Professional Documents
Culture Documents
by
ELWIN GREGG COLLIER, B.S.
A THESIS
IN
CHEMICAL ENGINEERING
December, 1980
ACKNOWLEDGMENTS
n
TABLE OF CONTENTS
PAGE
ACKNOWLEDGMENTS ii
LIST OF TABLES iv
LIST OF FIGURES vi
CHAPTER 1 INTRODUCTION 1
CHAPTER 2 LITERATURE REVIEW 3
CHAPTER 3 SOLAR COLLECTOR CLEANING METHOD EVALUATION 17
CHAPTER 4 EXPERIMENTAL APPARATUS AND PROCEDURES 28
System Design 28
Basis for Operating Conditions 34
Preliminary Exposure Tests 36
Basis for Simulation 45
Exposure Tests 46
CHAPTER 5 RESULTS AND DISCUSSION 48
CHAPTER 6 CONCLUSIONS 71
CHAPTER 7 RECOMMENDATIONS FOR FUTURE RESEARCH 72
BIBLIOGRAPHY 74
APPENDIX A 78
APPENDIX B 82
m
LIST OF TABLES
PAGE
IV
PAGE
Table 5.9 Percent Loss in Reflectivity for Exposure
Test IV at 40 Degrees Incidence 59
LIST OF FIGURES
PAGE
Figure 3.1 Schematic of the Reflectometer Used
in this Study 18
Figure 4.1 Schematic of the Duststorm Simulation
Chamber 29
Figure 4.2 Side Cross-Sectional View of the
Exposure and Mixing Chambers 30
Figure 4.3 Cross-Section of the Silica Flour
Auger System 31
Figure 4.4 Effective Particle Size Efficiency
for the Panel Filter Used 35
Figure 4.5 Reflectivity Losses and Velocities for
the First Preliminary Exposure Test
Using Common Glass Mirrors 37
Figure 4.6 Reflectivity Losses and Velocities
for the Second Preliminary Exposure Test
Using Common Glass Mirrors 38
Figure 4.7 Reflectivity Losses and Velocities
for the Third Preliminary Exposure Test
Using Common Glass Mirrors 39
Figure 4.8 Reflectivity Losses and Velocities
for the Fourth Preliminary Exposure Test
Using Carolina Glass Mirrors 40
Figure 5.1 Velocity* Profiles With and Without
Silica Flour and the Additional Braces
for Exposure Test III Conditions 61
Figure 5.2 Velocity* Profiles With and Without
Silica Flour and the Additional Braces
for Exposure Test IV Conditions 62
Figure 5.3 Raw Data on v; and a Coordinates 67
Figure 5.4 Raw Data and Equation (5.13) on L
and \l) Coordinates 68
VI
CHAPTER 1
INTRODUCTION
The growing energy demands of the world and the depletion of petro-
leum reserves have created a serious energy shortage which necessitates
the development of supplemental energy sources. Solar energy is one such
source. Texas Tech University is presently engaged in developing a solar-
to-thermal energy conversion process using a fixed mirror, distributed
focus (FMDF) concept to convert solar to electric energy. The cost and
performance data obtained from this prototype system will provide valuable
information for the design of future solar power electric utilities.
Overall system performance is strongly dependent upon the quality of
the concentrator mirror panels as characterized by reflectivity and dim-
ensional stability. Abrasion resistance is of prime importance in regions
of windblown dust and sand such as the Southwest because of the sandblast-
ing effects on exposed mirror surfaces. This slow abrasion causes a loss
in reflectivity due to an increase in light dispersion.
The purpose of the project was two-fold. Firstly, the development
of a procedure for simulating long-term exposure of mirrors to duststorms
in order to assess the effects on mirror quality as indicated by reflec-
tivity was needed. Secondly, the determination of an economically and
technically practical method to clean the mirror panels in use at the
Crosbyton Solar Power Project (CROSPO) test site was required. Achieve-
ment of the first objective required the simulation of duststorm condi-
tions. This was accomplished by using the kinetic energy of an average
particle found in a worst-case duststorm to fix the velocity of the
1
silica flour particles used in the simulation chamber. The concentration
of the particles was Increased to enhance the rate of collision between
the particles and the mirrors. Using loss In reflectivity as the corre-
lating parameter, the damage occurring from actual duststorm exposure
was compared with that from sample exposure in the simulation chamber.
