstone intraclasts, and sediment aggregates. Turbate
21 structures, grain lineations, and soft sediment deformation of the matrix below larger grains are locally
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22 observed. Sedimentological analysis reveals that deposition occurred in an ice-intermediate to ice-
23 distal, poorly agitated shelf environment by material supplied from meltwater buoyant plumes and
24 rain-out from ice-rafted debris. Remobilization by mass-flow processes (cohesive debris flows and
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25
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slumps) was an important mechanism particularly for the formation of massive diamictites. The
26 glaciomarine deposits represent a typical deglaciation sequence reflecting retreat of the ice front
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27 (grounded or floating ice sheet), relative sea-level rise and gradually reduced sedimentation rate with
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28 increasing contribution from suspension fallout. This sequence was deposited on the non-glaciated
29 shelf of the intracratonic North Gondwana platform along the southern margin of the Rheic Ocean.
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30 The Hirnantian strata of the Balkan Terrane can be correlated with similar glaciomarine deposits
31 known from peri-Gondwana terranes elsewhere in Europe showing clear ‘Armorican affinity’. Several
32 lines of evidence suggest that the provenance of siliciclastic material was associated mainly with
33 sedimentary recycling of mature sands which had been deposited across North Gondwana in Cambrian
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40 1. Introduction
41
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43 palaeoclimatic, palaeogeographic, palaeoenvironmental and palaeotectonic reconstructions
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44 (Chumakov, 1985; Crowell, 1999; Menzies, 2002; Hambrey and Glasser, 2003; Eyles and
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45 Januszczak, 2004; Eyles, 2008). It provides information about the major controls, duration
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46 and severity of cold climatic conditions, size and dynamics of the ice masses, related eustatic
47 changes, the complexity of glaciated basins, depositional settings and products, the relation to
48
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adjacent non-glacial environments, and the impact of ancient glaciations on the evolution of
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49 life on Earth. The sedimentary records from pre-Pleistocene glaciations are dominated by
50 glaciomarine deposits which are typically thicker than their terrestrial counterparts (Eyles and
51 Eyles, 1992; Eyles, 1993) being well documented from all major glacial episodes in the
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52 Precambrian and Phanerozoic (Hambrey and Harland, 1981; Deynoux et al., 1994; Eyles,
53 2008). Glaciomarine sediments have a higher potential for preservation because of sufficient
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54 accommodation space and also because they are covered rapidly by transgressive deposits due
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55 to the postglacial sea-level rise (Eyles, 1993). Glacially influenced marine environments
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56 provide valuable records of ice sheet fluctuations because they occur beyond the limits of ice
57 advance and erosion (Licht, 2009). Glaciomarine deposits may also be potential reservoir
58 facies and targets for hydrocarbon exploration in sedimentary basins (Potter et al., 1995;
60 The Hirnantian age of the late Ordovician was a time of extensive ice-sheet growth over
61 large parts of the Gondwana Supercontinent which occupied a southern polar position
62 throughout most of the early Palaeozoic (Ghienne et al., 2007; Le Heron and Dowdeswell,
63 2009; Le Heron and Howard, 2010; Torsvik and Cocks, 2011; Pohl et al., 2016). Various
64 glacial non-depositional features and glacial rocks have been recognized in many countries,
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65 e.g., from Africa, Europe, Asia, and South America (Beuf et al., 1971; Young et al., 2004;
66 Turner et al., 2005; Ghienne et al., 2007; Schönian and Egenhoff, 2007; Gutiérrez-Marco et
67 al., 2010; Le Heron et al., 2010; Ghienne, 2011, among others). Glaciomarine deposits have
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68 been identified in particular from glaciated and non-glaciated shelf areas of the intracratonic
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69 North Gondwana platform (Ghienne et al., 2007). They consist of diverse ice-contact, ice-
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70 proximal and ice-distal facies which provide information about advance/retreat phases of the
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71 ice sheet(s) as well as the palaeogeographic position of many Gondwana and peri-Gondwana
72 terranes during the late Ordovician (e.g., Steiner and Falk, 1981; Robardet and Doré, 1988;
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Brenchley and Štorch, 1989; Leone et al., 2002; Monod et al., 2003; Denis et al., 2007; Le
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74 Heron et al., 2007; Ghavidel-syooki et al., 2011; Moreau, 2011; Schönlaub et al., 2011; Couto
75 et al., 2013). Prolific glaciogenic hydrocarbon systems occur in the Upper Ordovician/Lower
76 Silurian of North Africa and the Middle East (Le Heron et al., 2009; Huuse et al., 2012, and
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77 references therein) with postglacial black shales being important source rocks (Lüning et al.,
78 2000).
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79 This study focuses on the sedimentology of Hirnantian glaciomarine strata which are
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80 exposed in the western part of the Palaeozoic Balkan Terrane in western Bulgaria. A detailed
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81 petrographic description of the siliciclastic rocks is presented with special emphasis on the
82 depositional characteristics of the diamictites. The field and microscopic observations are
83 used to interpret the particular glaciomarine environment and to clarify the relative
85 proximity of the ice front and related temporal changes in sea level, sedimentation rate,
86 depositional mechanisms and products are also discussed. Conclusions are drawn about the
88 and major-element chemistry. A correlation with similar glaciomarine deposits known from
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89 other peri-Gondwana terranes and results from previous studies are integrated to determine
90 the palaeogeographic position and affinity of the Balkan Terrane during the late Ordovician.
91
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92 2. The Ordovician System in Bulgaria – a brief synopsis
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94 The occurrence of Ordovician rocks in Bulgaria was identified by Haberfelner and
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95 Bončev (1934) who found trilobite and graptolite fauna in Palaeozoic exposures from the
96 western part of the country. Later, palaeontological and biostratigraphical studies resulted in
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the subdivision of Ordovician series and stages as well as establishing formal and informal
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98 lithostratigraphic units (Spassov, 1960, 1968; Sachanski and Tenchov, 1993; Yanev et al.,
99 1995; Gutierrez-Marco et al., 2003; Sachanski and Tanatsiev, 2010, among others).
100 Three Palaeozoic terranes (Moesian, Balkan and Thracian) were distinguished in the
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101 basement of the eastern Balkan Peninsula (Fig. 1) with Gondwana and peri-Gondwana origins
102 although each terrane is characterized by specific tectonic and sedimentary evolution (Yanev,
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103 1993, 1997, 2000; Haydoutov and Yanev, 1997; Yanev et al., 2005). Palaeomagnetic data for
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104 the Balkan Terrane obtained from outcrops in neighbouring Serbia (Milicevic, 1994)
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105 indicated palaeolatitudes of 29–50°S, 30–40°S and 38°S during the Early, Middle and Late
106 Ordovician, respectively. The occurrence of Middle to Upper Ordovician oolitic ironstones
107 and glaciomarine diamictites (Sachanski, 1994; Yanev, 2000; Gutierrez-Marco et al., 2003)
108 was considered as good evidence for deposition in the temperate humid zone at about 40°S
109 (Yanev et al., 2005). In the Ordovician period the Balkan Terrane represented a shallow
110 marine environment characterized by siliciclastic deposition (Yanev et al., 2005, 2006). It was
111 also presumed that the Balkan Terrane was closely linked to the ‘Armorican Terrane
112 Assemblage’, i.e., during its entire Palaeozoic evolution (Yanev et al., 2005, 2006;
113 Winchester et al., 2006). The origin and palaeogeographic affinity of the Moesian Terrane
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114 during the early Palaeozoic remains unclear as different interpretations were proposed for its
115 western part, i.e., in Bulgaria and Romania (e.g., Yanev et al., 2006; Oczlon et al., 2007;
116 Kalvoda and Bábek, 2010). Geochronological and geochemical studies on the metamorphic
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117 basement of the Thracian Terrane, i.e., present-day Rhodope and Serbo-Macedonian massifs,
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118 revealed the presence of North Gondwana and peri-Gondwana protoliths of early Palaeozoic
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119 age (Himmerkus et al., 2009; Bonev et al., 2013; Antić et al., 2016). According to a recently
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120 published global reconstruction for the late Ordovician, Moesia was an integral part of the
121 Armorica sub-terrane and the Rhodope massif belonged to the intra-Alpine sub-terrane of the
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ribbon-like Galatian superterrane (Stampfli et al., 2013). Palaeoclimatic indicators and
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123 palaeomagnetic data support a continuous migration of the Balkan and Moesian Terranes
124 from temperate southern latitude in the Ordovician/Silurian to the northern arid zone in the
125 Permain (Yanev, 1993; Haydoutov and Yanev, 1997; Yanev, 2000; Yanev et al., 2005).
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126 According to Stampfli et al. (2013) the Galatian superterrane became detached in segments
127 from Gondwana during the Devonian, starting with the Armorica sub-terrane around 400 Ma.
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128 The thickest Ordovician sequence in Bulgaria is known from the Balkan Terrane,
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129 reaching up to 4700 m in the western part of the country (Yanev, 2000). It comprises about
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130 2000 m thick marine sedimentary strata (Yanev et al., 2006) including predominantly
131 siliciclastic rocks (claystones, siltstones, sandstones), minor chert, and rare oolitic ironstones.
132 The Middle to Late Ordovician age of these deposits was determined on the basis of
133 macrofossils (graptolites, trilobites) and palynomorphs (Spassov, 1960; Kalvacheva, 1990;
134 Sachanski, 1993; Gutiérez-Marco et al., 2002, 2003; Lakova and Sachanski, 2004). Various
135 taxa and associations of acritarchs, trilobites and brachiopods from the western Balkan
136 Terrane are closely related to peri-Gondwana provinces (Kalvacheva, 1990; Gutierrez-Marco
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140
141 Ordovician sedimentary rocks are mainly exposed in the western Balkan Terrane.
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142 Geographically, they occur in the western sector of Stara planina Mountains which are
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143 integral part of the Alpine Carpathian-Balkan belt (Fig. 2). In terms of Alpine tectonic
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144 subdivision the Palaeozoic outcrops belong to the Svoge Unit which is the northernmost
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145 allochthone fragment of the Srednogorie Zone (Ivanov, 1988). The latter represents a specific
146 element of the so called Intermediate Balkanides (Fig. 2, inset map) and was formed during
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the late Cretaceous on a variegated Hercynian basement and a Lower Mesozoic orogenic
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148 edifice. After the Middle Eocene the Srednogorie moved northwards and was thrusted over
149 parts of the West Balkan Zone (i.e., External Balkanides) as a result of general compression.
