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Modern Applications of Nanotechnology in Textiles

A.P.S.Sawhney1 and B. Condon


Abstract Nanotechnology (NT) deals with mate- Agriculture Research Service, United States Department
rials ito 100 nm in length. At the National Nanote- ofAgriculture Southern Regional Research Center New
chnology Initiative (NNI), NT is defined as the Orleans, LA 70124, USA
understanding, manipulation, and control of mat-
ter at the above-stated length, such that the physi- K.V. Singh
cal, chemical, and biological properties of the Mechanical and Manufacturing Engineering Department,
materials (individual atoms, molecules, and bulk Miami University, Oxford OH 45056, USA
matter) can be engineered, synthesized, and altered
to develop the next generation of improved materi- S.S. Pang and G. Li
als, devices, structures, and systems. NT at the Mechanical Engineering Department, Louisiana State
molecular level can be used to develop desired tex- University, Baton Rouge, LA 70803, USA
tile characteristics, such as high tensile strength,
unique surface structure, soft hand, durability, water
David Hui
repellency, fire retardancy, antimicrobial properties, Mechanical Engineering Department University of New
and the like. Indeed, advances in NT have created
Orleans, New Orleans, LA 70148, USA
enormous opportunities and challenges for the tex-
tile industry, including the cotton industry. The
focus of this paper is to summarize recent applica-
tions of NT as they relate to textile fibers, yarns, and
fabrics.

Key words nanotechnology, fibers, yarns, tex-


tiles, technical fabrics

Although the term nanotechnology (NT) is relatively new, in the decades following, there have been numerous
the underlying technology is old, because the term "sub- advances in NT and its many applications in the textile
micro" was used in the production of extremely small parti- industry. Because of its limitless potential in consumer-ori-
cles of polymers and copolymers. Today, the technology ented applications, the textile industry is one of the pre-
that deals with the science and engineering of materials at mier beneficiaries of advances in NT. Being one of the
the dimensions of roughly ito 100 nm (1 billion nm = i m) largest consumer-supported industries, with significant
in length is called NT. At the National Nanotechnology Ini- impact on a nation's economy, advances in applications of
tiative (NNI), NT is defined as the understanding, manipu- NT to improve textile properties offer obvious, high eco-
lation, and control of matter at the above stated length nomic potential for the industry's growth.
scale, such that the physical, chemical, and biological prop- It was demonstrated in recent years that NT can be used
erties of materials (individual atoms, molecules, and bulk to enhance textile attributes, such as fabric softness, durabil-
matter) can be engineered, synthesized, or altered to ity, and breathability, water repellency, fire retardancy, anti-
develop the next generations of improved materials, devices, microbial properties, and the like in fibers, yarns, and
structures, and systems [1]. Although, there is no clear fabrics. In addition to the millions of dollars invested by
indication of when and how the term evolved, Professor the private sector, it is estimated that for the year 2003,
Richard Feynman, almost 50 years ago, in a lecture titled worldwide government funding for research and develop-
"There's Plenty of Room at the Bottom," [21 demonstrated
that matter at nanometer dimensions can be exploited to
attain considerably improved material properties. Indeed, Corresponding author: e-mail: ap.singh@ars.usda.gov

Textile Research Journal Vol 78(8) 731-739 DOt 10.1177/0040517508091066 www.trj.sagepubcom © 2008 SAGE Publications
Figures 1 2 appear in color online http//trj.sagepubcom Los Angeles, London, New Delhi and Singapore
IY 732 Textile Research Journal 78(8)