The result was a predictive equation for the loss in reflectivity with
exposure time.
LITERATURE REVIEW
dv(z) - 3 V ( u ( z ) - v(z))^
dt 8r p'
where
(Gillette and Walker, 1977). The above equation simply states that the
acceleration of the particle is proportional to the difference between
the wind speed and the particle speed, squared, and it varies according
to the particle's size and density.
The particles found in duststorms on the South Plains are of two
basic types: clays which range from submicron to 20 ym and quartz (sili-
con dioxide) which ranges from 20 to 200 ym (Gillette and Walker, 1977;
Gillette, et al., 1974). The size distribution of the particles in the
first 1.3 cm above eroding soil for all cases is highly similar to the
size distribution of the loose particles smaller than 400 ym in the parent
soil. The size distribution very close to the ground thus reflects the
availability of particles from the soil (Gillette, 1976). A sample soil
size distribution is: 88% with diameter greater than 50 ym, 3.2% with
8
diameter between 2 and 50 ym, and 8.8% with diameter less than 2 ym
(Gillette, et al., 1974). From this, the proportion of particles smaller
than 20 ym is very small.
C = C o^z
J ^ )' ^
0
where
C = concentration at height z
Cp = drag coefficient of the particle
C = concentration at height z
K = von Karman's constant
U = mean wind speed
U* = friction velocity = (0^)^^^ U
' = -sed/KU*
^sed ^ sedimentation velocity which is a function of wind
turbulence
Rosinski and Langer (1974) showed that soil particles break upon
impact and that the number of secondary particles increases with increas-
ing particle diameter larger than 10 ym. Fine particulates are also
produced by the sandblasting effect of saltation which acts to dislodge
fine particles from the surfaces of larger particles. Small particles
are also produced when large particles "splash" into reservoirs of fine
particles. These actions and the greater settling velocity of large
particles explain why Gillette (1976) observed that at 1 m above eroding
soil the mass proportion of particles greater than 40 ym is reduced so
that the frequency of occurrence of particles smaller than 20 ym is im-
portant. They also help explain why Barriger (1978) observed mass median
diameters between 5 and 11 ym for duststorms at Crosbyton during the
1977 duststorm season.
The reflectors used in solar collectors are of two basic configura-
tions. If the reflective metal is deposited on the back of an imper-
vious, stable material, the collector is considered a second-surface
reflector. First-surface mirrors have the reflective surface located
on the front (exposed) surface of the substrate. The substrate for a
second-surface mirror is usually chosen for its weatherability; that for
a first-surface is chosen more for its structural properties (Jacobi,
1975).
The materials most commonly considered are polished metals, certain
polymers, and glass. Metals have yet to prove themselves in solar focus-
ing applications because of their loss in reflectivity. Tabor (1959)
reported commercial aluminum mirrors showed a 50% decrease in reflecti-
vity after a few months of outdoor exposure. Silver has the highest
solar reflectance. Unfortunately, it tarnishes and loses its high re-
flectivity quite easily (Bradford and Hass, 1965) and it is too expen-
sive for commercial applications. Chrome-plated and nickel-plated brass
10
sheets have been tried but their low reflectivities made them unsuitable
(Munoz and Almanza, 1978). Super-pure electrolytically anodized aluminum
such as Alzak has been shown to be a good collector (Tabor, 1959;
Meinel and Meinel, 1976) due to the protective qualities of its oxide
film which is ultimately about 40 K thick and relatively transparent
(Bradford and Hass, 1965). A severe problem with first-surface metal
collectors is the extreme care which must be taken to avoid or minimize
scratching either due to manufacturing or regular cleaning. Another
problem is some metals tend to be static prone and attract large amounts
of dust (Lamensdorf, 1976).
Of all the polymers, acrylics seem to be the most durable and demon-
strate the highest outdoor weatherability (Hampton and Lind, 1978). They
are transparent, stable against discoloration, lightweight and show good
resistance to weathering, breakage and chemical attack. They do have a
relatively large coefficient of thermal expansion, a softening point at
about 250°F, and become brittle with age or cold weather. Acrylics may
be extremely clear with transmittance values exceeding that of glass.