150 From the south the Svoge Unit is bounded by other tectonic units of the Srednogorie Zone and
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151 the superimposed Neogene-Quaternary Sofia graben. The pre-Mesozoic basement of the
152 Svoge Unit was greatly influenced by Hercynian and Alpine deformations.
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153 The Ordovician succession outcropping in the western part of Srednogorie Zone
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154 consists of five lithostratigraphic units (Angelov et al., 2010, 2011): siltstone-argillite
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155 metaformation, Grohoten Formation, Tseretsel Formation, Sirman Formation, and the
156 lowermost part of Saltar Formation. According to Sachanski and Tanatsiev (2010) the four
157 formal units have chronostratigraphic range from the Darriwilian Stage of the Middle
158 Ordovician Series to the Hirnantian Stage of the Upper Ordovician Series (Fig. 3). The
159 siliciclastic rocks studied herein are referred to as Sirman Fm (Sachanski and Tenchov, 1993).
160 Non-fosiliferous strata of the underlying Tseretsel Fm (Spassov, 1960) correspond to the
161 Katian Stage as defined by their stratigraphic position (Sachanski, 1994; Sachanski and
162 Tanatsiev, 2010). These light grey-greenish, fissile mudstones display a change of the rock
163 colour to dark grey in the uppermost 2-3 m of the unit, showing a sharp lithological contact
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164 (planar or slightly undulating) with diamictites of the Sirman Fm (Fig. 4a, b). Thin-bedded,
165 dark grey to black cherts (lydites), organic-rich shales and siliceous shales of the Saltar Fm
166 (Sachanski and Tenchov, 1993) have a sharp lithological but conformable contact with the
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167 Sirman Fm (Fig. 4c). The chronostratigraphic range of the chert-shale succession was
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168 determined to span from the upper Hirnantian Stage of the Upper Ordovician Series to the
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169 lower Telychian Stage of the Llandovery Series on the basis of graptolites (Sachanski, 1993;
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170 Lakova and Sachanski, 2004). In particular, the presence of Normalograptus persculptus
171 (now referred to as Metabolograptus persculptus, e.g., Melchin et al., 2011; Štorch and
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Schönlaub, 2012) at the very base of the Saltar Fm gives grounds to define a late Hirnantian
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173 age (persculptus Biozone) for the Sirman Fm (Sachanski, 1993).
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177 Ten stratigraphic sections with exposed Upper Ordovician rocks were selected across
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178 the study area for description and sampling in the field (Fig. 2). The thicknesses of Sirman Fm
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179 were measured and macroscopic characteristics of the rocks (stratal boundaries, colours,
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180 sedimentary structures, lithologies, clast morphology, composition and size) were described.
181 Seven polished slabs were prepared from laminated rock types and sixty-six samples (plus
182 three additional samples from the underlying Tseretsel Fm) were collected for observation
183 with transmitted light microscopy. All thin sections were stained with dilute HCl solution of
184 Alizarine red S and potassium ferricyanide to detect the presence of carbonates.
185 The bulk rock composition of diamictites and mudstones was determined by wet
186 chemical analysis of twelve powdered samples. To estimate the relative extent of
187 palaeoweathering and to examine the provenance composition the chemical index of
188 alteration (CIA, Nesbitt and Young, 1982) was calculated from data for the major oxides
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189 using molar proportions in the formula Al2O3/[Al2O3 + CaO* + Na2O + K2O] × 100. Because
190 CaO* represents CaO content in the silicate minerals only, corrections were made for CaO in
191 apatite using the available P2O5 data (Fedo et al., 1995). If the remaining number of moles
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192 was less than that of Na2O, the CaO value was adopted as CaO*, and if the number of moles
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193 for CaO was greater than Na2O, the CaO* was assumed to be equivalent to Na2O (McLennan,
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194 1993).
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195
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198 5.1. Stratification, macropetrography and lithofacies
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200 The lower part of the Sirman Fm consists of thick-bedded (0.6-0.8 m), dark grey or
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201 grey-greenish diamictites showing massive or uncommon slump structures (lithofacies 1) and
202 two layers (15 cm and 5 cm thick, respectively) of dark grey, structureless mudstones
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203 (lithofacies 2) having sharp conformable contacts (Fig. 4d, e). The stacked diamictite beds
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204 also have sharp non-erosive basal contacts with local development of low-amplitude load
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205 casts. Subangular to well rounded extrabasinal clasts derived from light grey-greenish
206 mudstones (Fig. 5a, b) and light grey sandstones (Fig. 5c) display a maximum size of about 3
207 cm (i.e., outsized clasts), diverse shapes, and subvertical, random or subparallel orientation to
208 bedding. It is noteworthy that most mudstone extraclasts greatly resemble rocks of the
209 underlying Tseretsel Fm. A second clast type includes dark grey mudstones showing the same
210 maximum size, mostly flattened shape, various degree of roundness, and random orientation
211 (Fig. 5d). The conspicuous similarity of those clasts to the interbedded mudstones of
212 lithofacies 2 implies their intrabasinal origin. Upwards in the section the diamictites become
213 characterized by dominantly medium bedding (0.3-0.5 m) and crude parallel lamination
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214 (lithofacies 3) with the discrete laminae displaying various thicknesses (up to 5 mm), colours,
215 and grain sizes (Figs. 4f, 5e). These rocks contain the same types of extraclasts and intraclasts
216 but having maximum granule size, dominantly elongated shape, and subparallel orientation to
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217 bedding. The siliciclastic succession is topped by a 0.5 m thick bed of grey, finely laminated
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218 mudstones (lithofacies 4) showing gradual transition from the underlying laminated
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219 diamictites (Fig. 5f). The measured thickness of the Sirman Fm ranges between 6.30 m and
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220 7.20 m (Fig. 3).
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5.2. Rock classification and depositional textures
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224 Under the microscope, the two diamictite lithofacies can be classified more precisely by
225 applying the non-genetic textural scheme of poorly sorted sediments proposed by Moncrieff
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226 (1989) and later modified by Hambrey (1994). This classification is based on the proportion
227 between sand and mud (as matrix) against the relative amount of gravel clasts. The Hirnantian
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228 rocks are defined as clast-poor to clast-rich diamictites because the gravel-sized component
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229 varies quantitatively in the 1-15% interval. Muddy (Fig. 6a, b), intermediate (Fig. 6c, d) and
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230 sandy (Fig. 6e, f) varieties of these diamictites are distinguished according to the sand/mud
231 ratio with poor sorting of the sand-sized material being a typical characteristic. The main
232 textural constituents are monocrystalline (strongly dominant) and polycrystalline (sparse)
233 detrital quartz grains as their total amount constantly exceeds 90% of the sand fraction. The
234 grain morphology is subangular to well rounded with moderate degree of sphericity being
235 most common. The bulk of monocrystalline grains are non-undulatory while the rest exhibit
236 sweeping extinction (Fig. 7a). Few quartz grains are characterized by deformation lamellae
237 (Fig. 7b). Some grains are recognized as having definite origin, for example, volcanic quartz
238 shows partly preserved idiomorphic crystal habit, rounded edges, embayments and uniform
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239 extinction (Fig. 7c), while reworked sedimentary quartz is distinguished by the presence of
240 abraded quartz overgrowths (Fig. 7d). Individual crystals in the polycrystalline grains have
241 various numbers, shapes and sizes, and their crystal boundaries are either sutured or straight
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242 indicating metamorphic or plutonic igneous source (Fig. 7e, f). Exotic rock fragments in the
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243 diamictites include quartzites (Fig. 7g), quartzose and arkosic sandstones (Fig. 7h, k),
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244 microcrystalline chert (Fig. 7i), and granitoids (Fig. 7j). Much more common are lithic grains
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245 derived from mudstones, as most of them resemble by colour and texture the rocks of the
246 underlying Tseretsel Fm. These mudstone extraclasts have diverse shapes and degree of
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roundness being invariably characterized by thin oxidized rims (Fig. 8a, b) while few grains
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248 contain quartz veinlets inherited from the parent rock (Fig. 8c). Other mudstone clasts imply
249 intrabasinal source by displaying good rounding, absence of sharply outlined boundaries or
250 oxidized rims, locally manifested effects of mechanical compaction, and great similarity to
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251 the interbedded mudstones of lithofacies 2 (Fig. 8d–f). A specific type of ‘intraclasts’
252 comprises sediment aggregates that bear a resemblance to the surrounding diamictite
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253 groundmass. These aggregates rarely show elongated morphology and distinct boundaries
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254 (Fig. 8g) but more commonly have irregular shape with diffuse boundaries and higher amount
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255 of mud (Fig. 8h–j). Minor detrital constituents in the diamictites include feldspar grains (Figs.
256 6e, 7l) and muscovite flakes (Fig. 6b). The scarce heavy minerals are largely dominated by
257 zircon (Fig. 7f) with tourmaline and rutile being present as single grains. Besides the parallel
258 lamination which is defined by vertical changes in the colour, grain size, and/or sand/mud
259 ratio (Figs. 6f, 9i), some specific microfabrics are also observed in the rocks. For example, in
260 the diamictites of lithofacies 1 there are very rare and isolated occurrences of galaxy/turbate
261 structure, i.e., circular alignment of grains and matrix without a core grain (Fig. 9a, b) or
262 around a large clastic grain (Fig. 9c), as well as grain lineations, i.e., linear arrangement of
263 three or more grains with their long axes being parallel to one another (Fig. 6f). In the crudely
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264 laminated diamictites (lithofacies 3), elongated clasts or mineral grains display subvertical
265 orientation of their long axis (Figs. 7f, 9d), while soft deformation of the matrix occurs below
266 some detrital grains of very coarse sand or granule sizes (Fig. 9d, e).
