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Arab J Geosci

DOI 10.1007/s12517-010-0135-0

ORIGINAL PAPER

Mapping groundwater contamination risk using GIS


and groundwater modelling. A case study from the Gaza
Strip, Palestine
Husam Musa Baalousha

Received: 26 October 2009 / Accepted: 8 March 2010


# Saudi Society for Geosciences 2010

Abstract Increasing pressure on water resources worldwide Introduction


has resulted in groundwater contamination, and thus the
deterioration of the groundwater resources and a threat to the Groundwater is an invaluable source of drinking water in
public health. Risk mapping of groundwater contamination is many areas around the world. Due to extensive pumping,
an important tool for groundwater protection, land use agricultural, and industrial activities, aquifers are at risk of
management, and public health. This study presents a new being contaminated. Intensive application of pesticides and
approach for groundwater contamination risk mapping, based fertilisers, discharge of wastewater, and industrial effluent and
on hydrogeological setting, land use, contamination load, and excessive groundwater abstraction are just a few examples of
groundwater modelling. The risk map is a product of activities that lead to groundwater contamination. These
probability of contamination and impact. This approach was activities have resulted in the deterioration of water resources
applied on the Gaza Strip area in Palestine as a case study. A in various regions around the world (Pandey et al. 1999).
spatial analyst tool within Geographical Information System Aquifers are valuable sources for water. Therefore, a quick
(GIS) was used to interpolate and manipulate data to develop action should be taken to prevent aquifers from contamina-
GIS maps of vulnerability, land use, and contamination tion and to reduce the risk of contamination impact.
impact. A groundwater flow model for the area of study was Groundwater contamination risk mapping can help
also used to track the flow and to delineate the capture zones planners and decision-makers on proper land use and water
of public wells. The results show that areas of highest resources management. This will enable incorporation of
contamination risk occur in the southern cities of Khan Yunis groundwater protection and health impact assessment in the
and Rafah. The majority of public wells are located in an analysis. Risk mapping is not only a preventative measure
intermediate risk zone and four wells are in a high risk zone. but it also assist with mitigation processes of groundwater
contamination.
Keywords Groundwater contamination . Risk mapping . Risk, by definition, is the probability of an event
GIS . MODFLOW . Capture zones . Vulnerability . multiplied by its impact. In environment context, risk is
Gaza Strip . Drastic the probability that a hazard will turn into a disaster. In
groundwater context, risk can be defined as the probability
that groundwater at a drinking well becomes contaminated
to an unacceptable level by activities on the land surface
(Morris and Foster 1998).
H. M. Baalousha (*) Risk can be reduced by implementing a mitigation
Hawke’s Bay Regional Council,
strategy with best management practice. Best practice
159 Dalton Street,
Napier 4110, New Zealand avoids high-risk areas when locating a site of possible
e-mail: Baalousha@web.de pollution potential.
Arab J Geosci

Geographical Information System (GIS) has been widely drawback of geostatistical approach is that it does not
used in risk mapping (e.g., Bartels and Beurden 1998; consider hydrogeological settings that have a significant
Ducci 1999; Al-Adamat et al. 2003; Mimi and Assi 2009). effect on contamination risk.
It is very common to use intrinsic vulnerability either alone In this study, a new approach is proposed for contamination
or coupled with other factors to assess groundwater con- risk mapping. This approach depends on the idea that
tamination risk. The most widely used method for intrinsic groundwater contamination risk is a product of probability
vulnerability assessment is the DRASTIC approach (Aller of contamination occurring and contamination impact. A
et al. 1985). DRASTIC is based on seven hydrogeological contamination risk map is a function of probability overlaid
parameters: Depth to water table, Recharge, Aquifer media, with a map of potential impact of groundwater contamination.
Soil media, Topography, Influence of vadose zone, and The resultant convergence of probability of contamination and
hydraulic Conductivity to assess the intrinsic aquifer contamination impact is and assessed geospatially on map as a
vulnerability. Each map is classified and rated, then cross-product of the probability map and the contamination
weighted based on standard DRASTIC weigh system (Aller impact map. In the case study presented in this paper, the
et al. 1985). Vulnerability index is the sum of each rated contamination probability map was created based on a
map multiplied by its respective weight as shown in the previous work by the author using the DRASTIC approach
equation below. The final DRASTIC product is a map (Baalousha 2006). In this paper, the vulnerability map was
showing vulnerability index. DRASTIC has been used in coupled with land use to represent the probability of
different studies to assess aquifer vulnerability (e.g., contamination. The impact map was based on two factors:
Lasserrea et al. 1999; Baalousha 2006; Nobre et al. 2007; health impact of major contaminants in the area of study and
Assaf and Saadeh 2009). the public water supply capture zone.