( Macro-technolog ." \hcro-technolog


\aeogs
101 10-110 10-4lO 106 10 108 iO 10-10m
Figure 1 Fiber size and associated
manufacturing/processing tech-
Ordinary Fibers Fine denier Fibers Micro Fibers Nano Fibers nologies.
Fiber diameters

ment in NT was about $3 billion [ 3 ] It is expected that in through sub-micrometer diameter spinnerets to afford fib-
the next decade, enhancement of textile materials through ers on a grounded collector plate subjected to high poten-
advances in NT may evolve into a multi-billion dollar tial difference between the spinnerets and the plate. The
industry with associated economic and ecologic benefits to process is an established technique to generate fibers of
the textile consumers and society at large [4]. In this paper, extremely small diameters and enhanced properties [7-9].
we compile and summarize modern developments and Further enhancement of fiber strength and conductivity is
applications of NT of textile fibers, yarns, and fabrics, and achieved with heat treatment. The resulting nano-fibers
provide references that relate information on research find applications such as bullet-proof vests and electro-
groups and industries that are actively involved in the pro- magnetic wave-tolerant fabrics. However, it should be
duction, preparation, and finishing of improved textile fib- mentioned that mechanical properties of textiles rein-
ers, yarns and fabrics. forced by CNT do not necessarily meet the very high levels
of properties of constituent nano-fibers. This is due to the
fact that the transverse surface effects of the reinforced
Improvements in Fiber/Yarn textiles may not always proportionately contribute to the
latter's mechanical properties, which traditionally are
Manufacturing by using determined in their linear direction. The growing applica-
tions of nanotechnologies in special-purpose, textile, and
Nanotechnology related composites certainly have advantages of transverse
surface characteristics of reinforced materials.
The properties and performance of textile fibers are essen- It was discovered that unique composite fibers were
tial to fabric manufacturing and utilization. While it is well- produced from synthetic nano-fibers obtained through an
known that fabrics made of cotton fibers provide desirable advanced electro-spinning process, such as the coagula-
properties, such as high absorbency, breathability, and tion-based carbon-nano-tube spinning method [10,11].
softness for wear and comfort, expanded utility of cotton These composite fibers afford electronic textiles for super
fabrics in certain classical and especially non-classical capacitors. During electro-spinning process, nano-yarns,
applications is somewhat limited due to the fiber's rela- comprised of Multi-Walled CNT (MWCNT) that consist of
tively low strength, less-than-satisfactory durability, easy several (usually 7 to 20) concentric cylinders of Single-
creasing, easy soiling, and flammability. On the other hand, Walled CNT, can be produced by simultaneous reduction
fabrics made with synthetic fibers generally are strong, of fiber diameter and increase in twist (up to 1000 times) in
crease resistant, antimicrobial, and dirt resistant. However, the electro-spinning process. These highly twisted yarns
they certainly lack the comfort properties of cotton fabrics. facilitate extra strength, toughness, energy-damping capa-
NT induces enticement to develop de novo fibers with the bility, etc., and thus can be deployed to produce electronic
advantages of both cotton and synthetics. textiles for supporting multi-functionalities, such as capa-
A wide range of fiber size or thickness can be utilized in bility for actuation, energy storage capacity, radio or
textile processing (Figure 1). microwave absorption, electrostatic discharge protection,
Ordinary and fine-denier textile fibers range from 1 to textile heating, or wiring for electronic devices [12]. It is
100 tLm in diameter and are produced by established dry- clear that the current developments in nano-fibers and
wet-dry, jet melt spinning through spinnerets 1-100 A m in nano-yarns will be utilized in producing the next genera-
diameter. Nano-fibers of diameters in the nanometer tion textiles, which would be capable of providing radio or
range are mostly manufactured by electro-spinning proc- microwave absorption, electrostatic discharge protection,
ess, although there are also other methods. Carbon nano- textile heating, or wiring for electronic devices of the
tubes [ 5 ] (CNT) provide fibers of ultra-high strength and twenty-first century.
performance. It was shown that super-aligned arrays of By changing the surface structures of synthetic fibers,
CNT provide nano-yarns [6] that exhibit Young's modulus several diverse fiber functionalities can be obtained for
in the TPa range, tensile strength equaled 200 GPa, elastic profitable exploitation of functional fabrics in special
strain up to 5%, and breaking strain of 20%. In electro- applications. One of the possibilities to develop desired
spinning, a charged polymer melt or solution is extruded functionality is by embossing the surface of synthetic fibers
Modern Applications of Nanotechnotogy in Textiles ARS. Sawhney et a. 733