Ultraviolet (UV) radiation is the primary cause of degradation. Photo-
degradation of poly methylmethacrylate (PMMA) results in a decrease in
viscosity and in average molecular weight; it also contributes to the
formation of small amounts of volatile products produced by outgassing.
Polycarbonates are receiving much attention in the area of solar
collector development because of their high Impact resistance and high
optical transmission and because they are available in relatively specu-
lar form (less than 2% haze). These materials exhibit poor solvent and
abrasion resistance and show a high degree of yellowing upon outdoor
n
Halocarbon polymers also show some promise for solar energy collec-
tion. Teflon , a fluorinated ethylene-propylene material from this
group, has a solar transmittance comparable to that of glass and exhibits
wery good UV stability. Cross-linking resulting in embrittlement is the
predominant ageing mechanism. It possesses a highly non-wettable sur-
face which tends to attract and hold dust particles making it difficult
to clean (Hampton and Lind, 1978). It is this dust attraction and sub-
D
Some materials which have been tested for the reflective coating in
second-surface mirrors are aluminum, copper, gold, platinum, rhodium and
silver. All except aluminum and silver were found unacceptable because
of their low reflectivities, 76 to 87% (Bradford and Hass, 1965). There-
fore, the primary attention in any study of solar reflectors should cen-
ter around the use of aluminum and silver (Jacobi, 1975). These reflec-
tive coatings may be deposited chemically or in a vacuum. In the case
of chemical deposition, silver produces the best possible second-surface
mirror if the silver is properly sealed to protect it from the environ-
ment. One problem which must be avoided is the Infusion of water between
the reflective coating and the substrate which can result in a separation
of the reflective film.
Aluminum and silver can also be deposited on a substrate by vacuum
evaporation or sputtering. Aluminum deposits easily due to its low melt-
ing point and high vapor pressure. Silver tends to agglomerate upon vac-
uum deposition yielding a poorer reflective surface although it does ad-
here to the substrate much more readily than does chemically deposited
silver. Because of better adhesion, water creep is not often a signifi-
cant problem.
The effect of one duststorm has been noted (Blackmon, 1978). Re-
flectance data was taken on March 2, 1977 and again on March 14, 1977.
The duststorm occurred on March 9, 1977. It was visually observed that
a fine dust was deposited on the surface. The reflectance loss for a
glass heliostat and an acrylic heliostat after the storm was 7.17% and
10.95% respectively. The reflectance of the glass heliostat after cleaning
returned essentially the same pre-storm value (0.5% loss which is within
the standard deviation of + 1% for reflectivity losses). This indicates
that the glass tended to stay cleaner than the acrylic for duststorm con-
ditions, perhaps because dust does not adhere to glass as strongly as to
acrylics.
The objective of outdoor exposure testing is the determination of
the weathering performance of materials for any one or combination of
the following reasons: to provide statistical data regarding the predic-
tion of the Influence of weathering on material properties; as a quality
control technique; or as an end in itself (that is to ascertain the
15
model 750 Carousel projector was used as a point light source. The cal-
culated divergence of the light beam that was passed through the 7 mm
iris was 2 mrad. A 5.6 mm diameter mask was placed over the active area
of the detector to give a 15 mrad acceptance angle. This limits the de-
tection of random scattering from the reflecting surface. The correspond-
ing output from the detector was recorded by a model EU-20B Heath Servo-
Recorder. The mirrors were adjusted to provide the maximum reading at
17
18
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each point. The points were selected at random to provide a true measure
of the reflectivity.
Because of a limited supply of the Carolina glass mirrors used at
the Crosbyton solar power site, common glass mirrors were used for initial
evaluation of a number of possible cleaning methods. Testing was started
by dividing 24 12.7 cm by 12.7 cm (5 in. x 5 in.) common glass mirrors
into eight groups of three. The initial reflectivity of each mirror was
determined and the homogeneity of variance of the groups was verified by
an F-test at the 5% significance level. Next, each mirror group was
cleaned in a different way to evaluate the effect of cleaning method on
reflectivity. The cleaning methods used were:
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the water evaporated naturally 21 times. All the mirrors were then
brought inside and stored in a sealed plastic bag until reflectivity
testing. The results of these treatments were exceedingly low reflecti-
vities, about 5% before cleaning. The mirrors were then separated into
2 groups and cleaned either with high pressure tap water alone (HP) or
high pressure soap followed by a DMDI rinse (HS, DR). Although there was
high variability in the reflectance values, t-tests based on reflectivity
measurements at four randomly selected sites on each mirror indicated no
difference in HS, DR vs. HP either before or after cleaning for all treat-
ments. The data also showed that both cleaning techniques Increased the
reflectivity of both groups as shown in Table 3.2.
which were:
p
1) Glass Plus (household window cleaner)
p .