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267 The interbedded mudstones of lithofacies 2 are characterized by a homogeneous texture
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268 where the silt fraction occurs in minor or negligible amount (Fig. 9f, g). Similarly to the mud
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269 matrix of the diamictites these rocks consist of low birefringent clay particles and randomly
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270 dispersed silt grains largely dominated by quartz. Laminae formed of quartz silt without
271 grading are typical features of the mudstones comprising lithofacies 4 (Fig. 9h). The thin
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laminae (0.2-0.5 mm) are planar to slightly undulating and only locally discontinuous without
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273 showing evidence of significant soft deformation or erosion of underlying units.
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277 The major diagenetic alterations in the diamictites include compaction and mineral
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279 deformation of mudstone intraclasts (Fig. 8b, e, f) or sediment agrregates (Fig. 8g–j), and
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280 scarce grain fracturing plus pressure solution effects which are only present in the sandy
281 diamictites (Fig. 6f). Very small amounts (<1%) of calcite replacing feldspar or lithoclasts are
282 detected in two samples while replacement of feldspar grains by clay minerals is more
283 common (Fig. 7l). Coarse pyrite crystals and aggregates display clear replacement pattern in
284 some crudely laminated diamictites (Fig. 5e). A spectacular feature in the same lithofacies is
285 the occurrence of chamosite strain fringes developed between quartz grains and/or quartz-rich
286 rock fragments (Fig. 9j), and quartz strain fringes grown around subhedral to euhedral pyrite
287 crystals (Fig. 9k). These fringes have been interpreted as products of coaxial progressive
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288 deformation under low temperature conditions and broadly related to the Variscan orogeny of
290
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291 6. Major element chemistry and CIA
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293 The major element concentrations of the Hirnantian diamictites and mudstones are
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294 given in Table 1. Analytical data show that most of the diamictite samples (n = 8) are rich in
295 SiO2 (69.13–81.84%). The source of silica is mainly detrital quartz but also includes quartz-
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bearing rock fragments, mudstone lithoclasts, and silicate minerals in the matrix. The
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297 diamictites have a narrow range of Al2O3 (8.10–13.68%) which is basically related to clay
298 minerals forming the matrix and mudstone lithoclasts. The relatively low content of CaO
299 (0.59–1.72%), Na2O (0.12–1.47%) and K2O (1.33–2.69%) is due to the minor presence of
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300 feldspars, muscovite, some lithic grains and probably illite in the matrix. The mudstone
301 samples (n = 4) have lower values for SiO2 (34.44–62.59%) but higher values for Al2O3
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302 (8.89–20.88%) which is a consequence of the large amount of clay minerals and
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303 predetermines a lower SiO2/Al2O3 ratio compared to the diamictites. The slightly higher
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304 contents of CaO (0.65–3.02%), Na2O (0.53–1.82%) and K2O (0.83–4.41%) in these rocks are
305 likely associated with illite and smectite minerals (see Chatalov, 2014).
306 The calculated average CIA value is 68.8 ± 7.2 (n = 8) for the diamictites and 72.3 ± 5.3
307 (n = 4) for the mudstones, respectively. This slight difference is seemingly related to the
308 presence of detrital feldspar plus feldspar-rich lithic grains (i.e., derived from arkosic
309 sandstones and granitoids) and the less amount of aluminous clays in the coarse-grained
310 lithofacies. Such an effect of grain sorting on the mineralogical and chemical composition of
311 sediments and rocks, and consequently on the CIA values, is a well known relationship as
312 demonstrated by Nesbitt and Young (1996) and Nesbitt et al. (1996). All recorded values are
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313 close to the average shale (70-75) and in particular to the average composition (~70) of
314 Phanerozoic shale (Nesbitt and Young, 1982; Taylor and McLennan, 1985; Condie et al.,
315 2001).
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316
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317 7. Interpretation of the results
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318
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319 7.1. Evidence for glaciomarine sedimentation
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Diamictites are poorly sorted rocks that can be products of various geological settings
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322 regardless of latitude or climate, including the formation of glacial deposits, debrites,
323 turbidites, olistostromes, lahars, regoliths, submarine slumps, tectonites, and impact breccias
324 (Eyles and Januszczak, 2004). In glacial and glacially influenced environments diamictite can
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325 form from lodgement and deformation of subglacial sediments, in situ meltout of ice and
326 release of poorly sorted basal, englacial or supraglacial debris, slumping and reworking of
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328 ‘ploughing’ by grounding ice masses, and from rainout of fine-grained sediment and ice-
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330 Some characteristics of the studied diamictites are typical for both glacial terrestrial and
331 glacial marine deposits (see Hambrey and Glasser, 2003), e.g., poor sorting of clasts,
332 variations of grain and clast morphology and composition, constant mix of clasts over wide
333 area, and presence of well preserved unstable lithic fragments. In addition, the rocks show
334 explicit evidence for a glaciomarine origin, i.e., sedimentation in a marine setting by
335 combination of glacial and marine processes. Thus, they correspond to several criteria
336 proposed for the identification of glaciomarine deposits (Hambrey and Glasser, 2003) which
337 precludes a glacial terrestrial origin: distinct stratification, lower and upper boundaries with
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338 marine strata, presence of lonestones, random arrangement of clasts, and evidence for
339 resedimentation by subaqueous gravity flows. Moreover, the Hirnantian strata occur as
340 laterally persistent deposits having almost constant thickness (i.e., sheet-like geometry) and
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341 showing uniformity in the stratification pattern, rock colours, lithological composition,
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342 depositional structures and textures across the whole area of exposure (see Eyles et al., 1985).
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343 In comparison, relatively thin (<10-15 m) tabular sheets of massive or stratified diamictites
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344 interbedded with mudstones and sandstones are characteristic of modern and late Cenozoic
345 cool-temperate or subpolar glaciomarine shelf sequences (e.g., Dowdeswell et al., 1998;
346
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Elverhøi and Henrich, 2002; Powell and Cooper, 2002), and glaciomarine successions having
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347 similar thicknesses and lithologies are also known from the pre-Mesozoic geological record
348 (Brenchley and Štorch, 1989; Ghienne, 2003; Halverson et al., 2004; Marenssi et al., 2005;
349 Dobrzinski and Bahlburg, 2007; Schönlaub et al., 2011; Ghienne et al., 2013, among others).
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350 Deposition in a glaciomarine environment is further emphasized by the sharp but non-
351 erosional basal contacts of the diamictite beds, sedimentary structures (i.e., parallel
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352 lamination, slumps, low-amplitude load casts), sand-dominated grain size, interlayered marine
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354 Other textural characteristics of the Hirnantian rocks are not diagnostic but appear
355 consistent with the interpreted glaciomarine origin, for example, the occurrence of cm-sized
356 lonestones (i.e., outsized clasts) in the non-laminated diamictites. According to Eyles and
357 Januszczak (2004) lonestones are not a reliable indicator of glacial environments because they
358 are commonly associated with sediment gravity flows. It has been also demonstrated that
359 outsized clasts in fine-grained strata can be formed by other specific processes not particularly
360 related to glaciation (Bennett et al., 1996; Tachibana, 2013, and references therein).
361 Lonestones are usually interpreted as ice-rafted debris, i.e., dropstones, if they deform the
362 underlying sediment (Thomas and Connell, 1985). In this case such deformation was not
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363 observed macroscopically but this may be due to relatively small size of the lonestones,
364 firmness of the substrate at the time of their settling (see Álvaro and Van Vliet-Lanoë, 2009),
365 redeposition by sediment gravity flows, later compaction effects, and/or massive (i.e., non-
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366 laminated) appearance of the diamictites. Meanwhile, possible evidence for ice-rafted origin
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367 includes the subvertical orientation of some elongated lonestones, local concentrations of up
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368 to three outsized clasts, and the overall clast lithology that partly differs from the local
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369 basement (i.e., mudstones of the Tseretsel Fm).
371
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matrix and draping of sediment on the top of very coarse sand- to granule-sized detrital grains
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372 suggest that the latter originated as ice-rafted debris. This small-scale soft sediment
373 deformation was presumably controlled by the particular shape and relatively small size of the
374 dropped grains (Thomas and Connell, 1985). The anisometric extraclasts and mineral grains
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375 with preserved steep dip of their long axis likewise indicate drop release from floating ice and
376 subsequent piercing into stiff or soft substrate (see Álvaro and Van Vliet-Lanoë, 2009). In
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377 addition, the presence of glacial erratics, including unstable lithic fragments such as arkosic
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378 sandstones, granitoids, and some mudstones (not derived from the local basement), implies
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380 Lithified sediment aggregates that resemble the surrounding groundmass in diamictites
381 are similar to aggregates described in the literature termed sediment pellets that have been
382 related to various glacial processes (e.g., Piotrowski et al., 2006; Tomkins et al., 2009; Li et
383 al., 2011, Cowan et al., 2012, and references therein). The so called ‘till pellets’ (Ovenshine,
384 1970) can originate as unconsolidated sediment filling interstices in glacial ice and carried
385 seawards by icebergs to be released through the water column as cohesive pellets upon
386 melting (Ovenshine, 1970; Gilbert, 1990; Goldschmidt et al., 1992). The recognition of such
387 formerly frozen masses of ice-rafted debris in the studied diamictites is based on their diffuse
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388 boundaries (Arnaud and Etienne, 2011), predominantly irregular shape, and lower sand/mud
389 ratio with respect to the diamictite groundmass. Thus, they can be distinguished from the
390 more rarely observed sediment aggregates (pellets) that display distinct boundaries, mostly
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391 elongated morphology, very similar texture to the surrounding diamictite, and probably
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392 represent intrabasinal rip-up clasts.