with nano-structures [13]. Integration of nano-sized antimi- been studied [33]. Through optimal orientation and crys-
crobial particles into textile fibers leads to the development tallization of nano-fibers, excellent properties of composite
of superior wound dressings. Similarly, by incorporating fibers can be achieved and successfully used for the micro-
ceramic nano-particles into a spinning solution, polyimidoa- filtration applications in the medical field [34]. In another
mide fibers can be produced in which Si0 2 nano-particles recent study, it has been shown that by melt extruding, a
are present. Such a "nano-treatment" can also produce anti- range of "nano-additives yarns" of exceptional properties
static polyacrylonitrile (PAN) fibers consisting of electrically can be produced [35]. Obviously, such a wide range of
conductive channels, which not only possess antistatic prop- advances towards the enhancement mechanical properties,
erties but also have good mechanical properties [14,15]. surface textures, and fabrication processes of fibers/yarns is
Chemical modifications of synthetic fibers using nano-par- expected to lead to the development of the next generation
tides can enhance the fibers' porosity and absorption prop- of woven and non-woven fabrics for thus far unforeseen
erties, which are useful in producing thermal-resistant and applications.
flame-resistant fabrics. Desirable thermal properties as
well as enhanced fiber tenacity can also be obtained by mod-
ifying the surface of the fibers with other (nano-) matters,
such as diamine (diaminodiphenyl methane), montmorillo-
Progress Towards the Fabric
nite, and silica nano-particles, etc. [16-20]. Specific func- Finishing by using Nanotechnotogy
tionality in fibers can also be achieved by another leading
chemical oxidative deposition technology, which deals with Finishing of fabrics made of natural and synthetic fibers to
the deposition of Conducting Electroactive Polymers (CEP), achieve desirable hand, surface texture, color, and other
that is, polyaniline, polypyrrole, polythiophene, and their special aesthetic and functional properties, has been a pri-
derivatives (in nano-form) onto different kinds of synthetic mary focus in textile manufacturing. In the last decade, the
fibers, resulting in special composite fibers with high ten- advent of NT has spurred significant developments and
sile strength and good thermal stability [21, 22]. Surface innovations in this field of textile technology. Fabric finish-
polymerization of CEP (by Graft copolymerization) of pol- ing has taken new routes and demonstrated a great poten-
ymer fibers has a potential to increase the fibers' conductiv- tial for significant improvements by applications of NT.
ity almost 10 times by decreasing their electrical resistivity The developments in the areas of surface engineering and
[23-25]. These so-called coated polymeric composite fibers fabric finishing have been highlighted in several papers
can be used in microwave attenuation, EMI shielding, and [36-39]. There are many ways in which the surface proper-
dissipation of static electric charge. They can also be useful ties of a fabric can be manipulated and enhanced, by
in developing fabrics intended for military applications, for implementing appropriate surface finishing, coating, and/
example., camouflage, stealth protection, and the like or altering techniques, using nanotechnology. A few repre-
[26,27]. It may be mentioned that the polymer deposition sentative applications of fabric finishing using NT are sche-
techniques can be further improved to obtain many other matically displayed in Figure 2.
desirable characteristics of CEP coated textiles. NT provides plenty of efficient tools and techniques to
The development of nano-composites usually contain- produce desirable fabric attributes, mainly by engineering
ing 2 to 5% of nano-fibers has been extensively reviewed by modifications of the fabric surface. For example, the pre-
Mondal [28]. In his paper, the basic properties, fabrication vention of fluid wetting towards the development of water-
process, and some applications of nano-fibers or nano- or stain-resistant fabrics has always been of great concern
tubes are covered. Some "nano-mechanical" properties of in textile manufacturing. The basic principles and theoreti-
transverse sections of mature and immature cotton fibers cal background of "fluid-fabric" surface interaction are
have also been investigated and the behavior, properties, well described in a recent manuscript by Schrauth et al.
and potential applications of these textile micro structures [40]. They have demonstrated that by altering the micro-
have been summarized [29-30]. and nano-scale surface features on a fabric surface, a more
By uniformly dispersing aligned nano-tubes in the poly- robust control of wetting behavior can be attained. They
mer matrix, some novel CNT reinforced polymer compos- also showed that such an alteration in the fabric's surface
ite materials have been developed, which can be used for properties is capable of exhibiting the "Lotus-Effect,"
developing multifunctional textiles having superior which demonstrates the natural hydrophobic behavior of a
strength, toughness, lightweight, and high electrical con- leaf surface. This sort of surface engineering, which is
ductivity [31]. By using melt-spinning process, polypropylene/ capable of replicating hydrophobic behavior, can be uti-
nano-carbon fiber composites with significantly enhanced lized in developing special chemical finishes for producing
modulus, compressive strength, and dispersion properties water-and/or stain- resistant fabrics.
can be produced [32]. The morphology, crystallinity, and In recent years, several attempts have been made by
several mechanical properties of non-woven mats contain- researchers and industries to utilize similar concepts of
ing nano-structured poly-capro-lactone (PCL) have also surface-engineered modifications through NT to develop
734 Textile Research Journal 78(8)

