MODEL SOLUTIONS TO IIT JEE 2010

Paper II
PART I

1 2 3 4 5 6
C A C B C D

7 8 9 10 11
7 2 2 6 3
12 13 14 15 16 17
B A D B C B

18 19
A – R, S, T A – P, S
B–T B – P, Q, R, T
C – P, Q C – P, Q, T
D–R D–P

Section I
5. NaOH / Br2
1. In (P), the activating OH group controls the H3C CO NH2
orientation of the product. In (Q), the more
activating OCH3 directs the orientation in
COCl
product formation. In (S), NO2 group enters
para to the benzene ring attached to the H3C NH2
activating Ogroup.
O
2. B2(10) 1s2 *1s2 2s2 *2s2  2p2x H3C NH C
B. O = 1 diamagnetic.

3. For FCC packing efficiency is 74.05%

6. S
4. Magnetic moment is 2.82 BM ie 2 unpaired
2
electrons (NiCl4) is an outer orbital complex O F
F
with two unpaired electrons in it. It is sp3 hybridization is sp3. There is one lone pair and
hybridized and paramagnetic. three bond pair.

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 13. (A)

Section II 14. (D)

ZxM 15. S1 has only one radial node

7. d=
a3 x NA Total number of radial nodes = n   1
4 x 108 ie for 2s orbital, n   1 = 2  0  1 = 1
a3 =
10 .5 x 6.022 x 10 23
= 6.8  1023 z2 32
16. E   = 2.25
a = 4  108 cm = 4  1010 m n2 22
Area of a face = a2
= 16  1020 m
2 17. Third orbital of Li2+ is having the same energy as
Number of atoms in each face = 2 that of the first orbit of H. Third orbital has 3s, 3p
2 x 10 12 and 3d orbitals, of which 3p has only one radial
Number of atoms in 1012 m2 = node.
16 x 10 20
ie  = 1
= 1.25  107.
8. F exhibits only 1 oxidation state whereas Na
exhibits only +1 oxidation state other than zero.
Section IV
V2
9. W s = 2.303 nRT log 18. Reaction of benzene diazonium chloride with
V1
phenol (A) is known as coupling reaction and it is
5.5
= 2.303  4  0.5 log = 4.8 Latm an example of aromatic electrophilic substitution.
0.5
(B) is pinacole  pinacolone rearrangement and it
W d = 4(2  0.5) + 1(3  2) + 0.5 (5.5  3)
involves carbocation intermediate. Reduction of
= 6 + 1 + 1.25 = 8.25
acetophenone with LiAIH4 involves addition of H
Wd
= 1.72  2 to the carbonyl group and we get a racemic
Ws
mixture of the product. (D) involves nucleophillic
substitution reaction.
10. H2SO4, H3PO3, H2CO3, H2S2O7, H2CrO4 and
H2SO3 are dibasic acids. 19.A (CH3)2 SiCl2 hydrolyses to form silicones HCl
is also formed.
11. It is a square planar complex of type Mabcd and B XeF4 produces HF, Xe, XeO3 and O2. HF
there are three geometrical isomers. reacts with glass.
C Cl2 forms HCl and HOCl. HOCl liberates O2

D VCl5 can be hydrolysed to form HCl, VO 2
Section III 3
12. an d VO 4

CH 3 CH 3
K2CO 3
H3C CH CHO CH 3 C CHO

H - CHO

(R)
CH3 CN CH 3
(i) H 3O+
CH3 C CH OH CH 3 C CH OH
(ii) heat
CH2OH CH 2 C O

(S) O

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 PART II

20 21 22 23 24 25
A C B D B B

26 27 28 29 30
5 1 4 3 3
31 32 33 34 35 36
C B B D C A

37 38
A–q A–t
B–p B – p,r
C – p, s, t C – q, r, s, t
D–q D–r

Section I A receiving correctly  A; A receiving wrongly 

r A;
20.  from p(1, 2, 1) to the plane is
1 4  2   Similarly B and B
 5
3 Green signal received by B
2
(5 + ) = 25  9  
= P(GAB) + P GA B + P RAB + P RA B    
2
25 +  + 10 = 225  Required probability
2 + 10  200 = 0
=
PGAB  P GA B  
2 + 20  10  200 = 0   
PGAB  P GA B  P RAB  P RA B   
( + 20)  10 ( + 20) = 0
=
 = 10 2 2
 4  3   4  1 
      