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393 The presence of galaxy/turbate structure is mainly known from debris flows (e.g.,
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394 Menzies and Zaniewski, 2003; Phillips, 2006; Isbell et al., 2016) and subglacial tills (e.g.,
395 Denis et al., 2010; Cowan et al., 2012; Lea and Palmer, 2014). However, this rotational
396
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structure has been also documented from Neogene and Quaternary glaciomarine diamicts
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397 (Carr et al., 2000; Nelson et al., 2009; Kilfeather et al. 2010). In this case, the rare occurrence
398 of galaxy/turbate structure in the diamictites not associated with other micro-scale
399 deformation features (see Menzies, 2000) supports the interpretation of a glaciomarine origin
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401 To sum up, the combination of macro- and micropetrographic characteristics of the
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402 Upper Ordovician rocks shows close correspondence to other ancient glaciomarine deposits
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403 (Fortuin, 1984; Eyles et al., 1985; Štorch, 1990; Kellerhals and Matter, 2003; Allen et al.,
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404 2004; Bernárdez et al., 2006; Dobrzinski and Bahlburg, 2007; Álvaro and Van Vliet-Lanoë,
405 2009; Ampaiwan et al., 2009; Perez Loinaze et al., 2010; Ghienne et al., 2010; Couto et al.,
406 2013, among many others). Furthermore, indirect evidence comes from the regional
407 correlation with Hirnantian glaciogenic successions exposed in some countries of Europe,
409
411
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412 Glaciomarine sedimentation is controlled by basin geometry, water depth, relief of the
413 sea floor, hydrodynamic regime, volume of meltwater input, debris amount in glacier ice and
414 icebergs, and the proximity of a glacial front (Eyles et al., 1985). Glaciomarine environments
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415 may be subdivided into ice-marginal to ice-proximal, i.e., dominated by glacial processes, and
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416 ice-intermediate to ice-distal, i.e., glacially influenced or dominated by non-glacial marine
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417 processes (Eyles and Eyles, 1992). The combination of several characteristics of the
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418 Hirnantian strata suggests ice-intermediate to ice-distal origin, i.e., deposition from several to
419 tens of kilometers away from the ice margin. These diagnostic features include: relatively
420
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small and persistent thickness of the glaciomarine succession (i.e., sheet-like geometry);
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421 uniformity with respect to the stratification pattern (i.e., distinct bedding), overall lithology
422 (i.e., dominant diamictites and subordinate mudstones) and sedimentary structures; sandy
423 (i.e., gravel-poor) character of the diamictites; presence of cm-sized lonestones; homogeneous
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424 composition of the lithic fragments and intraclasts (see Eyles et al., 1985; Štorch, 1990;
425 Kellerhals and Matter, 2003; Allen et al., 2004; Dobrzinski and Bahlburg, 2007; Álvaro and
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426 Van Vliet-Lanoë, 2009; Ampaiwan et al., 2009; Ghienne et al., 2010; Perez Loinaze et al.,
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427 2010; Arnaud and Etienne, 2011; Couto et al., 2013). In this context, equally important is the
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428 virtual absence of ice-marginal or ice-proximal facies. The Hirnantian strata lack diagnostic
429 features such as coarse-grained (i.e., gravel-rich) deposits, rapid lateral or vertical changes in
430 thickness and lithofacies, irregular bed geometries, major erosional surfaces, fining-up and
432 and glaciotectonic deformation (e.g., Lønne, 1995; Allen et al., 2004; Rieu et al., 2006;
433 Ampaiwan et al., 2009; Henry et al., 2010; Isbell, 2010; Passchier and Erukanure, 2010; Perez
434 Loinaze et al., 2010; Arnaud and Etienne, 2011; Arnaud, 2012; Busfield and Le Heron, 2013;
435 Couto et al., 2013; Koch and Isbell, 2013; Le Heron et al., 2014; Girard et al., 2015).
436 Laminated sediments may form in both ice-proximal and ice-distal modern (e.g., Ó Cofaigh
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437 and Dowdeswell, 2001) and ancient environments (e.g., Couto et al., 2013). However, some
438 characteristics of the laminated lithofacies 3 and 4 are more consistent with ice-distal origin,
439 i.e., sand- or mud-dominated grain size, horizontal orientation and undeformed pattern of
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440 laminae, and lack of outsized clasts. Furthermore, the complete absence of high-energy
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441 depositional or erosional structures in conjunction with the non-winnowed textures and low
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442 degree of sorting of the detrital material in all diamictites and mudstones suggests
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443 sedimentation in poorly agitated mid- to outer-shelf setting, i.e., most probably below the
445
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Sediment material is supplied in glaciomarine systems by meltwater buoyant plumes
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446 released from the glacial margin, ice-rafted debris, mass-flow events, and ocean currents
447 (Eyles et al., 1985; Eyles, 1993). The Hirnantian primary diamicts originated mainly from
448 coupled suspension settling of clay- to sand-sized particles from turbid meltwater plumes and
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449 rain-out of fine- to coarse-grained ice-rafted debris. This general conclusion is based on the
450 following evidence: a) blanket-like geometry of the glaciomarine deposits draping the
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451 substrate; b) lack of grading and wave- or current-induced depositional and erosional
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452 structures; c) random grain alignment and textural variation (i.e., from mud- to sand-
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453 dominated) in the diamictites of lithofacies 1; and d) planar lamination with subparallel
454 orientation of elongated grains and clasts in the diamictites of lithofacies 3. The turbid plumes
455 most likely emanated from the front of a distant grounded or floating glacier while the ice-
456 rafted debris may have been derived from far-travelled icebergs or seasonal sea ice.
457 Distinction between the latter two sources is difficult in ancient successions especially for
458 sand-sized material (Gilbert, 1990; Goldschmidt et al., 1992; Álvaro and Van Vliet-Lanoë,
459 2009) and requires detailed study of grain microtextures (e.g., Stickley et al., 2009; St John et
460 al., 2015). Nevertheless, the diamictite lithology, variable roundness of the detrital material,
461 presence of diverse exotic clasts not derived from the local basement (for comparison see
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462 Isbell et al., 2013) and the occurrence of ‘till pellets’ imply far-travelled iceberg-related
464 diamictites forming the upper part of the Hirnantian succession probably reflects fluctuations
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465 in meltwater discharge from the distant grounded/floating glacier and/or changes in the ratio
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466 between suspension fallout and ice-rafting.
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467 A subaqueous mass flow origin for the primary diamicts can be ruled out considering
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468 the sheet-like geometry, presence of ice-rafted debris and parallel lamination, scarcity of soft-
469 sediment deformation, no correlation between the bed thickness and the maximum clast size,
470
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and lack of associated facies unambiguously produced by sediment gravity flows (e.g.,
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471 turbidites). However, redeposition of the thick-bedded diamictites by such flows, i.e.,
472 cohesive debris flows (Mulder and Alexander, 2001; Talling et al., 2012), is implied by their
473 stacked nature (less than 2 m thick beds), sharp non-erosive basal contacts (probably as a
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474 result from hydroplaning of individual flows), lack of internal structures (except slumped
475 beds), grading and preferred orientation of the clasts, formation of load casts, very poor
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476 sorting, presence of extraclasts derived from basement lithologies, locally abundant mud
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477 matrix and mudstone intraclasts, and absence of disturbance below lonestones (see López-
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478 Gamundí, 1991; Visser, 1994; Mulder and Alexander, 2001; Eyles and Januszczak, 2004;
479 Arnaud and Eyles, 2006; Dobrzinski and Bahlburg, 2007; Ampaiwan et al., 2009; Henry et
480 al., 2010, 2012; Arnaud and Etienne, 2011; Couto et al., 2013; Isbell et al., 2016). In the same
481 context, it is noteworthy that some of the above described textural characteristics, e.g.,
482 outsized clasts, galaxy/turbate structures and sediment aggregates (pellets), are known from
483 deposits of subaqueous debris flows. Moreover, although grain lineations are most common
484 within subglacial tills (van der Meer, 1996; Hiemstra and Rijsdijk, 2003; Cowan et al., 2012),
485 they have been also interpreted as related to debris flow processes (Harris, 1998; Menzies and
487 Subaqueous glaciogenic debris flows may have run-out distances of hundreds of
488 kilometres, even on shallow slopes (Dowdeswell et al., 1998; Laberg and Vorren, 2000;
489 Taylor et al., 2002). Therefore, while the Hirnantian diamictites are believed to have
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490 originally formed by dominant rain-out and suspension settling, those having massive or
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491 slump structures were particularly remobilized by mass-flow processes (Eyles, 1993; Arnaud
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492 and Eyles, 2006) as a result from high sedimentation rates, local oversteepened slopes with
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493 unstable water-saturated substrate, seismic shocks, storm events, meltwater surges, impact of
494 calving icebergs events, or combination of these processes (Boulton, 1990; Álvaro and Van
495
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Vliet-Lanoë, 2009; Arnaud and Etienne, 2011). Similarly, the coeval operation of fallout
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496 processes and sediment gravity flows in glaciomarine (including ice-distal) environments has
497 been interpreted or presumed in many studies of ancient diamictites (e.g., López-Gamundí,
498 1991; Visser, 1997; Marenssi et al., 2005; Arnaud and Eyles, 2006; Rieu et al., 2006;
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499 Dobrzinski and Bahlburg, 2007; Le Heron et al., 2007, 2014; Álvaro and Van Vliet-Lanoë,
500 2009; Ampaiwan et al., 2009; Perez Loinaze et al., 2010; Lang et al., 2012; Henry et al.,
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501 2012; Couto et al., 2013; Deschamps et al., 2013; Dineen et al., 2013). In summary, the
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502 balance between transported material by meltwater turbid plumes, rain-out from ice-rafted
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503 debris and resedimentation by gravity flows could have varied but the homogeneous
505 Episodic bottom currents may have further assisted in the distribution of glaciogenic detrital
506 material across the shelf despite the lack of preserved current-formed structures in the
507 diamictites. Slight variations in the total thickness of the glaciomarine succession were
508 probably caused by uneven sea floor topography (e.g., Eyles et al., 1985), laterally variable
509 supply of siliciclastics from meltwater plumes, and/or locally enhanced redeposition by
511 The sharp and conformable contacts between the diamictites and interbedded mudstones
512 record abrupt changes in the energy regime and sediment supply. The structureless mudstones
513 may have formed by suspension settling of dominantly clay-sized particles supplied from
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514 sand-free meltwater plumes during quiescent periods of suppressed ice-rafting (i.e.,
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515 Dowdeswell et al., 2000; Ó Cofaigh and Dowdeswell, 2001). Alternatively, their deposition
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516 occurred as a result of mud density flows (sensu Talling et al., 2012) producing so called
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517 densite mud (see also Isbell et al., 2016). While the former mechanism applies for the finely
518 laminated mudstones forming the top of the glaciomarine succession, it is likely that subtle
519
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changes in the turbid meltwater discharge and coeval background hemipelagic sedimentation
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520 (i.e., fine terrigenous deposition unrelated to meltwater plumes) produced laminated ungraded
521 sediments in an open-marine, low-energy setting during the maximum glacial retreat.