UV rays and radiation


Coating of fabrics with
FAI nano-beads used for carrying
desirable molecules

Breathability and
temperature control "Z
0
0 c 0

Fluid
Stain
droplet

Cotton fibers wrapping


core

Nano-structures to
prevent wetting Figure 2 Fabric finishing for enhan-
Synthetic
due to fluids ced properties and performance.
fiber core

certain high-performance fabrics. Most successful develop- Nano Care technology is offered to produce wrinkle-
ments in this regard can be attributed to a US-based com- free/resistant and shrink-proof fabrics made of cellulosic
pany [41], Nano-Tex TM. By using NT, they have developed fibers, such as cotton. Nano Diy technology, on the other
several fabric treatments to achieve certain enhanced hand, provides hydrophilic finishing to synthetic fabrics.
fabric attributes, such as superior durability, softness, This nano-based finish allows the fabric to whisk away the
tear strength, abrasion resistance, and durable-press! contact body's moisture/sweat, which quickly evaporates to
wrinkle-resistance. In fact, this company is a pioneer in the provide comfort to the wearer. This company has also
development of several fabric coatings and treatments, developed a technology in which Nanobeads are used into
which are capable of providing the above-stated high-per- the textile substrate for carrying bioactive or anti-biological
formance fabric attributes. For example, their trademark agents, drugs, pharmaceuticals, sun blocks, and textile dyes,
Nano-Pel technology for stain-rcsistance and oil-repellency which subsequently can provide desired high performance
treatments utilizes the concept of surface engineering and attributes and functionalitics to the treated fabrics [50].
develops hydrophobic fabric surfaces that are capable of Recently, Beringer and Hofer have demonstrated that
repelling liquids and resisting stains, while complementing by combining the nano-particles of hydroxylapatite, Ti02,
the other desirable fabric attributes, such as breathability, ZnO and Fe 7 03 with other organic and inorganic sub-
softness, and comfort. Basically, this sort of surface treat- stances, the surfaces of the textile fabrics can be apprecia-
ment attaches small nano-whiskers, which are nano-struc- bly modified to achieve considerably greater abrasion
tures, to provide roughness to the fabric surface so that resistance, water repellency, ultraviolet (UV) resistance, and
fluid-surface interaction and consequently fluid penetra- electromagnetic- and infrared-protection properties [51].
tion can be avoided and so the treated fabric has perma- For example, the titanium-dioxide nano-particles have
nent water- and stain-resistant properties. The same been utilized for UV protection. Similarly, by using nano-
company has also developed several other fabric treat- sized silicon dioxide as an additive in coating materials, sig-
ments and trademarked technologies [42-49]. Nano Touch nificant improvements in the strength and flame-resistance
is a trademark for one of their nanotechnologies for treat- of textile fabrics can be achieved [52,53]. For cotton fab-
ing a 'core-wrap" type of fabric. In a core-warp yarn or rics, wrinkle resistance can be developed by using the
fabric, a core of usually synthetic fibers is wrapped with nano-engineered cross-linking agents during the fabric fin-
natural fibers, such as cotton. The (nano)-treated core ishing process. Besides the wrinkle resistance, such finish-
component of a core-wrap bicomponent fabric provides ing is also capable of eliminating toxic agents, while
high strength, permanent anti-static behavior, and durabil- maintaining the desired comfort properties of cotton [54].
ity, while the traditionally-treated wrap component of the It has also been shown that a wide range of so-called func-
fabric provides desirable softness, comfort, and aesthetic tional finishing of fabrics can be obtained by using a micro-
characteristics. encapsulation technique, which is widely used in the phar-
Modern Applications of Nanotechnology in Textiles A.P.S. Sawhney et at. 735