2) ECG (commercial glass cleaner and degreaser) in DMDI water
p
Table 3.2
Caliche - Water 35
CaCO^ - Water 5 40
(Lab)
CaCO^ - Water 13 86
Caliche - Water 4 41
CaC03 - Water 1 26
(Lab)
Caliche - Water 77
24
One of the FMDF panels (#321) was selected at random and brought in
from the field to be tested. The reflectivity was measured before and
after initial cleaning. The initial cleaning method was to wash the panel
with high pressure soap (HS) followed by rinsing one half with deionized
(DI) water and the other half with water purified by reverse osmosis (RO).
Next, the panel was divided into 18 10 cm by 30 cm (4 in. by 12 in.)
areas, 9 on the DI side and 9 on the RO side. Each cleaning method was
tested on both sides. The individual treatments lasted for 90 sec during
which the area was rubbed vigorously. After treatment, the area was wiped
with a clean cotton towel and allowed to air dry. Upon completion of all
treatments, the reflectivity of each area was taken in triplicate (see
Table 3.3 for average results). A case 2 t-test found the DI water side
equal to the RO water side at the 5% significance level. Therefore, aver-
age values were used for comparisons.
Glass Plus gave the highest reflectance (87.8%) and has the advan-
p
tages of being premixed and nonstreaking. The reflectivity of ECG was
86.6% but this material must be mixed. It forms if too concentrated.
p p
Alconox and Finish must also be mixed prior to use. Therefore, Glass
R R R R R
Plus is better than ECG , Alconox or Finish . Bon Ami and steel wool
were eliminated from consideration due to scratching. By comparing re-
ft R
flectivity for Glass Plus with those of indoor-outdoor carpet, Scrunge
R R
Table 3.3
Cleaning Average
Method DI RO % Reflectance
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CHAPTER 4
System Design
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37 cm x 1.9 cm (14 1/2 in. x 3/4 in.) steel shaft, a pillow block, two
flat-back double-sealed bearings, an aluminum cylinder, a steel plug, and
various pulleys. One end of the shaft was machined to have 3.15 left-
handed square threads per cm for 6.3 cm (2.5 in.). The threads were
0.48 cm (3/16 in.) deep. This end of the shaft fit into a 6.4 cm deep x
1.9 cm diameter (2.5 in. x 3/4 in.) longitudinal hole drilled in the
steel plug which was 8.6 cm long x 4.76 cm diameter (3 in. x 1 7/8 in.).
The other end of the shaft was supported by the pillow block. The bear-
ings provided support along the shaft. The steel plug fit securely into
one end of the aluminum cylinder (20 cm long x 10 cm O.D. x 7.76 cm I.D.
(8 in. X 4 in. x 1 7/8 in.)) which also housed the bearings. The pulley
fit on the shaft between the pillow block and the aluminum cylinder. Two
2.5 cm (1 in.) radial holes which extended to the center of the steel plug
were added to the cylinder and the plug. These holes were tapped for a
1.9 cm (3/4 in.) pipe. The first hole; i.e., the entrance port was cen-
tered 5.7 cm (2.25 in.) from the end of the cylinder. The gravity feed
hopper was connected to the entrance port and mounted directly above it.
The second hole (exit port) was centered 2.5 cm (1 in.) from the end and
rotated 180° from the entrance port. A 1.9 cm (3/4 in., sch. 40) pipe
was screwed into the exit port and extended approximately 13 cm (5 in.)
into the mixing chamber. The shaft rpm could be varied by changing
pulleys on the motor and/or on the shaft. A shaft speed of 22 rpms which
resulted in a feed rate of 3 g (j^ 10%) of silica flour per minute was
selected for use in the simulation. This was not critical since the
weathering effect should have been independent of dosage rate as long as
there was no particle-particle interaction.