P(1, 2, 1)  5  4   5  4 
2 2
 5  3   4  1   1  3  1  1  1  3 
               
 4  4   5  4   5  4  4  5  4  4 
(plane) 40 20
= 
x + 2y  2z =10 46 23
Equations of the perpendicular line:
x 1 y  2 z 1 22.
 = k
1 2 2 D C
(k + 1, 2k  2, 2k + 1)
The above point lies on the plane
 i  2 j  2k
k + 1 + 4k  4  2 (2k + 1) = 10
9k = 15 
5 
k=
3 A 2r  10 j  11k B
 8 4 7  2  20  22
Point is  , ,  cos =
3 3 3  225 9
40 8
= 
21. Events are denoted as below: 45 9
Green signal  G; Red signal  R; cos( + ) = 0
cos cos = sin sin
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 8 11 2
tan = cot =
17 ie  a  n  1d  990
1
17
cos =
9
11 a2 + 2ad  n  1 + d  n  12  990
2

2 2
11a + 2ad 55 + d  5  11  21 = 990
2 2
23. Ar = Cr
10 a + 10ad + 5  21d = 90
2
B10 = 20C10 7d + 30d + 27 = 0
C10 = 30C10 11
 d = 2,
10 7
 10 Cr 20 C10 20 Cr 30 C10 10 Cr  Since d <
3
we get d = 2
r 1 2
10 10 a,  911
 10 Cr 
2
20 10
Cr 20 Cr 30 C10  5
 C10  11
r 1 1
(1 + x)10 = 10C0 + 10C1x + 10C2x2 +  + 10C10x10
27. ln gx  = f(x)
(1 + x)20 = 20C20 + 20C19x + 20C18x2 +  + 20C0x20
10 Differentiating both sides with respect to x,
10
 Cr 20 Cr  coeffient of x20 in (1 + x)10  g' ( x )
= f’(x)
r 1 gx 
20
(1 + x)  1 g’(x) = 0 at x = 2009, 2010, 2011
20 30
= Coeffient of x in (1 + x)  1 g’(x) changes sign from positive to negative as x
30 30
= C20 = C10  1 crosses the point 2009
10 Number of points in R at which g(x) has total
 10 Cr   
2 20! 20
 1 = C10  1
10!  10! maximum is 1
r 1
Substituting in (1)
28. |Adj A| = |A|2
Required num
= 20C10  (30C10  1)  30C10 {20C10}
|A| = (2k  1) (1 + 4k2)  2 k  2 k  4k k 
= 30C10   20C10 2
+ k (4 k k + 2 k )
= C10  B10 8
= (2k  1) (1 + 4k2) + 8k(2k + 1)
24. Let g(x) = f-1(x)  g  f(x) = x |A| = 2k + 1 + 8k3  4k2 + 16k2 + 8k
Differentiating  g’(f(x)) + f’(x) = 1 = 8k3 + 12k2 + 6k + 1 = (2k + 1)3
1 Obviously |B| = 0
 g' f ( x ) 
f ' (x ) ( B is skew symmetric matrix of odd order)
1  |A|2 = 106  (2k + 1)6 = 106
g’(2) = (since 2 = f(x)  x = 0)
f ( 0) (2k + 1) = 10
1 9
 g’(2) = . 2k = 9  k =
3 2
[k] = 4
25. There are 24 subjects. S and  are disjoint
29.
{1} is disjoint with all sets formed from 2, 3 and 4
and with . No. of disjoint sets with {1} = a
3
2 + 1 = 9. Disjoint pairs with singleton sets = 2
4  9  6 = 30
Disjoint pairs with ‘only 2 elements’ sets = 3 2
Total no. of disjoint pairs = 1 + 30 + 3 = 34 b