Active and'\
casual wear Military
Jackets, dresses & combat
outfit
gloves,
caps etc.
Camouflage
and tents
Electronic
Awr I

U I
in textiles ;ear
ii
Climate
Control
garments
'9.

O
Under
Medical garments
Fabrics,
Tissue
ngineering fabrics and
Is
Figure 3 Some representative appli-
cations of NT in textiles.
D

maceutical industries. This technology enables to carry out nylon, continue to be the most widely-used fibers for
several liquid or solid agents (fragrant, flame-retardant apparel manufacturing. Synthetic fibers are mostly suitable
agents, etc.) that are encapsulated in phase-changing mate- for domestic and industrial applications, such as carpets,
rials acting as binders (e.g. wax). This technology, for tents, tires, ropes, belts, cleaning cloths, and medical prod-
example, can be used to develop odor-eliminating finishes ucts. Natural and synthetic fibers generally have different
of fabrics. Fire-retardant and anti-microbial agents can characteristics, which make them ideally suitable mainly
also be microencapsulated for advanced fabric finishing for apparel. Depending on the end-use application, some
[55,56]. These advances in the application of NT are of those characteristics may be good, while the others may
expected to further improve fabric finishing for the next not be as good to contribute to the desired performance of
generation of fabrics. the end product. As stated previously, NT brings the possi-
bility of combining the merits of natural and synthetic fib-
ers, such that advanced fabrics that complement the
A Few Representative Textile desirable attributes of each constituent fiber can be pro-
duced. Towards that end, companies such as Nano-Tex
Products Based on Nanotechnology have already made significant progress in the development
of improved apparel. Their fabric finishing products are
Within the last decade, NT-based progress in textile fibers, now widely available to the textile apparel industries for
yarns, and fabric-finishing have led to the development of clothing, active wear, casual and business attire, uniforms,
several new and improved textile products (Figure 3). etc. These novel products are now available to the consum-
Numerous references in the literatures are now available, ers through the worldwide retailers, such as Old Navy,
which highlight the various applications of NT for the tex- GAP, Eddie Bauer, and LL. Bean.
tile industries [57-66]. Throughout history, the textiles Recently, a Swiss company Scholler [67] has also devel-
have been used worldwide in a very wide range of con- oped a nano-based technology to produce a new line of
sumer applications. Natural fibers, such as cotton, silk, and brand name fabrics, such as "Soft-Shells," functional
wool, along with synthetic fibers, such as polyester and stretch multi-layer fabrics. The fabrics and the garments
736 Textile Research Journal 78(8)