33
Upon leaving the mixing section of the test chamber, the air and
silica flour were accelerated to the appropriate velocity by a tapered
section of 2 mm thick (14 gauge) sheet metal duct work. The end of this
section was 16.5 cm x 19 cm (6.5 in. x 7.5 in.) and was covered by a 10
mesh (6.3 holes per cm x 0.25 mm diameter wire (16 holes per in. and .01
in. diameter wire)) screen wire supported by a 3.5 mesh (1.57 holes per
cm X 0.64 mm diameter wire (4 holes per in. x 0.025 in. diameter wire))
screen wire. The purpose of the screen wire was to Insure plug flow of
the simulated duststorms as it entered the exposure chamber. The exposure
chamber consisted of a straight run of 30 cm x 30 cm (12 in. x 12 in.)
0.8 thick (22 gauge) sheet metal duct work and a mirror holder which could
contain up to sixteen 3.2 cm x 3.2 cm (1.25 in. x 1.25 in.) mirror speci-
mens. The holder was centered in the oncoming air stream and 25.4 cm
(10 in.) downstream from the screen wire flow diffuser. The mirror samples
were held vertically on the 16.5 cm x 19 cm (6.5 in. x 7.5 in.) holder
and faced into the air stream. The Interior of the exposure chamber could
be viewed through and was accessible by three windows in the sides and in
the top of the duct work around the mirror holder.
metal section. The cyclones were Wm. W. Meyer models HV-14 and HV-18
3 3
with rated capacities of 11.3 m /min (400 cfm) and 18.4 m /min, (650 cfm),
respectively, with 7 cm (2.5 in.) of water resistance. At these flow
rates the cyclones were rated to have a capture efficiency of over 99 plus
34
a Riga-flow 100 panel filter which had a rated capacity of 42.5 m /min
(1500 cfm) with less than 2.5 cm (1.0 in.) of water resistance. Filter
cleaning was accomplished by using a 0.95 cm (3/8 in., sch. 40) pipe as
a nozzle to blow 414 kPa (60 psi) air backwards through the filter for
cleaning purposes. The filter was rated at 95% removal for 2 ym and
larger particles and 99% removal for 4 ym and larger particles and essen-
tially 100% for particles above 15 ym as shown by the efficiency curve of
Figure 4.4. After filtration, the air was vented to the atmosphere. For
this reason, the simulation was conducted outdoors. Dust masks (Part No.
08710, 3M Company, MSA approval no. TC-21C-132) were worn whenever the
system was worked on or in operation for personal protection against the
respiratory hazard associated with exposure to free crystalline silica.
The silica flour used in the simulation had a mass distribution which
was linear on log-probability paper. This Implied that the size distribu-
tion was log-normal with a mass median diameter of 32 ym and a geometric
standard deviation of 1.86 ym.
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41
matched by the point velocity distribution. It was felt that the uneven
air velocities resulted in uneven ageing and were due to the shorter path
length and fewer abrupt changes in the duct work through the HV-14 cyclone.
To correct this pressure drop inequality, four layers of 10 mesh (6.3
holes per cm x 0.25 mm diameter wire) screen wire were added to the top
left-hand quarter. Two layers of this screen wire were added to the
lower left-hand and upper right-hand quarters of the 30 cm x 30 cm (12 in.
X 12 in.) duct work downstream from the mirror holder. The screen wire
that covered the entrance in front of positions P-12, P-15, and P-16 was
also removed. A 2.5 cm (1 in.) extension was added to the top of the
mirror holder. The velocity in front of each mirror position was measured
again. Figure 4.6 shows the results. Based on this data, a second pre-
liminary test using common glass mirrors was conducted. Figure 4.6 also
shows those results. From that test it was obvious that the velocity in-
equality problem had been over-corrected. The 2.5 cm extension was there-
fore reduced to 1.2 cm (0.5 in.) and the gap in the entrance screen wire
over positions P-12, P-15, and P-16 was covered with 6 mesh (3.15 holes
per cm x 0.44 mm diameter wire (8 holes per in. x 0.017 in. diameter wire))
screen wire. After this modification a third preliminary test was con-
ducted. The results are shown in Figure 4.7. After evaluating all of
the available data, a fourth preliminary test using Carolina glass mir-
rors was conducted. The results of that test are shown in Figure 4.8.