Section II

26. Given 9k2 + 9k = 2 9k 1

ie {9n} in an A. P 2 cos  = a; 2 cos  = b
11
2 cos  + 2 cos  = a + b = 3 1
given  ax2  990
1
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  cos  3 1 3 1 = clearly t lies in the interval
cos    
2K K 2 2 2 2
33. f’(x) = 12x + 6x + 2
= cos 30 + cos 60 = 2(6x2 + 3x + 1)
  1 3
 K 3 t   ,  Choice B
2K 6 2 4
[K] = 3
x2 y2
30.  = 15 3 34. Equation of any tangent on  1
9 4
2 2 2
c = a + b – 2ab cosC x y
i.e cos + sin = 1;
= 136 – 120 cosC 3 2
 30 3 It passes through P(3, 4)
r  i.e. cos + 2 sin = 1
s 16  c
1 1  t2 4t
15 3  ab sin C  30 sin C i.e. 2
 1
2 1 t 1  t2
2 2
 C = 120 (since C is obtuse) i.e. 1  t + 4t = 1 + t  4t = 2t
 c = 40  t = 0 or 2
when t = 0, A is (3, 0)
r= 3  r2  3
 9 8 
t = 2 A is  , 
 5 5
Section III
 9 8 
35. P(3, 4) A(3, 0) B  , 
31. f(x) = 1 + 2x + 3x2 + 4x3  5 5
f’(x) = 2 + 6x + 12x2
Equation of AP in n = 3 and equation of BP is
> 0 for all real x
x  2y + 5 = 0
f(x) is monatomic increasing f(0) > 0
f(x) = 0 has no positive roots  Equation of altitude through B is
f(1) = 1  2 + 3  4 < 0 8
y = (1) and
Real root lies between 0 and (1) 5
 1  1 3 4 equation of altitude through A is
f  = 1  +  2x + y  6 = 0  (2)
4
  2 16 64
Solving (1) and (2) we get the orthocentre is
1 1  11 8 
=1  >0  , .
2 8
 5 5
 1 3 4
f   = 1  1 + 
 2 4 8 36. Equation of AB x + 3y  3 = 0
 3  3 39 4  27 P(3, 4)
f  = 1  + 
 4  2 16 64  (x  3)2 + (y  4)2 =
x  3y  32
 3 1  10
lies in the interval   ,  i.e. x2 + y2  6xy  54x  62y + 241 = 0
 4 2 

Section IV
32.
37.
(A). z  i z  z  i z

i.e. x  iy  ir  x  iy  ir where r  x 2  y 2
x  i ( y  r )  x  i (y  r )
2 2 2 2
i.e. x + (y  r) = x + (y + r)
1 0  ry = 0  y = 0 Im(z) = 0
1
(A)  (q)
2
t
2 3 4 t (B) z  4  z  4 = 10 represents an ellipse with
 f x dx = (x + x + x + x )
2a = 10 and 2ae = 8
0
2 3
= t +t +t + t4

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 4  x3 x3 3
–1  
(B) tan  1  x 2  9  = tan  4 
–1
e=
5
(B)  (p) 2
 x = 16  x =  4.
(B)  (p), (r)
1 1
(C) x + iy = 2 cos + 2i sin - cos + i sin
2 2
3 5 (C) a   b  4c  a2  4a.c
= cos   i sin 
2 2 0  b2  4b.c
17 2bc  ba
| z| =
2
 (3 – 2) b2 + 4c2 = a2 ------ (1)
(C)  (p), (s), (t)  
bc.ba 0 
2
4   b  a2 ----- (2)
(D) x = 0; y = 2i sin Solving (1) and (2),
(D)  (q) 4c 2
1+=
b2
38.
>–1
(A). As per the given conditions,
(C)  (q), (r), (s), (t)
(r1 + 2, –2r1 + 1, r1 – 1) is any point on the first
line

9nx
8 sin
(2r2 + , –r2 – 3, r2 + 1) is any point on the 2
3 (D). In =  x
second line 0 sin
2
1  In – In-2 = 0
Solving r1 = 3 and r2 =
3  I9 – I7 = 0 …….. etc.
 10 10 4   I9 = I1
 points are (5, –5, 2) and  , , 
 3 3 3 
2
 d2 = 6. the required integral =
 
 2  1 dx  4
(A)  (t) 0
(D)  (r)

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 PART III

39 40 41 42 43 44
C A D D B B

45 46 47 48 49
6 3 8 4 2
50 51 52 53 54 55
A C C D B C

56 57
A – p, r A – r, s, t
B – q, s, t B – q, r, s, t
C – p, r, t C – p, q
D – q, s D – q, r, s, t

Section I 43.
39.  Fdt  p  p ( p initial = 0)
   
2
2 3 1
p
K.E = ; Area = 6  1.5 = 4.5 = p
2 m
30 cm 10 cm
m = 2  K.E = 5.06 j = 2f
 2f = 30

40. q1 = q2 = .2R2 3010=20

These charges are located at CM of hemisphere,
R
(at a distane of ) from centre
2  20
R
 d = 2 = R
2
 u =+10
q1q2
F=
40d2 1 1 1
   v  6
2 2 4 2 2 v  10  15
 4 R  R
= 2

4 0R 0  +6
2 2 3  16 cm from mirror
 R

0 v 1 T T
44.  
4L  m m
4 3 
41. qE = 6rv = r g
3 Using data, v = 320, L = 0.8, T = 50,  = 0.5, m is
Solving, using given data, q = 8.0  1019 C determined as 0.01 kg

