Professional Documents
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ThyssenKrupp
A company
of ThyssenKrupp
Technologies
Uhde
2 Table of contents
Page
1. Company profile 3
2. Overview 5
5. Process highlights 9
6. Process description
of the new Evonik-Uhde HPPO technology 10
6.1 Reaction 10
6.2 Propene recycling 10
6.3 PO purification 10
6.4 Methanol processing 11
6.5 Purification of chemical-grade propene 11
The new hydrogen peroxide to propylene oxide (HPPO) process using propene and
hydrogen peroxide as the feedstocks is the result of co-operation between Evonik
Industries and Uhde.
Figure 1:
Main applications of PO/world
consumption of PO in percent
Propylene oxide
Main applications
65 % Polyether polyols
polyurethanes (PUR), flexible and rigid foam
15 % Others
3. Fundamentals of propylene oxide 7
PO is a bulk chemical primarily used for the Since 2008 the world’s first commercial scale
production of polyurethane precursors namely plant for the production of propylene oxide
based on the innovative HPPO process has
polyether polyols, as well as for propylene glycol been in successful operation
and glycol ethers. Polyurethanes are used in a
wide range of applications, including automobile
components, furniture upholstery, thermal
insulation, coating materials, sports shoes and
sporting goods.
The new Evonik-Uhde HPPO technology for the system which operates at elevated pressure
production of propylene oxide via H2O2 is shown and moderate temperature. The special design
in figure 2. The highly exothermic process takes combines an intense heat transfer with an
place under relatively mild process conditions. almost ideal plug-flow characteristic, resulting in
a high PO selectivity.
In the reaction unit, the catalytic epoxidation of
propene is carried out in the presence of a titanium The quality and characteristics of the hydrogen
silicalite catalyst using hydrogen peroxide (H2O2) peroxide have a substantial influence on the
in methanol as the solvent. The focal point of process parameters. Evonik has developed a
the development was the epoxidation reactor for grade of hydrogen peroxide specifically designed
the synthesis of PO using a fixed-bed reaction for use as an oxidising agent in the epoxidation
Figure 2:
New Evonik-Uhde HPPO technology of propene.
Decompressing/
Propene recyling
PO Methanol
purification processing
PO Waste water
5. Process highlights 9
Environment-friendly production:
• Totally closed solvent and feedstock cycles
• The waste water, which contains small
amounts of by-products, can be sent to a
biological or a thermal treatment unit
• All off-gas streams from the PO plant can
be treated using state-of-the-art technologies.
If chemical-grade propene is used, the
surplus propane can be used as an additional
energy source.
10 6. Process description
of the new Evonik-Uhde HPPO technology
Reaction section CW
CW
Flash system
Product mixture
Recycle propene to
Steam reaction section
Product mixture
11