522
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524
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525 Glaciomarine environments have complex dynamics which are controlled by ice
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526 advances or retreats and related sea-level changes. In general, most glaciomarine
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527 sedimentation takes place during glacial retreats when large volumes of meltwater are
528 released from grounded or floating ice sheets, and hence, sediments deposited during
529 deglaciation phases constitute the bulk of the stratigraphic record (Eyles and Eyles, 1992,
530 2010). Such deposits have great potential for preservation in marine environments because
531 they are covered rapidly by transgressive deposits due to postglacial sea-level rise, and also
533 The Katian mudstones of the Tseretsel Fm forming the immediate pre-Hirnantian
534 basement have been interpreted as deep marine deposits exclusively on the basis of trace
535 fossil analysis (Aceñolaza and Yanev, 2001). Their sharp lithological contact with the
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536 overlying Sirman Fm may be the only record of distant ice sheet advance and related sea-level
537 fall, while the glaciomarine deposits were accumulated mainly during the following glacial
538 retreat and sea-level rise (Fig. 10). Only the thin mudstone interbeds within the lower
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539 diamictite interval probably reflect minor re-advances or stabilisation of the ice front between
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540 phases of intensive glacier ice melting. This general pattern of glacially influenced
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541 sedimentation resulted in the formation of a typical deglaciation sequence (sensu Visser,
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542 1997). Several lines of evidence suggest increasing distance of the depositional locus from the
543 ice front with progressive change in the style of glaciomarine sedimentation and resultant
544
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deposits. For example, the upsection transition from dominantly structureless to crudely
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545 laminated diamictites is accompanied by decreasing bed thickness, disappearance of
546 lonestones, slightly increasing mud content, and diminishing amount and size of mudstone
547 intraclasts and extraclasts derived from the local basement. Moreover, macro- and micro-
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548 characteristics indicative of mass-flow processes, e.g., slumps, load casts, random orientation
549 of clasts, galaxy/turbate structures, grain lineations and intrabasinal rip-up clasts from
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550 diamictites (but not ‘till pellets’), are lacking in the upper part of the glaciomarine succession.
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551 The clear evidence for dropped ice-rafted grains and the appearance of parallel lamination
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552 implies dominant fallout deposition in a more ice-distal setting probably influenced by
553 episodic bottom currents but not dominated by sediment gravity flows. Further decrease of the
554 glacial influence is inferred from the gradual upward transition from crudely laminated, clast-
555 poor diamictites to finely laminated, clast-free mudstones. The greatly diminished thickness
556 and grain size of the discrete laminae reflect reduced sedimentation rate along with increasing
557 distance from the melting ice source by analogy with observations from modern glaciomarine
558 settings (e.g., Boulton, 1990; Ó Cofaigh and Dowdeswell, 2001, and references therein). The
559 formation of fine lamination is particularly interpreted to indicate the increasing contribution
561 during maximum recession of the ice front (see Marenssi et al., 2005; Moreau, 2011;
562 Passchier et al., 2011) in the absence of ice-rafting and most likely intermittent supply of fine-
563 grained material from turbid meltwater plumes. The outlined retrogradational trend continues
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564 in the uppermost Hirnantian to Llandovery strata of the Saltar Fm with the occurrence of
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565 postglacial sediments, e.g., black cherts (lydites) and siliceous shales. Their sharp and
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566 conformable contact with the underlying glaciomarine strata suggests abrupt environmental
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567 change after the final glacial retreat (see Henry et al., 2012), and therefore these deposits were
568 formed during a major transgressive phase in a deeper marine setting (Yanev et al., 2005)
569
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without any glacial influence. Such rapid eustatic sea-level rise as a result of deglaciation is
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570 commonly related to the deposition of black shales as evidenced from the Cryogenian and
571 Lower Palaeozoic sedimentary records (e.g., Lüning et al., 2000; Armstrong et al., 2005; Page
572 et al., 2007; Le Heron et al., 2009, 2011; Melchin et al., 2013).
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573 Similar deglaciation sequences reflecting glacial retreat with concomitant transition
574 from ice-proximal to ice-distal sedimentation were described from Phanerozoic glaciomarine
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575 deposits by Visser (1997), Troedson and Riding (2002), Ghienne (2003), Marenssi et al.
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576 (2005), Vesely and Assine (2006), Ghienne et al. (2010), López-Gamundí (2010), Lang et al.
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578
579 7.4. Palaeoweathering and provenance – clues from the CIA and micropetrography
580
581 The Chemical Index of Alteration (CIA) is the most widely used proxy to determine the
582 intensity of weathering and associated climatic regime in the source area (Bahlburg and
583 Dobrzinski, 2011). It measures quantitatively the extent to which primary minerals such as
584 feldspars are transformed into secondary aluminous clays with removal of mobile cations
585 (Ca2+, Na+, K+) which is enhanced during chemical weathering (Nesbitt and Young, 1982).
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586 While unweathered igneous rocks have CIA values below 55 reflecting cool and/or arid
587 conditions, intense weathering in humid and warm climate results in high concentrations of
588 residual kaolinite clays and/or Al oxihydroxides producing CIA values close to 100. The
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589 average CIA values in shales (70-75) largely correspond to muscovite, illite and smectite
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590 compositions indicating a moderate degree of weathering. The CIA has been successfully
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591 applied in a number of studies on Precambrian and Phanerozoic glacial deposits including
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592 glaciomarine mudstones and diamictites (Nesbitt and Young, 1982, 1996; Visser and Young,
593 1990; Young and Nesbitt, 1999; Young, 2001; Dobrzinski et al., 2004; Young et al., 2004;
594
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Scheffler et al., 2006; Rieu et al., 2007; Passchier and Erukanure, 2010; von Eynatten et al.,
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595 2012; Rose et al., 2013; Gaschnig et al., 2014; Rashid and Ganai, 2015; Ding et al., 2016; Li
596 et al., 2016). Because weathering products dominantly occur in the finer grain-size fractions,
597 CIA values of mudrocks are used to better assess the maximum weathering level in the source
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599 The calculated CIA values for the Hirnantian diamictites (63–76) and mudstones (67–
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600 76) indicate moderate degree of weathering in the source area. The lower mean values for the
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601 diamictites (68.8) relative to the mudstones (72.3) reflect less amount of aluminous clays in
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602 the rock matrix and the same grain size control on CIA has been recorded in other studies of
603 modern and ancient glacial deposits (e.g., Visser and Young, 1990; Nesbitt and Young, 1996;
604 Young and Nesbitt, 1999; von Eynatten et al., 2012). The obtained results conform to
605 previously performed XRD studies on mudstones of the Sirman Fm which revealed the
606 presence of partly ordered R=1 illite/smectite plus minor amounts of kaolinite (Chatalov,
607 2014).
608 A more informative method of representing the CIA than simple comparison of
609 numerical values employs a ternary diagram of A-CN-K with plotted molar proportions of
610 Al2O3, CaO*+Na2O and K2O (Nesbitt and Young, 1984). This triangle may indicate
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612 (Fedo et al., 1995). In the A–CN–K diagram, data points of the diamictites and mudstones
613 outline a cluster that is oriented subparallel to the A–CN line (Fig. 11). Thus, it closely
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614 follows the ideal weathering trend as would be predicted from both theoretical and empirical
IP
615 weathering studies (Nesbitt and Young, 1984). The recorded slight deviation from the ideal
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616 weathering trend is probably due to minor post-depositional increase in K (Fedo et al., 1995)
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617 that could be linked to the presence of illite in the rock matrix and as alteration product of
618 feldspar because the other possible source, i.e., replacement of plagioclase by authigenic K-
619
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feldspar (Fedo et al., 1995), was not observed microscopically. In constraining the initial
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620 compositions of the parent rocks, the samples plot on a line that is consistent with a chemical
621 weathering trend of felsic rocks, i.e., the Hirnantian glacial sediments were derived from
622 rocks having granodioritic to granitic composition (see Rieu et al., 2007; Passchier and
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623 Erukanure, 2010; Nagarajan et al., 2015; Rashid and Ganai, 2015). This conclusion is
624 reinforced by the fact that chemical weathering during glacial erosion and transport is
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625 minimal (van de Kamp, 2010) so that CIA values largely reflect the source rocks (Nesbitt and
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626 Young, 1996; Bahlburg and Dobrzinski, 2011). Gaschnig et al. (2014) found out that the CIA
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627 values of Precambrian and Palaeozoic glacial diamictites are generally higher than those of
628 fresh igneous rocks and the pervasive depletion in Sr relative to the average upper continental
629 crust demonstrates variable rate of chemical weathering of the source terrains. These glacial
630 diamictites generally show a weathering signature inherited from their provenance because
631 there has been very limited syn- or post-depositional chemical weathering (Li et al., 2016).
