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Depression
Driving Question
How can you determine the molecular weight of a compound by measuring the freezing
point depression?
Background
Understanding the process by which solutions are made helps one understand colligative
properties. The solution process involves breaking bonds and forming new bonds. The
bonds between ions and molecules in solid phase have to be broken (ionic bonds in ionic
lattices, or intermolecular forces between molecules in molecular compounds) and some
bonds among the solvent molecules have to be broken to accommodate the dissolved
particles. These steps require energy.
The ions formed or molecules freed form bonds with the free solvent molecules. This
process releases energy. The result of these three energy changes is the “heat of
solution,” which can be positive or negative. A positive energy change indicates an
endothermic solution process; a negative energy change indicates an exothermic
process.
Because of the bonds formed between the solute and solvent molecules, a solution has
fewer "free" solvent molecules available to escape from the liquid phase into the gas
phase. This important consequence means that the vapor of the solvent builds a lower
vapor pressure over the solution. Use the phase diagram to understand the effect of the
lower vapor pressure.
The top diagram applies to the states of matter of a substance in general. The bottom
diagram compares the freezing and boiling points of a solution and the pure solvent.
D Critical
point B
Solid Liquid Gas
Vaporization
Condensation
Melting
Freezing
A Triple Point
Sublimation
Deposition
C
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Lab 4: Molecular Weight by Freezing Point Depression
Pressure
1 atm
Solid Liquid Gas
Pure liquid
solvent
Triple point of
solvent
Solution
Pure solid
solvent Triple point of solution
Freezing point of solution Boiling point of solvent
} Freezing point of solvent Boiling point of solution
}
ΔTf Temperature ΔTb
The phase diagram shows how the vapor pressure over a solution is lower at any given
temperature compared with the solvent. Because of the lower vapor pressure over
solutions, the vapor pressure reaches the atmospheric pressure at a higher temperature
than the boiling point and at a lower temperature than the freezing point of the pure
solvent. Compared with pure solvent, the freezing point of solutions is lower and the
boiling point of solutions is higher.
Note that the standard freezing point phase transition occurs at atmospheric pressure
and the standard boiling point phase transition occurs at atmospheric pressure.
The respective temperature changes are referred to as the freezing point depression
(ΔTf) and boiling point elevation (ΔTb).
F
Vapor
E
D
Liquid and vapor
(vaporization)
Liquid
B C
Solid and liquid (melting)
A Solid
The temperature of solid (AB), liquid (CD), and gas (EF) phases increases as heat is
absorbed. However, at the freezing point and boiling point the temperature remains
constant while the heat of fusion (BC) and heat of vaporization (DE) are absorbed. In this
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Student Inquiry Worksheet
activity students will perform the process in the reverse direction: instead of heating,
they will cool a liquid solvent and solution until it freezes.
Safety
Add these important safety precautions to your normal laboratory procedures:
♦ Handle the hot water bath carefully while mounting and removing the test tube.
♦ Upon completion, wash all equipment properly with the assigned solvent for cleaning.
Sequencing Challenge
The steps below are part of the Procedure for this lab activity. They are not in the right order. Determine
the proper order and write numbers in the circles that put the steps in the correct sequence.
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Lab 4: Molecular Weight by Freezing Point Depression
Measure about
0.50 g of the Measure about
Melt the contents
unknown sample 8.0 g of solvent
of the test tube Record the
to the nearest and place it into a
and dissolve the cooling curve of
milligram and test tube. Melt
solution with the the solution.
add it to the the contents of
unknown solute.
solvent in the test the test tube.
tube.
Start data
collection and
From the freezing
record the
point depression,
cooling curve
calculate the
while stirring the
molecular weight.
solvent in the test
tube.
Procedure
After you complete a step (or answer a question), place a check mark in the box () next to that step.
Note: When you see the symbol "�" with a superscripted number following a step, refer to the numbered Tech
Tips listed in the Tech Tips appendix that corresponds to your PASCO data collection system. There you will find
detailed technical instructions for performing that step. Your teacher will provide you with a copy of the
instructions for these operations.
Set Up
2. Connect the stainless steel temperature sensor to the data collection system. �(2.1)
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Student Inquiry Worksheet
7. Use a clamp to connect the test tube to the ring stand so it is immersed in the
water as far as possible. If necessary, add more water to the beaker.
8. Wrap the copper wire coil around the stainless steel sensor. Clamp it to the ring
stand and insert it into the test tube as shown in the illustration.
Collect Data
Important: Make sure there is no loss of the sample when doing a transfer.
11. When the crystals melt, place the stainless steel sensor with the copper coil
wrapped around it into the melted crystals.