Section II
42. 20 VSD = 16 MSD  1 VSD = 0.8 MSD
 L.C = 1 MSD  1 VSD = 0.2 MSD 45.
= 0.2  1 mm = 0.2 mm R

C 8

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 1/ 3
 3 rT 
3 R =  
Sin C =  2 g 
5
1/ 3
3  3  5  10  4  0.11 
R = 8 tan C = 8  = 6 cm =  
4  2  1000  10 
 
= 2.02  103 m
1 1 1 2
46. Using formula    = 2.0  103 m
v u f R
u1 = 50 m, u2 = 25 m 2
25 m
52. Energy = 4R T
 speed of object = = 3 kmph = 4  (2.0  103)  0.11
30 s
 5.4  106 J

dN
47. = N = N0et nh
dt 53. L = (Bohr’s postulate)
2
take loge : y = c  t  |slope| = 
n2h2
1 n2  L2 = --- (i)
|slope| is  t1/2 = = n4 4 2
2 1
2
2 But L = 2 KE for rotating body
4.16 years n2h2
=3  (i)  2 KE =
t 1/ 2 4 2
( 3 n4 = 6 n2  6  0.693 = 4.16) n2h2
 KE =
 After 3 half lives factor is p = 8 8 2 

48. Adiabat: TV  1 = constant,   1 = 0.4 h2

.T1V1
0.4 54. KE1 =
T1V10.4 =   = 320.4 = 322/5 8 2
0.4
32
22 h2 4h2
= 22 = 4 KE2 = 
8 2  8 2gI

49. V = V0 (1  et/)  et/ = 0.6 4h2 h2

KE = KE2  KE1 = 2

( V = 6, V0 = 10) 8  8 2 

 et/ =
10 5 t
  = n5  n3 = 0.5 3h2
= ---- (i)
6 3  8 2
 t = 0.5   But KE = h = hf ---- (ii)
 = Req Ceq = 4  t = 2 s
3h2
From (i) & (ii) = hf
8 2

Section III 3h 3 2  10 34

  CM = 2
 2

8 f 8 4
 1011

50. 2
= 0.1875  1045 kg m
2
= 1.875  1046 kg m

55.
d

C x O

  
12 amu CM 16 amu
r
16 d 4d
Vertical force, F = 2r T x= 
12  16 7
12 d 3d
4 y= 
51. 2r T = R3g 12  16 7
3
2  3 rT 6 rT 3 rT  CM = 12x + 16y2
2

 R3 =  
4 g 4 g 2 g
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 2 2 q not possible (V1 = 0, not proportional to )
 4d  3d 
= 12   16  r possible
 7   7  s possible
192 d2 144 d2 336 d2 t possible
=   amu m2  A  r, s, t
49 49 49
336 d2 5 B.   0, V2 > V1
  10 27 kg m
2
=
49 3 (p not possible for reasons given in (A)
But CM = 1.875  1046 from (54) above above)
q possible ( V2  0, V1 = 0, V2 > V1)
336 d2 5 If R > XL, V2 > V1 for (r)
 1.875  1046 =   10 27
49 3 XL = L = 2fL = 2  50  6  103 = 1.88 
1/ 2 R = 2 ,  R > XL  (r) is correct.
 1.875  3 10  46  49 
2
d =    If XC > XL, V2 > V1 for (s)
 5 336  10 27  1
XC = 6
= 1061 
 d = 1.28  1010 m  1.3  1010 m 3  10  2  50
XC > XL  (s) is correct.
If XC > R, V2 > V1 for (t)
Section IV XC > 1061  > 1000   t correct.

56. A. 1 < 2  (B)  q, r, s, t

Refracted ray bends towards normal.
 p, r correct. C. V1 = 0, V2 = V
 p is correct (no correct, V1 = 0, V2 = V)
B. 1 > 2  q is correct (XL = 0  V1 = 0, V2 = V)
Refracted ray bends away from normal Not possible for r, s, t
 q, s, t correct.
 (C)  p, q
C. 2 = 3
No bending of emergent ray D.   0, V2  
 p, r, t correct. Not possible in (p) (  = 0)
In (q), V1 = 0, V2 = R, possible
D. 2 > 3 Possible in r, s and t
Emergent ray bends away from normal.
 q, s correct.  (D)  q, r, s, t

57. A.   0, V1  
p not possible (C blocks DC)

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