632 The extrabasinal components of the Hirnantian diamictites are largely dominated by
633 detrital quartz and the bulk of associated rock fragments (excluding mudstones derived from
634 the local basement) are also markedly quartz-rich. This mineralogically mature composition is
635 further emphasized by the ultrastable heavy mineral assemblage with prevailing zircon. The
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636 paucity of feldspar grains and abundance of detrital quartz in association with the variable but
637 generally high amount of clay matrix suggest terrigenous supply from a source area that has
638 been subjected to intensive chemical weathering (see Suttner et al., 1981; Johnson, 1993;
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639 Nesbitt et al., 1996; van de Kamp, 2010). Although the quartz was evidently derived from
IP
640 diverse parent rocks the pronounced dominance of monocrystalline grains with uniform to
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641 slightly undulose extinction implies a felsic plutonic source, i.e., granitoids (Basu et al.,
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642 1975). These conclusions about palaeoweathering and provenance based on micropetrography
643 are consistent with the above interpretation of the CIA values. However, the compositional
644
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maturity of the diamictites is accompanied by some textural maturity as evidenced by the
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645 good roundness and medium to high degree of sphericity of many detrital grains. This may
646 indicate recycling of older sediments or sedimentary rocks because the glaciomarine
648
650
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652
653 An attempted correlation between the Balkan Terrane and other regions with Hirnantian
654 glaciomarine record in Europe, Africa and Asia (Fig. 12A) reveals close similarities to
655 occurrences of ice-distal deposits in France (Doré, 1981; Robardet and Doré, 1988; Barca et
656 al., 1996; Piçarra et al., 2002), Germany (Steiner and Falk, 1981; Katzung, 1999; Ziegler and
657 Wimmenauer, 2001), Italy (Leone et al., 2002; Oggiano and Mameli, 2006), Austria
658 (Schönlaub et al., 2011), and the Czech Republic (Brenchley and Štorch, 1989; Štorch, 1990).
659 The most prominent feature is the presence of fine-grained diamictites (i.e., having muddy to
660 sandy groundmass) with outsized clasts despite variations in the clast size, morphology,
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661 abundance and provenance described from those areas. Other common characteristics include
662 rock colour, bedding patterns, sedimentary structures, quartz enrichment, lack of fossils, and
663 lithology of the postglacial cover. The glaciomarine successions have various total
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664 thicknesses but constantly conformable contacts with underlying and overlying marine strata.
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665 A close analogue of the Sirman Fm occurs in the Kučaj Unit of the East Serbian Carpatho–
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666 Balkanides, i.e., Serbian part of the Balkan Terrane, where similar characteristics (thickness,
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667 colour, bedding, texture, composition) of a Hirnantian silicilastic unit and its relations with
668 the units below and above led Krstič et al. (2005) to infer deposition in a glaciomarine
669
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environment. In contrast to the presented evidence from other peri-Gondwana terranes with
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670 exposed glaciomarine strata, i.e., Morocco (Le Heron et al., 2008), Portugal (Brenchley et al.,
671 1991), Spain (Álvaro and Van Vliet-Lanoë, 2009), France (Doré, 1981), Czech Republic
672 (Štorch, 2006), Turkey (Monod et al., 2003) and Iran (Ghavidel-syooki et al., 2011), the
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673 acquired data from the Balkan Terrane allow recognition of only one major cycle of ice sheet
674 advance and retreat which produced a thin deglacial sequence. Most studies have
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675 demonstrated that the Hirnantian included two main phases of ice advance and retreat with the
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676 second phase in the late Hirnantian marking the glacial maximum (see Melchin et al., 2013;
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677 Ghienne et al., 2014, and references therein). The late Hirnantian age (persculptus Biozone)
678 of the Sirman Fm implies that the recorded single cycle of ice advance–retreat corresponds to
680 The new sedimentological results and the regional correlation unequivocally
681 demonstrate that the Hirnantian rocks of western Bulgaria were deposited on the non-
682 glaciated shelf of the North Gondwana platform. This conclusion is consistent with available
683 palaeobiogeographic data from the Ordovician System of the Balkan Terrane, for example,
684 the Middle Ordovician benthic faunas (brachiopods and trilobites) and acritarchs that are
685 closely related to peri-Gondwana provinces (Kalvacheva, 1990; Gutierrez-Marco et al., 2002,
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686 2003). Although the peri-Gondwana origin of three Palaeozoic terranes in Bulgaria was
687 suggested long ago by Yanev (1993), the Balkan Terrane has been rarely shown since then on
688 global or regional palaeogeographic maps, and moreover, these refer mainly to post-
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689 Ordovician time slices of the Palaeozoic (Yanev et al., 2006; Oczlon et al., 2007; Kalvoda and
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690 Bábek, 2010; Sachanski et al., 2010). Only recently, Sachanski et al. (2015) used the
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691 Hirnantian reconstruction of North Gondwana after Scotese (2014) to illustrate the
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692 palaeogeographic position of Silurian–Lower Devonian sequences exposed in Africa, Europe
693 and Turkey, including the Balkan Terrane. The same global palaeomap can be applied in this
694
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study to show the inferred location of the Balkan Terrane in the latest Ordovician (Fig. 12B)
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695 with juxtaposition of the other peri-Gondwana terranes where dominantly glaciomarine
696 sedimentation occurred during the Hirnantian (based on data compiled from Monod et al.,
697 2003; Yanev et al., 2006; Linnemann et al., 2011; Torsvik and Cocks, 2011; Melchin et al.,
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698 2013; Stampfli et al., 2013; Sachanski et al., 2015, and references therein).
699 Several peri-Gondwana terranes having different present-day locations in Europe were
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700 situated along the north periphery of Gondwana, i.e., on the southern margin of the Rheic
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701 Ocean, during the early Palaeozoic. Some of them (Armorica s. str., Iberia, Bohemia, Saxo-
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702 Thuringia) have been referred to as ‘Armorican Terrane Assemblage’ (Tait et al., 1997) in the
703 literature, although the number of terranes included varies according to different authors (e.g.,
704 Franke, 2000; Yanev et al., 2006; Stampfli et al., 2013). Linnemann et al. (2000) noted that
705 this term should be used for the group of peri-Gondwana terranes showing important common
706 features, i.e., ‘Armorican affinities’, such as the occurrence of Cadomian (Pan-African)
709 these considerations, Yanev et al. (2005, 2006) and Winchester et al. (2006) assigned the
710 Balkan Terrane to the Armorican Terrane Assemblage on the basis of stratigraphic,
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712 mentioned above) the presence of late Neoproterozoic oceanic lithosphere and Cambrian–
713 early Ordovician island-arc magmatism (von Quadt et al. 1998; Savov et al., 2001; Carrigan
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714 et al., 2003), occurrence of Ordovician oolitic ironstones (Yanev, 2000; Gutierrez-Marco et
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715 al., 2003), and Emsian chitinozoans showing Gondwana affinities (Yanev et al., 2005, 2006).
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716 In the global reconstruction for the Hirnantian proposed by Stampfli et al. (2013) the Balkan
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717 Terrane can be integrated as part of the Armorica sub-terrane of the Galatian superterrane.
718 The Armorican Terrane Assemblage (or Armorica sub-terrane, Armorica s.l.) became
719
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detached from Gondwana in the Early–Middle Devonian along with closing of the Rheic
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720 Ocean and opening of the Palaeotethys Ocean (Robardet, 2003; Nance et al., 2010; Torsvik
722
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724
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725 The presence of mudstone extraclasts in the glaciomarine deposits of the Balkan
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726 Terrane reflects erosional processes which probably affected the locally emergent pre-
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727 Hirnantian basement as a result of the significant glacio-eustatic sea-level fall (see Brenchley
728 et al., 2006; Loi et al., 2010; Ghienne, 2011; Kröger et al., 2015). However, the bulk of
730 diamictites, and hence implies a specific major sediment source. This compositional maturity
731 is mainly indicated by the large predominance of detrital quartz but also by the ultrastable
732 heavy mineral assemblage, presence of quartz-rich lithics, scarcity of feldspar grains, very
733 low amount of unstable rock fragments (excluding those derived from basement lithologies),
734 and abundant clay matrix. The provenance may have been related in general to chemically
735 weathered felsic plutonic rocks which is confirmed by both the CIA values of analyzed bulk
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736 samples from all lithofacies and the optical characteristics of detrital quartz grains in the
737 diamictites. However, some textural maturity of the diamictites is evidenced by the roundness
738 and sphericity of many detrital grains, and therefore suggests possible recycling of older
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739 sediments or sedimentary rocks.
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740 Extreme chemical weathering and erosion on the uplifted landscape of North Gondwana
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741 took place from the latest Neoproterozoic to the pre-glacial Ordovician forming a peneplain
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742 and producing large volumes of quartz-rich sands (Avigad et al., 2003, 2005). These
743 sediments were derived mainly from the Neoproterozoic Pan-African continental basement
744
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(including abundant granitoids) and deposited as a thick sheet of first-cycle sediments across
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745 a vast area extending from the present-day northwestern Africa to the Arabian Peninsula
746 (Noblet and Lefort, 1990; Burke et al., 2003; Avigad et al., 2005). Meanwhile, other studies
747 based on detrital zircon geochronologies suggested contribution from more remote Gondwana
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748 source areas comprising older Precambrian crust (Avigad et al., 2003; Kolodner et al., 2006;
749 Squire et al., 2006; Linnemann et al., 2011; Morag et al., 2011; Altumi et al., 2013; Meinhold
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750 et al., 2013; Rösel et al., 2014). Dispersal of the eroded sandy material on the margins of
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751 North Gondwana was favoured by thermal subsidence in the aftermath of a late
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752 Neoproterozoic (post-orogenic) rifting that provided accommodation for the thick blanket of
753 fluvial and marine quartz-rich sands (Burke et al., 2003). Transport during Cambrian–
754 Ordovician times occurred via a continent-wide braided river system with general south-to-
755 north direction throughout North Africa and Arabia (Beuf et al., 1971; Avigad et al., 2005;
756 Kolodner et al., 2006), and further northwards in peri-Gondwana areas (Noblet and Lefort,
757 1990; Linnemann and Romer, 2002; Avigad et al., 2012; Shaw et al., 2014). The siliciclastic
759 mature sandstones (Avigad et al., 2005; Kolodner et al., 2006; Sabaou et al., 2009;
760 Linnemann et al., 2011; Bassis et al., 2016). This maturity resulted not only from the intensive
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761 chemical weathering but also from the long-distance fluvial transport (Morag et al., 2011;
762 Shaw et al., 2014) and coastal reworking where deposition took place in shallow marine
763 environment (Sabaou et al., 2009). Sedimentation during the Ordovician became dominated
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764 by quartz arenites (e.g., Avigad et al., 2005; Kolodner et al., 2006; Morag et al., 2011; Shaw
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765 et al., 2014) suggesting recycled sediment sources (Noblet and Lefort, 1990; Linnemann and
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766 Romer, 2002; Sabaou et al., 2009).