DRASTIC index ¼ Dr  Dw þ Rr  Rw þ Ar  Aw
Methodology
þ Sr  Sw þ Tr  Tw þ Ir  Iw
þ Cr  Cw ð1Þ The assessment of groundwater contamination risk requires
two main factors: probability of contamination and the
Where r and w denote DRASTIC rating and weight, contamination impact, as depicted in Fig. 1. For example,
respectively. when a site has a high contamination probability but has a
In many studies, vulnerability map was coupled with low impact of contamination, then the risk is low. But when
hazard map or land use map to produce risk maps (Ducci both contamination impact and probability of contamina-
1999). For example, Al-Adamat et al. (2003) have coupled
a DRASTIC vulnerability map with a land use map to
produce a risk map.
Intrinsic vulnerability is a good measure of weaknesses of
an aquifer, as it considers the hydrogeological characteristics
of the area under consideration. Intrinsic vulnerability alone,
however, is not a measure of risk. Using vulnerability alone,
or with land use to represent the risk, lacks the contamination
impact, which is an essential factor for risk assessment. In
addition, the movement of contaminants in the groundwater,
which affects the capture zone around wells, is not considered
in this approach. A highly vulnerable area, for instance, is not
under contamination risk unless it is susceptible to a
contamination source and the contamination impact is high.
Other approaches of groundwater contamination risk
mapping use a probability map of contaminants distribution
(Zhu et al. 2001; Wackernagel et al. 2004; Amini et al.
2005). The probability map approach uses geostatistics
(i.e., kriging) to interpolate the actual concentration of a
certain contaminant in groundwater and to create a
groundwater contamination probability map. The main Fig. 1 The concept of groundwater contamination risk mapping
Arab J Geosci

tion are high, then the risk is high. Thus, the contamination necessary to consider the capture zones of public water
risk (R) can be written as: supply.
For the study area, maps of vulnerability and land use were
R ¼ pðcontÞ \ pðimpactÞ R 2 ½0; 1 ð2Þ
combined using the Spatial Analyst tool of ArcMap from
where, p(cont) is the probability of contamination; p(con) ∈ ESRI® to produce a contamination probability map. The map
[0,1] and p(impact) is the impact of contamination; p of well capture zones was combined with the map of
(impact) ∈ [0,1. contamination health impact to produce a contamination impact
Using Eq. 2, a map of contamination probability can be map. The final risk map was produced by multiplying the
classified in the probability space; that is p ∈ [0,1], and the contamination probability and the contamination impact maps.
same for contamination impact (Fig. 1). The cross-product
of both maps is the risk map. The study area
A flowchart of stepwise methodology is shown in Fig. 2.
The first step is to prepare the contamination probability The Gaza Strip area is located at longitudes 31° 25′ North and
map, which comprises intrinsic vulnerability and land use. In latitude 34° 20′ East. It extends 40 km along the south-eastern
this study, DRASTIC intrinsic vulnerability map was used shore of the Mediterranean. The Strip is situated on a wide
(Baalousha 2006). The vulnerability map was then coupled Palestinian coastal plain. The total area of Gaza Strip is about
with land use to create a probability map. It was important to 365 km2 and more than 1.4 million inhabitants are living in
combine the land use map with the vulnerability map as both this small area (Palestinian Central Bureau of Statistics
affect the probability of contamination. The vulnerability (PCBS) 2009). The population density in Gaza Strip is one of
map shows intrinsic weaknesses of the hydrogeological the highest in the world, especially in the eight refugee camps.
system and the land use map represents potential sources Because of its location, the Gaza Strip forms a transitional
of contamination (point source and non-point source) such as zone between the semi-humid coastal area in the north and the
wastewater treatment plants. Aquifers in high vulnerability semi-arid Sinai desert in the south (EUROCONSULT and
areas are more likely to be contaminated than other areas. IWACO 1994). The area is characterised by a Mediterranean
The impact map was based on a combination of two climate with 4 months of hot dry summer and a short winter with
factors. These factors are the contamination health-impact rain from November to March. The average summer and winter
of major contaminants in groundwater and the capture temperatures in Gaza Strip are 25°C and 7°C, respectively.
zones of drinking water supply. The classification of the
impacts of different contaminants in groundwater is Hydrogeology and water resources
important as different contaminants in groundwater have
differing impacts on public health. Nitrate contamination The aquifer system in Gaza Strip is part of the larger
health impact, for example, is worse than chloride contam- Palestinian coastal plain hydrogeological system, which
ination (Baalousha 2008). Because the impact of contam- extends from Haifa City in the north to Sinai desert in the
ination is in the vicinity of the drinking water wells, it south and over an area of about 2,000 km2 (Metcalf and
Eddy 2000). The Palestinian coastal plain is characterised
by flat relief, and is bounded to the east by the foothills of
the West Bank mountain belt. This plain is narrow in the
north and gets wider in the south. It has an average width of
about 13 km. The main aquifer formation is composed of
calcareous sandstone and gravel from the Pleistocene age
and recent Holocene sand dunes. Some silts, clay, and
conglomerate exist in the aquifer formation. Three main
clay layers intercalate the aquifer and divide it into three
main sub-aquifers in the west (Fig. 3). These clay layers
extend from the shore in the west to about 3-5 km inland.
Thus, the aquifer is mainly unconfined in the eastern part and
confined/unconfined in the western part. Aquifer thickness
varies from a few metres in the east of Gaza Strip to about
170 m near the shoreline. The aquifer overlies thick
impermeable marine clay of the Tertiary age called the
Fig. 2 Groundwater contamination risk mapping Saqaya Formation (EUROCONSULT and IWACO 1994).
Arab J Geosci