Examination of the data by the standard two-way analysis of variance
method indicated that there were no row or column effects at the 90% con-
fidence level. Each mirror position could, therefore, be considered
equivalent to any other position. The simulation chamber was then ready
for the simulated 20-year field exposure tests using Carolina glass mirrors
42
Direction
Northwest
Southwest
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45
r = ill— (A n
^ V + 0.309 ^ ^
3
where: C = concentration in mg/m and
V = visibility in km.
The hourly records of the NWS provided the visibility along with the wind
speed and direction and the time and date of the reading. From this it
was possible to calculate the data in Tables 4.2 and 4.3. When a dust-
storm was beginning and ending, the last and first non-blowing dust times
were also recorded so that they could be used in approximating the total
46
time of blowing dust. The mass, momentum and kinetic energy of the dust
in Table 4.2 take into account the wind direction. Those values were cal-
culated using the velocity component normal to the mirror surface. The
time of blowing dust listed in Tables 4.2 and 4.3 takes into account all
the time when the wind direction was within 90° of the surface normal of
the mirror. The program by which the data in Tables 4.2 and 4.3 was cal-
culated is presented as Appendix A. The data from the National Weather
Service is Included as Appendix B. From the data in Tables 4.1, 4.2 and
4.3, the mirrors averaged a reflectivity loss of one percent eyery 7200
minutes of blowing dust. Since Lubbock averages 223 blowing dust hours
per year and 78% of that is from the southwest quadrant, a new glass mir-
ror facing in that direction would be expected to lose 1.45% of its orig-
inal reflectivity during its first year in the field.
When 908 g (2 lb.) of silica flour were used in the fourth prelim-
inary simulated exposure tests an average loss in reflectivity of 1.9%
was obtained. Therefore the average yearly duststorm exposure can be
simulated by feeding 692.5 g of silica flour through the simulation cham-
ber.
Exposure Tests
The exposure tests were started by cleaning the filter, emptying the
dust arrestor boxes, placing 16 virgin Carolina glass mirrors in the hold-
er, sealing the windows to the exposure chamber, placing a measured amount
of silica flour in the feed hopper and starting the blower and then the
silica flour feed system in that order. The hopper was refilled as nec-
essary until 3460 g (7 lb., 10 oz.) of silica flour had been used. Then
the silica flour feed system and the blower were turned off, the window
47
was opened and four randomly selected mirrors were removed. The system
was then sealed, the hopper filled and the blower and feeder restarted.
This procedure was repeated until all the mirrors had been removed at the
end of the simulated 20-year exposure. Upon removal, the mirrors were
labelled and set aside for at least 24 hours to allow any mirror-dust
interactions to approach equilibrium. The mirrors were then cleaned with
Glass Plus and the reflectivity of each measured at two different in-
cidence angles (10° and 40°) and with five different masks in front of
the detector. The acceptance angles of the masks were 0.5 mrad, 1.0 mrad,
1.5 mrad, 2.0 mrad and 15 mrad. The reflectivity of each mirror at each
angle-mask combination was measured twice. The second measurement was
made after the mirror had been rotated 90° about its surface normal from n
the first reading. The average of the two measurements was used for comp- J
A
utational purposes.
n
%
1?
CHAPTER 5
48
49
The mass weighing factor for each position was determined from
Z [mass collected ]
WF.. = :=1 \ mass fed
k=l\ I^^
/ijk (5 ^j
ij 16 2 /mass collected *\
Z Z I mass fed lijlk/16
j=l k=l ^ '
The mass weighing factors and the measured velocities for each position
at each set of exposure test conditions are given in Table 5.1.
The results of Exposure Test I are shown in Tables 5.2 and 5.3. To
verify that the test was reproducible. Exposure Test II was conducted
using the same mass intervals (3460 g of silica flour) and the same aver-
age velocity (6.7 m/sec) as Exposure Test I. The results of Exposure
Test II are shown in Tables 5.4 and 5.5. Statistical analysis of the
two exposure tests using case 2 t-tests at the 90% confidence level indi-
cated that the two exposure tests were equivalent. Therefore, the test
results were assumed reproducible at the 10% singificance level.