made there from are capable of dynamic climate control, sensitive (for different climate controls), and embeddable
which provide optimal balance of comfort, air permeabil- with multipurpose micro-/nano-sensors [75]. In addition,
ity, and wind and water resistance, through their "soft several antimicrobial textile treatments are currently being
inner layer" and "tough and durable outer layer." The produced that can play very significant roles in protection
technology is being used in the manufacture of apparel for against a wide range of physical/chemical/biological threats
extreme cold weather conditions and for out-door, moun- [76]. To produce battle-ready smart textiles, several dispa-
tain sports, ski sports, and various other sportswear appli- rate technologies, such as micro capsulation, biotechnolo-
cations. The company has also developed an innovative gies, and information technology, are being utilized [77].
Nano-Sphere' finishing treatment of the fabrics, which An interesting review, which specifically focuses on poten-
provides a self-cleaning feature and resists stains. The tial developments of textiles that would carry and/or bear
company's Schoeller®-PCM technology offers moisture various bioactive compounds, is presented by Breteler et
management features and provides comfort and protec- al. [78]. Advanced nano-fibers of nano-sized particles are
tion at the same time [68,69]. The combination of Nano- also being developed for efficient applications in wound
Sphere" finish and Soft-Shell technology is capable of dressings [79,80]. Quantum Group Inc., in its recently pat-
producing fabrics/garments that repel rain and snow. Sev- ented technology, has shown that the combination of
eral fabric and garment manufacturing companies have "nano-fibrils" (0.4-1 nm), produced by electro-spinning
utilized these advanced technologies in developing a wide processes with reinforcing, strong fibers, or filaments) can
range of special-purpose apparel. For example, ski-wear be used to produce yarns as well as non-woven fabrics that
and jackets with 3XDRY® Moisture Management System can be utilized in tissue engineering [81,82]. Otsuka
by Allsport, extreme performance jacket and pants by Kagaku has developed new electro-conductive (nano-)fib-
Mammut Mountaineering, cliff pants and jackets by Millet, ers that can be used for protection against radiation emitted
and abrasion- and tear-proof footwear that is light, breath- by electronics. Several other technologies for producing fab-
able, and air permeable is offered by Schoeller®-Kepro- rics to shield from radiation are also being investigated [83].
tec® (material provided by Springboost), and gloves by It may be noted that the above-mentioned nano-based
Reusch and Swany [70]. Similar lines of products have also advances affect the advances of not only military applica-
been designed by several other companies. For example, tions but also the civilian applications, such as those in the
Germany's Franz-Ziener has introduced ski jackets, which biomedical fields. Development of nano-functional fibers
feature Nano-Tex coatings to make them windproof, water- has been directed to the manufacturing of hygienic fabrics
proof, and breathable 1711. With the help of advanced fin- for undergarments. Several companies are using these new
ishing products, UV protection can also be obtained, in fibers to develop odor-free clothing, such as socks, stock-
addition to the good durability, good air permeability, and ings, and undergarments, etc. For example, socks contain-
soft hand feel [72]. Incidentally, the technology of incorpo- ing nano-particles of silver minimize foot odor [84]. Nano-
rating NT in textiles is not only limited to the United States Tex is developing a new technology known as "Nano-
and Europe. In fact, it is now evolving worldwide. The Fresh," which is intended to absorb sweat, dry quickly, and
growth of NT in Asia is also significant. It is expected that trap odor. Several other high-tech fabrics are being devel-
within a few years, thousands of companies worldwide oped that will remove sweat, repel stains, provide a mas-
will be engaged in the production of CNT and nano-fibers sage, and even provide a sensational fragrance. Hanes has
developed some anti-cellulite shaper wear fabrics, which
Significant advances are envisioned towards the devel- utilize the micro-encapsulation techniques to modify the
opment of military and combat uniforms and apparel, appearance of cellulite.
using NT. One of the largest and perhaps unique research Nano-based textile composite materials comprise another
centers in the world, whose main focus is on the develop- promising sector, which is leading the developments of
ment of next generation of materials for soldiers, is the new materials for engineering applications. Strong graph-
Institute for Soldier Nanotechnologies (ISN) [ 7 ] . This ite nano-fibers have been developed, which can support
institution is a consortium of research collaboration among large engineering loads and high pressures at room tem-
the US Army, the Massachusetts Institute of Technology peratures. A research group in Belgium is exploring the
(MIT), and several industrial organizations. The research possibility of developing novel yarns by melt extruding a
conducted by this consortium is dedicated to developing, range of nano-additives [85]. Research in this sector has
mainly for the military, advanced textile materials and led to a number of significant developments, such as:
products by utilizing NT. The main focus is to develop a
variety of textile fabrics and other products/materials that a. anti-SARS masks for use by medical personnel [86];
are lightweight (so that the overall load on soldiers can be b. acoustic fibers for automotive textiles [87];
reduced significantly), strong, abrasion/wear resistant, c. nano-surfaces suitable for bioactive culture matrices,
durable, waterproof, capable of changing color (to improve textile nano-sensors, and microelectrodes [88,89];
camouflage), energy absorbent (bulletproof), temperature d. wireless sensing devices;
Modern Applications of NanotechnoLogy in Textiles A.P.S. Sawhney et aL. 737