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767 The combined analysis of micropetrographical and geochemical data obtained from
768 glaciomarine rocks of the Balkan Terrane implies that the major source of siliciclastic
769
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material was associated with quartz-rich sands deposited across the North Gondwana platform
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770 in Cambrian and pre-glacial Ordovician times. During the Hirnantian glaciation the mature
771 sandy detritus was incorporated in the expanding ice-sheet and then released from the melting
772 ice on the broad shelf area of the platform (Huuse et al., 2012). This conclusion is supported
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773 by available data for the main palaeo-ice flow orientations which indicate that the glaciogenic
774 material was transported by continental glaciers and floating ice in northwest to northeast
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775 directions (Beuf et al., 1971; Monod et al., 2003; Moreau et al., 2005; Ghienne et al., 2007;
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776 Le Heron and Craig, 2008; Denis et al., 2010; Le Heron and Howard, 2010). The redeposition
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778 sediments was particularly suggested for glaciogenic successions in Lybia (Le Heron and
779 Howard, 2010) and Saudi Arabia (Bassis et al., 2016). Furthermore, a literature review reveals
780 that significant quartz enrichment of Hirnantian glaciomarine diamictites was reported in a
781 number of studies of peri-Gondwanan terranes in Portugal (Brenchley et al., 1991; Couto et
782 al., 2013), Spain (Fortuin, 1984; Álvaro and Van Vliet-Lanoë, 2009), France (Robardet and
783 Doré, 1988), Sardinia (Leone et al., 2002), Czech Republic (Brenchley and Štorch, 1989),
784 Turkey (Ghienne et al., 2010), and Iran (Ghavidel-syooki et al., 2011). Published
785 micropetrographic data demonstrate that the morphology of detrital quartz grains varies from
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786 angular (e.g., Fortuin, 1984) to well rounded (e.g., Brenchley and Štorch, 1989). Therefore, a
787 major source of mature siliciclastics for those ice-proximal to ice-distal environments must
788 have been also related to the Cambrian-Ordovician quartz-rich sands of North Gondwana
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789 although the patterns of sedimentary recycling and glacial/deglacial reworking have
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790 apparently varied.
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791 The calculated CIA values for the studied glaciomarine deposits closely correspond to
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792 the composition of average shale thus indicating moderate degree of weathering in the source
793 area. However, assuming that the major source of siliciclastics was associated with
794
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sedimentary recycling of mature Cambro-Ordovician sands from North Gondwana is at
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795 variance with the extreme chemical weathering conditions which prevailed across that vast
796 area from the latest Neoproterozoic to the pre-glacial Ordovician and produced first-cycle
797 quartz arenites with abundant kaolinite (i.e., Avigad et al., 2005). This discrepancy can be
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798 explained by some contribution of terrigenous material derived from less weathered sources
799 (see Romer and Hahne, 2010) and/or erosion of the local pre-glacial basement that generated
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801
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802 9. Conclusions
803
804 Hirnantian siliciclastic rocks exposed in the western Balkan Terrane comprise four
805 lithofacies having distinct morphological and microtextural characterisitics. The diamictites
806 and mudstones provide clear evidence for glaciomarine sedimentation in an ice-intermediate
807 to ice-distal, low-energy shelf envrionment. Deposition resulted from suspension settling from
808 meltwater plumes, rain-out of ice-rafted debris, remobilization by sediment gravity flows, and
809 probably episodic bottom currents. The glaciomarine sediments accumulated mainly during
810 retreat of a distant grounded or floating ice sheet and coeval sea-level rise in the late
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811 Hirnantian. A single deglaciation sequence was produced, reflecting a gradually reduced
812 sedimentation rate, waning of mass-flow processes and sediment supplied through ice-rafting,
813 and increasing contribution from suspension fallout. This glaciomarine succession is
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814 relatively thin and laterally persistent thus representing an important stratigraphic marker in
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815 the Lower Palaeozoic sedimentary record of the Balkan Terrane. It also provides valuable
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816 support for the ‘Armorican affinity’ and palaeogeographic position of this Palaeozoic terrane
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817 during the late Ordovician. The sedimentological analysis and correlation with Hirnantian
818 glaciogenic strata from other regions conclude that deposition occurred on the non-glaciated
819
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shelf of the North Gondwana platform. In a compiled palaeogeographic reconstruction of the
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820 broad domain with glaciomarine sedimentation along the southern margin of the Rheic ocean,
821 the Balkan Terrane is placed as a missing piece of the north peri-Gondwana jigsaw puzzle,
822 thus linking numerous terranes from Northwest Africa/Europe and remote terranes in
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823 Southwest Asia (Turkey, Iran). Mineralogical maturity of the Hirnantian diamictites and
824 additional geochemical data imply that the provenance of siliciclastic material was associated
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825 mainly with sedimentary recycling of mature sands which had been deposited in fluvial and
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826 marine environments across North Gondwana in Cambrian and pre-glacial Ordovician times.
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827 These results can be widely used for correlation with glaciomarine strata from the
828 Hirnantian record of other North Gondwana and peri-Gondwana terranes. On a broader scale,
829 the present study enables better understanding of glaciomarine sedimentation in ancient
830 environments in terms of depositional processes and their products. In particular, the
831 investigated deposits represent a prominent example of deglaciation sequence formed entirely
832 in ice-intermediate to ice-distal settings. Therefore, they provide a solid basis for comparison
833 with similar glaciogenic successions from the geological record suggesting reliable criteria for
835 Furthermore, this study demonstrates that combined field, microtextural and geochemical data
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836 may be used to thoroughly analyze the provenance of siliclastic material supplied in
838
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839 Acknowledgements
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840
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841 I greatly acknowledge Assoc. Prof. Dian Vangelov (Sofia University ‘St. Kliment Ohridski’)
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842 who gave the original idea for this study. I am also deeply grateful to Assoc. Prof. Valeri Sachanski
843 and Dr. Stoyan Tanatsiev (Mining-Geological University ‘St. Ivan Rilski’, Sofia) for their very
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844 important assistance during the field work. I thank Prof. Petr Štorch (Czech Republic) and an
845 anonymous reviewer for their helpful comments and critical remarks on the manuscript.
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846
847 References
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1366 Sachanski, V., Göncüoglu, M.C., Gedik, I., 2010. Late Telychian (early Silurian) graptolitic shales and
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1488 Bulgaria: Palaeozoic marine basin development, palaeogeography and tectonic evolution.
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1494 Mediterranean Region. Geological Society of London, Special Publications 260, pp. 51–67.
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1495 Young, G.M., 2001. Comparative geochemistry of Pleistocene and Paleoproterozoic (Huronian)
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1501 Young, G.M., Minter, W.E.L., Theron, J.N., 2004. Geochemistry and palaeogeography of upper
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1502 Ordovician glaciogenic rocks in the Table Mountain Group, South Africa. Palaeogeography,
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1504 Ziegler, P.A., Wimmenauer, W., 2001. Possible glaciomarine diamictites in Lower Paleozoic series of
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1505 the southern Black Forest (Germany). Neues Jahrbuch für Geologie und Paläontologie,
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1527 Figure 7
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1530 Figure 8
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1539 Figure 11
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1548
1549 Fig. 1. Palaeozoic terranes and exposures (shown as blue patches) in Bulgaria (from
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1550 Yanev, 2000; Yanev et al., 2006).
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1551
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1552 Fig. 2. Outcrops of Hirnantian glaciomarine rocks (Sirman Fm) in the western
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1553 Srednogorie Zone (data used from Angelov et al., 2010, 2011). Symbols: 1 – Quaternary
1554 sediments, 2 – Permian volcanic and sedimentary rocks, 3 – Carboniferous volcanic and
1555
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sedimentary rocks, 4 – Lower–Upper Devonian sedimentary rocks, 5 – Pridoli–Lower
1559 sections. Inset map: Alpine tectonic subdivision of Bulgaria (from Ivanov, 1988) with
1560 designated location of the study area. Hachures outline the Srednogorie Zone and dotted
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1562
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1563 Fig. 3. (left) Stratigraphy of the Ordovician System in the western Srednogorie Zone
1564 (from Sachanski and Tanatsiev, 2010) with only formal lithostratigraphic units shown. (right)
1565 Lithologic log of the Sirman Fm and vertical distribution of the recognized glaciomarine
1566 lithofacies.
1567
1568 Fig. 4. (a) Sharp planar contact (marked by hammer) between fissile mudstones of the
1569 Tseretsel Fm (TsF) and thick-bedded diamictites of the Sirman Fm (SmF). Scale: hammer is
1570 31 cm long; (b) Slightly undulating contact (arrows) between the same two units. (c) Sharp
1571 conformable contact (marked by hammerhead) between laminated mudstones of the Sirman
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1572 Fm (SmF) and thin-bedded cherts of the Saltar Fm (StF); (d) Thick beds of structureless
1573 diamictites separated by thin mudstone bed (marked by hammerhead). Scale: hammer is 33
1574 cm long; (e) Slump developed in diamictite; (f) Lower and upper parts of the Sirman Fm
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1575 (boundary marked by dashed line) consisting of thick-bedded massive diamictites (md) and
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1576 medium-bedded laminated diamictites (ld), respectively. Scale: yardstick (arrow) is 1 m long.
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1577
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1578 Fig. 5. Structureless diamictites (lithofacies 1) from the lower part (a–d) and laminated
1579 rocks from the upper part of the Sirman Fm (e, f): (a) Well rounded pebbly lonestones
1580
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(encircled) probably derived from mudstones of the underlying Tseretsel Fm. Coin diameter
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1581 is 24 mm; (b) Elongated outsized clasts of mudstones (smaller one shown by arrow) with
1582 subvertical orientation to bedding (dashed line indicates bedding plane); (c) Pebble-sized
1583 lonestone of sandstone lying with its long axis subparallel to bedding. Pen is 14 cm long; (d)
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1584 Rock specimen with flat-shaped pebbly intraclasts of dark grey mudstones (arrows) having
1585 various sizes and degree of roundness; (e) Polished slab of crudely laminated diamictite
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1586 (lithofacies 3) showing mudstone extraclasts (blue arrows) and intraclasts (yellow arrows)
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1587 with maximum granule size, mostly elongated shape and subparallel orientation to bedding.