12. What is the white deposit and why does it appear on the sensor?
13. Once the test tube is clear (the crystals are melted),
remove the test tube from the water bath, with the
sensor and coil still in it, and clamp it in the empty
Erlenmeyer flask.
17. Mount the test tube into the water bath again and allow the contents of the test
tube to melt.
18. Measure about 0.5 g of the unknown sample to the nearest 0.01 g and record the
mass in Table 1.
Important: Make sure there is no loss of the sample when making the transfer.
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Lab 4: Molecular Weight by Freezing Point Depression
20. What happens if you lose some of the sample during the transfer?
21. Once the test tube is clear (the crystals are melted), remove the test tube from
the water bath, with the sensor and coil still in it, and clamp it in the empty
Erlenmeyer flask.
Important: Do not stop stirring while collecting data. Even a few seconds without stirring can affect your
graph.
22. Start the data recording �(6.2) and start stirring the contents of the test tube by
moving the copper coil up and down.
23. Once the contents of the test tube are completely solidified, stop data recording.
�(6.2)
25. From the curves, locate the freezing points of the pure solvent and the solution.
Record these in Table 1.
27. Melt the contents of the test tube again and dispose of the chemicals into the
designated waste container.
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Student Inquiry Worksheet
Data Analysis
Parameter Value
Freezing point of lauric acid mixed with the unknown solute (°C)
Possible solute
2. Calculate the number of moles of the solute used, based on the calculated formula weight and
determine the molality of the solution.
3. Based on the formula weights of the compounds in Table 2, what solute have you
been using? Record it and its formula weight in Table 1.
Salicylic acid
138.1
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Lab 4: Molecular Weight by Freezing Point Depression
Benzoic acid
122.4
Acetylsalicylic acid
(aspirin)
180.2
Acetyl phenol
136.1
4. Determine the percent error between the experimental molar mass and the molar
mass from Table 2.
5. What are the sources of error?( explain how each error would affect the results as
it did)
6. Sketch or paste the graph with the cooling curves as shown in the example
below. Label the curve corresponding to the solvent and the curve corresponding
to the solution.
1. Why is lauric acid the solvent in this experiment, even though lauric acid is
solid at room temperature and solvents are usually liquids at room
temperature?
2. How would the error show itself if the test tube was dirty?
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Student Inquiry Worksheet
4. Why would you collect data for an additional cooling curve with additional
unknown sample?
B. Assuming the same mass of unknown A and B (ms) and the same mass of
solvent (msolvent) are used, a greater freezing point depression with A would
mean that A has a greater formula weight than B.
C. Assuming the same mass of unknown A and B (ms) and the same mass of
solvent (msolvent) are used, a greater freezing point depression with A would
mean that B has a smaller formula weight than A.
D. Not enough information
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Lab 4: Molecular Weight by Freezing Point Depression
Pre-Lab Activity
As a solute is added to a solvent, the freezing point of the resulting solution is lowered.
The freezing point depression of the solution is dependent on two things: the solvent and
the amount of solute added. However, it does not depend on the nature of the solute.
The following equation describes this relationship:
ΔTf = K f m
where
ns
ΔTf = K f
msolvent
where
ms
ns =
F Ws
where
ms
FWs ms
ΔTf = Kf = Kf
msolvent msolvent FWs
ms
FWs = K f
ΔT f msolvent
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Student Inquiry Worksheet
In this experiment, you will measure the freezing point of a pure solvent, lauric acid
(dodecanoic acid). You will measure the freezing point of a mixture of lauric acid and an
unknown solute. From the freezing point change, the formula weight of the solute can be
calculated.
To obtain the cooling curve, the melted solvent or the melted solution must be cooled
very slowly. During this time, the temperature of the system is monitored and the
contents of the test tube are continuously mixed.
The freezing point of the pure solvent is 43.8 °C. The freezing point of the solution is
41.2 °C. Therefore the freezing point depression is 2.60 °C, or 2.60 K.
Substituting these values into the relevant equation to find the formula weight:
FWs = 3.90
K kg ( 0.9407g) = 166
g
mol ( 2.60K ) ( 0.00850kg) mol
1. Why is the vapor pressure lower over solutions than over the pure solvent?
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2. How does a lower vapor pressure result in standard boiling point elevation?
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Lab 4: Molecular Weight by Freezing Point Depression
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3. Knowing how the heating curve looks, sketch a graph of the cooling curve
starting from the liquid phase and ending with the solid phase. Label the axes,
the points where freezing starts, freezing ends, and label the freezing point.
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5. Using the fact that the temperature remains constant at the freezing point
for a an interval of time, how would you measure the freezing point change of
a solution relative to the freezing point of a pure solvent?
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