e. Dyneema® (a high performance polyethylene fiber) repellant, while still maintaining the cotton's well admired,
combined with CNT; and excellent comfort character, and aesthetics. By deploying
f. electronically, chemically, and/or biologically inte- NT, ultra-strong, durable, and specific-function-oriented
grated smart fabrics [90-92]. fabrics can be efficiently produced for a number of end-use
applications, including medical, industrial, military, domes-
Recently, USDA researchers have developed a patented tic, apparel, household furnishing, and much more. It is
technology for producing cellulose-based nano-compos- now conceivable that by combining the optical fibers,
ites, using nano-particles of clay as the nano-filler material micro mirrors, functional coatings, and electronics, cus-
[93]. Cellulose from a variety of very cheap sources, such as tomized fabrics and garments can be developed, which will
grass, kenaf, cotton fiber, cotton plant material, etc., may change their colors as per the consumer's desire and taste.
be used. These composites improve the thermal stability The textile industry certainly has the biggest customer base
of the cellulose and, therefore, may lead to the develop- in the world. Therefore, the advances in the customer-ori-
ment of certain flame-retardant end-products, such as ented products will be the main focus for future NT appli-
non-wovens, special-purpose papers, filaments, coatings, cations, and the textile industry is expected to be one of the
etc. main beneficiaries. However, it goes without saying that
In addition to the development of improved textile fab- there certainly are some limitations and unknown health
rics and materials, several advances in the area of textile risks pertaining to the rapid development and growth of
processing have also been made. For example, the textile NT and also their end-use products. For example, it is
dyeing and finishing processes use dyes and other chemicals extremely difficult and complex to process carbon fibers of
that are expensive and cause a serious environmental con- < 200 nm with traditional textile practices and procedures.
cern when after processing the effluents are discharged into Regarding safety of personnel involved in production, con-
public waterways. Nano-filtration membrane technology version and even use of nano-fibers and their products, we
developed in recent years is being aggressively investigated still do not know of any short-term or long-term (unknown)
to try to recover the dyes for economic and environmental health risks, especially the probable risks of pulmonary
benefits and, at the same time, conserve precious water [94- (lung) diseases due to the "nano-size" of the particles
97]. Nano-filtration technology consists of a separation involved. The Washington Post recently had raised an alert
process in which relatively small organic molecules along to this effect [105].
with some ionic components are retained by a nano-porous
membrane. These grafted membranes are capable of
removing the dye molecules, so that the dye can be recov- Acknowledgment
ered and the processed water can be recycled and reused This study was partly supported by the specific cooperative
[98-101]. A novel, spiral-wound membrane technology also research grant by the Southern Regional Research Center,
exists for the treatment of textile effluents, using nano- and Agriculture Research Service, United States Department
ultra-filtration units [102]. NT is also widely applied in the of Agriculture (SRRC-ARS-USDA). This article is an
developments of pigment particles used for dyeing and extension of the underlying research project on size-free
printing of textile fabrics [103]. Recently, in order to mass weaving and the research collaboration between the Loui-
produce nano-fibers for textile applications, Nanospider' siana State University and the Cotton Chemistry and Utili-
technology was invented and patented by the researchers at zation (CCU) Research Unit of SRRC-ARS-USDA, New
Technical University of Liberec (Oldtich Jirsák) [104]. Orleans, Louisiana.

Summary Literature Cited


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7.
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EM 738 Textile Research Journal 78(8)

10. Dalton, A., Collins, S., Muñoz, E., Razal, J., Ebron, V. H., Fer- 43. Linford, M. R., Soane, D. S., and Offord, D. A., US Patent
raris, J., Coleman, J., Kim, B., and Baughman, R., Nature, 423, 6,855,772 (to Nano Tex LLC.), 15 February 2005.
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