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1588 Some authigenic pyrite crystals with developed whitish quartz strain fringes are encircled.
1589 Coin diameter is 11 mm; (f) Polished slab of finely laminated mudstone (lithofacies 4).
1590
1591 Fig. 6. Various types of clast-poor and clast-rich diamictites distinguished according to
1592 the sand/mud ratio (i.e., based on the textural classification of poorly sorted sediments from
1593 Moncrieff, 1989; modified by Hambrey, 1994): (a, b) Muddy diamictites (mi – mudstone
1594 intraclast, arrow – muscovite); (c, d) Intermediate diamictites; (e, f) Sandy diamictites (circle
1595 – plagioclase, arrows – pressure-solution grain contacts, dashed line – grain lineation). Note
1596 the poor sorting and various degree of roundness of the sand-sized grains which are almost
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1597 entirely represented by detrital quartz. All microphotographs are in cross-polarized light.
1599
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1600 Fig. 7. Detrital grains of mono- and polycrystalline quartz (a–f), quartz-rich rock
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1601 fragments (g–k), and feldspar (l) in the diamictites: (a) Grain with undulatory extinction
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1602 (arrow); (b) Three grains showing deformation lamellae; (c) Volcanic quartz with partly
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1603 preserved idiomorphic crystal habit, rounded edges and embayments; (d) Sedimentary quartz
1604 with abraded quartz overgrowths (arrows); (e, f) Polycrystalline grains with mostly elongated
1605
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individual crystals and sutured crystal boundaries (arrow – detrital zircon); (g) Quartzite
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1606 fragment showing evidence of pressure solution (concavo-convex to slightly serrated grain
1607 boundaries) in the parent rock; (h) Extrabasinal clast of very fine grained quartzose sandstone;
1608 (i) Lithic grain consisting of microcrystalline quartz (probably derived from chert); (j) Exotic
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1609 rock fragment of granitoid (plagioclase shown by arrow); (k) Extraclast of fine grained
1610 arkosic sandstone; (l) Plagioclase grains (arrows) with the upper one showing replacement by
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1611 clay minerals. All microphotographs except c (in plane-polarized light) are in cross-polarized
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1613
1614 Fig. 8. (a) Brownish mudstone extraclasts with thin oxidized dark rims greatly
1615 resembling rocks of the underlying Tseretsel Fm; (b) Associated extrabasinal (ex) and
1616 intrabasinal (in) clasts of mudstones showing different sizes, shapes, colours, and degree of
1617 roundness. The extraclast has oxidized rim and the intraclast is affected by mechanical
1618 compaction; (c) Extrabasinal mudstone clast with quartz veinlet inherited from the parent
1619 rock; (d–f) Intraclasts (arrows) derived from semi-consolidated mudstones (see also Figure
1620 9f) displaying good rounding, local effects of mechanical compaction, and absence of sharply
1621 outlined boundaries or oxidized rims; (g) Elongated rip-up clast of diamictite with distinct
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1622 boundaries; (h–j) Sediment aggregates (shown by dashed lines) having irregular shapes,
1623 diffuse boundaries, and higher amount of mud compared to the surrounding diamictite
1624 groundmass. These are interpreted as ‘till pellets’, i.e., frozen masses of ice-rafted debris. All
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1625 microphotographs are in plane-polarized light. Scale bar is 0.3 mm across.
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1626
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1627 Fig. 9. Depositional and deformational fabrics in the diamictites (a–e, i–k) and
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1628 mudstones (f-h): (a, b) Galaxy/turbate structure (dashed circles) outlined by circular
1629 alignment of quartz grains and matrix (lithofacies 1); (c) Rotational structure (arrows) around
1630
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large core grain (lithofacies 1); (d) Soft deformation of the matrix (arrows) below elongated
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1631 quartz grain with preserved steep dip of its long axis (lithofacies 3); (e) Syndepositionally
1632 disturbed matrix (arrows) below granule-sized detrital grain (lithofacies 3); (f, g)
1633 Homogeneous microfabrics consisting of low birefringent clay particles and randomly
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1634 dispersed silt grains dominated by quartz (lithofacies 2); (h) Finely laminated fabric
1635 (lithofacies 4) with quartz silt enrichment in the light coloured laminae. The latter are planar
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1636 to slightly undulating and only locally discontinuous without evidence of significant soft
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1637 deformation or erosion of the underlying laminae; (i) Parallel lamination defined by vertical
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1638 changes in the colour, grain size and sand/mud ratio (lithofacies 3); (j) Chamosite strain
1639 fringes (arrows) developed between detrital quartz grains (lithofacies 3); (k) Quartz strain
1640 fringes (arrows) grown around diagenetic pyrite crystal (lithofacies 3). All microphotographs
1641 except a, g and k (in cross-polarized light) are in plane-polarized light. Scale bar is 0.3 mm
1642 across.
1643
1644 Fig. 10. Schematic representation of the successive deglaciation phases characterized by
1646 dominantly structureless diamictites with lonestones (A), crudely laminated diamictites (B),
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1647 and finely laminated mudstones (C). Progressive retreat of the ice front (grounded or floating
1648 ice sheet) and related sea-level rise resulted in waning of mass-flow processes, decreasing
1649 supply of ice-rafted debris (IRD), increasing contribution from suspension settling, and
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1650 reduced sedimentation rates.
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1652 Fig. 11. A-CN-K diagram with plotted molar proportions of Al2O3, CaO*+Na2O and
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1653 K2O for the analyzed samples of diamictites (red circles) and mudstones (yellow circles).
1654 Data points outline a cluster that closely follows the ideal weathering trend (arrows) of felsic
1655
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rocks (Nesbitt and Young, 1984; Fedo et al., 1995), thus implying that the glaciomarine
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1656 sediments were derived from chemically weathered parent rocks having granodioritic to
1657 granitic composition. However, the compositional and some textural maturity of the
1658 diamictites indicates recycling of older sediments or sedimentary rocks (see text).
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1661
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1662 Fig. 12. (A) Present-day geographical distribution of Hirnantian glaciomarine rocks
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1663 deposited along the periphery of the North Gondwana platform. The occurrences in Morocco,
1664 (Le Heron et al., 2007, 2008), Algeria (Beuf et al., 1971; Paris et al., 2000), Portugal
1665 (Brenchley et al., 1991; Couto et al., 2013), Spain (Fortuin, 1984; Robardet and Doré, 1988;
1666 Bernárdez et al., 2006; Álvaro and Van Vliet-Lanoë, 2009; Gutiérez-Marco et al., 2010),
1667 Turkey (Monod et al., 2003; Ghienne et al., 2010) and Iran (Ghavidel-syooki et al., 2011)
1668 indicate sedimentation close to the maximum ice-front position of the Gondwana-based ice
1669 sheet (or satellite ice caps). The rest occurrences in France, Germany, Italy, Austria, Czech
1670 Republic, Serbia (see references in text) and Bulgaria comprise ice-distal deposits. (B)
1671 Palaeogeographic reconstruction of North Gondwana for the Hirnantian age (after Scotese,
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1672 2014) with inferred location of the Balkan Terrane and juxtaposition of the other peri-
1673 Gondwana terranes where dominantly glaciomarine sedimentation occurred (compiled from
1674 Monod et al., 2003; Yanev et al., 2006; Linnemann et al., 2011; Torsvik and Cocks, 2011;
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1675 Melchin et al., 2013; Stampfli et al., 2013; Sachanski et al., 2015, and references therein).
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1677 Table 1
1678 Major oxides (weight %) and calculated CIA values of the Hirnantian glaciomarine
1679 rocks.
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1680 d i a m i c t i t e s m u d s t o n e s*
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1681 _____________________________________________ __________________________
1682 __________________________________________________________________________________
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1683 ___________
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1684 SiO2 69.13 73.93 81.84 72.32 80.94 76.91 76.02 81.23 54.59 53.81
1686
1687
TiO2
0.64 0.67
0.70 0.47 0.53 0.52 0.57
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0.60 0.63 0.63 1.38 0.99
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1688 Al2O3 9.36 10.37 8.94 13.68 9.37 10.72 8.62 8.10 20.88 20.61
1690 Fe2O3 8.40 4.26 2.21 3.62 1.99 3.33 6.29 3.50 8.66 9.35
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1692 MnO 0.37 0.18 0.01 0.01 0.01 0.01 0.02 0.03 0.04 0.05
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1694 MgO 2.67 1.74 1.10 1.37 0.73 0.99 1.18 1.10 2.68 2.81
1696 CaO 1.70 1.72 0.59 0.60 0.67 0.64 0.73 0.78 0.89 0.65
1698 Na2O 0.68 1.35 0.83 1.47 0.12 0.84 1.00 0.93 1.82 0.65
1700 K2O 1.33 1.54 1.78 2.69 2.35 2.40 2.32 1.35 4.30 4.41
1702 P2O5 0.87 0.24 0.22 0.21 0.32 0.27 0.19 0.17 0.18 0.27
1704 L.O.I. 4.88 3.99 2.02 3.34 2.56 2.98 3.10 2.01 4.55 6.05
1706 Total 100.09 99.79 100.07 99.83 99.63 99.69 100.10 99.83 99.97 99.65
1708 CIA 72 63 70 69 76 70 63 67 70 76
1709 67 76
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1712 *The last sample is from finely laminated mudstones forming the top of Sirman Fm and the other
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1713 three mudstone samples are from non-laminated rocks in the lower part of the unit.
1714
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1715 Highlights
1716 Deposition occurred on the non-glaciated shelf of the North Gondwana platform
1717 Ice-intermediate and ice-distal deposits constitute a typical deglaciation sequence
1718 Provenance was related to sedimentary recycling of mature Cambro-Ordovician sands
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