Fig. 3 Conceptual hydrogeological west-east cross-section

Fig. 4 Vulnerability map for


the Gaza Strip based on
DRASTIC approach
Arab J Geosci

Fig. 5 Land use map for


the Gaza Strip and locations
of wastewater treatment
plants (WWTP)

Groundwater is the only source of water supply in the obtained from Palestinian Water Authority). Only part of
area as there is almost no surface water. The natural this precipitation percolates into the aquifer and contributes
groundwater flow pattern is from east to west. However, the to aquifer recharge and the rest is lost evapotranspiration.
natural flow pattern was disturbed due to intensive pumping
at different locations, especially in densely populated areas DRASTIC vulnerability
like Gaza City.
Wadi Gaza (ephemeral stream) runs across the Gaza The intrinsic vulnerability map for the Gaza Strip was
Strip from the Naqab desert and the Hebron Mountains in the created using the DRASTIC approach (Fig. 4), which was
east and drains into the Mediterranean. The catchment area of done by author (Baalousha 2006), and briefly discussed
Wadi Gaza is about 3,500 km2 (United Nations 2003). Before hereafter. Seven maps were prepared using ArcGIS. Hydro-
1967, flash floods in the Wadi closed the main motorway in geological parameters for DRASTIC mapping such as
the strip for few days each year (Al-Agha 1995). However, hydraulic conductivity and aquifer properties were based on
no water flows in this Wadi anymore since Israel has built literature data and data obtained from the Palestinian Water
many dams just behind the border of the Gaza Strip Authority (PWA). Groundwater recharge data was based on a
preventing most of the natural water flow from reaching previous study (Baalousha 2005). Topography data was
Gaza (Al-Agha 1995; EUROCONSULT and IWACO 1994; obtained from PWA in digital format, and groundwater level
United Nations 2003). Currently, the Wadi is used as an records were obtained from monitoring data of PWA.
effluent discharge channel for the raw sewage from refugee Figure 4 shows that areas close to the coast have the
camps adjacent to the watercourse, estimated at 6,000- highest vulnerability. This is because groundwater is shallow
8,000 m3/day (United Nations 2003). in that area and the area is covered by sand dune formations.
The coastal aquifer beneath the Gaza Strip is recharged In addition, this area receives the highest recharge. On the
by rainfall, at an average annual rate of 300 mm (data contrary, the area east of Khan Yunis has the lowest
Arab J Geosci