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54
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55
approximately 865 g of silica flour. The results for all 20 test samples rt
are given in Tables 5.8 and 5.9. Exposure Test IV results show more /^
scatter between reflectivity measurements made on the same mirror with
different detector apertures and at different angles than had been ob-
served in earlier tests. These differences were due to non-uniform de-
gradation of the mirror surface resulting from fewer but larger surface
blemishes.
Preliminary evaluation of the test data indicated that each sample
in the bottom row (positions 13, 14, 15, and 16) of Exposure Test IV
showed an unaccountably large degradation. Upon examination of the dust-
storm simulation chamber, four possible causes were found. Firstly, the
braces supporting the mirror holder could have acted as spoilers. Second-
ly, there were some entrance effects such as silica flour deposition be-
low the velocity diffusion screens which could not be quantified. Third-
ly, Exposure Test IV was performed at the highest velocity (12.4 m/sec)
56
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59
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60
and was in the compressible flow region leading to exit effects which
could have been a major factor. And fourthly, silica flour was not being
fed into the system when the velocity at each position was measured. De-
termination of the entrance and exit effects was beyond the scope of this
work.
The effects of the mirror holder braces were examined by adding two
braces to the top of the mirror holder and then re-measuring the velocity
in front of each mirror position. The effect of the silica was examined
by feeding silica flour into the system while measuring the velocity at
each position. These tests were carried out at average wind speeds of
9.5 m/sec and 12.4 m/sec. The various velocities for both sets of tests
4
are given in Figures 5.1 and 5.2. Visual examination of the data indi- I^
cates that the presence of the second set of braces may have caused a ^
shift in the velocity profile. A similar shift was caused by the pre-
sence of the silica flour. Statistical evaluation of the velocities
using standard three-way analysis of variance procedures indicated that
there was no difference between the velocities at the 90% confidence
level.
Further study of all data from Exposure Tests I-IV revealed that
the specimens in positions 13, 14, 15, and 16 always exhibited larger
losses per unit exposure than the other samples in their respective
tests. All the data from those positions was thus discarded.
The reflectivity as a function of the incidence angle and aperture
depends upon the number, size and shape of the mirror's surface blemishes.
It has been shown that those change with length of exposure (Barriger,
1978). The function relating reflectivity to the incidence angle and
61
<
Figure 5.1. Velocity* Profiles With and Without Silica Flour and
the Additional Braces for Exposure Test III Conditions
62
Figure 5.2. Velocity* Profiles With and Without Silica Flour and
the Additional Braces for Exposure Test IV Conditions.
63
The data at the 40° Incidence angle and 15 mrad aperture was con-
sidered to be the most useful data because there were fewer mirror align-
ment problems at 40° than at 10°. The alignment problems at 10° were due
in part to the steeper slope of the mirrors which resulted in less weight
being exerted normal to the mirror mount, causing the mirrors to be more ^
<
I = Nj^ Ap (5.2)
64
R = RQ(I-L) (5.3)
R^ = the i n i t i a l reflectivity
0 "^
Therefore
R^ - R R,
^ =A - =r (5.4)
0 0 i
\
where: R, = loss in reflectivity. .
L is then the normalized loss in reflectivity. A
Since L was the quantity of interest and was directly measurable, jg
no attempt was made to model N^ and A,, separately. ^ can be considered a Z>
function of the number of particles that strike the mirrors, the total [\
mass of the particles and their average speed. The damage mechanisms
are probably related to momentum transport, energy deposition or higher
powers of the particle velocity. Prime candidates for the physical
parameter are thus
^ = J (m V) N dt (5.5)
0 ^
|.T
(m v^) N dt (5.6)
and
65
if = ] (m (v-e) ) N dt (5.7)
0 ^
T = time of exposure
a = characteristic constant
V = velocity of the p a r t i c l e s .