Table 1 Different land uses and their potential pollution impact level agricultural practices, including the heavy application of
(Baalousha 1998) pesticides and fertiliser and leakage from three sewage
treatment plants. In built-up areas such as Khan Yunis City,
Land use Impact
the use of cesspits is the only means for domestic
Wastewater treatment plants and unsewered areas 6 (high) wastewater discharge. High levels of nitrate have been
Green houses 5 detected in groundwater in that area. The detected high
Citrus 4 nitrate concentrations are directly related to wastewater
Grapes 3 leakage (Baalousha 2008).
Olives 2
Some types of agriculture such as citrus traditionally
Dates and almonds 1
receive higher fertiliser loadings, and thus, their environ-
Open fields (no irrigation) 0 (low)
mental impact is high. Other types of agriculture like dates
and olives may have less potential impact on the environ-
ment. These have been classified from high to low in
vulnerability because the vadose zone is thick and the Table 1.
recharge rates are low.
Contamination probability map
Land use
The groundwater contamination probability map (Fig. 6) is
The land use map of the Gaza Strip is shown in Fig. 5. The a combination of the DRASTIC index vulnerability map
main potential source of contamination in the area is from (Fig. 4) and the land use map (Fig. 5). Both DRASTIC

Fig. 6 Probability of ground-


water contamination in the
Gaza Strip
Arab J Geosci

index and land use were given equal weights as they The recharge boundary was based on rainfall-recharge
equally affect the groundwater contamination and reclassi- analysis. Annual rainfall varies between 200 mm in the
fied within the probability space. south to 450 mm in the north.
There are about 110 municipal water wells for public
Well capture zone water supply in the Gaza Strip. Drinking water well
abstraction data was obtained from PWA. The hydraulic
An existing finite difference groundwater flow model properties were obtained from pumping test data, PWA, and
(Baalousha 2003) was used as a basis to delineate capture from literature (i.e., Metcalf and Eddy 2000).
zones of public drinking water supply wells in the area at Particle tracking (Pollock 1989) within the Processing
different times (1, 2, 5 and 20 years). The advective Modflow Package was used to delineate the capture zones of
transport code PMPATH of Processing MODFLOW pack- public water wells at different time intervals. The backward
age was used for this purpose (McDonald and Harbaugh tracking (Fig. 7) shows capture zones for periods of 1, 5, 10,
1988). and 20 years. Potential pollution in areas within capture zones
The aquifer system consists of calcareous sandstone and of wells will have a higher impact on public health. All known
conglomerate with intermittent clay layers of different public water supply wells have been considered in this study.
thicknesses. The basement of the aquifer is a thick
impermeable clay layer called the “Saqya Formation” Potential sources of pollutants and their possible impact
(Fig. 3). Groundwater flows from east to west, perpendic-
ular to the shoreline. The western boundary of the model In the Gaza Strip, nitrate is considered a major groundwater
(the Mediterranean) was considered a constant head contaminant (Shomar et al. 2008) and is believed to be
boundary. anthropogenic (Al-Agha 1997; Baalousha 2008).
Fig. 7 Modeled capture zones
of public water supply wells in
the Gaza Strip
Arab J Geosci