Equation (5.7) represents the most general form of the degradation equa-
where
m v N d t + C J m u^NdT (5.9)
J rT
m vHdt +B m v^Ndt = m^ vNT -t- Bm^y^NT (5.10)
P p p p
and
66
mp NT = a (5.11)
L = A -^ B a y -H D a u ^ (5.12)
t i o n was
data. Figure 5.3 shows the (a,u) data with Equation (5.13) superimposed J
for various values of L. Figure 5.4 shows the (a,v) data and Equation
J '•
I
L = ^^ dt
at (5.14)
o
CM
CD
LO
o 00
I
LO
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CO
O LO
to
cu
03
, CO
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o
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0
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( LUO/6) LU
68
to
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03
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<
03
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CD
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+->
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cu
3
CD
00 CO CM
o
o o o o o
69
or 9
L = B[<v> a(T) + C</> a(T)] (5.17)
The duststorm simulation model does not account for a l l the degrad-
by Chin (1978) was not used because there were only four mirrors in the
measured a f t e r 720 days for the tower mirrors and 1040 days of exposure
storms from January 1 , 1973 through December 31, 1978. Using these values
and the average yearly amount of dust from the west (0.617 g/cm ) in
I
\
i
I
fit
=
CHAPTER 6
CONCLUSIONS
1
\
(
•
1
-4
1
71
CHAPTER 7
would be to determine whether or not the same momentum and kinetic energy g
model apply to all glass mirrors. The next objective in the accelerated
testing program would then be to test different types of materials such
as polymers (polycarbonates, polymethacrylates, and polyacrylates) and
polished metals (Alzak*^, Kinglux CH/4o'^, etc.).
BIBLIOGRAPHY
Berg, R. S.: "Heliostat Dust Buildup and Cleaning Studies," pp. 1-33,
Report N6, SAND 78-0510, Sandia Laboratories, Albuauerque, New
Mexico (1978).
Cowgill, D. M.: "Air Pollution Control, 1970 Annual Report," pp. 1-9,
Lubbock City-County Health Department, Lubbock, Texas (1971).
74
75
Gaines, G. B., Thomas, R. E., Noel, G. T., Shilliday, T. S., Wood, V. E.,
and Carmicheal, D. C : "Development of Accelerated Test Design for
Service-Life Prediction of Solar Array at Mead, Nebraska," pp. 1-24,
Call No. E 1.28, DOE/JPL/954328-10, Battelle Columbus Laboratories,
Columbus, Ohio (1979).
:i
Rainhart, L. G. and Schimmel, W. P.: "Effect of Outdoor Aging on Acrylic .a
Sheet," Solar Energy V7: 259-264 fl975).
Rausch, R. A. and Gupta, B. P.: "Exposure Test Results for Reflective
Materials," paper presented at Solar Reflective Materials Technology
Workshop, Denver, Colorado (1978).
Rosinski, J. and Langer, G.: "Extraneous Particles Shed from Large Soil
Particles," Aerosol Science 5_: 1-6 (1974).
Sidwell, R.: "Sand and Duststorm in the Vicinity of Lubbock, Texas,"
Economic Geography T4: 98-102 (1938).
Skoda, L. F. and Master, L. W.: Solar Energy Systems - Survey of Materials
Performance, pp. 1-57, Report No. NBSIR 77-1314, U.S. Department of
Commerce, Washington, D.C. (1977).
77
Warn, G. F. and Cox, W. H.: "A Sedimentary Study of Dust Storms in the
Vicinity of Lubbock, Texas," American Journal of Science 249:
553-568 (1951).
ni
:»
APPENDIX A
i
1
9
a
01
I
78
79
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^ .— . 0 0 • • I LU— ^ O 2: >^ - ^ Q » • •ii^
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CiO O • 3 3 - ' ^^^d-"—H- Q O vf • CU C < : ^^•^u~.
LU i^—' C:?—* - . ' — * OLU * I— CJ »— Z • w-^—_j
s: <+ —* • 'O oo'-x >a 02 CJ < ^ 2_5:-jL.M
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i~ II c r — X <rLr»t~x <r> ^1- 33LL >ro
II — -»- 3 ' ^ • »>_-LP.'—~>^ — X COCO>I— »
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2: • t n v C ^ r ' - ^ o r - c r : \ ' ^ C i n . .—UJ
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CJC_>LJO
APPENDIX B
•I
82
83
Z\
84
))
II
88
17 : 5 6 3 50 30 0.500
3 40 32 0.750 II
18 : 2 0
1 8 :: 5 6 3 50 25 0.750 :)
3 50 23 1.500 •I
19 : 2 8
1 9 :: 5 4 3 50 25 2.500
2 0": 5 6 3 40 22 3.000
21 :53 DUST NOT BLOWING
89
>i
91