Fig. 8 Nitrate, chloride, and


fluoride impact map for the
Gaza Strip

Infants of 6 months or less are the most vulnerable to coning of brackish water and brines as a result of heavy
nitrate impact in drinking water, as it can cause methae- pumping (e.g., Gaza City, Khan Yunis; Qahman and Larabi
moglobinaemia (also known as blue baby syndrome). 2003).
Several cases of methemoglobin have been reported in Fluoride in groundwater originates from phosphates
Gaza Strip in the last few years (Abu Maila et al. 2004). derived by natural dissolution of phosphate minerals and
Pathogens and viruses can also arise from wastewater long-term weathering of phosphates (Al-Agha 1995). High
discharge and agricultural activities. While pathogens and fluoride concentrations, above the WHO limit (1.5 mg/l) have
viruses may be naturally eliminated through attenuation been detected in the southern areas of Gaza Strip (i.e., Khan
processes in the unsaturated zone, nitrate is more difficult to Yunis and Rafah). Excess amount of fluoride in groundwater
mitigate. can cause fluorosis, which affects the teeth and bones (WHO
The second widely spread contaminant in groundwater 2009). Long-term ingestion of fluoride can lead to potentially
in the area is chloride, resulting in high salinity. There is no severe skeletal problems (WHO 2004). There is a high dental
known health impact of high chloride in groundwater. The fluorosis index in Gaza Strip (WHO 1999). Shomar et al.
250 mg/l maximum concentration limit assigned by World (2004) have found a correlation between high fluoride
Health Organisation (WHO 2004) is aesthetic based. concentration in drinking water and dental fluorosis among
However, high chloride makes water non-potable. Less school children in the Gaza Strip.
than 10% of groundwater in the area meets the WHO Other pollutants such as heavy metals were found to
standards for chloride. There are two sources of high have concentrations below the maximum permissible limits
chloride concentrations in the area. The first is through assigned by the WHO. In summary, the major identified
seawater intrusion, especially in Khan Yunis area (Yakirevich contaminants in the area are nitrate, fluoride, and chloride.
et al. 1998) and the Gaza City area. The other source is up- Areas where these parameters exceed the maximum
Arab J Geosci

permissible limits for drinking water have been identified respectively). The resultant map of impact is shown in
based on up to date monitoring data from PWA (WHO Fig. 9.
2004). Figure 8 shows the resulting impact from a
combination of exceedance of the three parameters. Nitrate Risk map
and chloride data from 1990 to date was obtained from
PWA. Fluoride data was obtained from the Ministry of The final risk map was obtained as a cross-product of the
Health. Nitrate and fluoride were given double weights as probability map (Fig. 6) and the impact map (Fig. 9). The
chloride in the pollutants impact map, as they pose higher global risk map is shown in Fig. 10. Risk varies between
threat to health than chloride. 0.0244, which is minimal to 0.786, which is high. The risk
range was divided into equal intervals, as shown in Fig. 10.
Impact map

The impact map was prepared as a combination of the Discussion


capture zone of the drinking water wells and the health
impact of different contaminant in the area of study. The Contamination risk mapping of the Gaza Strip shows that
following sections outline the procedure of each map approximately 34% of the area (124 km2) is located in the
preparation and the combination of the capture zone map very low-risk zone and just less than half of its area 46.5%
and health impact map to produce the impact map. or 170 km2 falls within the low-risk zone (Fig. 10 and
The final impact map was created by combining the Table 2). Intermediate and high-risk areas constitute
capture zone map and pollutants impact map (Figs. 7 and 8, 19.45% of the entire area or 71 km2.

Fig. 9 Impact map for the Gaza


Strip based on well capture
zones and potential contamina-
tions in the groundwater
Arab J Geosci

Fig. 10 Risk map of ground-


water contamination for the
Gaza Strip

Analysis of results revealed that four municipal wells out the high-risk zones. Such mitigation measure can be
of 110 municipal wells are located in a high contamination- achieved using water from these wells for non-drinking
risk zone (risk more than 0.6). The four wells are L/87, L/ purposes or treating the water before drinking.
127, L/43, P/124 and all are located in the Khan Yunis and Figure 10 shows that there are areas where groundwater
Rafah areas. Sampling results of these wells show that they contamination risk is low or very low. These areas are the
have nitrate concentration of more than 200 mg/l on south-eastern and northern areas of Gaza Strip. However,
average, which is four times higher than WHO drinking the aquifer in the south-eastern area is non-productive as
water standards. The majority of wells (88 wells) are the vadose zone there is thick providing high contamination
located in the intermediate-risk zone, with the remainder in attenuation capacity. Some narrow coastal areas at Khan
the low-risk zone. It is important to take action to mitigate Yunis and Rafah in the south have low risk too, because
the potential health impact of drinking water from wells in these areas receive high recharge (covered by sand dunes)

Table 2 Results of the Gaza


Strip groundwater contamina- Risk class Risk index Area (km2) Percentage of total area (%)
tion risk mapping
Very low 0.0-0.1 124.0 33.97
Low 0.1-0.3 170.0 46.57
Intermediate 0.3-0.6 69.7 19.09
High 0.6-0.8 1.3 0.36
Arab J Geosci

and pumping is not intensive. Other areas of low risk are at Aller L, Bennett T, Lehr JH, Petty RJ (1985) DRASTIC: a standardized
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